TWM587817U - Wafer bonding film - Google Patents

Wafer bonding film Download PDF

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TWM587817U
TWM587817U TW108206265U TW108206265U TWM587817U TW M587817 U TWM587817 U TW M587817U TW 108206265 U TW108206265 U TW 108206265U TW 108206265 U TW108206265 U TW 108206265U TW M587817 U TWM587817 U TW M587817U
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wafer
bonding layer
layer
intermediate bonding
resin
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范家彰
周弘海
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瑋鋒科技股份有限公司
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Abstract

本創作係一種晶圓接合膜,包括晶圓切割承載層、中間接合層、晶圓接合層,並由中間接合層貼附到晶圓切割承載層,且由晶圓接合層安置晶圓,而且晶圓接合層對晶圓具有優良的黏性,尤其照射紫外光後的晶圓切割承載層對中間接合層會降低黏性或失去黏性,因而晶圓可相當牢固的安置在晶圓接合層上,同時中間接合層可很輕易的脫離晶圓切割承載層,方便進行後續的半導體封裝處理製程,大幅提高整體處理效率及產品良率。This creation is a wafer bonding film, which includes a wafer dicing carrier layer, an intermediate bonding layer, and a wafer bonding layer. The intermediate bonding layer is attached to the wafer dicing carrier layer, and the wafer is placed on the wafer bonding layer. The wafer bonding layer has excellent adhesion to the wafer, especially the wafer cutting carrier layer after UV light irradiation will reduce the viscosity or lose the adhesion to the intermediate bonding layer, so the wafer can be placed relatively firmly on the wafer bonding layer At the same time, the intermediate bonding layer can be easily separated from the wafer dicing carrier layer, which facilitates the subsequent semiconductor packaging processing process, which greatly improves the overall processing efficiency and product yield.

Description

晶圓接合膜Wafer bonding film

本創作係有關於一種晶圓接合膜,尤其是利用中間接合層、晶圓接合層形成雙層結構,並由位於雙層結構下方的中間接合層貼附到晶圓切割承載層,且由位於雙層結構上方的晶圓接合層安置晶圓,而晶圓接合層對晶圓具有優良的黏性,且照射紫外光後的晶圓切割承載層對中間接合層會降低黏性或失去黏性,因而晶圓可相當牢固的安置在晶圓接合層上,同時中間接合層可很輕易的脫離晶圓切割承載層,方便進行後續的半導體封裝處理製程,大幅提高整體處理效率及產品良率。This creation relates to a wafer bonding film, in particular, a double-layer structure is formed by using an intermediate bonding layer and a wafer bonding layer, and the intermediate bonding layer located below the double-layer structure is attached to the wafer cutting bearing layer, and The wafer bonding layer above the double-layer structure is used to place the wafer, and the wafer bonding layer has excellent adhesion to the wafer, and the wafer cutting carrier layer after ultraviolet light irradiation will reduce the viscosity or lose the adhesion to the intermediate bonding layer. Therefore, the wafer can be fairly firmly placed on the wafer bonding layer, and at the same time, the intermediate bonding layer can be easily separated from the wafer cutting carrier layer, which facilitates the subsequent semiconductor packaging processing process and greatly improves the overall processing efficiency and product yield.

在半導體製程中,經多道微影蝕刻處理後的晶圓已包含多個晶粒,且每個晶粒包含電氣電路,需要進行適當切割處理而分離出個別的晶粒,供後續的打線、封裝處理,形成市售的積體電路(IC)。In the semiconductor manufacturing process, the wafer after multiple lithographic etching processes already contains multiple dies, and each die contains electrical circuits. Appropriate cutting processing is required to separate individual dies for subsequent wire bonding, Packaging process to form a commercially available integrated circuit (IC).

為切割晶圓以分離出個別的晶粒,需要先將晶圓固定在特定承載膜上,而習用技術常常使用晶粒貼附膜( Die Attaching File,DAF)當作所需的承載膜。具體而言,晶粒貼附膜的上表面係用以安置晶圓,而晶粒貼附膜的下表面係用以貼附到晶圓切割承載層,其中晶粒貼附膜的上表面對晶圓具有相當的黏性,以穩固晶圓,避免移動,而晶圓切割承載層被照射紫外光後會對晶粒貼附膜的下表面失去黏性,所以能輕易相互脫離。In order to cut the wafer to separate individual dies, the wafer needs to be fixed on a specific carrier film, and conventional technologies often use a die attach file (DAF) as the required carrier film. Specifically, the upper surface of the die attach film is used to place a wafer, and the lower surface of the die attach film is used to attach to a wafer cutting carrier layer, wherein the upper surface of the die attach film faces The wafer is quite sticky to stabilize the wafer and avoid movement, and the wafer cutting carrier layer will lose the stickiness to the lower surface of the die attach film after being irradiated with ultraviolet light, so they can be easily separated from each other.

