TWI665966B - Oil and fat composition, wheat puffed food to which the oil and fat composition is added, and method for producing the oil and fat composition - Google Patents

Oil and fat composition, wheat puffed food to which the oil and fat composition is added, and method for producing the oil and fat composition Download PDF

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TWI665966B
TWI665966B TW103133044A TW103133044A TWI665966B TW I665966 B TWI665966 B TW I665966B TW 103133044 A TW103133044 A TW 103133044A TW 103133044 A TW103133044 A TW 103133044A TW I665966 B TWI665966 B TW I665966B
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oil
fat
alginate
fat composition
composition
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TW201517802A (en
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小原淳志
戶田徹
日高一郎
小澤拓也
羽染芳宗
宮島千尋
安竹良礼
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日清奧利友集團股份有限公司
喜美克股份有限公司
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    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/16Fatty acid esters
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/16Fatty acid esters
    • A21D2/165Triglycerides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/01Other fatty acid esters, e.g. phosphatides
    • A23D7/011Compositions other than spreads
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/01Other fatty acid esters, e.g. phosphatides
    • A23D7/013Spread compositions
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/007Other edible oils or fats, e.g. shortenings, cooking oils characterised by ingredients other than fatty acid triglycerides
    • A23D9/013Other fatty acid esters, e.g. phosphatides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Edible Oils And Fats (AREA)

Abstract

提供一種油脂組成物、添加有該油脂組成物之小麥膨化食品、及該油脂組成物的製造方法,其中,該油脂組成物可對小麥膨化食品等賦予份量感、柔軟感及濕潤感。 Provided are an oil and fat composition, a wheat puffed food to which the oil and fat composition is added, and a method for producing the oil and fat composition, wherein the oil and fat composition can impart weight, softness, and moistness to wheat puffed food and the like.

本發明提供一種油脂組成物,其含有酯化度為23%以上且未滿75%的褐藻酸酯。前述油脂組成物,亦可為乳化油脂組成物。本發明提供添加有上述油脂組成物之小麥膨化食品、及上述油脂組成物的製造方法。 The present invention provides a fat and oil composition containing an alginate having an esterification degree of 23% or more and less than 75%. The fat and oil composition may be an emulsified fat and oil composition. The present invention provides a wheat puffed food to which the above-mentioned oil and fat composition is added, and a method for producing the above-mentioned oil and fat composition.

Description

油脂組成物、添加有該油脂組成物之小麥膨化食品、及該油脂組成物的製造方法 Oil and fat composition, wheat puffed food to which the oil and fat composition is added, and method for producing the oil and fat composition

本發明關於油脂組成物,添加有該油脂組成物之小麥膨化食品、及該油脂組成物的製造方法。 The present invention relates to a fat and oil composition, a wheat puffed food to which the fat and oil composition is added, and a method for producing the fat and oil composition.

近年來,為了迎合消費者多樣化的嗜好,販賣著各式各樣的麵包類及蛋糕點心產品等小麥膨化食品。特別是需要具有膨鬆份量感的外觀,且具有柔軟感及濕潤感(帶有濕潤的口感)等口感的小麥膨化食品。 In recent years, in order to meet the diversified tastes of consumers, various types of breads, cakes, and snack products such as wheat puffed foods have been sold. In particular, there is a need for a wheat puffed food that has the appearance of a bulky texture and has a soft feel and a moist feel (with a moist texture).

作為改善小麥膨化食品的份量感的方法,可舉出使用果膠作為品質改良劑的方法(專利文獻1)、使用酸作為生麵團改良劑的方法(專利文獻2)。作為賦予小麥膨化食品柔軟感等口感的方法,可舉出將修飾澱粉及活性麩質代替一部分的小麥粉來使用的方法(專利文獻3)。 Examples of the method for improving the feeling of weight of a puffed wheat food include a method using pectin as a quality improver (Patent Document 1) and a method using an acid as a dough improver (Patent Document 2). Examples of a method for imparting a soft texture such as a wheat puffed food include a method in which modified starch and active gluten are used instead of a part of wheat flour (Patent Document 3).

此外,作為提升小麥膨化食品的份量感及口感的方法,添加褐藻酸酯於小麥膨化食品的方法被提出(例如,專利文獻4~7)。 In addition, as a method for improving the weight and texture of wheat puffed food, a method of adding alginate to wheat puffed food has been proposed (for example, Patent Documents 4 to 7).

[先前技術文獻] [Prior technical literature] (專利文獻) (Patent Literature)

專利文獻1:日本特開平7-289144號公報 Patent Document 1: Japanese Patent Application Laid-Open No. 7-289144

專利文獻2:日本特開平8-256670號公報 Patent Document 2: Japanese Patent Application Laid-Open No. 8-256670

專利文獻3:日本特開平3-87135號公報 Patent Document 3: Japanese Patent Application Laid-Open No. 3-87135

專利文獻4:日本特開2010-98993號公報 Patent Document 4: Japanese Patent Application Laid-Open No. 2010-98993

專利文獻5:日本特開2013-85483號公報 Patent Document 5: Japanese Patent Application Publication No. 2013-85483

專利文獻6:日本特開2004-65245號公報 Patent Document 6: Japanese Patent Application Laid-Open No. 2004-65245

專利文獻7:日本特開2012-24002號公報 Patent Document 7: Japanese Patent Application Publication No. 2012-24002

然而,以往的技術,都只有改善小麥膨化食品的份量感與口感的其中之一,有無法對小麥膨化食品一併賦予份量感、柔軟感及濕潤感的可能性。 However, the conventional techniques have only improved one of the texture and texture of the wheat puffed food, and there is a possibility that the texture, softness, and moistness of the wheat puffed food cannot be provided together.

本發明是為了解決上述的問題而完成,其目的在於提供一種能對小麥膨化食品等賦予食品份量感、柔軟感及濕潤感的油脂組成物、添加有該油脂組成物之小麥膨化食品、及該油脂組成物的製造方法等。 The present invention has been made in order to solve the above-mentioned problems, and an object thereof is to provide an oil-fat composition capable of imparting a sense of weight, softness and moistness to food such as wheat puffed food, a wheat puffed food to which the oil-fat composition is added, and the same Production method of oil and fat composition and the like.

本發明人發現,藉由於油脂組成物中添加具有特定酯化度的褐藻酸酯,可解決上述問題,遂完成本發明。具體而言,本發明提供下述之物。 The inventors have found that the above problem can be solved by adding alginate with a specific degree of esterification to the oil and fat composition, and thus completed the present invention. Specifically, the present invention provides the following.

(1)一種油脂組成物,其含有酯化度為23%以上且未滿75%的褐藻酸酯。 (1) An oil and fat composition containing an alginate having an esterification degree of 23% or more and less than 75%.

(2)如(1)所述之油脂組成物,其中,前述的油脂組成物是乳化油脂組成物。 (2) The fat or oil composition according to (1), wherein the fat or oil composition is an emulsified fat or oil composition.

(3)一種小麥膨化食品,其添加有如(1)或(2)所述之油脂組成物。 (3) A wheat puffed food added with the oil-fat composition as described in (1) or (2).

(4)如(3)所述之小麥膨化食品,其中,前述小麥膨化食品是高含水麵包(high hydrated bread)。 (4) The wheat puffed food according to (3), wherein the wheat puffed food is high hydrated bread.

(5)一種油脂組成物的製造方法,其包含將酯化度為23%以上且未滿75%的褐藻酸酯與油脂加以混合的步驟,且前述褐藻酸酯的1質量%水溶液於20℃時的黏度是30mPa.S以上。 (5) A method for producing a fat and oil composition, comprising a step of mixing alginate with an esterification degree of 23% or more and less than 75% with fats and oils, and a 1% by mass aqueous solution of the alginate at 20 ° C The viscosity at time is 30mPa. S or more.

