TWI871273B - 含有介電常數高並且溫度穩定之介電層的場效應有機電晶體 - Google Patents

含有介電常數高並且溫度穩定之介電層的場效應有機電晶體 Download PDF

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TWI871273B
TWI871273B TW107127632A TW107127632A TWI871273B TW I871273 B TWI871273 B TW I871273B TW 107127632 A TW107127632 A TW 107127632A TW 107127632 A TW107127632 A TW 107127632A TW I871273 B TWI871273 B TW I871273B
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composition
dielectric constant
vdf
structural units
trifluoroethylene
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TW107127632A
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Chinese (zh)
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TW201910416A (zh
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朵絲 桑德斯 法比斯 多明古斯
泰巴特 索列斯汀
戴門 索奧
喬治 海地利歐農
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法商愛克瑪公司
法國波爾多大學
法國波爾多理工學院
法國國家科學研究中心
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    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/141—Organic polymers or oligomers comprising aliphatic or olefinic chains, e.g. poly N-vinylcarbazol, PVC or PTFE
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16—Homopolymers or copolymers or vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/151—Copolymers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
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    • H10N30/85—Piezoelectric or electrostrictive active materials
    • H10N30/857—Macromolecular compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/16—Homopolymers or copolymers of vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2427/16—Homopolymers or copolymers of vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2433/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
    • H10K10/40—Organic transistors
    • H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
    • H10K10/462—Insulated gate field-effect transistors [IGFETs]
    • H10K10/468—Insulated gate field-effect transistors [IGFETs] characterised by the gate dielectrics
    • H10K10/471—Insulated gate field-effect transistors [IGFETs] characterised by the gate dielectrics the gate dielectric comprising only organic materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Formation Of Insulating Films (AREA)
  • Thin Film Transistor (AREA)
TW107127632A 2017-08-09 2018-08-08 含有介電常數高並且溫度穩定之介電層的場效應有機電晶體 TWI871273B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1757604A FR3070042B1 (fr) 2017-08-09 2017-08-09 Transistor organique a effet de champ contenant une couche dielectrique a haute permittivite dielectrique et stable en temperature
FR1757604 2017-08-09
??1757604 2017-08-09

Publications (2)

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TW201910416A TW201910416A (zh) 2019-03-16
TWI871273B true TWI871273B (zh) 2025-02-01

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Country Link
US (1) US11871650B2 (enExample)
EP (2) EP4255162A3 (enExample)
JP (1) JP7508365B2 (enExample)
KR (2) KR102759816B1 (enExample)
CN (1) CN111315817B (enExample)
FR (1) FR3070042B1 (enExample)
TW (1) TWI871273B (enExample)
WO (1) WO2019030453A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3070041B1 (fr) 2017-08-09 2019-08-30 Arkema France Formulations a base de fluoropolymeres electroactifs et leurs applications
JP7071664B2 (ja) * 2020-04-22 2022-05-19 ダイキン工業株式会社 含フッ素重合体フィルム
CN113214424B (zh) * 2021-06-09 2022-06-21 上海交通大学 改性聚偏氟乙烯基铁电聚合物低电场制冷性能的方法及其应用
EP4156208A1 (en) * 2021-09-24 2023-03-29 Arkema France Electroactive fibre
CN116231062A (zh) * 2023-02-16 2023-06-06 深圳大学 一种固态聚合物电解质膜及其制备方法、锂金属电池

