JP6845075B2 - Small piece oil and fat composition for bakery - Google Patents

Small piece oil and fat composition for bakery Download PDF

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JP6845075B2
JP6845075B2 JP2017090164A JP2017090164A JP6845075B2 JP 6845075 B2 JP6845075 B2 JP 6845075B2 JP 2017090164 A JP2017090164 A JP 2017090164A JP 2017090164 A JP2017090164 A JP 2017090164A JP 6845075 B2 JP6845075 B2 JP 6845075B2
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oil
bakery
fat
dough
triglyceride
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JP2018186723A (en
JP2018186723A5 (en
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雅久 綿地
雅久 綿地
隆太 小中
隆太 小中
沼野 新一
新一 沼野
敏幸 廣川
敏幸 廣川
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Adeka Corp
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本発明は、ベーカリー生地に添加混合した場合に練り込まれにくく、また、添加したベーカリー生地のべたつきが抑えることのできるベーカリー用小片状油脂組成物に関する。 The present invention relates to a bakery small piece oil / fat composition that is difficult to knead when added to and mixed with a bakery dough and can suppress the stickiness of the added bakery dough.

ベーカリー生地製造における、マーガリンやショートニングを立方体、直方体、円柱状、アレイ型、薄片などの小片状に加工したベーカリー用小片状油脂組成物の使用方法としては、練りパイ生地やタルト生地のように、ベーカリー用小片状油脂組成物を小麦粉や水と共に混合後、ロールインしたり視認不可能なまで練り込んだりする方法が基本である。また、包餡機用の生地、あるいは食パン生地や菓子パン生地のような高水分の生地の場合は、練り上げた生地にベーカリー用小片状油脂組成物を分散させて油脂を生地中に視認可能な程度の粒を残す方法も行われる。
そして、ベーカリー用小片状油脂組成物を包餡機用の生地に使用した場合、包餡機内のアジテータ等により生地中の油脂粒の消失が防止され、食パン生地や菓子パン生地のような高水分の生地に使用した場合は、内相中に油脂粒に由来する油脂の局在化部分が分散した特異的なベーカリー製品が得られる(例えば特許文献1参照)。
In the production of bakery dough, the usage of the bakery small piece oil and fat composition obtained by processing margarine and shortening into small pieces such as cubes, squares, cylinders, arrays, and flakes is like kneaded pie dough and tart dough. In addition, the basic method is to mix the bakery fragmentary oil and fat composition with flour and water, and then roll it in or knead it until it is invisible. In the case of dough for bean paste machines, or high-moisture dough such as bread dough and sweet bread dough, the bakery piece-like fat and oil composition is dispersed in the kneaded dough so that the fat and oil can be visually recognized in the dough. There is also a method of leaving a degree of grain.
When the small piece of oil / fat composition for bakery is used for the dough for the bean paste machine, the agitator in the bean paste machine prevents the disappearance of the oil / fat particles in the dough, and the high moisture content such as bread dough and sweet bread dough. When used in the dough of the above, a specific bakery product in which localized portions of fats and oils derived from fats and oils are dispersed in the internal phase can be obtained (see, for example, Patent Document 1).

そして、この2種の使用方法に共通する小片状油脂組成物の必要特性は、ロールインあるいは分散時に生地中に容易に練り込まれて均質化しない程度の硬さを有することである。
そのため、これらの用途に適したものとするために、ベーカリー用小片状油脂組成物に高融点油脂を使用することが基本である。そのため、ベーカリー用小片状油脂組成物を使用して得られたベーカリー製品は口溶けが悪いものとなってしまう。
A necessary property of the small piece of oil / fat composition common to these two methods of use is that it has a hardness that is not easily kneaded into the dough at the time of roll-in or dispersion and is not homogenized.
Therefore, in order to make it suitable for these uses, it is basic to use a high melting point fat or oil in a small piece of fat or oil composition for bakery. Therefore, the bakery product obtained by using the bakery small piece oil / fat composition has poor melting in the mouth.

このような問題を避けるため、前者の使用方法の場合は、生地製造時に小麦粉や水などのベーカリー生地の原材料をあらかじめ冷却して用いる方法や、ベーカリー用小片状油脂組成物を冷凍して用いる方法により、高融点油脂を使用することなく、良好な口溶けのベーカリー製品を得ることが行われている。
ただし、この方法は後者の使用方法の場合は適用できない。これは、特に食パン生地や菓子パン生地は捏ね上げ時点の温度が25〜38℃と高温であることから、ここに冷凍状態の小片状油脂組成物を添加しても練り込まれ防止効果は殆ど期待できないし、パン生地の温度が下がってしまって、その後のホイロ工程での生地の伸びが悪くなり、得られるパンの品質が大きく低下してしまうためである。
また、前者の使用方法の場合でも、連続生産等の理由で冷却不可能な場合もある。
In order to avoid such problems, in the case of the former method, the raw materials of the bakery dough such as flour and water are cooled in advance at the time of dough production, or the bakery piece-like oil / fat composition is frozen and used. By the method, a bakery product that melts in the mouth is obtained without using a high melting point fat or oil.
However, this method is not applicable to the latter usage. This is because the temperature at the time of kneading is as high as 25 to 38 ° C, especially for bread dough and sweet bread dough, so even if a frozen small piece of oil and fat composition is added here, the effect of preventing kneading is almost the same. This is because it cannot be expected, and the temperature of the bread dough drops, the dough does not stretch well in the subsequent proofing process, and the quality of the obtained bread is greatly reduced.
Moreover, even in the case of the former usage method, cooling may not be possible due to continuous production or the like.

このため、生地温度が高い場合であっても、添加したベーカリー用小片状油脂組成物が練り込まれることが防止され、且つ、口溶けのいいベーカリー製品を得ることができるベーカリー用小片状油脂組成物が求められていた。 Therefore, even when the dough temperature is high, it is possible to prevent the added bakery piece-like oil / fat composition from being kneaded and to obtain a bakery product that melts in the mouth. The composition was sought after.

この視点から、例えば、ハードバターとして一般的に使用されるパーム中融点部を主体としパーム油のエステル交換油脂で可塑性を出した配合の油脂組成物(たとえば特許文献2参照)が提案されている。しかしながら、この方法を用いると、得られるベーカリー用小片状油脂組成物は口溶けが悪く、また、該ベーカリー用小片状油脂組成物を用いた生地がべたつきやすいという問題があった。 From this point of view, for example, a fat and oil composition (see, for example, Patent Document 2) in which the melting point of palm, which is generally used as hard butter, is mainly used and the palm oil is transesterified to obtain plasticity has been proposed. .. However, when this method is used, there is a problem that the obtained small piece oil / fat composition for bakery is poorly melted in the mouth and the dough using the small piece oil / fat composition for bakery is easily sticky.

また、別の方法として、ベーカリー用小片状油脂組成物を水中油型乳化物とする方法(たとえば特許文献3参照)も提案されている。しかしながら、この方法を採用すると、水相に使用する増粘安定剤の食感によって、得られるベーカリー製品の食感が低下しやすく、また、油脂の機能、例えばジューシー感の付与などの効果が感じられないという問題もあった。 Further, as another method, a method of converting a bakery fragmentary oil / fat composition into an oil-in-water emulsion (see, for example, Patent Document 3) has also been proposed. However, when this method is adopted, the texture of the thickening stabilizer used for the aqueous phase tends to reduce the texture of the obtained bakery product, and the function of fats and oils, for example, the effect of imparting a juicy feeling, is felt. There was also the problem of not being able to do it.

一方、ベーカリー用小片状油脂組成物に関する別の問題として、保管中に、自重又は溶解などにより、ベーカリー用小片状油脂組成物が相互結着を起こしてしまう問題もある。
この問題の解消のために、例えば、ベーカリー用小片状油脂組成物の表面に加熱により油脂膜を生成させる方法(例えば特許文献4参照)、ベーカリー用小片状油脂組成物の表面に焙焼小麦粉を付着させる方法(例えば特許文献5、6参照)、水相に糖液を使用したベーカリー用小片状油脂組成物(例えば特許文献7参照)が提案されている。
On the other hand, as another problem regarding the bakery fragmented oil / fat composition, there is also a problem that the bakery fragmented oil / fat composition causes mutual binding due to its own weight or dissolution during storage.
In order to solve this problem, for example, a method of forming an oil film on the surface of a bakery piece-like oil / fat composition by heating (see, for example, Patent Document 4), or roasting on the surface of a bakery piece-like oil / fat composition. A method for adhering wheat flour (see, for example, Patent Documents 5 and 6) and a bakery piece-like oil and fat composition using a sugar solution in the aqueous phase (see, for example, Patent Document 7) have been proposed.

しかし、特許文献4の方法は液状油配合量の多いベーカリー用小片状油脂組成物でないと逆に結着が強まってしまうことから、高融点の油脂組成物には適用できないという問題があった。特許文献5及び6に記載の方法であると、得られるベーカリー製品の食感がぱさつくなど、食感に影響が出てしまう問題があった。特許文献7に記載の方法は、ベーカリー用小片状油脂組成物に十分な硬さが得られず、また、得られるベーカリー製品に甘味が付与されてしまい、更には浮きが悪くなってしまうという問題があった。更にこれらのベーカリー用小片状油脂組成物を添加した生地はべとつきやすく、ミキサーやラウンダーでの付着が激しいという問題があった。 However, the method of Patent Document 4 has a problem that it cannot be applied to a high melting point oil / fat composition because the binding becomes stronger unless the composition is a small piece of oil / fat composition for bakery containing a large amount of liquid oil. .. The methods described in Patent Documents 5 and 6 have a problem that the texture of the obtained bakery product is affected, such as a dry texture. According to the method described in Patent Document 7, sufficient hardness cannot be obtained for the bakery fragmented oil / fat composition, sweetness is imparted to the obtained bakery product, and the floating becomes worse. There was a problem. Further, the dough to which these small pieces of oil and fat composition for bakery are added is easily sticky, and there is a problem that the dough adheres violently with a mixer or a rounder.

