TW201517802A - Fat composition, puffed wheat food product containing the fat composition, and production method for the fat composition - Google Patents

Fat composition, puffed wheat food product containing the fat composition, and production method for the fat composition Download PDF

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TW201517802A
TW201517802A TW103133044A TW103133044A TW201517802A TW 201517802 A TW201517802 A TW 201517802A TW 103133044 A TW103133044 A TW 103133044A TW 103133044 A TW103133044 A TW 103133044A TW 201517802 A TW201517802 A TW 201517802A
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oil
fat composition
fat
alginate
composition
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TW103133044A
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TWI665966B (en
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Atsushi Ohara
Toru Toda
Ichiro Hidaka
Takuya Ozawa
Yoshimune Hasome
Chihiro Miyajima
takanori Yasutake
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Nisshin Oillio Group Ltd
Kimica Corp
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    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/16Fatty acid esters
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/16Fatty acid esters
    • A21D2/165Triglycerides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/01Other fatty acid esters, e.g. phosphatides
    • A23D7/011Compositions other than spreads
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/01Other fatty acid esters, e.g. phosphatides
    • A23D7/013Spread compositions
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/007Other edible oils or fats, e.g. shortenings, cooking oils characterised by ingredients other than fatty acid triglycerides
    • A23D9/013Other fatty acid esters, e.g. phosphatides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Edible Oils And Fats (AREA)

Abstract

Provided are a fat composition which can impart volume, softness, and moistness to a puffed wheat food product or the like; a puffed wheat food product containing the fat composition; and a production method for the fat composition. The present invention provides a fat composition containing an alginic acid ester having a degree of esterification of at least 23% but less than 75%. The fat composition may be an emulsified fat composition. The present invention also provides a puffed wheat food product containing the fat composition, and a production method for the fat composition.

Description

油脂組成物、添加有該油脂組成物之小麥膨化食品、及該油脂組成物的製造方法 Oil composition, wheat expanded food to which the oil composition is added, and method for producing the oil composition

本發明關於油脂組成物,添加有該油脂組成物之小麥膨化食品、及該油脂組成物的製造方法。 The present invention relates to a fat or oil composition, a wheat expanded food to which the oil and fat composition is added, and a method for producing the oil or fat composition.

近年來,為了迎合消費者多樣化的嗜好,販賣著各式各樣的麵包類及蛋糕點心產品等小麥膨化食品。特別是需要具有膨鬆份量感的外觀,且具有柔軟感及濕潤感(帶有濕潤的口感)等口感的小麥膨化食品。 In recent years, in order to cater to the diversification of consumers, wheat floured foods such as various breads and cake snack products have been sold. In particular, a wheat puffed food having an appearance of a bulky feeling and a mouthfeel such as a soft feeling and a moist feeling (with a moist mouthfeel) is required.

作為改善小麥膨化食品的份量感的方法,可舉出使用果膠作為品質改良劑的方法(專利文獻1)、使用酸作為生麵團改良劑的方法(專利文獻2)。作為賦予小麥膨化食品柔軟感等口感的方法,可舉出將修飾澱粉及活性麩質代替一部分的小麥粉來使用的方法(專利文獻3)。 A method of using pectin as a quality improving agent (Patent Document 1) and a method of using an acid as a dough improving agent (Patent Document 2) are mentioned as a method of improving the feeling of the amount of the wheat puffed food. As a method of imparting a soft feeling such as a soft feeling to a wheat puffed food, a method in which a modified starch and an active gluten are used in place of a part of wheat flour is used (Patent Document 3).

此外,作為提升小麥膨化食品的份量感及口感的方法,添加褐藻酸酯於小麥膨化食品的方法被提出(例如,專利文獻4~7)。 In addition, as a method of improving the feeling and texture of the wheat puffed food, a method of adding alginate to the wheat puffed food is proposed (for example, Patent Documents 4 to 7).

[先前技術文獻] [Previous Technical Literature] (專利文獻) (Patent Literature)

專利文獻1:日本特開平7-289144號公報 Patent Document 1: Japanese Patent Laid-Open No. Hei 7-289144

專利文獻2:日本特開平8-256670號公報 Patent Document 2: Japanese Patent Laid-Open No. Hei 8-256670

專利文獻3:日本特開平3-87135號公報 Patent Document 3: Japanese Patent Laid-Open No. 3-87135

專利文獻4:日本特開2010-98993號公報 Patent Document 4: Japanese Laid-Open Patent Publication No. 2010-98993

專利文獻5:日本特開2013-85483號公報 Patent Document 5: Japanese Laid-Open Patent Publication No. 2013-85483

專利文獻6:日本特開2004-65245號公報 Patent Document 6: Japanese Laid-Open Patent Publication No. 2004-65245

專利文獻7:日本特開2012-24002號公報 Patent Document 7: JP-A-2012-24002

然而,以往的技術,都只有改善小麥膨化食品的份量感與口感的其中之一,有無法對小麥膨化食品一併賦予份量感、柔軟感及濕潤感的可能性。 However, in the prior art, only one of the feelings and texture of the wheat puffed food is improved, and there is a possibility that the wheat puffed food cannot be given a sense of color, softness, and moist feeling.

本發明是為了解決上述的問題而完成,其目的在於提供一種能對小麥膨化食品等賦予食品份量感、柔軟感及濕潤感的油脂組成物、添加有該油脂組成物之小麥膨化食品、及該油脂組成物的製造方法等。 The present invention has been made to solve the above problems, and an object of the present invention is to provide an oil and fat composition capable of imparting a feeling of food, softness, and moist feeling to a wheat puffed food or the like, a wheat puffed food to which the oil and fat composition is added, and A method for producing a fat or oil composition.

本發明人發現,藉由於油脂組成物中添加具有特定酯化度的褐藻酸酯,可解決上述問題,遂完成本發明。具體而言,本發明提供下述之物。 The present inventors have found that the above problems can be solved by adding alginate having a specific degree of esterification to the oil and fat composition, and the present invention has been completed. Specifically, the present invention provides the following.

(1)一種油脂組成物,其含有酯化度為23%以上且未滿75%的褐藻酸酯。 (1) A fat or oil composition comprising alginate having a degree of esterification of 23% or more and less than 75%.

(2)如(1)所述之油脂組成物,其中,前述的油脂組成物是乳化油脂組成物。 (2) The oil and fat composition according to (1), wherein the oil and fat composition is an emulsified oil composition.

(3)一種小麥膨化食品,其添加有如(1)或(2)所述之油脂組成物。 (3) A wheat puffed food comprising the oil or fat composition according to (1) or (2).

(4)如(3)所述之小麥膨化食品,其中,前述小麥膨化食品是高含水麵包(high hydrated bread)。 (4) The wheat puffed food according to (3), wherein the wheat puffed food is a high hydrated bread.

(5)一種油脂組成物的製造方法,其包含將酯化度為23%以上且未滿75%的褐藻酸酯與油脂加以混合的步驟,且前述褐藻酸酯的1質量%水溶液於20℃時的黏度是30mPa.S以上。 (5) A method for producing a fat or oil composition, comprising the steps of mixing alginate having a degree of esterification of 23% or more and less than 75% with fats and oils, and the 1% by mass aqueous solution of the alginate at 20 ° C The viscosity at the time is 30mPa. S or above.

(6)如(1)所述之油脂組成物,其中,前述褐藻酸酯的1質量%水溶液於20℃時的黏度是30mPa.S以上。 (6) The oil and fat composition according to (1), wherein the viscosity of the 1% by mass aqueous solution of the alginate at 20 ° C is 30 mPa. S or above.