(6)如(1)所述之油脂組成物,其中,前述褐藻酸酯的1質量%水溶液於20℃時的黏度是30mPa.S以上。 (6) The oil and fat composition according to (1), wherein the viscosity of the 1% by mass aqueous solution of the alginate at 20 ° C is 30 mPa. S or more.

依據本發明,提供一種能對小麥膨化食品等賦予份量感、柔軟感及濕潤感的油脂組成物、添加有該油脂組成物之小麥膨化食品、及該油脂組成物的製造方法。 According to the present invention, there are provided an oil-fat composition capable of imparting weight, softness, and wetness to wheat puffed food, etc., a wheat puffed food to which the oil-fat composition is added, and a method for producing the oil-fat composition.

以下說明本發明的實施型態,但本發明並不限於下述的實施型態。 The embodiments of the present invention will be described below, but the present invention is not limited to the following embodiments.

[油脂組成物] [Grease composition]

本發明的油脂組成物,至少包含酯化度為23%以上且未滿75%的褐藻酸酯及油脂。以下說明各成分。 The oil and fat composition of the present invention contains at least alginate and an oil and fat having an esterification degree of 23% or more and less than 75%. Each component is explained below.

(褐藻酸酯) (Alginate)

褐藻酸酯是指一種具有下述結構之化合物:構成褐藻酸的羧基,至少一部分轉變成酯。褐藻酸是指一種多醣類,其 具有以2種糖醛酸(甘露糖醛酸及古羅糖醛酸)任意地進行直鏈聚合而成的構造,且富含於昆布、海帶芽等天然褐藻類中。 Alginate refers to a compound having a structure in which at least a part of a carboxyl group constituting alginic acid is converted into an ester. Alginic acid is a polysaccharide that It has a structure in which two kinds of uronic acid (mannuronic acid and guluronic acid) are arbitrarily linearly polymerized, and is rich in natural brown algae such as kelp and kelp buds.

褐藻酸酯,可依照周知的方法,藉由將褐藻酸進行酯化來調製。其中一例如下述所示。例如,利用藉由酸所實施的加水分解等方法,由褐藻類等獲得精製的褐藻酸。將所獲得的褐藻酸,於加壓及/或加熱條件下,與環氧丙烷進行酯化,藉此得到褐藻酸酯。供應於酯化過程的褐藻酸,亦能是藉由氫氧化鈉或是碳酸鈉等被部分中和後的褐藻酸鹽。 Alginate can be prepared by esterifying alginic acid according to a known method. One example is shown below. For example, refined alginic acid is obtained from brown algae and the like by a method such as hydrolysis performed by an acid. The obtained alginic acid is esterified with propylene oxide under pressure and / or heating to obtain alginate. The alginic acid supplied to the esterification process can also be an alginate that has been partially neutralized with sodium hydroxide or sodium carbonate.

褐藻酸酯的原料並無限定,可為天然的褐藻酸,亦可為合成的褐藻酸。 The raw material of the alginate is not limited, and may be natural alginic acid or synthetic alginic acid.

本發明的褐藻酸酯中,會混有未酯化的褐藻酸,作為這種未酯化的褐藻酸,可舉出褐藻酸及/或褐藻酸鹽。本發明中,亦將褐藻酸酯、褐藻酸及/或褐藻酸鹽之混合物,稱為「褐藻酸酯」。 The alginate of the present invention is mixed with unesterified alginic acid. Examples of such unesterified alginic acid include alginic acid and / or alginate. In the present invention, a mixture of alginate, alginic acid and / or alginate is also referred to as "alginate".

本發明的褐藻酸酯,其酯化度為23%以上且未滿75%,較佳是35%~70%,更佳是40%~65%,最佳是45%~60%。經本發明人檢討後的結果發現,若將酯化度為上述範圍的褐藻酸酯添加於油脂組成物,意外地會得到一種油脂組成物,其能對食品等賦予份量感、柔軟感及濕潤感。若油脂組成物中的褐藻酸酯的酯化度是在上述範圍之外,則添加有該油脂組成物之食品等,其份量感、柔軟感及濕潤感中的任一種性質、或是所有的性質,會有較劣等的可能性。 The alginate of the present invention has an esterification degree of 23% or more and less than 75%, preferably 35% to 70%, more preferably 40% to 65%, and most preferably 45% to 60%. As a result of review by the present inventors, it was found that if alginate having an esterification degree within the above range is added to a fat or oil composition, a fat or oil composition is unexpectedly obtained, which can impart weight, softness, and moistness to foods and the like. . If the degree of esterification of the alginate in the oil and fat composition is outside the above range, the food, etc. to which the oil and fat composition is added may have any of the properties of weight, softness, and wetness, or all Nature, there may be inferior possibilities.

「酯化度」是表示在褐藻酸酯所包含的羧基中,被酯化的羧基的比例的數值,是根據日本食品添加物公定書第8 版的「褐藻酸丙二酯的純度試驗(1)」為基準來特定而成。本發明的「褐藻酸酯的酯化度」,是指褐藻酸酯中混有褐藻酸及/或褐藻酸鹽時,由這些混合物全體所求得的酯化度,被稱為「褐藻酸酯的酯化度」。 "Esterification degree" is a numerical value which shows the ratio of the carboxyl group which is esterified among the carboxyl group contained in alginate, and is based on the 8th "Purity Test of Propionate Alginate (1)" is specified as a reference. The "esterification degree of alginate" in the present invention refers to the degree of esterification obtained from the whole of these mixtures when alginate and / or alginate are mixed with alginate, and is referred to as "alginate Degree of esterification. "

酯化度為上述範圍的褐藻酸酯,可藉由在調製褐藻酸酯時,於進行與環氧丙烷進行酯化之際,適當地調整環氧丙烷的使用量、褐藻酸與環氧丙烷的酯化反應時間及反應溫度來得到。 The alginate having an esterification degree within the above range can be adjusted by appropriately adjusting the amount of propylene oxide and the amount of alginic acid and propylene oxide when esterifying with propylene oxide when preparing alginate. Obtained by esterification reaction time and reaction temperature.

作為本發明的褐藻酸酯,若其酯化度為上述範圍之物則無特別限定,較為合適的是,使用褐藻酸酯的1質量%水溶液於20℃時的黏度為30mPa.S以上之物,較佳為使用黏度為50mPa.S以上之物,更佳為使用黏度為80mPa.S以上之物。藉由使用具有這樣的黏度特性的褐藻酸酯,會得到容易將份量感賦予食品等的油脂組成物。褐藻酸酯的黏度越高,越具有容易將份量感賦予食品等的傾向。 The alginate of the present invention is not particularly limited as long as it has an esterification degree within the above range. It is more suitable that the viscosity of a 1% by mass aqueous solution of alginate at 20 ° C is 30 mPa. For substances above S, it is preferred to use a viscosity of 50 mPa. For substances above S, it is more preferable to use a viscosity of 80mPa. Above S. By using an alginate having such a viscosity characteristic, an oil-fat composition that easily imparts a portion feeling to foods and the like can be obtained. The higher the viscosity of the alginate, the more it tends to impart a feeling of portion to foods and the like.