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56153606A (en) 1980-04-28 1981-11-27 Kureha Chemical Ind Co Ltd High molecular dielectric material
JPS6122590A (ja) * 1984-07-10 1986-01-31 ダイキン工業株式会社 高分子複合発熱体
FR2583914B1 (fr) * 1985-06-21 1989-04-07 Thomson Csf Materiaux dielectriques a base de polymeres et a permittivite dielectrique elevee
JP2773215B2 (ja) 1989-04-07 1998-07-09 ダイキン工業株式会社 高分子誘電体材料
FR2720750B1 (fr) * 1994-06-01 1996-07-19 Atochem Elf Sa Dispersion stable aqueuse de copolymères fluorés hydroxyles et de copolymères acryliques, son procédé de préparation et son utilisation comme peinture en phase aqueuse.
WO2007078916A2 (en) * 2005-12-28 2007-07-12 The Penn State Research Foundation High electric energy density polymer capacitors with fast discharge speed and high efficiency based on unique poly(vinylidene fluoride) copolymers and terpolymers as dielectric materials
US7842390B2 (en) * 2006-10-03 2010-11-30 The Penn State Research Foundation Chain end functionalized fluoropolymers having good electrical properties and good chemical reactivity
WO2009151694A2 (en) * 2008-03-13 2009-12-17 Strategic Polymer Sciences, Inc. High electrric energy density polymeric compositions, methods of the manufacture therefor, and articles comprising the same
FR2944285B1 (fr) 2009-04-09 2011-11-25 Francois Bauer Procede de fabrication de terpolymeres a base de vdf, trfe et cfe ou ctfe
US20120178880A1 (en) 2009-07-15 2012-07-12 Qiming Zhang Polymer blends electrostrictive terpolymer with other polymers
FR2948943B1 (fr) * 2009-08-05 2012-03-16 Arkema France Film a base de polymere fluore et d'oxyde de zinc sans odeur acrylique pour application photovoltaique
CN103187466B (zh) 2011-12-28 2015-10-21 山东东岳高分子材料有限公司 一种太阳能电池封装膜及其制备方法
CN102604280B (zh) * 2012-03-14 2013-11-13 北京化工大学 一种混合晶型无机纳米填料/聚合物基复合介电薄膜
FR2999187B1 (fr) 2012-12-11 2016-10-07 Arkema France Terpolymeres et films prepares a partir de ceux-ci
CN103387682B (zh) 2013-04-16 2015-05-13 西安交通大学 可交联耐高电压高储能聚偏氟乙烯塑料薄膜的制备方法
FR3014878B1 (fr) 2013-12-18 2015-12-18 Arkema France Film pvdf resistant a la dechirure a basse temperature et ininflammable
CN103951917B (zh) * 2014-04-29 2016-03-02 上海交通大学 柔性高介电聚合物复合材料及其制备方法
KR101539050B1 (ko) 2014-05-12 2015-07-23 울산대학교 산학협력단 강유전 고분자를 이용한 초음파 변환기
EP2960280A1 (en) 2014-06-26 2015-12-30 E.T.C. S.r.l. Photocrosslinkable compositions, patterned high k thin film dielectrics and related devices
WO2016039830A1 (en) * 2014-09-12 2016-03-17 Sabic Global Technologies B.V. Use of ambient-robust solution processing for preparing nanoscale organic ferroelectric films
US20160087185A1 (en) * 2014-09-18 2016-03-24 Nascent Devices Llc Methods to improve the mechanical performance of electrocaloric polymers in electrocaloric refrigerators
FR3026740B1 (fr) 2014-10-06 2018-02-16 Arkema France Procede de preparation de derives du polyfluorure de vinylidene
JP6983778B2 (ja) * 2015-11-30 2021-12-17 ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． フッ化ビニリデンとトリフルオロエチレンのコポリマー及びフッ素化エラストマーを含むフルオロポリマー組成物
FR3070041B1 (fr) 2017-08-09 2019-08-30 Arkema France Formulations a base de fluoropolymeres electroactifs et leurs applications

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
期刊 Soon-Won Jung Low-voltage-operated top-gate polymer thin-film transistors with high capacitance poly(vinylidene fluoride-trifluoroethylene)/poly(methyl methacrylate) dielectrics Journal of Applied Physics Vol. 11/No. 3 22 Jan 2011 S214-S218

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Publication number Publication date
KR102569460B1 (ko) 2023-08-21
EP3665226B1 (fr) 2023-08-30
EP3665226A1 (fr) 2020-06-17
EP4255162A3 (fr) 2024-01-10
FR3070042A1 (fr) 2019-02-15
KR20200038961A (ko) 2020-04-14
WO2019030453A1 (fr) 2019-02-14
FR3070042B1 (fr) 2020-08-21
KR20230124113A (ko) 2023-08-24
TW201910416A (zh) 2019-03-16
US11871650B2 (en) 2024-01-09
JP2020529508A (ja) 2020-10-08
EP4255162A2 (fr) 2023-10-04
KR102759816B1 (ko) 2025-01-23
CN111315817A (zh) 2020-06-19
US20210376239A1 (en) 2021-12-02
JP7508365B2 (ja) 2024-07-01
CN111315817B (zh) 2023-06-30

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