依據本發明,提供一種能對小麥膨化食品等賦予份量感、柔軟感及濕潤感的油脂組成物、添加有該油脂組成物之小麥膨化食品、及該油脂組成物的製造方法。 According to the present invention, there is provided a fat or oil composition capable of imparting a feeling of a part, a soft feeling and a moist feeling to a wheat puffed food or the like, a wheat puffed food to which the oil and fat composition is added, and a method for producing the fat or oil composition.

以下說明本發明的實施型態,但本發明並不限於下述的實施型態。 Hereinafter, the embodiment of the present invention will be described, but the present invention is not limited to the embodiment described below.

[油脂組成物] [grease composition]

本發明的油脂組成物,至少包含酯化度為23%以上且未滿75%的褐藻酸酯及油脂。以下說明各成分。 The oil and fat composition of the present invention contains at least a brown alginate and a fat or oil having a degree of esterification of 23% or more and less than 75%. Each component will be described below.

(褐藻酸酯) (alginate)

褐藻酸酯是指一種具有下述結構之化合物:構成褐藻酸的羧基,至少一部分轉變成酯。褐藻酸是指一種多醣類,其 具有以2種糖醛酸(甘露糖醛酸及古羅糖醛酸)任意地進行直鏈聚合而成的構造,且富含於昆布、海帶芽等天然褐藻類中。 Alginate refers to a compound having the structure: at least a portion of a carboxyl group constituting alginic acid is converted into an ester. Alginic acid refers to a polysaccharide, It has a structure in which two types of uronic acid (mannuronic acid and guluronic acid) are linearly polymerized, and is rich in natural brown algae such as kelp and kelp buds.

褐藻酸酯,可依照周知的方法,藉由將褐藻酸進行酯化來調製。其中一例如下述所示。例如,利用藉由酸所實施的加水分解等方法,由褐藻類等獲得精製的褐藻酸。將所獲得的褐藻酸,於加壓及/或加熱條件下,與環氧丙烷進行酯化,藉此得到褐藻酸酯。供應於酯化過程的褐藻酸,亦能是藉由氫氧化鈉或是碳酸鈉等被部分中和後的褐藻酸鹽。 Alginate can be prepared by esterifying alginic acid according to a known method. One of them is shown below. For example, purified alginic acid is obtained from brown algae or the like by a method such as hydrolysis by an acid. The obtained alginic acid is esterified with propylene oxide under pressure and/or heating, thereby obtaining alginate. The alginic acid supplied to the esterification process can also be a brown alginate which is partially neutralized by sodium hydroxide or sodium carbonate.

褐藻酸酯的原料並無限定,可為天然的褐藻酸,亦可為合成的褐藻酸。 The raw material of the alginate is not limited, and may be natural alginic acid or synthetic alginic acid.

本發明的褐藻酸酯中,會混有未酯化的褐藻酸,作為這種未酯化的褐藻酸,可舉出褐藻酸及/或褐藻酸鹽。本發明中,亦將褐藻酸酯、褐藻酸及/或褐藻酸鹽之混合物,稱為「褐藻酸酯」。 In the alginate of the present invention, unesterified alginic acid is mixed, and as such unesterified alginic acid, alginic acid and/or alginate may be mentioned. In the present invention, a mixture of alginate, alginic acid and/or alginate is also referred to as "alginate".

本發明的褐藻酸酯,其酯化度為23%以上且未滿75%,較佳是35%~70%,更佳是40%~65%,最佳是45%~60%。經本發明人檢討後的結果發現,若將酯化度為上述範圍的褐藻酸酯添加於油脂組成物,意外地會得到一種油脂組成物,其能對食品等賦予份量感、柔軟感及濕潤感。若油脂組成物中的褐藻酸酯的酯化度是在上述範圍之外,則添加有該油脂組成物之食品等,其份量感、柔軟感及濕潤感中的任一種性質、或是所有的性質,會有較劣等的可能性。 The alginate of the present invention has a degree of esterification of 23% or more and less than 75%, preferably 35% to 70%, more preferably 40% to 65%, most preferably 45% to 60%. As a result of the review by the present inventors, it has been found that when a brown alginate having a degree of esterification in the above range is added to the oil and fat composition, an oil and fat composition is unexpectedly obtained, which can impart a feeling of a feeling, a soft feeling and a moist feeling to a food or the like. . When the degree of esterification of the alginate in the oil-and-fat composition is out of the above range, the food or the like to which the oil-and-fat composition is added, and any one of the feeling of feeling, softness, and moist feeling, or all of them Nature, there will be a possibility of inferiority.

「酯化度」是表示在褐藻酸酯所包含的羧基中,被酯化的羧基的比例的數值,是根據日本食品添加物公定書第8 版的「褐藻酸丙二酯的純度試驗(1)」為基準來特定而成。本發明的「褐藻酸酯的酯化度」,是指褐藻酸酯中混有褐藻酸及/或褐藻酸鹽時,由這些混合物全體所求得的酯化度,被稱為「褐藻酸酯的酯化度」。 The "degree of esterification" is a numerical value indicating the ratio of the carboxyl group esterified in the carboxyl group contained in the alginate, and is based on the 8th of the Japanese Food Additives. The "Purity test (1) of propylene glycol alginate" is specified based on the standard. The "degree of esterification of alginate" in the present invention means the degree of esterification obtained from the whole of these mixtures when alginic acid and/or alginate are mixed in the alginate, and is called "alginate." Degree of esterification."

酯化度為上述範圍的褐藻酸酯,可藉由在調製褐藻酸酯時,於進行與環氧丙烷進行酯化之際,適當地調整環氧丙烷的使用量、褐藻酸與環氧丙烷的酯化反應時間及反應溫度來得到。 The alginate having a degree of esterification in the above range can be appropriately adjusted to the amount of propylene oxide used, alginic acid and propylene oxide when esterification with propylene oxide is carried out in the preparation of alginate. The esterification reaction time and the reaction temperature are obtained.

作為本發明的褐藻酸酯,若其酯化度為上述範圍之物則無特別限定,較為合適的是,使用褐藻酸酯的1質量%水溶液於20℃時的黏度為30mPa.S以上之物,較佳為使用黏度為50mPa.S以上之物,更佳為使用黏度為80mPa.S以上之物。藉由使用具有這樣的黏度特性的褐藻酸酯,會得到容易將份量感賦予食品等的油脂組成物。褐藻酸酯的黏度越高,越具有容易將份量感賦予食品等的傾向。 The alginate of the present invention is not particularly limited as long as the degree of esterification is in the above range, and it is preferred to use a 1% by mass aqueous solution of alginate at a viscosity of 30 mPa at 20 ° C. For the above S, it is preferred to use a viscosity of 50 mPa. Above S, it is better to use a viscosity of 80mPa. Above S. By using alginate having such a viscosity characteristic, it is possible to obtain an oil and fat composition which is easy to impart a feeling of the amount to a food or the like. The higher the viscosity of the alginate, the more likely it is to impart a feeling of serving to a food or the like.

褐藻酸酯的黏度的上限並沒有特別限定,較合適的是,褐藻酸酯的1質量%水溶液於20℃時的黏度為1000mPa.S以下,較佳是500mPa.S以下,更佳是300mPa.S以下,進而更佳是160mPa.S以下。若油脂組成物中含有黏度上限為上述範圍的褐藻酸酯,將該油脂組成物添加於食品(特別是小麥膨化食品)等的時候所得到的生麵團,會變得適合加工。 The upper limit of the viscosity of the alginate is not particularly limited. Preferably, the 1% by mass aqueous solution of alginate has a viscosity of 1000 mPa at 20 ° C. Below S, preferably 500 mPa. Below S, more preferably 300mPa. S is below, and more preferably 160mPa. S below. When the fat or oil composition contains alginate having an upper limit of viscosity in the above range, the dough obtained by adding the fat or oil composition to a food (especially a wheat puffed food) or the like is suitable for processing.