褐藻酸酯的黏度的上限並沒有特別限定,較合適的是,褐藻酸酯的1質量%水溶液於20℃時的黏度為1000mPa.S以下,較佳是500mPa.S以下,更佳是300mPa.S以下,進而更佳是160mPa.S以下。若油脂組成物中含有黏度上限為上述範圍的褐藻酸酯,將該油脂組成物添加於食品(特別是小麥膨化食品)等的時候所得到的生麵團,會變得適合加工。 The upper limit of the viscosity of alginate is not particularly limited. It is more suitable that the viscosity of a 1% by mass aqueous solution of alginate at 20 ° C is 1000 mPa. Below S, preferably 500 mPa. Below S, more preferably 300mPa. Below S, and more preferably 160 mPa. S or less. When an alginate having an upper limit of viscosity within the above range is contained in the fat and oil composition, the dough obtained when the fat and oil composition is added to foods (especially wheat puffed foods) and the like becomes suitable for processing.

褐藻酸酯的黏度,是使用黏度計(東京計器股份有限公司製,型號:TVB-10M VISCOMETER(MODEL:BM)的旋轉器No.1(旋轉數30rpm)),藉由對褐藻酸酯的1質量%水溶 液,測定其於20℃時的黏度來進行特定。 The viscosity of the alginate was determined by using a viscometer (rotor No. 1 (30 rpm) of TVB-10M VISCOMETER (MODEL: BM) manufactured by Tokyo Keiki Co., Ltd.). Mass% water soluble The liquid is specified by measuring its viscosity at 20 ° C.

具有上述範圍的黏度之褐藻酸酯,是藉由調整原料也就是褐藻酸的分子量而得。具體而言,是依照周知的方法,使用經低分子化的褐藻酸作為褐藻酸酯的原料所獲得。例如,作為將褐藻酸酯進行低分子化的方法,可舉出將高分子的褐藻酸藉由酵素(褐藻酸裂解酶)進行分解的方法、將高分子的褐藻酸藉由酸或熱進行加水分解的方法等。若使用高分子的褐藻酸作為褐藻酸酯的原料,會得到高黏度的褐藻酸酯。若使用低分子的褐藻酸作為褐藻酸酯的原料,會得到低黏度的褐藻酸酯。 An alginate having a viscosity in the above range is obtained by adjusting the molecular weight of the alginic acid, which is a raw material. Specifically, it is obtained by using a low-molecular-weight alginic acid as a raw material of alginate according to a well-known method. For example, as a method for reducing the molecular weight of alginate, a method of decomposing a polymer of alginic acid by an enzyme (alginate lyase), and adding water of a polymer of alginic acid by acid or heat may be mentioned. Methods of decomposition, etc. If a high-molecular-weight alginic acid is used as a raw material of alginate, a high-viscosity alginate is obtained. If a low-molecular-weight alginic acid is used as a raw material of alginate, a low-viscosity alginate will be obtained.

本發明的褐藻酸酯的其他特性,在不阻礙本發明目的之範圍內並無特別限定,亦可具有任意的平均分子量及分子量分布等。 Other characteristics of the alginate of the present invention are not particularly limited as long as they do not hinder the object of the present invention, and they may have an arbitrary average molecular weight, molecular weight distribution, and the like.

作為本發明的褐藻酸酯,就方便取得、適合食用、容易發揮本發明效果這些觀點而言,較佳是褐藻酸丙二酯。又,作為本發明的褐藻酸酯,適合使用符合日本食品添加物公定書第八版所定基準的褐藻酸酯。 As the alginate of the present invention, propylene alginate is preferred from the viewpoints of being easily available, suitable for consumption, and easy to exhibit the effects of the present invention. In addition, as the alginate of the present invention, an alginate meeting the standards set forth in the Eighth Edition of the Japanese Food Additives Convention is suitably used.

本發明的油脂組成物,亦可含有1種以上的褐藻酸酯。本發明的油脂組成物含有數種褐藻酸酯時,各褐藻酸酯的含量,可依照欲獲得的酯化度與黏度來進行調整,油脂組成物中所含有的褐藻酸酯,是依照使整體的酯化度及黏度符合上述範圍的方式來進行調整。 The oil and fat composition of the present invention may contain one or more kinds of alginates. When the oil and fat composition of the present invention contains several kinds of alginates, the content of each alginate can be adjusted according to the degree of esterification and viscosity to be obtained. The alginate contained in the oil and fat composition is based on the whole The degree of esterification and viscosity are adjusted in such a manner as to conform to the above range.

(油脂) (grease)

作為本發明的油脂,並無特別限定,可使用通常供作食 用的油脂。例如,可舉出棕櫚油、棕櫚核油、椰子油、玉米油、棉籽油、大豆油、菜籽油、高芥酸菜籽油、芥花油、米油、葵花油、紅花油、花生油、芝麻油、橄欖油、可可脂、娑羅脂(sal fat)、牛脂、豬脂、乳脂、魚油等各種動植物性油脂。又,亦可將選自上述的各種動植物性油脂的1種或2種以上的動植物性油脂,視所需進行加工(氫化、酯交換、分離等),並將所得到的各種加工油脂作為本發明的油脂使用。上述的任一種油脂,可單獨使用,亦可將2種以上的油脂適當地調配作為混合油使用。本發明的油脂,亦可是乳化油脂。 The fats and oils of the present invention are not particularly limited, and can be generally used for food Used grease. For example, palm oil, palm kernel oil, coconut oil, corn oil, cottonseed oil, soybean oil, rapeseed oil, canola oil, canola oil, rice oil, sunflower oil, safflower oil, peanut oil, Various animal and vegetable fats such as sesame oil, olive oil, cocoa butter, sal fat, beef tallow, pork fat, milk fat, fish oil and the like. In addition, one or two or more kinds of animal and vegetable oils and fats selected from the above-mentioned various animal and vegetable oils and fats may be processed (hydrogenation, transesterification, separation, etc.) as necessary, and the obtained processed oils and fats may be used as the base Invention of grease. Any of the above-mentioned fats and oils may be used alone, or two or more kinds of fats and oils may be appropriately blended as a mixed oil. The fats and oils of the present invention may be emulsified fats and oils.

(油脂組成物的製造方法) (Manufacturing method of fat composition)

本發明的油脂組成物的製造方法,並無特別限制,可基於周知的油脂組成物的製造條件及製造方法來製造。例如,依照周知的方法,可藉由將本發明的褐藻酸酯與油脂混合,並進行適當的攪拌來製造本發明的油脂組成物。 The method for producing a fat or oil composition of the present invention is not particularly limited, and can be produced based on well-known production conditions and production methods for a fat or oil composition. For example, according to a well-known method, the alginate of the present invention can be mixed with fats and oils, and then appropriately stirred to produce the fat and oil composition of the present invention.

油脂組成物中的褐藻酸酯的含量,並無特別限定,相對於油脂組成物整體,較佳是0.1~10質量%,更佳是0.3~5.0質量%,最佳是0.5~3.0質量%。油脂組成物中的褐藻酸酯的含量,相對於油脂即便不是過度的量,依然可發揮本發明的效果。 The content of the alginate in the oil and fat composition is not particularly limited. It is preferably 0.1 to 10% by mass, more preferably 0.3 to 5.0% by mass, and most preferably 0.5 to 3.0% by mass relative to the entire oil and fat composition. The content of the alginate in the oil and fat composition can exhibit the effects of the present invention even if it is not an excessive amount with respect to the oil and fat.

油脂組成物中的油脂含量,並無特別限定,相對於油脂組成物整體,較佳是10~99質量%,更佳是30~90質量%,最佳是50~85質量%。若油脂組成物中所佔的油脂含量為上述範圍,則容易發揮本發明的效果。 The content of oil and fat in the oil and fat composition is not particularly limited, and is preferably 10 to 99% by mass, more preferably 30 to 90% by mass, and most preferably 50 to 85% by mass relative to the entire oil and fat composition. When the content of fats and oils in the fats and oils composition is in the above range, the effects of the present invention are easily exhibited.

本發明的油脂組成物中,依照所需,亦可含有褐藻 酸酯及油脂以外的成分(水、食鹽、乳化劑(卵磷脂、飽和脂肪酸單甘油酯等)、香料、酵素、糖分、呈味成分、增黏劑、抗氧化劑、色素等)。這些成分的種類及添加量等,可依照所欲獲得的效果來適當地調整。 The oil and fat composition of the present invention may further contain brown algae as required. Ingredients (water, salt, emulsifiers (lecithin, saturated fatty acid monoglycerides, etc.), flavors, enzymes, sugars, flavor components, thickeners, antioxidants, pigments, etc.) other than esters and fats. The type and addition amount of these components can be appropriately adjusted according to the desired effect.

油脂組成物中含有褐藻酸酯及油脂以外的成分時,本發明的油脂組成物,可為將油相(含有褐藻酸酯、油脂及油溶性成分的狀態)與水相(含有水及水溶性成分的狀態)進行乳化的油脂組成物(意即,乳化油脂組成物),亦可為由油相所成之物。作為乳化油脂組成物,可舉出人造奶油(margarine)、食用塗脂(fat spread)等。作為由油相而成的油脂組成物,可舉出烤酥油(shortening)等。若褐藻酸酯為水合狀態,被認為容易發揮本發明的效果,因此,本發明的油脂組成物,較佳是乳化油脂組成物,特佳是人造奶油及食用塗脂。 When the oil and fat composition contains components other than alginate and oil and fat, the oil and fat composition of the present invention may be an oil phase (a state containing alginate, oil and oil-soluble components) and an aqueous phase (containing water and water-soluble The state of the components), which is an oil and fat composition to be emulsified (that is, an emulsified oil and fat composition), may be an oil phase. Examples of the emulsified oil and fat composition include margarine, edible fat spread, and the like. Examples of the oil and fat composition composed of an oil phase include baking shortening and the like. If the alginate is in a hydrated state, it is considered that the effects of the present invention are easily exhibited. Therefore, the fat and oil composition of the present invention is preferably an emulsified fat and oil composition, and particularly preferably margarine and edible fat.

油脂組成物中含有褐藻酸酯及油脂以外的成分時,例如可藉由下述的方法來製造本發明的油脂組成物或乳化油脂組成物:將油脂與油溶性成分(卵磷脂、飽和脂肪酸單甘油酯等)混合溶解,再使褐藻酸酯分散於其中,製造油脂組成物的方法;將油脂與油溶性成分混合溶解,再使褐藻酸酯分散於其中調製油相,藉由將所得到的油相與另外調製的水相混合乳化,製造乳化油脂組成物的方法。 When an oil or fat composition contains components other than alginate and oil or fat, the oil or fat composition or emulsified oil or fat composition of the present invention can be produced by, for example, the following method: oil and fat and oil-soluble components (lecithin, saturated fatty acid monohydrate) Glyceride, etc.) mixed and dissolved, and then dispersing alginate therein to produce a fat and oil composition; mixing and dissolving oil and fat and an oil-soluble component, and dispersing alginate in the oil phase to prepare an oil phase; A method for producing an emulsified oil-fat composition by emulsifying an oil phase and a water phase prepared separately.

油脂組成物具有可塑性時,較佳的是,於調製油相後或是於將油相與水相混合乳化後,進行冷卻,使油脂組成物可塑化。冷卻條件,較佳是-0.5℃/分以上,更佳是-5℃/分以上。油脂組成物的冷卻,相較於緩慢冷卻的方式, 以急速冷卻的方式為佳。作為用來冷卻所使用的機器,可舉出密閉型連續式管式冷卻機、人造奶油製造機(螺旋式熱交換器(votator)、配合器(combinator)、刮板式熱交換器(Perfector)等),板型熱交換機等。此外,亦可使用開放型的Dia冷卻器(Diacooler)與人造奶油製造器(Complector)的組合,作為用來冷卻的機器。 When the fat or oil composition has plasticity, it is preferred that after the oil phase is prepared or after the oil phase and the water phase are mixed and emulsified, cooling is performed to plasticize the fat and oil composition. The cooling condition is preferably -0.5 ° C / min or more, and more preferably -5 ° C / min or more. Cooling of grease composition, compared to slow cooling, It is better to use rapid cooling. Examples of the equipment used for cooling include a closed continuous tube cooler, a margarine maker (a spiral heat exchanger (votator), a combiner, a scraper heat exchanger (Perfector), etc.) ), Plate heat exchangers, etc. In addition, a combination of an open type Diacooler and a margarine maker (Complector) may be used as a device for cooling.

於調製油相後或是混合乳化油相與水相後,亦可對油脂組成物進行殺菌處理。作為殺菌的方法,並無特別限定,可舉出使用油槽的分批方式、使用板型熱交換機或刮取式熱交換機的連續方式。 After the oil phase is prepared or the emulsified oil phase and the water phase are mixed, the oil and fat composition may be sterilized. The method of sterilization is not particularly limited, and examples thereof include a batch method using an oil tank, and a continuous method using a plate-type heat exchanger or a scraped heat exchanger.

(小麥膨化食品) (Wheat puffed food)

本發明的油脂組成物,由於可將良好的份量感、柔軟感及濕潤感,平衡地賦予食品等,因此適合使用在製造這些要求外觀性與口感的食品等。小麥膨化食品是特別要求具有優異的份量感、柔軟感及濕潤感的食品,因此本發明的油脂組成物,特別適合用於小麥膨化食品的製造。因此,本發明的油脂組成物,可適合使用作為小麥膨化食品用油脂組成物。 Since the fat and oil composition of the present invention can impart a good feeling of portion, softness, and moistness to foods and the like in balance, it is suitable for use in the production of foods and the like that require appearance and texture. The wheat puffed food is a food which is particularly required to have an excellent portion feeling, softness, and moist feeling. Therefore, the oil-fat composition of the present invention is particularly suitable for the production of wheat puffed food. Therefore, the oil-fat composition of this invention can be used suitably as an oil-fat composition for wheat puffed foods.

本發明的「小麥膨化食品」是指,於穀物粉(典型如麵粉等)中,加入水、食鹽,並依照所需加入糖類、乳製品、酵母、蛋類、添加物等,調製出經捏揉而成的生麵團後,再將生麵團進行塑形及烘烤所製造的食品。添加有本發明的油脂組成物的小麥膨化食品,除了加入本發明的油脂組成物作為生麵團成分這一點外,其餘部分可基於周知的製造方法來製造。此外,本發明的「添加」是意指,於小麥膨化食品中, 作為該食品的原料包含本發明的油脂組成物,製造小麥膨化食品時,即使失去油脂組成物中的一部分成分(水分等),所得到的小麥膨化食品仍稱為「添加本發明的油脂組成物的小麥膨化食品」。 The "wheat puffed food" of the present invention refers to adding water and salt to cereal flour (typically flour, etc.), and adding sugars, dairy products, yeast, eggs, additives, etc. as required to prepare a kneaded dough. After kneading the dough, the dough is shaped and baked. The wheat puffed food to which the fat and oil composition of the present invention is added can be produced based on a well-known manufacturing method, except that the fat and oil composition of the present invention is added as a dough ingredient. In addition, the "addition" of the present invention means that in wheat puffed food, The raw material of this food contains the oil-fat composition of the present invention. When wheat puffed foods are manufactured, even if some of the components (moisture, etc.) in the oil-fat composition are lost, the obtained wheat puffed food is still called "added with the oil-fat composition of the present invention Wheat puffed food. "

相對於小麥膨化食品,本發明的油脂組成物的添加量,並無特別限定,例如,相對於小麥膨化食品的生麵團的總量,可添加本發明的油脂組成物1~40質量%。 The amount of the fat composition of the present invention added to the wheat puffed food is not particularly limited. For example, the fat composition of the present invention may be added in an amount of 1 to 40% by mass based on the total amount of the dough of the wheat puffed food.

