TWI742123B - 製備新穎甲磺草胺配製物之方法及其用途 - Google Patents
製備新穎甲磺草胺配製物之方法及其用途 Download PDFInfo
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Classifications
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
提供了施用於植物以控制雜草之除草組成物，並且該組成物包括甲磺草胺與抗光解劑，其中該抗光解劑是左旋莫多草。左旋莫多草的量和甲磺草胺的量的比通常在約2：1至約5：1的範圍內。較佳的甲磺草胺的量是該除草組成物按重量計的約10%至約15.6%，並且較佳的左旋莫多草的量是該除草組成物按重量計的約45%至約50%。該組成物還可以包括液體稀釋劑、固體稀釋劑、潤濕劑、分散劑或增稠劑、及其組合。
Description
本發明是關於2',4'-二氯-5'-(4-二氟甲基-4,5-二氫-3-甲基-5-側氧基-1H-1,2,4-三唑-1-基)甲基磺醯基苯胺(甲磺草胺)與抗光解劑之新穎配製物、其製備方法及其在農用化學製劑中之用途。
2',4'-二氯-5'-(4-二氟甲基-4,5-二氫-3-甲基-5-側氧基-1H-1,2,4-三唑-1-基)甲基磺醯基苯胺(甲磺草胺)為原紫質原氧化酶抑制劑。甲磺草胺的分子式為C11H10Cl2F2N4O3S。它的化學結構是：
將其在出苗前或種植前併入施用，用於大豆、甘蔗和煙草對抗一年生闊葉雜草、某些草和莎草屬雜草。
甲磺草胺與其他農業化學品一樣可以配製成各種不同配製物的濃縮物。然而，它將容易經歷半衰期小於0.5天的光解。根據“Willut JM等人；在Picogram,Preprint Abstract[預印本摘要]，Iss.52，Amer Chem Soc,Div Agrochem[美國化學會農用化學品分類] (1997)中”，暴露於模擬日光中的甲磺草胺緩衝水溶液迅速發生直接光解，其中在pH 6和pH 7下半衰期約為1小時，在pH 5時半衰期為12小時。
因此，甲磺草胺的含量隨著時間而下降，並不利地影響甲磺草胺的功能。
過往發現，適當選擇配製物佐劑意外地有助於穩定配製物中的活性成分。更具體地，意外地發現左旋莫多草可以顯著地抑制甲磺草胺之光解。甲磺草胺的半衰期可以延長，並且因此該等雜草更長時間地暴露於該配製物中，並且該配製物的效力得到提高。本揭露是關於本發明之實施方式，其中本發明提供了降低或避免所遇到的光解問題的甲磺草胺之新穎配製物。
左旋莫多草(IUPAC名稱：(aRS,1S)-2-氯-6'-乙基-N-(2-甲氧基-1-甲基乙基)乙醯-鄰甲苯胺和(aRS,1R)-2-氯-6'-乙基-N-(2-甲氧基-1-甲基乙基)乙醯-鄰甲苯胺的混合物)具有化學結構如下：
相應地，在一個實施方式中，本發明是關於2',4'-二氯-5'-(4-二氟甲基-4,5-二氫-3-甲基-5-側氧基-1H-1,2,4-三唑-1-基)甲基磺醯基苯胺(甲磺草胺)與抗光解劑之新穎配製物、其製備方法及其在農用化學製劑中之用途。
出人意料的是，左旋莫多草被發現可以用作甲磺草胺的抗光解劑。
在另一個實施方式中，本發明是關於藉由將有效量的 左旋莫多草施用於含有甲磺草胺的組成物來提高磺草胺的穩定性之方法。
特別感興趣的是左旋莫多草的抗光解化合物。
該等抗光解化合物與甲磺草胺的重量比在很寬的範圍內變化，並典型地在約2：1至約5：1，或約2.5：1至約4.75：1，或約3：1至約4.5：1，或約3.5：1至約4：1的範圍內，並且最較佳的是3.75：1。