褐藻酸酯的黏度,是使用黏度計(東京計器股份有限公司製,型號:TVB-10M VISCOMETER(MODEL:BM)的旋轉器No.1(旋轉數30rpm)),藉由對褐藻酸酯的1質量%水溶 液,測定其於20℃時的黏度來進行特定。 The viscosity of the alginate was measured by a viscometer (manufactured by Tokyo Keiki Co., Ltd., model: TVB-10M VISCOMETER (MODEL: BM) rotator No. 1 (rotation number 30 rpm)) Mass % water soluble The liquid was measured for its viscosity at 20 ° C to make it specific.

具有上述範圍的黏度之褐藻酸酯,是藉由調整原料也就是褐藻酸的分子量而得。具體而言,是依照周知的方法,使用經低分子化的褐藻酸作為褐藻酸酯的原料所獲得。例如,作為將褐藻酸酯進行低分子化的方法,可舉出將高分子的褐藻酸藉由酵素(褐藻酸裂解酶)進行分解的方法、將高分子的褐藻酸藉由酸或熱進行加水分解的方法等。若使用高分子的褐藻酸作為褐藻酸酯的原料,會得到高黏度的褐藻酸酯。若使用低分子的褐藻酸作為褐藻酸酯的原料,會得到低黏度的褐藻酸酯。 The alginate having a viscosity in the above range is obtained by adjusting the molecular weight of the raw material, that is, alginic acid. Specifically, it is obtained by using a low molecular weight alginic acid as a raw material of alginic acid ester according to a well-known method. For example, as a method of degrading alginate, a method of decomposing a polymer of alginic acid by an enzyme (alginate lyase), and adding a polymer of alginic acid by acid or heat may be mentioned. Decomposition method, etc. When high molecular alginate is used as a raw material of alginate, a high viscosity alginate is obtained. If low molecular alginic acid is used as a raw material for alginic acid ester, a low viscosity alginate will be obtained.

本發明的褐藻酸酯的其他特性,在不阻礙本發明目的之範圍內並無特別限定,亦可具有任意的平均分子量及分子量分布等。 The other characteristics of the alginate of the present invention are not particularly limited as long as the object of the present invention is not inhibited, and may have any average molecular weight, molecular weight distribution, and the like.

作為本發明的褐藻酸酯,就方便取得、適合食用、容易發揮本發明效果這些觀點而言,較佳是褐藻酸丙二酯。又,作為本發明的褐藻酸酯,適合使用符合日本食品添加物公定書第八版所定基準的褐藻酸酯。 The alginate of the present invention is preferably propylene glycol alginate from the viewpoint of being easily obtained, suitable for consumption, and easily exhibiting the effects of the present invention. Further, as the alginate of the present invention, alginate suitable for the standard of the eighth edition of the Japanese Food Additives Convention is suitably used.

本發明的油脂組成物,亦可含有1種以上的褐藻酸酯。本發明的油脂組成物含有數種褐藻酸酯時,各褐藻酸酯的含量,可依照欲獲得的酯化度與黏度來進行調整,油脂組成物中所含有的褐藻酸酯,是依照使整體的酯化度及黏度符合上述範圍的方式來進行調整。 The oil and fat composition of the present invention may contain one or more kinds of alginate. When the oil and fat composition of the present invention contains several kinds of alginate, the content of each alginate can be adjusted according to the degree of esterification and viscosity to be obtained, and the alginate contained in the oil and fat composition is in accordance with the whole The degree of esterification and viscosity are adjusted in such a manner as to conform to the above range.

(油脂) (grease)

作為本發明的油脂,並無特別限定,可使用通常供作食 用的油脂。例如,可舉出棕櫚油、棕櫚核油、椰子油、玉米油、棉籽油、大豆油、菜籽油、高芥酸菜籽油、芥花油、米油、葵花油、紅花油、花生油、芝麻油、橄欖油、可可脂、娑羅脂(sal fat)、牛脂、豬脂、乳脂、魚油等各種動植物性油脂。又,亦可將選自上述的各種動植物性油脂的1種或2種以上的動植物性油脂,視所需進行加工(氫化、酯交換、分離等),並將所得到的各種加工油脂作為本發明的油脂使用。上述的任一種油脂,可單獨使用,亦可將2種以上的油脂適當地調配作為混合油使用。本發明的油脂,亦可是乳化油脂。 The fat or oil of the present invention is not particularly limited, and can be used for cooking. Used grease. For example, palm oil, palm kernel oil, coconut oil, corn oil, cottonseed oil, soybean oil, rapeseed oil, canola oil, canola oil, rice oil, sunflower oil, safflower oil, peanut oil, Sesame oil, olive oil, cocoa butter, sal fat, tallow, pig fat, milk fat, fish oil and other animal and vegetable oils. In addition, one or two or more kinds of animal and vegetable oils and fats selected from the various animal and vegetable oils and fats described above may be processed (hydrogenation, transesterification, separation, etc.) as needed, and the obtained various processed fats and oils may be used as The grease of the invention is used. Any of the above-mentioned fats and oils may be used singly, or two or more kinds of fats and oils may be appropriately blended as a mixed oil. The fat or oil of the present invention may also be an emulsified fat or oil.

(油脂組成物的製造方法) (Method for producing oil composition)

本發明的油脂組成物的製造方法,並無特別限制,可基於周知的油脂組成物的製造條件及製造方法來製造。例如,依照周知的方法,可藉由將本發明的褐藻酸酯與油脂混合,並進行適當的攪拌來製造本發明的油脂組成物。 The method for producing the oil and fat composition of the present invention is not particularly limited, and can be produced based on the production conditions and production methods of known oil and fat compositions. For example, the oil and fat composition of the present invention can be produced by mixing the alginic acid ester of the present invention with fats and oils and appropriately stirring according to a known method.

油脂組成物中的褐藻酸酯的含量,並無特別限定,相對於油脂組成物整體,較佳是0.1~10質量%,更佳是0.3~5.0質量%,最佳是0.5~3.0質量%。油脂組成物中的褐藻酸酯的含量,相對於油脂即便不是過度的量,依然可發揮本發明的效果。 The content of the alginate in the oil and fat composition is not particularly limited, and is preferably 0.1 to 10% by mass, more preferably 0.3 to 5.0% by mass, most preferably 0.5 to 3.0% by mass based on the total of the oil and fat composition. The content of the alginate in the oil and fat composition can exhibit the effects of the present invention even if it is not excessively large.

油脂組成物中的油脂含量,並無特別限定,相對於油脂組成物整體,較佳是10~99質量%,更佳是30~90質量%,最佳是50~85質量%。若油脂組成物中所佔的油脂含量為上述範圍,則容易發揮本發明的效果。 The oil content in the oil and fat composition is not particularly limited, and is preferably from 10 to 99% by mass, more preferably from 30 to 90% by mass, most preferably from 50 to 85% by mass, based on the total of the oil and fat composition. When the oil and fat content in the oil and fat composition is in the above range, the effects of the present invention are easily exhibited.