作為小麥膨化食品的例子,可舉出如麵包類、蛋糕類、烘培點心類等。麵包類可舉出吐司麵包、特殊麵包、調理麵包(菜餚麵包)、甜點麵包、酥皮麵包製品等。這些麵包類,亦可調製作為高含水麵包。作為吐司麵包,可舉出白吐司、黑麥吐司、雜糧吐司、麵包捲(餐包、奶油捲餐包、圓形麵包等)。作為特殊麵包,可舉出瑪芬等。作為調理麵包(菜餚麵包),可舉出熱狗麵包、漢堡等。作為甜點麵包,可舉出紅豆麵包、果醬麵包、克林姆麵包、菠蘿麵包、糖霜麵包捲等。作為酥皮麵包製品,可舉出可頌麵包、丹麥麵包、派等。作為蛋糕類,可舉出海綿蛋糕、戚風蛋糕、蛋糕捲、法式海綿小餅、磅蛋糕、點心蛋糕等。作為烘培點心類,可舉出餅乾、小西點等。 Examples of wheat puffed foods include breads, cakes, baked goods, and the like. Examples of the bread include toast bread, special bread, prepared bread (dish bread), dessert bread, and puff pastry products. These breads can also be prepared as high-moisture bread. Examples of toast bread include white toast, rye toast, multi-grain toast, and bread rolls (meal packs, cream roll meal packs, round breads, and the like). Examples of the special bread include muffin. Examples of the prepared bread (dish bread) include hot dog bread and burger. Examples of the dessert bread include red bean bread, jam bread, klimb bread, pineapple bread, and frosted bread rolls. Examples of the pastry bread products include chanter bread, Danish bread, and pie. Examples of cakes include sponge cakes, chiffon cakes, cake rolls, French sponge cakes, pound cakes, and dessert cakes. Examples of the baked confectionery include biscuits and pastries.

本發明的「高含水麵包」是指,相較於一般的麵包類,麵包生麵團中的水分(水、溫水等)的添加量較多的麵包。本發明中,若調製高含水麵包作為小麥膨化食品,可得到柔軟度特別優異的小麥膨化食品。高含水麵包中,麵包生麵團中的水分的添加量,雖然會隨著所使用的穀物粉或其他原料 的種類與添加量、製造時的溫度等的製造環境而有所變化,但通常相較於一般麵包中的水分的添加量,高含水麵包中的水分的添加量,相對於穀物粉的質量,是多出1~12質量%。作為一般的麵包生麵團中的水分的添加量,舉例來說,相對於穀物粉的質量,吐司中水分的添加量是60~70質量%,奶油餐包中水分的添加量是35~60質量%,法式海綿小餅中水分的添加量是55~73質量%,甜點麵包中是40~55質量%。吐司的製造中,一般的麵包生麵團中的水分的添加量,相對於穀物粉的質量%為60~70質量%,但在製造作為高含水麵包時,水分的添加量可增加至71~82質量%為止。此外,「麵包生麵團中的水分的添加量」是指,相對於穀物粉的質量,麵包生麵團中所加入的水分的質量比例。「麵包生麵團中所加入的水分」是指,調製麵包生麵團中,作為原料水所使用的水或溫水等,並不包含源自其他的原料(例如乳製品、蛋類)的水分。 The "high-water bread" of the present invention refers to bread in which the amount of water (water, warm water, etc.) added to bread dough is larger than that of ordinary breads. In the present invention, if a high-moisture bread is prepared as a wheat puffed food, a wheat puffed food having particularly excellent softness can be obtained. In high-moisture bread, the amount of water in the bread dough is added, although it may vary with the grain flour or other ingredients used. The type and the amount of addition, the manufacturing temperature, and other manufacturing environments vary, but usually compared to the amount of water in ordinary bread, the amount of water in high-water bread is relative to the quality of grain flour, It is 1 to 12% more by mass. As the amount of water added in general bread dough, for example, the amount of water added in toast is 60 to 70% by mass relative to the quality of cereal flour, and the amount of water added in butter packs is 35 to 60. Mass%, the amount of water in French sponge eclairs is 55-73% by mass, and dessert bread is 40-55% by mass. In the production of toast, the amount of water added to general bread dough is 60 to 70% by mass relative to the mass% of cereal flour. However, the amount of water added can be increased to 71 ~ Up to 82% by mass. In addition, the "added amount of water in the bread dough" refers to the mass ratio of the water added to the bread dough with respect to the quality of the cereal flour. "Moisture added to bread dough" refers to water or warm water used as raw water in the preparation of bread dough, and does not include moisture derived from other raw materials (for example, dairy products, eggs).

本發明的褐藻酸酯,並非直接添加於小麥膨化食品的生麵團,而是作為油脂組成物中的調配成分來添加於生麵團,藉此可對小麥膨化食品賦予特別優異的份量感。小麥膨化食品的份量感的程度,可使用周知的體積計測機,藉由算出小麥膨化食品的比容積來決定。小麥膨化食品的柔軟感,是藉由感官評鑑,以判定小麥膨化食品的柔軟度(或硬度)來決定。小麥膨化食品的濕潤感,藉由感官評鑑,以判定小麥膨化食品的乾燥程度(或濕潤程度)來決定。 The alginate of the present invention is not directly added to the dough of wheat puffed food, but is added to the dough as a blending ingredient in a fat and oil composition, whereby a particularly excellent portion feel can be imparted to the wheat puffed food. The degree of weight feeling of the wheat puffed food can be determined by calculating the specific volume of the wheat puffed food using a known volume measuring machine. The softness of wheat puffed food is determined by sensory evaluation to determine the softness (or hardness) of wheat puffed food. The moist feeling of wheat puffed food is determined by sensory evaluation to determine the dryness (or wetness) of wheat puffed food.

(實施例) (Example)

以下,藉由實施例來更詳細說明本發明,但本發明並不限於此。 Hereinafter, the present invention will be described in more detail through examples, but the present invention is not limited thereto.

[調製例1:調製褐藻酸酯] [Preparation example 1: Preparation of alginate]

將由褐藻類精製而成的褐藻酸,依照周知的方法,藉由酸進行水解,而得到9種褐藻酸。分別將所得到的褐藻酸,依照周知的方法,於高壓滅菌釜中,50~70℃、2~12小時的條件下,與環氧丙烷進行酯化反應,而得到9種褐藻酸丙二酯。 Nine kinds of alginic acid were obtained by hydrolyzing the alginic acid refined from the alginate in accordance with a known method. The obtained alginic acid was respectively esterified with propylene oxide in an autoclave at 50 to 70 ° C for 2 to 12 hours in accordance with a well-known method to obtain 9 types of alginic acid propylene glycolate. .

分別將所得到的褐藻酸丙二酯,基於下述的方法來求得酯化度及1質量%的水溶液黏度。其結果如表1所示。此外,以下表中的「褐藻酸酯」是指褐藻酸丙二酯。 The degree of esterification and the viscosity of an aqueous solution of 1% by mass of the obtained propylene glycol alginate were determined based on the following methods, respectively. The results are shown in Table 1. The "alginate" in the following table refers to propylene alginate.

(酯化度) (Degree of esterification)

依照日本食品添加物公定書第8版的「褐藻酸丙二酯純度測驗(1)」為基準,測定各種褐藻酸丙二酯的酯化度。 The degree of esterification of various types of propylene glycol alginate was measured in accordance with the "Proton Alginate Purity Test (1)" of the 8th edition of the Japanese Food Additives Convention.

