JP3422508B2 - Oil composition - Google Patents

Oil composition

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Publication number
JP3422508B2
JP3422508B2 JP03981593A JP3981593A JP3422508B2 JP 3422508 B2 JP3422508 B2 JP 3422508B2 JP 03981593 A JP03981593 A JP 03981593A JP 3981593 A JP3981593 A JP 3981593A JP 3422508 B2 JP3422508 B2 JP 3422508B2
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JP
Japan
Prior art keywords
cream
starch
oil
baked
fat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP03981593A
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Japanese (ja)
Other versions
JPH06253736A (en
Inventor
悟 小堀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Adeka Corp
Original Assignee
Asahi Denka Kogyo KK
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Application filed by Asahi Denka Kogyo KK filed Critical Asahi Denka Kogyo KK
Priority to JP03981593A priority Critical patent/JP3422508B2/en
Publication of JPH06253736A publication Critical patent/JPH06253736A/en
Application granted granted Critical
Publication of JP3422508B2 publication Critical patent/JP3422508B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Edible Oils And Fats (AREA)

Description

【発明の詳細な説明】 【0001】 【産業上の利用分野】本発明は耐熱性に優れた油脂組成
物、詳しくはクッキー類、スナック類等の焼き菓子の生
地にあらかじめセンタークリームとして内包してから焼
き菓子の生地と共に焼成することが可能な油脂組成物に
関する。 【0002】 【従来の技術及び発明が解決しようとする課題】現在、
クッキー類やスナック類等の焼き菓子にクリームを付加
した形の多種多様の複合菓子が市販されている。その中
に、焼き菓子のセンターにクリームを内包したものが多
数見られるが、ほとんどの製品は穀粉生地の焼成後にク
リームを注射針等で注入する方法で製造されている。セ
ンターにクリームを内包した焼き菓子を製造する場合、
クリームを穀粉生地で内包してから焼成できると、それ
だけ工程の簡略化が図れるため焼き菓子の生産効率が向
上するが、従来のクリーム類では穀粉生地に内包してか
ら焼成すると、クリーム自体が硬くなったり、焼成直後
は柔らかくても経時的に硬くなったり、あるいは、焼成
中にクリームの油脂分が生地に移行してクリームが目減
りしたりする等の問題が生じる。 【0003】このような焼き菓子のセンターに内包可能
な耐熱クリームを得る方法としては、クリームに分画レ
シチンとナッツ類を配合する方法(特開昭64─399
46号公報)、オカラ粉末を配合する方法(特公昭58
─51739号公報)、及び砂糖とHLB値が10以上
のポリグリセリン脂肪酸エステルを配合する方法(特公
平2─11220号公報)等がある。 【0004】しかしナッツ類、オカラ粉末等を配合する
方法は、ナッツ類、オカラ粉末が独特の風味・色を有し
ているため、チョコレートクリームやナッツクリーム等
の製造には適用し得るが、ミルク味クリーム、バニラク