本發明的油脂組成物中,依照所需,亦可含有褐藻 酸酯及油脂以外的成分(水、食鹽、乳化劑(卵磷脂、飽和脂肪酸單甘油酯等)、香料、酵素、糖分、呈味成分、增黏劑、抗氧化劑、色素等)。這些成分的種類及添加量等,可依照所欲獲得的效果來適當地調整。 The oil and fat composition of the present invention may also contain brown algae as needed Components other than acid esters and fats and oils (water, salt, emulsifier (lecithin, saturated fatty acid monoglyceride, etc.), flavors, enzymes, sugars, taste components, tackifiers, antioxidants, pigments, etc.). The type, amount, and the like of these components can be appropriately adjusted in accordance with the desired effect.

油脂組成物中含有褐藻酸酯及油脂以外的成分時,本發明的油脂組成物,可為將油相(含有褐藻酸酯、油脂及油溶性成分的狀態)與水相(含有水及水溶性成分的狀態)進行乳化的油脂組成物(意即,乳化油脂組成物),亦可為由油相所成之物。作為乳化油脂組成物,可舉出人造奶油(margarine)、食用塗脂(fat spread)等。作為由油相而成的油脂組成物,可舉出烤酥油(shortening)等。若褐藻酸酯為水合狀態,被認為容易發揮本發明的效果,因此,本發明的油脂組成物,較佳是乳化油脂組成物,特佳是人造奶油及食用塗脂。 When the oil and fat composition contains components other than alginic acid ester and fat or oil, the oil and fat composition of the present invention may be an oil phase (a state containing alginate, a fat or oil, and an oil-soluble component) and an aqueous phase (containing water and water-soluble). The fat or oil composition (that is, the emulsified oil and fat composition) which is emulsified in the state of the component may be an oil phase. Examples of the emulsified fat or oil composition include margarine, fat spread, and the like. Examples of the oil and fat composition derived from the oil phase include shortening and the like. When the alginate is in a hydrated state, it is considered that the effect of the present invention is easily exhibited. Therefore, the oil and fat composition of the present invention is preferably an emulsified fat or oil composition, and particularly preferably margarine and edible fat.

油脂組成物中含有褐藻酸酯及油脂以外的成分時,例如可藉由下述的方法來製造本發明的油脂組成物或乳化油脂組成物:將油脂與油溶性成分(卵磷脂、飽和脂肪酸單甘油酯等)混合溶解,再使褐藻酸酯分散於其中,製造油脂組成物的方法;將油脂與油溶性成分混合溶解,再使褐藻酸酯分散於其中調製油相,藉由將所得到的油相與另外調製的水相混合乳化,製造乳化油脂組成物的方法。 When the oil and fat composition contains a component other than alginic acid ester and fat or oil, for example, the oil-fat composition or the emulsified oil-and-fat composition of the present invention can be produced by the following method: oil and fat and oil-soluble component (lecithin, saturated fatty acid single) a method in which a glyceride or the like is dissolved and dissolved, and alginate is dispersed therein to produce a fat or oil composition; a fat and oil-soluble component are mixed and dissolved, and then the alginate is dispersed therein to prepare an oil phase, and the obtained oil phase is obtained. A method in which an oil phase is mixed with an additionally prepared aqueous phase to produce an emulsified oil composition.

油脂組成物具有可塑性時,較佳的是,於調製油相後或是於將油相與水相混合乳化後,進行冷卻,使油脂組成物可塑化。冷卻條件,較佳是-0.5℃/分以上,更佳是-5℃/分以上。油脂組成物的冷卻,相較於緩慢冷卻的方式, 以急速冷卻的方式為佳。作為用來冷卻所使用的機器,可舉出密閉型連續式管式冷卻機、人造奶油製造機(螺旋式熱交換器(votator)、配合器(combinator)、刮板式熱交換器(Perfector)等),板型熱交換機等。此外,亦可使用開放型的Dia冷卻器(Diacooler)與人造奶油製造器(Complector)的組合,作為用來冷卻的機器。 When the oil or fat composition has plasticity, it is preferred to emulsifie after the oil phase is prepared or after mixing the oil phase and the water phase, and then to cool the oil and fat composition. The cooling condition is preferably -0.5 ° C / min or more, more preferably - 5 ° C / min or more. Cooling of the oil composition, compared to the way of slow cooling, The method of rapid cooling is preferred. Examples of the apparatus used for cooling include a sealed continuous tube cooler, a margarine maker (a spiral heat exchanger, a combiner, a scraper heat exchanger, etc.). ), plate type heat exchangers, etc. In addition, a combination of an open Dia cooler and a synthetic cream maker can be used as a machine for cooling.

於調製油相後或是混合乳化油相與水相後,亦可對油脂組成物進行殺菌處理。作為殺菌的方法,並無特別限定,可舉出使用油槽的分批方式、使用板型熱交換機或刮取式熱交換機的連續方式。 After the oil phase is prepared or after the emulsified oil phase and the aqueous phase are mixed, the oil and fat composition may be sterilized. The method of sterilization is not particularly limited, and examples thereof include a batch method using an oil bath, and a continuous method using a plate type heat exchanger or a scraping type heat exchanger.

(小麥膨化食品) (wheat puffed food)

本發明的油脂組成物,由於可將良好的份量感、柔軟感及濕潤感,平衡地賦予食品等,因此適合使用在製造這些要求外觀性與口感的食品等。小麥膨化食品是特別要求具有優異的份量感、柔軟感及濕潤感的食品,因此本發明的油脂組成物,特別適合用於小麥膨化食品的製造。因此,本發明的油脂組成物,可適合使用作為小麥膨化食品用油脂組成物。 Since the oil and fat composition of the present invention can be imparted to a food or the like in a balanced manner with a good feeling of feeling, a soft feeling, and a moist feeling, it is suitable for use in the production of foods and the like which require the desired appearance and texture. The wheat puffed food is a food which is particularly required to have an excellent feeling, a soft feeling and a moist feeling. Therefore, the oil and fat composition of the present invention is particularly suitable for use in the production of a wheat puffed food. Therefore, the oil and fat composition of the present invention can be suitably used as a fat or oil composition for wheat expanded foods.

本發明的「小麥膨化食品」是指,於穀物粉(典型如麵粉等)中,加入水、食鹽,並依照所需加入糖類、乳製品、酵母、蛋類、添加物等,調製出經捏揉而成的生麵團後,再將生麵團進行塑形及烘烤所製造的食品。添加有本發明的油脂組成物的小麥膨化食品,除了加入本發明的油脂組成物作為生麵團成分這一點外,其餘部分可基於周知的製造方法來製造。此外,本發明的「添加」是意指,於小麥膨化食品中, 作為該食品的原料包含本發明的油脂組成物,製造小麥膨化食品時,即使失去油脂組成物中的一部分成分(水分等),所得到的小麥膨化食品仍稱為「添加本發明的油脂組成物的小麥膨化食品」。 The "puffed wheat food" of the present invention means that water, salt, and sugar, dairy products, yeast, eggs, additives, etc. are added to the grain flour (typically, flour, etc.), and the kneaded product is prepared. After the dough is kneaded, the dough is shaped and baked. The wheat puffed food to which the oil and fat composition of the present invention is added can be produced by a known production method, except that the fat or oil composition of the present invention is added as a dough component. In addition, the "addition" of the present invention means that in wheat puffed food, When the fat or oil composition of the present invention is contained as a raw material of the food, when a wheat puffed food is produced, even if a part of the components (water and the like) in the oil and fat composition are lost, the obtained wheat puffed food is referred to as "adding the fat or oil composition of the present invention". Wheat puffed food."