該配製物中左旋莫多草的量是提供光解抗性的有效量並且可以是該配製物的從按重量計約10%至按重量計約80%，或從按重量計約20%至按重量計約70%，或從按重量計約30%至按重量計約60%，或按重量計約40%至按重量計約55%。
該配製物中甲磺草胺的量可以低於該配製物的按重量計約40%，或低於該配製物的按重量計約30%，或低於該配製物的按重量計約15%。
在一個較佳的實施方式中，甲磺草胺的量為該配製物的從按重量計約10%至約15.6%，並且左旋莫多草的量為該配製物的從按重量計約45%至約50%，並且更較佳的是甲磺草胺的量為該配製物的按重量計12.8%，並且左旋莫多草的量為該配製物的按重量計48%。
甲磺草胺的除草活性是本領域已知的並且以商業規模使用。製備和使用含甲磺草胺的組成物的方法也是在本領域已知的。根據本發明的實施方式，本文所描述的甲磺草胺的配製物可以以類似的方式進行配製和施用。
在另一方面，本發明提供了包含如上文所定義的甲磺草胺和抗光解劑之除草組成物。
另一方面，本發明還提供了製備用於控制雜草的包含甲磺草胺和抗光解劑的組成物之方法，以及藉由施用根據本發明實施方式的組成物來控制雜草之方法。
在另一個實施方式中，本發明提供了賦予包含除草有效量的甲磺草胺的除草組成物光解抗性之方法，該方法包括向該除草組成物中添加提供光解抗性的有效量的左旋莫多草。
甲磺草胺和抗光解劑的組成物可以以已知的方式、使用合適的助劑和載體或溶劑轉化成常規配製物，例如水懸劑(SC)、水分散性油懸劑(OD)、水溶性粒劑(SG)、水分散性乳劑(DC)、乳劑(EC)、種子處理乳劑(ES)、種子處理用水懸劑(FS)、粒劑、微粒劑(MG)、濃懸乳劑(SE)和水分散性粒劑(WG)。
在這裡，甲磺草胺應當以該組成物或配製物的按重量計從約0.1%至約50%的濃度存在，即以施用於希望除草控制的所在地後足以達到所需的劑量之量。例如藉由將甲磺草胺和抗光解劑與水、溶劑和/或載體組合，如果合適的話使用乳化劑和/或分散劑和/或其他助劑，來製備該等配製物。
根據本發明實施方式的配製物可以藉由將甲磺草胺和左旋莫多草抗光解劑與除草可接受的添加劑(例如液體稀釋劑、固體稀釋劑、潤濕劑、分散劑、增稠劑和其他配製物成分)混合來製備。
液體稀釋劑包括例如水、N,N-二甲基胺、二甲基亞碸、N-烷基吡咯啶酮、乙二醇、聚丙二醇、碳酸丙烯酯、二元酯、石蠟、烷基苯、烷基萘、甘油、甘油三乙酸酯(triacetine)、橄欖油、蓖麻油、亞麻籽油、芝麻油、玉米油、花生油、棉籽油、大豆油、油菜籽油和椰子油、酮(如環己酮、2-庚酮、異佛爾酮和4-羥基-4-甲基-2-戊酮)、乙酸酯(如乙酸己酯、乙酸庚酯和乙酸辛酯)、以及醇(如甲醇、環己醇、癸醇、苯甲醇和四氫糠醇)。
固體稀釋劑可為水溶性的或水不溶性的。水溶固體稀釋劑包括但不限於：鹽，如鹼金屬磷酸鹽(例如磷酸二氫鈉)，鹼土 金屬磷酸鹽，鈉、鉀、鎂和鋅的硫酸鹽，氯化鈉和氯化鉀，乙酸鈉，碳酸鈉，苯甲酸鈉，和/或糖和糖衍生物如山梨糖醇、乳糖、蔗糖和甘露醇。水不溶性固體稀釋劑的例子包括但不限於：黏土，合成二氧化矽和矽藻土，矽酸鈣和矽酸鎂，二氧化鈦，氧化鋁、氧化鈣和氧化鋅。
潤濕劑包括但不限於：烷基磺基琥珀酸酯、月桂酸酯、烷基硫酸酯和磷酸酯、炔二醇、乙氧基氟化醇、乙氧基化矽氧烷、烷基酚乙氧基化物、苯磺酸酯、烷基取代的苯磺酸酯，烷基α-烯烴磺酸酯、萘磺酸酯、烷基取代的萘磺酸酯、萘磺酸酯和烷基取代的萘磺酸酯與甲醛的縮合物，和醇乙氧基化物，以及任何該等的鹽形式。烷基萘磺酸鹽鈉鹽對於本發明的組成物和配製物是特別較佳的。
分散劑包括但不限於：木質素磺酸鹽的鈉鹽、鈣鹽和氨鹽(視情況被聚乙氧基化的)；馬來酸酐共聚物的鈉鹽和氨鹽；縮合苯酚磺酸的鈉鹽和氨鹽；和萘磺酸鹽-甲醛縮合物及其鈉鹽和銨鹽。值得注意的是包含高達按重量計約10%的分散劑的組成物。木質素磺酸鹽(如木質素磺酸鈉)對於本發明的組成物和配製物是特別較佳的。萘磺酸鹽-甲醛縮合物(及其鹽)，如萘磺酸聚合物與甲醛的縮合物(如鈉鹽)，對本發明的組成物和配製物是特別較佳的。
增稠劑包括但不限於：瓜爾膠、果膠、酪蛋白、角叉菜膠、黃原膠、藻酸鹽、甲基纖維素、羥乙基纖維素、羥丙基纖維素和羧甲基纖維素。合成增稠劑包括前面類別的衍生物，以及還有聚乙烯醇、聚丙烯醯胺、聚乙烯吡咯烷酮、聚醚和它們的共聚物以及聚丙烯酸及其鹽。烷基聚乙烯吡咯烷酮對於本發明的實施方式的組成物和配製物是特別較佳的。
其他配製物成分(例如染料，消泡劑，乾燥劑等)可用於本發明所述的某些實施方式中。該等配製物成分是熟習該項技術者所已知的。
形成根據本發明實施方式的配製物組分的甲磺草胺可以以其市售配製物和由該等配製物製備的使用形式，以及作為與其他活性化合物(如殺昆蟲劑、引誘劑、滅菌劑、殺細菌劑、殺蟎劑、殺線蟲劑、殺真菌劑、生長調節物質、除草劑、安全劑、肥料和化學信息素，以及其組合)的混合物存在。作為與其他已知的活性化合物(例如除草劑，肥料，生長調節劑，安全劑，資訊化學物質或與用於改善植物性質的藥劑)的混合物存在也是可能的。
當根據本發明實施方式用作除草劑時，該活性化合物可以以其市售配製物，以及由該等配製物製備之使用形式，或作為與協同劑的混合物存在。協同劑是增加活性化合物的作用的化合物，而不需要所添加的增效劑本身具有活性。
任何植物或植物部分易受甲磺草胺控制或保護均可以根據本發明所述的實施方式處理。在本文中，植物被理解為表示所有的植物和植物種群，例如希望和不希望的野生植物或作物植物(包括天然存在的作物植物)。作物植物可以是可以藉由常規育種和優化方法，藉由生物技術和遺傳工程方法，或藉由這些方法的組合獲得的植物，包括轉基因植物和可以或不能被植物育種人權利保護的植物栽培品種。植物部分應理解為意指地上或地下的植物的所有部分和器官，如芽，葉，花和根。可被提到的例子包括葉、針葉、杆、莖、花、果實體、果實、種子、根、塊莖和根莖。植物部分還包括收穫的材料，以及植物和生殖繁殖材料，例如切片、塊莖、根狀莖、分枝和種子。
本發明實施方式所述用該等活性化合物處理植物和植物部分是直接地(即藉由將配製物直接施用於植物或植物部分)或藉由將該等化合物施用於植物或植物部分的周圍環境、棲息地或儲存空間(也稱為施用於植物或植物部分的所在地)來進行。該等施用方法的實例包括浸漬、噴霧、汽化、霧化、撒播、塗抹，並在繁殖材料的情況下施加一個或多個塗層(尤其在種子的情況下)。
本發明可用於控制如下雜草：刺苞果屬(Acanthospermum spp.)、藿香薊屬(Ageratum spp.)、莧屬(Amaranthus spp.)、鬼針草屬(Bidens spp.)、異芒菊屬(Blainvillea spp.)、臂形草屬(Brachiaria spp.)、蒺藜草屬(Cenchrus spp.)、決明屬(Chamaecrista spp.)、鴨跖草屬(Commelina spp.)、狗牙根屬(Cynodon spp.)、莎草屬(Cyperus spp.)