リーム、オレンジクリーム、ストロベリークリーム、ピ
ーチクリーム等、大多数のクリームの製造には、ナッツ
類、オカラ粉末等の風味や色が隠せないため困難であっ
た。また、ポリグリセリン脂肪酸エステルを配合する方
法も、クリームの甘さを加減する為にナッツ類や黄粉等
を加えることになるため、同様の問題があった。 【0005】従って本発明の目的は、焼き菓子のセンタ
ークリームとして用いられ、焼き菓子生地と共に焼成
されたとき硬くなったり、流れたりせず、焼成後も目
減りしたり、硬さの変化がなく、異味・異臭を呈せず
且つ白色又は淡色で思い通りの着色・着香が可能であ
り、良好な食感を呈する油脂組成物を提供することに
ある。 【0006】 【課題を解決するための手段】本発明者らは鋭意研究を
行った結果、クリームの主要構成成分として、油脂に、
α−化架橋エーテル澱粉を配合した油脂組成物が上記目
的を達成し得ることを知見した。本発明は、上記知見に
基づいてなされたもので、焼き菓子の生地にあらかじめ
センタークリームとして内包してから焼き菓子の生地と
共に焼成される油脂組成物であって、可塑性油脂100
重量部に、α−化架橋エーテル澱粉10〜200重量部
を配合してなることを特徴とする油脂組成物を提供する
ものである。 【0007】以下に本発明の油脂組成物について詳述す
る。本発明の油脂組成物に配合されるα−化架橋エーテ
ル澱粉の原料澱粉としては、馬鈴薯澱粉、甘藷澱粉、サ
ゴ澱粉、タピオカ澱粉、コーンスターチ、ワキシー、コ
ーンスターチ、米澱粉、小麦澱粉、豆澱粉等の天然澱粉
が挙げらる。 【0008】本発明の油脂組成物に用いられるα−化架
橋エーテル澱粉は、澱粉にあらかじめ架橋剤及びエーテ
ル化剤を作用させ、得られた架橋エーテル澱粉をα−化
することによって製造される。上記架橋エーテル澱粉は
常法に従って澱粉に架橋剤とエーテル化剤を反応させて
得られる。上記架橋エーテル澱粉は、澱粉に架橋剤のみ
を作用させた後、エーテル化させて製造しても良いが、
エーテル化と架橋反応とを同時に行って製造された架橋
エーテル澱粉が好ましい。この際の好ましい架橋剤とし
ては、メタリン酸塩、オキシ塩化リン、エピクロルヒド
リン、アクロレイン等が例示される。また、好ましいエ
ーテル化剤としては、エチレンオキサイド、プロピレン
オキサイド、モノクロル酢酸ソーダ等が例示され、プロ
ピレンオキサイドがより好ましい。架橋エーテル澱粉の
エーテル化の程度は、D.S. (Degree of Substituti
onの略で、澱粉のグルコース1残基あたりのエーテル基
の置換基の数を表す)0.01〜0.25が好ましい。 【0009】このようにして得られた架橋エーテル澱粉
をα−化してα−化架橋エーテル澱粉を得る。α−化
は、常法に従ってドラムドライヤー、エクストルーダー
等で処理することにより行うが、110〜170℃下
で、α化の割合が95%以上となるように処理するのが
好ましい。 架橋エーテル澱粉の架橋の程度は最終的に
α−化した後のα−化架橋エーテル澱粉の吸水度が0.
15〜0.40になるようにする。吸水度は支配的に架
橋の程度に支配されるが、その他、用いる澱粉の種類、
エーテル化度、α−化の条件によっても違ってくる。い
ずれにしてもこれらの要因を加味してα−化架橋エーテ
ル澱粉としたものの吸水度が上述の範囲になるように架
橋すればよい。 【0010】尚、ここで述べる上記吸水度は次の方法に
よって測定される。あらかじめ水を張って密閉した容器
(デシケーターが好ましい)を60℃の恒温槽に入れて
おく。シャーレにサンプルを計り取り(W0 とする)、
密閉した容器中に入れて12時間放置する。次にシャー
レを室温で30分間放置後に重量を測定する(W1 とす
る)。吸水度は以下の式で表される。 吸水度=(W1 −W0 )/W0 本発明の油脂組成物においては、上述のα−化架橋エー
テル澱粉は、1種又は2種以上を混合したものが用いら
れる。 【0011】また、本発明の油脂組成物に用いられる油
脂は可塑性油脂であり、例えば、大豆油、菜種油、米ぬ
か油、ヒマワリ油、綿実油、コーン油、パーム油、魚
油、牛脂、豚脂等の動植物油脂をそのまま若しくは水素
添加、分別、エステル交換等の処理を施したものの1種
または2種以上を混合した、融点15〜35℃程度のも
のが挙げられる。本発明の油脂組成物は,上記可塑性油
脂100重量部に、上記α−化架橋エーテル澱粉10〜
200重量部、好ましくは50〜150重量部を配合し