相對於小麥膨化食品,本發明的油脂組成物的添加量,並無特別限定,例如,相對於小麥膨化食品的生麵團的總量,可添加本發明的油脂組成物1~40質量%。 The amount of the oil and fat composition of the present invention is not particularly limited, and for example, the oil and fat composition of the present invention may be added in an amount of 1 to 40% by mass based on the total amount of the dough of the wheat expanded food.

作為小麥膨化食品的例子,可舉出如麵包類、蛋糕類、烘培點心類等。麵包類可舉出吐司麵包、特殊麵包、調理麵包(菜餚麵包)、甜點麵包、酥皮麵包製品等。這些麵包類,亦可調製作為高含水麵包。作為吐司麵包,可舉出白吐司、黑麥吐司、雜糧吐司、麵包捲(餐包、奶油捲餐包、圓形麵包等)。作為特殊麵包,可舉出瑪芬等。作為調理麵包(菜餚麵包),可舉出熱狗麵包、漢堡等。作為甜點麵包,可舉出紅豆麵包、果醬麵包、克林姆麵包、菠蘿麵包、糖霜麵包捲等。作為酥皮麵包製品,可舉出可頌麵包、丹麥麵包、派等。作為蛋糕類,可舉出海綿蛋糕、戚風蛋糕、蛋糕捲、法式海綿小餅、磅蛋糕、點心蛋糕等。作為烘培點心類,可舉出餅乾、小西點等。 Examples of the wheat puffed food include breads, cakes, and baked snacks. Examples of the bread include toast bread, special bread, conditioning bread (dish bread), dessert bread, and meringue bread products. These breads can also be prepared as high-water-containing breads. Examples of toast bread include white toast, rye toast, miscellaneous grains and toast, bread rolls (meal bags, cream rolls, round breads, etc.). As a special bread, Muffin et al. As a conditioning bread (dish bread), hot dog bread, a burger, etc. are mentioned. Examples of the dessert bread include red bean bread, jam bread, klimt bread, pineapple bread, and icing bread roll. Examples of meringue bread products include glutinous bread, danish bread, pie, and the like. As the cake, a sponge cake, a hurricane cake, a cake roll, a French sponge cake, a pound cake, a snack cake, and the like can be given. Examples of the baked snacks include biscuits, small dots, and the like.

本發明的「高含水麵包」是指,相較於一般的麵包類,麵包生麵團中的水分(水、溫水等)的添加量較多的麵包。本發明中,若調製高含水麵包作為小麥膨化食品,可得到柔軟度特別優異的小麥膨化食品。高含水麵包中,麵包生麵團中的水分的添加量,雖然會隨著所使用的穀物粉或其他原料 的種類與添加量、製造時的溫度等的製造環境而有所變化,但通常相較於一般麵包中的水分的添加量,高含水麵包中的水分的添加量,相對於穀物粉的質量,是多出1~12質量%。作為一般的麵包生麵團中的水分的添加量,舉例來說,相對於穀物粉的質量,吐司中水分的添加量是60~70質量%,奶油餐包中水分的添加量是35~60質量%,法式海綿小餅中水分的添加量是55~73質量%,甜點麵包中是40~55質量%。吐司的製造中,一般的麵包生麵團中的水分的添加量,相對於穀物粉的質量%為60~70質量%,但在製造作為高含水麵包時,水分的添加量可增加至71~82質量%為止。此外,「麵包生麵團中的水分的添加量」是指,相對於穀物粉的質量,麵包生麵團中所加入的水分的質量比例。「麵包生麵團中所加入的水分」是指,調製麵包生麵團中,作為原料水所使用的水或溫水等,並不包含源自其他的原料(例如乳製品、蛋類)的水分。 The "high-water-containing bread" of the present invention refers to a bread having a large amount of water (water, warm water, etc.) added to the bread dough compared to a general bread. In the present invention, when high-water-containing bread is prepared as a wheat-expanded food, a wheat-expanded food having particularly excellent softness can be obtained. In high-water-containing bread, the amount of moisture added to the bread dough, although it will vary with the grain flour or other ingredients used. The type of the product and the manufacturing environment such as the amount of addition and the temperature at the time of manufacture vary. However, the amount of water added to the high-water-containing bread is generally higher than the quality of the grain powder, compared to the amount of water added to the bread. It is 1 to 12% by mass. As the amount of moisture added to the bread dough in general, for example, the amount of moisture added to the toast is 60 to 70% by mass, and the amount of moisture added to the cream meal is 35 to 60. The mass %, the amount of moisture added to the French sponge cake is 55 to 73% by mass, and 40 to 55 mass% in the dessert bread. In the production of toast, the amount of moisture added to the bread dough in the general bread is 60 to 70% by mass based on the mass% of the cereal flour. However, when the bread is produced as a high-water-containing bread, the amount of moisture added can be increased to 71~ 82% by mass. In addition, "the amount of moisture added to the bread dough" means the mass ratio of the moisture added to the bread dough with respect to the mass of the grain flour. The "water added to the bread dough" means water or warm water used as raw material water in the preparation of the bread dough, and does not contain water derived from other raw materials (for example, dairy products or eggs).

本發明的褐藻酸酯,並非直接添加於小麥膨化食品的生麵團,而是作為油脂組成物中的調配成分來添加於生麵團,藉此可對小麥膨化食品賦予特別優異的份量感。小麥膨化食品的份量感的程度,可使用周知的體積計測機,藉由算出小麥膨化食品的比容積來決定。小麥膨化食品的柔軟感,是藉由感官評鑑,以判定小麥膨化食品的柔軟度(或硬度)來決定。小麥膨化食品的濕潤感,藉由感官評鑑,以判定小麥膨化食品的乾燥程度(或濕潤程度)來決定。 The alginate of the present invention is not directly added to the dough of the wheat puffed food, but is added to the dough as a blending component in the oil and fat composition, whereby the wheat puffed food can be provided with a particularly excellent feeling. The degree of the feeling of the amount of the wheat puffed food can be determined by calculating the specific volume of the wheat puffed food using a well-known volume measuring machine. The softness of the wheat puffed food is determined by sensory evaluation to determine the softness (or hardness) of the wheat puffed food. The moist feeling of the wheat puffed food is determined by sensory evaluation to determine the degree of dryness (or degree of wetting) of the puffed food of the wheat.

(實施例) (Example)

以下,藉由實施例來更詳細說明本發明,但本發明並不限於此。 Hereinafter, the present invention will be described in more detail by way of examples, but the invention is not limited thereto.

[調製例1:調製褐藻酸酯] [Modulation Example 1: Preparation of alginate]

將由褐藻類精製而成的褐藻酸,依照周知的方法,藉由酸進行水解,而得到9種褐藻酸。分別將所得到的褐藻酸,依照周知的方法,於高壓滅菌釜中,50~70℃、2~12小時的條件下,與環氧丙烷進行酯化反應,而得到9種褐藻酸丙二酯。 Alginic acid obtained by purifying brown algae is hydrolyzed by an acid according to a known method to obtain nine kinds of alginic acid. The obtained alginic acid was respectively esterified with propylene oxide in an autoclave at 50 to 70 ° C for 2 to 12 hours according to a known method to obtain 9 kinds of propylene glycol alginate. .

分別將所得到的褐藻酸丙二酯,基於下述的方法來求得酯化度及1質量%的水溶液黏度。其結果如表1所示。此外,以下表中的「褐藻酸酯」是指褐藻酸丙二酯。 The obtained propylene glycol alginate was each obtained by the following method to determine the degree of esterification and the viscosity of the aqueous solution of 1% by mass. The results are shown in Table 1. Further, "alginate" in the following table means propylene glycol alginate.