このように、保管中の相互結着性が抑制され、更には食パン生地や菓子パン生地に添加混合した際に練り込まれにくく、また、添加したベーカリー生地のべたつきが抑えることのできる、ベーカリー用小片状油脂組成物が求められていた。 In this way, mutual binding during storage is suppressed, and when added to and mixed with bread dough or sweet bread dough, it is difficult to knead, and the stickiness of the added bakery dough can be suppressed. A flake oil / fat composition has been sought.

特開平06−233649号公報Japanese Unexamined Patent Publication No. 06-23649 特開2009―207444号公報Japanese Unexamined Patent Publication No. 2009-207444 特開2002―262760号公報Japanese Unexamined Patent Publication No. 2002-262760 特公昭46―013264号公報Tokukousho 46-013264 特開平11―318318号公報Japanese Unexamined Patent Publication No. 11-318318 特開平11―318319号公報Japanese Unexamined Patent Publication No. 11-318319 特開平07―039301号公報Japanese Unexamined Patent Publication No. 07-039301

従って、本発明の課題は、保管中の相互結着性が抑制され、更にはベーカリー生地に添加混合した際にベーカリー生地に練り込まれにくく、また、ベーカリー生地のべたつきが抑えられ、得られるベーカリー製品の口溶けがいい、ベーカリー用小片状油脂組成物を提供することにある。 Therefore, the subject of the present invention is that the mutual binding property during storage is suppressed, the bakery dough is less likely to be kneaded when added to and mixed with the bakery dough, and the stickiness of the bakery dough is suppressed. The purpose is to provide a bakery flaky oil / fat composition that melts in the mouth of the product.

本発明者等は、上記課題を解決すべく種々検討した結果、ベーカリー生地の捏ね上げ温度である30〜36℃程度での固形脂含量が高く、該油温度域でのトリグリセリド組成において対称型トリグリセリドとトリ飽和トリグリセリドの比が高いといった、特定のトリグリセリド組成の油脂組成物により上記課題が解決可能であることを見出した。
すなわち本発明は、トリグリセリド組成が下記の条件(1)及び(2)を満たすベーカリー用小片状油脂組成物を提供するものである。
(1)S3、S2m、S2d及びSm2を合計した含有量が50〜80質量%である。
(2)(StStSt+PPP+StOSt+POSt+POP)/(StStSt+PPP+S2m+S2d+Sm2)=0.50〜0.90
ただし、
S:炭素数16〜18の飽和脂肪酸
m:炭素数16〜18のモノ不飽和脂肪酸
d:炭素数16〜18のポリ不飽和脂肪酸
S3:炭素数16〜18の飽和脂肪酸が3個結合したトリグリセリド
S2m:炭素数16〜18の飽和脂肪酸が2個、炭素数16〜18のモノ不飽和脂肪酸が1個結合したトリグリセリド
S2d:炭素数16〜18の飽和脂肪酸が2個、炭素数16〜18のポリ不飽和脂肪酸が1個結合したトリグリセリド
Sm2:炭素数16〜18の飽和脂肪酸が1個、炭素数16〜18のモノ不飽和脂肪酸が2個結合したトリグリセリド
PPP:パルミチン酸が3個結合したトリグリセリド
StStSt:ステアリン酸が3個結合したトリグリセリド
StOSt:1、3位にステアリン酸、2位にオレイン酸が結合したトリグリセリド
POSt:1、3位にステアリン酸及びパルミチン酸、2位にオレイン酸が結合したトリグリセリド
POP:1、3位にパルミチン酸、2位にオレイン酸が結合したトリグリセリド
である。
As a result of various studies to solve the above problems, the present inventors have a high solid fat content at the kneading temperature of bakery dough, which is about 30 to 36 ° C., and a symmetric triglyceride in the triglyceride composition in the oil temperature range. It has been found that the above-mentioned problems can be solved by an oil / fat composition having a specific triglyceride composition, such as a high ratio of triglyceride to triglyceride.
That is, the present invention provides a bakery flaky oil / fat composition in which the triglyceride composition satisfies the following conditions (1) and (2).
(1) The total content of S3, S2m, S2d and Sm2 is 50 to 80% by mass.
(2) (StStSt + PPP + StOSt + POSt + POP) / (StStSt + PPP + S2m + S2d + Sm2) = 0.50 to 0.90
However,
S: Saturated fatty acids with 16 to 18 carbon atoms m: Monounsaturated fatty acids with 16 to 18 carbon atoms d: Polyunsaturated fatty acids with 16 to 18 carbon atoms S3: Triglyceride in which three saturated fatty acids with 16 to 18 carbon atoms are bonded S2m: Triglyceride in which two saturated fatty acids having 16 to 18 carbon atoms and one monounsaturated fatty acid having 16 to 18 carbon atoms are bonded S2d: Two saturated fatty acids having 16 to 18 carbon atoms and 16 to 18 carbon atoms Triglyceride with one polyunsaturated fatty acid Sm2: Triglyceride with one saturated fatty acid with 16-18 carbon atoms and two monounsaturated fatty acids with 16-18 carbon atoms PPP: Triglyceride with three palmitic acids bonded StStSt: Triglyceride with 3 stearic acids StOSt: 1 Triglyceride with stearic acid at 3rd position and oleic acid at 2nd position POSt: 1 with stearic acid and palmitic acid at 3rd position and oleic acid at 2nd position Triglyceride POP: A triglyceride in which palmitic acid is bound at the 3-position and oleic acid is bound at the 2-position.

本発明のベーカリー用小片状油脂組成物は、保管中の相互結着性が抑制され、更にはベーカリー生地に添加混合した際にベーカリー生地に練り込まれにくい。また、本発明のベーカリー用小片状油脂組成物を添加したベーカリー生地はべたつきが抑えられている。更に、本発明のベーカリー用小片状油脂組成物を用いて得られるベーカリー製品は口溶けが良好となる。 The bakery flaky oil / fat composition of the present invention suppresses mutual binding during storage, and is less likely to be kneaded into the bakery dough when added to and mixed with the bakery dough. Further, the bakery dough to which the small piece-like oil / fat composition for bakery of the present invention is added is suppressed from stickiness. Further, the bakery product obtained by using the bakery fragmentary oil / fat composition of the present invention has good melting in the mouth.

以下、本発明のベーカリー用小片状油脂組成物について詳述する。
本発明のベーカリー用小片状油脂組成物は油相のトリグリセリド組成が下記の条件(1)及び(2)を満たすものである。
(1)S3、S2m、S2d及びSm2を合計した含有量が50〜80質量%である。
(2)(StStSt+PPP+StOSt+POSt+POP)/(StStSt+PPP+S2m+S2d+Sm2)=0.50〜0.80
ただし、
S:炭素数16〜18の飽和脂肪酸
m:炭素数16〜18のモノ不飽和脂肪酸
d:炭素数16〜18のポリ不飽和脂肪酸
S3:炭素数16〜18の飽和脂肪酸が3個結合したトリグリセリド
S2m:炭素数16〜18の飽和脂肪酸が2個、炭素数16〜18のモノ不飽和脂肪酸が1個結合したトリグリセリド
S2d:炭素数16〜18の飽和脂肪酸が2個、炭素数16〜18のポリ不飽和脂肪酸が1個結合したトリグリセリド
Sm2:炭素数16〜18の飽和脂肪酸が1個、炭素数16〜18のモノ不飽和脂肪酸が2個結合したトリグリセリド
PPP:パルミチン酸が3個結合したトリグリセリド
StStSt:ステアリン酸が3個結合したトリグリセリド
StOSt:1、3位にステアリン酸、2位にオレイン酸が結合したトリグリセリド
POSt:1、3位にステアリン酸及びパルミチン酸、2位にオレイン酸が結合したトリグリセリド
POP:1、3位にパルミチン酸、2位にオレイン酸が結合したトリグリセリド
である。
Hereinafter, the bakery flaky oil / fat composition of the present invention will be described in detail.
In the bakery flaky oil / fat composition of the present invention, the triglyceride composition of the oil phase satisfies the following conditions (1) and (2).
(1) The total content of S3, S2m, S2d and Sm2 is 50 to 80% by mass.
(2) (StStSt + PPP + StOSt + POSt + POP) / (StStSt + PPP + S2m + S2d + Sm2) = 0.50 to 0.80
However,
S: Saturated fatty acids with 16 to 18 carbon atoms m: Monounsaturated fatty acids with 16 to 18 carbon atoms d: Polyunsaturated fatty acids with 16 to 18 carbon atoms S3: Triglyceride in which three saturated fatty acids with 16 to 18 carbon atoms are bonded S2m: Triglyceride in which two saturated fatty acids having 16 to 18 carbon atoms and one monounsaturated fatty acid having 16 to 18 carbon atoms are bonded S2d: Two saturated fatty acids having 16 to 18 carbon atoms and 16 to 18 carbon atoms Triglyceride with one polyunsaturated fatty acid Sm2: Triglyceride with one saturated fatty acid with 16-18 carbon atoms and two monounsaturated fatty acids with 16-18 carbon atoms PPP: Triglyceride with three palmitic acids bonded StStSt: Triglyceride with 3 stearic acids StOSt: 1 Triglyceride with stearic acid at 3rd position and oleic acid at 2nd position POSt: 1 with stearic acid and palmitic acid at 3rd position and oleic acid at 2nd position Triglyceride POP: A triglyceride in which palmitic acid is bound at the 3-position and oleic acid is bound at the 2-position.

