TWI713701B - Agricultural greenhouse, plant cultivation method using the agricultural greenhouse, and heat-ray reflective film structure - Google Patents
Agricultural greenhouse, plant cultivation method using the agricultural greenhouse, and heat-ray reflective film structure Download PDFInfo
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- TWI713701B TWI713701B TW106105951A TW106105951A TWI713701B TW I713701 B TWI713701 B TW I713701B TW 106105951 A TW106105951 A TW 106105951A TW 106105951 A TW106105951 A TW 106105951A TW I713701 B TWI713701 B TW I713701B
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- agricultural greenhouse
- reflective film
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- ray reflective
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Abstract
本發明之農業溫室及使用此農業溫室之植物栽培方法,係在農業溫室內部至少具備:供給二氧化碳的CO2供給手段、熱線遮蔽手段及冷卻農業溫室內部的除濕冷卻手段;該熱線遮蔽手段係使用波長400~700nm的光之平均穿透率為80%以上,且波長800~1200nm的光之平均反射率為70%以上的熱線反射薄膜所形成;及在該熱線遮蔽手段上,以既定間隔形成有複數個貫通孔,藉此,植物每單位收穫量所投入的能量較少而能夠經濟且有效率地栽培植物,由於可減少對植物的供給水量,在乾燥地區等也能栽培植物,而且,可防止因結露而引起變色、劣化等的品質下降。 The agricultural greenhouse of the present invention and the plant cultivation method using the agricultural greenhouse are equipped with at least: CO 2 supply means for supplying carbon dioxide, hot wire shielding means, and dehumidification cooling means for cooling the inside of the agricultural greenhouse; the hot wire shielding means is used The heat-ray reflection film is formed with an average transmittance of light with a wavelength of 400~700nm or more than 80%, and an average reflectance of light with a wavelength of 800~1200nm is more than 70%; and the heat-ray shielding means is formed at predetermined intervals There are a plurality of through holes, whereby the energy input per unit harvest of the plant is small, and the plant can be grown economically and efficiently. Since the water supply to the plant can be reduced, the plant can be grown in dry areas, etc., and, It can prevent deterioration of quality such as discoloration and deterioration due to condensation.
又,本發明之熱線反射薄膜構造體係由:將以在交互層合折射率不同的至少2種樹脂層而得,且可見光(波長400~750nm的光)之平均穿透率為80%以上、熱線(波長800~1100nm的光)之平均反射率為70%以上之多層 層合薄膜的至少單側表面設有滑性賦予層之原薄膜經裁切的細帶狀條帶,編織成為經紗或緯紗,並將以絲紗或紡紗編織成為緯紗或經紗的編織物所構成,根據絲紗或紡紗的粗細度為該細帶狀條帶之寬度的0.01~0.30倍、相鄰之該細帶狀條帶的間隔為該細帶狀條帶之寬度的0.1~0.5倍之構造,可經濟且有效率地進行利用太陽光之在農業溫室中的植物栽培。 In addition, the heat-ray reflective film structure system of the present invention is obtained by alternately laminating at least two types of resin layers with different refractive indexes, and the average transmittance of visible light (light with wavelength of 400 to 750 nm) is over 80%, Multi-layers with the average reflectivity of the heating wire (light of wavelength 800~1100nm) above 70% At least one side surface of the laminated film is provided with a slippery imparting layer. The original film is cut into a thin ribbon-like strip, woven into warp yarn or weft yarn, and knitted into weft yarn or warp yarn by silk yarn or spun yarn. According to the composition, the thickness of the silk yarn or spinning is 0.01~0.30 times the width of the thin strip, and the interval between adjacent thin strips is 0.1~0.5 of the width of the thin strip The double structure allows economical and efficient plant cultivation in agricultural greenhouses using sunlight.
Description
本發明係有關於一種日間關閉天窗、夜間敞開天窗的利用太陽光之農業溫室及使用此農業溫室之植物栽培方法。 The present invention relates to an agricultural greenhouse using sunlight that closes the skylight during the day and opens the skylight at night, and a plant cultivation method using the agricultural greenhouse.
又,本發明係有關於一種在利用太陽光之農業溫室中所使用的熱線反射薄膜構造體。 In addition, the present invention relates to a heat-ray reflection film structure used in an agricultural greenhouse using sunlight.
利用農業溫室來栽培植物,係基於控制包圍之空間而作出最適合植物生長的環境,以謀求植物的收穫量增加及高品質化而廣泛地進行。尤其是,近年來隨著人口增加而衍生食料危機的問題,於此情況下,便有人針對使用農業溫室之植物的有效栽培方法進行各種研究。 The cultivation of plants in agricultural greenhouses is based on the control of the enclosed space to create an environment that is most suitable for plant growth, in order to increase the harvest of plants and improve their quality. In particular, in recent years, with the increase in population, there has been a food crisis. Under this situation, some people have conducted various researches on effective cultivation methods for plants in agricultural greenhouses.
植物的光合作用係如下述式(1)所示,是一種以光能量為驅動源,由從空氣中吸收的二氧化碳、與從地底等吸收的水生成氧氣與碳水化合物的反應。為了大量且經濟地栽培植物,比起人工光係更佳利用太陽光。 The photosynthesis system of plants is represented by the following formula (1). It is a reaction that uses light energy as a driving source to generate oxygen and carbohydrates from carbon dioxide absorbed from the air and water absorbed from the ground. In order to cultivate plants in large quantities and economically, sunlight is better used than artificial light.
6CO2+6H2O → 6O2+C6H12O6 (1) 6CO 2 +6H 2 O → 6O 2 +C 6 H 12 O 6 (1)
在利用太陽光的農業溫室中,太陽光包含:利用於植物的光合作用之波長400~700nm或波長400~750nm的光(以下有稱為「可見光」)、以及使農業溫室內的溫度上昇之波長800~1100nm或波長800~1200nm的光(以下有稱為「熱線」),而為了防止農業溫室內的溫度上昇,則需將熱線遮蔽。這是因為,農業溫室內的溫度因熱線而上昇時,為保持於適合植物生長的溫度(下稱「適溫」),換氣、除濕冷卻等需耗時費力且耗費成本之故。 In agricultural greenhouses that use sunlight, sunlight includes: light with a wavelength of 400 to 700 nm or 400 to 750 nm (hereinafter referred to as "visible light") used for photosynthesis of plants, and the increase in temperature in the agricultural greenhouse Light with a wavelength of 800~1100nm or 800~1200nm (hereinafter referred to as "hot wire"), and in order to prevent the temperature rise in the agricultural greenhouse, the hot wire must be shielded. This is because when the temperature in the agricultural greenhouse rises due to the heating wire, in order to maintain the temperature suitable for plant growth (hereinafter referred to as "suitable temperature"), it takes time, labor, and cost for ventilation, dehumidification and cooling.
又,由上述式(1)亦可知,藉由將二氧化碳濃度維持於高程度,可使光合作用活潑地進行而促進植物的生長。對於利用太陽光之農業溫室中的植物栽培,專利文獻1~3中提案將農業溫室內的二氧化碳濃度維持於高程度來促進植物的生長。 Also, from the above formula (1), it can be seen that by maintaining the carbon dioxide concentration at a high level, photosynthesis can be actively performed to promote plant growth. For plant cultivation in agricultural greenhouses using sunlight, Patent Documents 1 to 3 propose to maintain the carbon dioxide concentration in agricultural greenhouses at a high level to promote plant growth.
另一方面,會活潑地進行光合作用的日間,由於會因太陽光而使農業溫室內的溫度上昇,因此,作為用以將農業溫室內保持於適溫之較為經濟的手段,一般係採用換氣。例如,日間日射量極充分時,農業溫室內的溫度經常會超過40℃,因此,藉由自然換氣或強制通氣,農業溫室內的溫度可維持於20~25℃左右或20~30℃左右之適溫。 On the other hand, during the day when photosynthesis is active, the temperature in the agricultural greenhouse will rise due to sunlight. Therefore, as a relatively economical means to keep the temperature in the agricultural greenhouse at an appropriate temperature, replacement is generally adopted. gas. For example, when the amount of sunlight is extremely sufficient during the day, the temperature in the agricultural greenhouse will often exceed 40°C. Therefore, through natural ventilation or forced ventilation, the temperature in the agricultural greenhouse can be maintained at about 20~25°C or 20~30°C. The suitable temperature.
然而,伴隨著換氣,供給至農業溫室內的二氧化碳會朝外部放出,因此,尤其是在日間極不易將農業溫室內的溫度保持於適溫並同時將二氧化碳濃度維持於高 程度。 However, with the ventilation, the carbon dioxide supplied to the agricultural greenhouse is released to the outside. Therefore, it is extremely difficult to maintain the temperature in the agricultural greenhouse at an appropriate temperature during the day and the carbon dioxide concentration at the same time. degree.
專利文獻3中提出,於日間使植物栽培設施實際上成為密閉狀態,而將設施內的二氧化碳濃度保持於高程度,同時使用冷氣機設備將設施內的溫度保持於20℃左右的適溫;然而,要在日間使冷氣機設備作動,將廣大設施內的溫度維持於20℃左右的適溫,需要極大的能量而較不經濟。
又,專利文獻4~7中記載對作為農業用薄膜之聚乙烯、聚酯等的合成樹脂薄膜層合金屬蒸鍍層、金屬箔、含金屬層等來遮蔽熱線等。然而,專利文獻4~5及7中雖記載反射太陽光來遮光,但未記載使可見光穿透。 又,專利文獻6中雖記載層合薄膜具有可見光穿透性能、遠紅外線反射性能,但基本上係由含金屬層反射遠紅外線,因此,「遠紅外反射率(%)」雖高達「81~89%」,但「可見光穿透率(%)」低至「50~65%」(實施例1~9)。 In addition, Patent Documents 4 to 7 describe that synthetic resin films such as polyethylene and polyester, which are agricultural films, are laminated with metal vapor-deposited layers, metal foils, metal-containing layers, and the like to shield heat rays. However, although Patent Documents 4 to 5 and 7 describe reflecting sunlight to block light, they do not describe allowing visible light to pass through. In addition, although Patent Document 6 describes that the laminated film has visible light penetration performance and far-infrared reflection performance, it basically reflects far-infrared rays from the metal-containing layer. Therefore, the "far-infrared reflectance (%)" is as high as "81~ 89%", but the "visible light transmittance (%)" is as low as "50~65%" (Examples 1-9).
[專利文獻1]日本專利第2963427號公報 [Patent Document 1] Japanese Patent No. 2963427
[專利文獻2]日本專利第3917311號公報 [Patent Document 2] Japanese Patent No. 3917311
[專利文獻3]日本特開昭53-098246號公報 [Patent Document 3] JP 53-098246 A
[專利文獻4]日本特開2001-009996號公報 [Patent Document 4] JP 2001-009996 A
[專利文獻5]日本特開2004-176210號公報 [Patent Document 5] JP 2004-176210 A
[專利文獻6]日本特開2012-206430號公報 [Patent Document 6] JP 2012-206430 A
[專利文獻7]日本特開2013-252107號公報 [Patent Document 7] JP 2013-252107 A
本發明之課題在於提供一種植物每單位收穫量所投入的能量較少而能夠經濟且有效率地栽培植物,可減少對植物的供給水量,在乾燥地區等也能栽培植物的農業溫室及使用此農業溫室之植物栽培方法。 The subject of the present invention is to provide an agricultural greenhouse that can grow plants economically and efficiently with less energy input per unit harvest amount, reduce the amount of water supplied to the plants, and can also cultivate plants in dry areas and the like. Plant cultivation methods for agricultural greenhouses.
又,本發明之其他課題在於提供一種在利用太陽光之農業溫室中所使用,可經濟且有效率地進行植物的栽培的熱線反射薄膜構造體。 In addition, another subject of the present invention is to provide a heat-ray reflection film structure that can be used in an agricultural greenhouse that utilizes sunlight and can economically and efficiently cultivate plants.
針對本發明之農業溫室及使用此農業溫室之植物栽培方法的上述課題可藉由一種農業溫室及使用此農業溫室之植物栽培方法來解決,該農業溫室係日間關閉設於屋頂部之天窗、夜間敞開設於屋頂部之天窗的利用太陽光之農業溫室,其中在農業溫室內部至少具備:供給二氧化碳的CO2供給手段、熱線遮蔽手段及冷卻農業溫室內部的除濕冷卻手段,該熱線遮蔽手段係使用波長400~700nm的光之平均穿透率為80%以上,且波長800~1200nm的光之平均反射率為70%以上的熱線反射薄膜所形成,在該熱線遮蔽手段上,以既定間隔形成有複數個貫 通孔。 The above-mentioned problems of the agricultural greenhouse of the present invention and the plant cultivation method using the agricultural greenhouse can be solved by an agricultural greenhouse and the plant cultivation method using the agricultural greenhouse. The agricultural greenhouse closes the skylights installed on the roof during the day and at night. An agricultural greenhouse that uses sunlight with skylights opened on the roof. The agricultural greenhouse has at least: CO 2 supply means for supplying carbon dioxide, hot wire shielding means, and dehumidification cooling means for cooling the inside of the agricultural greenhouse. The hot wire shielding means is used The average transmittance of light with a wavelength of 400 to 700 nm is 80% or more, and the average reflectance of light with a wavelength of 800 to 1200 nm is 70% or more. The heating ray shielding means is formed at predetermined intervals. Plural through holes.
又,針對本發明之熱線反射薄膜構造體的上述課題可藉由一種熱線反射薄膜構造體來解決,其係在利用太陽光之農業溫室中所使用的熱線反射薄膜構造體,該熱線反射薄膜構造體係由:將以在折射率不同的至少2種樹脂層交互層合而得之波長400~750nm的光之平均穿透率為80%以上、波長800~1100nm的光之平均反射率為70%以上之多層層合薄膜的至少單側表面設有滑性賦予層之原薄膜經裁切的細帶狀條帶編織成為經紗或緯紗、以絲紗或紡紗編織成為緯紗或經紗的編織物所構成,該絲紗或紡紗的粗細度為該細帶狀條帶之寬度的0.01~0.30倍,相鄰之該細帶狀條帶的間隔為該細帶狀條帶之寬度的0.1~0.5倍。 In addition, the above-mentioned problems of the heat-reflective film structure of the present invention can be solved by a heat-reflective film structure, which is a heat-reflective film structure used in an agricultural greenhouse using sunlight. The heat-reflective film structure The system consists of: the average transmittance of light with a wavelength of 400~750nm is over 80%, and the average reflectance of light with a wavelength of 800~1100nm is 70% by alternately laminating at least two resin layers with different refractive indexes. The above multi-layer laminated film has at least one side surface of the original film provided with a slippery imparting layer. The thin ribbon-shaped strips cut by the warp are woven into warp yarns or weft yarns, and silk yarns or spun yarns are woven into weft yarns or warp yarns. Composition, the thickness of the silk yarn or spun yarn is 0.01~0.30 times the width of the thin strip, and the interval between adjacent thin strips is 0.1~0.5 of the width of the thin strip Times.
本案發明人等提出如第5圖所示之農業溫室(下稱「先前之農業溫室」)作為可將農業溫室內的二氧化碳濃度維持於高程度,同時將農業溫室內經濟地保持於適溫的農業溫室,於2011年3月由農業情報學會獲頒「農業、食料產業創新大獎」。 The inventors of this case proposed the agricultural greenhouse as shown in Figure 5 (hereinafter referred to as the "previous agricultural greenhouse") as a way to maintain the carbon dioxide concentration in the agricultural greenhouse at a high level while economically maintaining the temperature in the agricultural greenhouse. The agricultural greenhouse was awarded the "Agricultural and Food Industry Innovation Award" by the Agricultural Information Society in March 2011.
先前之農業溫室係如第5圖所示,具有如下特徵:a)將農業溫室的屋頂部101與栽培部102以透明的樹脂板「SUNNYCOAT 103」隔熱、區隔開來;b)於「SUNNYCOAT 103」的上部被覆「近紅外線吸收薄膜104」,以吸收遮蔽太陽光108所含之使栽培部
102的溫度上昇之波長800nm以上的光的約70%,同時使太陽光108所含之對植物生長所需之400~700nm的光的約70%穿透;c)經由設於屋頂部101之天窗105置換空氣,以防止「近紅外線吸收薄膜104」之發熱所引起的溫度上昇;d)對栽培部102設置「CO2產生裝置106」以將二氧化碳濃度維持於高程度,同時設置「熱泵107」以將溫度保持於適溫。
As shown in Figure 5, the previous agricultural greenhouse system has the following characteristics: a) The
如此,本案發明人等先前提出的農業溫室,藉由將農業溫室的屋頂部與栽培部以透明的樹脂板「SUNNYCOAT」隔熱、區隔開來,由於二氧化碳不會從栽培部漏出,故可將栽培部的二氧化碳濃度經濟地保持於高濃度,而且,由於係將「近紅外線吸收薄膜」的發熱從與栽培部隔熱、區隔開來的屋頂部,經由設於屋頂部之天窗向外部放出,因此可防止栽培部的溫度上昇。 In this way, the agricultural greenhouse previously proposed by the inventors of the present invention has a transparent resin plate "SUNNYCOAT" that insulates and separates the roof of the agricultural greenhouse and the cultivation part, so that carbon dioxide does not leak from the cultivation part, so it can The carbon dioxide concentration in the cultivation area is kept at a high concentration economically, and the heat generated by the "near infrared absorbing film" is transmitted from the roof that is insulated and isolated from the cultivation area to the outside through the skylight provided in the roof. Since it is released, the temperature of the cultivation part can be prevented from rising.
本案發明人等發現,在日間關閉天窗而將農業溫室內的二氧化碳濃度經濟地維持於高濃度、夜間敞開天窗而使農業溫室內的溫度降低之利用太陽光之農業溫室中,透過使用具備特定構造、物性的熱線遮蔽手段來替代先前之農業溫室的「SUNNYCOAT」及「近紅外線吸收薄膜」,與先前之農業溫室相比,可更經濟且有效率地進行植物的栽培,而完成本發明之農業溫室及使用此農業溫室之植物栽培方法之發明。 The inventors of the present case discovered that the carbon dioxide concentration in the agricultural greenhouse is economically maintained at a high concentration by closing the skylight during the day, and that the temperature in the agricultural greenhouse is lowered by opening the skylight at night. The agricultural greenhouse using sunlight has a specific structure through use. , Physical property hot wire shielding means to replace the "SUNNYCOAT" and "Near Infrared Absorbing Film" of the previous agricultural greenhouse. Compared with the previous agricultural greenhouse, the plant can be cultivated more economically and efficiently to complete the agriculture of the present invention. The invention of the greenhouse and the plant cultivation method using this agricultural greenhouse.
又,本案發明人等發現,在利用太陽光之農 業溫室中,透過使用具備特定構造、物性的熱線反射薄膜構造體來替代先前之農業溫室的「SUNNYCOAT」及「近紅外線吸收薄膜」,與先前之農業溫室相比,可更經濟且有效率地進行植物的栽培,而完成本發明之熱線反射薄膜構造體之發明。 In addition, the inventors of this case discovered that the use of sunlight In the industrial greenhouse, by using a heat-ray reflective film structure with a specific structure and physical properties to replace the "SUNNYCOAT" and "Near Infrared Absorbing Film" of the previous agricultural greenhouse, it can be more economical and efficient than the previous agricultural greenhouse The cultivation of plants was carried out, and the invention of the heat-ray reflective film structure of the present invention was completed.
以下示出本發明之要旨: The gist of the present invention is shown below:
(1)一種農業溫室,其係日間關閉設於屋頂部之天窗、夜間敞開設於屋頂部之天窗的利用太陽光之農業溫室,其特徵為:在農業溫室內部至少具備:供給二氧化碳的CO2供給手段、熱線遮蔽手段及冷卻農業溫室內部的除濕冷卻手段,該熱線遮蔽手段係使用波長400~700nm的光之平均穿透率為80%以上,且波長800~1200nm的光之平均反射率為70%以上的熱線反射薄膜所形成,在該熱線遮蔽手段上,以既定間隔形成有複數個貫通孔。 (1) An agricultural greenhouse, which is an agricultural greenhouse using sunlight that closes the skylights on the roof during the day and opens the skylights on the roof at night, and is characterized in that the agricultural greenhouse has at least: CO 2 for supplying carbon dioxide. Supply means, hot wire shielding means, and dehumidification cooling means for cooling the inside of agricultural greenhouses. The hot wire shielding means uses light with a wavelength of 400~700nm with an average transmittance of 80% or more, and an average reflectivity of light with a wavelength of 800~1200nm 70% or more of the heat ray reflection film is formed, and the heat ray shielding means has a plurality of through holes formed at predetermined intervals.