(黏度) (Viscosity)

使用黏度計(東京計器股份有限公司製、型號:TVB-10M VISCOMETER(MODEL:BM))的旋轉器No.1(旋轉數為30rpm),測定各種褐藻酸丙二酯的1質量%水溶液於20℃時的黏度。 Using a viscometer (manufactured by Tokyo Keiki Co., Ltd., model: TVB-10M VISCOMETER (MODEL: BM)), the spinner No. 1 (the number of rotations was 30 rpm) was used to measure a 1% by mass aqueous solution of propylene glycol alginate at 20 Viscosity at ℃.

分別將表1中的1~9號的褐藻酸丙二酯,提供作為以下的實施例及比較例使用。此外,表1中,3~8號的褐藻酸丙二酯相當於本發明的褐藻酸酯。 The propylene glycol alginate Nos. 1 to 9 in Table 1 were provided as examples and comparative examples below. In addition, in Table 1, the propylene-alginate number 3-8 is equivalent to the alginate of this invention.

[調製例2:調製含有褐藻酸酯的油脂組成物(食用塗脂)] [Preparation Example 2: Preparation of alginate-containing oil and fat composition (edible grease)]

使用表1中任一種褐藻酸丙二酯,基於表2的配方,將油脂(菜籽油及棕櫚油)及乳化劑(卵磷脂及飽和脂肪酸單甘油酯)融解混合,並使褐藻酸丙二酯分散於其中來調製油相。接下來,將食鹽溶於水中調製水相。混合所得到的油相及水相,進行預備乳化,獲得預備乳化物。將所得到的預備乳化物,依照常法,使用配合器將其急速冷卻進行可塑化,而得到含有1質量%褐藻酸丙二酯之油脂組成物(食用塗脂)。 Using any of the alginic acid alginate in Table 1, based on the formula in Table 2, melt the fats (rapeseed oil and palm oil) and emulsifier (lecithin and saturated fatty acid monoglyceride), and make the alginic acid malonate The ester is dispersed therein to prepare an oil phase. Next, the salt was dissolved in water to prepare an aqueous phase. The obtained oil phase and water phase were mixed and pre-emulsified to obtain a pre-emulsified product. The obtained preliminary emulsion was rapidly cooled and plasticized using a compounder in accordance with a conventional method, thereby obtaining a fat and oil composition (edible grease) containing 1% by mass of propylene alginate.

此外,表2中的各種材料詳述如下。 In addition, various materials in Table 2 are detailed below.

菜籽油:日清奧利友集團股份有限公司製,商品名「日清芥花籽油」。 Rapeseed oil: manufactured by Nissin Olivier Group Co., Ltd. under the trade name "Nissin Canola Oil".

棕櫚油:日清奧利友集團股份有限公司製造品。 Palm oil: manufactured by Nissin Olivier Group Co., Ltd.

飽和脂肪酸單甘油酯:理研vitamin股份有限公司製,商品名「Emaruji-P-100」。 Saturated fatty acid monoglyceride: manufactured by Riken Vitamin Co., Ltd. under the trade name "Emaruji-P-100".

卵磷脂:日清奧利友集團股份有限公司製,商品名「Lecithin DX」。 Lecithin: "Lecithin DX" manufactured by Nissin Olivier Group Co., Ltd.

[製造例1:吐司的製造(70%中種法)-I] [Manufacturing example 1: Toast manufacturing (70% medium seed method) -I]

使用上述的調製例2所調製的食用塗脂,基於表3的生麵團配方及表4的步驟,製造方型吐司及圓頂型吐司。又,除了油脂組成物中不含有褐藻酸丙二酯這一點以外,其餘皆基於表3的生麵團配方及表4的步驟,製造用來對照的方型吐司及圓頂型吐司。下述表中的「對照」,是指對照的方型吐司及圓頂型吐司。 Using the edible fat prepared in Preparation Example 2 described above, based on the dough recipe in Table 3 and the procedures in Table 4, a square toast and a dome-shaped toast were produced. In addition, except for the fact that propylene glycol alginate is not contained in the oil and fat composition, the square toast and the dome-shaped toast for comparison are produced based on the dough recipe of Table 3 and the steps of Table 4. The "control" in the following table refers to a square toast and a dome toast for comparison.

此外,下述表中的「穀物粉%」是表示,將穀物粉的質量(本例中是高筋麵粉的總量)設為100時,穀物粉以外的材料相對於穀物粉的比例。 The "grain flour%" in the following table indicates the ratio of materials other than grain flour to grain flour when the mass of the grain flour (the total amount of high-gluten flour in this example) is 100.

此外,表3中的各種材料詳述如下。 In addition, the various materials in Table 3 are detailed below.

高筋麵粉:日清製粉股份有限公司製,商品名「camellia」。 High-gluten flour: manufactured by Nisshin Milling Co., Ltd. under the trade name "camellia".

酵母:Oriental酵母工業股份有限公司製,商品名「Regular yeast」。 Yeast: Made by Oriental Yeast Industry Co., Ltd. under the trade name "Regular yeast".

脫脂奶粉:森永乳業股份有限公司製,商品名「脫脂粉 乳」。 Skimmed milk powder: made by Morinaga Milk Industry Co., Ltd. milk".

油脂組成物:以上述調製例2所調製的食用塗脂。 Oil and fat composition: Edible grease prepared by the above-mentioned Preparation Example 2.

[吐司的評價] [Evaluation of Toast]

分別對上述所製成的吐司,以下述的方法來評價份量 感、柔軟感、及濕潤感。 For the toasts prepared as described above, the portions were evaluated in the following manner. Feel, softness, and wetness.

(份量感的評價) (Evaluation of weight sense)

分別對上述所製造的圓頂型吐司,於烘烤完成的一天後,以下述的方法來評價其份量感。 For each of the dome-shaped toasts produced as described above, one day after the baking was completed, the feeling of weight was evaluated by the following method.

使用超高速雷射體積計測/非接觸CCD狹縫雷射掃描方式(ASTEX股份有限公司製,商品名「Selnac-WinVM2000」),依照下述數式,算出各吐司的比容積。 The ultra-high-speed laser volume measurement / non-contact CCD slit laser scanning method (manufactured by ASTEX Corporation, trade name "Selnac-WinVM2000") was used to calculate the specific volume of each toast according to the following formula.

比容積=烘烤完成後的吐司的體積(cm3)/烘烤完成後的生麵團重量(g) Specific volume = volume of toast after baking (cm 3 ) / weight of dough after baking (g)

接下來,將各吐司的比容積,除以對照的圓頂型吐司的比容積,作為比容積的比值算出,並依照下述基準來進行評價。其結果如表5~7所示。此外,下述表中的「-」是表示未進行評價。 Next, the specific volume of each toast was divided by the specific volume of the dome-shaped toast of the control, and the specific volume was calculated as the ratio of the specific volume, and evaluated according to the following criteria. The results are shown in Tables 5 to 7. In addition, "-" in the following table means that evaluation was not performed.

◎:比容積的比值為1.02以上 ◎: The ratio of specific volume is 1.02 or more

○:比容積的比值為1.01以上且未滿1.02 ○: The ratio of specific volume is 1.01 or more and less than 1.02

△:比容積的比值為1.00以上且未滿1.01 △: The ratio of specific volume is 1.00 or more and less than 1.01

×:比容積的比值未滿1.00 ×: The ratio of the specific volume is less than 1.00

(柔軟感) (Soft feeling)

分別對上述所製造的方型吐司,於烘烤完成的一天後,進行感官評價。將各種吐司的柔軟感,依照下述的基準來評價。其結果如表5~7所示。 The square toasts manufactured above were subjected to sensory evaluation one day after the baking was completed. The softness of various toasts was evaluated in accordance with the following criteria. The results are shown in Tables 5 to 7.