簡言之,晶粒貼附膜必須對晶圓具有很強的黏性,同時對晶圓切割承載層具有很低的黏性。In short, the die attach film must have strong adhesion to the wafer and low adhesion to the wafer dicing carrier layer.

習用技術中,一般是先調整晶粒貼附膜的上、下界面達到適中的貼附性質程度後,再加入矽氧烷偶聯劑,藉以改善對晶圓面的親和性。然而,上述習用技術的缺點在於無法同時也保持對晶圓切割承載層具有很低的黏性。因此,非常需要一種創新的晶圓接合膜,提高整體的晶圓處理效率及產品良率,藉以解決上述習用技術的所有問題。In conventional technology, generally, the upper and lower interfaces of the die attach film are adjusted to a moderate degree of attach property, and then a siloxane coupling agent is added to improve the affinity to the wafer surface. However, the conventional technique has the disadvantage that it cannot maintain the low viscosity of the wafer dicing carrier layer at the same time. Therefore, there is a great need for an innovative wafer bonding film to improve the overall wafer processing efficiency and product yield, so as to solve all the problems of the conventional technology.

本創作之主要目的在於提供一種晶圓接合膜,包括具電氣絕緣性且由下而上依序堆疊的晶圓切割承載層、中間接合層、晶圓接合層,且中間接合層的厚度係大於或等於晶圓接合層的厚度,可用以接合、承載接合晶圓,並方便對晶圓進行後續處理。The main purpose of this creation is to provide a wafer bonding film, which includes a wafer cutting carrier layer, an intermediate bonding layer, and a wafer bonding layer that are electrically insulating and are stacked sequentially from bottom to top, and the thickness of the intermediate bonding layer is greater than Or equal to the thickness of the wafer bonding layer, which can be used to bond and carry the bonded wafer and facilitate subsequent processing of the wafer.

具體而言,晶圓切割承載層具電氣絕緣性,且具有上表面及下表面,並包含第一樹脂材料、光啟始劑以及氟素修飾丙烯酸樹脂,其中氟素修飾丙烯酸樹脂在晶圓切割承載層中的重量百分比為1~5%,且第一樹脂材料包含丙烯酸樹脂。Specifically, the wafer dicing carrier layer is electrically insulating, has an upper surface and a lower surface, and includes a first resin material, a photoinitiator, and a fluorine-modified acrylic resin. The fluorine-modified acrylic resin is cut on the wafer. The weight percentage in the bearing layer is 1 to 5%, and the first resin material includes an acrylic resin.

中間接合層為電氣絕緣性,且具上表面及下表面,而中間接合層的下表面是貼附到晶圓切割承載層的上表面,尤其,晶圓切割承載層的上表面對中間接合層的下表面具有黏性。此外,中間接合層包含第二樹脂材料、多環樹脂、無機材料以及中間接合層硬化劑,其中第二樹脂材料包含環氧樹脂以及丙烯酸樹脂的至少其中之一,而多環樹脂包含芴環樹脂以及萘環樹脂的至少其中之一,且無機材料在該中間接合層中的重量百分比為50~80%。The intermediate bonding layer is electrically insulating and has an upper surface and a lower surface. The lower surface of the intermediate bonding layer is attached to the upper surface of the wafer dicing carrier layer. In particular, the upper surface of the wafer dicing carrier layer faces the intermediate bonding layer. The lower surface is sticky. In addition, the intermediate bonding layer includes a second resin material, a polycyclic resin, an inorganic material, and an intermediate bonding layer hardener. The second resin material includes at least one of an epoxy resin and an acrylic resin, and the polycyclic resin includes a fluorene ring resin. And at least one of the naphthalene ring resin, and the weight percentage of the inorganic material in the intermediate bonding layer is 50 to 80%.