てなるもので、α−化架橋エーテル澱粉の配合量が上記
量未満であると油脂組成物が焼成時に飴状になって硬く
なり、上記量を超えても硬くなる。 【0012】本発明の油脂組成物は、目的(用途)に応
じて、必要に応じ砂糖、その他の添加剤が加えられて使
用される。また本発明の油脂組成物を、カレー味、チー
ズ味、ピザ味等のセイボリークリームのように砂糖のほ
とんど入らないクリームをセンタークリームとする焼き
菓子のセンタークリームとして用いる場合には、油脂組
成物中のα−化架橋エーテル澱粉の割合を増やすことに
より、目的とする焼き菓子の製造が可能となる。本発明
の油脂組成物に砂糖を添加する場合に、油脂組成物10
0重量部に対し砂糖0〜200重量部が好ましく、砂糖
としては市販品を用い得るが、吸湿を防ぐために澱粉を
数%混合して用いるのが好ましい。 【0013】さらに、本発明の油脂組成物に難消化性デ
キストリン及び/又は乳糖を配合することにより、食感
がなめらかなクリームを得ることができる。難消化性デ
キストリンは焙焼デキストリンを水に溶解し、α−アミ
ラーゼを作用させることによって製造され、さらに、ト
ランスグルコシダーゼを作用させて食物繊維含量を増加
させるのが好ましく、食物繊維含量が10〜100重量
%であるものがクリームへの配合には適している。な
お、上記食物繊維含量はプロスキー−AOAC法(月刊
フードケミカル1990−9、p69)によって測定し
た。 【0014】難消化性デキストリン及び/叉は乳糖の油
脂組成物への適正配合量は、目的とするクリームの種類
によって異なるが、α−化架橋エーテル澱粉100重量
部に対し10〜150重量部、好ましくは30〜120
重量部が焼成時のクリームの状態及び食感が良い。 【0015】 【実施例】以下、本発明の油脂組成物を、焼き菓子のセ
ンタークリームとして用いる場合の実施例及び比較例に
より具体的に説明する。 【0016】 〔実施例1〕 ミルク味クリーム入り包餡クッキー (ミルク味クリームの調製)表−1の配合の原料をミキ
サーで混合後、ロール掛けして微粉砕し、レシチン0.
3%とミルク味フレーバー0.2%を加え、30分間コ
ンチングすることによって混合し、10℃で2時間以上
固化・放置し、ミルク味クリームを調製した。 【0017】 【表1】 (クッキーの調製)表−2の配合にて常法によりクッキ
ー生地を調製し、シーターで約3mm厚にのばし、次いで
約10gを円形に型抜きして、上述の如く調製したミル
ク味クリーム約5gを包み、包餡クッキーを調製した。
これをオーブンにより上部温度200℃で15分間焼成
した。 【0018】 【表2】【0019】上記のように焼成した2種のクッキーは、
ともにクリームが硬くなったり、流れたりすることがな
く、また、クリームの経時的な硬さ変化や目減りもな
く、クリームは焼成前と同様に柔らかく、さらに、異味
・異臭がなく、クリームの色はミルク味にマッチした白
色であり、味は良好であった。また、食感は、No.2
の方がなめらかで好ましかったが、No.1でも問題な
いものであった。 【0020】〔実施例−2〕 ストロベリークリーム入
り包餡クッキー 実施例−1と同様にして、表−3の配合にレシチン0.
3%とストロベリーフレーバー0.2%を加えてストロ
ベリークリームを調製し、実施例−1で調製したクッキ
ー生地と同じクッキー生地を用いて包餡クッキーを調製
した。 【0021】 【表3】 【0022】上記包餡クッキーを実施例−1と同様にし
て焼成したクッキーは、クリームが硬くなったり、流れ
たりすることがなく、またクリームの経時的な硬さの変
化や目減りもなく、焼成前と同様に柔らかく、さらに異
味・異臭がなく、クリームの色はストロベリー味にマッ
チしたピンク色であり、食感・味はともに良好であっ
た。 【0023】〔比較例−1〕実施例−1と同様にして、
表−4の配合にてミルク味クリームを調製し、それぞれ
包餡クッキーを調製し、焼成した。 【0024】 【表4】 【0025】得られたクッキーは、何れもクリームの表
面が飴状になって硬くなる現象が見られた。 【0026】〔比較例−2〕実施例−1と同様にして、
表−5の配合にてミルク味クリームを調製し、包クッキ
ーを調製し、焼成した。 【0027】 【表5】 【0028】得られたクッキーはクリームの表面が飴状
になり、食するのに不適なものであった。 【0029】〔実施例−3〕 カレークリーム入り包餡
クッキー 実施例−1と同様にして、表−6の配合にレシチン0.
