CN109906840A - A kind of radiation refrigeration curtain - Google Patents

A kind of radiation refrigeration curtain Download PDF

Info

Publication number
CN109906840A
CN109906840A CN201910129920.6A CN201910129920A CN109906840A CN 109906840 A CN109906840 A CN 109906840A CN 201910129920 A CN201910129920 A CN 201910129920A CN 109906840 A CN109906840 A CN 109906840A
Authority
CN
China
Prior art keywords
radiation refrigeration
layer
item
radiation
curtain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910129920.6A
Other languages
Chinese (zh)
Inventor
徐绍禹
丁海林
其他发明人请求不公开姓名
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo Ruiling New Energy Technology Co Ltd
Original Assignee
Ningbo Ruiling New Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ningbo Ruiling New Energy Technology Co Ltd filed Critical Ningbo Ruiling New Energy Technology Co Ltd
Priority to CN201910129920.6A priority Critical patent/CN109906840A/en
Publication of CN109906840A publication Critical patent/CN109906840A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/25Greenhouse technology, e.g. cooling systems therefor

Abstract

The invention discloses a kind of radiation refrigeration curtains, multiple film items including weave frame and in weave frame, at least partly film item includes radiation refrigeration layer, radiation refrigeration layer includes resin and the radiation refrigeration body being dispersed in resin, and emissivity of the radiation refrigeration layer in 7 μm~14 μ m wavelength ranges is 70%~100%.Radiation refrigeration curtain of the invention is light, bending resistance is good, mounting means is diversified, when being cooled down, it is laid on outside object to be cooled down or space, and make radiation refrigeration layer towards outside, radiation refrigeration layer by the thermal energy of its own in the form of 7~14 μm of electromagnetic waves by " atmospheric window " be discharged into temperature close to absolute zero external space, to make own temperature reduce, due to the presence of the temperature difference, heat in object to be cooled down or space is constantly transmitted to the lower radiation refrigeration layer of temperature, the final cooling realized to object or space.And when not needing to be cooled down, radiation refrigeration curtain is packed up.