、山螞蝗屬(Desmodium spp.)、馬唐屬(digitaria spp.)、稗屬(Echinochloa spp.)、椮屬(Eleusine spp.)、一點紅屬(Emilia spp.)、大戟屬(Euphorbia spp.)、牛膝菊屬(Galinsoga spp.)、山香屬(Hyptis spp.)、番薯屬(Ipomoea spp.)、假酸漿屬(Nicandra spp.)、黍屬(Panicum spp.)、銀膠菊屬(Parthenium spp.)、狼尾草屬(Pennisetum spp.)、馬齒莧屬(Portulaca spp.)、紅毛草屬(Rhynchelytrum spp.)、假鴨舌癀屬(Richardia spp.)、黃花稔屬(Sida spp.)、茄屬(Solanum spp.)、鴨舌廣舅屬(Spermacoce spp.)、刺苞果(Acanthospermum austral)、硬毛刺苞菊(Acanthospermum hispidum)、藿香薊(Ageratum conyzoides)、毛葉莧(Amaranthus deflexus)、綠穗莧(Amaranthus hybridus)、反枝莧(Amaranthus retroflexus)、皺果莧(Amaranthus viridis)、鬼針草(Bidens pilosa)、百能葳(Blainvillea latifolia)、伏生臂形草(Brachiaria decumbens)、車前臂形草(Brachiaria plantaginea)、蒺藜草(Cenchrus echinatus)、圓葉決明(Chamaecrista rotundifolia)、圓葉鴨跖草(Commelina benghalensis)、狗牙根(Cynodon dactylon)、莎草(Cyperus rotundus)、南美山螞蝗(Desmodium tortuosum)、水平馬唐草(digitaria horizontalis)、稗草(Echinochloa crusgalli)、牛筋草(Eleusine indica)、一點紅(Emilia sonchifolia)、白苞猩猩草(Euphorbia heterophylla)、牛膝菊(Galinsoga parviflora)、香苦草(Hyptis suaveolens)、大葉山楝番薯(Ipomoea grandifolia)、假酸漿(Nicandra physaloides)、大黍(Panicum maximum)、銀膠菊(Parthenium hysterophorus)、牧地狼尾草(Pennisetum setosum)、 馬齒莧(Portulaca oleracea)、紅毛草(Rhynchelytrum repens)、巴西擬鴨舌癀(Richardia brasiliensis)、葛拉氏黃花稔(Sida glaziovii)、白背黃花稔(Sida rhombifolia)、少花龍葵(Solanum americanum)、闊葉豐花草(Spermacoee alata)和闊葉鴨舌癀舅(Spermacoce latifolia)。