◎:極為柔軟 ◎: Extremely soft

○:柔軟 ○: Soft

△:稍硬 △: Slightly hard

×:硬 ×: Hard

(濕潤感) (Wetness)

分別對上述所製造的方型吐司,於烘烤完成的一天後,進行感官評價。將各種吐司的濕潤感,依照下述的基準來評價。其結果如表5~7所示。 The square toasts manufactured above were subjected to sensory evaluation one day after the baking was completed. The moist feeling of various toasts was evaluated in accordance with the following criteria. The results are shown in Tables 5 to 7.

◎:極為濕潤 ◎: Extremely moist

○:有濕潤感 ○: Moist feeling

△:口感稍乾 △: slightly dry

×:口感為乾 ×: Dry texture

(綜合評價) (Overview)

基於上述3種的評價結果(份量感、柔軟感及濕潤感),對各吐司進行綜合評價。 Based on the above three kinds of evaluation results (a feeling of weight, a feeling of softness, and a feeling of wetness), each toast was comprehensively evaluated.

◎:全部的評價結果為○以上 :: All evaluation results were ○ or more

○:全部的評價中,沒有×,且有一個△ ○: Among all the evaluations, there is no × and there is one △

×:評價結果的任一者皆為×,或是有2個以上的△ ×: Any of the evaluation results is ×, or there are two or more △

如表5~7所示,可知含有本發明的油脂組成物的吐司,綜合評價為「○」以上,份量感、柔軟感及濕潤感具有良好的平衡,且任一者皆為良好。特別是,若褐藻酸酯的酯化度為43.0~63.9的範圍內,則份量感、柔軟感及濕潤感的任一者都極為良好。 As shown in Tables 5 to 7, it can be seen that the toast containing the oil-and-fat composition of the present invention has a comprehensive evaluation of "○" or more, and has a good balance of weight, softness, and wetness, and all of them are good. In particular, when the degree of esterification of alginate is in the range of 43.0 to 63.9, any of the feeling of weight, softness, and moistness is extremely good.

[調製例3:調製含有褐藻酸酯的油脂組成物(烤酥油)] [Preparation Example 3: Preparation of alginate-containing fat and oil composition (grilled shortening)]

使用表1中的「4」的褐藻酸丙二酯,基於表8的配方,將油脂(菜籽油及棕櫚油)及乳化劑(卵磷脂及飽和脂肪酸單甘油酯)融解混合,並使褐藻酸丙二酯分散於其中來調製油相。 接下來,將所得到的油相,依照常法,使用配合器將其急速冷卻進行可塑化,而得到含有1質量%褐藻酸丙二酯之油脂組成物(烤酥油)。各種材料的詳細資料,與調製例2相同。 Using the "4" propylene glycol alginate in Table 1, based on the formula in Table 8, the fats (rapeseed oil and palm oil) and the emulsifier (lecithin and saturated fatty acid monoglyceride) were melted and mixed, and the brown algae The propylene acid ester is dispersed therein to prepare an oil phase. Next, the obtained oil phase was rapidly cooled and plasticized using a compounder in accordance with a conventional method, thereby obtaining a fat and oil composition (roasted shortening) containing 1% by mass of propylene alginate. The details of each material are the same as those in Preparation Example 2.

[製造例2:吐司的製造(70%中種法)-II] [Manufacturing example 2: Toast manufacturing (70% medium seed method) -II]

使用表1中的「4」的褐藻酸丙二酯,除了表3中的油脂組成物是以上述調製例3所調製的烤酥油這一點之外,其餘皆基於表3的生麵團配方及表4的步驟,來製造出含有烤酥油的方型吐司及圓頂型吐司。 The "4" propylene alginate in Table 1 was used, except that the fat composition in Table 3 was the baking ghee prepared in the above Preparation Example 3, and the rest were based on the dough recipe and table in Table 3. 4 steps to make square toast and dome-shaped toast containing roasted ghee.

又,使用不含有褐藻酸丙二酯的油脂組成物,且將褐藻酸丙二酯與油脂組成物分開,直接添加至生麵團來製造吐司。具體而言,除了從表2的配方中剔除褐藻酸丙二酯的這一點之外,其餘皆與上述調製例2同樣地調製出油脂組成物(食用塗脂)。使用所得到的油脂組成物,基於表3的生麵團配方及表4的步驟,來製造出方型吐司及圓頂型吐司。褐藻酸丙二酯是使用表1中的「4」,於表4中的「再混揉步驟」的「混拌」步驟時,將與上述的實施例及比較例的生麵團中的褐藻酸丙二酯含量等量(相對於穀物粉0.1%)的該褐藻酸丙二酯,添加至生麵團中。 Further, a toast was produced by using an oil and fat composition not containing propylene alginate, separating the propylene and alginate from the oil and fat composition, and directly adding it to the dough. Specifically, the oil-fat composition (edible grease) was prepared in the same manner as in the above-mentioned Preparation Example 2 except that the propylene glycol alginate was excluded from the formula in Table 2. Using the obtained fat and oil composition, based on the dough recipe of Table 3 and the procedure of Table 4, a square toast and a dome-shaped toast were produced. When using "4" in Table 1 and "mixing" step in the "re-kneading step" in Table 4, the alginic acid is the same as the alginic acid in the dough of the above examples and comparative examples. The propylene glycol alginate was added to the dough with an equal amount of propylene glycol (0.1% with respect to the cereal flour).

分別對所製造的吐司,與上述「吐司的評價」相同 的方式,對份量感、柔軟感及濕潤感進行評價,進而進行綜合評價。其結果示於表9。此外,表9中的「(烤酥油)」是指,上述吐司中,含有烤酥油的吐司。又,表9中的「(直接添加)」是指,上述吐司中,將褐藻酸丙二酯直接添加至生麵團所製造的吐司。 Each of the toasts produced is the same as the above "Evaluation of Toast" Method to evaluate the feeling of weight, softness, and wetness, and then comprehensively evaluate. The results are shown in Table 9. In addition, "(grilled shortening)" in Table 9 means the toast which contains the grilled shortening among the said toast. In addition, the "(direct addition)" in Table 9 means the toast manufactured by adding the alginate directly to the dough in the said toast.

若比較使用油相而成油脂組成物的烤酥油之實施例7(表9),與使用乳化油脂組成物的食用塗脂之實施例3(表6),雖然兩者所含的褐藻酸酯是同一種,前者在份量感及柔軟感卻稍顯低劣。因此,本發明的油脂組成物,調製成乳化油脂組成物的話,被認為更容易發揮本發明的效果。乳化油脂組成物更容易發揮本發明的效果的理由,被認為是與褐藻酸酯在乳化油脂組成物中進行水合作用有關。 Comparing Example 7 (Table 9) of grilled shortening with an oil and fat composition using the oil phase with Example 3 (Table 6) of edible fat coating using an emulsified oil and fat composition, although the alginate contained in both It is the same type, but the former is slightly inferior in weight and softness. Therefore, it is considered that the effect of the present invention is more easily exhibited when the fat and oil composition of the present invention is prepared as an emulsified fat and oil composition. The reason why the emulsified oil and fat composition is more likely to exert the effects of the present invention is considered to be related to the hydration of alginate in the emulsified oil and fat composition.

又,本發明的褐藻酸酯,能賦予麵包更佳的份量感與柔軟感的方式,並非直接添加於生麵團中,而是藉由調配於油脂組成物中來使用。 In addition, the alginate of the present invention can be used to impart better bread feel and softness to the bread, not by directly adding it to the dough, but by blending it in a fat or oil composition.