Description

A kind of radiation refrigeration curtain
Technical field
The present invention relates to a kind of radiation refrigeration curtains.
Background technique
Currently, greenhouse is widely used in the fields such as fruits and vegetables, flowers, cultivation.Greenhouse can be played in weather cold The effect of heat preservation avoids animals and plants frostbite in canopy, and still, during the broiling summer, canopy temperature is excessively high, also can be to dynamic in canopy Plant damages.When ambient temperature is higher, how to guarantee that there is suitable temperature in greenhouse, is to need what is solved to ask at present Topic.
In the prior art, it is some be by increasing shading system on greenhouse, to reduce greenhouse room temperature, but this Kind of mode cooling effect is limited, and when light is blocked excessive, also will affect the normal growth of animals and plants.There are also it is some be Increase ventilating system on greenhouse to reduce greenhouse room temperature, but if outdoor temperature is inherently relatively high, using ventilation The effect that mode cools down is not obvious.
Summary of the invention
For overcome the deficiencies in the prior art, it the purpose of the present invention is to provide a kind of radiation refrigeration curtain, can be applied to Outside greenhouse roof, passively cooled down to greenhouse.
The purpose of the present invention adopts the following technical scheme that realization:
A kind of radiation refrigeration curtain, multiple film items including weave frame and in the weave frame, at least portion Point film item includes radiation refrigeration layer, and the radiation refrigeration layer includes resin and the radiation refrigeration that is dispersed in the resin Body, emissivity of the radiation refrigeration layer in 7 μm~14 μ m wavelength ranges are 70%~100%.
Further, multiple film items are side by side or compartment of terrain is threaded through in the weave frame, the table of each film item Area accounts for the 20%~100% of the radiation refrigeration curtain total surface area.
Further, the visible light transmittance of the radiation refrigeration layer be greater than 50%, the radiation refrigeration layer with a thickness of 10 μm~1000 μm.
Further, at least partly described film item includes reflecting layer, and the reflecting layer is in 300nm~2500nm wave-length coverage Interior reflectivity is 20%~100%.
Further, at least partly described film item includes the radiation refrigeration layer and is arranged in the radiation refrigeration layer one The reflecting layer of side, reflectivity of the reflecting layer in 300nm~2500nm wave-length coverage are 20%~100%.
Further, the reflecting layer includes metal layer and/or ceramic layer, the reflecting layer with a thickness of 5nm~ 2000nm。
Further, the reflecting layer be the stratiform resin with foam structure, the reflecting layer with a thickness of 10 μm~ 400μm。
Further, multiple film items are respectively light-transmission type membrane item and reflection-type film item, the light-transmission type membrane item packet The radiation refrigeration layer is included, the visible light transmittance of the light-transmission type membrane item is greater than 50%, and the reflection-type film item includes described Radiation refrigeration layer and the reflecting layer that radiation refrigeration layer side is arranged in, the reflection-type film item is in 300nm~2500nm Reflectivity in wave-length coverage is 20%~100%.
Further, the thermal absorptivity of the radiation refrigeration curtain is 2~60%.
Further, the average-size of the radiation refrigeration body is 10nm~30 μm, and the radiation refrigeration body is selected from following It is one or more: silica, titanium dioxide, silicon carbide, calcium carbonate, zinc oxide, aluminium oxide, barium sulfate.
Compared with prior art, light, bending resistance that the beneficial effects of the present invention are: radiation refrigeration curtains of the invention Good, mounting means diversification, when being cooled down, is laid on outside object to be cooled down or space, and make radiation refrigeration layer Towards outside, the thermal energy of its own is discharged into temperature by " atmospheric window " in the form of 7~14 μm of electromagnetic waves by radiation refrigeration layer The external space close to absolute zero is spent, to make own temperature reduce, due to the presence of the temperature difference, in object to be cooled down or space Heat be constantly transmitted to the lower radiation refrigeration layer of temperature, the final cooling realized to object or space.And do not need into When row cooling, radiation refrigeration curtain is packed up.
Detailed description of the invention
Fig. 1 is the schematic diagram of one embodiment of radiation refrigeration curtain of the invention;
Fig. 2 is the schematic diagram of one embodiment of film item of the invention;
Fig. 3 is the schematic diagram of another embodiment of film item of the invention;
Fig. 4 is the schematic diagram of another embodiment of radiation refrigeration curtain of the invention;
Fig. 5 is the schematic diagram of the further embodiment of radiation refrigeration curtain of the invention;
Fig. 6 is the schematic diagram of the further embodiment of film item of the invention;
In figure: 1, weave frame;2, film item;201, light-transmission type membrane item;202, reflection-type film item;211, radiation refrigeration layer; 212, reflecting layer;221, base;222, reflecting layer.
Specific embodiment
In the following, being described further in conjunction with specific embodiment to the present invention, it should be noted that is do not collided Under the premise of, new embodiment can be formed between various embodiments described below or between each technical characteristic in any combination.
In the description of the present invention, it should be noted that " transverse direction ", " vertical if any term " center " for the noun of locality To ", " length ", " width ", " thickness ", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", The indicating positions such as "bottom", "inner", "outside", " clockwise ", " counterclockwise " and positional relationship are orientation based on the figure or position Relationship is set, the narration present invention is merely for convenience of and simplifies description, rather than the device or element of indication or suggestion meaning are necessary It constructs and operates with specific orientation, with particular orientation, should not be understood as limiting specific protection scope of the invention.
It should be noted that term " includes " in the description and claims of this application and " having " and they Any deformation, it is intended that cover it is non-exclusive include, for example, containing the process, method of a series of steps or units, being System, product or equipment those of are not necessarily limited to be clearly listed step or unit, but may include be not clearly listed or For the intrinsic other step or units of these process, methods, product or equipment.