(2)如(1)之農業溫室,其中前述熱線反射薄膜為折射率不同的至少2種樹脂層交互層合而成的多層層合薄膜。 (2) The agricultural greenhouse as in (1), wherein the heat ray reflective film is a multilayer laminate film formed by alternately laminating at least two resin layers with different refractive indexes.
(3)如(2)之農業溫室,其中前述多層層合薄膜之前述2種樹脂層的至少一者為由具有縮合型芳香環之樹脂所構成的樹脂層。 (3) The agricultural greenhouse according to (2), wherein at least one of the two types of resin layers of the multilayer laminate film is a resin layer composed of a resin having a condensed aromatic ring.
(4)如(1)~(3)中任一項之農業溫室,其中設 於前述熱線遮蔽手段之前述複數個貫通孔的開孔率為0.5~10%的範圍。 (4) Such as the agricultural greenhouse of any one of (1) ~ (3), which includes The opening ratio of the plurality of through holes in the hot wire shielding means is in the range of 0.5-10%.
(5)如(1)~(4)中任一項之農業溫室,其中前述熱線遮蔽手段係具有於前述熱線反射薄膜穿設有貫通孔的構造。 (5) The agricultural greenhouse according to any one of (1) to (4), wherein the heat shielding means has a structure in which the heat reflecting film is penetrated with through holes.
(6)如(1)~(4)中任一項之農業溫室,其中前述熱線遮蔽手段係具有將以前述熱線反射薄膜經裁切成細帶狀之細帶狀條帶編織成為經紗及/或緯紗的構造,且於該經紗間及/或緯紗間形成有貫通孔。 (6) The agricultural greenhouse according to any one of (1) to (4), wherein the heat shielding means is provided with a thin ribbon-shaped strip cut into a thin ribbon with the heat-reflective film weaving into warp yarns and/ Or the structure of the weft yarn, and through holes are formed between the warp yarns and/or between the weft yarns.
(7)如(1)~(6)中任一項之農業溫室,其中前述熱線反射薄膜之波長350nm的光線穿透率為10%以下。 (7) The agricultural greenhouse described in any one of (1) to (6), wherein the light transmittance of the heat-ray reflective film with a wavelength of 350 nm is less than 10%.
(8)如(1)~(7)中任一項之農業溫室,其中前述熱線反射薄膜係於最外層的至少單側具有紫外線吸收層。 (8) The agricultural greenhouse according to any one of (1) to (7), wherein the heat ray reflective film is provided with an ultraviolet absorbing layer on at least one side of the outermost layer.
(9)如(8)之農業溫室,其中前述紫外線吸收層係含有黏合劑樹脂,且該黏合劑樹脂為氟樹脂。 (9) The agricultural greenhouse of (8), wherein the ultraviolet absorbing layer contains a binder resin, and the binder resin is a fluororesin.
(10)如(1)~(9)中任一項之農業溫室,其中前述農業溫室係用於藉由太陽光來進行光合作用之果菜類的栽培。 (10) The agricultural greenhouse according to any one of (1) to (9), wherein the aforementioned agricultural greenhouse is used for the cultivation of fruits and vegetables for photosynthesis by sunlight.
(11)一種植物栽培方法,其係使用如(1)~(10)中任一項之農業溫室的植物栽培方法,其中,日間關閉設於屋頂部之天窗而調整二氧化碳濃度,夜間敞開設於屋頂部之天窗而進行溫度調整,並且, 至少日間將農業溫室內部的溫度控制成35℃以下,將二氧化碳濃度控制成500~1500ppm及將濕度飽和差控制成4g/m3以下來栽培植物。 (11) A method of plant cultivation, which uses the method of plant cultivation in an agricultural greenhouse as described in any one of (1) to (10), wherein the skylight provided on the roof is closed during the day to adjust the carbon dioxide concentration, and the carbon dioxide concentration is opened at night. The temperature of the skylight on the roof is adjusted, and at least during the day, the temperature inside the agricultural greenhouse is controlled to 35°C or less, the carbon dioxide concentration is controlled to 500 to 1500 ppm, and the humidity saturation difference is controlled to 4 g/m 3 or less to cultivate plants.
(12)一種熱線反射薄膜構造體,其係在利用太陽光之農業溫室中所使用的熱線反射薄膜構造體,該熱線反射薄膜構造體係由:將以在折射率不同的至少2種樹脂層交互層合而得之波長400~750nm的光之平均穿透率為80%以上、波長800~1100nm的光之平均反射率為70%以上之多層層合薄膜的至少單側表面設有滑性賦予層之原薄膜經裁切的細帶狀條帶編織成為經紗或緯紗、以絲紗或紡紗編織成為緯紗或經紗的編織物所構成,該絲紗或紡紗的粗細度為該細帶狀條帶之寬度的0.01~0.30倍,相鄰之該細帶狀條帶的間隔為該細帶狀條帶之寬度的0.1~0.5倍。 (12) A heat ray reflective film structure, which is a heat ray reflective film structure used in an agricultural greenhouse that utilizes sunlight. The heat ray reflective film structure system is composed of: interacting with at least two resin layers with different refractive indices The average transmittance of light with a wavelength of 400 to 750 nm is more than 80%, and the average reflectance of light with a wavelength of 800 to 1100 nm is more than 70%. At least one side of the multilayer laminate film is provided with slipperiness. The thin ribbon-like strips cut by the original film of the layer are woven into warp yarns or weft yarns, and silk yarns or spun yarns are woven into weft yarns or warp yarns. The thickness of the silk yarn or spun yarn is the thin ribbon The width of the strip is 0.01 to 0.30 times, and the interval between adjacent thin strips is 0.1 to 0.5 times the width of the thin strip.
(13)如(12)之熱線反射薄膜構造體,其中前述多層層合薄膜係於至少單側表面設有紫外線吸收層。 (13) The heat-ray reflective film structure according to (12), wherein the aforementioned multilayer laminate film is provided with an ultraviolet absorbing layer on at least one surface.
(14)如(13)之熱線反射薄膜構造體,其中前述紫外線吸收層係含有黏合劑樹脂,且該黏合劑樹脂為氟樹脂。 (14) The heat-ray reflective film structure of (13), wherein the ultraviolet absorbing layer contains a binder resin, and the binder resin is a fluororesin.
(15)如(12)~(14)中任一項之熱線反射薄膜構造體,其中前述熱線反射薄膜構造體的開孔率為10~30%、波長350nm的光線穿透率為7~21%。 (15) The heat ray reflective film structure of any one of (12) to (14), wherein the opening rate of the heat ray reflective film structure is 10-30%, and the light transmittance of 350nm wavelength is 7-21 %.
(16)如(12)~(15)中任一項之熱線反射薄膜構造體,其中前述多層層合薄膜之折射率較高的樹脂層為由 具有縮合型芳香環之樹脂所構成的樹脂層。 (16) The heat-ray reflective film structure of any one of (12) to (15), wherein the resin layer with a higher refractive index of the aforementioned multilayer laminate film is due to A resin layer composed of a resin with a condensed aromatic ring.
(17)如(12)~(16)中任一項之熱線反射薄膜構造體,其中前述多層層合薄膜之前述2種樹脂層於面內方向上的平均折射率差為至少0.03。 (17) The heat-ray reflective film structure according to any one of (12) to (16), wherein the average refractive index difference in the in-plane direction of the two resin layers of the multilayer laminate film is at least 0.03.
(18)如(12)~(17)中任一項之熱線反射薄膜構造體,其中前述多層層合薄膜係具有至少101層之光學厚度為150~400nm的樹脂層。 (18) The heat-ray reflective film structure according to any one of (12) to (17), wherein the aforementioned multilayer laminate film has at least 101 resin layers with an optical thickness of 150 to 400 nm.
在本發明之農業溫室及使用此農業溫室之植物栽培方法中,會活潑地進行光合作用的日間係關閉設於屋頂部之天窗而使農業溫室成為密閉狀態,可將農業溫室內的溫度、二氧化碳濃度及濕度維持、控制於活潑地進行光合作用的範圍,而且,透過使用:使用可見光的穿透率高、熱線的反射率高之熱線反射薄膜所形成的熱線遮蔽手段,可在不妨礙植物的生長下降低能量成本。 In the agricultural greenhouse of the present invention and the plant cultivation method using the agricultural greenhouse, the daytime system that can actively perform photosynthesis closes the skylights on the roof to make the agricultural greenhouses airtight, which can reduce the temperature and carbon dioxide in the agricultural greenhouses. The concentration and humidity are maintained and controlled in the range of active photosynthesis. Moreover, through use: the heat ray shielding method formed by the heat ray reflection film with high transmittance of visible light and high heat ray reflectivity can be used without disturbing plants. Reduce energy costs while growing.
又,不會活潑地進行光合作用的夜間係敞開設於屋頂部之天窗,可使農業溫室內的溫度下降以防備翌日的日間溫度上昇,而且,透過使用在熱線反射薄膜上以既定間隔形成有複數個貫通孔的熱線遮蔽手段,可使農業溫室下部之於日間經加熱的空氣通過熱線遮蔽手段向外部逸散;而且,於夜間,尤為清晨,即使靠近屋頂之上部的空氣遇冷時,仍可防止在熱線遮蔽手段底面發生的結露形成水滴滴到植物,使植物的果實、葉、花等變色、劣化等 發生品質下降或薄膜本身發生劣化的情形。 In addition, the skylights opened on the roof at night, which do not actively perform photosynthesis, can reduce the temperature in the agricultural greenhouse to prevent the daytime temperature rise of the next day. Moreover, the heat-ray reflective film is used to form a heat-ray reflective film at predetermined intervals. Multiple through-hole hot wire shielding means can make the air heated during the day in the lower part of the agricultural greenhouse escape to the outside through the hot wire shielding means; moreover, at night, especially in the early morning, even if the air near the top of the roof is cold, It can prevent the condensation that occurs on the bottom surface of the heating wire shielding means from forming water droplets on the plants, discoloring and deteriorating the fruits, leaves, flowers, etc. The quality of the film may deteriorate or the film itself may deteriorate.
又,在本發明之農業溫室及使用此農業溫室之植物栽培方法中,日間係關閉設於屋頂部之天窗,由於農業溫室內的水分不易向外部逸散,可減少對植物的供給水量,在乾燥地區等也能栽培植物。 In addition, in the agricultural greenhouse of the present invention and the plant cultivation method using the agricultural greenhouse, the skylights provided on the roof are closed during the day. Since the water in the agricultural greenhouse is not easy to escape to the outside, the water supply to the plants can be reduced. Plants can also be cultivated in dry areas.
又,在本發明之農業溫室及使用此農業溫室之植物栽培方法中,透過使用以既定間隔形成有複數個貫通孔的熱線遮蔽手段,可將紫外線穿透率調整於可防止熱線反射薄膜之由紫外線引起的劣化,同時不會妨礙果實的顏色形成、由蜜蜂所進行之授粉活動的範圍。 In addition, in the agricultural greenhouse of the present invention and the plant cultivation method using the agricultural greenhouse, by using a heat shielding means in which a plurality of through holes are formed at predetermined intervals, the transmittance of ultraviolet rays can be adjusted to prevent the heat ray reflection film. The degradation caused by ultraviolet rays will not hinder the color formation of the fruit and the range of pollination activities performed by bees.
本發明之熱線反射薄膜構造體由於係使用可見光的穿透率高、熱線的反射率高的多層層合薄膜所形成,可在不妨礙植物的生長下抑制農業溫室內的溫度的上昇。 Since the heat-ray reflective film structure of the present invention is formed by using a multilayer laminate film with high visible light transmittance and high heat-ray reflectivity, the temperature rise in the agricultural greenhouse can be suppressed without hindering the growth of plants.
又,本發明之熱線反射薄膜構造體由於為將以在此多層層合薄膜的兩表面設有滑性賦予層之原薄膜經裁切的細帶狀條帶編織成為經紗或緯紗、以絲紗或紡紗(以下亦稱「絲紗等」)編織成為緯紗或經紗的編織物,故可順利且均質地進行編織,與使用多層層合薄膜單質的情形相比,可使捲繞性、抗黏連性、耐撕裂性、耐久性等的機械強度更良好,而且,藉由形成於細帶狀條帶、絲紗等之間的開口,可確保通氣性。 In addition, the heat-reflective film structure of the present invention is woven into warp yarns or weft yarns and silk yarns from the original film provided with slippage imparting layers on both surfaces of the multilayer laminate film. Or spun yarn (hereinafter also referred to as "silk yarn, etc.") is woven into a weft or warp knitted fabric, so it can be knitted smoothly and uniformly. Compared with the case of using a multi-layer laminated film, it can achieve winding and resistance The mechanical strength such as adhesion, tear resistance, durability, etc. is better, and the air permeability can be ensured by openings formed between thin ribbon-like strips, silk yarns, etc.
再者,本發明之熱線反射薄膜構造體係使此編織物之細帶狀條帶的寬度、相鄰之絲紗等的間隔及相鄰 之細帶狀條帶的間隔成特定的範圍,而使開孔率成為適確的範圍,與使用多層層合薄膜單質的情形相比,可確保毫不遜色之較高的可見光的穿透率及熱線的反射率,同時使波長350nm的光線(以下有稱為「紫外線」)的穿透率成為適確的範圍。 Furthermore, the heat-ray reflective film construction system of the present invention makes the width of the thin ribbon-like strips of the woven fabric, the interval between adjacent silk yarns, and the adjacent The interval of the thin ribbon-like strips is in a specific range, so that the aperture ratio becomes an appropriate range. Compared with the case of using a multi-layer laminated film, it can ensure a higher visible light transmittance. And the reflectance of the heat ray, and the transmittance of light with a wavelength of 350nm (hereinafter referred to as "ultraviolet rays") into an appropriate range.
1:農業溫室 1: Agricultural greenhouse
2:CO2供給手段 2: CO 2 supply means
3:熱線遮蔽手段或熱線反射薄膜構造體 3: Heat shielding means or heat reflecting film structure
4:除濕冷卻手段 4: Dehumidification and cooling means
5:天窗 5: Skylight
7:細帶狀條帶 7: Thin ribbon strip
8:透明絲線 8: Transparent silk thread
11:細帶狀條帶(經紗) 11: Thin ribbon strip (warp yarn)
12:絲紗等(緯紗) 12: Silk yarn, etc. (weft yarn)
13:絲紗等(經紗) 13: Silk yarn, etc. (warp yarn)
101:(農業溫室的)屋頂部 101: (Agricultural greenhouse) roof department
102:(農業溫室的)栽培部 102: (Agricultural Greenhouse) Cultivation Department
103:SUNNYCOAT 103:SUNNYCOAT
104:近紅外線吸收薄膜 104: Near infrared absorption film
105:天窗 105: Skylight
106:CO2產生裝置 106: CO 2 generator
107:熱泵 107: Heat Pump
108:太陽光 108: Sunlight
A:緯紗(絲紗等)的粗細度 A: The thickness of the weft yarn (silk yarn, etc.)
B:細帶狀條帶的寬度 B: The width of the thin ribbon
C:緯紗的間隔 C: weft interval
D:細帶狀條帶的間隔 D: Interval between thin strips
E:聚乙烯製絲紗等的粗細度 E: Thickness of polyethylene silk yarn, etc.
第1圖為用以說明本發明之農業溫室或熱線反射薄膜構造體之表示農業溫室的一例的示意圖。 Figure 1 is a schematic diagram for explaining an example of an agricultural greenhouse or a heat-ray reflective film structure of the present invention.
第2圖為在本發明之農業溫室中可適宜使用之熱線遮蔽手段的實例,係對薄膜經裁切成細帶狀之細帶狀條帶進行編織而成者的一部分前視圖。 Figure 2 is an example of a hot wire shielding method that can be suitably used in the agricultural greenhouse of the present invention. It is a partial front view of a thin ribbon-shaped strip that is cut into thin ribbons.
第3圖為表示本發明之熱線反射薄膜構造體之一實施形態的一部分前視圖。 Fig. 3 is a partial front view showing an embodiment of the heat-ray reflective film structure of the present invention.
第4圖為表示本發明之熱線反射薄膜構造體之另一實施形態的一部分前視圖。 Fig. 4 is a partial front view showing another embodiment of the heat-ray reflective film structure of the present invention.
第5圖為表示先前之農業溫室(由本案發明人等所提案,獲頒農業、食料產業創新大獎之農業溫室)的示意圖。 Figure 5 is a schematic diagram showing the previous agricultural greenhouse (the agricultural greenhouse proposed by the inventors of this case and awarded the Agriculture and Food Industry Innovation Award).
以下,就本發明之實施形態,使用圖式具體 加以說明,惟本發明不受此等所限制。 Hereinafter, regarding the embodiment of the present invention, the diagrams are used specifically It should be noted that the present invention is not limited by these.
第5圖為表示先前之農業溫室的示意圖,係如先前所說明,將農業溫室的屋頂部101與栽培部102以透明的樹脂板「SUNNYCOAT103」隔熱、區隔開來,而將栽培部102的二氧化碳濃度經濟地保持於高濃度,同時將「近紅外線吸收薄膜104」的發熱從與栽培部102隔熱、區隔開來的屋頂部101,通過天窗105向外部放出,來防止栽培部102的溫度上昇。
Figure 5 is a schematic diagram showing the previous agricultural greenhouse. As previously described, the
首先,就本發明之農業溫室及使用此農業溫室之植物栽培方法加以說明。 First, the agricultural greenhouse of the present invention and the plant cultivation method using the agricultural greenhouse will be described.
第1圖為用以說明本發明之農業溫室或熱線反射薄膜構造體之表示農業溫室的一例的示意圖;就符號3,在本發明之農業溫室的說明中係表示熱線阻隔手段,在本發明之熱線反射薄膜構造體的說明中則表示熱線反射薄膜構造體。
Figure 1 is a schematic diagram for explaining an example of an agricultural greenhouse or a heat-ray reflective film structure of the present invention; as for
此利用太陽光之農業溫室1,於上部被覆有熱線遮蔽手段3,於下部具備對農業溫室1的內部供給二氧化碳的CO2供給手段2及冷卻農業溫室1的內部的除濕冷卻手段4。此農業溫室1中,日間係關閉天窗5而將農業溫室內的二氧化碳濃度經濟地維持於高濃度,夜間則敞開天窗5而使農業溫室內的溫度下降。
This agricultural greenhouse 1 using sunlight is covered with a heating wire shielding means 3 on the upper part, a CO 2 supply means 2 for supplying carbon dioxide to the inside of the agricultural greenhouse 1 and a dehumidification cooling means 4 for cooling the inside of the agricultural greenhouse 1 at the lower part. In this agricultural greenhouse 1, the
此熱線遮蔽手段3係使用波長400~700nm的
光之平均穿透率為80%以上,且波長800~1200nm的光之平均反射率為70%以上的熱線反射薄膜所形成,以既定間隔形成有複數個貫通孔。
This hot-
本發明之農業溫室,由於未設有如「SUNNYCOAT」之樹脂板,與先前之農業溫室相比,具有以下優點: Since the agricultural greenhouse of the present invention is not equipped with a resin board such as "SUNNYCOAT", compared with the previous agricultural greenhouse, it has the following advantages:
1)可提高植物的生長所需之可見光的穿透率。(在設有「SUNNYCOAT」的先前之農業溫室中,係如前述,植物的生長所需之400~700nm的光的穿透率係頂多為70%左右而甚低) 1) It can improve the transmittance of visible light required for plant growth. (In the previous agricultural greenhouse with "SUNNYCOAT", as mentioned above, the transmittance of 400~700nm light required for the growth of plants is at most about 70%, which is very low)
2)可減輕農業溫室的設備費用。 2) It can reduce the equipment cost of agricultural greenhouses.
3)不會發生:於夜間,尤為清晨,由於栽培部與屋頂部之間的溫差變大,在「SUNNYCOAT」的底面發生結露而形成水滴滴到植物,使植物的果實、葉、花等變色、劣化的問題。 3) It will not happen: at night, especially early in the morning, due to the large temperature difference between the cultivation part and the roof part, condensation occurs on the bottom surface of "SUNNYCOAT" and forms water droplets to the plants, discoloring the fruits, leaves, flowers, etc. , The problem of deterioration.
又,在先前之農業溫室中,為了遮蔽太陽光所含的熱線而使用「近紅外線吸收薄膜」,但此種熱線吸收型薄膜會吸收熱線而使薄膜本身發熱,而使農業溫室內的溫度上昇。另一方面,在本發明之農業溫室中由於係使用「波長800~1200nm的光之平均反射率為70%以上的熱線反射薄膜」之熱線反射型薄膜,而不易使農業溫室內的溫度上昇。 In addition, in the previous agricultural greenhouses, "near infrared absorbing films" were used to shield the heat rays contained in sunlight. However, such heat absorbing films will absorb the heat rays and cause the film itself to generate heat, thereby increasing the temperature in the agricultural greenhouse. . On the other hand, in the agricultural greenhouse of the present invention, since the heat-reflecting film of "the heat-reflecting film with an average reflectivity of light with a wavelength of 800 to 1200 nm of 70% or more" is used, it is difficult to increase the temperature in the agricultural greenhouse.