晶圓接合層為電氣絕緣性,並具上表面及下表面,且晶圓接合層的下表面是貼附到中間接合層的上表面,而晶圓接合層的上表面對晶圓具有黏性,用以貼附而安置晶圓。此外,晶圓接合層包含第三樹脂材料以及晶圓接合硬化劑,其中第三樹脂材料包含環氧樹脂以及丙烯酸樹脂的至少其中之一。The wafer bonding layer is electrically insulating and has an upper surface and a lower surface. The lower surface of the wafer bonding layer is attached to the upper surface of the intermediate bonding layer, and the upper surface of the wafer bonding layer is adhesive to the wafer. For attaching and placing wafers. In addition, the wafer bonding layer includes a third resin material and a wafer bonding hardener, wherein the third resin material includes at least one of an epoxy resin and an acrylic resin.

再者,晶圓切割承載層的光啟始劑是在照射紫外光時促使晶圓切割承載層產生反應,且在反應後,晶圓切割承載層的上表面對中間接合層的下表面失去黏性而相互脫離。Furthermore, the photoinitiator of the wafer dicing carrier layer causes the wafer dicing carrier layer to react when irradiated with ultraviolet light, and after the reaction, the upper surface of the wafer dicing carrier layer loses adhesion to the lower surface of the intermediate bonding layer. Sexually separated from each other.

因此,本創作利用中間接合層、晶圓接合層形成雙層結構,並由位於雙層結構下方的中間接合層貼附到晶圓切割承載層,且由位於雙層結構上方的晶圓接合層安置晶圓,尤其是,晶圓接合層對晶圓具有優良的黏性,而照射紫外光後的晶圓切割承載層對中間接合層會降低黏性或失去黏性。顯而易見的是,晶圓可相當牢固的安置在晶圓接合層上,同時,中間接合層可很輕易的脫離晶圓切割承載層,方便進行後續的半導體封裝處理製程,大幅提高整體處理效率及產品良率。Therefore, this creation uses the intermediate bonding layer and the wafer bonding layer to form a double-layer structure, and the intermediate bonding layer located below the double-layer structure is attached to the wafer dicing carrier layer, and the wafer bonding layer is located above the double-layer structure. When placing a wafer, in particular, the wafer bonding layer has excellent adhesiveness to the wafer, and the wafer dicing carrier layer after ultraviolet light irradiation may reduce or lose adhesion to the intermediate bonding layer. It is obvious that the wafer can be fairly firmly placed on the wafer bonding layer. At the same time, the intermediate bonding layer can be easily separated from the wafer cutting carrier layer, which facilitates the subsequent semiconductor packaging processing process and greatly improves the overall processing efficiency and product. Yield.

以下配合圖示及元件符號對本創作之實施方式做更詳細的說明,俾使熟習該項技藝者在研讀本說明書後能據以實施。 The following is a more detailed description of the implementation of this creation with illustrations and component symbols, so that those skilled in the art can implement it after studying this manual.

請參考第一圖,本創作實施例晶圓接合膜的示意圖。如第一圖所示,本創作的晶圓接合膜包括具電氣絕緣性且由下而上依序堆疊的晶圓切割承載層10、中間接合層20、晶圓接合層30,可用以接合、承載接合晶圓(Wafer)40,方便進行後續的切割、封裝處理。 Please refer to the first figure, which is a schematic diagram of a wafer bonding film of this creative embodiment. As shown in the first figure, the wafer bonding film of this creation includes a wafer dicing carrier layer 10, an intermediate bonding layer 20, and a wafer bonding layer 30 which are electrically insulating and are sequentially stacked from bottom to top, which can be used for bonding, Carries a bonded wafer (Wafer) 40 to facilitate subsequent dicing and packaging processes.

具體而言,晶圓切割承載層10具有上表面及下表面,並且是包含第一樹脂材料、光啟始劑以及氟素修飾丙烯酸樹脂,其中第一樹脂材料包含丙烯酸樹脂,而且氟素修飾丙烯酸樹脂在整個晶圓切割承載層中的重量百分比為1~5%。 Specifically, the wafer dicing carrier layer 10 has an upper surface and a lower surface, and includes a first resin material, a light initiator, and a fluorine-modified acrylic resin. The first resin material includes an acrylic resin, and the fluorine-modified acrylic resin. The weight percentage of the resin in the entire wafer dicing carrier layer is 1 to 5%.