(酯化度) (degree of esterification)

依照日本食品添加物公定書第8版的「褐藻酸丙二酯純度測驗(1)」為基準,測定各種褐藻酸丙二酯的酯化度。 The degree of esterification of various propylene glycol alginate was measured in accordance with the "Molybdate Alginate Purity Test (1)" of the 8th edition of the Japanese Food Additives Convention.

(黏度) (viscosity)

使用黏度計(東京計器股份有限公司製、型號:TVB-10M VISCOMETER(MODEL:BM))的旋轉器No.1(旋轉數為30rpm),測定各種褐藻酸丙二酯的1質量%水溶液於20℃時的黏度。 Using a rotator No. 1 (rotation number: 30 rpm) of a viscometer (manufactured by Tokyo Keiki Co., Ltd., model: TVB-10M VISCOMETER (MODEL: BM)), various 1% by mass aqueous solutions of propylene glycol alginate were measured at 20 Viscosity at °C.

分別將表1中的1~9號的褐藻酸丙二酯,提供作為以下的實施例及比較例使用。此外,表1中,3~8號的褐藻酸丙二酯相當於本發明的褐藻酸酯。 The propylene glycol alginate Nos. 1 to 9 in Table 1 were used as the following examples and comparative examples. Further, in Table 1, propylene glycol alginate of Nos. 3 to 8 corresponds to the alginate of the present invention.

[調製例2:調製含有褐藻酸酯的油脂組成物(食用塗脂)] [Preparation Example 2: Preparation of a fat-containing composition containing alginate (edible fat)]

使用表1中任一種褐藻酸丙二酯,基於表2的配方,將油脂(菜籽油及棕櫚油)及乳化劑(卵磷脂及飽和脂肪酸單甘油酯)融解混合,並使褐藻酸丙二酯分散於其中來調製油相。接下來,將食鹽溶於水中調製水相。混合所得到的油相及水相,進行預備乳化,獲得預備乳化物。將所得到的預備乳化物,依照常法,使用配合器將其急速冷卻進行可塑化,而得到含有1質量%褐藻酸丙二酯之油脂組成物(食用塗脂)。 Using any of the propylene glycol alginate in Table 1, based on the formulation of Table 2, the oil (canola oil and palm oil) and the emulsifier (lecithin and saturated fatty acid monoglyceride) were melted and mixed, and the alginic acid was used. The ester is dispersed therein to prepare an oil phase. Next, the salt is dissolved in water to prepare an aqueous phase. The obtained oil phase and aqueous phase were mixed and pre-emulsified to obtain a preliminary emulsion. The prepared preliminary emulsion was rapidly cooled and plasticized using a blender according to a usual method to obtain a fat or oil composition (food fat) containing 1% by mass of propylene glycol alginate.

此外,表2中的各種材料詳述如下。 In addition, the various materials in Table 2 are detailed below.

菜籽油:日清奧利友集團股份有限公司製,商品名「日清芥花籽油」。 Rapeseed oil: manufactured by Nisshin Olympus Group Co., Ltd., trade name "Nissin Mustard Seed Oil".

棕櫚油:日清奧利友集團股份有限公司製造品。 Palm oil: manufactured by Nissin Aoliyou Group Co., Ltd.

飽和脂肪酸單甘油酯:理研vitamin股份有限公司製,商品名「Emaruji-P-100」。 Saturated fatty acid monoglyceride: manufactured by Riken Vitamin Co., Ltd., trade name "Emaruji-P-100".

卵磷脂:日清奧利友集團股份有限公司製,商品名「Lecithin DX」。 Lecithin: manufactured by Nisshin Olympus Group Co., Ltd., trade name "Lecithin DX".

[製造例1:吐司的製造(70%中種法)-I] [Manufacturing Example 1: Manufacturing of Toast (70% of the Medium Method) - I]

使用上述的調製例2所調製的食用塗脂,基於表3的生麵團配方及表4的步驟,製造方型吐司及圓頂型吐司。又,除了油脂組成物中不含有褐藻酸丙二酯這一點以外,其餘皆基於表3的生麵團配方及表4的步驟,製造用來對照的方型吐司及圓頂型吐司。下述表中的「對照」,是指對照的方型吐司及圓頂型吐司。 Using the edible fat prepared in the above Preparation Example 2, a square toast and a dome-shaped toast were produced based on the dough formulation of Table 3 and the procedure of Table 4. Further, in addition to the fact that the oil and fat composition did not contain propylene glycol alginate, the square toast and dome-shaped toast used for the control were produced based on the dough formulation of Table 3 and the procedure of Table 4. The "control" in the following table refers to the control square toast and dome-shaped toast.

此外,下述表中的「穀物粉%」是表示,將穀物粉的質量(本例中是高筋麵粉的總量)設為100時,穀物粉以外的材料相對於穀物粉的比例。 In addition, "% of cereal flour" in the following table is a ratio of the material other than the cereal flour to the cereal flour when the mass of the cereal flour (in this example, the total amount of the high-gluten flour) is 100.

此外,表3中的各種材料詳述如下。 In addition, the various materials in Table 3 are detailed below.

高筋麵粉:日清製粉股份有限公司製,商品名「camellia」。 High-gluten flour: manufactured by Nissin Milling Co., Ltd., trade name "camellia".

酵母:Oriental酵母工業股份有限公司製,商品名「Regular yeast」。 Yeast: manufactured by Oriental Yeast Industries Co., Ltd. under the trade name "Regular yeast".

脫脂奶粉:森永乳業股份有限公司製,商品名「脫脂粉 乳」。 Skim milk powder: manufactured by Morinaga Dairy Co., Ltd., trade name "grease powder milk".

油脂組成物:以上述調製例2所調製的食用塗脂。 Grease composition: Edible fat prepared by the above Preparation Example 2.

[吐司的評價] [toast's evaluation]

分別對上述所製成的吐司,以下述的方法來評價份量 感、柔軟感、及濕潤感。 The toast prepared above was evaluated for the amount of the following method. Sense, softness, and moist feeling.

(份量感的評價) (evaluation of the sense of quantity)

分別對上述所製造的圓頂型吐司,於烘烤完成的一天後,以下述的方法來評價其份量感。 The dome-shaped toast produced as described above was evaluated for the amount of the portion by the following method after one day of baking.

使用超高速雷射體積計測/非接觸CCD狹縫雷射掃描方式(ASTEX股份有限公司製,商品名「Selnac-WinVM2000」),依照下述數式,算出各吐司的比容積。 Using a super-high speed laser volume measurement/non-contact CCD slit laser scanning method (trade name "Selnac-WinVM2000", manufactured by ASTEX Co., Ltd.), the specific volume of each toast was calculated according to the following formula.

比容積=烘烤完成後的吐司的體積(cm3)/烘烤完成後的生麵團重量(g) Specific volume = volume of toast after baking (cm 3 ) / dough weight after baking (g)

接下來,將各吐司的比容積,除以對照的圓頂型吐司的比容積,作為比容積的比值算出,並依照下述基準來進行評價。其結果如表5~7所示。此外,下述表中的「-」是表示未進行評價。 Next, the specific volume of each toast was divided by the specific volume of the control dome-shaped toast, and the ratio was calculated as the ratio of the specific volume, and the evaluation was performed according to the following criteria. The results are shown in Tables 5-7. In addition, "-" in the following table means that evaluation was not performed.

◎:比容積的比值為1.02以上 ◎: The ratio of specific volume is 1.02 or more

○:比容積的比值為1.01以上且未滿1.02 ○: The ratio of the specific volume is 1.01 or more and less than 1.02.

△:比容積的比值為1.00以上且未滿1.01 △: The ratio of the specific volume is 1.00 or more and less than 1.01.

×:比容積的比值未滿1.00 ×: The ratio of the specific volume is less than 1.00

(柔軟感) (soft feeling)

分別對上述所製造的方型吐司,於烘烤完成的一天後,進行感官評價。將各種吐司的柔軟感,依照下述的基準來評價。其結果如表5~7所示。 Each of the square toasts produced above was subjected to sensory evaluation one day after the completion of baking. The soft feeling of various toasts was evaluated according to the following criteria. The results are shown in Tables 5-7.

◎:極為柔軟 ◎: Extremely soft

○:柔軟 ○: soft

△:稍硬 △: Slightly hard

×:硬 ×: hard

(濕潤感) (wet feeling)

分別對上述所製造的方型吐司,於烘烤完成的一天後,進行感官評價。將各種吐司的濕潤感,依照下述的基準來評價。其結果如表5~7所示。 Each of the square toasts produced above was subjected to sensory evaluation one day after the completion of baking. The moist feeling of various toasts was evaluated according to the following criteria. The results are shown in Tables 5-7.

◎:極為濕潤 ◎: extremely humid

○:有濕潤感 ○: There is a sense of moistness

△:口感稍乾 △: The taste is slightly dry

×:口感為乾 ×: The taste is dry

(綜合評價) (Overview)

基於上述3種的評價結果(份量感、柔軟感及濕潤感),對各吐司進行綜合評價。 Based on the above three evaluation results (partial feeling, soft feeling, and moist feeling), each toast was comprehensively evaluated.

◎:全部的評價結果為○以上 ◎: All evaluation results are ○ or more

○:全部的評價中,沒有×,且有一個△ ○: In all evaluations, there is no × and there is a △

×:評價結果的任一者皆為×,或是有2個以上的△ ×: Any one of the evaluation results is ×, or there are two or more △

如表5~7所示,可知含有本發明的油脂組成物的吐司,綜合評價為「○」以上,份量感、柔軟感及濕潤感具有良好的平衡,且任一者皆為良好。特別是,若褐藻酸酯的酯化度為43.0~63.9的範圍內,則份量感、柔軟感及濕潤感的任一者都極為良好。 As shown in Tables 5 to 7, it is understood that the toast containing the oil-and-fat composition of the present invention has a total evaluation of "○" or more, and has a good balance of the feeling of feeling, softness, and moist feeling, and is excellent in either case. In particular, when the degree of esterification of alginate is in the range of 43.0 to 63.9, any of the feeling of feeling, softness, and moist feeling is extremely excellent.

[調製例3:調製含有褐藻酸酯的油脂組成物(烤酥油)] [Preparation Example 3: Preparation of a fat composition containing alginate (baked ghee)]

使用表1中的「4」的褐藻酸丙二酯,基於表8的配方,將油脂(菜籽油及棕櫚油)及乳化劑(卵磷脂及飽和脂肪酸單甘油酯)融解混合,並使褐藻酸丙二酯分散於其中來調製油相。 接下來,將所得到的油相,依照常法,使用配合器將其急速冷卻進行可塑化,而得到含有1質量%褐藻酸丙二酯之油脂組成物(烤酥油)。各種材料的詳細資料,與調製例2相同。 Using the "4" alginate propylene glycol in Table 1, based on the formulation of Table 8, the oil (canola oil and palm oil) and the emulsifier (lecithin and saturated fatty acid monoglyceride) were melted and mixed, and the brown algae was made. The acid propylene diester is dispersed therein to prepare an oil phase. Next, the obtained oil phase was rapidly cooled and plasticized using a blender according to a usual method to obtain a fat composition (baked ghee) containing 1% by mass of propylene glycol alginate. The details of various materials are the same as in Modification 2.

[製造例2:吐司的製造(70%中種法)-II] [Manufacturing Example 2: Manufacture of Toast (70% Medium Method)-II]

使用表1中的「4」的褐藻酸丙二酯,除了表3中的油脂組成物是以上述調製例3所調製的烤酥油這一點之外,其餘皆基於表3的生麵團配方及表4的步驟,來製造出含有烤酥油的方型吐司及圓頂型吐司。 The propylene glycol alginate of "4" in Table 1 was used, except that the oil and fat composition in Table 3 was the baking ghee prepared in the above Preparation Example 3, and the rest were based on the dough formulation and the table of Table 3. Step 4 to make a square toast and a dome-shaped toast containing the ghee.

又,使用不含有褐藻酸丙二酯的油脂組成物,且將褐藻酸丙二酯與油脂組成物分開,直接添加至生麵團來製造吐司。具體而言,除了從表2的配方中剔除褐藻酸丙二酯的這一點之外,其餘皆與上述調製例2同樣地調製出油脂組成物(食用塗脂)。使用所得到的油脂組成物,基於表3的生麵團配方及表4的步驟,來製造出方型吐司及圓頂型吐司。褐藻酸丙二酯是使用表1中的「4」,於表4中的「再混揉步驟」的「混拌」步驟時,將與上述的實施例及比較例的生麵團中的褐藻酸丙二酯含量等量(相對於穀物粉0.1%)的該褐藻酸丙二酯,添加至生麵團中。 Further, a fat or oil composition containing no propylene glycol alginate was used, and propylene glycol alginate was separated from the fat and oil composition, and directly added to the dough to produce toast. Specifically, the oil and fat composition (food fat) was prepared in the same manner as in the above-described Preparation Example 2 except that the propylene glycol alginate was removed from the formulation of Table 2. Using the obtained fat and oil composition, a square toast and a dome type toast were produced based on the dough formulation of Table 3 and the procedure of Table 4. The propylene glycol alginate is the alginic acid in the dough of the above-mentioned examples and comparative examples when the "mixing" step of "remixing step" in Table 4 is used using "4" in Table 1. The propylene glycol content is equivalent (relative to 0.1% of the grain flour) of the propylene glycol alginate added to the dough.

分別對所製造的吐司,與上述「吐司的評價」相同 的方式,對份量感、柔軟感及濕潤感進行評價,進而進行綜合評價。其結果示於表9。此外,表9中的「(烤酥油)」是指,上述吐司中,含有烤酥油的吐司。又,表9中的「(直接添加)」是指,上述吐司中,將褐藻酸丙二酯直接添加至生麵團所製造的吐司。 The toast produced is the same as the above evaluation of "toast" The method is to evaluate the feeling of volume, softness, and moist feeling, and then perform comprehensive evaluation. The results are shown in Table 9. In addition, "(baked ghee)" in Table 9 means the toast which contains the baking ghee in the said toast. In addition, "(direct addition)" in Table 9 means the toast produced by directly adding propylene glycol alginate to the dough in the above-mentioned toast.

若比較使用油相而成油脂組成物的烤酥油之實施例7(表9),與使用乳化油脂組成物的食用塗脂之實施例3(表6),雖然兩者所含的褐藻酸酯是同一種,前者在份量感及柔軟感卻稍顯低劣。因此,本發明的油脂組成物,調製成乳化油脂組成物的話,被認為更容易發揮本發明的效果。乳化油脂組成物更容易發揮本發明的效果的理由,被認為是與褐藻酸酯在乳化油脂組成物中進行水合作用有關。 Comparing Example 7 (Table 9) of the baking ghee using the oil phase to the oil composition, and Example 3 (Table 6) of the edible coating using the emulsified oil composition, although the alginate contained in both It is the same kind, the former is slightly inferior in weight and softness. Therefore, when the oil and fat composition of the present invention is prepared into an emulsified fat or oil composition, it is considered that the effects of the present invention are more easily exhibited. The reason why the emulsified oil and fat composition more easily exerts the effects of the present invention is considered to be related to the hydration of the alginate in the emulsified oil and fat composition.

又,本發明的褐藻酸酯,能賦予麵包更佳的份量感與柔軟感的方式,並非直接添加於生麵團中,而是藉由調配於油脂組成物中來使用。 Further, the alginate of the present invention can be used by blending it in a fat or oil composition, without adding it directly to the dough, in a manner that imparts a better sense of breadiness and softness to the bread.

[製造例3:甜點麵包的製造(70%中種法)] [Production Example 3: Manufacturing of dessert bread (70% of the method)]

使用表1中的「4」的褐藻酸丙二酯,並基於表10的生 麵團配方及表11的步驟,來製造甜點麵包。又,除了油脂組成物中不含褐藻酸丙二酯這一點之外,其餘皆基於表10的生麵團配方及表11的步驟,來製造對照的甜點麵包。 Use "4" of propylene glycol alginate in Table 1, and based on the life of Table 10. The dough recipe and the steps in Table 11 were used to make dessert bread. Further, the control dessert bread was produced based on the dough formulation of Table 10 and the procedure of Table 11 except that the oil and fat composition did not contain propylene glycol alginate.

此外,表10中的各種材料詳述如下。 In addition, the various materials in Table 10 are detailed below.

高筋麵粉:日清製粉股份有限公司製,商品名「camellia」。 High-gluten flour: manufactured by Nissin Milling Co., Ltd., trade name "camellia".

酵母:Oriental酵母工業股份有限公司製,商品名「Regular yeast」。 Yeast: manufactured by Oriental Yeast Industries Co., Ltd. under the trade name "Regular yeast".

脫脂奶粉:森永乳業股份有限公司製,商品名「脫脂粉乳」。 Skim milk powder: manufactured by Morinaga Dairy Co., Ltd., trade name "skimmed milk powder".

油脂組成物:以上述調製例2所調製的食用塗脂。 Grease composition: Edible fat prepared by the above Preparation Example 2.

含有本發明的油脂組成物的甜點麵包,相較於對照的甜點麵包,更具有份量感。又,若實際品嘗,相對於對照的甜點麵包有較硬、乾的口感,含有本發明的油脂組成物的甜點麵包,具有良好的柔軟感,且強烈地感受到濕潤感。 The dessert bread containing the fat or oil composition of the present invention has a feeling of weight compared to the control dessert bread. Further, in actual taste, the dessert bread having a hard and dry texture with respect to the control, and the dessert bread containing the fat or oil composition of the present invention have a good soft feeling and strongly feel a moist feeling.

[製造例4:吐司(高含水麵包)的製造(70%中種法)-III] [Production Example 4: Manufacture of toast (high-water-containing bread) (70% of the medium method)-III]

添加表1中的「5」的褐藻酸丙二酯,使用與上述調製例2相同的方式所調製而成的食用塗脂(油脂組成物),基於表12的生麵團配方及表4的步驟,來調製麵包生麵團,該麵包生麵團添加有相對於穀物粉(高筋麵粉)的總量為80質量%的水,來製造高含水麵包。又,除了油脂組成物中不含褐藻酸丙二酯這一點之外,其餘皆基於表12的生麵團配方及表4的步驟,來製造對照的高含水麵包。以下,表格中的「對照」是指,對照的高含水麵包。 Adding "5" alginate propylene glycol in Table 1 to an edible fat (oil composition) prepared in the same manner as in Preparation Example 2, based on the dough formulation of Table 12 and the steps of Table 4. To prepare a bread dough, the bread dough was added with water in an amount of 80% by mass based on the total amount of the cereal flour (high-gluten flour) to produce a high-water-containing bread. Further, in addition to the fact that the oil and fat composition did not contain propylene glycol alginate, the control was based on the dough formulation of Table 12 and the procedure of Table 4 to produce a control high-water-containing bread. Hereinafter, "control" in the table means a control high-water-containing bread.

此外,表10中的各種材料詳述如下。 In addition, the various materials in Table 10 are detailed below.

高筋麵粉、酵母及脫脂奶粉:使用與製造例3相同之物。 High-gluten flour, yeast, and skim milk powder: The same materials as in Production Example 3 were used.

生麵團改良劑:Oriental酵母工業股份有限公司製,商品名「C Oriental Food」。 Dough improver: manufactured by Oriental Yeast Industries Co., Ltd. under the trade name "C Oriental Food".

[高含水麵包的評價] [Evaluation of high-water-containing bread]

分別將所製造的高含水麵包,與上述[吐司的評價]同樣地對份量感及濕潤感進行評價,進而進行綜合評價。此外,關於柔軟感,基於下述的基準來進行評價。其結果如表13所示。 Each of the produced high-water-containing breads was evaluated for the amount of feeling and the moist feeling in the same manner as in the above [Evaluation of Toast], and further comprehensive evaluation was performed. In addition, the soft feeling was evaluated based on the following criteria. The results are shown in Table 13.

(柔軟感) (soft feeling)

分別對上述所製造的高含水麵包,於烘烤完成的一天後,進行感官評價。將各高含水麵包的柔軟感,依照下述的基準來評價。 Each of the high-water-containing breads produced above was subjected to sensory evaluation one day after the completion of baking. The soft feeling of each high-water-containing bread was evaluated according to the following criteria.

◎:極為柔軟 ◎: Extremely soft

○:柔軟 ○: soft

△:稍有黏牙感 △: slightly sticky feeling

×:有黏牙感 ×: There is a sticky feeling

如表13所示,對照的高含水麵包缺乏柔軟感,且具有稍顯粗糙的口感,相對於此,含有本發明的油脂組成物的高含水麵包,除了具有較良好的份量感及優異的濕潤感,亦具有優異的柔軟感。 As shown in Table 13, the comparative high-water-containing bread lacked a soft feeling and had a slightly rough texture. On the other hand, the high-water-containing bread containing the oil-and-fat composition of the present invention had a better portion feeling and excellent moisturization. It also has an excellent soft feeling.

Claims (5)

一種油脂組成物,其含有酯化度為23%以上且未滿75%的褐藻酸酯。 An oil and fat composition comprising alginate having a degree of esterification of 23% or more and less than 75%. 如請求項1所述之油脂組成物,其中,前述的油脂組成物是乳化油脂組成物。 The oil and fat composition according to claim 1, wherein the oil and fat composition is an emulsified fat or oil composition. 一種小麥膨化食品,其添加有如請求項1或2所述之油脂組成物。 A wheat puffed food comprising the fat or oil composition according to claim 1 or 2. 如請求項3所述之小麥膨化食品,其中,前述小麥膨化食品是高含水麵包。 The wheat puffed food according to claim 3, wherein the wheat puffed food is a high-water-containing bread. 一種油脂組成物的製造方法,其包含將酯化度為23%以上且未滿75%的褐藻酸酯與油脂加以混合的步驟,且前述褐藻酸酯的1質量%水溶液於20℃時的黏度是30mPa.S以上。 A method for producing a fat or oil composition, comprising the steps of mixing alginate having a degree of esterification of 23% or more and less than 75% with a fat or oil, and viscosity of the 1% by mass aqueous solution of the alginate at 20 ° C It is 30mPa. S or above.
TW103133044A 2013-09-30 2014-09-24 Oil and fat composition, wheat puffed food to which the oil and fat composition is added, and method for producing the oil and fat composition TWI665966B (en)

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