以下,就本發明之農業溫室依序加以說明。 Hereinafter, the agricultural greenhouse of the present invention will be described in order.
本發明之農業溫室係利用太陽光者。若使用LED等的人工光,雖可調整、控制作為光合作用之驅動源的光能量的量,但須耗費照射能量,而非適於植物的大量生產。 The agricultural greenhouse of the present invention uses sunlight. If artificial light such as LEDs is used, although the amount of light energy used as the driving source of photosynthesis can be adjusted and controlled, the irradiation energy is required and it is not suitable for mass production of plants.
而且,在利用太陽光之農業溫室中,由於太陽光包含植物的生長所需之可見光、以及使農業溫室內的溫度上昇的熱線,為了將農業溫室內保持於適溫,一般係採用自然換氣、強制通氣等的換氣作為經濟的冷卻手段,而換氣需耗時費力且耗費成本,而且會因換氣使害蟲更容易侵入農業溫室內。 Moreover, in agricultural greenhouses that use sunlight, since sunlight includes visible light necessary for the growth of plants, and a hot line that raises the temperature in the agricultural greenhouse, natural ventilation is generally adopted in order to keep the temperature in the agricultural greenhouse. Ventilation, such as forced ventilation, is used as an economical cooling method. Ventilation requires time, labor, and cost, and it will make it easier for pests to invade agricultural greenhouses due to ventilation.
再者,在將二氧化碳濃度維持於高程度的農業溫室中,為了盡可能不使二氧化碳逸散至外部,則需保持較低的換氣率;為此,於日間必須使冷氣機設備作動而將廣大農業溫室內的溫度維持於適溫,冷氣機需耗費大量的能量。 Furthermore, in an agricultural greenhouse that maintains a high level of carbon dioxide concentration, in order to prevent the carbon dioxide from escaping to the outside as much as possible, it is necessary to maintain a low air exchange rate; for this reason, the air conditioner must be activated during the day. The temperature in the vast agricultural greenhouse is maintained at an appropriate temperature, and the air conditioner consumes a lot of energy.
本發明之農業溫室,會活潑地進行光合作用的日間係關閉設於屋頂部之天窗而使農業溫室成為密閉狀態,藉由供給二氧化碳的CO2供給手段,將農業溫室內的二氧化碳濃度維持、控制於活潑地進行光合作用的範圍,同時藉由除濕冷卻手段,將農業溫室內的溫度及濕度維持、控制於活潑地進行光合作用的範圍,由此可效率良好地栽培植物。 The agricultural greenhouse of the present invention actively performs photosynthesis in the daytime system. The skylights installed on the roof are closed to make the agricultural greenhouse in a sealed state. The CO 2 supply means for supplying carbon dioxide can maintain and control the carbon dioxide concentration in the agricultural greenhouse. The temperature and humidity in the agricultural greenhouse are maintained and controlled in the range of active photosynthesis by means of dehumidification and cooling, so that plants can be cultivated efficiently.
再者,該熱線遮蔽手段係使用可見光之平均 穿透率高達80%以上,且熱線之平均反射率高達70%以上的熱線反射薄膜,由此可在不妨礙植物的生長下防止農業溫室內的溫度上昇,並降低適溫的維持所需之能量成本。 Furthermore, the hot wire shielding method uses the average of visible light A heat-ray reflective film with a transmittance of over 80% and an average reflectivity of the heat line of over 70%, which prevents the temperature rise in the agricultural greenhouse without hindering the growth of plants, and reduces the need for maintaining a suitable temperature Energy cost.
又,本發明之農業溫室,不會進行光合作用的夜間係敞開設於屋頂部之天窗,使農業溫室內的溫度下降以防備翌日的日間溫度上昇;藉由在熱線遮蔽手段上以既定間隔形成複數個貫通孔,可使農業溫室下部之於日間經加熱的空氣通過熱線遮蔽手段向外部逸散;而且,於夜間,尤為清晨,即使靠近屋頂之上部的空氣遇冷時,仍可防止在熱線遮蔽手段底面發生的結露形成水滴滴到植物,使植物的果實、葉、花等變色、劣化等發生品質下降或薄膜本身發生劣化的情形。 In addition, the agricultural greenhouse of the present invention does not undergo photosynthesis at night by opening the skylights opened on the roof, so that the temperature in the agricultural greenhouse is lowered to prevent the daytime temperature rise the next day; it is formed at predetermined intervals on the hot wire shielding means Multiple through holes allow the heated air in the lower part of the agricultural greenhouse to escape to the outside through the hot-line shielding means; and, at night, especially in the morning, even if the air near the upper part of the roof is cold, it can still prevent the hot-line Condensation on the bottom surface of the shielding means forms water droplets and drips onto the plant, causing discoloration and deterioration of the plant's fruits, leaves, flowers, etc., or deterioration of the film itself.
作為本發明之農業溫室內部所具備之對農業溫室內部供給二氧化碳的CO2供給手段,可使用周知的各種手段。可舉出例如以酸使碳酸鹽或重碳酸鹽中和之手段、燃燒烴類之手段、使用液化二氧化碳之手段等;而由較為經濟且雜質較少而言,可較佳使用燃燒LP氣體、液化天然氣之手段。 As the CO 2 supply means for supplying carbon dioxide inside the agricultural greenhouse provided in the agricultural greenhouse of the present invention, various well-known means can be used. Examples include methods for neutralizing carbonates or bicarbonates with acids, methods for burning hydrocarbons, and methods for using liquefied carbon dioxide. In terms of economy and less impurities, it is better to use burning LP gas, The means of liquefied natural gas.
作為本發明之農業溫室內部所具備之冷卻農業溫室內部的手段,係使用如藉由熱泵之熱交換的除濕冷卻手段。 As a means for cooling the interior of the agricultural greenhouse provided in the agricultural greenhouse of the present invention, a dehumidification cooling means such as heat exchange by a heat pump is used.
農業溫室內的冷卻,一般係採用噴出微細的霧,利用蒸發時的氣化冷卻來予以冷卻的細霧冷卻手段,而在如本發明之日間經密閉的農業溫室中,由於未進行換氣,水蒸氣呈飽和狀態,細霧自始就不會氣化,因而無法使用細霧冷卻手段來予以冷卻。 The cooling in agricultural greenhouses generally uses a fine mist cooling method that sprays fine mist and uses vaporization cooling during evaporation to cool down. However, in the closed agricultural greenhouse during the day as in the present invention, since ventilation is not performed, The water vapor is saturated, and the mist will not vaporize from the beginning, so the mist cooling method cannot be used to cool it.
本發明之農業溫室所使用之熱線遮蔽手段的第1特徵在於,熱線遮蔽手段非為如一般的農業溫室中所使用之藉由金屬蒸鍍層、金屬箔、含金屬層之金屬來反射熱線以及可見光的薄膜,而是使用光學干涉濾光器、層合玻璃領域中所使用的熱線反射薄膜所形成。 The first feature of the heat ray shielding means used in the agricultural greenhouse of the present invention is that the heat ray shielding means is not the same as that used in general agricultural greenhouses by reflecting the heat rays and visible light by a metal vapor deposition layer, metal foil, and metal containing a metal layer The film is formed by using optical interference filters and heat-ray reflective films used in the field of laminated glass.
具體而言,此熱線反射薄膜,其中太陽光所含之可見光之平均穿透率高達80%以上,且太陽光所含之熱線之平均反射率高達70%以上。此外,於此,可見光係指波長400~700nm的光;熱線則指波長800~1200nm的光。 Specifically, in this heat-ray reflective film, the average transmittance of visible light contained in sunlight is as high as 80% or more, and the average reflectivity of heat rays contained in sunlight is as high as 70% or more. In addition, here, visible light refers to light with a wavelength of 400 to 700 nm; hot wire refers to light with a wavelength of 800 to 1200 nm.
透過使用可見光之平均穿透率高達80%以上的熱線反射薄膜,可將作為光合作用之驅動源的可見光充分地供給至植物,故可充分促進植物的生長。 By using a heat-ray reflective film with an average transmittance of visible light as high as 80% or more, the visible light that is the driving source of photosynthesis can be fully supplied to the plants, so the growth of the plants can be fully promoted.
又,透過使用熱線之平均反射率高達70%以上的熱線反射薄膜,可充分遮蔽使農業溫室內的溫度上昇的熱線。再者,由於如熱線吸收薄膜之薄膜本身的發熱亦 較少,可抑制農業溫室內的溫度的上昇,而能夠降低除濕冷氣機所需之成本。 In addition, by using a heat-ray reflective film with an average reflectivity of the heat-wire as high as 70% or more, the heat-wire that raises the temperature in the agricultural greenhouse can be sufficiently shielded. Furthermore, due to the heat generated by the film itself, such as the heat-absorbing film Less, can suppress the temperature rise in the agricultural greenhouse, and can reduce the cost of the dehumidification air conditioner.
作為此種具有可見光之較高之平均穿透率及熱線之較高之平均反射率的熱線反射薄膜,可較佳使用○如日本特表平9-506837號公報所記載之用於光學干涉濾光器的聚酯系多層光學薄膜、○如日本特表平11-508380號公報所記載之貼附於窗玻璃表面之包含多層聚合物薄膜與透明導電體的薄膜、○如國際公開第2005/040868號所記載之以層合玻璃層合於玻璃而使用的層合聚酯薄膜、○如國際公開第2013/080987號所記載之以層合玻璃層合於玻璃而使用的雙軸延伸層合聚酯薄膜、○如日本特開2014-228837號公報所記載之以層合玻璃層合於玻璃而使用的雙軸延伸層合聚酯薄膜、等的多層層合薄膜。 As this kind of hot ray reflective film with high average transmittance of visible light and high average reflectivity of hot ray, it is preferable to use it for optical interference filter as described in JP 9-506837 The polyester-based multilayer optical film of the optical device, ○A film containing a multilayer polymer film and a transparent conductor attached to the surface of a window glass as described in JP 11-508380A, ○ such as International Publication No. 2005/ Laminated polyester film used for laminating glass on glass as described in No. 040868, ○ Biaxially stretched laminate used for laminating glass on glass as described in International Publication No. 2013/080987 Polyester film, ○, a biaxially stretched laminated polyester film used for laminating glass with laminated glass as described in JP 2014-228837 A, a multilayer laminated film such as.
此等多層層合薄膜非為如在農業溫室中一般所使用之以金屬蒸鍍層、金屬箔、含金屬層等反射熱線等者,而是折射率不同的至少2種樹脂層交互層合而成的多層層合薄膜,可使太陽光中的可見光穿透,並選擇性地反射熱線。 These multi-layer laminated films are not made of metal vapor deposition layers, metal foils, metal-containing layers, etc., as generally used in agricultural greenhouses, but are formed by alternately laminating at least two resin layers with different refractive indexes. The multi-layer laminated film can penetrate visible light in sunlight and selectively reflect heat rays.
用於本發明中之熱線反射薄膜的多層層合薄膜,只要是具有上述特性者則不特別限制,較佳為折射率不同的至少2種樹脂層交互層合而成。折射率不同的樹脂層之交互層合所產生的反射,反射波長可依樹脂層的光學 厚度(折射率×厚度)來設計,反射率則可依樹脂層的總數與樹脂層間的折射率差來設計;可選擇樹脂及調整樹脂層的厚度或層合數,以使其成為所要的反射特性。 The multilayer laminate film used in the heat-ray reflective film of the present invention is not particularly limited as long as it has the above-mentioned characteristics, and it is preferably formed by alternately laminating at least two types of resin layers with different refractive indexes. The reflection caused by the alternate lamination of resin layers with different refractive indexes, the reflection wavelength can be based on the optical Thickness (refractive index×thickness) is designed, and the reflectance can be designed according to the total number of resin layers and the difference in refractive index between the resin layers; the resin can be selected and the thickness or number of layers of the resin layer can be selected to make it the desired reflection characteristic.
作為形成多層層合薄膜之樹脂層的樹脂,可採用其本身周知者,可舉出聚酯、聚碸、聚醯胺、聚醚、聚酮、聚丙烯酸、聚碳酸酯、聚縮醛、聚苯乙烯、聚醯胺醯亞胺、聚芳酯、聚烯烴、多氟聚合物、聚胺基甲酸酯、聚芳基碸、聚醚碸、聚芳硫醚、聚氯乙烯、聚醚醯亞胺、四氟乙烯、聚醚酮,此等非限於均聚物,亦可為共聚合。又,由容易提高樹脂間的折射率差而言,較佳為至少樹脂層之一具有容易提高折射率之萘環等的縮合型芳香環作為重複單元的樹脂,亦可使其以共聚合成分存在。 As the resin forming the resin layer of the multilayer laminate film, those known per se can be used, and examples include polyester, polyamide, polyamide, polyether, polyketone, polyacrylic acid, polycarbonate, polyacetal, and polyacetal. Styrene, polyamide imine, polyarylate, polyolefin, polyfluoropolymer, polyurethane, polyaryl sulfide, polyether sulfide, polyarylene sulfide, polyvinyl chloride, polyether amide Imine, tetrafluoroethylene, polyether ketone, these are not limited to homopolymers, but can also be copolymers. In addition, in terms of easily increasing the refractive index difference between resins, at least one of the resin layers is preferably a resin having a condensed aromatic ring such as a naphthalene ring that easily increases the refractive index as a repeating unit, or it may be a copolymerized component exist.
此等當中,作為折射率較高之樹脂層所使用的樹脂,由容易藉由延伸而展現高度的分子配向而言較佳為具結晶性之熱可塑性樹脂,尤以熔點為200℃以上的熱可塑性樹脂為佳。由此觀點而言,作為具體的熱可塑性樹脂,較佳為聚酯,更佳為聚對苯二甲酸乙二酯或聚乙烯-2,6-萘二羧酸酯,尤其是由折射率高、能以高度的延伸倍率實施延伸而言,較佳為具有縮合型芳香環的聚乙烯-2,6-萘二羧酸酯。 Among them, the resin used as a resin layer with a higher refractive index is preferably a crystalline thermoplastic resin in terms of easily exhibiting a high degree of molecular alignment by stretching, especially a thermal plastic resin with a melting point of 200°C or higher. Plastic resin is preferred. From this point of view, as the specific thermoplastic resin, polyester is preferred, and polyethylene terephthalate or polyethylene-2,6-naphthalene dicarboxylate is more preferred. , In terms of stretching at a high stretching ratio, polyethylene-2,6-naphthalenedicarboxylate having a condensed aromatic ring is preferred.
另一方面,就折射率較低之樹脂層所使用的樹脂而言,只要是可展現與折射率較高之樹脂層之充分的折射率差,並可維持所需之密接性者則不特別限制。亦可使用例如將可降低折射率之共聚合成分與折射率較高之樹 脂層所使用的樹脂共聚合而成的樹脂等。又,由不需要藉由延伸等來提高折射率而言,亦可使用比非晶性樹脂或折射率較高之樹脂層的樹脂具有極低之熔點的樹脂。例如,可較佳使用包含對苯二甲酸乙二酯成分的非晶性聚酯等。 On the other hand, as far as the resin used in the resin layer with a lower refractive index is concerned, it is not special as long as it can exhibit a sufficient refractive index difference with the resin layer with a higher refractive index and can maintain the required adhesion. limit. It is also possible to use, for example, a copolymer component that can reduce the refractive index and a tree with a higher refractive index. The resin used in the grease layer is copolymerized with resin, etc. In addition, since it is not necessary to increase the refractive index by stretching or the like, it is also possible to use a resin having an extremely lower melting point than an amorphous resin or a resin of a resin layer with a higher refractive index. For example, amorphous polyester containing an ethylene terephthalate component can be preferably used.
本發明之農業溫室所使用之熱線遮蔽手段的第2特徵在於,在熱線遮蔽手段上以既定間隔形成有複數個貫通孔。 The second feature of the heating wire shielding means used in the agricultural greenhouse of the present invention is that a plurality of through holes are formed in the heating wire shielding means at predetermined intervals.
本發明之農業溫室所使用之熱線遮蔽手段,由於需充分遮蔽熱線,而如第1圖所示,涵蓋農業溫室的上部整面地被覆,將農業溫室區隔成上部與下部,為使農業溫室的上部與下部的通氣性更良好,而以既定間隔形成有複數個貫通孔。 The hot wire shielding method used in the agricultural greenhouse of the present invention requires sufficient shielding of the hot wire. As shown in Figure 1, it covers the entire upper surface of the agricultural greenhouse, and divides the agricultural greenhouse into upper and lower regions, so that the agricultural greenhouse The air permeability of the upper and lower parts of the slab is better, and a plurality of through holes are formed at predetermined intervals.
本發明之農業溫室,不會進行光合作用的夜間係敞開設於屋頂部之天窗,使農業溫室內的溫度下降以防備翌日的日間溫度上昇;藉由在熱線遮蔽手段上以既定間隔形成複數個貫通孔,可使農業溫室下部之於日間經加熱的空氣通過熱線遮蔽手段向外部逸散;而且,於夜間,尤為清晨,即使靠近屋頂之上部的空氣遇冷時,仍可防止在熱線遮蔽手段底面發生結露,形成水滴滴到植物,使植物的果實、葉、花等變色、劣化等發生品質下降或熱線遮蔽手段本身發生劣化的情形。 In the agricultural greenhouse of the present invention, the skylights in the roof are opened at night, which will not undergo photosynthesis, so that the temperature in the agricultural greenhouse is lowered to prevent the daytime temperature rise of the next day; by forming a plurality of heat-wire shielding means at predetermined intervals The through hole allows the heated air in the lower part of the agricultural greenhouse to escape to the outside through the hot wire shielding means; moreover, at night, especially in the early morning, even if the air near the upper part of the roof is cold, it can still prevent the hot wire shielding means Condensation occurs on the bottom surface, forming water droplets and dripping onto the plant, causing discoloration and deterioration of the plant's fruits, leaves, flowers, etc., and the quality of the plant's fruits, leaves, flowers, etc., or the heat-ray shielding means itself deteriorates.
形成於熱線遮蔽手段之複數個貫通孔的開孔率較佳為 0.5~10%,更佳為1~5%的範圍。 The opening ratio of the plurality of through holes formed in the hot wire shielding means is preferably 0.5~10%, more preferably 1~5% range.
此外,本發明中的「開孔率」係對熱線遮蔽手段之其中一表面上長寬各10cm的正方形部分(面積100cm2),由表面垂直方向進行表面觀察時,以無阻礙地可看見背面側的部分作為開孔,求出該開孔的面積(稱為開孔面積)之總和(Scm2),依式:〔S(cm2)/100(cm2)〕×100來求得。 In addition, the "opening rate" in the present invention refers to the square part (area 100cm 2 ) of 10 cm in length and width on one surface of the heat shielding means. When the surface is viewed from the vertical direction of the surface, the back surface can be seen without obstruction. The part on the side is regarded as an opening, and the total area (Scm 2 ) of the area of the opening (referred to as the opening area) is calculated according to the formula: [S(cm 2 )/100(cm 2 )]×100.
在本發明之農業溫室中,開孔率若為0.5%以上則可使熱線遮蔽手段的通氣性更良好,在不會進行光合作用的夜間敞開設於屋頂部之天窗,使農業溫室內的溫度下降以防備翌日的日間溫度上昇時,可使農業溫室下部之於日間經加熱的空氣通過熱線反射薄膜向外部逸散。而且,於夜間,尤為清晨,即使靠近屋頂之上部的空氣遇冷時,仍可防止在薄膜底面發生之結露形成水滴滴到植物,使植物的果實、葉、花等變色、劣化等發生品質下降或薄膜本身發生劣化的情形,因而較佳。再者,開孔率若為1%以上則熱線反射薄膜的通氣性更良好,因而較佳。 In the agricultural greenhouse of the present invention, if the aperture ratio is 0.5% or more, the ventilation of the hot wire shielding means can be improved, and the skylights in the roof are opened at night when photosynthesis will not occur, so that the temperature in the agricultural greenhouse When the temperature is lowered to prevent the temperature rise the next day, the air heated during the day in the lower part of the agricultural greenhouse can escape to the outside through the heat reflection film. Moreover, at night, especially early in the morning, even when the air near the upper part of the roof is cold, it can still prevent condensation on the bottom of the film from forming water droplets on the plant, causing the plant's fruits, leaves, flowers, etc. to discolor and deteriorate. Or the film itself is degraded, which is preferable. Furthermore, if the porosity is 1% or more, the air permeability of the heat ray reflective film is better, which is preferable.