3%を加えてカレークリームを調製し、包餡クッキーを
調製し、焼成した。 【0030】 【表6】【0031】得られたクッキーはクリームが硬くなった
り、流れたりすることがなく、また、クリームの経時的
な硬さ変化や目減りもなく、焼成前と同様に柔らかく、
さらに、異味・異臭がなく、クリームの色はカレー味に
マッチした色であり、食感・味はともに良好であった。 【0032】 【発明の効果】本発明の油脂組成物は、焼き菓子のセン
タークリームとして用いられ、焼き菓子生地と共に焼
成されたとき硬くなったり、流れたりせず、焼成後も
目減りしたり、硬さの変化がなく、異味・異臭を呈せ
ず且つ白色又は淡色で、良好な食感を呈するものであ
る。
Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an oil / fat composition having excellent heat resistance, and more particularly, to a baked confectionery such as cookies and snacks, which is contained in advance as a center cream. The present invention relates to an oil / fat composition which can be baked together with baked confectionery dough. 2. Description of the Related Art
A wide variety of complex confections in which cream is added to baked confectionery such as cookies and snacks are commercially available. Among them, there are many baked goods in which cream is included in the center of baked confectionery, but most products are manufactured by a method of injecting the cream with a syringe needle or the like after baking the flour dough. When manufacturing baked goods with cream in the center,
If the cream can be included in the flour dough and then baked, the process can be simplified and the production efficiency of baked confectionery will improve, but with conventional creams, if the cream is included in the flour dough and then baked, the cream itself will be hard There is a problem that the cream becomes softer immediately after baking but becomes harder with the lapse of time, or the fats and oils of the cream migrate to the dough during baking and the cream is reduced. As a method of obtaining a heat-resistant cream that can be included in such a baked confectionery center, a method of blending fractionated lecithin and nuts with the cream (Japanese Patent Laid-Open No. 64-399)
No. 46), a method of blending okara powder (JP-B-58)
No. 51739) and a method of blending sugar and a polyglycerin fatty acid ester having an HLB value of 10 or more (Japanese Patent Publication No. 211220). However, the method of blending nuts and okara powder can be applied to the production of chocolate cream, nut cream, etc., because nuts and okara powder have a unique flavor and color. It has been difficult to produce the majority of creams, such as taste creams, vanilla creams, orange creams, strawberry creams, peach creams, etc., because the flavors and colors of nuts, okara powders and the like cannot be hidden. Also, the method of blending the polyglycerin fatty acid ester has the same problem because nuts and yellow powder are added to adjust the sweetness of the cream. [0005] Accordingly, an object of the present invention is used as the center cream baked come confectionery, or become hard when fired with baked goods dough, without or flow, after firing even or eroded, there is no change in hardness Another object of the present invention is to provide an oil / fat composition which does not exhibit an off-flavor or odor, is white or pale, can be colored and flavored as desired, and presents a good texture. Means for Solving the Problems As a result of intensive studies, the present inventors have found that fats and oils are
It has been found that an oil / fat composition containing an α-crosslinked ether starch can achieve the above object. The present invention has been made on the basis of the above findings, and has been applied to baked confectionery dough in advance.
After including it as a center cream,
A fat and oil composition to be fired together, wherein the plastic fat and oil 100
It is an object of the present invention to provide an oil or fat composition characterized by comprising 10 to 200 parts by weight of an α-linked crosslinked ether starch in parts by weight. Hereinafter, the fat and oil composition of the present invention will be described in detail. Raw material starch of α-linked cross-linked ether starch blended in the oil and fat composition of the present invention includes potato starch, sweet potato starch, sago starch, tapioca starch, corn starch, waxy, corn starch, rice starch, wheat starch, bean starch and the like. Examples include natural starch. [0008] The α-linked crosslinked ether starch used in the oil and fat composition of the present invention is produced by preliminarily reacting a starch with a crosslinking agent and an etherifying agent to α-convert the obtained crosslinked ether starch. The crosslinked ether starch is obtained by reacting a starch with a crosslinking agent and an etherifying agent according to a conventional method. The cross-linked ether starch may be manufactured by reacting only the cross-linking agent on the starch and then etherifying the starch.