The present invention " atmospheric window " mentioned below refers to: atmosphere has different transmissions to the electromagnetic wave of different wave length Rate, the higher wave band of transmissivity are known as " atmospheric window ".Wherein the atmospheric window of 7~14 mu m wavebands is that researcher is most interested , because the black body radiation under room temperature is concentrated mainly on this section.Radiation refrigeration body described in the present invention can be by self heat In the form of 7~14 μm of electromagnetic waves by " atmospheric window " be discharged into temperature close to absolute zero external space, to reach The purpose of itself cooling.
The present invention provides a kind of radiation refrigeration curtain, including weave frame 1 and the multiple films being arranged in weave frame 1 Item 2, wherein at least partly film item 2 includes radiation refrigeration layer 211, and radiation refrigeration layer 211 includes resin and is dispersed in resin Radiation refrigeration body, emissivity of the radiation refrigeration layer 211 in 7~14 μ m wavelength ranges be 70%~100%.
Film item 2 is arranged in weave frame 1 by the present invention, and the radiation refrigeration curtain of acquisition can be bent or fold. Further, since weave frame 1 itself has certain braiding gap, so that radiation refrigeration curtain has more hole, These holes make radiation refrigeration curtain have preferable gas permeability.Radiation refrigeration layer 211 on radiation refrigeration curtain has spoke Refrigeration effect is penetrated, can passively be cooled down.
Radiation refrigeration curtain of the invention is light, bending resistance is good, mounting means is diversified, will when being cooled down It is laid on outside object to be cooled down or space, and makes radiation refrigeration layer 211 towards outside, radiation refrigeration layer 211 by its own Thermal energy in the form of 7~14 μm of electromagnetic waves by " atmospheric window " be discharged into temperature close to absolute zero external space, thus Reduce own temperature, due to the presence of the temperature difference, the heat in object to be cooled down or space is constantly transmitted to the lower spoke of temperature Refrigerating layer 211 is penetrated, the final cooling realized to object or space.And when not needing to be cooled down, radiation refrigeration curtain is received It rises.
In hot weather, radiation refrigeration curtain of the invention is laid on big ceiling, can be effectively reduced in greenhouse Temperature, avoid the animals and plants in greenhouse by high-temperature damage.The plastics of greenhouse can also be directly replaced using radiation refrigeration curtain Film can not only reduce the temperature in greenhouse, it can also be ensured that good air circulation in greenhouse.Certainly, spoke of the invention Refrigeration curtain is penetrated in addition to that can apply on greenhouse, can be applied on building, vehicle etc. facility.
In some preferred embodiments, emissivity of the radiation refrigeration layer 211 in 7~14 μ m wavelength ranges be 90%~ 100%.The emissivity of radiation refrigeration layer 211 is higher, and cooling, refrigeration effect are better.
Multiple film items 2 can be threaded through side by side in weave frame 1, can also be threaded through spaced reciprocally in weave frame 1. It, can be by adjusting the spacing distance between each film item 2, to change light transmission, the permeability of radiation refrigeration curtain when practical application. The present invention is not defined the spacing distance between film item 2 each in weave frame 1.Fig. 1,4,5 show film item 2 for length The schematic diagram of bar shaped, but the shape of film item 2 can also be irregular polygon, circle etc., shape of the present invention to film item 2 It is not defined, those skilled in the art can according to need the shape for selecting suitable film item 2.
In some embodiments, the surface area of film item 2 accounts for the 20%~100% of radiation refrigeration curtain total surface area.
It is exemplified below the several embodiments with film item 2:
In the first embodiment, multiple film items 2 are light-transmission type membrane item 201, as shown in Figure 1, 2, light-transmission type membrane item 201 include radiation refrigeration layer 211, and the visible light transmittance of light-transmission type membrane item 201 is greater than 50%.The radiation refrigeration curtain of the embodiment Cloth allows visible light-transmissive, is applied when on greenhouse, while playing cooling function, it can also be ensured that animals and plants obtain Certain illumination.
Radiation refrigeration layer 211 with a thickness of 10 μm~1000 μm.
In the second embodiment, multiple film items 2 are reflection-type film item 202, as shown in figure 3, reflection-type film item 202 Including radiation refrigeration layer 211 and reflecting layer 212, reflectivity of the reflecting layer 212 in 300nm~2500nm wave-length coverage is 20%~100%.On the one hand the radiation refrigeration curtain of the embodiment has the cooling effect of radiation refrigeration, on the other hand also have The heat insulation of reflective thermal radiation is disposed at outside greenhouse or building, cooling and insulating excellent effect.
Reflection-type film item 202 with a thickness of 20 μm~2000 μm.
In an embodiment in reflecting layer 212, reflecting layer 212 includes metallic reflector and/or ceramic reflective layer, instead Penetrate layer 212 with a thickness of 5nm~2000nm.The material of metallic reflector can be but not limited to one of Ag, Al, Cr, Ti Or it is a variety of;The material of ceramic reflective layer can be but not limited to aluminium oxide, titanium oxide, silica, niobium oxide, zinc oxide, oxidation One of indium, tin oxide, silicon nitride, titanium nitride, silicated aluminum, zinc sulphide, indium sulfide, artificial gold, magnesium fluoride, calcirm-fluoride are more Kind.Metallic reflector or ceramic reflective layer can be used the methods of vapor deposition and be formed on radiation refrigeration layer 211, metallic reflection Layer, ceramic reflective layer preparation method be the prior art, the present invention repeats no more.
Reflecting layer 212 can only include metallic reflector, can also only include ceramic reflective layer, can also include alternately setting The metallic reflector and ceramic reflective layer set.Since the stability of metallic reflector is relatively poor, it is preferable that in metallic reflection Ceramic reflective layer is arranged in the side or two sides of layer.
In another embodiment in reflecting layer 212, reflecting layer 212 is the stratiform resin with foam structure, reflecting layer 212 with a thickness of 10 μm~400 μm.It is higher that the foam structure in reflecting layer has it in 300nm~2500nm wave-length coverage Reflectivity, foam structure can by drawing process formed and also by addition foaming agent formed, addition can also be passed through Some particulate matters are formed.