まず上記条件(1)について述べる。
本発明のベーカリー用小片状油脂組成物は、油相のトリグリセリド組成におけるS3、S2m、S2d及びSm2を合計した含有量が50〜80質量%、好ましくは55〜75質量%である。合計含有量が50質量%未満であると、ベーカリー用小片状油脂組成物をベーカリー生地に添加混合する際に油脂固形分含量が不足するため、ベーカリー用小片状油脂組成物が練り込まれやすくなってしまう。また、ベーカリー用小片状油脂組成物を用いたベーカリー生地のべたつきが激しくなってしまう。一方、合計含有量が80質量%超であると、ベーカリー用小片状油脂組成物をベーカリー生地に添加混合する際に油脂固形分含量が高すぎるため、ベーカリー用小片状油脂組成物とベーカリー生地とのなじみが悪く、生地に入っていきにくいことに加え、油脂組成物を小片状に成形加工する際に調温を厳格に行わないと割れを生じてしまう問題も発生してしまう。
First, the above condition (1) will be described.
The bakery flaky oil / fat composition of the present invention has a total content of S3, S2m, S2d and Sm2 in the triglyceride composition of the oil phase of 50 to 80% by mass, preferably 55 to 75% by mass. If the total content is less than 50% by mass, the oil and fat solid content is insufficient when the bakery small oil and fat composition is added and mixed with the bakery dough, so that the bakery small oil and fat composition is kneaded. It will be easier. In addition, the stickiness of the bakery dough using the bakery small piece oil / fat composition becomes severe. On the other hand, when the total content is more than 80% by mass, the oil and fat solid content is too high when the bakery fragmented oil and fat composition is added and mixed with the bakery dough, so that the bakery fragmentary oil and fat composition and the bakery In addition to poor compatibility with the dough and difficulty in entering the dough, there is a problem that cracks occur if the temperature is not strictly controlled when the oil / fat composition is molded into small pieces.

次に上記条件(2)について述べる。
本発明のベーカリー用小片状油脂組成物は油相のトリグリセリド組成において、(2)(StStSt+PPP+StOSt+POSt+POP)/(StStSt+PPP+S2m+S2d+Sm2)の値が0.50〜0.90、好ましくは0.55〜0.90である。上記比の値が0.50未満であると、ベーカリー用小片状油脂組成物をベーカリー生地に添加混合する際に粘りが出やすく、ベーカリー生地のべたつきが激しくなってしまう。一方、上記比の値が0.90超であると、ベーカリー用小片状油脂組成物が脆い物性になりやすく、ベーカリー生地に添加混合する際に割れて細かい油脂片になってしまい、ベーカリー生地中の油脂部分が小さくなりすぎ、その後の製パン工程中に完全に練りこまれてしまうという問題を生じる。
Next, the above condition (2) will be described.
The bakery flaky oil / fat composition of the present invention has a triglyceride composition of the oil phase in which the values of (2) (StStSt + PPP + StOSt + POSt + POP) / (StStSt + PPP + S2m + S2d + Sm2) are 0.50 to 0.90, preferably 0.55 to 0.90. is there. If the value of the above ratio is less than 0.50, the bakery dough becomes sticky when the bakery small oil / fat composition is added and mixed with the bakery dough. On the other hand, if the value of the above ratio is more than 0.90, the small piece of fat and oil composition for bakery tends to have brittle physical properties, and when it is added and mixed with the bakery dough, it breaks into fine pieces of fat and oil, and the bakery dough. There is a problem that the oil and fat portion inside becomes too small and is completely kneaded during the subsequent bread making process.

本発明のベーカリー用小片状油脂組成物は上記条件(1)及び(2)に加え、下記の条件(3)を満たすことが好ましい。
以下、上記条件(3)について述べる。
本発明のベーカリー用小片状油脂組成物は油相のトリグリセリド組成における(StStSt+PPP)/(StStSt+PPP+StOSt+POSt+POP)の値が0.5以下であることが好ましく、より好ましくは0.25以下、最も好ましくは0.05以下である。上記比の値が0.5超であると、得られるベーカリー製品の口溶けが悪化してしまう。なお、(StStSt+PPP)/(StStSt+PPP+StOSt+POSt+POP)の値の下限は0である。
The bakery flaky oil / fat composition of the present invention preferably satisfies the following condition (3) in addition to the above conditions (1) and (2).
The above condition (3) will be described below.
In the bakery flaky oil / fat composition of the present invention, the value of (StStSt + PPP) / (StStSt + PPP + StOSt + POSt + POP) in the triglyceride composition of the oil phase is preferably 0.5 or less, more preferably 0.25 or less, and most preferably 0. It is 0.05 or less. If the value of the above ratio is more than 0.5, the melting of the obtained bakery product in the mouth deteriorates. The lower limit of the value of (StStSt + PPP) / (StStSt + PPP + StOSt + POSt + POP) is 0.

本発明のベーカリー用小片状油脂組成物は油相におけるS3、S2m、S2d、Sm2、PPP、StStSt、StOSt、POSt、POP等のトリグリセリドの含有量は、例えば、基準油脂分析試験法(2、4、6、2−2013トリアシルグリセリン組成(高速液体クロマトグラフ法)と銀イオン−高速液体クロマトグラフ法の併用により測定することができる。 In the bakery fragmentary oil / fat composition of the present invention, the content of triglycerides such as S3, S2m, S2d, Sm2, PPP, StStSt, StOSt, POSt, and POP in the oil phase is determined by, for example, the reference oil / fat analysis test method (2, 4, 6, 2-2013 triacylglycerin composition (high performance liquid chromatography) ) and silver ion-high performance liquid chromatography can be used in combination.

ここで、本発明のベーカリー用小片状油脂組成物の油相が上記条件(1)及び(2)、好ましくは上記条件(1)、(2)及び(3)を満たすためには、ベーカリー用小片状油脂組成物が下記の油脂Aと下記の油脂Bとを含有することが好ましい。油脂Aと油脂Bとの配合比は、油脂A:油脂Bが質量比で、50〜90:50〜10であることが好ましく、60〜80:40〜20であることがより好ましい。また、本発明のベーカリー用小片状油脂組成物における油相中の油脂における油脂A及び油脂Bの合計含有量は、70〜100質量%であることが好ましく、80〜100質量%であることがより好ましく、80〜100質量%であることが更に好ましく、油相が油脂A及び油脂Bのみからなることが特に好ましい。更に、前記の配合比及び合計含有量を満たすことを条件として、本発明における油脂Aの含有量は30〜90質量%であることが好ましく、45〜80質量%であることがより好ましく、最も好ましくは60〜80質量%である。同様に、本発明における油脂Bの含有量は6〜50質量%であることが好ましく、15〜40質量%であることがより好ましく、最も好ましくは20〜40質量%である。
油脂A:SUSを多く含有する油脂
油脂B:30℃で液状である油脂
ここで、SUS:1、3位に炭素数16〜18の飽和脂肪酸、2位に炭素数16〜18の不飽和脂肪酸が結合したトリグリセリドである。
Here, in order for the oil phase of the bakery fragmentary oil / fat composition of the present invention to satisfy the above conditions (1) and (2), preferably the above conditions (1), (2) and (3), the bakery It is preferable that the small piece of oil / fat composition contains the following oil / fat A and the following oil / fat B. The blending ratio of the fat A and the fat B is preferably 50 to 90:50 to 10 and more preferably 60 to 80:40 to 20 in terms of the mass ratio of fat A: fat B. Further, the total content of the fats and oils A and B in the fats and oils in the oil phase in the bakery fragmentary fats and oils composition of the present invention is preferably 70 to 100% by mass, preferably 80 to 100% by mass. Is more preferable, 80 to 100% by mass is further preferable, and it is particularly preferable that the oil phase is composed of only fat A and fat B. Further, the content of the fat and oil A in the present invention is preferably 30 to 90% by mass, more preferably 45 to 80% by mass, and most preferably, on condition that the above-mentioned compounding ratio and total content are satisfied. It is preferably 60 to 80% by mass. Similarly, the content of fats and oils B in the present invention is preferably 6 to 50% by mass, more preferably 15 to 40% by mass, and most preferably 20 to 40% by mass.
Fats and oils A: Fats and oils containing a large amount of SUS Fats and oils B: Fats and oils that are liquid at 30 ° C. Here, SUS: 1, saturated fatty acids with 16 to 18 carbon atoms at the 3rd position and unsaturated fatty acids with 16 to 18 carbon atoms at the 2nd position. Is a bound triglyceride.