Crosslinked ether starch produced by simultaneously performing etherification and crosslinking reaction is preferred. Preferred examples of the crosslinking agent at this time include metaphosphate, phosphorus oxychloride, epichlorohydrin, acrolein and the like. Preferred etherifying agents include ethylene oxide, propylene oxide, sodium monochloroacetate and the like, with propylene oxide being more preferred. The degree of etherification of the cross-linked ether starch is described in S. (Degree of Substituti
(On stands for the number of substituents of ether groups per glucose residue of starch.) 0.01 to 0.25 is preferred. The crosslinked ether starch thus obtained is α-converted to obtain an α-crosslinked ether starch. The α-formation is carried out by treating with a drum dryer, an extruder or the like according to a conventional method, but it is preferable to carry out the treatment at 110 to 170 ° C. so that the proportion of the α-formation becomes 95% or more. The degree of cross-linking of the cross-linked ether starch is such that the water absorption of the α-cross-linked cross-linked ether starch after finally being α-converted is 0.1.
15 to 0.40. The water absorption is dominantly controlled by the degree of crosslinking, but in addition, the type of starch used,
It differs depending on the degree of etherification and the condition of α-formation. In any case, the α-linked crosslinked ether starch is formed by taking these factors into consideration, but the crosslink may be performed so that the water absorption is in the above range. The above-mentioned water absorption is measured by the following method. A container (preferably a desiccator), which is previously filled with water and sealed, is placed in a thermostat at 60 ° C. Measure the sample in a Petri dish (W0),
Place in a closed container and leave for 12 hours. Next, the petri dish is left at room temperature for 30 minutes and then weighed (referred to as W1). The water absorption is represented by the following equation. Water absorption = (W1 -W0) / W0 In the fat and oil composition of the present invention, the above-mentioned α-linked crosslinked ether starch is used alone or as a mixture of two or more. The fats and oils used in the fat and oil composition of the present invention are plastic fats and oils such as soybean oil, rapeseed oil, rice bran oil, sunflower oil, cottonseed oil, corn oil, palm oil, fish oil, beef tallow, lard, etc. A mixture of one or more of animal and vegetable fats or oils which have been subjected to treatments such as hydrogenation, fractionation, transesterification or the like as they are or having a melting point of about 15 to 35 ° C. can be mentioned. The oil / fat composition of the present invention is prepared by adding 100 parts by weight of the above-mentioned plastic oil / fat to the α-linked cross-linked ether starch 10 to 10 parts by weight.
200 parts by weight, preferably 50 to 150 parts by weight, if the amount of the α-linked cross-linked ether starch is less than the above amount, the fat and oil composition becomes candy-like during firing and becomes hard, It becomes hard even if it exceeds the amount. The fat and oil composition of the present invention is used after adding sugar and other additives as necessary according to the purpose (use). When the oil or fat composition of the present invention is used as a center cream of a baked confectionery having a cream containing almost no sugar such as savory cream such as curry taste, cheese taste and pizza taste as the center cream, By increasing the proportion of the α-linked cross-linked ether starch, it is possible to produce the desired baked confectionery. When sugar is added to the oil and fat composition of the present invention, the oil and fat composition 10
The sugar is preferably 0 to 200 parts by weight with respect to 0 parts by weight. As the sugar, a commercial product can be used, but it is preferable to use a mixture of several percent of starch to prevent moisture absorption. Furthermore, by blending the indigestible dextrin and / or lactose with the oil or fat composition of the present invention, a cream having a smooth texture can be obtained. Indigestible dextrin is produced by dissolving roasted dextrin in water and reacting with α-amylase, and furthermore, it is preferred that transglucosidase is acted on to increase the dietary fiber content. What is by weight is suitable for incorporation into creams. The dietary fiber content was measured by the Prosky-AOAC method (Monthly Food Chemical 1990-9, p69). [0014] The appropriate amount of the indigestible dextrin and / or lactose in the oil composition differs depending on the type of the target cream, but is 10 to 150 parts by weight per 100 parts by weight of the α-crosslinked ether starch. Preferably 30 to 120
By weight, the cream condition and texture during baking are good. The present invention will be described in more detail with reference to Examples and Comparative Examples in which the fat and oil composition of the present invention is used as a center cream for baked confectionery. Example 1 Milk-Taste Cream-Contained Cookie (Preparation of Milk-Taste Cream) After mixing the ingredients having the composition shown in Table 1, the mixture was rolled and finely pulverized.
3% and 0.2% of milk flavor flavor were added, mixed by conching for 30 minutes, and solidified and allowed to stand at 10 ° C. for 2 hours or more to prepare a milk flavor cream. [Table 1] (Preparation of Cookies) Cookie dough is prepared according to a conventional method with the composition shown in Table 2, and is spread to a thickness of about 3 mm with a sheeter. Then, about 10 g is cut into a circular shape, and about 5 g of the milk flavor cream prepared as described above. Was wrapped to prepare a cookie.