In some cases, reflecting layer 212 can be prepared by the following method: inorganic particulate, foaming agent are mixed with resin, Then film layer is prepared using drawing process.Wherein, inorganic particulate can be but not limited to one of silica, titanium dioxide Or it is a variety of, foaming agent can be but not limited to poly(4-methyl-1-pentene) organic foaming agent or the organic hair of cyclic olefin copolymer resins Infusion.Resin during stretching, can form foam structure, abscess is finer and close, is more conducive to improve around inorganic particulate Reflectivity, the effect of foaming agent are to increase the abscess quantity generated in reflecting layer 212.
Reflecting layer 212 and radiation refrigeration layer 211 can be connected by bonding agent, reflecting layer 212 can also be with radiation refrigeration Layer 211 uses coextruding method one-pass molding.
Preferably, reflectivity of the reflecting layer 212 in 300nm~2500nm wave-length coverage is 70%~100%, reflecting layer 212 reflectivity in 300nm~2500nm wave-length coverage is higher, and heat insulation is better.
In the third embodiment, multiple film items 2 are respectively light-transmission type membrane item 201 and reflection-type film item 202, are such as schemed Shown in 4, wherein light-transmission type membrane item 201 is with the light-transmission type membrane item 201 of the first embodiment, and reflection-type film item 202 is the same as second The reflection-type film item 202 of embodiment.Light-transmission type membrane item 201 and reflection-type film item 202 are arranged alternately, light-transmission type membrane item 201 It can be adjusted according to the demand to light transmission capacity with the quantity of reflection-type film item 202.Light-transmission type membrane item 201 and reflection-type film item There are many 202 modes being arranged alternately, and two kinds of film items, such as two light-transmission types of every setting can be arranged alternately according to certain rule One reflection-type film item 202 is set between film item 201.Light-transmission type membrane item 201 can also replace at random with reflection-type film item 202 Setting.On the one hand radiation refrigeration curtain in the embodiment has the cooling effect of radiation refrigeration, on the other hand also have anti- The heat insulation of heat radiation is penetrated, simultaneously as a part of film light-permeable, therefore applied when on greenhouse, it can also protect Card animals and plants obtain certain illumination.
Preferably, the thermal absorptivity in 300nm~2500nm wave-length coverage of the radiation refrigeration curtain be 2~ 60%.
In the 4th kind of embodiment, a part of multiple film items 2 is the film 2a with radiation refrigeration layer 211, another Part is the film 2b without radiation refrigeration layer 211, as shown in Figure 5.Wherein, the film 2a with radiation refrigeration layer 211 can To be light-transmission type membrane item 201 and/or reflection-type film item 202;Film 2b without radiation refrigeration layer 211 is that transparent plastic is thin The material of film, transparent plastic film can be but not limited to: polyethylene terephthalate (PET), poly-methyl methacrylate Ester (PMMA), polycarbonate (PC), poly- 4- methylpentene (TPX), polybutylene terephthalate (PBT) (PBT), poly- terephthaldehyde Sour glycol ester -1,4 cyclohexane dimethanol ester (PETG), polypropylene (PP), polyethylene (PE), polyvinyl chloride (PVC), polyphenyl Ethylene (PS).
In the 5th kind of embodiment, a part of multiple film items 2 is the film 2a with radiation refrigeration layer 211, another Part is the film 2b without radiation refrigeration layer 211, as shown in Figure 5, wherein the film 2a with radiation refrigeration layer 211 can To be light-transmission type membrane item 201 and/or reflection-type film item 202;Film 2b without radiation refrigeration layer 211 is reflectance coating item, instead Penetrating reflectivity of the film item in 300nm~2500nm wave-length coverage is 50%~100%.
In some cases, as shown in fig. 6, film 2b includes base 221 and the reflecting layer that is arranged in base 221 222, when reflecting layer 222 is metallic reflector and/or ceramic reflective layer.
In other cases, film 2b includes reflecting layer, and reflecting layer is the stratiform resin with foam structure.
It is noted that the film 2b for not having radiation refrigeration layer 211 can also be the film item with other function, this Invention the above various embodiments is not exhausted enumerates.
In some other implementation, light-transmission type membrane item 201 can also include other layers in addition to radiation refrigeration layer 211, Only need to guarantee that light-transmission type membrane item 201 has required light transmittance.Similarly, reflectivity film item 202 can also include removing spoke Penetrate other layers except refrigerating layer 211, reflecting layer 212.
In each embodiment, the radiation refrigeration body in radiation refrigeration layer 211 can be but not limited to silica, titanium dioxide One of titanium, silicon carbide, calcium carbonate, zinc oxide, aluminium oxide, barium sulfate are a variety of, and the average grain diameter of radiation refrigeration body is 10nm~30 μm.
In each embodiment, the resin in radiation refrigeration layer 211 can be but not limited to: polyethylene terephthalate (PET), polymethyl methacrylate (PMMA), polycarbonate (PC), poly- 4- methylpentene (TPX), poly terephthalic acid fourth two Alcohol ester (PBT), polyethylene terephthalate -1,4 cyclohexane dimethanol ester (PETG), polypropylene (PP), polyethylene (PE), polyvinyl chloride (PVC), polystyrene (PS).
Weave frame 1 is the network structure formed using yarn woven, for multiple film items 2 being separated from each other to be combined shape Integral curtain.Material used in weave frame 1 can be various plastics, fiber etc., material used in weave frame 1 Material can be transparent or opaque material.Weave frame 1 can be used prior art preparation and obtain, and the present invention repeats no more.
In some embodiments, weave frame 1 is preferably prepared using transparent material, to reduce 1 shadow of weave frame as far as possible Ring the radiation refrigeration effect of film item.
In further embodiments, weave frame 1 is preferably formed as multiple netted mounting portions 11 being parallel to each other, at least partly Film item 2 is equipped in netted mounting portion 11.
In further embodiments, the material at least partially radiation refrigeration fiber of weave frame 1, radiation system are knitted to form Cold fiber includes resin and the radiation refrigeration body being dispersed in resin, and preparation method can refer to existing preparation method, spoke Penetrate refrigeration body can be but not limited to silica, titanium dioxide, silicon carbide, calcium carbonate, zinc oxide, aluminium oxide, in barium sulfate It is one or more, the average grain diameter of radiation refrigeration body is 10nm~30 μm.
[embodiment 1]
A kind of radiation refrigeration curtain includes weave frame 1 and multiple film items 2 for being disposed side by side in weave frame 1, more A film item 2 is respectively the light-transmission type membrane item 201 and reflection-type film item 202 being arranged alternately, as shown in Figure 4.
Light-transmission type membrane item 201 includes resin and the radiation refrigeration body being dispersed in resin, and radiation refrigeration body is that partial size is 10 microns of SiO2, the mass ratio of radiation refrigeration body and resin is 2:99, light-transmission type membrane item 201 with a thickness of 100 microns.
Reflection-type film item 202 includes radiation refrigeration layer 211 and the reflecting layer 212 being formed on radiation refrigeration layer 211.Spoke The radiation refrigeration body that refrigerating layer 211 includes resin and is dispersed in resin is penetrated, radiation refrigeration body is that partial size is 10 microns SiO2, the mass ratio of radiation refrigeration body and resin is 2:99, radiation refrigeration layer 211 with a thickness of 100 microns.Reflecting layer 212 Including the metallic aluminum with a thickness of 20nm and with a thickness of the alumina layer of 30nm.The layer structure of reflection-type film item 202 is successively Radiation refrigeration layer, metallic aluminum, the alumina layer of setting.
Using Perkin Elmer, 950 type UV/Vis/NIR Spectrometer of Lambda to light-transmission type membrane item 201 into The test of row visible light transmittance, the survey that the reflectivity in 300nm~2500nm wave-length coverage is carried out to reflection-type film item 202 Thermal absorptivity of the radiation refrigeration curtain in 300nm~2500nm wave-length coverage is tested in examination.Using SOC- 100Hemispherical Directional Reflectometer to light-transmission type membrane item 201 and reflection-type film item 202 into The test of the emissivity of 7~14 mum wavelength of row.Test result are as follows: hair of the light-transmission type membrane item 201 in 7 μm~14 μ m wavelength ranges Penetrating rate is 93.2%;The visible light transmittance of light-transmission type membrane item 201 is 92.1%;Reflection-type film item 202 is in 7 μm~14 mum wavelengths Emissivity in range is 93.0%;Reflectivity of the reflection-type film item 202 in 300nm~2500nm wave-length coverage be 93.4%;Thermal absorptivity of the radiation refrigeration curtain in 300nm~2500nm wave-length coverage is 5.2%.
[embodiment 2]
A kind of radiation refrigeration curtain includes weave frame 1 and multiple film items 2 for being disposed side by side in weave frame 1, more A film item 2 is light-transmission type membrane item 201.
Light-transmission type membrane item 201 includes resin and the radiation refrigeration body being dispersed in resin, and radiation refrigeration body is that partial size is 10 microns of SiO2, the mass ratio of radiation refrigeration body and resin is 2:99, light-transmission type membrane item 201 with a thickness of 100 microns.
Using Perkin Elmer, 950 type UV/Vis/NIR Spectrometer of Lambda to light-transmission type membrane item 201 into The test of row visible light transmittance carries out thermal absorptivity of the radiation refrigeration curtain in 300nm~2500nm wave-length coverage Test.Using SOC-100Hemispherical Directional Reflectometer to light-transmission type membrane item 201 carry out 7~ The test of the emissivity of 14 mum wavelengths.Test result are as follows: emissivity of the light-transmission type membrane item 201 in 7 μm~14 μ m wavelength ranges It is 93.2%;The visible light transmittance of light-transmission type membrane item 201 is 92.1%;Radiation refrigeration curtain is in 300nm~2500nm wavelength Thermal absorptivity in range is 7.0%.
[comparative example 1]
A kind of curtain includes weave frame and multiple film items for being disposed side by side in weave frame, and multiple film items are reflection Film item, reflectance coating item include base layer of resin and the reflecting layer that is formed in base layer of resin, and reflecting layer includes with a thickness of 20nm's Metallic aluminum and alumina layer with a thickness of 30nm.The layer structure of reflectance coating item is the base layer of resin set gradually, metallic aluminium Layer, alumina layer.Wherein, base layer of resin with a thickness of 100 microns, radiation refrigeration layer in the material and embodiment 1 of base layer of resin Resin it is identical.
Reflectance coating item is carried out using Perkin Elmer, 950 type UV/Vis/NIR Spectrometer of Lambda The test of reflectivity in 300nm~2500nm wave-length coverage, the heat absorption to curtain in 300nm~2500nm wave-length coverage Rate is tested.Test result are as follows: reflectivity of the reflectance coating item in 300nm~2500nm wave-length coverage is 93.4%;Radiation The thermal absorptivity of refrigeration curtain is 5.1%.
The radiation refrigeration curtain of embodiment 1, embodiment 2, comparative example 1 is separately positioned on the outside of greenhouse, while phase is set Greenhouse with size is as blank control example.It tests the outdoor temperature of 9:00~17:00 of a certain regional some day, be covered with implementation The greenhouse A internal temperature of 1 curtain of example is equipped with the greenhouse B internal temperature of 2 curtain of embodiment, is covered with the greenhouse of 1 curtain of comparative example C internal temperature and the greenhouse D internal temperature for not spreading curtain, test result are shown in Table 1.
Table 1
From the test data of table 1 it can be seen that being provided with the canopy temperature of the radiation refrigeration curtain of embodiment 1, compare family Outer temperature is 2~4 DEG C low;The canopy temperature of radiation refrigeration curtain provided with embodiment 2,2~5 DEG C lower than outdoor temperature;If The canopy temperature for having set the curtain of comparative example 1 is 2~9 DEG C higher than outdoor temperature;The greenhouse of not set any curtain, Indoor Temperature Degree is higher by 5~12 DEG C than outdoor temperature.
It can be found that: radiation refrigeration curtain of the invention is set on greenhouse with apparent refrigeration effect, can be made big Temperature of shed is lower than outdoor temperature, and radiation refrigeration is combined (i.e. embodiment 1) with reflective insulation, can achieve preferably Cooling effect;The curtain of comparative example 1 is only set on greenhouse, although canopy temperature ratio is not provided with low when curtain, its temperature Degree will not be lower than outdoor temperature, and cooling effect is poor.
The above embodiment is only the preferred embodiment of the present invention, and the scope of protection of the present invention is not limited thereto, The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention Claimed range.