上記油脂Aについて述べる。
上記「SUSを多く含有する油脂」とは、SUSを15質量%以上、好ましくは30質量%以上含有する油脂である。「SUSを多く含有する油脂」としては、例えば、パーム油、カカオ脂、シア脂、マンゴー核脂、サル脂、イリッペ脂、コクム脂、デュパー脂、モーラー脂、フルクラ脂及びチャイニーズタロー等の各種植物油脂、これらの各種植物油脂を分別した加工油脂、並びに下記に記載するエステル交換油脂、該エステル交換油脂を分別した加工油脂を用いることができる。本発明では、これらの油脂の中から選ばれた1種又は2種以上を用いることができる。
上記エステル交換油脂としては、例えば、パーム油、コーン油、オリーブ油、綿実油、大豆油、ナタネ油、米油、ヒマワリ油、サフラワー油、牛脂、乳脂、豚脂、カカオバター、シア脂、マンゴー核脂、サル脂、イリッペ脂、魚油及び鯨油等の各種動植物油脂、これらの各種動植物油脂を必要に応じて水素添加及び/又は分別した後に得られる加工油脂、脂肪酸、脂肪酸低級アルコールエステルを用いて製造したエステル交換油脂であって、SUSが15質量%以上、好ましくは30質量%以上である油脂である。エステル交換の方法としては、酵素を用いても、化学触媒を用いてもよく、またランダムエステル交換でも、1,3位置選択性のあるエステル交換でもよい。
本発明のベーカリー用小片状油脂組成物においては、上記「SUSを多く含有する油脂」として、パーム油、カカオ脂、シア脂、マンゴー核脂、サル脂及びイリッペ脂等の各種植物油脂の分別中部油や分別硬部油を使用することが好ましく、カカオ脂分別硬部油、パーム油分別硬部油、パーム油分別中部油、シア脂分別硬部油及びコクム脂分別硬部油から選択される油脂のうちの1種又は2種以上を使用することがより好ましく、より口溶けの良好であるベーカリー用小片状油脂組成物が得られる点で、パーム油分別硬部油、パーム油分別中部油及びシア脂分別硬部油から選択される油脂のうちの1種又は2種以上を使用することがより好ましく、特に好ましくはシア脂分別硬部油を少なくとも使用する。
The fat and oil A will be described.
The above-mentioned "fat and oil containing a large amount of SUS" is a fat and oil containing 15% by mass or more, preferably 30% by mass or more of SUS. Examples of "fat and oil containing a large amount of SUS" include various vegetables such as palm oil, cacao butter, shea butter, mango kernel fat, monkey fat, ilippe fat, kokum fat, duper fat, mahua fat, fulcla fat and Chinese tallow. Oils and fats, processed oils and fats obtained by separating these various vegetable oils and fats, and the transesterified oils and fats described below, and processed oils and fats obtained by separating the transesterified oils and fats can be used. In the present invention, one or more selected from these fats and oils can be used.
Examples of the ester-exchanged fats and oils include palm oil, corn oil, olive oil, cottonseed oil, soybean oil, rapeseed oil, rice oil, sunflower oil, safflower oil, beef tallow, milk fat, pork fat, cacao butter, shea fat, and mango kernel. Manufactured using various animal and vegetable fats and oils such as fat, safflower, iripe fat, fish oil and whale oil, and processed fats and oils, fatty acids and fatty acid lower alcohol esters obtained after hydrogenating and / or separating these various animal and vegetable fats and oils as necessary. The ester-exchanged fats and oils are those having a SUS of 15% by mass or more, preferably 30% by mass or more. The method of transesterification may be an enzyme, a chemical catalyst, random transesterification, or transesterification with 1,3 regioselectivity.
In the bakery fragmentary oil / fat composition of the present invention, various vegetable oils / fats such as palm oil, cacao oil, shea oil, mango kernel oil, monkey oil and ilippe oil are separated as the above-mentioned "SUS-rich oil / oil". It is preferable to use central oil or separated hard part oil, and it is selected from cacao fat separated hard part oil, palm oil separated hard part oil, palm oil separated central part oil, shea fat separated hard part oil and kokum fat separated hard part oil. It is more preferable to use one or more of the above oils and fats, and a small piece of oil and fat composition for bakery having better melting in the mouth can be obtained. It is more preferable to use one or more of the oils and fats selected from the oil and the shear fat separated hard part oil, and particularly preferably at least the shear fat separated hard part oil is used.

次いで上記油脂Bについて述べる。
上記「30℃で液状である油脂」としては、大豆油、菜種油(キャノーラ油)、コーン油、綿実油、オリーブ油、落花生油、米油、べに花油、ハイオレイックサフラワー油、ひまわり油及びハイオレイックひまわり油等の、常温(30℃)で液状の油脂が挙げられる。また、これらの油脂の他に、パーム油、パーム核油、ヤシ油、シア脂、サル脂、マンゴー核脂、乳脂、牛脂、乳脂、豚脂、カカオ脂、魚油及び鯨油等の、常温(30℃)で固体の油脂を分別することで得られた軟部油であって、常温(30℃)で液状である油脂も使用することもできる。また、これらの油脂に対し、水素添加、分別、エステル交換等の物理的又は化学的処理の1種又は2種以上の処理を施した油脂についても、得られる加工油脂が30℃で液状である範囲内において使用することもできる。本発明においては、これらの油脂を単独で用いることもでき、又は2種以上を組み合わせて用いることもできる。
本発明では、得られる油脂組成物の口溶けを良好なものとすることが可能な点から、上記「30℃で液状である油脂」として、大豆油、菜種油(キャノーラ油)、コーン油、綿実油、オリーブ油、落花生油、米油、べに花油、ハイオレイックサフラワー油、ひまわり油及びハイオレイックひまわり油のうちから選択される1種又は2種以上を使用することが好ましい。
Next, the fat and oil B will be described.
The above-mentioned "oils and fats that are liquid at 30 ° C" include soybean oil, rapeseed oil (canola oil), corn oil, cottonseed oil, olive oil, peanut oil, rice oil, safflower oil, high oleic safflower oil, sunflower oil and high oleic sunflower. Examples thereof include oils and fats that are liquid at room temperature (30 ° C.). In addition to these fats and oils, palm oil, palm kernel oil, palm oil, shea butter, monkey fat, mango kernel fat, milk fat, beef tallow, milk fat, pork fat, coconut fat, fish oil, whale oil, etc., at room temperature (30) It is a soft part oil obtained by separating solid fats and oils at (° C.), and fats and oils that are liquid at room temperature (30 ° C.) can also be used. In addition, the processed fats and oils obtained by subjecting these fats and oils to one or more physical or chemical treatments such as hydrogenation, separation, and transesterification are liquid at 30 ° C. It can also be used within the range. In the present invention, these fats and oils can be used alone or in combination of two or more.
In the present invention, soybean oil, rapeseed oil (canola oil), corn oil, cotton seed oil, etc. It is preferable to use one or more selected from olive oil, peanut oil, rice oil, safflower oil, high oleic sunflower oil, sunflower oil and high oleic sunflower oil.

本発明のベーカリー用小片状油脂組成物は、上記油脂A及び上記油脂Bに加え、その他の油脂を使用することができる。上記その他の油脂の含有量は、好ましくは30質量%以下、より好ましくは20質量%以下、更に好ましくは10質量%以下である。その他の油脂の含有量が30質量%を超えると、良好な物性(生地への練り込まれ耐性)が得られないおそれがある。 In addition to the above-mentioned fats and oils A and the above-mentioned fats and oils B, other fats and oils can be used in the bakery fragmentary fats and oils composition of the present invention. The content of the other fats and oils is preferably 30% by mass or less, more preferably 20% by mass or less, and further preferably 10% by mass or less. If the content of other fats and oils exceeds 30% by mass, good physical properties (tolerance to be kneaded into the dough) may not be obtained.

本発明のベーカリー用小片状油脂組成物は、エステル交換油脂の含有量が、好ましくは30質量%以下、より好ましくは20質量%以下、更に好ましくは10質量%以下であり、エステル交換油脂を含まないことが特に好ましい。エステル交換油脂はトリグリセリド組成が複雑であることから、これを含有すると、油脂組成物が硬くなってしまいやすく、得られるベーカリー製品の口溶けが悪くなるという問題や、油脂組成物を小片状に加工する際の作業性が悪化し、均質な小片状に加工することが困難となってしまうという問題がある。 The bakery fragmented oil / fat composition of the present invention has a transesterified oil / fat content of preferably 30% by mass or less, more preferably 20% by mass or less, still more preferably 10% by mass or less, and the transesterified oil / fat. It is particularly preferable not to include it. Since transesterified fats and oils have a complicated triglyceride composition, if they are contained, the fats and oils composition tends to become hard, which causes a problem that the obtained bakery product does not melt in the mouth, and the fats and oils composition is processed into small pieces. There is a problem that workability is deteriorated and it becomes difficult to process it into a homogeneous small piece.