This was baked in an oven at an upper temperature of 200 ° C. for 15 minutes. [Table 2] The two types of cookies baked as described above are:
In both cases, the cream does not harden or flow, there is no change in hardness of the cream over time and there is no loss, the cream is soft as before baking, furthermore, there is no unpleasant taste and smell, the color of the cream is The white color matched the milk taste, and the taste was good. In addition, the texture was no. 2
No. was smoother and preferred, but No. One was no problem. Example 2 Enclosed cookie with strawberry cream In the same manner as in Example 1, lecithin 0.1% was added to the composition shown in Table 3.
3% and strawberry flavor 0.2% were added to prepare a strawberry cream, and an encased cookie was prepared using the same cookie dough as the cookie dough prepared in Example-1. [Table 3] The cookie obtained by baking the above-mentioned encased cookie in the same manner as in Example 1 does not cause the cream to harden or flow, and does not change the hardness of the cream with time or lose its weight. As before, it was soft, without any off-flavors and off-flavors, and the cream color was pink, matching the strawberry flavor, and both texture and taste were good. Comparative Example 1 In the same manner as in Example 1,
Milk flavor creams were prepared according to the composition shown in Table-4, and wrapped cookies were prepared and baked. [Table 4] In each of the obtained cookies, the phenomenon that the surface of the cream became candy-like and became hard was observed. Comparative Example 2 In the same manner as in Example 1,
A milk flavor cream was prepared according to the formulation in Table 5, a cookie wrap was prepared, and baked. [Table 5] The obtained cookies had a creamy candy-like surface and were unsuitable for eating. [Example 3] In the same manner as in Example 1, the wrapped cookie containing curry cream was mixed with lecithin 0.1% in the composition shown in Table 6.
Curry cream was prepared by adding 3%, and an encased cookie was prepared and baked. [Table 6] The obtained cookies do not harden or flow the cream, have no change in the hardness of the cream with time or decrease, and are as soft as before baking.
Furthermore, there was no off-taste or off-flavor, and the color of the cream matched the curry taste, and the texture and taste were both good. The oil composition of the present invention according to the present invention is used as the center cream baked come confectionery, or become hard when fired with baked goods dough, without or flow, or ullage after firing, It has no change in hardness, does not exhibit off-flavors and off-flavors, and is white or light-colored, exhibiting good texture.

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) A23D 7/00 A21D 2/16 ──────────────────────────────────────────────────続 き Continued on front page (58) Field surveyed (Int. Cl. 7 , DB name) A23D 7/00 A21D 2/16

Claims (1)

(57)【特許請求の範囲】 【請求項1】 焼き菓子の生地にあらかじめセンターク
リームとして内包してから焼き菓子の生地と共に焼成さ
れる油脂組成物であって、可塑性油脂100重量部に、
α−化架橋エーテル澱粉10〜200重量部を配合して
なることを特徴とする油脂組成物。
(57) [Claims] [Claim 1] The center cake is added to the baked confectionery dough in advance.
It is baked together with the baked goods dough as a ream
Fat composition, 100 parts by weight of plastic fat,
An oil or fat composition comprising 10 to 200 parts by weight of an α-crosslinked ether starch.
JP03981593A 1993-03-01 1993-03-01 Oil composition Expired - Fee Related JP3422508B2 (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
JPH06253736A JPH06253736A (en) 1994-09-13
JP3422508B2 true JP3422508B2 (en) 2003-06-30

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Publication number Priority date Publication date Assignee Title
JP6446767B2 (en) * 2013-07-25 2019-01-09 不二製油株式会社 Chocolates for inclusion in bakery products and methods for producing bakery products
JP6825802B2 (en) * 2014-03-28 2021-02-03 不二製油株式会社 Manufacturing method of chocolates and bakery products for bakery products
JP6572531B2 (en) * 2014-10-28 2019-09-11 不二製油株式会社 Chocolates for bakery products and methods for producing bakery products
CN112544759A (en) * 2019-09-25 2021-03-26 嘉吉公司 Chocolate composition for baking with long-lasting fluidity and application thereof

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