又,開孔率若為10%以下,由熱線反射薄膜所獲得的熱線反射機能不會大幅降低,因而較佳。再者,開孔率若為5%以下,可進一步減少熱線反射能力的降低,因而更佳。 In addition, if the aperture ratio is 10% or less, the heat-ray reflection function obtained by the heat-ray reflection film will not be greatly reduced, which is preferable. Furthermore, if the aperture ratio is 5% or less, the decrease in heat ray reflection ability can be further reduced, which is better.
作為熱線遮蔽手段,可使用對熱線反射薄膜穿設貫通孔之構造者。 As the heat shielding means, a structure in which a through hole is provided for the heat reflecting film can be used.
貫通孔的配置較佳為以既定間隔穿設,以使熱線遮蔽 手段的強度、剛性等物性盡可能為均等。為使熱線遮蔽手段的通氣性盡可能為均等,貫通孔的間隔係取30cm以下,較佳為20cm以下,更佳為10cm以下。 The through holes are preferably arranged at a predetermined interval to shield the hot wire The physical properties such as strength and rigidity of the means are as uniform as possible. In order to make the air permeability of the heating wire shielding means as uniform as possible, the interval between the through holes is 30 cm or less, preferably 20 cm or less, and more preferably 10 cm or less.
作為熱線遮蔽手段的具體構造,可為僅對熱線反射薄膜以所定間隔穿設圓形、三角形、四角形等既定形狀的孔而成者;熱線遮蔽手段有時在夜間、冬季等會收捲起來,因此,為使熱線遮蔽手段的捲繞性更良好,孔的形狀較佳作成比起熱線遮蔽手段之長度方向的長度,寬度方向(亦即與長度方向正交之方向)的長度較長者。 As the specific structure of the heat ray shielding means, it can be formed by piercing the heat ray reflective film with holes of predetermined shapes such as circles, triangles, and quadrangles at predetermined intervals; the heat ray shielding means may be rolled up at night or in winter. Therefore, in order to improve the winding property of the heating wire shielding means, the shape of the hole is preferably made to have a longer length in the width direction (that is, the direction orthogonal to the longitudinal direction) than the length of the heating wire shielding means in the longitudinal direction.
為使熱線遮蔽手段的捲繞性、抗黏連性、耐撕裂性、耐久性等更良好,與其以1片熱線反射薄膜形成熱線遮蔽手段,較佳作成以熱線反射薄膜經裁切成細帶狀之細帶狀條帶為經紗及/或緯紗經編織而成的編織物。再者,更佳作成以熱線反射薄膜之細帶狀條帶為經紗或緯紗、以透明絲線為緯紗或經紗編織而成的織物。就細帶狀條帶而言,係使用將熱線反射薄膜裁切成寬度1~50mm,較佳為寬度2~20mm,更佳為寬度4~8mm左右之細帶狀(經細切加工)者。 In order to improve the winding properties, blocking resistance, tear resistance, durability, etc. of the heat ray shielding means, instead of forming the heat ray shielding means with a sheet of heat ray reflecting film, it is better to make the heat ray reflecting film cut into thin pieces. Ribbon-shaped thin ribbon-shaped strips are knitted fabrics knitted by warp yarns and/or weft yarns. Furthermore, it is better to make a fabric woven with the thin ribbon-like strips of the heat reflecting film as warp yarns or weft yarns, and transparent silk yarns as weft yarns or warp yarns. As for the thin strips, the heat-ray reflective film is cut into a thin strip with a width of 1-50mm, preferably a width of 2-20mm, and more preferably a width of 4-8mm (after fine cutting) .
作為編織物的較佳之構造,可舉出如第2圖(a)、(b)、(c)所示之對細帶狀條帶7以透明絲線8編織而成者。第2圖(a)之編織物係以細帶狀條帶7為經紗,架設於織機上橫向穿入透明絲線8編織而成者;第2圖(b)之編織物係以細帶狀條帶7為緯紗、以透明絲線8為經紗編織而成者;又,第2圖(c)之編織物係以
細帶狀條帶7為經紗、以透明絲線8為緯紗編織而成者。
As a preferable structure of the braid, a thin ribbon-like strip 7 woven with
編織物中的貫通孔係形成於經紗間及/或緯紗間,貫通孔的開孔率可根據經紗、緯紗的密度等來調整。 The through holes in the knitted fabric are formed between the warp yarns and/or between the weft yarns, and the opening rate of the through holes can be adjusted according to the density of the warp yarns and the weft yarns.
本發明中的熱線遮蔽手段,由於日間係曝曬於太陽光下,為防止紫外線所引起的劣化,較佳使形成熱線遮蔽手段之熱線反射薄膜之波長350nm的光線穿透率(以下稱「紫外線穿透率」)為10%以下。 The heat-ray shielding means of the present invention is exposed to sunlight during the day. In order to prevent deterioration caused by ultraviolet rays, it is preferable to make the heat-ray-reflecting film forming the heat-ray shielding means have a light transmittance of 350nm (hereinafter referred to as "ultraviolet penetration "Transmittance") is 10% or less.
當熱線反射薄膜含有具有萘二環等縮合型芳香環的樹脂時,由於熱線反射薄膜的紫外線穿透率會自行降低,因此,未必需要設置紫外線吸收層;而熱線反射薄膜的紫外線穿透率較高時,較佳在熱線反射薄膜之最外層的至少單側設置紫外線吸收層,以使紫外線穿透率降低。 When the heat ray reflective film contains a resin with a condensed aromatic ring such as naphthalene dicyclic ring, the ultraviolet light transmittance of the heat ray reflective film will decrease by itself, so it is not necessary to provide an ultraviolet absorbing layer; while the heat ray reflective film has a higher UV transmittance When it is high, it is preferable to provide an ultraviolet absorbing layer on at least one side of the outermost layer of the heat ray reflective film to reduce the ultraviolet transmittance.
作為含於紫外線吸收層的紫外線吸收劑,可舉出例如三系紫外線吸收劑、苯并三唑系紫外線吸收劑、二苯甲酮系紫外線吸收劑、苯并噁酮系紫外線吸收劑、水楊酸酯系紫外線吸收劑、氰基丙烯酸酯系紫外線吸收劑、水楊酸酯系紫外線吸收劑,較佳可使用三系紫外線吸收劑、苯并三唑系紫外線吸收劑。具體而言,可例示2-(2-羥基-4-〔1-辛氧基羰基乙氧基〕苯基)-4,6-雙(4-苯基苯基)-1,3,5-三、2-(2H-苯并三唑-2-基)-4,6-雙(1-甲基-1-苯乙基)酚、2-(2H-苯并三唑-2-基)-6-(1-甲基-1-苯乙基)-4-(1,1,3,3-四甲基丁基)酚、辛基-3-〔 3-三級丁基-4-羥基-5-(5-氯-2H-苯并三唑-2-基)苯基〕丙酸酯、2-乙基己基-3-〔3-三級丁基-4-羥基-5-(5-氯-2H-苯并三唑-2-基)苯基〕丙酸酯、2-(2H-苯并三唑-2-基)4,6-雙(1-乙基-1-苯乙基)酚、酚、2-(5-氯-2H-苯并三唑-2-基)-6-(1,1-二甲基乙基)4-甲基、2,2’-亞甲基雙〔6-(2H-苯并三唑-2-基)-4-1,1,3,3-四甲基丁基〕酚、2-(4,6-二苯基-1,3,5-三-2-基)-5-〔(己基)氧基〕酚、2,4-雙(2-羥基-4-丁氧基苯基)-6-(2,4-雙-丁氧基苯基)-1,3,5-三、苯丙酸、3-(2H-苯并三唑-2-基)-5-(1,1-二甲基乙基)-4-羥基-C7-9分支及鏈狀烷基酯、2-(2-羥基-5-三級甲苯基)-2H-苯并三唑、2-(2H-苯并三唑-2-基)-4,6-二-三級戊基酚、2,2’-二羥基-4-甲氧基二苯甲酮、2-〔4,6-雙(2,4-二甲基苯基)-1,3,5-三-2-基〕-5-(辛氧基)酚、2-(2’-羥基-5’-辛基苯基)苯并三唑。 As the ultraviolet absorber contained in the ultraviolet absorbing layer, for example, three UV absorber, benzotriazole UV absorber, benzophenone UV absorber, benzoxan Ketone UV absorbers, salicylate UV absorbers, cyanoacrylate UV absorbers, salicylate UV absorbers, preferably three It is a UV absorber, benzotriazole UV absorber. Specifically, 2-(2-hydroxy-4-[1-octyloxycarbonylethoxy]phenyl)-4,6-bis(4-phenylphenyl)-1,3,5- three , 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenethyl)phenol, 2-(2H-benzotriazol-2-yl)- 6-(1-methyl-1-phenylethyl)-4-(1,1,3,3-tetramethylbutyl)phenol, octyl-3-〔3-tertiarybutyl-4-hydroxyl -5-(5-chloro-2H-benzotriazol-2-yl)phenyl]propionate, 2-ethylhexyl-3-[3-tertiarybutyl-4-hydroxy-5-(5 -Chloro-2H-benzotriazol-2-yl)phenyl]propionate, 2-(2H-benzotriazol-2-yl)4,6-bis(1-ethyl-1-phenylethyl) Base) phenol, phenol, 2-(5-chloro-2H-benzotriazol-2-yl)-6-(1,1-dimethylethyl)4-methyl, 2,2'-methylene Bis[6-(2H-benzotriazol-2-yl)-4-1,1,3,3-tetramethylbutyl]phenol, 2-(4,6-diphenyl-1,3 ,5-three -2-yl)-5-[(hexyl)oxy]phenol, 2,4-bis(2-hydroxy-4-butoxyphenyl)-6-(2,4-bis-butoxyphenyl) )-1,3,5-three , Phenylpropionic acid, 3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxy-C7-9 branched and chain alkyl ester, 2 -(2-Hydroxy-5-tertiary tolyl)-2H-benzotriazole, 2-(2H-benzotriazol-2-yl)-4,6-di-tertiary amylphenol, 2, 2'-Dihydroxy-4-methoxybenzophenone, 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-tri -2-yl]-5-(octyloxy)phenol, 2-(2'-hydroxy-5'-octylphenyl)benzotriazole.
又,作為紫外線吸收層的黏合劑樹脂,可例示例如聚酯樹脂、丙烯酸樹脂、丙烯酸矽樹脂、胺基甲酸酯樹脂、氟樹脂、矽樹脂、三聚氰胺系樹脂、纖維素樹脂、及聚醯胺樹脂。此等黏合劑樹脂當中,丙烯酸樹脂、丙烯酸矽樹脂、胺基甲酸酯樹脂、矽樹脂、氟樹脂因光穩定性優良而較佳。 In addition, as the binder resin of the ultraviolet absorbing layer, for example, polyester resin, acrylic resin, acrylic silicone resin, urethane resin, fluororesin, silicone resin, melamine resin, cellulose resin, and polyamide can be illustrated. Resin. Among these binder resins, acrylic resins, acrylic silicone resins, urethane resins, silicone resins, and fluororesins are preferred because of their excellent light stability.
作為設置紫外線吸收層的手法,可舉出例如在多層層合薄膜的表面藉由共擠出法設置紫外線吸收劑層之手法、以塗敷等方法設置紫外線吸收劑層之手法。 As a method of providing the ultraviolet absorbing layer, for example, a method of providing an ultraviolet absorber layer on the surface of a multilayer laminate film by a coextrusion method, or a method of providing an ultraviolet absorber layer by a method such as coating.
如上述,基於防止熱線遮蔽手段的紫外線劣 化之觀點,較佳使紫外線穿透率低至10%以下;然而,過度遮蔽紫外線的話,則會發生茄子等的果實生長時呈現成熟顏色的情況較差、在農業溫室內蜜蜂無法充分接近花而無法正常進行授粉活動等問題。 As mentioned above, based on the prevention of the UV From the viewpoint of chemical conversion, it is better to make the UV transmittance as low as 10% or less; however, if the UV rays are shielded too much, the fruits such as eggplants will appear to be less mature when they grow, and the bees cannot fully approach the flowers in agricultural greenhouses. Problems such as inability to conduct pollination activities normally.
熱線遮蔽手段的紫外線穿透率過低時,可如下將紫外線穿透率調整得更高。 When the ultraviolet light transmittance of the hot ray shielding means is too low, the ultraviolet light transmittance can be adjusted higher as follows.
當熱線遮蔽手段為對熱線反射薄膜穿設貫通孔者時,藉由調整穿設之貫通孔的大小、密度來調整開孔率,可將熱線遮蔽手段調整為不會過度地遮蔽紫外線。 When the heat-ray shielding means is the one that penetrates the heat-ray reflective film with through holes, by adjusting the size and density of the through-holes to be penetrated to adjust the aperture ratio, the heat-ray shielding means can be adjusted to not excessively shield ultraviolet rays.
又,當熱線遮蔽手段為熱線反射薄膜之細帶狀條帶與透明絲線的編織物時,藉由調整構成編織物之細帶狀條帶及/或透明絲線的密度,來調整形成於細帶狀條帶間及/或透明絲線間之貫通孔的開孔率;作為細帶狀條帶,透過與熱線反射薄膜共同使用如聚乙烯薄膜之紫外線穿透率較高的透明薄膜等,可將熱線遮蔽手段調整為不會過度地遮蔽紫外線。 In addition, when the heat shielding means is a thin ribbon-like strip of the heat-reflective film and a braid of transparent threads, the density of the thin strip and/or transparent threads forming the braid can be adjusted to adjust the thin strip The opening rate of the through holes between the strips and/or between the transparent threads; as a thin strip, it can be used together with the heat-reflective film, such as polyethylene film, a transparent film with high ultraviolet transmittance, etc. The hot-ray shielding means is adjusted to not excessively shield ultraviolet rays.
一般而言,當熱線反射薄膜含有具有萘環等縮合型芳香環的樹脂時,由於會有熱線反射薄膜的紫外線穿透率過度降低的傾向,此時,對熱線遮蔽手段自表面垂直方向進行表面觀察時,較佳使熱線反射薄膜在熱線遮蔽手段中所占的面積比率(下稱「被覆率」)成為95%以下。 Generally speaking, when the heat ray reflection film contains a resin with a condensed aromatic ring such as a naphthalene ring, the ultraviolet light transmittance of the heat ray reflection film tends to be excessively reduced. In this case, the heat ray shielding means is surfaced from the surface perpendicular to the surface. During the observation, it is preferable that the area ratio of the heat-ray reflecting film in the heat-ray shielding means (hereinafter referred to as "coverage rate") is 95% or less.
本發明之農業溫室可適用於藉由太陽光進行光合作用之果菜類,例如番茄、茄子、青椒、紅椒、小黃瓜、西瓜、南瓜、辣椒、豌豆、蠶豆、草莓、綠花菜、花椰菜等的栽培。 The agricultural greenhouse of the present invention can be applied to fruits and vegetables that undergo photosynthesis by sunlight, such as tomatoes, eggplants, green peppers, red peppers, cucumbers, watermelons, pumpkins, peppers, peas, broad beans, strawberries, broccoli, broccoli, etc. Cultivated.
在使用本發明之農業溫室的植物栽培方法中,會活潑地進行光合作用的日間係關閉設於屋頂部之天窗使農業溫室成為密閉狀態,而將農業溫室內的溫度、二氧化碳濃度及濕度維持、控制於活潑地進行光合作用的範圍,但日間暫時敞開天窗亦無妨。具體而言,較佳將農業溫室內部的溫度維持、控制35℃以下,將二氧化碳濃度維持、控制於500~1500ppm及將濕度飽和差維持、控制於4g/m3以下來進行植物的栽培。 In the plant cultivation method using the agricultural greenhouse of the present invention, the daytime system that actively performs photosynthesis closes the skylights provided on the roof to make the agricultural greenhouses airtight, and maintains the temperature, carbon dioxide concentration and humidity in the agricultural greenhouses. It is controlled within the scope of active photosynthesis, but it is okay to temporarily open the skylight during the day. Specifically, it is preferable to maintain and control the temperature inside the agricultural greenhouse at 35° C. or less, maintain and control the carbon dioxide concentration at 500 to 1500 ppm, and maintain and control the humidity saturation difference at 4 g/m 3 or less to cultivate plants.
農業溫室內部的溫度可依據擬栽培之植物的適溫、最高極限溫度來設定。例如,日間之果菜類的適溫及最高極限溫度(以〔適溫、最高極限溫度〕表示)係番茄〔20~25℃,35℃〕、茄子〔23~28℃,35℃〕、青椒〔25~30℃,35℃〕、小黃瓜〔23~28℃,35℃〕、西瓜〔23~28℃,35℃〕、南瓜〔20~25℃,35℃〕。由此,農業溫室內部的溫度係以35℃以下,較佳為30℃以下,更佳為20~30℃為宜。 The temperature inside the agricultural greenhouse can be set according to the optimum temperature and the highest limit temperature of the plant to be cultivated. For example, the suitable temperature and maximum limit temperature of fruits and vegetables in the daytime (expressed as [suitable temperature, maximum limit temperature]) are tomatoes (20~25℃, 35℃], eggplant [23~28℃, 35℃], green peppers [ 25~30℃, 35℃], cucumber [23~28℃, 35℃], watermelon [23~28℃, 35℃], pumpkin [20~25℃, 35℃]. Therefore, the temperature inside the agricultural greenhouse is preferably 35°C or less, preferably 30°C or less, and more preferably 20-30°C.
一般空氣的二氧化碳濃度為300ppm左右,而藉由將農業溫室內部的二氧化碳濃度設定為500~1500ppm,可大幅促進植物的光合作用。二氧化碳濃度未達500ppm時,光合作用的促進效果不夠充分;而超過 1500ppm也幾乎無法促進光合作用,因此經濟上的優點較小。 Generally, the concentration of carbon dioxide in the air is about 300ppm, and by setting the concentration of carbon dioxide inside the agricultural greenhouse to 500~1500ppm, the photosynthesis of plants can be greatly promoted. When the carbon dioxide concentration is less than 500ppm, the photosynthesis promotion effect is not sufficient; 1500ppm can hardly promote photosynthesis, so the economic advantage is small.
植物的水分狀態,比起相對濕度更會強烈受到濕度飽和差(係表示水蒸氣還有多少空間進入某溫度與濕度的空氣之指標,以g數表示空氣每1m3的水蒸氣之容隙)的影響,而在本發明之栽培方法中,係藉由除濕冷卻手段,將農業溫室內部的濕度飽和差維持、控制於4g/m3以下來進行植物的栽培。 The moisture state of plants is more strongly affected by the humidity saturation difference than the relative humidity (it is an index that indicates how much space the water vapor has to enter the air of a certain temperature and humidity, and the number of g indicates the volume of water vapor per 1m 3 of the air) In the cultivation method of the present invention, the humidity saturation difference in the agricultural greenhouse is maintained and controlled below 4g/m 3 by means of dehumidification and cooling to cultivate plants.
農業溫室內部的濕度飽和差可設定於適於擬栽培之植物的範圍,一般而言,濕度飽和差過大的話,植物便無法關閉氣孔而進行蒸散,而無法活潑地進行光合作用,因此,宜使農業溫室內部的濕度飽和差較佳為4g/m3以下,更佳為3.5g/m3以下。 The humidity saturation difference inside the agricultural greenhouse can be set within the range suitable for the plants to be cultivated. Generally speaking, if the humidity saturation difference is too large, the plants cannot close the stomata and carry out evapotranspiration, and cannot actively carry out photosynthesis. Therefore, it is better to use The humidity saturation difference inside the agricultural greenhouse is preferably 4 g/m 3 or less, more preferably 3.5 g/m 3 or less.
又,濕度飽和差過小的話,植物與空氣無水蒸氣壓差,即使打開氣孔也無法發生蒸散,亦無法吸收二氧化碳,而無法活潑地進行光合作用,因此,宜使農業溫室內部的濕度飽和差較佳為2g/m3以上,更佳為2.5g/m3以上。 In addition, if the humidity saturation difference is too small, there will be no water vapor pressure difference between plants and the air. Even if the stomata are opened, evapotranspiration cannot occur, carbon dioxide cannot be absorbed, and photosynthesis cannot be actively performed. Therefore, the humidity saturation difference inside the agricultural greenhouse should be better. It is 2 g/m 3 or more, more preferably 2.5 g/m 3 or more.
為了將農業溫室內的溫度、二氧化碳濃度及濕度維持、控制於上述範圍,例如,只要在農業溫室內設置氣溫感測器、CO2感測器及濕度感測器,並依據此等的測定值調整CO2供給手段及除濕冷卻手段的運轉狀態即可。 In order to maintain and control the temperature, carbon dioxide concentration, and humidity in the agricultural greenhouse within the above range, for example, it is only necessary to install a temperature sensor, a CO 2 sensor, and a humidity sensor in the agricultural greenhouse, and based on these measured values It is sufficient to adjust the operating conditions of the CO 2 supply means and the dehumidification cooling means.
再者,由於會活潑地進行光合作用的溫度、 二氧化碳濃度及濕度係隨植物的種類、生長階段等而異,因此,農業溫室內的溫度、二氧化碳濃度及濕度的目標值較佳細微地設定、調整。 Furthermore, due to the temperature at which photosynthesis is active, The carbon dioxide concentration and humidity vary with plant types, growth stages, etc. Therefore, the target values of temperature, carbon dioxide concentration, and humidity in agricultural greenhouses are better set and adjusted finely.
如此,在本發明之農業溫室及使用此農業溫室之植物栽培方法中,會活潑地進行光合作用的日間係關閉設於屋頂部之天窗使農業溫室成為密閉狀態,可將農業溫室內的溫度、二氧化碳濃度及濕度維持、控制於活潑地進行光合作用的範圍。而且,透過使用可見光的穿透率高、熱線的反射率高的熱線反射薄膜所形成的熱線遮蔽手段,可在不妨礙植物的生長下降低能量成本而為優良者。 In this way, in the agricultural greenhouse of the present invention and the plant cultivation method using the agricultural greenhouse, the daytime system that actively performs photosynthesis closes the skylights provided on the roof to make the agricultural greenhouse in a sealed state, which can reduce the temperature in the agricultural greenhouse The carbon dioxide concentration and humidity are maintained and controlled within the range where photosynthesis is actively carried out. Moreover, the heat-ray shielding means formed by using the heat-ray reflecting film with high transmittance of visible light and high heat-ray reflectivity can reduce energy cost without hindering the growth of plants and is an excellent one.
又,本發明中,不會活潑地進行光合作用的夜間係敞開設於屋頂部之天窗,可使農業溫室內的溫度下降以防備翌日的日間溫度上昇。而且,透過使用以既定間隔形成有複數個貫通孔的熱線遮蔽手段,可使農業溫室下部之於日間經加熱的空氣通過熱線遮蔽手段向外部逸散。再者,於夜間,尤為清晨,即使靠近屋頂之上部的空氣遇冷時,仍可防止在熱線遮蔽手段底面發生的結露形成水滴滴到植物,使植物的果實、葉、花等變色、劣化等發生品質下降或薄膜本身發生劣化的情形而為優良者。 In addition, in the present invention, the skylight opened in the roof at night, which does not actively perform photosynthesis, can lower the temperature in the agricultural greenhouse to prevent the daytime temperature rise the next day. Furthermore, by using a heat shielding means in which a plurality of through holes are formed at predetermined intervals, the air heated during the day in the lower part of the agricultural greenhouse can escape to the outside through the heat shielding means. Furthermore, at night, especially early in the morning, even when the air close to the upper part of the roof is cold, it can still prevent condensation on the bottom surface of the heating wire shielding means from forming water droplets on the plants, discoloring and deteriorating the fruits, leaves, flowers, etc. It is an excellent one with deterioration in quality or deterioration of the film itself.
又,於本發明中,日間係關閉設於屋頂部之天窗,由於農業溫室內的水分不易向外部逸散,可減少對植物的供給水量,在乾燥地區等也能栽培植物而為優良者。 Furthermore, in the present invention, the skylight provided on the roof is closed during the daytime, and since the water in the agricultural greenhouse is not easy to escape to the outside, the amount of water supplied to the plants can be reduced, and it is an excellent one that can grow plants in dry areas.
又,於本發明中,透過使用以既定間隔形成 有複數個貫通孔的熱線遮蔽手段,可將紫外線穿透率調整於不會妨礙果實的顏色形成、由蜜蜂所進行之授粉活動的範圍而為優良者。 Also, in the present invention, it is formed at predetermined intervals by using The heat-ray shielding means with multiple through holes can adjust the ultraviolet light transmittance to the range that does not hinder the color formation of the fruit and the pollination activity performed by the bees is excellent.
接著,就本發明之熱線反射薄膜構造體加以說明。 Next, the heat-ray reflective film structure of the present invention will be described.
本發明之熱線反射薄膜構造體由於具備可見光的穿透率高、熱線的反射率高、通氣良好等物性、特性,可適用於利用太陽光之農業溫室,尤為如第1圖所示之藉由將農業溫室內的二氧化碳濃度維持於高程度來促進植物的生長的農業溫室。尤其是可作為農業溫室中的熱線遮蔽手段使用。此外,於此,可見光係指波長400~750nm的光;熱線則指波長800~1100nm的光。 Since the heat-ray reflective film structure of the present invention has high visible light transmittance, high heat-ray reflectivity, and good ventilation, it can be applied to agricultural greenhouses that use sunlight, especially as shown in Figure 1. An agricultural greenhouse that maintains the carbon dioxide concentration in an agricultural greenhouse at a high level to promote the growth of plants. In particular, it can be used as a means of shielding hot wires in agricultural greenhouses. In addition, here, visible light refers to light with a wavelength of 400 to 750 nm; hot wire refers to light with a wavelength of 800 to 1100 nm.
第1圖為用以說明本發明之農業溫室或熱線反射薄膜構造體之表示農業溫室的一例的示意圖;就符號3,在本發明之農業溫室的說明中係表示熱線阻隔手段,在本發明之熱線反射薄膜構造體的說明中則表示熱線反射薄膜構造體。
Figure 1 is a schematic diagram for explaining an example of an agricultural greenhouse or a heat-ray reflective film structure of the present invention; as for
此利用太陽光之農業溫室1,於上部被覆有熱線反射薄膜構造體3,於下部具備對農業溫室1的內部供給二氧化碳的CO2供給手段2、與冷卻農業溫室1的內部的除濕冷卻手段4。此農業溫室1中,日間可關閉天窗5而將農業溫室1內的二氧化碳濃度經濟地維持於高濃度,夜間則敞開天窗5而使農業溫室1內的溫度下降。
This agricultural greenhouse 1 that uses sunlight is covered with a heat-reflecting
本發明之熱線反射薄膜構造體係具備以下物性、構造: The heat-ray reflective film structure system of the present invention has the following physical properties and structures:
1)使用在將折射率不同的至少2種樹脂層交互層合而得,且可見光之平均穿透率為80%以上、熱線之平均反射率為70%以上之多層層合薄膜的至少單側表面設有滑性賦予層之原薄膜所形成者。 1) It is used on at least one side of a multilayer laminate film that is obtained by alternately laminating at least two resin layers with different refractive indexes, and has an average transmittance of visible light of 80% or more and an average reflectivity of heat rays of 70% or more The surface is formed by the original film with a slippery imparting layer.
2)以此原薄膜經裁切的細帶狀條帶為經紗或緯紗、以絲紗等為緯紗或經紗經編織而成的編織物。 2) The thin ribbon-shaped strip cut from the original film is a warp yarn or a weft yarn, and a silk yarn or the like is a weft yarn or a warp yarn knitted fabric.
3)於此編織物中,將該絲紗等的粗細度取該細帶狀條帶之寬度的0.01~0.30倍,將相鄰之該細帶狀條帶的間隔取該細帶狀條帶之寬度的0.1~0.5倍者。 3) In this knitted fabric, the thickness of the silk yarn etc. is taken to be 0.01~0.30 times the width of the thin strip, and the interval between the adjacent thin strips is taken as the thin strip 0.1~0.5 times the width.
設有本發明之熱線反射薄膜構造體之例如日間關閉天窗而夜間敞開天窗的利用太陽光之農業溫室,由於未設有如「SUNNYCOAT」之樹脂板,與先前之農業溫室相比,具有以下優點: The heat-ray reflective film structure of the present invention, such as an agricultural greenhouse with sunroof closed during the day and open at night, is not equipped with a resin board such as "SUNNYCOAT". Compared with the previous agricultural greenhouse, it has the following advantages:
1)可提高植物的生長所需之可見光的穿透率。(在設有「SUNNYCOAT」的先前之農業溫室中,係如前述,植物的生長所需之400~700nm的光的穿透率係頂多為70%左右而甚低) 1) It can improve the transmittance of visible light required for plant growth. (In the previous agricultural greenhouse with "SUNNYCOAT", as mentioned above, the transmittance of 400~700nm light required for the growth of plants is at most about 70%, which is very low)
2)可減輕農業溫室的設備費用。 2) It can reduce the equipment cost of agricultural greenhouses.
3)不會發生:於夜間,尤為清晨,栽培部與屋頂部之間的溫差變大,在「SUNNYCOAT」的底面發生結露而形成水滴滴到植物,使植物的果實、葉、花等變色、劣化的問題。 3) It will not happen: At night, especially early in the morning, the temperature difference between the cultivation part and the roof becomes larger, and condensation occurs on the bottom surface of "SUNNYCOAT" to form water droplets on the plant, discoloring the fruits, leaves, flowers, etc., The problem of deterioration.
又,在先前之農業溫室中,為了阻隔熱線而使用「近紅外線吸收薄膜」,但此種熱線吸收型薄膜會吸收熱線而使薄膜本身發熱,而使農業溫室內的溫度上昇。另一方面,本發明之熱線反射薄膜構造體由於係使用「熱線(波長800~1100nm的光)之平均反射率為70%以上的多層層合薄膜」之熱線反射型薄膜,而不易使農業溫室內的溫度上昇。 In addition, in previous agricultural greenhouses, "near-infrared absorbing films" were used to block heat insulation, but such heat-absorbing films absorb the heat and cause the film itself to generate heat, thereby increasing the temperature in the agricultural greenhouse. On the other hand, the heat-ray reflective film structure of the present invention is a heat-ray reflective film that uses a "multilayer laminate film with an average reflectivity of the heat ray (light with a wavelength of 800 to 1100 nm) of 70% or more." The indoor temperature rises.
以下,就本發明之熱線反射薄膜構造體的物性、構造等依序加以說明。 Hereinafter, the physical properties and structure of the heat-ray reflective film structure of the present invention will be described in order.
適用本發明之熱線反射薄膜構造體的農業溫室係利用太陽光者。若使用LED等的人工光,雖可調整、控制作為光合作用之驅動源的光能量的量,但須耗費照射能量,而非適於植物的大量生長。 The agricultural greenhouse to which the heat-ray reflective film structure of the present invention is applied uses sunlight. If artificial light such as LEDs is used, although the amount of light energy used as the driving source of photosynthesis can be adjusted and controlled, it is necessary to consume irradiation energy and is not suitable for the mass growth of plants.
而且,在利用太陽光之一般的農業溫室中,由於常因太陽光所含的熱線使農業溫室內的溫度上昇,因此需藉由自然換氣、強制通氣等將農業溫室內保持於適溫,而換氣需耗時費力且耗費成本,而且會因換氣使害蟲更容易侵入農業溫室內。 Moreover, in general agricultural greenhouses that use sunlight, the temperature in the agricultural greenhouse is often raised due to the heat contained in the sunlight. Therefore, it is necessary to keep the agricultural greenhouse at an appropriate temperature through natural ventilation and forced ventilation. The air exchange requires time, labor, and cost, and the air exchange makes it easier for pests to invade the agricultural greenhouse.
再者,在將二氧化碳濃度維持於高程度的農業溫室中,為了盡可能不使二氧化碳逸散至外部,則需保持較低的換氣率;為此,於日間必須使冷氣機設備作動而將廣大農業溫室內的溫度維持於適溫,冷氣機需耗費大量 的能量。 Furthermore, in an agricultural greenhouse that maintains a high level of carbon dioxide concentration, in order to prevent the carbon dioxide from escaping to the outside as much as possible, it is necessary to maintain a low air exchange rate; for this reason, the air conditioner must be activated during the day. The temperature in the vast agricultural greenhouses is maintained at an appropriate temperature, and the air conditioner needs a lot of energy of.
適用本發明之熱線反射薄膜構造體的利用太陽光之農業溫室,較佳的是,會活潑地進行光合作用的日間係關閉設於屋頂部之天窗而使農業溫室成為密閉狀態,將農業溫室內的溫度、二氧化碳濃度及濕度維持、控制於活潑地進行光合作用的範圍;而且,不會活潑地進行光合作用的夜間則敞開設於屋頂部之天窗,使農業溫室內的溫度下降以防備翌日的日間溫度上昇,透過使用具備特定構造、物性的熱線反射薄膜構造體,可經濟且有效率地進行植物的栽培。 For agricultural greenhouses using sunlight to which the heat-ray reflective film structure of the present invention is applied, it is preferable that the daytime system that actively performs photosynthesis closes the skylights provided on the roof to make the agricultural greenhouses airtight. The temperature, carbon dioxide concentration and humidity are maintained and controlled within the range of active photosynthesis; moreover, the skylights in the roof are opened at night when photosynthesis is not active, so that the temperature in the agricultural greenhouse will drop to prevent the next day. The temperature rises during the day, and by using a heat-ray reflective film structure with a specific structure and physical properties, plants can be cultivated economically and efficiently.
本發明之熱線反射薄膜構造體的第1特徵在於,作為熱線反射薄膜構造體的素材薄膜,非為如農業溫室中一般所使用之藉由金屬蒸鍍層、金屬箔、含金屬層之金屬來反射熱線以及可見光之類型的薄膜,而是使用光學干涉濾光器、層合玻璃領域中所使用的熱線反射型多層層合薄膜,並於此多層層合薄膜的至少單側表面設置滑性賦予層。 The first feature of the heat-ray reflective film structure of the present invention is that the material film of the heat-ray reflective film structure is not a metal that is generally used in agricultural greenhouses for reflection by a metal vapor deposition layer, a metal foil, or a metal-containing layer. Heat ray and visible light type films, but use optical interference filters, heat ray reflection type multilayer laminate films used in the field of laminated glass, and provide a slippery imparting layer on at least one side of the multilayer laminate film .
具體而言,此多層層合薄膜,其中太陽光所含之可見光之平均穿透率高達80%以上,且太陽光所含之熱線之平均反射率高達70%以上。 Specifically, in this multilayer laminated film, the average transmittance of visible light contained in sunlight is as high as 80% or more, and the average reflectivity of heat rays contained in sunlight is as high as 70% or more.
透過使用可見光之平均穿透率高達80%以上的多層層合薄膜,可將作為光合作用之驅動源的可見光充分地供給至植物,故可充分促進植物的生長。 By using a multi-layer laminated film with an average transmittance of visible light as high as 80% or more, the visible light as the driving source of photosynthesis can be fully supplied to the plant, so the growth of the plant can be fully promoted.
又,透過使用熱線之平均反射率高達70%以上的多層層合薄膜,可充分遮蔽使農業溫室內的溫度上昇的熱線。再者,由於如熱線吸收薄膜之薄膜本身的發熱亦較少,可抑制農業溫室內的溫度的上昇,而能夠降低除濕冷氣機所需之成本。 In addition, by using a multi-layer laminate film with an average reflectivity of the heating wire as high as 70% or more, the heating wire that raises the temperature in the agricultural greenhouse can be sufficiently shielded. Furthermore, since the film itself, such as the heat-absorbing film, generates less heat, the temperature rise in the agricultural greenhouse can be suppressed, and the cost of the dehumidifying air conditioner can be reduced.
作為此種具有可見光較高之平均穿透率及熱線較高之平均反射率的素材薄膜,可較佳使用上述<熱線遮蔽手段>之〔熱線反射薄膜〕一項所列舉之專利文獻所記載的多層層合薄膜。 As such a material film having a high average transmittance of visible light and a high average reflectivity of the heat rays, it is preferable to use the patent documents listed in the above-mentioned "Heat ray shielding means" [Heat ray reflection film] Multilayer laminated film.
此等多層層合薄膜為折射率不同的至少2種樹脂層交互層合而成的多層層合薄膜,可使太陽光中的可見光穿透,並選擇性地反射熱線。為了藉由多層層合薄膜適確地進行可見光的穿透及熱線的選擇性反射,2種樹脂層於面內方向上的平均折射率差較佳至少為0.03。又,多層層合薄膜係以具有至少101層之光學厚度為150~400nm,較佳為200~300nm的樹脂層為佳。 These multilayer laminate films are multilayer laminate films formed by alternately laminating at least two resin layers with different refractive indices, which can penetrate visible light in sunlight and selectively reflect heat rays. In order to properly perform visible light penetration and selective reflection of heat rays through the multilayer laminate film, the average refractive index difference between the two resin layers in the in-plane direction is preferably at least 0.03. In addition, the multilayer laminate film preferably has at least 101 resin layers with an optical thickness of 150 to 400 nm, preferably 200 to 300 nm.
本發明之熱線反射薄膜構造體所使用的多層層合薄膜,只要是具有上述特性者則不特別限制,較佳為折射率不同的至少2種樹脂層交互層合而成。折射率不同的樹脂層之交互層合所產生的反射,反射波長可依樹脂層的光學厚度(折射率×厚度)來設計,反射率則可依樹脂層的總數與樹脂層間的折射率差來設計;可選擇樹脂及調整樹脂層的厚度或層合數,以使其成為所要的反射特性。 The multilayer laminate film used in the heat ray reflective film structure of the present invention is not particularly limited as long as it has the above-mentioned characteristics, and it is preferably formed by alternately laminating at least two types of resin layers with different refractive indexes. The reflection caused by the alternate lamination of resin layers with different refractive indexes, the reflection wavelength can be designed according to the optical thickness of the resin layer (refractive index × thickness), and the reflectivity can be determined by the total number of resin layers and the refractive index difference between the resin layers Design; select the resin and adjust the thickness or the number of layers of the resin layer to make it the desired reflection characteristics.
作為形成多層層合薄膜之樹脂層的樹脂,係 與上述<熱線遮蔽手段>之〔熱線反射薄膜〕一項所記載之形成多層層合薄膜之樹脂層的樹脂相同。又,就折射率較高之樹脂層所使用的樹脂及折射率較低之樹脂層所使用的樹脂,亦與上述<熱線遮蔽手段>之〔熱線反射薄膜〕一項所記載之折射率較高之樹脂層所使用的樹脂及折射率較低之樹脂層所使用的樹脂分別相同。 As the resin forming the resin layer of the multilayer laminate film, It is the same as the resin used to form the resin layer of the multilayer laminate film described in the item [Heat Ray Reflective Film] of the above-mentioned <Heat Ray Shielding Means>. In addition, the resin used in the resin layer with a higher refractive index and the resin used in the resin layer with a lower refractive index are also higher than the refractive index described in the [Heat Ray Reflective Film] item of the above-mentioned <Heat Ray Shielding Means> The resin used in the resin layer and the resin used in the resin layer with a lower refractive index are respectively the same.
本發明中,藉由進一步在此多層層合薄膜的至少單側表面,較佳為兩表面設置滑性賦予層,便能以多層層合薄膜經裁切之細帶狀條帶為經紗或緯紗、以絲紗等為緯紗或經紗順利且均質地進行編織。未設置此滑性賦予層時,在進行編織之際,則會發生:細帶狀條帶在儲存中發生黏連、或無法在織編機內順暢地移送,而無法順利地進行編織,或無法均質地進行編織等不良情形。 In the present invention, by further providing slippage imparting layers on at least one side surface of the multilayer laminate film, preferably on both surfaces, the thin ribbon-shaped strips cut by the multilayer laminate film can be warp yarns or weft yarns. , Weaving smoothly and uniformly with silk yarns as wefts or warps. If this slipperiness imparting layer is not provided, during weaving, it will happen that the thin ribbon-like strips are stuck during storage, or cannot be smoothly transferred in the weaving machine, and the weaving cannot be performed smoothly, or Unfavorable situations such as inability to knit uniformly
滑性賦予層可透過對多層層合薄膜塗設含有平均粒徑為0.05~0.5μm之微細粒子或蠟等潤滑劑的樹脂層、或藉由共擠出進行層合而形成。 The slippage imparting layer can be formed by coating the multilayer laminate film with a resin layer containing fine particles with an average particle diameter of 0.05 to 0.5 μm or a lubricant such as wax, or by laminating by coextrusion.