此外,中間接合層20具有上表面及下表面,並包含第二樹脂材料、多環樹脂、無機材料以及中間接合層硬化劑。中間接合層20的下表面是貼附到晶圓切割承載層10的上表面,且晶圓切割承載層10的上表面對中間接合層20的下表面具有黏性。進一步,第二樹脂材料包含環氧樹脂以及丙烯酸樹脂的至少其中之一,且多環樹脂可包含芴環樹脂以及萘環樹脂的至少其中之一,而無機材料可包含二氧化矽(SiO2),且中間接合層20中的重量百分比為50~80%。 In addition, the intermediate bonding layer 20 has an upper surface and a lower surface, and includes a second resin material, a polycyclic resin, an inorganic material, and an intermediate bonding layer hardener. The lower surface of the intermediate bonding layer 20 is attached to the upper surface of the wafer dicing carrier layer 10, and the upper surface of the wafer dicing carrier layer 10 is adhesive to the lower surface of the intermediate bonding layer 20. Further, the second resin material includes at least one of an epoxy resin and an acrylic resin, and the polycyclic resin may include at least one of a fluorene ring resin and a naphthalene ring resin, and the inorganic material may include silicon dioxide (SiO 2 ). The weight percentage in the intermediate bonding layer 20 is 50 to 80%.

中間接合層20的厚度是特別設計成大於或等於晶圓接合層30的厚度,且中間接合層20的玻璃轉移溫度(Tg)為120℃至220℃之間。另外,中間接合層20的熱膨脹係數在上述玻璃轉移溫度以下時為20至50ppm/K之間,而且中間接合層20的熱膨脹係數在玻璃轉移溫度以上時為120至250ppm/K之間。The thickness of the intermediate bonding layer 20 is specifically designed to be greater than or equal to the thickness of the wafer bonding layer 30, and the glass transition temperature (Tg) of the intermediate bonding layer 20 is between 120 ° C and 220 ° C. In addition, the thermal expansion coefficient of the intermediate bonding layer 20 is between 20 and 50 ppm / K when the glass transition temperature is below, and the thermal expansion coefficient of the intermediate bonding layer 20 is between 120 and 250 ppm / K when the glass transition temperature is above.

再者,晶圓接合層30具有上表面及下表面,並包含第三樹脂材料以及晶圓接合硬化劑。晶圓接合層30的下表面是貼附到中間接合層20的上表面,而且晶圓接合層30的上表面對晶圓40具有黏性,用以貼附而安置晶圓40。進一步,第三樹脂材料包含環氧樹脂以及丙烯酸樹脂的至少其中之一。Furthermore, the wafer bonding layer 30 has an upper surface and a lower surface, and includes a third resin material and a wafer bonding hardener. The lower surface of the wafer bonding layer 30 is attached to the upper surface of the intermediate bonding layer 20, and the upper surface of the wafer bonding layer 30 is adhesive to the wafer 40 and is used to attach and place the wafer 40. Further, the third resin material includes at least one of an epoxy resin and an acrylic resin.

更加具體而言,上述晶圓切割承載層10的光啟始劑是可在照射紫外光(UV)時,促使晶圓切割承載層10產生特定的反應,且在反應後,晶圓切割承載層10的上表面會對中間接合層20的下表面失去黏性而相互脫離。尤其,氟素修飾丙烯酸樹脂可用以在特定的反應後改變晶圓切割承載層10的表面特性,比如增加表面張力,因而很容易與中間接合層20相互脫離。More specifically, the photo-initiator of the wafer dicing carrier layer 10 can cause the wafer dicing carrier layer 10 to generate a specific reaction when irradiated with ultraviolet light (UV), and after the reaction, the wafer dicing carrier layer 10 can react. The upper surface of 10 loses the adhesiveness to the lower surface of the intermediate bonding layer 20 and becomes detached from each other. In particular, the fluorine-modified acrylic resin can be used to change the surface characteristics of the wafer dicing carrier layer 10 after a specific reaction, such as increasing the surface tension, so that it can be easily separated from the intermediate bonding layer 20.