[製造例3:甜點麵包的製造(70%中種法)] [Manufacturing example 3: Production of dessert bread (70% medium seed method)]

使用表1中的「4」的褐藻酸丙二酯,並基於表10的生 麵團配方及表11的步驟,來製造甜點麵包。又,除了油脂組成物中不含褐藻酸丙二酯這一點之外,其餘皆基於表10的生麵團配方及表11的步驟,來製造對照的甜點麵包。 The "4" propylene alginate in Table 1 was used, and Dough recipe and steps in Table 11 to make dessert bread. In addition, except for the fact that propylene glycol alginate is not contained in the fat and oil composition, the rest is based on the dough recipe in Table 10 and the steps in Table 11 to produce a control dessert bread.

此外,表10中的各種材料詳述如下。 In addition, the various materials in Table 10 are detailed below.

高筋麵粉:日清製粉股份有限公司製,商品名「camellia」。 High-gluten flour: manufactured by Nisshin Milling Co., Ltd. under the trade name "camellia".

酵母:Oriental酵母工業股份有限公司製,商品名「Regular yeast」。 Yeast: Made by Oriental Yeast Industry Co., Ltd. under the trade name "Regular yeast".

脫脂奶粉:森永乳業股份有限公司製,商品名「脫脂粉乳」。 Skimmed milk powder: Made by Morinaga Milk Industry Co., Ltd., trade name "skimmed powder milk"

油脂組成物:以上述調製例2所調製的食用塗脂。 Oil and fat composition: Edible grease prepared by the above-mentioned Preparation Example 2.

含有本發明的油脂組成物的甜點麵包,相較於對照的甜點麵包,更具有份量感。又,若實際品嘗,相對於對照的甜點麵包有較硬、乾的口感,含有本發明的油脂組成物的甜點麵包,具有良好的柔軟感,且強烈地感受到濕潤感。 The dessert bread containing the oil-and-fat composition of the present invention has a heavier feel than the control dessert bread. In addition, if it is actually tasted, it has a hard and dry texture compared with the control dessert bread, and the dessert bread containing the fat and oil composition of the present invention has a good soft feeling and a strong moist feeling.

[製造例4:吐司(高含水麵包)的製造(70%中種法)-III] [Manufacturing Example 4: Production of Toast (High Moisture Bread) (70% Medium Seed) -III]

添加表1中的「5」的褐藻酸丙二酯,使用與上述調製例2相同的方式所調製而成的食用塗脂(油脂組成物),基於表12的生麵團配方及表4的步驟,來調製麵包生麵團,該麵包生麵團添加有相對於穀物粉(高筋麵粉)的總量為80質量%的水,來製造高含水麵包。又,除了油脂組成物中不含褐藻酸丙二酯這一點之外,其餘皆基於表12的生麵團配方及表4的步驟,來製造對照的高含水麵包。以下,表格中的「對照」是指,對照的高含水麵包。 Add propylene alginate "5" in Table 1 and use the edible fat (oil composition) prepared in the same manner as in Preparation Example 2 above, based on the dough recipe in Table 12 and the procedures in Table 4 , To prepare a bread dough, the bread dough is added with 80% by mass of water with respect to the total amount of grain flour (high-gluten flour) to produce a highly water-containing bread. In addition, except for the fact that propylene glycol alginate was not contained in the fat and oil composition, the other ingredients were manufactured based on the dough recipe of Table 12 and the procedures of Table 4 to produce a comparatively high-water bread. In the following, the "control" in the table refers to a high-water bread.

此外,表10中的各種材料詳述如下。 In addition, the various materials in Table 10 are detailed below.

高筋麵粉、酵母及脫脂奶粉:使用與製造例3相同之物。 High-gluten flour, yeast, and skimmed milk powder: The same thing as in Production Example 3 was used.

生麵團改良劑:Oriental酵母工業股份有限公司製,商品名「C Oriental Food」。 Dough conditioner: Made by Oriental Yeast Industry Co., Ltd. under the trade name "C Oriental Food".

[高含水麵包的評價] [Evaluation of high moisture bread]

分別將所製造的高含水麵包,與上述[吐司的評價]同樣地對份量感及濕潤感進行評價,進而進行綜合評價。此外,關於柔軟感,基於下述的基準來進行評價。其結果如表13所示。 Each of the produced high-moisture breads was evaluated for weight feeling and moist feeling in the same manner as the above [Evaluation of Toast], and then comprehensively evaluated. The soft feeling was evaluated based on the following criteria. The results are shown in Table 13.

(柔軟感) (Soft feeling)

分別對上述所製造的高含水麵包,於烘烤完成的一天後,進行感官評價。將各高含水麵包的柔軟感,依照下述的基準來評價。 The highly watered breads produced above were subjected to sensory evaluation one day after the baking was completed. The softness of each high water-containing bread was evaluated according to the following criteria.

◎:極為柔軟 ◎: Extremely soft

○:柔軟 ○: Soft

△:稍有黏牙感 △: slightly sticky tooth feel

×:有黏牙感 ×: Sticky tooth feel

如表13所示,對照的高含水麵包缺乏柔軟感,且具有稍顯粗糙的口感,相對於此,含有本發明的油脂組成物的高含水麵包,除了具有較良好的份量感及優異的濕潤感,亦具有優異的柔軟感。 As shown in Table 13, the comparative high-moisture bread lacks softness and has a slightly rough texture. In contrast, the high-moisture bread containing the oil-and-fat composition of the present invention has a good feeling of weight and excellent moistness. It also has excellent soft feel.

Claims (6)

一種油脂組成物,其含有酯化度為49%以上且未滿75%的褐藻酸酯。A fat and oil composition containing an alginate having a degree of esterification of 49% or more and less than 75%. 如請求項1所述之油脂組成物,其中,前述的油脂組成物是乳化油脂組成物。The fat or oil composition according to claim 1, wherein the fat or oil composition is an emulsified fat or oil composition. 一種小麥膨化食品,其添加有如請求項1或2所述之油脂組成物。A wheat puffed food added with the fat and oil composition according to claim 1 or 2. 如請求項3所述之小麥膨化食品,其中,前述小麥膨化食品是高含水麵包。The wheat puffed food according to claim 3, wherein the wheat puffed food is a high-moisture bread. 一種油脂組成物的製造方法,其包含將酯化度為49%以上且未滿75%的褐藻酸酯與油脂加以混合的步驟,且前述褐藻酸酯的1質量%水溶液於20℃時的黏度是30mPa.S以上。A method for producing a fat and oil composition, comprising a step of mixing alginate having an esterification degree of 49% or more and less than 75% with fats and oils, and a viscosity of the 1% by mass aqueous solution of the alginate at 20 ° C It is 30mPa. S or more. 一種褐藻酸酯用於小麥膨化食品用的油脂組成物之用途,該褐藻酸酯的酯化度為23%以上且未滿75%。An alginate is used for the fat composition for wheat puffed food, and the degree of esterification of the alginate is 23% or more and less than 75%.
TW103133044A 2013-09-30 2014-09-24 Oil and fat composition, wheat puffed food to which the oil and fat composition is added, and method for producing the oil and fat composition TWI665966B (en)

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US3574641A (en) * 1968-03-29 1971-04-13 Kelco Co High neutralized propylene glycol alginate in french dressing
JP2012024001A (en) * 2010-07-22 2012-02-09 Kao Corp Bakery product

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US3574641A (en) * 1968-03-29 1971-04-13 Kelco Co High neutralized propylene glycol alginate in french dressing
JP2012024001A (en) * 2010-07-22 2012-02-09 Kao Corp Bakery product

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