Claims (10)

1. a kind of radiation refrigeration curtain, which is characterized in that multiple films including weave frame and in the weave frame Item, at least partly described film item includes radiation refrigeration layer, and the radiation refrigeration layer includes resin and is dispersed in the resin Radiation refrigeration body, emissivity of the radiation refrigeration layer in 7 μm~14 μ m wavelength ranges be 70%~100%.
2. radiation refrigeration curtain according to claim 1, which is characterized in that multiple film items are side by side or compartment of terrain is worn In the weave frame, the surface area of each film item accounts for the 20%~100% of the radiation refrigeration curtain total surface area.
3. radiation refrigeration curtain according to claim 1, which is characterized in that the visible light transmittance of the radiation refrigeration layer Greater than 50%, the radiation refrigeration layer with a thickness of 10 μm~1000 μm.
4. radiation refrigeration curtain according to claim 1, which is characterized in that at least partly described film item includes reflecting layer, Reflectivity of the reflecting layer in 300nm~2500nm wave-length coverage is 20%~100%.
5. radiation refrigeration curtain according to claim 1, which is characterized in that at least partly described film item includes the radiation Refrigerating layer and the reflecting layer that radiation refrigeration layer side is arranged in, the reflecting layer is in 300nm~2500nm wave-length coverage Interior reflectivity is 20%~100%.
6. radiation refrigeration curtain according to claim 4 or 5, which is characterized in that the reflecting layer include metal layer and/or Ceramic layer, the reflecting layer with a thickness of 5nm~2000nm.
7. radiation refrigeration curtain according to claim 4 or 5, which is characterized in that the reflecting layer is with foam structure Stratiform resin, the reflecting layer with a thickness of 10 μm~400 μm.
8. radiation refrigeration curtain according to claim 1, which is characterized in that multiple film items are respectively light-transmission type membrane item And reflection-type film item, the light-transmission type membrane item include the radiation refrigeration layer, the visible light transmittance of the light-transmission type membrane item Greater than 50%, the reflection-type film item includes the radiation refrigeration layer and the reflection that radiation refrigeration layer side is arranged in Layer, reflectivity of the reflection-type film item in 300nm~2500nm wave-length coverage are 20%~100%.
9. radiation refrigeration curtain according to claim 8, which is characterized in that the radiation refrigeration curtain 300nm~ Thermal absorptivity in 2500nm wave-length coverage is 2~60%.
10. -5,8,9 any radiation refrigeration curtain according to claim 1, which is characterized in that the radiation refrigeration body Average-size is 10nm~30 μm, and the radiation refrigeration body is selected from one or more of: silica, titanium dioxide, carbonization Silicon, calcium carbonate, zinc oxide, aluminium oxide, barium sulfate.
CN201910129920.6A 2019-02-21 2019-02-21 A kind of radiation refrigeration curtain Pending CN109906840A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910129920.6A CN109906840A (en) 2019-02-21 2019-02-21 A kind of radiation refrigeration curtain