本創作晶圓接合膜的者要目的在於穩固的接合並安置晶圓40以利後續對晶圓40進行切割處理而形成多個晶粒(Die)或晶片(Chip),同時,晶圓切割承載層10在照射紫外光後很容易與中間接合層20相互脫離,因此,中間接合層20的水氣穿透率是特別設計成低於10-15g/m2*day,而且晶圓接合層30的水氣穿透率是低於10-15g/m2*day。此外,為達到適當的機械強度,晶圓切割承載層10的厚度是特別設計在20至50μm之間,而且晶圓接合層30的厚度以及中間接合層20的厚度合計是在5至80μm之間。The purpose of the creator of the wafer bonding film is to firmly bond and place the wafer 40 to facilitate subsequent dicing of the wafer 40 to form multiple dies or chips. The layer 10 is easily separated from the intermediate bonding layer 20 after being irradiated with ultraviolet light. Therefore, the water vapor transmission rate of the intermediate bonding layer 20 is specifically designed to be lower than 10-15 g / m2 * day, and the wafer bonding layer 30 Water vapor transmission rate is below 10-15g / m2 * day. In addition, in order to achieve proper mechanical strength, the thickness of the wafer dicing carrier layer 10 is specifically designed to be between 20 and 50 μm, and the thickness of the wafer bonding layer 30 and the thickness of the intermediate bonding layer 20 are totaled between 5 to 80 μm .

為進一步更加清楚說明本創作晶圓接合膜的特點,請再參考第二圖至第六圖,本創作晶圓接合膜的應用示意圖,並以晶圓切割為實例。In order to further explain the characteristics of the original wafer bonding film more clearly, please refer to the second to sixth figures, the application schematic diagram of the original wafer bonding film, and taking wafer dicing as an example.

首先,將晶圓40貼附到本創作晶圓接合膜中具有黏性的晶圓接合層30上,因而固定住,且進一步用環形架50壓在晶圓接合層30上且靠近晶圓40的周圍。再接著利用晶圓切割工具60對晶圓40進行切割而形成多個切割道C,比如使用光學式雷射或機械式切割刀。First, the wafer 40 is attached to the adhesive wafer bonding layer 30 in the original wafer bonding film, so it is fixed, and further, the ring frame 50 is pressed on the wafer bonding layer 30 and close to the wafer 40. Around. Then, the wafer 40 is cut by the wafer cutting tool 60 to form a plurality of cutting lanes C, such as using an optical laser or a mechanical cutting knife.

然後,對晶圓切割承載層10照射紫外光L,比如由下往上照射,使得晶圓切割承載層10發生反應而大幅降低對中間接合層20的黏性,或甚至失去黏性。接著,利用晶片夾取器70,比如吸盤,用以對晶圓40中被切割道C分割開的個別晶粒41逐一由下往上取出,而為改善晶粒41的取出效率,還可進一步利用晶片推擠器71朝晶圓切割承載層10的下表面由下往上推而推擠晶粒41。Then, the wafer dicing carrier layer 10 is irradiated with ultraviolet light L, such as irradiating from the bottom to the top, so that the wafer dicing carrier layer 10 reacts to greatly reduce the adhesiveness to the intermediate bonding layer 20, or even lose the adhesiveness. Next, the wafer gripper 70, such as a suction cup, is used to take out the individual crystal grains 41 separated by the dicing path C from the bottom to the top one by one. To improve the extraction efficiency of the crystal grains 41, A die pusher 71 is used to push the die 41 toward the lower surface of the wafer dicing carrier layer 10 from the bottom up.

此外,可將上述的晶粒41安置在晶片載板80上,且由中間接合層20貼附到晶片載板80,亦即,晶圓接合層30是包夾在中間接合層20、晶片載板80之間,或者,也可將上述的多個晶粒41可堆疊成多層結構,如第六圖所示,再將多層結構安置在晶片載板80上。此時,晶粒41已安置在晶片載板80上,可進行所需的打線、封裝處理,用以完成電氣連接,並保護晶粒41以避免受外在環境的影響。In addition, the above-mentioned die 41 can be placed on the wafer carrier 80 and attached to the wafer carrier 80 by the intermediate bonding layer 20. That is, the wafer bonding layer 30 is sandwiched between the intermediate bonding layer 20 and the wafer carrier. Alternatively, the plurality of dies 41 described above may be stacked into a multilayer structure between the boards 80, as shown in FIG. 6, and then the multilayer structure is placed on the wafer carrier board 80. At this time, the die 41 has been placed on the wafer carrier board 80, and the required wire bonding and packaging processes can be performed to complete the electrical connection and protect the die 41 from the external environment.