作為前述微細粒子,可舉出例如聚苯乙烯、聚甲基丙烯酸甲酯、甲基丙烯酸甲酯共聚物、甲基丙烯酸甲酯共聚交聯體、聚四氟乙烯、聚偏二氟乙烯、聚丙烯腈、苯并胍胺樹脂、以丙烯酸系樹脂被覆聚苯乙烯粒子之外殼而成的芯殼型粒子等的有機微粒子、及二氧化矽、氧化鋁、二氧化鈦、高嶺土、滑石、石墨、碳酸鈣、長石、 二硫化鉬、碳黑、硫酸鋇等的無機微粒子等。此等之中,較佳為有機微粒子。 As the aforementioned fine particles, for example, polystyrene, polymethyl methacrylate, methyl methacrylate copolymer, methyl methacrylate copolymer crosslinked body, polytetrafluoroethylene, polyvinylidene fluoride, poly Organic particles such as acrylonitrile, benzoguanamine resin, core-shell particles formed by coating polystyrene particles with acrylic resin, and silica, alumina, titania, kaolin, talc, graphite, calcium carbonate , Feldspar, Inorganic particles such as molybdenum disulfide, carbon black, and barium sulfate. Among these, organic fine particles are preferred.
此微細粒子的平均粒徑未達0.05μm的話,因粒子量而有薄膜的滑性不足之傾向;另一方面,大於0.5μm的話,則因粒子從塗膜發生脫落而不佳。 If the average particle size of the fine particles is less than 0.05 μm, the slipperiness of the film tends to be insufficient due to the amount of particles; on the other hand, if it is larger than 0.5 μm, the particles may fall off the coating film.
以下,以進行塗設之情況為例加以說明。 The following describes the case of coating as an example.
作為供固著微細粒子的黏合劑,可例示醇酸樹脂、不飽和聚酯樹脂、飽和聚酯樹脂、酚樹脂、胺基樹脂、乙酸乙烯酯樹脂、氯乙烯-乙酸乙烯酯樹脂、丙烯酸樹脂、丙烯酸-聚酯樹脂等。此等樹脂可為均聚物或共聚物,又可為混合體。 As the binder for fixing fine particles, alkyd resins, unsaturated polyester resins, saturated polyester resins, phenol resins, amino resins, vinyl acetate resins, vinyl chloride-vinyl acetate resins, acrylic resins, Acrylic-polyester resin, etc. These resins can be homopolymers or copolymers, or mixtures.
前述微細粒子與被膜形成樹脂(黏合劑)的比例較佳依被膜表面特性的設計來決定,按每單位全部被膜形成成分,較佳的是微細粒子為0.1~40重量%,作為結合劑的被膜形成樹脂(黏合劑)為60~99.9重量%。微細粒子過少的話,無法對被膜提供均勻且既定量的突起;另一方面過多的話,則分散性會惡化,而不易提供均勻且既定量的突起。黏合劑的被膜形成樹脂過少的話,被膜對聚酯薄膜的密接性會變差;另一方面過多的話,則抗黏連性會變差。 The ratio of the aforementioned fine particles to the film forming resin (binder) is preferably determined according to the design of the surface characteristics of the film, and is based on the total film forming components per unit, preferably 0.1-40% by weight of the fine particles, as the film of the binder The formation resin (adhesive) is 60 to 99.9% by weight. If the number of fine particles is too small, a uniform and predetermined amount of protrusions cannot be provided to the film; on the other hand, if there are too many, the dispersibility will deteriorate and it is difficult to provide a uniform and predetermined amount of protrusions. If there is too little coating-forming resin of the adhesive, the adhesion of the coating to the polyester film will deteriorate; on the other hand, if it is too much, the blocking resistance will deteriorate.
作為對多層層合薄膜設置滑性賦予層之方法,可採用將含有微細粒子及被膜形成樹脂的塗液,較佳為水性塗液在多層層合薄膜的製造步驟中塗佈於結晶配向完成前的薄膜表面並進行乾燥固化的方法(線內塗佈 法)、或對經雙軸配向之多層層合薄膜塗佈含有微細粒子的樹脂塗液並進行乾燥固化的方法等,較佳為前者。尤以對縱延伸多層層合薄膜的表面塗佈水性塗液,接著進行乾燥、橫向延伸處理為佳。 As a method of providing a slippery imparting layer to a multilayer laminate film, a coating solution containing fine particles and a film-forming resin can be used, preferably an aqueous coating solution, which is applied before the crystal alignment is completed in the manufacturing step of the multilayer laminate film The method of drying and curing the film surface (in-line coating Method), or a method of applying a resin coating liquid containing fine particles to a biaxially oriented multilayer laminate film and drying and curing it, etc. The former is preferred. In particular, it is preferable to apply an aqueous coating liquid to the surface of the longitudinally stretched multilayer laminate film, followed by drying and lateral stretch processing.
於此,所稱結晶配向完成前的多層層合薄膜,係包含熔融擠出薄膜,經驟冷固化之未延伸薄膜、使該未延伸薄膜朝縱向或橫向之任一者配向的單軸延伸薄膜、或者朝雙軸方向延伸,但至少一方向為低倍率延伸且進一步需要該方向之延伸配向的雙軸延伸薄膜(最終使其朝縱向及/或橫向再延伸而使配向結晶化完成前的雙軸延伸薄膜)等。 Here, the multi-layer laminated film before the completion of the crystal alignment includes a melt-extruded film, an unstretched film that is quenched and solidified, and a uniaxially stretched film in which the unstretched film is oriented in either the longitudinal direction or the transverse direction. , Or biaxially stretched film extending in the biaxial direction, but at least one direction is low-magnification stretching and further needs the biaxially stretched film in this direction (finally it is re-extended in the longitudinal and/or transverse directions to make the biaxially stretched film before the alignment is crystallized. Axis stretch film) etc.
作為塗佈方法,可應用周知之任意塗敷法。宜單獨或組合應用例如輥塗法、凹版塗佈法、輥刷法、噴塗法、氣刀塗佈法、含浸法、淋幕塗佈法等。又,就共擠出而言可採用其本身周知之方法。 As the coating method, any well-known coating method can be applied. It is suitable to apply alone or in combination such as roll coating method, gravure coating method, roll brush method, spraying method, air knife coating method, impregnation method, curtain coating method, etc. In addition, a method known per se can be used for coextrusion.
本發明之熱線反射薄膜構造體的第2特徵在於,係採用:使用在上述多層層合薄膜的至少單側,較佳為兩表面設有滑性賦予層之原薄膜經裁切的細帶狀條帶作為經紗或緯紗、以絲紗等為緯紗或經紗經編織而成的編織物。 The second feature of the heat ray reflective film structure of the present invention is that it is used in at least one side of the above-mentioned multilayer laminate film, preferably in the shape of a cut thin strip of the original film provided with slippage imparting layers on both surfaces Strips are knitted fabrics made of warp yarns or weft yarns, silk yarns and the like as weft yarns or warp yarns.
如此,並非以薄膜單質使用多層層合薄膜,而是作成以在多層層合薄膜的表面設有滑性賦予層之原薄膜經裁切的細帶狀條帶為經紗或緯紗經編織而成的編織物 來使用,由此,可使熱線反射薄膜構造體的捲繞性、抗黏連性、耐撕裂性、耐久性等的機械強度更良好。 In this way, instead of using a multi-layer laminate film as a single film, it is made by knitting a thin ribbon-like strip of the original film with a slippage imparting layer on the surface of the multi-layer laminate film as warp yarns or weft yarns. Braid By using it, the mechanical strength of the heat-ray reflective film structure, such as winding properties, blocking resistance, tear resistance, and durability, can be improved.
再者,本發明之熱線反射薄膜構造體由於為編織物,藉由形成於細帶狀條帶、絲紗等之間的開口,可確保通氣性。如此,本發明之熱線反射薄膜構造體,與使用薄膜單質的情形相比,通氣性更優良,因此可防範於夜間,尤為清晨,栽培部與屋頂部之間的溫差變大,在薄膜的底面發生結露而形成水滴滴到植物,使植物的果實、葉、花等變色、劣化等問題的發生。 Furthermore, since the heat-ray reflective film structure of the present invention is a woven fabric, the air permeability can be ensured by the openings formed between the thin ribbon-shaped strips, silk yarns, and the like. In this way, the heat-ray reflective film structure of the present invention has better air permeability than when the film is used. Therefore, it can be prevented at night. Especially in the early morning, the temperature difference between the cultivation part and the roof part becomes large, and the bottom surface of the film Condensation occurs to form water droplets on plants, causing problems such as discoloration and deterioration of plant fruits, leaves, flowers, etc.
再者,以單質使用多層層合薄膜時,有時會過度遮蔽紫外線,而發生茄子等的果實生長時呈現成熟顏色的情況較差、在農業溫室內蜜蜂無法充分接近花而無法正常進行授粉活動等問題,而於本發明之熱線反射薄膜構造體中,由於形成有開口,故可避免此種過度遮蔽紫外線所伴隨的弊害。 In addition, when using a multilayer laminate film with a simple substance, ultraviolet rays may be excessively shielded, and fruit such as eggplants may appear to be ripe when they grow. In agricultural greenhouses, bees cannot get close to the flowers and cannot conduct pollination activities normally. The problem is that in the heat-ray reflective film structure of the present invention, since openings are formed, the disadvantages associated with such excessive shielding of ultraviolet rays can be avoided.
本發明之熱線反射薄膜構造體的第3特徵在於,於此編織物中,係將絲紗等的粗細度取該細帶狀條帶之寬度的0.01~0.30倍,將相鄰之該細帶狀條帶的間隔取該細帶狀條帶之寬度的0.1~0.5倍。「絲紗等」係指絲紗或紡紗。此外,就本發明中的絲紗,可使用單絲紗、複絲紗任一種,不特別限制。 The third feature of the heat-ray reflective film structure of the present invention is that in the knitted fabric, the thickness of the silk yarn or the like is taken as 0.01 to 0.30 times the width of the thin ribbon, and the adjacent thin ribbons The interval between the strips is 0.1 to 0.5 times the width of the thin strips. "Silk yarn, etc." refers to silk yarn or spun yarn. In addition, as for the silk yarn in the present invention, either monofilament yarn or multifilament yarn can be used, and it is not particularly limited.
如第3圖及第4圖所示,可舉出對多層層合 薄膜經裁切成細帶狀(經細切加工)之細帶狀條帶(經紗)11,以絲紗等(緯紗)12進行編織而成者作為其一例,若使用這些圖來說明,係使絲紗等(緯紗)12的粗細度A、細帶狀條帶(經紗)11的寬度B、相鄰之絲紗等(緯紗)12的間隔C及相鄰之細帶狀條帶(經紗)11的間隔D成特定的範圍,而使熱線反射薄膜構造體的開孔率成為適確的範圍,與使用多層層合薄膜單質的情形相比,可確保毫不遜色之較高的可見光的穿透率及熱線的反射率,同時使紫外線穿透率成為適確的範圍。 As shown in Fig. 3 and Fig. 4, the multi-layer laminate The thin ribbon (warp) 11 that the film is cut into thin ribbons (finely cut) is woven with silk yarn (weft) 12 as an example. If these figures are used to explain, Make the thickness A of the silk yarn etc. (weft yarn) 12, the width B of the thin ribbon-shaped strip (warp yarn) 11, the interval C between adjacent silk yarns and the like (weft yarn) 12, and the adjacent thin ribbon-shaped strip (warp yarn) ) The interval D of 11 is in a specific range, and the porosity of the heat ray reflective film structure is in an appropriate range. Compared with the case of using a multilayer laminate film, it can ensure a high visible light. The transmittance and reflectivity of the hot ray, while making the ultraviolet transmittance into an appropriate range.
具體而言,於編織物中,係藉由將絲紗等(緯紗)12的粗細度取細帶狀條帶(經紗)11之寬度的0.01~0.30倍,將相鄰之細帶狀條帶(經紗)11的間隔取細帶狀條帶(經紗)11之寬度的0.1~0.5倍,而使開孔率成為適確的範圍,與使用多層層合薄膜單質的情形相比,可確保毫不遜色之較高的可見光的穿透率及熱線的反射率,同時使紫外線穿透率成為適確的範圍。此外,由本發明之效果的觀點而言,相鄰之絲紗等(緯紗)12的間隔較佳為1.0~10mm的範圍。 Specifically, in the knitted fabric, the thickness of the silk yarn (weft yarn) 12 is taken to be 0.01 to 0.30 times the width of the thin ribbon (warp) 11, and the adjacent thin ribbon The interval of (warp yarn) 11 is 0.1 to 0.5 times the width of the thin ribbon (warp yarn) 11, so that the porosity becomes an appropriate range. Compared with the case of using a multilayer laminated film, it can ensure millimeters. Not inferior to high visible light transmittance and heat ray reflectivity, while making the ultraviolet transmittance into a proper range. In addition, from the viewpoint of the effect of the present invention, the interval between adjacent silk yarns and the like (weft yarns) 12 is preferably in the range of 1.0 to 10 mm.
就細帶狀條帶(經紗)11的寬度而言,較佳為1~10mm,更佳為2~6mm,再更佳為3~5mm。就細帶狀條帶(經紗)11的間隔,即相鄰之細帶狀條帶(經紗)11之端邊的距離而言,較佳為0.2~1.0mm,更佳為0.4~0.8mm,再更佳為0.5~0.7mm。就絲紗等(緯紗)12的粗細度而言,較佳為0.05~0.35mm,更佳為0.1~ 0.3mm,再更佳為0.15~0.25mm。本發明之熱線反射薄膜構造體係透過如上述設定編織物之細帶狀條帶的寬度、絲紗等的粗細度、相鄰之絲紗等的間隔及相鄰之細帶狀條帶的間隔,而使開孔率成為適確的範圍,與使用多層層合薄膜單質的情形相比,可確保毫不遜色之較高的可見光的穿透率及熱線的反射率,同時使紫外線穿透率成為適確的範圍。 As for the width of the thin ribbon-shaped strip (warp yarn) 11, it is preferably 1-10 mm, more preferably 2-6 mm, and still more preferably 3-5 mm. In terms of the interval between the thin ribbon-like strips (warp yarns) 11, that is, the distance between the ends of adjacent thin ribbon-like strips (warp yarns) 11, it is preferably 0.2 to 1.0 mm, more preferably 0.4 to 0.8 mm, More preferably, it is 0.5 to 0.7 mm. In terms of the thickness of silk yarn (weft yarn) 12, it is preferably 0.05~0.35mm, more preferably 0.1~ 0.3mm, more preferably 0.15~0.25mm. The heat-ray reflective film construction system of the present invention sets the width of the thin ribbon-like strips of the knitted fabric, the thickness of the silk yarns, etc., the interval between adjacent silk yarns, etc., and the interval between adjacent thin ribbons, as described above. By making the aperture ratio into a proper range, compared with the case of using a multilayer laminate film, it can ensure a higher visible light transmittance and heat ray reflectivity, and at the same time make the ultraviolet transmittance become Appropriate range.
熱線反射薄膜構造體的紫外線穿透率較佳取7~21%。紫外線穿透率若為7%以上,不易發生茄子等的果實生長時呈現成熟顏色的情況較差、在農業溫室內蜜蜂無法充分接近花而無法正常進行授粉活動等問題,因而較佳。又,紫外線穿透率若為21%以下,則不易發生妨礙植物的成長等問題,因而較佳。 The UV transmittance of the heat-reflective film structure is preferably 7-21%. If the UV penetration rate is 7% or more, it is less likely to cause problems such as eggplant and other fruits that show a mature color when growing, and the bees in the agricultural greenhouse cannot get close to the flowers sufficiently and cannot perform normal pollination activities, so it is better. In addition, if the ultraviolet transmittance is 21% or less, problems such as hindering the growth of plants are unlikely to occur, which is preferable.
熱線反射薄膜構造體的開孔率較佳取10~30%。此外,本發明中的「開孔率」係對熱線反射薄膜構造體之其中一表面上長寬各10cm的正方形部分(面積100cm2),對此部分由表面垂直方向進行表面觀察時,以無阻礙地可看見背面側的部分作為開孔,求出該開孔的面積(稱為開孔面積)之總和(Scm2),依式:〔S(cm2)/100(cm2)〕×100來求得。 The aperture ratio of the heat ray reflective film structure is preferably 10-30%. In addition, the "opening rate" in the present invention refers to a square part (area 100 cm 2 ) each having a length and width of 10 cm on one surface of the heat-reflecting film structure. The part where the back side is obstructively visible is used as an opening, and the total area (Scm 2 ) of the opening area (called the opening area) is calculated according to the formula: [S(cm 2 )/100(cm 2 )]× 100 to get it.
在本發明之熱線反射薄膜構造體中,開孔率若為10%以上,則可使熱線反射薄膜構造體的通氣性更良好,在不會進行光合作用的夜間敞開設於屋頂部之天窗,使農業溫室內的溫度下降以防備翌日的日間溫度上昇時, 可使農業溫室下部之於日間經加熱的空氣通過熱線反射薄膜構造體向外部逸散。而且,於夜間,尤為清晨,即使靠近屋頂之上部的空氣遇冷時,仍可防止在熱線反射薄膜構造體底面發生之結露形成水滴滴到植物,使植物的果實、葉、花等變色、劣化等發生品質下降或熱線反射薄膜構造體本身發生劣化的情形,因而較佳。又,開孔率若為30%以下,則可確保由多層層合薄膜所獲得的較高之可見光的穿透率及熱線的反射率,因而較佳。 In the heat-ray reflective film structure of the present invention, if the aperture ratio is 10% or more, the air-permeability of the heat-ray reflective film structure can be improved, and the skylight on the roof can be opened at night when photosynthesis does not occur. When the temperature in the agricultural greenhouse is lowered to prevent the daytime temperature from rising the next day, The air heated during the day in the lower part of the agricultural greenhouse can escape to the outside through the heat-ray reflective film structure. Moreover, at night, especially early in the morning, even when the air near the upper part of the roof is cold, it can still prevent condensation on the bottom surface of the heat-reflective film structure from forming water droplets on the plants, discoloring and deteriorating the fruits, leaves, flowers, etc. It is preferable if the quality is deteriorated or the heat ray reflection film structure itself is deteriorated. In addition, if the aperture ratio is 30% or less, the higher visible light transmittance and heat ray reflectance obtained by the multilayer laminate film can be ensured, which is preferable.
如本發明之熱線反射薄膜構造體的農業薄膜,由於日間係曝曬於太陽光下,為防止紫外線所引起的劣化,較佳在至少單面設置紫外線吸收層。 The agricultural film such as the heat-ray reflective film structure of the present invention is exposed to sunlight during the daytime. In order to prevent deterioration caused by ultraviolet rays, it is preferable to provide an ultraviolet absorbing layer on at least one side.
以具有萘環等縮合型芳香環的樹脂形成構成熱線反射薄膜構造體之多層層合薄膜之折射率較高的樹脂層時,由於此樹脂層易受紫外線引起的劣化,故設置紫外線吸收層係特別有效。此外,本發明之熱線反射薄膜構造體非為薄膜單質而是設有前述之開口部,因此,在設置此種紫外線吸收層時,仍可使必要的紫外線穿透,同時抑制熱線反射薄膜構造體自身的劣化。 When a resin with a condensed aromatic ring such as a naphthalene ring is used to form a resin layer with a high refractive index in the multilayer laminate film that constitutes the heat-ray reflective film structure, the resin layer is easily degraded by ultraviolet rays, so an ultraviolet absorbing layer system is provided Especially effective. In addition, the heat ray reflective film structure of the present invention is not a simple film but is provided with the aforementioned opening. Therefore, when such an ultraviolet absorbing layer is provided, necessary ultraviolet rays can still be penetrated while suppressing the heat ray reflective film structure Deterioration of itself.
紫外線吸收層的厚度較佳為1~5μm。紫外線吸收層的厚度若為1μm以上則可充分防止樹脂層的劣化;又,若為5μm以下則可經濟且有效率地充分防止樹脂層的劣化,因而較佳。 The thickness of the ultraviolet absorbing layer is preferably 1 to 5 μm. If the thickness of the ultraviolet absorbing layer is 1 μm or more, the deterioration of the resin layer can be sufficiently prevented; and if it is 5 μm or less, the deterioration of the resin layer can be sufficiently prevented economically and efficiently, which is preferable.
含於紫外線吸收層之紫外線吸收劑、黏合劑樹脂及設置紫外線吸收層之手法係與上述<熱線遮蔽手段>之〔紫外線吸收層〕一項所記載者相同。 The ultraviolet absorber, the adhesive resin contained in the ultraviolet absorbing layer, and the method of providing the ultraviolet absorbing layer are the same as those described in the item of [Ultraviolet absorbing layer] in the above-mentioned "Heat ray shielding means".
本發明之熱線反射薄膜構造體由於係使用可見的光穿透率高、熱線的反射率高的多層層合薄膜所形成,可在不妨礙植物的生長下抑制農業溫室內的溫度的上昇而為優良者。 The heat-ray reflective film structure of the present invention is formed by using a multilayer laminate film with high visible light transmittance and high heat-ray reflectivity, and can suppress the temperature rise in the agricultural greenhouse without hindering the growth of plants. Good ones.
又,本發明之熱線反射薄膜構造體由於為以在此多層層合薄膜的表面設有滑性賦予層之原薄膜經裁切的細帶狀條帶為經紗或緯紗、以絲紗等為緯紗或經紗經編織而成的編織物,故可順利且均質地進行編織,與使用多層層合薄膜單質的情形相比,可使捲繞性、抗黏連性、耐撕裂性、耐久性等的機械強度更良好;而且,藉由形成於細帶狀條帶、絲紗等之間的開口,可確保通氣性而為優良者。 In addition, the heat-reflective film structure of the present invention is based on the thin ribbon-shaped strips cut from the original film provided with a slippage imparting layer on the surface of the multilayer laminate film as warp yarns or weft yarns, and silk yarns as weft yarns. Or a woven fabric made of warp yarns, so it can be woven smoothly and uniformly. Compared with the case of using a multilayer laminate film, it can achieve winding properties, blocking resistance, tear resistance, durability, etc. The mechanical strength is better; and the openings formed between the thin ribbons, silk yarns, etc., can ensure air permeability and are excellent ones.
再者,本發明之熱線反射薄膜構造體係使此編織物之絲紗等的粗細度、細帶狀條帶的寬度、相鄰之絲紗等的間隔及相鄰之細帶狀條帶的間隔成特定的範圍,而使開孔率成為適確的範圍,與使用多層層合薄膜單質的情形相比,可確保毫不遜色之較高的可見光的穿透率及熱線的反射率,同時使紫外線穿透率成為適確的範圍。 Furthermore, the heat-ray reflective film structure system of the present invention makes the thickness of the silk yarns of the woven fabric, the width of the thin ribbon-like strips, the interval between adjacent silk yarns, etc., and the interval between the adjacent thin ribbons In a specific range, the aperture ratio becomes an appropriate range. Compared with the case of using a multi-layer laminated film, it can ensure the transmittance of visible light and the reflectance of heat rays that are not inferior. The ultraviolet transmittance becomes a proper range.
以下,根據實施例、比較例,就本發明之農業溫室及使用此農業溫室之植物栽培方法進一步詳細加以說明。 Hereinafter, the agricultural greenhouse of the present invention and the plant cultivation method using the agricultural greenhouse will be described in further detail based on examples and comparative examples.
作為熱線阻隔薄膜,係使用熱線反射型薄膜(下稱「薄膜A」)及熱線吸收型薄膜(下稱「薄膜B」)作為熱線阻隔薄膜,來比較農業溫室內的溫度上昇。 As heat-ray barrier films, heat-reflective film (hereinafter referred to as "film A") and heat-absorbing film (hereinafter referred to as "film B") are used as heat-ray barrier films to compare the temperature rise in agricultural greenhouses.
作為薄膜A,係使用具有以下構造、物性等的薄膜。 As the film A, a film having the following structure, physical properties, etc. is used.
*具有第1層(PEN樹脂,137層)與第2層(PETG樹脂,138層)交互層合而成的層合部,於此層合部的兩表面設有保護層(PEN樹脂,2層)的雙軸延伸層合聚酯薄膜 *With the first layer (PEN resin, 137 layer) and the second layer (PETG resin, 138 layer) alternately laminated to form a laminated part, on both surfaces of the laminated part is provided with protective layers (PEN resin, 2 Layer) biaxially stretched laminated polyester film
*PEN樹脂:固有黏度(鄰氯酚,35℃)0.62dl/g的聚-2,6-萘二甲酸乙二酯 *PEN resin: Polyethylene-2,6-naphthalate with intrinsic viscosity (o-chlorophenol, 35℃) 0.62dl/g
*PETG樹脂:共聚合30mol%的環己烷二甲醇之固有黏度(鄰氯酚,35℃)0.77dl/g的環己烷二甲醇共聚聚對苯二甲酸乙二酯 *PETG resin: copolymerized 30mol% cyclohexanedimethanol with an inherent viscosity (o-chlorophenol, 35℃) of 0.77dl/g cyclohexanedimethanol copolymerized polyethylene terephthalate
*層合部的厚度:40μm,各保護層的厚度:5μm,總厚度:50μm *The thickness of the laminated part: 40μm, the thickness of each protective layer: 5μm, the total thickness: 50μm
*調整第1層、第2層的厚度,使層合部之第1層與第2層的光學厚度比相等; * Adjust the thickness of the first layer and the second layer to make the optical thickness ratio of the first layer and the second layer of the laminated part equal;
*平均穿透率:88%,熱線之平均反射率:75% *Average transmittance: 88%, average reflectivity of hot wire: 75%
又,作為薄膜B,係使用市售之熱線吸收型薄膜(商品名「Megacool」,Mitsubishi Plastics Agri Dream股份有限公司製)。 In addition, as the film B, a commercially available heat-absorbing film (trade name "Megacool", manufactured by Mitsubishi Plastics Agri Dream Co., Ltd.) was used.
將薄膜A、薄膜B被覆於天窗關閉而密閉之農業溫室的上部,測定農業溫室內的溫度。將其結果示於表1。表1之圖表的縱軸係表示農業溫室內的溫度(℃)、橫軸表示時刻(0點~24點)。 The film A and the film B were covered on the upper part of the agricultural greenhouse with the skylight closed and airtight, and the temperature in the agricultural greenhouse was measured. The results are shown in Table 1. The vertical axis of the graph in Table 1 indicates the temperature (°C) in the agricultural greenhouse, and the horizontal axis indicates the time (0 o'clock to 24 o'clock).
由表1可知,透過使用如薄膜A之熱線反射型者作為利用太陽光之在農業溫室中使用的熱線阻隔薄膜,與使用如薄膜B之熱線吸收型者的情形相比,可抑制密閉之農業溫室內的溫度的上昇。 It can be seen from Table 1 that by using a heat-reflective film such as film A as a heat-ray barrier film used in agricultural greenhouses that use sunlight, compared with the case of using a heat-absorbing film such as film B, it can suppress closed agriculture The temperature rise in the greenhouse.
使用薄膜A,如下作成熱線遮蔽手段,並探討此等的性能。將結果示於表2。 Using film A, make the heat-ray shielding means as follows, and discuss these properties. The results are shown in Table 2.
以薄膜A經裁切的細帶狀條帶為經紗架設於織機上,橫向穿入透明絲線進行編織,作成如第2圖(a)所示之熱線遮蔽手段。 The thin ribbon-shaped strips cut by film A are used as warp yarns and placed on the loom, and transparent silk threads are inserted transversely for weaving to form the hot-wire shielding means shown in Figure 2 (a).
具體而言,係將薄膜A細切,作成短邊方向的寬度為4.5mm的扁紗,以此扁紗為經紗、以高密度聚乙烯樹脂製單絲(纖度:550dtex,拉伸強度:29N/根,伸度:35%)為緯紗,以織機編織熱線遮蔽手段。 Specifically, the film A is finely cut into a flat yarn with a width of 4.5 mm in the short-side direction, and the flat yarn is used as the warp, and a high-density polyethylene resin monofilament (fineness: 550dtex, tensile strength: 29N) / Root, elongation: 35%) is the weft yarn, which is covered by a loom weaving hot thread.
藉由調整經紗之扁紗的間隔,而得到具有如表2所示之開孔率的熱線遮蔽手段。 By adjusting the space between the flat yarns of the warp yarns, a hot-wire shielding method with the open porosity shown in Table 2 is obtained.
於上述實施例1之熱線反射薄膜的製作中,作為扁紗,係與由薄膜A所得之扁紗(扁紗a)共同使用由聚乙烯薄膜所得之同形狀的扁紗(扁紗b);作為經紗,係按每10根扁紗a配置1根扁紗b,此外係以與實施例1同樣的方式,以織機編織熱線遮蔽手段。 In the production of the heat-reflective film of Example 1, as the flat yarn, the flat yarn (flat yarn b) of the same shape obtained from the polyethylene film is used together with the flat yarn (flat yarn a) obtained from the film A; As the warp yarn, one flat yarn b was arranged for every ten flat yarns a, and in the same manner as in Example 1, the hot thread shielding means was knitted by a loom.
於實施例5中,係對薄膜A以等間隔穿設相同的圓形貫通孔使開孔率成為3%後作為熱線遮蔽手段使用。 In Example 5, the film A was used as a heat shielding means by piercing the same circular through holes at equal intervals so that the porosity was 3%.
又,於比較例1中則是將薄膜A直接作為熱線遮蔽手段使用。 In addition, in Comparative Example 1, the film A was directly used as a heat shielding means.
由表2可知,透過使用如薄膜A之熱線反射薄膜來形成及設置適度的開孔,可使熱線遮蔽手段具有通氣性並具有適度的紫外線穿透率。再者,藉由作成編織物構造,可使熱線遮蔽手段的捲繞性、抗黏連性、耐撕裂性、耐久性等更良好。 It can be seen from Table 2 that by using a heat-ray reflective film such as film A to form and set appropriate openings, the heat-ray shielding means can be air-permeable and have a moderate UV transmittance. Furthermore, by forming a braided structure, the winding property, blocking resistance, tear resistance, durability, etc. of the heat-ray shielding means can be improved.
以下,根據實施例、比較例,就本發明之熱線反射薄膜構造體進一步詳細加以說明。此外,實施例中的物性或特性係藉由下述方法來測定或評定。 Hereinafter, the heat ray reflective film structure of the present invention will be described in further detail based on Examples and Comparative Examples. In addition, the physical properties or characteristics in the examples were measured or evaluated by the following methods.
(1)使用可見光(波長:400-750nm)平均穿透率、紫外線(波長350nm)穿透率分光光度計(島津製作所製,MPC-3100),於波長300nm至2,100nm的範圍測定 各波長下之與經鋁蒸鍍而成的鏡面的相對鏡面反射率。由所得穿透率曲線,依據JIS R 3106:1998,算出可見光平均穿透率及紫外光穿透率。 (1) Use visible light (wavelength: 400-750nm) average transmittance, ultraviolet (wavelength 350nm) transmittance spectrophotometer (manufactured by Shimadzu Corporation, MPC-3100), measured in the wavelength range of 300nm to 2,100nm The relative specular reflectivity of the mirror surface formed by aluminum vapor deposition at each wavelength. From the obtained transmittance curve, according to JIS R 3106: 1998, the average transmittance of visible light and the transmittance of ultraviolet light are calculated.
(2)熱線(波長:800-1100nm)平均反射率 (2) Average reflectance of hot wire (wavelength: 800-1100nm)
使用分光光度計(島津製作所製、MPC-3100),於波長800nm至1100nm的範圍測定各波長下之與經鋁蒸鍍而成的鏡面的相對鏡面反射率。由測得的反射率曲線,算出熱線平均反射率。 Using a spectrophotometer (manufactured by Shimadzu Corporation, MPC-3100), the relative specular reflectance with the specular surface formed by aluminum vapor deposition at each wavelength was measured in the wavelength range of 800 nm to 1100 nm. From the measured reflectance curve, calculate the average reflectance of the hot line.
根據與日本特開2014-228837號公報之實施例1所示之製法同樣的製法,來製造多層層合薄膜A。 According to the same manufacturing method as that shown in Example 1 of JP 2014-228837 A, the multilayer laminate film A was manufactured.
分別準備作為屬第1層用且保護層用之聚酯的固有黏度(鄰氯酚,35℃)0.62dl/g的聚-2,6-萘二甲酸乙二酯(下稱「PEN」)、作為第2層用之聚酯的共聚合30mol%之環己烷二甲醇的固有黏度(鄰氯酚,35℃)0.77dl/g的環己烷二甲醇共聚聚對苯二甲酸乙二酯(下稱「PETG」)。 Separately prepare polyethylene-2,6-naphthalate (hereinafter referred to as "PEN") with an inherent viscosity (o-chlorophenol, 35°C) of 0.62dl/g as the polyester for the first layer and the protective layer , As the second layer of polyester copolymerization 30mol% cyclohexanedimethanol intrinsic viscosity (o-chlorophenol, 35 ℃) 0.77dl/g cyclohexanedimethanol copolymerized polyethylene terephthalate (Hereinafter referred to as "PETG").
其後,將屬第1層用且保護層用之聚酯於180℃乾燥5小時,將第2層用聚酯於60℃乾燥12小時後,供給至擠出機,PEN係加熱至300℃、PETG加熱至270℃而形成熔融狀態。使第1層的聚酯分歧成137層、第2層的聚酯分歧成138層後,使用第1層與第2層之各者的最大厚度與最小厚度的比連續地變化至最大/最小為1.4倍等 的層合構造部分、與在該層合構造部分的兩面層合有保護層等的多層供料套管裝置進行層合,在保持此層合狀態下導向模具,於澆鑄滾筒上進行澆鑄。然後,使薄膜兩面的最外層具有由PEN層構成的保護層,而作成層合構造部的總層數為275層的未延伸多層層合薄膜。 After that, the polyester for the first layer and protective layer was dried at 180°C for 5 hours, and the polyester for the second layer was dried at 60°C for 12 hours, and then supplied to the extruder, and the PEN system was heated to 300°C , PETG is heated to 270°C to form a molten state. After dividing the polyester of the first layer into 137 layers and dividing the polyester of the second layer into 138 layers, the ratio of the maximum thickness to the minimum thickness of each of the first and second layers is continuously changed to the maximum/minimum 1.4 times etc. The laminated structure part of the laminated structure part is laminated with a multi-layer supply sleeve device with a protective layer laminated on both sides of the laminated structure part, and the mold is guided while maintaining the laminated state and cast on the casting drum. Then, the outermost layers on both sides of the film were provided with protective layers composed of PEN layers, and a non-stretched multilayer laminate film with a total number of layers of the laminate structure portion was 275 layers.
將如此所得之未延伸之多層層合薄膜於120℃進行預加熱,並進一步在低速、高速的輥間自15mm上方以900℃的IR加熱器進行加熱,朝縱向延伸3.5倍。接著供給至拉幅機,於145℃朝橫向延伸4.5倍。將所得雙軸配向多層層合薄膜在180℃的溫度下進行熱固定30秒,而製成多層層合薄膜A。 The unstretched multilayer laminate film thus obtained was preheated at 120°C, and further heated in a low-speed, high-speed roll room from 15 mm above with an IR heater at 900°C, and stretched 3.5 times in the longitudinal direction. Then, it was supplied to a tenter and stretched 4.5 times in the lateral direction at 145°C. The obtained biaxially oriented multilayer laminate film was heat-fixed at a temperature of 180° C. for 30 seconds to form a multilayer laminate film A.
所得多層層合薄膜A其總厚度為50μm,表面及背面之保護層的厚度為5μm,保護層以外之層合部的第1層與第2層的光學厚度比係相等。此外,此等的厚度可藉由調整供給量、第1層與第2層的排出量來調整。又,所得多層層合薄膜A的可見光平均穿透率為89%,熱線平均反射率為75%。 The total thickness of the obtained multilayer laminate film A was 50 μm, the thickness of the protective layer on the front and back surfaces was 5 μm, and the optical thickness ratio of the first layer and the second layer of the laminate portion other than the protective layer was equal. In addition, these thicknesses can be adjusted by adjusting the supply volume and the discharge volume of the first and second layers. In addition, the average visible light transmittance of the obtained multilayer laminate film A was 89%, and the average reflectance of the hot ray was 75%.
除了在製造例1中,對縱向延伸後且橫向延伸前的多層層合薄膜的兩面,以輥塗法塗佈以下組成之塗液(滑性賦予塗液)成塗佈厚度為3μm,接著進行乾燥,再進行橫向延伸以外係以與製造例1同樣的方式製成多層層合薄膜B。 Except in Production Example 1, on both sides of the multi-layer laminate film after longitudinal stretching and before lateral stretching, the coating liquid (lubricity imparting coating liquid) of the following composition was applied by roll coating to a coating thickness of 3 μm, and then proceeded A multilayer laminate film B was produced in the same manner as in Production Example 1 except for drying and stretching in the lateral direction.
塗液之組成為丙烯酸-聚酯樹脂(高松油脂(股)製IN-170-6)的1.0wt%溶液76.9份、聚甲基丙烯酸甲酯微粒子(平均粒徑為0.06μm)的1.0wt%溶液3.1份、聚氧乙烯壬基苯基醚(日本油脂(股)製NS208.5)的1.0wt%溶液2.0份、聚氧乙烯壬基苯基醚(日本油脂(股)製NS240)的1.0wt%溶液18.0份,塗佈量在濕狀態下為2.7g/m2。 The composition of the coating solution is 76.9 parts of 1.0wt% solution of acrylic-polyester resin (IN-170-6 manufactured by Takamatsu Oil Co., Ltd.) and 1.0wt% of polymethyl methacrylate fine particles (average particle size of 0.06μm) 3.1 parts of solution, 2.0 parts of 1.0wt% solution of polyoxyethylene nonylphenyl ether (NS208.5 manufactured by Nippon Oil & Fat Co., Ltd.), 1.0 parts of polyoxyethylene nonylphenyl ether (NS240 manufactured by Nippon Oil & Fat Co., Ltd.) 18.0 parts of wt% solution, and the coating amount is 2.7 g/m 2 in a wet state.
除了在製造例2中,藉由對橫向延伸後之延伸前的多層層合薄膜的單面,將Obbligato PW202(AGC COAT-TECH股份有限公司製含紫外線吸收劑之氟樹脂)使用刮棒塗佈於多層層合薄膜的單面,並接著在100℃進行5分鐘的乾燥處理而設置膜厚為1μm的紫外線吸收層以外係以製造例2同樣的方式製成多層層合薄膜C。 Except in Manufacturing Example 2, Obbligato PW202 (a fluorine resin containing ultraviolet absorber manufactured by AGC COAT-TECH Co., Ltd.) was applied to one side of the multi-layer laminate film before stretching after lateral stretching. A multi-layer laminate film C was produced in the same manner as in Production Example 2 except that it was dried on one side of the multi-layer laminate film at 100° C. for 5 minutes to provide a 1 μm ultraviolet absorbing layer.
如下製造實施例6-1~6-4之熱線反射薄膜構造體。 The heat-ray reflective film structures of Examples 6-1 to 6-4 were manufactured as follows.
裁切多層層合薄膜B(有滑性賦予層,無紫外線吸收層)而作成細帶狀條帶,如第3圖及第4圖所示,以此細帶狀條帶為細帶狀條帶(經紗)11、以聚乙烯製單絲紗為絲紗等(緯紗)12進行編織,而作成熱線反射薄膜構造體。 Cut the multi-layer laminated film B (with a slippery imparting layer and no ultraviolet absorbing layer) into a thin ribbon-shaped strip, as shown in Figure 3 and Figure 4, the thin ribbon-shaped strip is a thin strip A belt (warp yarn) 11, a polyethylene monofilament yarn as a silk yarn (weft yarn) 12, etc. are woven to form a heat-reflective film structure.
此時, ○細帶狀條帶(經紗)11的寬度B取表3之「細帶狀條帶的寬度(B)〔mm〕」所示之值,○絲紗等(緯紗)12的粗細度A取表3之「單絲紗的粗細度(A)〔mm〕」所示之值,○相鄰之絲紗等(緯紗)12的間隔C取表3之「單絲紗的間隔(C)〔mm〕」所示之值,○相鄰之細帶狀條帶(經紗)11的間隔D取表3之「細帶狀條帶的間隔(D)〔mm〕」所示之值,編織成實施例6-1~6-4之熱線反射薄膜構造體。 at this time, ○The width B of the thin ribbon (warp yarn) 11 is the value shown in "The width of the thin ribbon (B) [mm]" in Table 3, and the thickness A of the silk yarn (weft) 12 is taken The value shown in Table 3 "Thickness (A) of Monofilament Yarn (A) [mm]", ○The interval C between adjacent silk yarns (weft yarns) 12 is taken as the "Interval of Monofilament Yarn (C) [ mm]", ○The interval D between adjacent thin strips (warp yarns) 11 takes the value shown in Table 3 "Interval between thin strips (D) [mm]" and weaves it into The heat-ray reflective film structure of Examples 6-1 to 6-4.
於此等熱線反射薄膜構造體中,「相鄰之絲紗等的間隔」、「絲紗等的粗細度相對於細帶狀條帶的寬度的倍率」及「相鄰之細帶狀條帶的間隔相對於細帶狀條帶的寬度的倍率」係分別為表3之「單絲紗的間隔(C)〔mm〕」、「A/B」及「D/A」所示之值。 In these heat-ray reflective film structures, "the interval between adjacent silk yarns, etc.", "the ratio of the thickness of the silk yarns to the width of the thin ribbon", and "adjacent thin ribbons "The magnification of the interval relative to the width of the thin ribbon" is the value shown in Table 3 "Monofilament Yarn Interval (C) [mm]", "A/B" and "D/A" respectively.