當施用殺有害生物組成物和/或配製物用於殺死如下有用植物的生長作物中的雜草時，本發明實施方式的益處是最顯著的：穀類(小麥、大麥、黑麥、燕麥、玉米、稻、高粱、小黑麥以及有關作物)；水果，如梨果、核果和軟果，如蘋果、葡萄、梨、李子、桃子、杏仁、阿月渾子(pistachio)、櫻桃、以及漿果(例如，草莓、覆盆子和黑莓)、燈籠椒(bell pepper)、辣椒；豆科植物(豆、扁豆、豌豆、大豆)；油料植物(油菜、芥菜、向日葵)；葫蘆科(西葫蘆、黃瓜、甜瓜)；纖維植物(棉、亞麻、大麻、黃麻)；柑屬，如四季橘(calamondin)、圓佛手柑(citrus citron)、柑屬雜種(包括chironja、橘柚(tangelo)、焦柑(tangor))、葡萄柚、金橘、檸檬、青檸、柑桔(柑橘)、酸橙、甜橙、柚子、以及溫州蜜柑(satsuma mandarin)；蔬菜(菠菜、生菜、蘆筍、甘藍、胡蘿蔔、洋蔥、蕃茄、馬鈴薯、紅辣椒)；咖啡；甘蔗；連同觀賞植物(花(如玫瑰)、灌木、闊葉樹和常青樹(如松柏類))，較佳的是穀物、柑橘、咖啡、纖維植物、水果、豆科植物、油料植物、甘蔗、煙草、樹，更較佳的是豆、卡諾拉(canola)、柑橘、咖啡、玉米、棉花、桉樹、鳳梨、大豆、甘蔗、向日葵和煙草。處理玉米和土豆的生長作物特別有益。
如本文所使用的，當詞語“約”與數值量或範圍結合使用時，意味著稍微大於或稍小於所述數值量或範圍，偏離所述數值量或該範圍的端點的±10%。
本文所用的，“所在地”和“周圍環境”是指植物生長的地方、植物的植物繁殖材料進行播種的地方或者植物的植物繁殖材料將會播種的地方。
除非另有說明，所有百分比均以重量%給出。
現在將藉由以下實例描述本發明的實施方式，所述實例僅提供用於說明目的，而不意在限制本揭露之範圍。
組成物中甲磺草胺的光解穩定性是藉由用UV燈的UV光連續照射樣品，然後基於比較照射前後的甲磺草胺含量來決定的光解相對百分比。光解相對百分比藉由下式計算：
藉由用高壓液相層析(HPLC)使用反相柱和洗提劑測定組成物來確定甲磺草胺含量。
實例1-製備樣品如下：將甲磺草胺和左旋莫多草溶於丙酮中。
實例19
將乳劑製備為具有如下組成：
使用以下步驟對實例1至18進行測試以決定其光解穩定性：將20mL的溶液添加到石英管中。用來自UV燈的UV光不斷地照射該管。在2小時和8小時時從該管中取出該溶液的等分試樣(100μL)。藉由HPLC測定每個等分試樣中甲磺草胺的濃度。
結果總結於下表2中。
在整篇本說明書和所附的申請專利範圍，除非上下文另外要求，否則字詞“包含(comprise)”及“包括(include)”和多種變化形式(如“包含(comprising)”和“包括(including)”)應被理解為意指包括所陳述的整體或者多個整體之群組，但不排除任何其他整體或者多個整體的群組。
本說明書中對任何先前技術的引用不是、並且不應被當作是承認任何示意，先前技術形成了普通公知常識的一部分的建議。
Claims (24)
- 一種除草組成物，包含：除草有效量的甲磺草胺，和抑制光解有效量的左旋莫多草，其中左旋莫多草的量和甲磺草胺的量的比是在2：1至5：1的範圍內。
- 如申請專利範圍第1項所述之除草組成物，其中左旋莫多草的量和甲磺草胺的量的比是在2.5：1至4.75：1的範圍內。
- 如申請專利範圍第1項所述之除草組成物，其中左旋莫多草的量和甲磺草胺的量的比是在3：1至4.5：1的範圍內。
- 如申請專利範圍第1項所述之除草組成物，其中左旋莫多草的量和甲磺草胺的量的比是在3.5：1至4：1的範圍內。
- 如申請專利範圍第1項所述之除草組成物，其中左旋莫多草的量和甲磺草胺的量的比是3.75：1。
- 如申請專利範圍第1項所述之除草組成物，其中甲磺草胺的量是小於該組成物的按重量計40%。
- 如申請專利範圍第1項所述之除草組成物，其中甲磺草胺的量是小於該組成物的按重量計30%。