綜上所述,本創作的特點在於利用中間接合層、晶圓接合層形成雙層結構,並由位於雙層結構下方的中間接合層貼附到晶圓切割承載層,且由位於雙層結構上方的晶圓接合層安置晶圓,尤其是,晶圓接合層對晶圓具有優良的黏性,而照射紫外光後的晶圓切割承載層對中間接合層會降低黏性或失去黏性,因此,晶圓可相當牢固的安置在晶圓接合層上,同時,中間接合層可很輕易的脫離晶圓切割承載層,方便進行後續的半導體封裝處理製程。In summary, the characteristics of this creation are that a double-layer structure is formed by using an intermediate bonding layer and a wafer bonding layer, and the intermediate bonding layer located below the double-layer structure is attached to the wafer cutting bearing layer, and the double-layer structure The wafer bonding layer on the top is used to place the wafer. In particular, the wafer bonding layer has excellent adhesion to the wafer, and the wafer cutting carrier layer after ultraviolet light irradiation will reduce the viscosity or lose the adhesion to the intermediate bonding layer. Therefore, the wafer can be fairly firmly placed on the wafer bonding layer, and at the same time, the intermediate bonding layer can be easily separated from the wafer cutting carrier layer, which facilitates subsequent semiconductor packaging processing processes.

以上所述者僅為用以解釋本創作之較佳實施例,並非企圖據以對本創作做任何形式上之限制,是以,凡有在相同之創作精神下所作有關本創作之任何修飾或變更,皆仍應包括在本創作意圖保護之範疇。The above are only for explaining the preferred embodiment of the creation, and are not intended to restrict the creation in any form. Therefore, any modification or change related to the creation under the same spirit of creation , Should still be included in the scope of protection of this creative intention.

10‧‧‧晶圓切割承載層
20‧‧‧中間接合層
30‧‧‧晶圓接合層
40‧‧‧晶圓
41‧‧‧晶粒
50‧‧‧環形架
60‧‧‧晶圓切割工具
70‧‧‧晶片夾取器
71‧‧‧晶片推擠器
80‧‧‧晶片載板
C‧‧‧切割道
L‧‧‧紫外光
10‧‧‧ Wafer dicing carrier
20‧‧‧ intermediate bonding layer
30‧‧‧ Wafer Bonding Layer
40‧‧‧ wafer
41‧‧‧ Grain
50‧‧‧ ring frame
60‧‧‧ Wafer Cutting Tool
70‧‧‧ Wafer gripper
71‧‧‧ Wafer Pusher
80‧‧‧ Wafer Carrier Board
C‧‧‧cut road
L‧‧‧ UV

第一圖顯示依據本創作實施例晶圓接合膜的示意圖。
第二圖至第六圖顯示本創作晶圓接合膜的應用示意圖。
The first figure shows a schematic diagram of a wafer bonding film according to this creative embodiment.
The second to sixth figures show application diagrams of the original wafer bonding film.

Claims (5)

一種晶圓接合膜,包括:
一晶圓切割承載層,為電氣絕緣性,具一上表面及一下表面,且包含一第一樹脂材料、一光啟始劑以及一氟素修飾丙烯酸樹脂,該氟素修飾丙烯酸樹脂在該晶圓切割承載層中的重量百分比為1~5%,該第一樹脂材料包含丙烯酸樹脂;
一中間接合層,為電氣絕緣性,具一上表面及一下表面,而該中間接合層的下表面是貼附到該晶圓切割承載層的上表面,且該晶圓切割承載層的上表面對該中間接合層的下表面具有黏性,該中間接合層包含一第二樹脂材料、一多環樹脂、一無機材料以及一中間接合層硬化劑,該第二樹脂材料包含環氧樹脂以及丙烯酸樹脂的至少其中之一,該多環樹脂包含芴環樹脂以及萘環樹脂的至少其中之一,該無機材料在該中間接合層中的重量百分比為50~80%;以及
一晶圓接合層,為電氣絕緣性,具一上表面及一下表面,該晶圓接合層的下表面是貼附到該中間接合層的上表面,而該晶圓接合層的上表面對一晶圓具有黏性,用以貼附而安置該晶圓,且該晶圓接合層包含一第三樹脂材料以及一晶圓接合硬化劑,該第三樹脂材料包含環氧樹脂以及丙烯酸樹脂的至少其中之一,
其中該中間接合層的一厚度係大於或等於該晶圓接合層的一厚度,該晶圓切割承載層的光啟始劑是在照射紫外光時促使該晶圓切割承載層產生一反應,且在該反應後,該晶圓切割承載層的上表面對該中間接合層的下表面失去黏性而相互脫離。
A wafer bonding film includes:
A wafer cutting carrier layer is electrically insulating, has an upper surface and a lower surface, and includes a first resin material, a photoinitiator, and a fluorine-modified acrylic resin. The fluorine-modified acrylic resin is in the crystal. The weight percentage in the circular cutting bearing layer is 1 to 5%, and the first resin material includes an acrylic resin;
An intermediate bonding layer is electrically insulating and has an upper surface and a lower surface, and the lower surface of the intermediate bonding layer is attached to the upper surface of the wafer dicing carrier layer, and the upper surface of the wafer dicing carrier layer It has adhesiveness to the lower surface of the intermediate bonding layer. The intermediate bonding layer includes a second resin material, a polycyclic resin, an inorganic material, and an intermediate bonding layer hardener. The second resin material includes epoxy resin and acrylic acid. At least one of resins, the polycyclic resin comprising at least one of a fluorene ring resin and a naphthalene ring resin, the weight percentage of the inorganic material in the intermediate bonding layer is 50 to 80%; and a wafer bonding layer, For electrical insulation, there is an upper surface and a lower surface, the lower surface of the wafer bonding layer is attached to the upper surface of the intermediate bonding layer, and the upper surface of the wafer bonding layer is adhesive to a wafer. The wafer is attached for placement, and the wafer bonding layer includes a third resin material and a wafer bonding hardener. The third resin material includes at least one of epoxy resin and acrylic resin. ,
Wherein, a thickness of the intermediate bonding layer is greater than or equal to a thickness of the wafer bonding layer, and the photo-initiator of the wafer dicing carrier layer causes the wafer dicing carrier layer to generate a reaction when irradiating ultraviolet light, and After the reaction, the upper surface of the wafer dicing carrier layer loses the adhesiveness to the lower surface of the intermediate bonding layer and becomes detached from each other.
依據申請專利範圍第1項所述之晶圓接合膜,其中該中間接合層的一玻璃轉移溫度(Tg)為120℃至220℃之間。The wafer bonding film according to item 1 of the scope of patent application, wherein a glass transition temperature (Tg) of the intermediate bonding layer is between 120 ° C and 220 ° C. 依據申請專利範圍第2項所述之晶圓接合膜,其中該中間接合層的一熱膨脹係數在該玻璃轉移溫度以下時為20至50ppm/K之間,且該中間接合層的一熱膨脹係數在該玻璃轉移溫度以上時為120至250ppm/K之間,而該無機材料包含二氧化矽(SiO 2)。 The wafer bonding film according to item 2 of the patent application scope, wherein a thermal expansion coefficient of the intermediate bonding layer is between 20 and 50 ppm / K below the glass transition temperature, and a thermal expansion coefficient of the intermediate bonding layer is between Above the glass transition temperature is between 120 and 250 ppm / K, and the inorganic material includes silicon dioxide (SiO 2 ). 依據申請專利範圍第1項所述之晶圓接合膜,其中該晶圓接合層的一水氣穿透率低於10-15g/m2*day,且該中間接合層的一水氣穿透率低於10-15g/m2*day。The wafer bonding film according to item 1 of the patent application scope, wherein a water vapor transmission rate of the wafer bonding layer is lower than 10-15 g / m2 * day, and a water vapor transmission rate of the intermediate bonding layer Below 10-15g / m2 * day. 依據申請專利範圍第1項所述之晶圓接合膜,其中該晶圓接合層的厚度以及該中間接合層的厚度合計在5至80μm之間,而該晶圓切割承載層的一厚度是在20至50μm之間。The wafer bonding film according to item 1 of the scope of the patent application, wherein the thickness of the wafer bonding layer and the thickness of the intermediate bonding layer are between 5 and 80 μm in total, and a thickness of the wafer cutting carrier layer is between Between 20 and 50 μm.
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