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910129920.6A CN109906840A (en) 2019-02-21 2019-02-21 A kind of radiation refrigeration curtain

Publications (1)

Publication Number Publication Date
CN109906840A true CN109906840A (en) 2019-06-21

Family

ID=66962033

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910129920.6A Pending CN109906840A (en) 2019-02-21 2019-02-21 A kind of radiation refrigeration curtain

Country Status (1)

Country Link
CN (1) CN109906840A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110256836A (en) * 2019-06-28 2019-09-20 宁波瑞凌新能源科技有限公司 A kind of selfreparing radiation refrigeration film
CN111877963A (en) * 2020-07-09 2020-11-03 河南五方合创建筑设计有限公司 Radiation refrigeration printing opacity solar protection devices
WO2021088398A1 (en) * 2019-11-06 2021-05-14 宁波瑞凌新能源科技有限公司 Radiation refrigeration fabric and product

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2537210Y (en) * 2001-09-25 2003-02-26 上海农园绿色工程有限公司 Reflection energy saving sun shade curtain
JP2010085917A (en) * 2008-10-02 2010-04-15 Asahi Kasei E-Materials Corp Transparent heat-ray reflecting film and heat-ray shielding windowpane using the same
CN108432507A (en) * 2018-06-11 2018-08-24 宁波瑞凌节能环保创新与产业研究院 A kind of Agricultural greenhouse film with radiation cooling function
CN108518026A (en) * 2018-06-11 2018-09-11 宁波瑞凌节能环保创新与产业研究院 A kind of radiation refrigeration bituminized shingle
CN207901779U (en) * 2017-11-14 2018-09-25 新奥科技发展有限公司 Pad pasting
CN108891115A (en) * 2018-08-24 2018-11-27 宁波瑞凌节能环保创新与产业研究院 A kind of radiation refrigeration film of achievable passive cooling
CN109341137A (en) * 2018-10-24 2019-02-15 苏州融睿纳米复材科技有限公司 Passive refrigeration structure based on photonic crystal
CN210094176U (en) * 2019-02-21 2020-02-21 宁波瑞凌新能源科技有限公司 Radiation refrigeration curtain