除使用多層層合薄膜A(無滑性賦予層及紫外線吸收層)作為多層層合薄膜以外係與實施例6-1同樣地進行編織而作成熱線反射薄膜構造體,由於多層層合薄膜A其表面的滑性極差,在裁切作成細帶狀條帶之步驟中的張力變動較大,而發生斷裂、或細帶狀條帶的寬度呈不均等,無法獲得均勻交織之熱線反射薄膜構造體。 Except that the multilayer laminate film A (non-slip imparting layer and ultraviolet absorbing layer) was used as the multilayer laminate film, it was woven in the same manner as in Example 6-1 to form a heat-ray reflective film structure. The multilayer laminate film A was The surface is extremely slippery, and the tension in the step of cutting into thin strips changes greatly, and breaks, or the width of the thin strips is uneven, and it is impossible to obtain a uniformly interwoven heat reflection film structure body.
未將多層層合薄膜B(有滑性賦予層,無紫外線吸收層)進行裁切、編織而直接作為比較例4-1之熱線反射薄膜構造體使用。 The multilayer laminate film B (with a slippery imparting layer, without an ultraviolet absorbing layer) was not cut and knitted, and was used as the heat-ray reflective film structure of Comparative Example 4-1.
除使用粗細度1.5mm的聚乙烯製單絲紗作為絲紗等(緯紗)12以外係與實施例6-1同樣地進行編織,而作成比較例4-2之熱線反射薄膜構造體。 Except that a polyethylene monofilament yarn with a thickness of 1.5 mm was used as the silk yarn (weft yarn) 12, the knitting was carried out in the same manner as in Example 6-1, and the heat-ray reflective film structure of Comparative Example 4-2 was produced.
於比較例4-2之熱線反射薄膜構造體中,「相鄰之絲紗等的間隔」、「絲紗等的粗細度相對於細帶狀條帶的寬度的倍率」及「相鄰之細帶狀條帶的間隔相對於細帶狀條帶的寬度的倍率」係分別為表3之「單絲紗的間隔(C)〔mm〕」、「A/B」及「D/A」所示之值。 In the heat-ray reflective film structure of Comparative Example 4-2, "the interval between adjacent silk yarns etc.", "the ratio of the thickness of the silk yarns etc. to the width of the thin ribbon" and "adjacent fineness" The magnification of the interval between the bands with respect to the width of the thin bands” is the “interval of monofilament yarn (C) (mm)”, “A/B” and “D/A” in Table 3, respectively. Show the value.
除使用多層層合薄膜C(有滑性賦予層及紫外線吸收層)作為多層層合薄膜以外係與實施例6-1同樣地進行編織,而作成實施例7-1之熱線反射薄膜構造體。 Except that the multilayer laminate film C (with a slippery imparting layer and an ultraviolet absorbing layer) was used as the multilayer laminate film, weaving was carried out in the same manner as in Example 6-1 to produce the heat ray reflective film structure of Example 7-1.
又,於實施例7-1~7-4中,○細帶狀條帶(經紗)11的寬度B取表4之「細帶狀條帶的寬度(B)〔mm〕」所示之值,○絲紗等(緯紗)12的粗細度A取表4之「單絲紗等的粗細度(A)〔mm〕」所示之值,○相鄰之絲紗等(緯紗)12的間隔C取表4之「單 絲紗等的間隔(C)〔mm〕」所示之值,○相鄰之細帶狀條帶(經紗)11的間隔D取表4之「細帶狀條帶的間隔(D)〔mm〕」所示之值,作成實施例7-1~7-4之熱線反射薄膜構造體。 In addition, in Examples 7-1 to 7-4, the width B of the thin ribbon (warp) 11 takes the value shown in the "width of the thin ribbon (B) [mm]" in Table 4 , ○The thickness A of silk yarn etc. (weft yarn) 12 takes the value shown in Table 4 "Thickness (A) of monofilament yarn etc. (A) [mm]", ○The interval between adjacent silk yarns etc. (weft yarn) 12 C takes the "single The interval between silk yarns etc. (C)〔mm〕" shows the value, ○The interval D between adjacent thin strips (warp yarns) 11 is taken from Table 4 "The space between thin strips (D) (mm) ]” The values shown in the heat-ray reflective film structures of Examples 7-1 to 7-4 were prepared.
於此等熱線反射薄膜構造體中,「相鄰之絲紗等的間隔」、「絲紗等的粗細度相對於細帶狀條帶的寬度的倍率」及「相鄰之細帶狀條帶的間隔相對於細帶狀條帶的寬度的倍率」係分別為表4之「單絲紗的間隔(C)〔mm〕」、「A/B」及「D/A」所示之值。 In these heat-ray reflective film structures, "the interval between adjacent silk yarns, etc.", "the ratio of the thickness of the silk yarns to the width of the thin ribbon", and "adjacent thin ribbons "The magnification of the interval relative to the width of the thin ribbon" is the value shown in Table 4 "Monofilament interval (C) [mm]", "A/B" and "D/A".
未將多層層合薄膜C(有滑性賦予層及紫外線吸收層)進行裁切、編織而直接作成比較例5-1之熱線反射薄膜構造體。 The multilayer laminate film C (with a slippery imparting layer and an ultraviolet absorbing layer) was not cut and knitted, and the heat ray reflection film structure of Comparative Example 5-1 was directly formed.
除相鄰之細帶狀條帶(經紗)11的間隔D取2.40mm以外係與實施例7-1同樣地進行編織,而作成比較例5-2之熱線反射薄膜構造體。 Weaving was performed in the same manner as in Example 7-1 except that the interval D between the adjacent thin band-shaped strips (warp yarns) 11 was 2.40 mm, and the heat-ray reflective film structure of Comparative Example 5-2 was produced.
於比較例5-2之熱線反射薄膜構造體中,「相鄰之絲紗等的間隔」、「絲紗等的粗細度相對於細帶狀條帶的寬度的倍率」及「相鄰之細帶狀條帶的間隔相對於細帶狀條帶的寬度的倍率」係分別為表4之「單絲紗的間隔(C)〔mm〕」、「A/B」及「D/A」所示之值。 In the heat-ray reflective film structure of Comparative Example 5-2, "the interval between adjacent silk yarns etc.", "the ratio of the thickness of the silk yarns etc. to the width of the thin ribbon" and "adjacent fineness" The magnification of the interval between the bands with respect to the width of the thin bands” is shown in Table 4, “Monofilament Yarn Interval (C) [mm]”, “A/B” and “D/A” respectively. Show the value.
此外,於實施例6-1~6-4、比較例3、比較例4-2、實施例7-1~7-4及比較例5-2中,為了對寬度較大的細帶狀條帶(經紗)11,使用緯紗牢固地進行編織,而使粗細度E(0.2mm)的聚乙烯製絲紗等(經紗)13作為經紗存在於相鄰之細帶狀條帶(經紗)11之間。 In addition, in Examples 6-1 to 6-4, Comparative Example 3, Comparative Example 4-2, Examples 7-1 to 7-4, and Comparative Example 5-2, in order to compare the width of the thin strip The tape (warp) 11 is firmly woven using weft yarns, and the polyethylene silk yarn (warp) 13 with a thickness of E (0.2mm) is present as a warp on the adjacent thin ribbon-shaped strips (warp) 11 between.
測定上述實施例及比較例之熱線反射薄膜構造體的可見光(波長400~750nm的光)之平均穿透率、熱線(波長800~1100nm的光)之平均反射率、及紫外線(波長350nm)穿透率,將其結果示於表3及表4。 Measure the average transmittance of visible light (light with a wavelength of 400 to 750 nm), the average reflectance of heat (light with a wavelength of 800 to 1100 nm), and the penetration of ultraviolet rays (wavelength of 350 nm) of the heat-ray reflective film structure of the above-mentioned examples and comparative examples. The transmittance, the results are shown in Table 3 and Table 4.
如比較例3使用未設有滑性賦予層的多層層合薄膜A時,由於多層層合薄膜A的表面滑性極差,在裁切作成細帶狀條帶之步驟中的張力變動較大,而發生斷裂、或細帶狀條帶的寬度呈不均等,無法獲得均勻交織之熱線反射薄膜構造體。因此,熱線反射薄膜構造體的開孔率、可見光平均穿透率、熱線平均反射率、紫外線穿透率皆產生不均。 As in Comparative Example 3, when the multilayer laminate film A without a slippage imparting layer is used, since the surface of the multilayer laminate film A is extremely slippery, the tension change in the step of cutting into thin strips is large. , And breakage occurs, or the width of the thin strips is uneven, and a uniformly interwoven heat ray reflective film structure cannot be obtained. Therefore, unevenness occurs in the aperture ratio, the average transmittance of visible light, the average reflectance of heat rays, and the transmittance of ultraviolet rays of the heat-ray reflective film structure.
又,即使使用設有滑性賦予層的多層層合薄膜B時,如比較例4-1,未將多層層合薄膜B進行裁切、 編織而直接作成熱線反射薄膜構造體時,如表3所示「開孔率仍為0%」,無法確保通氣性,而發生於夜間,尤為清晨,栽培部與屋頂部之間的溫差變大,在薄膜的底面發生結露形成水滴滴到植物,使植物的果實、葉、花等變色、劣化等問題。再者,如表3所示,「紫外線穿透率為5%」而過小,因而有發生茄子等的果實生長時呈現成熟顏色的情況較差、在農業溫室內蜜蜂無法充分接近花而無法正常進行授粉活動等問題之虞。 Moreover, even when the multilayer laminate film B provided with a slippage imparting layer is used, as in Comparative Example 4-1, the multilayer laminate film B is not cut, When woven directly into a heat-ray reflective film structure, as shown in Table 3, the "opening rate is still 0%", and ventilation cannot be ensured. It occurs at night, especially in the early morning, and the temperature difference between the cultivation area and the roof area increases. , Dew condensation occurs on the bottom surface of the film to form water droplets on plants, causing problems such as discoloration and deterioration of plant fruits, leaves, flowers, etc. Furthermore, as shown in Table 3, the "ultraviolet penetration rate of 5%" is too small, so that the fruit such as eggplants will appear mature color when growing. In agricultural greenhouses, bees cannot get close enough to the flowers and cannot proceed normally. Problems such as pollination activities.
又,即使使用設有滑性賦予層的多層層合薄膜B時,如比較例4-2,使用粗細度1.5mm之較粗者作為絲紗等時,如表3所示,與實施例6-1~6-4相比,「開孔率仍為7%」而較小,因此可見光平均穿透率為65%而過小。 In addition, even when the multilayer laminate film B provided with a slippage imparting layer is used, as in Comparative Example 4-2, when a thicker with a thickness of 1.5 mm is used as the silk yarn, etc., as shown in Table 3, it is similar to Example 6. Compared with -1~6-4, the "opening rate is still 7%" and small, so the average visible light transmittance is 65%, which is too small.
使用多層層合薄膜B的實施例6-1~6-4之熱線反射薄膜構造體,與比較例3之熱線反射薄膜構造體相比,可順利且均質地進行編織,而且,因此,熱線反射薄膜構造體的開孔率、可見光平均穿透率、熱線平均反射率、紫外線穿透率的不均皆較小而為優良者。 Compared with the heat-reflective film structure of Comparative Example 3, the heat-reflective film structures of Examples 6-1 to 6-4 using the multilayer laminate film B can be woven smoothly and uniformly, and, therefore, the heat-reflective film structure The film structure has relatively small variations in aperture ratio, average visible light transmittance, average heat ray reflectance, and ultraviolet transmittance, which is excellent.
又,實施例6-1~6-4之熱線反射薄膜構造體,與比較例4-1之熱線反射薄膜構造體相比,由於通氣性較優良,可防止於夜間,尤為清晨,栽培部與屋頂部之間的溫差變大,在薄膜的底面發生結露形成水滴滴到植物,使植物的果實、葉、花等變色、劣化等問題的發生,再者,由於不會過度遮蔽紫外線,而無對果實的成熟呈 色、授粉活動造成不良影響之虞。 In addition, the heat-ray reflection film structure of Examples 6-1 to 6-4, compared with the heat-ray reflection film structure of Comparative Example 4-1, has better air permeability and can be prevented from nighttime, especially in the early morning. The temperature difference between the roofs increases, and condensation occurs on the bottom surface of the film to form water droplets on the plants, causing discoloration and deterioration of the fruits, leaves, flowers, etc. of the plants. In addition, since the ultraviolet rays are not excessively shielded, there is no To the ripeness of the fruit Color and pollination activities may cause adverse effects.
又,實施例6-1~6-4之熱線反射薄膜構造體,與比較例4-2之熱線反射薄膜構造體相比,可確保毫不遜色之較高的熱線平均反射率(61~72%)及紫外線穿透率(11~21%),同時使可見光穿透率高達「86~89%」。 In addition, the heat ray reflection film structure of Examples 6-1 to 6-4, compared with the heat ray reflection film structure of Comparative Example 4-2, can ensure a high heat ray average reflectivity (61 to 72 %) and ultraviolet light transmittance (11~21%), while making visible light transmittance as high as "86~89%".
表4所示熱線反射薄膜構造體係使用設有滑性賦予層及紫外線吸收層的多層層合薄膜C製造而成者;如比較例5-1,未將多層層合薄膜進行裁切、編織而直接作成熱線反射薄膜構造體時,如表4所示「開孔率為0%」,無法確保通氣性,而發生於夜間,尤為清晨,栽培部與屋頂部之間的溫差變大,在薄膜的底面發生結露形成水滴滴到植物,使植物的果實、葉、花等變色、劣化等問題。再者,如表4所示,「紫外線穿透率為1%」而過小,因而有發生茄子等的果實生長時呈現成熟顏色的情況較差、在農業溫室內蜜蜂無法充分接近花而無法正常進行授粉活動等問題之虞。 The heat-ray reflective film structure system shown in Table 4 is manufactured using a multilayer laminate film C provided with a slippery imparting layer and an ultraviolet absorbing layer; as in Comparative Example 5-1, the multilayer laminate film is not cut or woven. When directly fabricating the heat-ray reflective film structure, as shown in Table 4, the "opening rate is 0%", and air permeability cannot be ensured. It occurs at night, especially in the early morning, when the temperature difference between the cultivation area and the roof becomes larger. Condensation occurs on the bottom surface of the plant, forming water droplets to the plant, causing problems such as discoloration and deterioration of plant fruits, leaves, flowers, etc. Furthermore, as shown in Table 4, the "ultraviolet penetration rate of 1%" is too small, so that the fruit of eggplant and other fruits will appear mature color when they grow, and the bees cannot get close to the flower sufficiently in the agricultural greenhouse and cannot proceed normally. Problems such as pollination activities.
又,如比較例5-2,使細帶狀條帶的間隔為2.40mm而過寬時,如表4所示,與實施例7-1~7-4相比,由於「開孔率為34%」而較大,故熱線平均反射率為52%而過小。 Also, as in Comparative Example 5-2, when the interval between the thin strips is 2.40 mm and is too wide, as shown in Table 4, compared with Examples 7-1 to 7-4, the "opening rate is 34%” is larger, so the average reflectivity of the hot line is 52%, which is too small.
使用多層層合薄膜C的實施例7-1~7-4之熱 線反射薄膜構造體,與比較例3之熱線反射薄膜構造體相比,可順利且均質地進行編織,而且,因此,熱線反射薄膜構造體的開孔率、可見光平均穿透率、熱線平均反射率、紫外線穿透率的不均皆較小而為優良者。 Heat of Examples 7-1~7-4 using multilayer laminated film C Compared with the heat-reflecting film structure of Comparative Example 3, the wire-reflecting film structure can be woven smoothly and uniformly. Therefore, the opening rate, the average visible light transmittance, and the average heat-ray reflection of the heat-reflecting film structure The unevenness of the rate and the UV transmittance are both small and excellent.
又,實施例7-1~7-4之熱線反射薄膜構造體,與比較例5-1之熱線反射薄膜構造體相比,由於通氣性較優良,可防止於夜間,尤為清晨,栽培部與屋頂部之間的溫差變大,在薄膜的底面發生結露形成水滴滴到植物,使植物的果實、葉、花等變色、劣化等問題的發生,再者,由於不會過度遮蔽紫外線,而無對果實的成熟呈色、授粉活動造成不良影響之虞。 In addition, the heat-ray reflection film structure of Examples 7-1 to 7-4, compared with the heat-ray reflection film structure of Comparative Example 5-1, has better air permeability and can be prevented at night, especially in the early morning. The temperature difference between the roofs increases, and condensation occurs on the bottom surface of the film to form water droplets on the plants, causing discoloration and deterioration of the fruits, leaves, flowers, etc. It may cause adverse effects on fruit ripening and coloring and pollination activities.
又,實施例7-1~7-4之熱線反射薄膜構造體,與比較例5-2之熱線反射薄膜構造體相比,可確保毫不遜色之可見光穿透率(88~93%)及紫外線穿透率(7~17%),同時使熱線反射率高達「58~71%」。 In addition, the heat-reflective film structure of Examples 7-1 to 7-4 can ensure the same visible light transmittance (88~93%) compared with the heat-reflective film structure of Comparative Example 5-2. Ultraviolet penetration rate (7~17%), while making the heat ray reflectivity as high as "58~71%".
準備: ready:
1)多層層合薄膜A、及2)對多層層合薄膜A的單面使用刮棒塗佈Obbligato PW202(AGC COAT-TECH股份有限公司製含紫外線吸收劑之氟樹脂),接著於100℃進行5分鐘的乾燥處理而設置膜厚為1μm之紫外線吸收層的薄膜,對此等1)及2)之薄膜進行暴露試驗(藉由Xenon Weather Meter,放射照度60W/m2、黑色面板溫度63℃、照射時間200小時),評定霧度值的差〔△Haze(%)〕。將結果示於表5。 1) Multilayer laminated film A, and 2) Obbligato PW202 (a fluororesin containing ultraviolet absorber manufactured by AGC COAT-TECH Co., Ltd.) was applied to one side of the multilayer laminated film A with a bar, and then carried out at 100°C After 5 minutes of drying treatment, a film with a thickness of 1μm ultraviolet absorbing layer is set, and exposure tests are performed on the films of 1) and 2) (using Xenon Weather Meter, irradiance 60W/m 2 , black panel temperature 63°C , Irradiation time 200 hours), evaluate the difference in haze value [△Haze(%)]. The results are shown in Table 5.
目視觀察暴露試驗後的薄膜,未設有紫外線吸收層的上述1)之薄膜其表面產生了微小的龜裂,設有紫外線吸收層的上述2)之薄膜,其外觀幾乎未看出變化。 Upon visual observation of the film after the exposure test, the surface of the film of 1) without an ultraviolet absorbing layer had microcracks, and the film of 2) with an ultraviolet absorbing layer showed little change in its appearance.
如此,以具有萘環等縮合型芳香環的樹脂形成構成熱線反射薄膜構造體之多層層合薄膜之折射率較高的樹脂層時,此樹脂層易受紫外線所引起的劣化,而藉由設置紫外線吸收層,則可充分防止薄膜的紫外線劣化,而能夠延長熱線反射薄膜構造體的使用期限。 In this way, when a resin having a condensed aromatic ring such as a naphthalene ring is used to form a resin layer with a high refractive index of the multilayer laminate film constituting the heat ray reflection film structure, the resin layer is susceptible to deterioration caused by ultraviolet rays, and the The ultraviolet absorbing layer can sufficiently prevent the ultraviolet deterioration of the film, and can extend the service life of the heat ray reflection film structure.
此外,本發明之熱線反射薄膜構造體非為薄膜單質,而是以薄膜經裁切的細帶狀條帶為經紗或緯紗、 以絲紗等為緯紗或經紗經編織而成的編織物,設有開口部,因此,在設有此種紫外線吸收層的情況下,仍可使必要的紫外線穿透,同時調整成可抑制熱線反射薄膜構造體本身的劣化。 In addition, the heat-ray reflective film structure of the present invention is not a simple film, but a thin ribbon-shaped strip cut by the film as warp yarn or weft yarn, Woven fabrics knitted with silk yarns as wefts or warp yarns are provided with openings. Therefore, when such an ultraviolet absorbing layer is provided, necessary ultraviolet rays can still be penetrated and adjusted to suppress heat Deterioration of the reflective film structure itself.
1‧‧‧農業溫室 1‧‧‧Agricultural Greenhouse
2‧‧‧CO2供給手段 2‧‧‧CO 2 supply means
3‧‧‧熱線遮蔽手段或熱線反射薄膜構造體 3‧‧‧Heat ray shielding means or heat ray reflective film structure
4‧‧‧除濕冷卻手段 4‧‧‧Dehumidification and cooling means
5‧‧‧天窗 5‧‧‧Skylight
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