本発明のベーカリー用小片状油脂組成物は、極度硬化油の含有量が、好ましくは30質量%以下、より好ましくは20質量%以下、更に好ましくは10質量%以下であり、極度硬化油を含まないことが特に好ましい。極度硬化油はトリグリセリド組成においてそのほぼ全部がS3であることから、これを含有すると油脂組成物が硬くなってしまいやすく、得られるベーカリー製品の口溶けが極度に悪化する問題や、油脂組成物を小片状に加工する際の作業性が悪化し、均質な小片状に加工することが困難となってしまうという問題がある。 The bakery fragmented oil / fat composition of the present invention has an extremely hydrogenated oil content of preferably 30% by mass or less, more preferably 20% by mass or less, still more preferably 10% by mass or less, and the extremely hydrogenated oil. It is particularly preferable not to include it. Since almost all of the extremely hydrogenated oil has S3 in the triglyceride composition, the oil / fat composition tends to become hard when it is contained, and the problem that the melt-in-the-mouth of the obtained bakery product is extremely deteriorated and the oil / fat composition is small. There is a problem that the workability when processing into a piece shape deteriorates, and it becomes difficult to process into a uniform small piece shape.

また、本発明のベーカリー用小片状油脂組成物は、トランス酸を実質的に含有しないことが好ましい。水素添加は油脂の融点を上昇させる典型的な方法であるが、これによって得られる水素添加油脂は、完全水素添加油脂を除いて、通常構成脂肪酸中にトランス酸が10〜50重量%程度含まれている。一方、天然油脂中にはトランス酸が殆ど存在せず、反芻動物由来の油脂に10重量%未満含まれているにすぎない。近年、化学的な処理、特に水素添加に付されていない油脂組成物、即ち実質的にトランス酸を含まない油脂組成物であって、適切なコンシステンシーを有するものが要求されている。
ここでいう「実質的に」とは、トランス酸含量が、本発明のベーカリー用小片状油脂組成物の全構成脂肪酸中、好ましくは10重量%未満、更に好ましくは5重量%未満、最も好ましくは2重量%未満であることを意味する。
本発明では、ベーカリー用小片状油脂組成物が水素添加油脂を使用せずとも良好なコンステンシーを有するため、トランス酸を実質的に含有しないベーカリー用小片状油脂組成物を得ることができる。
Further, it is preferable that the bakery fragmentary oil / fat composition of the present invention does not substantially contain trans acid. Hydrogenation is a typical method for raising the melting point of fats and oils, and the hydrogenated fats and oils obtained by this method usually contain about 10 to 50% by weight of trans acid in the constituent fatty acids, except for completely hydrogenated fats and oils. ing. On the other hand, there is almost no trans acid in the natural fats and oils, and the fats and oils derived from ruminants contain less than 10% by weight. In recent years, there has been a demand for fats and oils compositions that have not been chemically treated, particularly hydrogenated, that is, fats and oils compositions that are substantially free of transacids and have appropriate consistency.
The term "substantially" as used herein means that the trans acid content is preferably less than 10% by weight, more preferably less than 5% by weight, most preferably less than 10% by weight, more preferably less than 5% by weight, among all the constituent fatty acids of the bakery flaky oil / fat composition of the present invention. Means less than 2% by weight.
In the present invention, since the bakery fragmented oil / fat composition has good consistency without using hydrogenated oil / fat, it is possible to obtain a bakery fragmented oil / fat composition that does not substantially contain trans acid. ..

本発明のベーカリー用小片状油脂組成物は、油脂の含量が、好ましくは35〜100重量%、更に好ましくは40〜95重量%、最も好ましくは45〜87重量%である。また、本発明のベーカリー用小片状油脂組成物は、水の含量が、好ましくは65〜0重量%、更に好ましくは60〜10重量%、最も好ましくは55〜13重量%である。なお上記油脂含量及び水の含量には、下記のその他の成分に含まれる油分や水分を加算して算出するものとする。
なお、本発明のベーカリー用小片状油脂組成物が水分を含む場合、その乳化形態は、油中水型、水中油型、及び二重乳化型のいずれでも構わないが、油中水型であることが好ましい。
The bakery fragmented fat and oil composition of the present invention has a fat and oil content of preferably 35 to 100% by weight, more preferably 40 to 95% by weight, and most preferably 45 to 87% by weight. In addition, the bakery small oil / fat composition of the present invention has a water content of preferably 65 to 0% by weight, more preferably 60 to 10% by weight, and most preferably 55 to 13% by weight. It should be noted that the oil content and water content of the above fats and oils shall be calculated by adding the oil content and water content contained in the following other components.
When the bakery fragmentary oil / fat composition of the present invention contains water, the emulsification form may be any of a water-in-oil type, an oil-in-water type, and a double emulsification type, but the water-in-oil type is used. It is preferable to have.

なお、本発明のベーカリー用小片状油脂組成物はマーガリンあるいはショートニングに代表される可塑性油脂組成物であることが好ましい。油脂組成物に可塑性を付与するには、下で述べるように、油脂組成物製造時に急冷可塑化すればよい。 The bakery flaky oil / fat composition of the present invention is preferably a plastic oil / fat composition typified by margarine or shortening. In order to impart plasticity to the fat and oil composition, as described below, the fat and oil composition may be rapidly cooled and plasticized during production.

また、本発明のベーカリー用小片状油脂組成物は、ベーカリー用小片状油脂組成物が乳化剤を1種又は2種以上含有する場合がある。しかしながら、本発明のベーカリー用小片状油脂組成物は、乳化剤無添加であっても良好なロールイン性や生地への練り込まれ耐性を示し、更には水相を含有する場合でも、保存時やロールイン作業時に離水のない安定な乳化形態のものである。
上記の乳化剤としては、例えばグリセリン脂肪酸エステル、グリセリン酢酸脂肪酸エステル、グリセリン乳酸脂肪酸エステル、グリセリンコハク酸脂肪酸エステル、グリセリン酒石酸脂肪酸エステル、グリセリンクエン酸脂肪酸エステル、グリセリンジアセチル酒石酸脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ショ糖酢酸イソ酪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ポリオキシエチレンソルビタンモノグリセリド等の合成乳化剤や、例えば大豆レシチン、卵黄レシチン、大豆リゾレシチン、卵黄リゾレシチン、酵素処理卵黄、サポニン、植物ステロール類、乳脂肪球皮膜等の、合成乳化剤でない乳化剤が挙げられる。
Further, in the bakery small oil / fat composition of the present invention, the bakery small oil / fat composition may contain one or more emulsifiers. However, the bakery flaky oil / fat composition of the present invention exhibits good roll-in property and resistance to kneading into the dough even without the addition of an emulsifier, and even when it contains an aqueous phase, it is stored. It is a stable emulsified form that does not separate water during roll-in work.
Examples of the above emulsifier include glycerin fatty acid ester, glycerin acetic acid fatty acid ester, glycerin lactic acid fatty acid ester, glycerin succinic acid fatty acid ester, glycerin tartrate fatty acid ester, glycerin phenic acid fatty acid ester, glycerin diacetyl tartrate fatty acid ester, sorbitan fatty acid ester, and sucrose. Synthetic emulsifiers such as fatty acid ester, sucrose acetate isobutyric acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, stearoyl lactate calcium, stearoyl lactate sodium, polyoxyethylene sorbitan monoglyceride, for example, soybean lecithin, Examples thereof include emulsifiers that are not synthetic emulsifiers, such as egg yolk lecithin, soybean lysolecithin, egg yolk lysolecithin, enzyme-treated egg yolk, saponin, plant sterols, and milk fat globules.

本発明のベーカリー用小片状油脂組成物は、上記成分以外のその他の成分を含有する場合がある。該その他の成分としては、例えば、増粘安定剤、食塩、塩化カリウム等の塩味剤、酢酸、乳酸、グルコン酸等の酸味料、糖類や糖アルコール類、ステビア、アスパルテーム等の甘味料、β−カロチン、カラメル、紅麹色素等の着色料、トコフェロール、茶抽出物等の酸化防止剤、小麦蛋白や大豆蛋白といった植物蛋白、卵及び各種卵加工品、着香料、乳製品、調味料、pH調整剤、食品保存料、日持ち向上剤、果実、果汁、コーヒー、ナッツペースト、香辛料、ココアマス、ココアパウダー、穀類、豆類、野菜類、肉類及び魚介類等の食品素材や食品添加物が挙げられる。 The bakery flaky oil / fat composition of the present invention may contain other components other than the above components. Examples of the other components include thickening stabilizers, salting agents such as salt and potassium chloride, acidity agents such as acetic acid, lactic acid and gluconic acid, sweeteners such as sugars and sugar alcohols, stevia and aspartame, and β-. Colorants such as carotene, caramel and red koji pigment, antioxidants such as tocopherol and tea extract, plant proteins such as wheat protein and soybean protein, eggs and various processed egg products, flavoring agents, dairy products, seasonings, pH adjustment Examples include food materials and food additives such as agents, food preservatives, shelf life improvers, fruits, fruit juices, coffee, nut pastes, spices, cocoa mass, cocoa powder, grains, beans, vegetables, meats and seafood.

上記増粘安定剤としては、グアーガム、ローカストビーンガム、カラギーナン、アラビアガム、アルギン酸類、ペクチン、キサンタンガム、プルラン、タマリンドシードガム、サイリウムシードガム、結晶セルロース、カルボキシメチルセルロース、メチルセルロース、寒天、グルコマンナン、ゼラチン、澱粉及び化工澱粉等が挙げられ、これらの中から選ばれた1種又は2種以上を用いることができる。上記増粘安定剤の含量は、特に制限はないが、本発明のベーカリー用小片状油脂組成物中、好ましくは0〜10重量%、更に好ましくは0〜5重量%である。なお、本発明のベーカリー用小片状油脂組成物において、上記増粘安定剤が必要でなければ、増粘安定剤を用いなくてもよい。 Examples of the thickening stabilizer include guar gum, locust bean gum, carrageenan, arabic gum, alginic acid, pectin, xanthan gum, pullulan, tamarind seed gum, psyllium seed gum, crystalline cellulose, carboxymethyl cellulose, methyl cellulose, agar, glucomannan, and gelatin. , Glue, chemical starch and the like, and one or more selected from these can be used. The content of the thickening stabilizer is not particularly limited, but is preferably 0 to 10% by weight, more preferably 0 to 5% by weight, in the bakery small oil / fat composition of the present invention. If the thickening stabilizer is not required in the bakery small oil / fat composition of the present invention, the thickening stabilizer may not be used.

次に、本発明のベーカリー用小片状油脂組成物の製造方法を説明する。
本発明のベーカリー用小片状油脂組成物は、その製造方法が特に制限されるものではなく、上記条件(1)及び(2)、好ましくは条件(1)、(2)及び(3)を満たす油相を溶解し、冷却し、結晶化して油脂組成物とする際に、小片状に成形する工程を含むことによって得ることができる。
Next, a method for producing a small piece of oil / fat composition for bakery according to the present invention will be described.
The method for producing the small oil / fat composition for bakery of the present invention is not particularly limited, and the above conditions (1) and (2), preferably conditions (1), (2) and (3) are satisfied. It can be obtained by including a step of forming into small pieces when the oil phase to be filled is melted, cooled, and crystallized into an oil / fat composition.

具体的には、まず、条件(1)及び(2)、好ましくは条件(1)、(2)及び(3)の条件を満たす油相を溶解し、必要により水相を混合乳化する。そして次に、殺菌処理するのが望ましい。殺菌方法はタンクでのバッチ式でも、プレート型熱交換機や掻き取り式熱交換機を用いた連続式でも構わない。
次に、油相を冷却し、結晶化させる。好ましくは冷却可塑化する。冷却条件は、好ましくは−0.5℃/分以上、更に好ましくは−5℃/分以上とする。この際、徐冷却より急速冷却の方が好ましい。
冷却する機器としては、密閉型連続式チューブ冷却機、例えばボテーター、コンピネーター、パーフェクター等のマーガリン製造機やプレート型熱交換機等が挙げられ、また、開放型のダイアクーラーとコンプレクターの組み合わせが挙げられる。
Specifically, first, the oil phase satisfying the conditions (1) and (2), preferably the conditions (1), (2) and (3) is dissolved, and if necessary, the aqueous phase is mixed and emulsified. Then, it is desirable to sterilize. The sterilization method may be a batch type in a tank or a continuous type using a plate type heat exchanger or a scraping type heat exchanger.
The oil phase is then cooled and crystallized. It is preferably cooled and plasticized. The cooling conditions are preferably −0.5 ° C./min or higher, and more preferably −5 ° C./min or higher. At this time, rapid cooling is preferable to slow cooling.
Examples of the cooling device include a closed continuous tube cooler, for example, a margarine maker such as a botator, a compinator, and a perfector, a plate type heat exchanger, and the like, and a combination of an open type diacooler and a compressor. Can be mentioned.

また、本発明のベーカリー用小片状油脂組成物を製造する際のいずれかの製造工程で、窒素、空気等を含気させても、含気させなくても構わない。 In addition, nitrogen, air, or the like may or may not be aerated in any of the manufacturing steps when producing the bakery flaky oil / fat composition of the present invention.

次に、結晶化した油相を小片状に成形する。ここで、上記小片状に成形する方法としては、特に限定されるものではないが、上記条件(1)及び(2)、好ましくは条件(1)、(2)及び(3)の条件を満たす油脂組成物の製造時に、小片状の型に流しこみ冷却固化させる方法や、いったん冷却した上記条件(1)及び(2)、好ましくは条件(1)、(2)及び(3)の条件を満たす油脂組成物を、包丁や自動ラインで小片状にカットする方法や、小穴をあけた口金を通す押し出し成形で吐出させた後にカットして小片状とする方法等が挙げられる。
本発明において小片状とは、立方体状、直方体状、角柱状、円柱状、半円柱状、球状、薄片状、そぼろ状、塊状等の形状で、その大きさが、立方体状又は直方体状のものは一辺の長さが2mm以上30mm以下程度、角柱状のものは断面となる多角形の一辺が2mm以上30mm以下で長さが2mm以上100mm以下程度、円柱状又は半円柱状のものは直径が2mm以上30mm以下で長さが2mm以上100mm以下程度、球状のものは直径が2mm以上30mm以下程度、薄片状のものは厚さが0.5mm以上5mm以下程度、そぼろ状や塊状の場合はその平均粒径が2mm以上30mm程度のものである。ベーカリー用小片状油脂組成物の寸法が上記範囲外であると、ベースとなるパン生地への分散性が悪化するおそれがある。
Next, the crystallized oil phase is formed into small pieces. Here, the method for forming the small pieces is not particularly limited, but the above conditions (1) and (2), preferably the conditions (1), (2) and (3) are satisfied. During the production of the oil and fat composition to be satisfied, a method of pouring into a small piece-shaped mold and cooling and solidifying, and the above conditions (1) and (2) once cooled, preferably conditions (1), (2) and (3). Examples thereof include a method of cutting an oil / fat composition satisfying the conditions into small pieces with a kitchen knife or an automatic line, and a method of discharging the oil / fat composition by extrusion molding through a mouthpiece having a small hole and then cutting the composition into small pieces.
In the present invention, the small piece shape is a shape such as a cube shape, a rectangular parallelepiped shape, a prismatic shape, a columnar shape, a semicircular shape, a spherical shape, a flaky shape, a rag shape, a lump shape, and the size thereof is a cube shape or a rectangular parallelepiped shape. The one with a side length of about 2 mm or more and 30 mm or less, the one with a rectangular parallelepiped has a side of a polygon with a cross section of 2 mm or more and 30 mm or less and the length is about 2 mm or more and about 100 mm or less, and the one with a columnar or semi-cylindrical shape has a diameter. 2 mm or more and 30 mm or less and length of 2 mm or more and 100 mm or less, spherical ones have a diameter of 2 mm or more and 30 mm or less, flaky ones have a thickness of 0.5 mm or more and 5 mm or less, and rags or lumps The average particle size is about 2 mm or more and about 30 mm. If the size of the bakery small oil / fat composition is out of the above range, the dispersibility in the base bread dough may be deteriorated.

次に、本発明のベーカリー生地について述べる。
本発明のベーカリー生地は、本発明のベーカリー用小片状油脂組成物を含有する。本発明のベーカリー生地は、本発明のベーカリー用小片状油脂組成物を、ベースとなるベーカリー生地100質量部に対して、本発明のベーカリー用小片状油脂組成物を好ましくは5〜80質量部、更に好ましくは10〜50質量部、最も好ましくは10〜30質量部含有する。
Next, the bakery dough of the present invention will be described.
The bakery dough of the present invention contains the bakery flaky oil / fat composition of the present invention. In the bakery dough of the present invention, the bakery piece-like oil / fat composition of the present invention is preferably used in an amount of 5 to 80 parts by mass based on 100 parts by mass of the bakery dough as a base. It is contained in parts, more preferably 10 to 50 parts by mass, and most preferably 10 to 30 parts by mass.

ベースとなるベーカリー生地としては、食パン生地、菓子パン生地、パイ生地、デニッシュ生地、クロワッサン生地、フランスパン生地、セミハードロール生地、ワッフル生地及びスコーン生地等のパン生地である場合があり、クッキー生地、バターケーキ生地及びマフィン生地等の菓子生地である場合があるが、パン生地が好ましい。
上記パン生地は、従来から使用されているものを特に制限なく用いることができる。本発明のベーカリー生地では、ベースとなるパン生地が油脂含量及び糖類含量の高いリッチな配合の生地であることが、本発明の高い効果が得られる点、及び、良好な食感のベーカリー製品とすることが可能な点で好ましい。なお、この場合、ベースとなるパン生地に使用する澱粉類100質量部に対して油脂の配合量が好ましくは5〜30質量部、より好ましくは5〜20質量部であり、パン生地に使用する澱粉類100質量部に対して糖類の配合量が固形分として好ましくは5〜30質量部、より好ましくは9〜20質量部であるパン生地を用いることが好ましい。
The base bakery dough may be bread dough such as bread dough, sweet bread dough, pie dough, danish dough, croissant dough, French bread dough, semi-hard roll dough, waffle dough and scone dough, and cookie dough and butter cake dough. And may be confectionery dough such as muffin dough, but bread dough is preferable.
As the bread dough, those conventionally used can be used without particular limitation. In the bakery dough of the present invention, the fact that the base bread dough is a dough with a rich composition having a high fat content and sugar content is a point that the high effect of the present invention can be obtained and that the bakery product has a good texture. It is preferable in that it is possible. In this case, the blending amount of fats and oils is preferably 5 to 30 parts by mass, more preferably 5 to 20 parts by mass with respect to 100 parts by mass of the starches used for the base bread dough, and the starches used for the bread dough. It is preferable to use bread dough in which the amount of the saccharide to be blended is preferably 5 to 30 parts by mass, more preferably 9 to 20 parts by mass with respect to 100 parts by mass.

次に、本発明のベーカリー生地の製造方法について述べる。
本発明のベーカリー生地は、上記本発明のベーカリー用小片状油脂組成物を、ベースとなるベーカリー生地に分散させることによって得ることができる。その具体的な方法としては、ベースとなるベーカリー生地がパン生地である場合は、パン生地のミキシング時、好ましくはミキシングの最終段階で本発明のベーカリー用小片状油脂組成物を添加し、軽く混合する方法や、パン生地上に本発明のベーカリー用小片状油脂組成物を散布し、巻き込む方法等が挙げられる。また、ベースとなるベーカリー生地が菓子生地の場合は、菓子生地に本発明のベーカリー用小片状油脂組成物を添加し、軽く混合する方法が挙げられる。
Next, the method for producing the bakery dough of the present invention will be described.
The bakery dough of the present invention can be obtained by dispersing the above-mentioned small piece of oil and fat composition for bakery of the present invention in the base bakery dough. As a specific method, when the base bakery dough is bread dough, the bakery flaky oil / fat composition of the present invention is added at the time of mixing the bread dough, preferably at the final stage of mixing, and lightly mixed. Examples thereof include a method, a method of spraying a small piece of oil and fat composition for bakery of the present invention on bread dough, and entwining the dough. When the base bakery dough is a confectionery dough, a method of adding the bakery fragmentary oil / fat composition of the present invention to the confectionery dough and lightly mixing the dough can be mentioned.

なお、上記製造方法で用いる本発明のベーカリー用小片状油脂組成物は、1種でもよいが、2種以上を同時に、又は、別々に添加してもよい。 The bakery piece-like oil / fat composition of the present invention used in the above production method may be one kind, or two or more kinds may be added at the same time or separately.

なお、本発明のベーカリー生地は、ホイロをとらずに冷凍又は冷蔵してもよいし、ホイロをとった後に冷凍又は冷蔵してもよい。 The bakery dough of the present invention may be frozen or refrigerated without removing the proof, or may be frozen or chilled after removing the proof.

次に本発明のベーカリー製品について述べる。
本発明のベーカリー製品は、上記のベーカリー生地の加熱品である。加熱品の種類としては、焼成品、フライ品、蒸し品及び電子レンジ加熱品が挙げられるが、焼成品であることが好ましい。なお、本発明のベーカリー製品の具体的な製法としては、上記のベーカリー生地を通常のベーカリー生地と同様に、必要に応じ、分割し、丸めたり、延展したり、更に打抜く等の成形、型入れ、ホイロ等を行なった後、焼成、フライ、蒸す、電子レンジ加熱等の加熱工程に供することにより、得ることができる。
また、本発明のベーカリー生地が冷凍生地である場合は、解凍後、あるいは解凍することなく常法に従い、加熱してベーカリー製品とすることができる。
Next, the bakery product of the present invention will be described.
The bakery product of the present invention is a heated product of the above-mentioned bakery dough. Examples of the type of the heated product include a fired product, a fried product, a steamed product, and a microwave oven-heated product, and the fired product is preferable. As a specific manufacturing method of the bakery product of the present invention, the above-mentioned bakery dough is divided, rolled, stretched, further punched, etc. as necessary, as in the case of ordinary bakery dough. It can be obtained by subjecting it to a heating step such as baking, frying, steaming, or microwave heating after putting it in, proofing, or the like.
When the bakery dough of the present invention is a frozen dough, it can be heated according to a conventional method after thawing or without thawing to obtain a bakery product.

また、本発明のベーカリー生地を焼成等の加熱工程に供して得られたベーカリー製品は、冷凍保存することが可能であり、冷凍保存した該ベーカリー製品は、電子レンジで解凍調理することが可能である。 Further, the bakery product obtained by subjecting the bakery dough of the present invention to a heating step such as baking can be stored frozen, and the frozen stored bakery product can be thawed and cooked in a microwave oven. is there.

油脂Aとして、パーム油分別硬部油、パーム油分別中部油、及びシア脂分別硬部油を使用した。油脂Bとして菜種油を使用した。その他の油脂として、パーム油分別軟部油のランダムエステル交換油脂、パーム油分別硬部油のランダムエステル交換油脂、及び、パーム油:パーム極度硬化油=65:35の混合油脂のランダムエステル交換油脂を使用した。これらの油脂を表1に記載の配合し、下に記載の製造方法で、実施例1〜12及び比較例1〜9のベーカリー用小片状油脂組成物A〜Uを得た。なお、表1中の数値は質量部である。
実施例1〜12及び比較例1〜9のベーカリー用小片状油脂組成物A〜Uの
(1)S3、S2m、S2d及びSm2を合計した含有量
(2)(StStSt+PPP+StOSt+POSt+POP)/(StStSt+PPP+S2m+S2d+Sm2)
(3)(StStSt+PPP)/(StStSt+PPP+StOSt+POSt+POP)
As the oil and fat A, palm oil-separated hard part oil, palm oil-separated central part oil, and shea butter-separated hard part oil were used. Rapeseed oil was used as the fat B. Other fats and oils include random transesterified oils and fats of palm oil separated soft parts oil, random transesterified fats and oils of palm oil separated hard parts oils, and random transesterified fats and oils of mixed oils of palm oil: palm extremely hydrogenated oil = 65:35. used. These fats and oils were blended as shown in Table 1 and the bakery fragment fats and oils compositions A to U of Examples 1 to 12 and Comparative Examples 1 to 9 were obtained by the production method described below. The numerical values in Table 1 are parts by mass.
The total content of (1) S3, S2m, S2d and Sm2 of the bakery flaky oil and fat compositions A to 12 of Examples 1 to 12 and Comparative Examples 1 to 9 (2) (StStSt + PPP + StOSt + POSt + POP) / (StStSt + PPP + S2m + S2d + Sm)
(3) (StStSt + PPP) / ( StStSt + PPP + StOSt + POSt + POP)

<ベーカリー用小片状油脂組成物の製造方法>
表1に記載の油相原料を70℃で加温溶解し、表1に記載水相原料を70℃で加温溶解し、油相に水相を添加して油中水型に乳化し、これを急冷可塑化し、水分18質量%の可塑性油脂組成物を得た。この可塑性油脂組成物を20℃で24時間調温し、カッターで10mm角の立方体に細断し、実施例1〜12及び比較例1〜9のベーカリー用小片状油脂組成物A〜Uを得た。
<Manufacturing method of small piece oil and fat composition for bakery>
The oil phase raw material shown in Table 1 was heated and dissolved at 70 ° C., the aqueous phase raw material shown in Table 1 was heated and dissolved at 70 ° C., and the aqueous phase was added to the oil phase to emulsify into a water-in-oil type. This was rapidly cooled and plasticized to obtain a plastic oil / fat composition having a water content of 18% by mass. The temperature of this plastic oil / fat composition was adjusted at 20 ° C. for 24 hours, and the mixture was cut into cubes of 10 mm square with a cutter to obtain the bakery fragmentary oil / fat compositions A to U of Examples 1 to 12 and Comparative Examples 1 to 9. Obtained.

<ベーカリー試験>
上記ベーカリー用小片状油脂組成物A〜Uを使用し、下記の配合及び製法でパン生地、及びパンを得た。ここで、製パン工程における、(i)ベーカリー用小片状油脂組成物添加混合状態、及び、(ii)パン生地の状態を下記の評価基準に従って目視で確認した。結果を表2に記載する。また、(iii)得られたベーカリー製品の油脂粒部分の食感について下記の評価基準に従って評価を行い、評価結果を併せて表3に記載した。
<Bakery test>
Using the above-mentioned small pieces of bakery oil and fat compositions A to U, bread dough and bread were obtained by the following formulation and manufacturing method. Here, in the bread making step, (i) the mixed state of adding the small oil and fat composition for bakery and (ii) the state of the bread dough were visually confirmed according to the following evaluation criteria. The results are shown in Table 2. In addition, (iii) the texture of the oil and fat granules of the obtained bakery product was evaluated according to the following evaluation criteria, and the evaluation results are also shown in Table 3.

(ベーカリー生地配合・製法)
強力粉70質量部、生イースト4質量部、イーストフード0.1質量部、上白糖3質量部及び水40質量部をミキサーボウルに投入し、フックを使用し、低速で3分、中速で2分混合し、中種生地を得た。捏ね上げ温度は26℃であった。この中種生地を生地ボックスに入れ、温度28℃、相対湿度85%の恒温室で2時間、中種醗酵を行なった。終点温度は29℃であった。この中種醗酵の終了した生地を再びミキサーボウルに投入し、更に、薄力粉30質量部、異性化液糖(固形分70質量%)18質量部、脱脂粉乳3質量部、食塩1.5質量部及び全卵(正味)5質量部、水15質量部を添加し、低速で3分、中速で3分ミキシングした。ここで、練込油脂(マーガリン:油分80質量%)8質量部を投入し、フックを使用し、低速で3分、中速で4分ミキシングを行ない、菓子パン生地を得た。この時点での生地温度は31℃であった。
該菓子パン生地の油分含量は該菓子パン生地に含まれる澱粉類100質量部に対して、6.4質量部、糖類含量は該菓子パン生地に含まれる澱粉類100質量部に対して固形分として15.6質量部であった。
得られた菓子パン生地100質量部に、ベーカリー用小片状油脂組成物15質量部(対粉添加量は30質量部)を添加し、更に低速で1分混合し、パン生地を得た。ここで、フロアタイムを30分とった後、60gに分割・丸目を行ない、次いでベンチタイムを30分とった後、丸め成形し、38℃、相対湿度80%で50分ホイロをとった後、190℃に設定した固定オーブンに入れ、12分焼成して、パンを得た。
(Bakery dough formulation / manufacturing method)
Put 70 parts by mass of strong flour, 4 parts by mass of raw yeast, 0.1 parts by mass of yeast food, 3 parts by mass of white sugar and 40 parts by mass of water into a mixer bowl, and use a hook for 3 minutes at low speed and 2 parts at medium speed. The mixture was mixed for a minute to obtain a medium seed dough. The kneading temperature was 26 ° C. The medium seed dough was placed in a dough box and fermented in a constant temperature room at a temperature of 28 ° C. and a relative humidity of 85% for 2 hours. The end point temperature was 29 ° C. The dough that has been fermented with medium seeds is put into a mixer bowl again, and further, 30 parts by mass of soft flour, 18 parts by mass of isomerized liquid sugar (solid content 70% by mass), 3 parts by mass of defatted milk powder, and 1.5 parts by mass of salt. And 5 parts by mass of whole egg (net) and 15 parts by mass of water were added and mixed at low speed for 3 minutes and at medium speed for 3 minutes. Here, 8 parts by mass of kneaded fat (margarine: oil content 80% by mass) was added, and mixing was performed at low speed for 3 minutes and medium speed for 4 minutes using a hook to obtain a sweet bread dough. The dough temperature at this point was 31 ° C.
The oil content of the sweet bread dough was 6.4 parts by mass with respect to 100 parts by mass of starches contained in the sweet bread dough, and the sugar content was 15. It was 6 parts by mass.
To 100 parts by mass of the obtained sweet bread dough, 15 parts by mass of a bakery piece-like oil / fat composition (the amount added to flour was 30 parts by mass) was added, and the mixture was further mixed at a low speed for 1 minute to obtain a bread dough. Here, after setting the floor time to 30 minutes, divide and round to 60 g, then set the bench time to 30 minutes, then round the molding, take a 50-minute oven at 38 ° C. and 80% relative humidity, and then take a proof. It was placed in a fixed oven set at 190 ° C. and baked for 12 minutes to obtain bread.

<評価基準>
・(i)ベーカリー用小片状油脂組成物添加混合状態
◎:割れながら生地中に均質に分散した。
○:割れることなく伸びた形で生地中に均質に分散した。
△:硬すぎて生地に均質に入っていかなかった。
×:軟らかすぎて生地に練りこまれてしまう、又は、脆いため油脂粒が細かくなりすぎてしまう
・(ii)パン生地の状態
◎:ボウルへの付着が全くなく、べたつきのない生地であった。
○:ややボウルへの付着はあるものの、べたつきの殆ど感じられない生地であった。
△:ボウルに大部分が張り付き、べたつきが強い生地だった。
×:ボウルに張り付いて剥がれない状態であり、激しいべたつきのある生地であった。
・(iii)得られたベーカリー製品の油脂粒部分の食感
◎:良好な口溶けを有していた。
○:やや油性感はあるが良好な口溶けを有していた。
△:油性感が強く、口溶けがやや悪いものであった。
×:ねっとりとした油性感が強く口溶けが不良であった。
N:油脂粒部分が確認できなかった。
<Evaluation criteria>
-(I) Small piece of oil and fat composition for bakery added and mixed state ⊚: It was uniformly dispersed in the dough while cracking.
◯: It was uniformly dispersed in the dough in a stretched form without cracking.
Δ: It was too hard to enter the dough uniformly.
X: The dough is too soft and kneaded into the dough, or the oil and fat grains become too fine because it is brittle. (Ii) State of the bread dough ◎: The dough was not sticky without sticking to the bowl.
◯: Although there was some adhesion to the bowl, the dough was almost non-sticky.
Δ: Most of the dough was sticky to the bowl, and the dough was very sticky.
X: The dough was sticky to the bowl and could not be peeled off, and was extremely sticky.
(Iii) Texture of the oil and fat granules of the obtained bakery product ⊚: Good melting in the mouth.
◯: There was a slight oily feeling, but it had a good melting in the mouth.
Δ: The oily feeling was strong, and the melting in the mouth was slightly poor.
X: The oily feeling was strong and the melting in the mouth was poor.
N: The oil and fat particles could not be confirmed.

Claims (7)

ベースとなるパン生地に分散させるためのベーカリー用小片状油脂組成物であって、
油相のトリグリセリド組成が下記の条件(1)及び(2)を満たすベーカリー用小片状油脂組成物。
(1)S3、S2m、S2d及びSm2を合計した含有量が50〜80質量%である。
(2)(StStSt+PPP+StOSt+POSt+POP)/(StStSt+PPP+S2m+S2d+Sm2)=0.50〜0.90
ただし、
S:炭素数16〜18の飽和脂肪酸
m:炭素数16〜18のモノ不飽和脂肪酸
d:炭素数16〜18のポリ不飽和脂肪酸
S3:炭素数16〜18の飽和脂肪酸が3個結合したトリグリセリド
S2m:炭素数16〜18の飽和脂肪酸が2個、炭素数16〜18のモノ不飽和脂肪酸が1個結合したトリグリセリド
S2d:炭素数16〜18の飽和脂肪酸が2個、炭素数16〜18のポリ不飽和脂肪酸が1個結合したトリグリセリド
Sm2:炭素数16〜18の飽和脂肪酸が1個、炭素数16〜18のモノ不飽和脂肪酸が2個結合したトリグリセリド
PPP:パルミチン酸が3個結合したトリグリセリド
StStSt:ステアリン酸が3個結合したトリグリセリド
StOSt:1、3位にステアリン酸、2位にオレイン酸が結合したトリグリセリド
POSt:1、3位にステアリン酸及びパルミチン酸、2位にオレイン酸が結合したトリグリセリド
POP:1、3位にパルミチン酸、2位にオレイン酸が結合したトリグリセリド
である。
A bakery piece-like oil / fat composition for dispersing in the base bread dough.
A small oil / fat composition for bakery in which the triglyceride composition of the oil phase satisfies the following conditions (1) and (2).
(1) The total content of S3, S2m, S2d and Sm2 is 50 to 80% by mass.
(2) (StStSt + PPP + StOSt + POSt + POP) / (StStSt + PPP + S2m + S2d + Sm2) = 0.50 to 0.90
However,
S: Saturated fatty acids with 16 to 18 carbon atoms m: Monounsaturated fatty acids with 16 to 18 carbon atoms d: Polyunsaturated fatty acids with 16 to 18 carbon atoms S3: Triglyceride in which three saturated fatty acids with 16 to 18 carbon atoms are bonded S2m: Triglyceride in which two saturated fatty acids having 16 to 18 carbon atoms and one monounsaturated fatty acid having 16 to 18 carbon atoms are bonded S2d: Two saturated fatty acids having 16 to 18 carbon atoms and 16 to 18 carbon atoms Triglyceride with one polyunsaturated fatty acid Sm2: Triglyceride with one saturated fatty acid with 16-18 carbon atoms and two monounsaturated fatty acids with 16-18 carbon atoms PPP: Triglyceride with three palmitic acids bonded StStSt: Triglyceride with 3 stearic acids StOSt: 1 Triglyceride with stearic acid at 3rd position and oleic acid at 2nd position POSt: 1 with stearic acid and palmitic acid at 3rd position and oleic acid at 2nd position Triglyceride POP: A triglyceride in which palmitic acid is bound at the 3-position and oleic acid is bound at the 2-position.
更に油相のトリグリセリド組成が下記の(3)を満たす請求項1記載のベーカリー用小片状油脂組成物。
(3)(StStSt+PPP)/(StStSt+PPP+StOSt+POSt+POP)≦0.5
The bakery fragmentary oil / fat composition according to claim 1, wherein the triglyceride composition of the oil phase satisfies the following (3).
(3) (StStSt + PPP) / (StStSt + PPP + StOSt + POSt + POP) ≤0.5
(1)S3、S2m、S2d及びSm2を合計した含有量が55〜80質量%である請求項1又は2に記載のベーカリー用小片状油脂組成物。(1) The bakery piece-like oil / fat composition according to claim 1 or 2, wherein the total content of S3, S2m, S2d and Sm2 is 55 to 80% by mass. ベースとなるパン生地が、澱粉類100質量部に対して5〜30質量部の油脂を含有する生地である、請求項1〜3の何れか1項に記載のベーカリー用小片状油脂組成物。The small piece of fat or oil composition for bakery according to any one of claims 1 to 3, wherein the base bread dough is a dough containing 5 to 30 parts by mass of fat and oil with respect to 100 parts by mass of starch. 請求項1〜4の何れか1項記載のベーカリー用小片状油脂組成物を分散状態で含有するパン生地。 Any one bakery small pieces fat composition bread dough containing a dispersed state according to claim 1-4. 請求項に記載のパン生地の加熱品であるベーカリー製品。 Bakery products is heated products of bread dough according to claim 5. ベースとなるパン生地に請求項1〜4の何れか1項記載のベーカリー用小片状油脂組成物を分散させるパン生地の製造方法。 Method for producing a bread dough which bread dough disperse the bakery small pieces fat composition according to any one of claims 1-4 as a base.
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