- 如申請專利範圍第1項所述之除草組成物，其中甲磺草胺的量是小於該組成物的按重量計15%。
- 如申請專利範圍第1項所述之除草組成物，其中左旋莫多草的量為該組成物的從按重量計10%至按重量計80%。
- 如申請專利範圍第1項所述之除草組成物，其中左旋莫多草的量為該組成物的從按重量計20%至按重量計70%。
- 如申請專利範圍第1項所述之除草組成物，其中左旋莫多草的量為該組成物的從按重量計30%至按重量計60%。
- 如申請專利範圍第1項所述之除草組成物，其中左旋莫多草的量為該組成物的從按重量計40%至按重量計55%。
- 如申請專利範圍第1項所述之除草組成物，其中甲磺草胺的量為 該組成物的從按重量計10%至15.6%，並且左旋莫多草的量為該組成物的從按重量計45%至50%。
- 如申請專利範圍第1項所述之除草組成物，其中甲磺草胺的量為該組成物的按重量計12.8%，並且左旋莫多草的量為該組成物的按重量計48%。
- 如申請專利範圍第1至14項中任一項所述之除草組成物，其中將該組成物配製成水懸劑(SC)、水分散性油懸劑(OD)、水溶性粒劑(SG)、水分散性乳劑(DC)、乳劑(EC)、種子處理乳劑(ES)、種子處理用水懸劑劑(FS)、粒劑、微粒劑(MG)、濃懸乳劑(SE)和水分散性粒劑(WG)。
- 如申請專利範圍第15項所述之除草組成物，進一步包含選自下組的一種或多種助劑：液體稀釋劑、固體稀釋劑、潤濕劑、分散劑、增稠劑及其組合。
- 一種控制雜草之方法，包括向植物或植物部分或其周圍環境施用有效量的如申請專利範圍第1至16項中任一項所述之除草組成物。
- 一種賦予包含除草有效量的甲磺草胺的除草組成物光解抗性之方法，該方法包括向該除草組成物中加入提供光解抗性有效量的左旋莫多草，其中左旋莫多草的量和甲磺草胺的量的比是在2：1至5：1的範圍內。
- 如申請專利範圍第18項所述之方法，其中左旋莫多草的量和甲磺草胺的量的比是在2.5：1至4.75：1的範圍內。
- 如申請專利範圍第18項所述之方法，其中左旋莫多草的量和甲磺草胺的量的比是在3：1至4.5：1的範圍內。
- 如申請專利範圍第18項所述之方法，其中左旋莫多草的量和甲磺草胺的量的比是在3.5：1至4：1的範圍內。
- 如申請專利範圍第18項所述之方法，其中左旋莫多草的量和甲磺草胺的量的比是3.75：1。
- 如申請專利範圍第18項所述之方法，其中甲磺草胺的量為該組成物的從按重量計10%至15.6%，並且左旋莫多草的量為該組成物的從按重量計45%至50%。
- 如申請專利範圍第18項所述之方法，其中甲磺草胺的量為該組成物的按重量計12.8%，並且左旋莫多草的量為該組成物的按重量計48%。
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| CN110988157B (zh) * | 2019-11-20 | 2022-10-25 | 江苏宝众宝达药业股份有限公司 | 一种高效液相色谱法测定甲磺草胺原药中甲磺草胺的方法 |
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| CN114097784B (zh) * | 2021-12-14 | 2024-01-26 | 山东润博生物科技有限公司 | 一种含精异丙甲草胺和甲磺草胺的乳油及其制备方法 |
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