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2537210Y (en) * 2001-09-25 2003-02-26 上海农园绿色工程有限公司 Reflection energy saving sun shade curtain
JP2010085917A (en) * 2008-10-02 2010-04-15 Asahi Kasei E-Materials Corp Transparent heat-ray reflecting film and heat-ray shielding windowpane using the same
CN207901779U (en) * 2017-11-14 2018-09-25 新奥科技发展有限公司 Pad pasting
CN108432507A (en) * 2018-06-11 2018-08-24 宁波瑞凌节能环保创新与产业研究院 A kind of Agricultural greenhouse film with radiation cooling function
CN108518026A (en) * 2018-06-11 2018-09-11 宁波瑞凌节能环保创新与产业研究院 A kind of radiation refrigeration bituminized shingle
CN108891115A (en) * 2018-08-24 2018-11-27 宁波瑞凌节能环保创新与产业研究院 A kind of radiation refrigeration film of achievable passive cooling
CN109341137A (en) * 2018-10-24 2019-02-15 苏州融睿纳米复材科技有限公司 Passive refrigeration structure based on photonic crystal
CN210094176U (en) * 2019-02-21 2020-02-21 宁波瑞凌新能源科技有限公司 Radiation refrigeration curtain

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
康许科: "超临界CO2发泡法制备PS/PP微发泡反射板", 中国优秀硕士学位论文全文数据库, no. 9, pages 4 - 5 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110256836A (en) * 2019-06-28 2019-09-20 宁波瑞凌新能源科技有限公司 A kind of selfreparing radiation refrigeration film
CN110256836B (en) * 2019-06-28 2022-06-21 宁波瑞凌新能源科技有限公司 Self-repairing radiation refrigerating film
WO2021088398A1 (en) * 2019-11-06 2021-05-14 宁波瑞凌新能源科技有限公司 Radiation refrigeration fabric and product
CN111877963A (en) * 2020-07-09 2020-11-03 河南五方合创建筑设计有限公司 Radiation refrigeration printing opacity solar protection devices

Similar Documents

Publication Publication Date Title
TWI725533B (en) Radiative cooling material, method for manufacturing the same and application thereof
JP7023978B2 (en) Radiative cooling function paint and its applications
CN109906840A (en) A kind of radiation refrigeration curtain
KR101567996B1 (en) Article of the tent or shelter type
Hemming et al. Greenhouse cooling by NIR-reflection
KR20180120155A (en) Agricultural house, plant cultivation method using this agricultural house and heat ray reflective film structure
Heo et al. Heat-shedding with photonic structures: radiative cooling and its potential
WO2015094924A1 (en) Reflective articles and methods for increasing photosynthesis
Teitel et al. Greenhouse and screenhouse cover materials: Literature review and industry perspective
JP7265703B2 (en) Laminated films, greenhouse horticultural films, and woven and knitted fabrics
Hoffmann et al. Tropical and subtropical greenhouses-A challenge for new plastic films
Gangisetty et al. A review of nanoparticle material coatings in passive radiative cooling systems including skylights
CN210094176U (en) Radiation refrigeration curtain
CN205153944U (en) Energy -conserving shutter plate of transparent
US20220381524A1 (en) Systems and Methods for Spectrally Selective Thermal Radiators with Partial Exposures to Both the Sky and the Terrestrial Environment
CN210617539U (en) Radiation cooling material and composite material thereof
CN203374161U (en) Liquid intelligent temperature and light adjusting glass
CN104542091A (en) Greenhouse
RU2642555C1 (en) Sun-protective device
CN2537210Y (en) Reflection energy saving sun shade curtain
JP2008086284A (en) Material for natural lighting for agricultural and horticultural hot house, and agricultural and horticultural hot house
Montero et al. Greenhouse design and covering materials
TW201622988A (en) Temperature regulation film and manufacture method thereof
CN206851515U (en) A kind of heat-insulated antifog heliogreenhouse
JPS6158527A (en) Heat insulating greenhouse

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination