TWI632959B - Titanium composite and titanium for hot rolling - Google Patents
Titanium composite and titanium for hot rolling Download PDFInfo
- Publication number
- TWI632959B TWI632959B TW105124190A TW105124190A TWI632959B TW I632959 B TWI632959 B TW I632959B TW 105124190 A TW105124190 A TW 105124190A TW 105124190 A TW105124190 A TW 105124190A TW I632959 B TWI632959 B TW I632959B
- Authority
- TW
- Taiwan
- Prior art keywords
- titanium
- layer
- surface layer
- thickness
- hot rolling
- Prior art date
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 324
- 239000010936 titanium Substances 0.000 title claims abstract description 317
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 312
- 239000002131 composite material Substances 0.000 title claims abstract description 54
- 238000005098 hot rolling Methods 0.000 title claims description 90
- 239000002344 surface layer Substances 0.000 claims abstract description 159
- 239000010410 layer Substances 0.000 claims abstract description 144
- 229910001069 Ti alloy Inorganic materials 0.000 claims abstract description 63
- 239000000203 mixture Substances 0.000 claims abstract description 40
- 239000000126 substance Substances 0.000 claims abstract description 36
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 22
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 19
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 14
- 229910052742 iron Inorganic materials 0.000 claims abstract description 13
- 239000012535 impurity Substances 0.000 claims abstract description 12
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 229910052718 tin Inorganic materials 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 203
- 210000001161 mammalian embryo Anatomy 0.000 claims description 73
- 238000002844 melting Methods 0.000 claims description 34
- 230000008018 melting Effects 0.000 claims description 34
- 239000010949 copper Substances 0.000 claims description 17
- 238000005304 joining Methods 0.000 claims description 4
- 239000010953 base metal Substances 0.000 claims description 3
- 230000004927 fusion Effects 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 abstract description 134
- 238000007254 oxidation reaction Methods 0.000 abstract description 134
- 229910052710 silicon Inorganic materials 0.000 abstract description 21
- 238000010438 heat treatment Methods 0.000 description 101
- 238000000034 method Methods 0.000 description 50
- 239000000956 alloy Substances 0.000 description 43
- 229910045601 alloy Inorganic materials 0.000 description 39
- 238000004519 manufacturing process Methods 0.000 description 31
- 238000010894 electron beam technology Methods 0.000 description 29
- 238000012360 testing method Methods 0.000 description 29
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 21
- 238000005275 alloying Methods 0.000 description 20
- 238000005096 rolling process Methods 0.000 description 19
- 239000011261 inert gas Substances 0.000 description 17
- 238000000137 annealing Methods 0.000 description 16
- 238000005097 cold rolling Methods 0.000 description 16
- 238000005266 casting Methods 0.000 description 15
- 229910052760 oxygen Inorganic materials 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 11
- 238000004453 electron probe microanalysis Methods 0.000 description 11
- 229910017604 nitric acid Inorganic materials 0.000 description 11
- 238000012545 processing Methods 0.000 description 11
- 238000005253 cladding Methods 0.000 description 10
- 238000005554 pickling Methods 0.000 description 10
- 238000003466 welding Methods 0.000 description 10
- 238000005422 blasting Methods 0.000 description 9
- 238000005336 cracking Methods 0.000 description 9
- 239000011148 porous material Substances 0.000 description 9
- 230000007797 corrosion Effects 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000007711 solidification Methods 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000011162 core material Substances 0.000 description 7
- 238000005520 cutting process Methods 0.000 description 7
- 239000000155 melt Substances 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 206010040844 Skin exfoliation Diseases 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000005488 sandblasting Methods 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 229910000975 Carbon steel Inorganic materials 0.000 description 4
- 238000005204 segregation Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000010962 carbon steel Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000011135 tin Substances 0.000 description 3
- 150000003608 titanium Chemical class 0.000 description 3
- 239000011800 void material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910000883 Ti6Al4V Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 210000002257 embryonic structure Anatomy 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 238000009703 powder rolling Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910000905 alloy phase Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- -1 for example Inorganic materials 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004093 laser heating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000003584 silencer Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K15/00—Electron-beam welding or cutting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/04—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating by means of a rolling mill
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/18—High-melting or refractory metals or alloys based thereon
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Metal Rolling (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015149396 | 2015-07-29 | ||
| JP2015-149396 | 2015-07-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201718119A TW201718119A (zh) | 2017-06-01 |
| TWI632959B true TWI632959B (zh) | 2018-08-21 |
Family
ID=57884389
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW105124190A TWI632959B (zh) | 2015-07-29 | 2016-07-29 | Titanium composite and titanium for hot rolling |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP6515359B2 (ja) |
| TW (1) | TWI632959B (ja) |
| WO (1) | WO2017018514A1 (ja) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111278581B (zh) * | 2017-10-26 | 2021-10-01 | 日本制铁株式会社 | 钛热轧板的制造方法 |
| US10913991B2 (en) | 2018-04-04 | 2021-02-09 | Ati Properties Llc | High temperature titanium alloys |
| US11001909B2 (en) | 2018-05-07 | 2021-05-11 | Ati Properties Llc | High strength titanium alloys |
| US11268179B2 (en) | 2018-08-28 | 2022-03-08 | Ati Properties Llc | Creep resistant titanium alloys |
| CN114807790B (zh) * | 2022-04-25 | 2023-08-29 | 银邦金属复合材料股份有限公司 | 一种星用器件抗辐射层状复合材料及其制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11179566A (ja) * | 1997-02-14 | 1999-07-06 | Nkk Corp | チタンクラッド鋼板およびその製造法 |
| JP2004056090A (ja) * | 2002-05-31 | 2004-02-19 | Nippon Steel Corp | 磁気特性の優れた一方向性電磁鋼板およびその製造方法 |
| TW201144797A (en) * | 2010-02-23 | 2011-12-16 | Thk Co Ltd | Titanium material, rolling device including component composed of titanium material, and method of manufacturing titanium material |
| WO2014163086A1 (ja) * | 2013-04-01 | 2014-10-09 | 新日鐵住金株式会社 | 熱間圧延用チタン鋳片およびその製造方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5579988A (en) * | 1995-06-09 | 1996-12-03 | Rmi Titanium Company | Clad reactive metal plate product and process for producing the same |
| JP4516440B2 (ja) * | 2004-03-12 | 2010-08-04 | 株式会社神戸製鋼所 | 耐高温酸化性および耐食性に優れたチタン合金 |
| JP2016128171A (ja) * | 2013-04-01 | 2016-07-14 | 新日鐵住金株式会社 | 表面疵の発生し難いチタン熱間圧延用スラブおよびその製造方法 |
-
2016
- 2016-07-29 WO PCT/JP2016/072336 patent/WO2017018514A1/ja active Application Filing
- 2016-07-29 TW TW105124190A patent/TWI632959B/zh not_active IP Right Cessation
- 2016-07-29 JP JP2017530940A patent/JP6515359B2/ja active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11179566A (ja) * | 1997-02-14 | 1999-07-06 | Nkk Corp | チタンクラッド鋼板およびその製造法 |
| JP2004056090A (ja) * | 2002-05-31 | 2004-02-19 | Nippon Steel Corp | 磁気特性の優れた一方向性電磁鋼板およびその製造方法 |
| TW201144797A (en) * | 2010-02-23 | 2011-12-16 | Thk Co Ltd | Titanium material, rolling device including component composed of titanium material, and method of manufacturing titanium material |
| WO2014163086A1 (ja) * | 2013-04-01 | 2014-10-09 | 新日鐵住金株式会社 | 熱間圧延用チタン鋳片およびその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2017018514A1 (ja) | 2018-05-24 |
| WO2017018514A1 (ja) | 2017-02-02 |
| TW201718119A (zh) | 2017-06-01 |
| JP6515359B2 (ja) | 2019-05-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |