TWI619568B - Operation method of sintering machine - Google Patents

Operation method of sintering machine Download PDF

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TWI619568B
TWI619568B TW104135338A TW104135338A TWI619568B TW I619568 B TWI619568 B TW I619568B TW 104135338 A TW104135338 A TW 104135338A TW 104135338 A TW104135338 A TW 104135338A TW I619568 B TWI619568 B TW I619568B
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raw material
sintering
chute
fine powder
speed
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TW104135338A
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Chinese (zh)
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TW201622848A (en
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Yuji Iwami
Kazumi Iwase
Nobuyuki Ooyama
Tetsuya Yamamoto
Takahide Higuchi
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Jfe Steel Corp
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/16Sintering; Agglomerating
    • C22B1/20Sintering; Agglomerating in sintering machines with movable grates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B21/00Open or uncovered sintering apparatus; Other heat-treatment apparatus of like construction
    • F27B21/02Sintering grates or tables
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D2003/0034Means for moving, conveying, transporting the charge in the furnace or in the charging facilities
    • F27D2003/0039Means for moving, conveying, transporting the charge in the furnace or in the charging facilities comprising magnetic means
    • F27D2003/004Magnetic lifters

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • General Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

本發明提出燒結機的操作方法,其在將含有起磁性微粉原料的燒結調配原料燒結時,可使燒結原料裝入層的通氣性良好而實現燒結性的提高。本發明的燒結機的操作方法將燒結調配原料經由背面配設磁鐵而成的滑槽而裝入至燒結機的台車上進行燒結,在將所述燒結調配原料中的起磁性微粉原料裝入至台車上時,在將未對該滑槽上賦予磁力時的所述燒結調配原料的速度為零時的速度設為ν1 時,以所述滑槽下端部的所述起磁性微粉原料的速度ν成為1/5ν1 ~4/5ν1 的速度的方式,對所述磁鐵的磁力FM 進行調整。The invention provides a method for operating a sintering machine. When sintering a sintering blended raw material containing a magnetic fine powder raw material, the sintering raw material charging layer can have good air permeability and improve the sinterability. The operation method of the sintering machine of the present invention loads the sintering preparation raw material into a trolley of the sintering machine through a chute provided with a magnet on the back side for sintering, and loads the magnetically fine powder raw material in the sintering preparation raw material to When the speed of the sintered blended raw material when the magnetic force is not applied to the chute is zero, the speed is set to ν 1 , and the speed of the magnetically fine powdered raw material at the lower end of the chute is set to ν 1 . A mode in which ν becomes a speed of 1 / 5ν 1 to 4 / 5ν 1 adjusts the magnetic force F M of the magnet.

Description

燒結機的操作方法Operation method of sintering machine

本發明是有關於一種燒結調配原料的裝入方法中具有特徵的燒結機的操作方法。本發明特別提出如下的燒結機的操作方法,其將比普通的燒結原料容易磁化的含有磁鐵礦系微粉鐵礦石或燒結返礦(return ore)等起磁性(magnetizable)微粉原料的燒結調配原料裝入至燒結機的台車(pallet)上而進行燒結。 The present invention relates to a method for operating a sintering machine having a characteristic in a method for loading a sintered raw material. The present invention particularly proposes a method for operating a sintering machine that sinters and mixes magnetically fine powder-containing raw materials such as magnetite-based fine iron ore or sintering return ore, which are easier to magnetize than ordinary sintering raw materials. The raw materials are loaded on a pallet of a sintering machine and sintered.

作為高爐煉鐵法的主原料的燒結礦如圖1所示,藉由如下而製造,即,將除包含鐵礦石粉、軋屑或煉鐵塵等煉鐵廠內回收粉、燒結礦篩下粉(燒結返礦)外,亦包含如石灰石或白雲石般的含CaO原料、如生石灰般的造粒助劑、如焦粉、無煙煤般的碳材(固體燃料)等的燒結調配原料,裝入至DL燒結機的台車上而燒結。上述燒結調配原料使用如下原料,即,利用筒型混合機(drum mixer)等將多種燒結原料粉混合,繼而進行造粒,藉此形成算術平均徑為6.0mm以下的準粒子。如此獲得的燒結礦製造用的原料,即,燒結調配原料為用以裝入至燒結機的台車上,而形成僅稱作裝入層的燒結原料裝入層的原料。 As shown in FIG. 1, the sinter ore, which is the main raw material of the blast furnace ironmaking method, is produced by sieving the recovered powder and sintered ore in an ironmaking plant except for iron ore powder, crumbs, and ironmaking dust. In addition to powder (sintering and returning to ore), it also contains sintering and mixing raw materials such as limestone or dolomite containing CaO-containing raw materials, granulation aids such as quicklime, carbon materials such as coke powder, and anthracite (solid fuel). The sintering is carried out on a trolley of a DL sintering machine. As the sintering preparation raw material, a plurality of sintering raw material powders are mixed with a drum mixer or the like, and then granulated to form quasi-particles having an arithmetic mean diameter of 6.0 mm or less. The raw material for sinter ore production thus obtained, that is, the raw material for sinter preparation is a raw material for loading into a trolley of a sintering machine to form a sintering raw material loading layer called a loading layer.

一般而言,所述燒結原料裝入層的厚度(高度)為400mm~800mm左右。之後,該燒結原料裝入層在設置於台車的上 方的點火爐中,對該燒結原料裝入層中所含的碳材點火,然後經由配設於所述台車下的風箱將該燒結原料裝入層中的空氣向下方抽吸,藉此使該燒結原料裝入層中的碳材依次燃燒,並且使該燃燒配合台車的移動逐漸向下方且前方進行,利用此時產生的燃燒熱,使該燒結調配原料熔融,而變為燒結塊。之後,將所獲得的燒結塊粉碎後利用冷卻器加以冷卻、整粒,形成包含規定粒度(例如5.0mm以上)的聚集體(agglomerate)的成品燒結礦。 Generally, the thickness (height) of the sintering raw material charging layer is about 400 mm to 800 mm. After that, the sintering raw material charging layer is placed on the trolley. In the square igniter, the carbon material contained in the sintered raw material charging layer is ignited, and then the air in the sintered raw material charging layer is sucked downward through a bellows arranged under the trolley, whereby The carbon materials charged in the sintering raw material layer are sequentially burned, and the movement of the combustion cooperation trolley is gradually performed downward and forward, and the sintering preparation raw material is melted by the combustion heat generated at this time to become a sintered block. After that, the obtained sintered block is pulverized and then cooled by a cooler and granulated to form a finished sintered ore including aggregates (agglomerate) having a predetermined particle size (for example, 5.0 mm or more).

燒結礦的生產量一般由燒結生產率(t/hr.m2)×燒結機面積(m2)而決定。然而,燒結礦的生產量根據燒結機的機寬或機長、原料堆積層的厚度(燒結原料層的厚度)、燒結調配原料的體積密度、燒結(燃燒)時間、良率等而發生變化。而且,為了使該燒結礦的生產量增加,有效的是改善燒結原料裝入層的通氣性(壓損)而縮短燒結時間,或者提高粉碎前的燒結塊的冷強度而提高良率等。 The production amount of sintered ore is generally determined by sintering productivity (t / hr.m 2 ) × sintering machine area (m 2 ). However, the production amount of the sintered ore varies depending on the width or length of the sintering machine, the thickness of the raw material accumulation layer (thickness of the sintered raw material layer), the bulk density of the sintered blended raw material, the sintering (burning) time, and the yield. Further, in order to increase the production amount of the sintered ore, it is effective to improve the air permeability (pressure loss) of the sintering raw material charging layer and shorten the sintering time, or to increase the cold strength of the sintered block before pulverization to improve the yield and the like.

近年來,對於所述燒結調配原料中調配的鐵礦石粉,存在Al2O3、SiO2等紋石成分增加,另一方面,Fe成分降低的傾向。因此,高爐或轉爐中的爐渣的產生量增加,該爐渣的處理成為大的負擔。與此相對,先前,被稱作所謂起磁性微粉原料的材料的有效利用正受到關注,例如至今一直未作為燒結用原料而使用的鐵成分(FeO)多且微粉(250μm以下)多的磁鐵礦系微粉鐵礦石、軋屑、煉鐵塵等。 In recent years, with regard to the iron ore powder blended in the sintered blending raw material, there has been an increase in the grain size components such as Al 2 O 3 and SiO 2 , while the Fe content tends to decrease. Therefore, the amount of slag generated in the blast furnace or the converter is increased, and the processing of the slag becomes a large burden. On the other hand, effective use of materials called so-called magnetic fine powder raw materials has attracted attention. For example, magnets with many iron components (FeO) and fine powder (250 μm or less) have not been used as raw materials for sintering. Mineral powdered iron ore, crumbs, ironmaking dust, etc.

表1表示普通的鐵礦石A、鐵礦石B及磁鐵礦系微粉鐵 礦石或燒結返礦、軋屑、煉鐵塵(高爐塵、煉鋼塵等)等起磁性微粉原料的化學成分及平均粒徑的一例。該些起磁性微粉原料的特徵在於通常含有比粉鐵礦石多的鐵成分(FeO)。然而,如圖2所示,磁鐵礦系微粉鐵礦石或煉鐵塵等起磁性微粉原料的粒徑雖不及粒狀粉礦(pellet feed)般細,但比普通的燒結用粉鐵礦石微細,容易導致燒結處理步驟中的通氣性劣化,因此有降低燒結礦的生產性之虞。 Table 1 shows ordinary iron ore A, iron ore B, and magnetite-based fine iron An example of the chemical composition and average particle size of magnetic fine powder raw materials such as ore, sintering re-ore, slag, ironmaking dust (blast furnace dust, steelmaking dust, etc.). These magnetic fine powder raw materials are generally characterized by containing more iron components (FeO) than fine iron ore. However, as shown in FIG. 2, although the particle size of magnetic fine powder raw materials such as magnetite-based fine iron ore or ironmaking dust is not as fine as that of a pellet feed, it is smaller than that of ordinary sintering fine iron ore. The fine stone is liable to cause deterioration of the air permeability in the sintering process step, so there is a concern that the productivity of the sintered ore may be reduced.

在將微粉原料用作燒結原料時,先前作出用以有效利用普通的微粉鐵礦石的努力嘗試。例如,專利文獻1中提出如下方法:對調配階段中所述微粉鐵礦石與成為核的粉鐵礦石的比率進行調整,而形成微粉礦石有效率地附著於核的周圍的準粒子,藉此提高原料的造粒性且抑制通氣性的劣化。 When using a fine powder raw material as a sintering raw material, an attempt has been made to effectively use ordinary fine powder iron ore. For example, Patent Document 1 proposes a method of adjusting the ratio of the finely powdered iron ore to the nucleated fine iron ore in the preparation stage to form quasi-particles that the finely pulverized ore efficiently adheres to the periphery of the core, and This improves the granulation property of the raw material and suppresses the deterioration of the air permeability.

進而,專利文獻2中提出用以製造燒結調配原料的技術,即,在使用微粉礦石的情況下,將該微粉礦石在其他生產線 進行粉碎-攪拌,並混合黏合劑,藉此提高造粒性。 Furthermore, Patent Document 2 proposes a technique for producing a sintered blended raw material, that is, when a fine powder ore is used, the fine powder ore is used in another production line. The granulation is improved by pulverizing and stirring, and mixing the binder.

[現有技術文獻] [Prior Art Literature]

[專利文獻] [Patent Literature]

[專利文獻1]日本專利特開2008-101263號公報 [Patent Document 1] Japanese Patent Laid-Open No. 2008-101263

[專利文獻2]日本專利特開2007-77512號公報 [Patent Document 2] Japanese Patent Laid-Open No. 2007-77512

如上所述,現有技術中,在使用微粉鐵礦石等作為燒結調配原料的構成成分的情況下,首先,對實現造粒性的提高進行研究。例如,在專利文獻1的方法中,若今後粉礦石的紋石成分的含量或微粉礦右等的使用量進一步增加,則有用以形成準粒子的核粒子與微粉的比率不相適,成為核的粉礦石的比率成為生產性的限制之虞。而且,專利文獻2中,磁鐵礦系微粉鐵礦石並不及粒狀粉礦般小,因而仍存在需要重新對其進行粉碎步驟、及需要使用黏合劑等而成本增高的課題。 As described above, in the prior art, when using finely powdered iron ore or the like as a constituent component of a sintered blending raw material, first, research to achieve improvement in granulation property was performed. For example, in the method of Patent Document 1, if the content of the molybdenum component of the fine ore or the use amount of the fine ore is further increased in the future, the ratio of the core particles and the fine powder that are used to form the quasi-particles is not suitable and becomes a core. The ratio of fine ore becomes a limitation of productivity. Furthermore, in Patent Document 2, the magnetite-based fine powder iron ore is not as small as the granular powder ore, and therefore there are still problems in that the cost needs to be increased by re-pulverizing the powder and using a binder.

因此,本發明的目的在於提出燒結機的操作方法,其在將含有起磁性微粉原料的燒結調配原料燒結時,使燒結原料裝入層的通氣性良好而可實現燒結性的提高。 Therefore, an object of the present invention is to provide a method for operating a sintering machine, which can improve the sinterability of the sintering raw material charging layer when sintering the sintering preparation raw material containing the magnetic fine powder raw material, so that the sintering property can be improved.

本發明是為了解決所述課題開發而成,所述課題是使用含有大量成為燒結原料裝入層的通氣性劣化原因的起磁性微粉原料的燒結調配原料時的課題。即,本發明為一種燒結機的操作方 法,將燒結調配原料經由背面配設磁鐵而成的滑槽裝入至燒結機的台車上而進行燒結,所述燒結機的操作方法的特徵在於:所述燒結調配原料中的5質量%~30質量%為如下的起磁性微粉原料,即,FeO的含量為4.5質量%以上,粒徑以算術平均徑計具有0.2mm~2.5mm的大小,且其中250μm以下的微粉量以重量比例計為60質量%以下,在將該起磁性微粉原料裝入至台車上時,在將未對該滑槽賦予磁力(FM)時(FM=0)的滑槽下端部的所述燒結調配原料的速度設為ν1時,以所述滑槽下端部的所述起磁性微粉原料的速度νm成為1/5ν1~4/5ν1的速度的方式,對所述磁鐵的磁力FM進行調整。 The present invention has been developed in order to solve the above-mentioned problem, which is a problem when using a sintered blended raw material that contains a large amount of a magnetically fine powdered raw material that causes the air permeability deterioration of the sintered raw material charging layer. That is, the present invention is a method for operating a sintering machine. The sintering and preparing raw materials are loaded into a trolley of a sintering machine and sintered through a chute formed by magnets on the back side. The method of operating the sintering machine is characterized in that: 5 to 30% by mass of the sintered preparation raw material is a magnetically fine powder raw material, that is, the content of FeO is 4.5% by mass or more, and the particle diameter has a size of 0.2 mm to 2.5 mm in terms of the arithmetic mean diameter, and wherein The amount of fine powder of 250 μm or less is 60% by mass or less in terms of weight ratio. When the magnetic fine powder raw material is loaded on a trolley, the magnetic force (F M ) is not applied to the chute (F M = 0). When the speed of the sintered preparation raw material at the lower end of the chute is set to ν 1 , the speed of the magnetic fine powder raw material ν m at the lower end of the chute is set to a speed of 1 / 5ν 1 to 4 / 5ν 1 To adjust the magnetic force F M of the magnet.

本發明的所述燒結機的操作方法中,如下為更佳的構成:(1)所述250μm以下的微粉量以重量比例計為5質量%以上,(2)所述滑槽下端部的所述起磁性微粉原料的速度νm為2/5ν1~3/5ν1的速度,(3)所述滑槽下端部的所述起磁性微粉原料的速度νm在0.0004N~0.01N的範圍內調整所述磁鐵的磁力FM,(4)所述磁鐵的磁力FM為由下述式求出的數值, In the method for operating the sintering machine according to the present invention, a more preferable configuration is as follows: (1) the amount of the fine powder of 250 μm or less is 5% by mass or more in terms of weight ratio, and (2) the position of the lower end of the chute The speed ν m of the magnetic fine powder raw material is a speed of 2 / 5ν 1 to 3 / 5ν 1 ; (3) the speed ν m of the magnetic fine powder raw material at the lower end of the chute is in the range of 0.0004N to 0.01N. Internally adjust the magnetic force F M of the magnet, (4) the magnetic force F M of the magnet is a value obtained by the following formula,

m:質量(kg) m: mass (kg)

g:重力加速度(m/s2) g: acceleration of gravity (m / s 2 )

θ:滑槽角度(rad) θ: chute angle (rad)

μ:原料與滑槽的摩擦係數(-) μ: friction coefficient between raw material and chute (-)

kv2:空氣阻力(N) kv 2 : air resistance (N)

v0:初始速度(m/s) v 0 : initial speed (m / s)

v1:滑槽下端的速度(m/s) v 1 : speed at the lower end of the chute (m / s)

L:滑槽長度(m) L: Chute length (m)

LM:磁鐵板的長度(m) L M : length of magnet plate (m)

FM:磁力(N) F M : magnetic force (N)

(5)所述起磁性微粉原料中,該原料中的至少5質量%~15質量%為燒結返礦,剩餘部分包含磁鐵礦系微粉鐵礦石、軋屑及煉鐵塵中的任一種以上。 (5) In the magnetic fine powder raw material, at least 5 mass% to 15 mass% of the raw material is sintering return ore, and the remaining portion includes any one of magnetite-based fine powder iron ore, rolling slag and ironmaking dust the above.

根據本發明的燒結機的操作方法,在使用背面配置磁鐵而成的滑槽將包含起磁性微粉原料的燒結調配原料裝入至燒結機的台車上時,可確實地使該燒結調配原料中的該起磁性微粉原料選擇性地堆積(偏析裝入)至燒結原料裝入層的上層部,因而可抑制燒結原料裝入層的通氣性的劣化。其結果,可實現燒結礦的製造中的生產率、良率、冷強度等品質的提高。 According to the operation method of the sintering machine of the present invention, when a sintering compounding material containing magnetic fine powder raw materials is loaded on a trolley of a sintering machine using a chute formed with a magnet disposed on the back surface, the sintering compounding material in the sintering compounding material can be reliably made. The magnetic fine powder raw material is selectively deposited (segregated into the upper layer portion of the sintering raw material charging layer), so that deterioration of the air permeability of the sintering raw material charging layer can be suppressed. As a result, it is possible to improve quality such as productivity, yield, and cold strength in the production of sintered ore.

10‧‧‧碳系固體燃料(焦粉) 10‧‧‧ Carbon-based solid fuel (coke powder)

12‧‧‧石灰石 12‧‧‧ Limestone

14‧‧‧粉狀鐵礦石 14‧‧‧ Powdery Iron Ore

16‧‧‧造粒機 16‧‧‧ Granulator

18‧‧‧燒結礦 18‧‧‧ Sinter

20‧‧‧煙囪 20‧‧‧ Chimney

22‧‧‧吸風機 22‧‧‧ Suction fan

24‧‧‧燒結機 24‧‧‧Sintering machine

26‧‧‧集塵機 26‧‧‧ Dust Collector

28‧‧‧點火爐 28‧‧‧Ignition stove

30‧‧‧粉碎機 30‧‧‧ Crusher

32‧‧‧篩 32‧‧‧ sieve

34‧‧‧裝入裝置 34‧‧‧ Loading device

36‧‧‧空氣 36‧‧‧ air

38‧‧‧燃燒‧熔融帶 38‧‧‧combustion‧melting zone

40‧‧‧排風機 40‧‧‧Exhaust Fan

42‧‧‧起磁成分原料 42‧‧‧ from magnetic ingredients

44‧‧‧傾斜滑槽 44‧‧‧inclined chute

46‧‧‧磁鐵 46‧‧‧Magnet

48‧‧‧起磁性微粉原料 48‧‧‧ from magnetic fine powder raw materials

50‧‧‧燒結調配原料粒子 50‧‧‧ Sintered raw material particles

52‧‧‧料斗 52‧‧‧hopper

54‧‧‧帶式輸送機 54‧‧‧Belt Conveyor

56‧‧‧台車 56‧‧‧ trolley

58‧‧‧馬達 58‧‧‧Motor

60‧‧‧取樣盒 60‧‧‧Sampling box

圖1是說明DL燒結製程的示意圖。 FIG. 1 is a schematic diagram illustrating a DL sintering process.

圖2是表示起磁性微粉原料等的粒度分佈的圖。 FIG. 2 is a diagram showing a particle size distribution of raw materials such as magnetic fine powder.

圖3是表示燒結原料裝入層內的溫度與壓力的分佈的圖。 FIG. 3 is a diagram showing the distribution of temperature and pressure in the sintering raw material charging layer.

圖4的(a)~圖4的(c)是燒結機內的燒結原料裝入層內的溫度分佈與良率分佈的圖。 FIGS. 4 (a) to 4 (c) are diagrams of temperature distribution and yield distribution in the sintering raw material charging layer in the sintering machine.

圖5是表示起磁性微粉原料偏析裝入至燒結原料裝入層的上層部的狀態的示意圖。 FIG. 5 is a schematic diagram showing a state in which the magnetic fine powder raw material is segregated and loaded into an upper layer portion of a sintered raw material loading layer.

圖6是說明滑槽上的粒子的移動的示意圖。 FIG. 6 is a schematic diagram illustrating the movement of particles on a chute.

圖7是表示改變磁力(FM:0.01N)而裝入起磁性微粉原料時的堆積狀況的圖。 FIG. 7 is a view showing a deposition state when a magnetic fine powder raw material is loaded while changing a magnetic force (F M : 0.01N).

圖8是表示改變磁力(FM:超過0.01N)而裝入起磁性微粉原料時的堆積狀況的圖。 FIG. 8 is a view showing a state of accumulation when a magnetic fine powder raw material is loaded while changing a magnetic force (F M : more than 0.01 N).

圖9是表示改變磁力(FM:0.004N)而裝入起磁性微粉原料時的堆積狀況的圖。 FIG. 9 is a diagram showing a deposition state when a magnetic fine powder raw material is loaded while changing a magnetic force (F M : 0.004N).

圖10是表示改變磁力(FM:0N)而裝入起磁性微粉原料時的堆積狀況的圖。 FIG. 10 is a view showing a state of accumulation when a magnetic fine powder raw material is loaded while changing a magnetic force (F M : 0N).

圖11是試驗裝置中使用的裝入機的輪廓線圖。 FIG. 11 is an outline view of a loader used in the test device.

圖12是表示使用試驗裝置裝入時的起磁性微粉原料的堆積結果的圖。 FIG. 12 is a graph showing the accumulation results of the magnetically fine powder raw materials when loaded using a test device.

圖13是表示起磁性微粉原料的調配率與生產率的關係的圖。 FIG. 13 is a graph showing the relationship between the blending ratio of magnetic fine powder raw materials and productivity.

已知堆積於台車上的燒結原料裝入層中的壓力損失如 圖3所示,是在所裝入的濕原料堆積的區域(濕潤帶)、及焦粉等碳材燃燒而進行燒結調配原料的燒結反應的區域(反應.熔融帶)中產生,在燒結反應完成後的燒結礦存在的區域(燒結礦帶)幾乎不會產生壓力損失。而且,為了提高燒結性,重要的是整體減少壓力損失而實現原料裝入層整體的通氣性的提高。 It is known that the pressure loss in the sintering raw material charging layer deposited on the trolley is as follows As shown in Fig. 3, the sintering reaction occurs in a region (reaction zone) in which the loaded wet raw material is accumulated (wet zone) and a carbon material such as coke powder is burned to perform a sintering reaction of the sintered preparation raw material. The area where the completed sinter exists (sinter zone) hardly causes pressure loss. In order to improve the sinterability, it is important to reduce the pressure loss as a whole and to improve the air permeability of the entire raw material charging layer.

在本說明書中,10表示碳系固體燃料(焦粉),12表示石灰石,14表示粉狀鐵礦石,16表示造粒機,18表示燒結礦,20表示煙囪,22表示吸風機,24表示燒結機,26表示集塵機,28表示點火爐,30表示粉碎機,32表示篩,34表示裝入裝置,36表示空氣,38表示燃燒‧熔融帶,40表示排風機,42表示起磁成分原料,44表示傾斜滑槽,46表示磁鐵,48表示起磁性微粉原料,50表示燒結調配原料粒子,52表示料斗,54表示帶式輸送機,56表示台車,58表示馬達,60表示取樣盒。 In this specification, 10 indicates a carbon-based solid fuel (coke powder), 12 indicates limestone, 14 indicates powdery iron ore, 16 indicates a granulator, 18 indicates a sintered ore, 20 indicates a chimney, 22 indicates a suction fan, and 24 indicates Sintering machine, 26 is a dust collector, 28 is an ignition furnace, 30 is a pulverizer, 32 is a sieve, 34 is a loading device, 36 is air, 38 is a combustion and melting zone, 40 is an exhaust fan, and 42 is a raw material of magnetic components. 44 indicates an inclined chute, 46 indicates a magnet, 48 indicates a magnetic powder raw material, 50 indicates a sintered raw material particle, 52 indicates a hopper, 54 indicates a belt conveyor, 56 indicates a trolley, 58 indicates a motor, and 60 indicates a sampling box.

因此,本發明中,所述燒結調配原料中,在包含因微粉成分多而通氣性劣化的磁鐵礦系微粉鐵礦石等起磁性微粉原料的情況下,有意識地使該起磁性微粉原料堆積(偏析裝入)至燒結原料裝入層的上層部,藉此使燒結反應提前結束,並且將大量調配起磁性微粉原料時的通氣性的劣化限制在最小限度,藉此解決所述問題。 Therefore, in the present invention, when the sintering preparation raw material includes a magnetic fine powder raw material such as a magnetite-based fine powder iron ore that deteriorates permeability due to a large amount of fine powder components, the magnetic fine powder raw material is intentionally made. This problem is solved by accumulating (segregating) the upper layer portion of the sintering raw material charging layer, thereby ending the sintering reaction in advance, and minimizing the deterioration of air permeability when a large amount of the magnetic fine powder raw material is prepared.

關於本發明的此種觀點,可根據圖4的(a)~圖4的(c)來理解。即,圖4的(a)表示燒結機台車上的燒結原料裝入層(以下亦簡稱作「裝入層」)的燒結調配原料的燒結過程,圖 4的(b)表示該裝入層內的燒結過程的溫度分佈(加熱曲線(heat pattern)),而且圖4的(c)表示燒結塊的良率分佈。如根據圖4的(b)可知,燒結調配原料的裝入層的上層部,比起下層部,存在溫度上升困難,且高溫區保持時間亦相對變短的傾向。因此,在該裝入層的上層部,燃燒熔融反應(燒結化反應)不充分,燒結塊的強度降低,因而如圖4的(c)所示,成為良率低而導致生產性降低的因素。 This aspect of the present invention can be understood from FIGS. 4 (a) to 4 (c). That is, FIG. 4 (a) shows the sintering process of the sintering compounding material on the sintering raw material loading layer (hereinafter also simply referred to as “loading layer”) on the sintering machine trolley. (B) of 4 shows the temperature distribution (heat pattern) of the sintering process in the built-in layer, and (c) of FIG. 4 shows the yield distribution of the sintered block. As can be seen from FIG. 4 (b), the upper layer portion of the charging layer of the sintered blended raw material tends to have a higher temperature than the lower layer portion, and tends to have a shorter holding time in the high temperature region. Therefore, in the upper part of the loading layer, the combustion-melting reaction (sintering reaction) is insufficient, and the strength of the sintered block is reduced. As shown in FIG. 4 (c), it becomes a factor that results in a low yield and a decrease in productivity. .

根據發明者等人的研究可知,針對該問題,藉由進行所謂的偏析裝入便可解決,所述偏析裝入是在將燒結調配原料中調配有包含更多的FeO等容易磁化的起磁成分且為微粉狀的原料(起磁性微粉原料)所得者,裝入至台車上時,使該原料選擇性地堆積於裝入層的上層部。一般來說已知在(美國採礦、冶金和石油工程師協會匯刊(Transaction of American Institute of Mining,Metallurgical,and Petroleum Engineers,Trans.AIME)218(1960),116)中,在表示燒結反應的成分的影響的狀態圖中,伴隨FeO含量的增加,產生燒結反應所需的熔液的熔點(液相線溫度)降低。因此,若向燒結原料裝入層的上層部,偏析裝入例如含有大量FeO的磁鐵礦系微粉鐵礦石等起磁性微粉原料,則即便在該上層部溫度不易上升的狀況下亦可促進燒結反應,且亦可實現良率或強度的改善。 According to research by the inventors, this problem can be solved by performing so-called segregation charging, which is an easy magnetization magnetization containing more FeO in the sintered blending raw material. When the component is obtained from a powdery raw material (from a magnetic fine powder raw material), when the raw material is loaded on a trolley, the raw material is selectively deposited on the upper part of the loading layer. Generally known in (Transaction of American Institute of Mining, Metallurgical, and Petroleum Engineers (Trans.AIME) 218 (1960), 116), the components representing the sintering reaction In the state diagram of the influence of Fe, as the FeO content increases, the melting point (liquidus temperature) of the melt required for the sintering reaction decreases. Therefore, if the upper layer portion of the sintering raw material charging layer is segregated and loaded with magnetic fine powder raw materials such as magnetite-based fine iron ore containing a large amount of FeO, it can be promoted even if the temperature of the upper layer portion does not easily rise. The sintering reaction can also improve the yield or strength.

而且,將燒結調配原料裝入至台車上而形成的燒結調配原料的堆積層即裝入層,一般來說,伴隨在滑槽上滑落時的滲透 (percolation)引起的粒度偏析作用,在該燒結原料裝入層的上層部、中層部會大量分佈粒度小的細粒的燒結調配原料,另一方面,在下層部堆積粒度大的粗粒的燒結調配原料,而產生裝入層的偏析。然而,在含有更多的細(多為-260μm)微粉的情況下,偏析狀態不充分,本發明可正確地解決裝入含有更多的此種起磁性微粉原料的燒結調配原料時的問題。 In addition, the sintered blended raw material is formed by loading the sintered blended raw material on the trolley, that is, the loading layer. Generally, the permeation during sliding down on the chute is accompanied by the penetration layer. The particle size segregation caused by (percolation), the sintering raw material loading layer has a large amount of fine sintered blended raw materials with a small particle size distributed in the upper and middle layers, and the lower layer has a large sintered coarse particle size. The raw materials were prepared to cause segregation of the charged layer. However, in the case where more fine (mostly -260 μm) fine powder is contained, the segregation state is insufficient, and the present invention can correctly solve the problem when a sintered blended raw material containing more such fine magnetic powder raw material is loaded.

即,本發明中以如下為前提,即,將圖2所示的磁鐵礦系微粉鐵礦石,即,FeO的含有率高(4.5質量%~60質量%)、且粒徑具有以算術平均徑計為0.2mm~2.5mm的大小、並且為250μm以下的大小者,以累計重量比例計為60質量%以下的起磁性微粉原料用於燒結調配原料的一部分。而且,本發明為解決所述問題的方法,所述問題為使用圖5所示的滑槽將含有5質量%~30質量%的該起磁性微粉原料的燒結調配原料裝入至台車上時的問題。 That is, in the present invention, it is assumed that the magnetite-based finely powdered iron ore shown in FIG. 2 has a high content of FeO (4.5% by mass to 60% by mass), and the particle size has an arithmetic value. For those having an average diameter of 0.2 mm to 2.5 mm and a size of 250 μm or less, a magnetic fine powder raw material having a cumulative weight ratio of 60% by mass or less is used for a part of the sintered preparation raw material. In addition, the present invention is a method for solving the above-mentioned problem. The problem is that when a sintered blended raw material containing 5 to 30% by mass of the magnetic fine powder raw material is loaded on a trolley using a chute shown in FIG. 5. problem.

在實施此種裝入方法時,有效的是在該滑槽的背面配設永久磁鐵或電磁鐵,使磁力作用於該滑槽上的燒結調配原料的流動。藉此,關於燒結調配原料中所含的如強磁性的磁鐵礦系微粉鐵礦石或燒結返礦、軋屑、煉鐵塵(高爐塵、煉鋼塵等)般的起磁性微粉原料,因受到所述磁力的作用而速度降低(抑制),故在該滑槽的表面上(滑落)時,被引導並堆積至燒結原料裝入層(B)的上層部側。該情況下,粒徑大的普通的燒結調配原料堆積於下層。 When implementing such a loading method, it is effective to arrange a permanent magnet or an electromagnet on the back surface of the chute so that a magnetic force acts on the sintered blending material flow on the chute. With this, regarding the ferromagnetic fine powder raw materials such as ferromagnetic magnetite-based fine powder iron ore or sintering remineralization, slag, ironmaking dust (blast furnace dust, steelmaking dust, etc.) contained in the sintered blending raw material, Due to the magnetic force, the speed is reduced (suppressed). Therefore, when it is on the surface of the chute (slide down), it is guided and deposited on the upper layer side of the sintering raw material charging layer (B). In this case, a common sintering preparation material having a large particle diameter is deposited on the lower layer.

形成所述堆積構造是基於:在藉由所述滑槽將含有大量起磁性微粉原料的所述燒結調配原料裝入至台車上時,該些原料會受到配設於滑槽的背面側的永久磁鐵或電磁鐵的磁力的作用。即,關於因鐵成分多且粒徑小故容易受到磁力影響的起磁性微粉原料,在滑槽上滑落時的速度減弱,其結果,鐵成分少而粒徑大的非起磁性原料(普通的燒結原料)先形成下層部,另一方面,相應於速度降低,該起磁性微粉原料因磁力的作用而延遲,因而堆積於燒結原料裝入層的上層部。 The formation of the stacking structure is based on the fact that when the sintered blended raw materials containing a large amount of magnetic fine powder raw materials are loaded into the trolley through the chute, these raw materials are permanently arranged on the back side of the chute. The magnetic force of a magnet or an electromagnet. That is, with regard to the magnetically fine powder raw material which is susceptible to magnetic influence due to its large iron component and small particle size, the speed at which it slides down on the chute decreases. As a result, non-magnetic raw materials (ordinary The sintering raw material) first forms the lower layer portion. On the other hand, in response to the decrease in speed, the magnetic fine powder raw material is delayed by the action of the magnetic force, and thus is deposited on the upper layer portion of the sintering raw material charging layer.

若所述起磁性微粉原料中FeO的含量少於4.5質量%,則不易受到配置於傾斜滑槽的背面的磁鐵的磁力的影響,難以獲得速度的調整(降低)效果。另一方面,只要FeO含量的上限能夠藉由磁力調整而變更速度,則無需作特別規定,起磁性微粉原料的FeO含量最大約為60質量%。 If the content of FeO in the magnetic fine powder raw material is less than 4.5% by mass, it is difficult to be affected by the magnetic force of a magnet disposed on the back surface of the inclined chute, and it is difficult to obtain a speed adjustment (reduction) effect. On the other hand, as long as the upper limit of the FeO content can be changed by magnetic force adjustment, there is no need to make a special rule, and the FeO content of the magnetic fine powder raw material is about 60% by mass at the maximum.

而且,關於原料粒徑,在所述起磁性微粉原料的算術平均粒徑為2.5mm以上的情況下,與非起磁性原料的粒徑差減小,難以使起磁性微粉原料良好地偏析至裝入層的上層部。另一方面,在該起磁性微粉原料的算術平均徑小於0.2mm的情況下,或包含具有250μm以下的粒徑的微粉的比例以累計重量比例計超過60質量%的情況下,燒結層(sintering bed)對通氣性的影響增大,即便使該起磁性微粉原料堆積於燒結原料裝入層的上層部,亦存在使燒結機的生產性降低的可能性。而且,若具有250μm以下的粒徑的微粉少於5質量%則本發明的效果減弱。作為具有250μm 以下的粒徑的微粉的較佳的下限,為15質量%左右。 Moreover, regarding the particle diameter of the raw material, when the arithmetic average particle diameter of the magnetically fine powdered raw material is 2.5 mm or more, the particle size difference from the non-magnetically generated raw material is reduced, and it is difficult to segregate the magnetically fine powdered raw material well to the packaging. Into the upper part of the layer. On the other hand, when the arithmetic mean diameter of the magnetic fine powder raw material is less than 0.2 mm, or when the proportion of the fine powder having a particle diameter of 250 μm or less exceeds 60% by mass based on the cumulative weight ratio, the sintering layer (sintering) The influence of the bed) on the air permeability is increased, and even if the magnetic fine powder raw material is deposited on the upper layer portion of the sintering raw material charging layer, the productivity of the sintering machine may be reduced. If the fine powder having a particle diameter of 250 μm or less is less than 5 mass%, the effect of the present invention is weakened. As having 250 μm The preferable lower limit of the fine powder having the following particle diameter is about 15% by mass.

圖6是說明將含有大量起磁性微粉原料的燒結調配原料,經由背面具備磁鐵的滑槽裝入時的粒子的移動的圖。如該圖所示,在含有起磁性微粉原料的燒結調配原料在該滑槽上滑落時,關於作用於該原料粒子的力,在將重力的粒子運動方向成分設為(1),重力與磁力引起的摩擦阻力設為(2),伴隨粒子的運動的空氣阻力設為(3)時,粒子運動方向(滑槽水平面方向)上的運動方程式可如下述般表示。 FIG. 6 is a diagram illustrating the movement of particles when a sintered blended raw material containing a large amount of magnetic fine powder raw materials is loaded through a chute provided with a magnet on the back surface. As shown in the figure, when the sintered blended raw material containing the magnetic fine powder raw material slides down on the chute, the force acting on the raw material particles is set to (1) as the particle motion direction component of gravity, and gravity and magnetic force. When the induced frictional resistance is (2) and the air resistance accompanying the particle motion is (3), the equation of motion in the particle motion direction (the horizontal direction of the chute) can be expressed as follows.

m:質量(kg) m: mass (kg)

g:重力加速度(m/s2) g: acceleration of gravity (m / s 2 )

θ:滑槽角度(rad) θ: chute angle (rad)

μ:原料與滑槽的摩擦係數(-) μ: friction coefficient between raw material and chute (-)

FM:磁力(N) F M : magnetic force (N)

CD:阻力係數(-) C D : coefficient of resistance (-)

S:粒子剖面積(m2) S: Particle cross-sectional area (m 2 )

ρ:空氣的密度(kg/m3) ρ: density of air (kg / m 3 )

v:粒子相對於空氣的相對速度(m/s) v: relative velocity of particles relative to air (m / s)

另外,所述(1)式中的磁力FM的通式為下述(2)式。 The general formula of the magnetic force F M in the formula (1) is the following formula (2).

m:質量(kg) m: mass (kg)

X:磁化率(-) X: magnetic susceptibility (-)

H:磁通密度(T) H: magnetic flux density (T)

χ:滑槽表面與磁鐵的距離(m) χ: distance between the groove surface and the magnet (m)

因此,在所述起磁性微粉原料在滑槽上滑落時的所述式(1)及式(2)的磁鐵引起的磁力FM的式,進而可如以下般進行處理。 Therefore, the formula of the magnetic force F M caused by the magnets of the formula (1) and the formula (2) when the magnetic fine powder raw material slides down on the chute can be further processed as follows.

即,每當裝入包含起磁性微粉原料的燒結調配原料時,在提供該起磁性微粉原料的FeO含量或粒徑、該起磁性微粉原料的調配比例,而且,提供磁鐵與滑槽表面的距離(χ)及滑槽角度(θ)、滑槽長度(L),而且提供作為常數的重力加速度(g)、原料與滑槽的摩擦係數(μ)、阻力係數(Cp)、空氣的密度(ρ)、粒子相對於空氣的相對速度(v)時,所述式(1)、式(2)的運動方程式可如下述(3)式的能量保存式般處理。 That is, whenever a sintered blended raw material containing a magnetic fine powder raw material is loaded, the FeO content or particle size of the magnetic fine powder raw material is provided, and the blending ratio of the magnetic fine powder raw material is provided, and the distance between the magnet and the surface of the chute is provided. (χ), chute angle (θ), chute length (L), and constant gravity acceleration (g), friction coefficient (μ), drag coefficient (Cp), and air density ( ρ) and relative velocity (v) of the particles with respect to air, the equations of motion of the above formulas (1) and (2) can be processed as the energy conservation formula of the following formula (3).

m:質量(kg) m: mass (kg)

g:重力加速度(m/s2) g: acceleration of gravity (m / s 2 )

θ:滑槽角度(rad) θ: chute angle (rad)

μ:原料與滑槽的摩擦係數(-) μ: friction coefficient between raw material and chute (-)

kv2:空氣阻力(N) kv 2 : air resistance (N)

v0:初始速度(m/s) v 0 : initial speed (m / s)

v1:滑槽下端的速度(m/s) v 1 : speed at the lower end of the chute (m / s)

L:滑槽長度(m) L: Chute length (m)

LM:磁鐵板的長度(m) L M : length of magnet plate (m)

FM:磁力(N) F M : magnetic force (N)

進而,本發明中,作用於該滑槽表面上的所述起磁性微粉原料的所述(3)式的磁力FM,需要使滑槽下端的速度ν1大於零(0),即,比未對滑槽賦予磁力FM時的非起磁性原料的速度慢,因此,(3)式可進而如(4)式般處理。 Furthermore, in the present invention, the magnetic force F M of the formula (3) acting on the magnetic fine powder raw material on the surface of the chute needs to make the speed ν 1 at the lower end of the chute greater than zero (0), that is, the ratio When the magnetic force F M is not applied to the chute, the speed of the non-magnetizing raw material is slow. Therefore, the formula (3) can be further processed as the formula (4).

m:質量(kg) m: mass (kg)

g:重力加速度(m/s2) g: acceleration of gravity (m / s 2 )

θ:滑槽角度(rad) θ: chute angle (rad)

μ:原料與滑槽的摩擦係數(-) μ: friction coefficient between raw material and chute (-)

kv2:空氣阻力(N) kv 2 : air resistance (N)

v0:初始速度(m/s) v 0 : initial speed (m / s)

v1:滑槽下端的速度(m/s) v 1 : speed at the lower end of the chute (m / s)

L:滑槽長度(m) L: Chute length (m)

LM:磁鐵板的長度(m) L M : length of magnet plate (m)

FM:磁力(N) F M : magnetic force (N)

總之,本發明為以如下方式運轉的方法,即,調整(增 大)容易磁化的起磁性微粉原料在滑槽上滑落時的阻力,即,抑制燒結調配原料中的該起磁性微粉原料的速度,藉此偏析裝入至燒結原料裝入層的上層部。 In summary, the present invention is a method that operates in such a way that adjustment (increase Large) The resistance when the magnetically fine powdered raw material that is easily magnetized slips on the chute, that is, the speed of the magnetically fine powdered raw material in the sintered blended raw material is suppressed, and the powder is segregated into the upper part of the sintered raw material loading layer.

另外,若無限增大所述磁力FM,即,使容易磁化的起磁性微粉原料不附著於滑槽上,則欠佳。表2為FM設為0×10-3N~10.5×10-3N時的利用離散要素法調查滑槽下端的磁力FM與起磁性微粉原料的滑槽下端部的速度νm的關係的模擬結果。如該表所示,在磁力(FM)過大而摩擦阻力變得過於非常大的示例(S1:0/5ν1)中,滑槽上附著有起磁性微粉原料。藉此,有可能寬度方向上的裝入變得不均勻,或最差情況下,有因附著物而滑槽上堵塞從而無法進行裝入本身之虞。另一方面,在完全未賦予磁力的示例(S6:5/5ν1)中,完全無法進行偏析裝入。另一方面,S2因磁力(FM=10.0×10-3N)的制動效應(braking effect)大,故原料裝入層的密度過於降低(空隙率增加),通氣性佳而生產率提高,但良率降低。而且,S5中,表示磁力(FM=0.4×10-3N)弱,裝入速度νm大,偏析裝入的效果差的結果。因此,可知有效的是在與起磁性微粉原料的滑槽下端部的速度νm的關聯中調整磁力FM。而且,S3、S4的偏析狀況均為良好,並且原料裝入層的密度不會過於降低(空隙率增加),因而通氣性佳,良率或生產率亦良好。 In addition, it is unfavorable to increase the magnetic force F M indefinitely, that is, to prevent the easily magnetizable fine powder raw material from adhering to the chute. Table 2 shows the relationship between the magnetic force F M at the lower end of the chute and the speed ν m at the lower end of the chute from which the magnetic fine powder raw material is investigated using the discrete element method when F M is set to 0 × 10 -3 N to 10.5 × 10 -3 N. Simulation results. As shown in this table, in the example (S1: 0 / 5ν 1 ) where the magnetic force (F M ) is too large and the friction resistance becomes too large, the magnetic fine powder raw material is attached to the chute. Thereby, there is a possibility that the mounting in the width direction becomes uneven, or in the worst case, the chute may be blocked due to the adhered substance and the mounting itself may not be performed. On the other hand, in the example (S6: 5 / 5ν 1 ) where no magnetic force was applied at all, segregation loading could not be performed at all. On the other hand, S2 has a large braking effect due to the magnetic force (F M = 10.0 × 10 -3 N), so the density of the raw material loading layer is too low (the porosity is increased), the air permeability is good, and the productivity is improved, but Yield decreases. In S5, the results show that the magnetic force (F M = 0.4 × 10 -3 N) is weak, the loading speed ν m is large, and the effect of the segregation loading is poor. Therefore, it can be seen that it is effective to adjust the magnetic force F M in association with the speed ν m of the lower end portion of the chute from which the magnetic fine powder raw material is fed. In addition, the segregation conditions of S3 and S4 are both good, and the density of the raw material loading layer does not decrease too much (the porosity increases), so the air permeability is good, and the yield and productivity are also good.

根據以上,所述磁力FM的調整基於以下的基準而進行。即,磁力FM的適宜的範圍較佳為以如下方式進行調整,即,基於滑槽下端的起磁性微粉原料與非起磁性粗.細粒原料的速度差(速度比),在燒結台車上起磁性微粉原料偏析而堆積至燒結原料裝入層的上部。 Based on the above, the adjustment of the magnetic force F M is performed based on the following criteria. That is, the suitable range of the magnetic force F M is preferably adjusted in the following manner, that is, based on the magnetically fine powder raw material and the non-magnetically coarse material at the lower end of the chute. The speed difference (speed ratio) of the fine-grained raw materials is segregated on the sintering trolley and deposited on the upper part of the sintered raw material charging layer.

因此,本發明中,作為所述能量保存式的所述式(4)中,在將向滑槽上的落下位置的速度(初始速度)設為ν0,滑槽下端的未賦予磁力時的速度設為ν1(與非起磁性原料的速度相同)時,以滑槽下端部的所述起磁性微粉原料的速度νm為下述範圍內的方式,來調整磁力FMTherefore, in the present invention, in the formula (4) as the energy conservation formula, when the speed (initial speed) to the drop position on the chute is set to ν 0 and the magnetic force is not applied to the lower end of the chute. When the speed is set to ν 1 (same as the speed of the non-magnetic raw material), the magnetic force F M is adjusted so that the speed ν m of the magnetic fine powder raw material at the lower end of the chute is within the following range.

關於磁力FM與滑槽下端部的速度νm的關係,根據起磁性微粉原料的滑槽下端部的速度設定為0、1/5ν1、2/5ν1、3/5ν1、4/5ν1、ν1的試驗(S1~S6)中的、表2所示的結果而可知。即,如表2所示,在該起磁性微粉原料的滑槽下端部的速度νm處於1/5ν1~4/5ν1的範圍時,所述偏析裝入的狀況良好,尤其2/5ν1~3/5ν1的範圍內良率更良好。 The relationship between the magnetic force F M and the speed ν m at the lower end of the chute is set to 0, 1 / 5ν 1 , 2 / 5ν 1 , 3 / 5ν 1 , 4 / 5ν according to the speed of the lower end of the chute from the magnetic fine powder raw material. 1, test 1, v (S1 ~ S6) of, and results shown in table 2 can be seen. That is, as shown in Table 2, when the speed ν m at the lower end of the chute of the magnetic fine powder raw material is in the range of 1 / 5ν 1 to 4 / 5ν 1 , the state of the segregation loading is good, especially 2 / 5ν The yield is better in the range of 1 to 3 / 5ν 1 .

因此,本發明中,在將包含所述規定量(5質量%~30質量%)的起磁性微粉原料的燒結調配原料裝入至燒結台車上時,考慮該起磁性微粉原料的FeO含量、粒徑或調配量,而質量m或磁化率X發生變化的情況下,預先對使用的磁鐵的磁通密度(H)、滑槽表面與磁鐵的距離χ及滑槽角度進行調整後,以所述滑槽下端部的該起磁性微粉原料的滑落速度νm處於一定的範圍內(在非起磁性原料的滑槽下端速度為ν1時,為1/5ν1~4/5ν1)的方式,對所述磁鐵引起的磁力FM進行調整,藉此可僅將燒結調配原料中的起磁性微粉原料選擇性地堆積於台車上的燒結原料裝入層的上層部。 Therefore, in the present invention, when the sintered blended raw material containing the prescribed amount (5 mass% to 30 mass%) of the magnetically fine powdered raw material is loaded on a sintering trolley, the FeO content and grains of the magnetically fined powder raw material are considered. If the mass m or magnetic susceptibility X changes, the magnetic flux density (H) of the used magnet, the distance between the chute surface and the magnet, and the chute angle are adjusted in advance. The sliding speed ν m of the magnetic fine powder raw material at the lower end of the chute is in a certain range (when the speed of the lower end of the chute of the non-magnetic raw material is ν 1 , it is 1 / 5ν 1 ~ 4 / 5ν 1 ). By adjusting the magnetic force F M caused by the magnet, only the sintering raw material in the sintering preparation raw material can be selectively deposited on the upper part of the layer of the sintering raw material charging layer.

結果,在所提供的一定條件(起磁性微粉原料的FeO的含量、平均粒徑、該原料的調配比例等)下,所述磁力FM的理想的範圍,即,使起磁性微粉原料一直僅堆積於燒結原料裝入層的上層部,而能夠穩定地進行燒結機的操作的條件,是指以滑槽下端部的起磁性微粉原料的速度為所述1/5ν1~4/5ν1的方式,將磁鐵引起的磁力FM於0.0004~0.01的範圍內,理想的是於0.004~0.009 的範圍內進行調整而進行燒結調配原料的裝入,從而使得燒結機的操作穩定。 As a result, under the provided conditions (the content of FeO from the magnetic fine powder raw material, the average particle size, the blending ratio of the raw material, etc.), the ideal range of the magnetic force F M is to keep the magnetic fine powder raw material only The condition that the sintering machine can be stably operated by being deposited on the upper part of the sintering raw material charging layer means that the speed of the magnetically fine powdered raw material at the lower end of the chute is 1 / 5ν 1 to 4 / 5ν 1 In the method, the magnetic force F M caused by the magnet is in the range of 0.0004 to 0.01, and it is desirable to adjust the range of 0.004 to 0.009 to load the sintering compounding material, so that the operation of the sintering machine is stable.

圖7表示如下的模擬結果,即,作為燒結調配原料中的起磁性微粉原料,對含有15質量%的FeO為7.0質量%的燒結返礦、5質量%的FeO為4.7質量%的磁鐵礦系微粉鐵礦石的原料,將所述式(4)中的磁力FM設定為0.01N而裝入,可知該起磁性微粉原料的滑槽上的速度降低,且其大部分堆積於燒結原料層的上層部。 FIG. 7 shows the results of a simulation in which, as the magnetizing fine powder raw material in the sintering preparation raw material, for sintering remineralization containing 15% by mass of FeO at 7.0% by mass, and 5% by mass of FeO at 4.7% by mass of magnetite It is a raw material of fine powder iron ore, and the magnetic force F M in the formula (4) is set to 0.01N, and it is found that the speed on the chute of the magnetic fine powder raw material decreases, and most of it accumulates on the sintering raw material. The upper part of the layer.

接下來,圖8中,作為燒結調配原料中的起磁性微粉原料,對含有15質量%的FeO為7.0質量%的燒結返礦、5質量%的FeO為4.7質量%的磁鐵礦系微粉鐵礦石的原料,同樣地將磁力FM設定為超過0.01N而進行模擬後,結果無法進行一定速度下的燒結調配原料的裝入,從而妨礙燒結機的操作。 Next, in FIG. 8, as the magnetizing fine powder raw material in the sintering preparation raw material, the magnetite-based fine powder iron containing 15% by mass of FeO and 7.0% by mass of sintering remineralization, and 5% by mass of FeO being 4.7% by mass of magnetite. Similarly, the raw material of the ore was simulated by setting the magnetic force F M to more than 0.01 N, and as a result, the charging of the sintering preparation material at a certain speed could not be carried out, which hindered the operation of the sintering machine.

接下來,圖9中,作為燒結調配原料中的起磁性微粉原料,對含有15質量%的FeO為7.0質量%的燒結返礦、5質量%的FeO為4.7質量%的磁鐵礦系微粉鐵礦石的原料,同樣地將磁力FM設定為0.004N而進行模擬後,可知為理想的偏析裝入。 Next, in FIG. 9, as the magnetizing fine powder raw material in the sintering preparation raw material, magnetite-based fine powder iron containing 15% by mass of FeO at 7.0% by mass and 5% by mass of FeO at 4.7% by mass The raw material of the ore was similarly set to have a magnetic force F M of 0.004 N, and it was found that it was ideally segregated.

接下來,圖10為如下示例,即,作為燒結調配原料中的起磁性微粉原料,對含有15質量%的FeO為7.0質量%的燒結返礦、5質量%的FeO為4.7質量%的磁鐵礦系微粉鐵礦石的原料,進行普通裝入,將磁力FM設定為0而進行模擬後,可知完全無法期待起磁性微粉原料的偏析裝入。 Next, FIG. 10 is an example in which, as a magnetizing fine powder raw material in the sintering preparation raw material, a magnet containing 7.0% by mass of FeO with 15% by mass of FeO and 4.7% by mass of FeO with 5% by mass of FeO The raw materials of the ore-based fine-powder iron ore were generally loaded, and the magnetic force F M was set to 0 for simulation. It was found that the segregation of the magnetic fine-powder raw materials could not be expected at all.

[實施例] [Example]

以下所述的實施例中,使用模擬了圖11所示的實物裝入裝置的實驗裝置,進行燒結調配原料的裝入實驗。該實驗中,使用以表3所示的調配而包含磁鐵礦系微粉礦石或燒結返礦等起磁性微粉原料的燒結調配原料。而且,向設置於所述模擬器上方的料斗內填充所述燒結調配原料,在表4所示的條件下使用滑槽而裝入至模擬台車上。從裝入至模擬台車上而獲得的裝入層的上層部、中層部、下層部分別採取燒結調配原料,利用化學分析調查磁鐵礦成分(FeO)的偏析狀況。進而,然後將裝入後的燒結調配原料轉移至燒結鍋試驗裝置而進行燒結實驗,並調查對生產性的影響等。 In the examples described below, an experimental device that simulates the physical loading device shown in FIG. 11 was used to carry out the loading experiment of the sintered blended raw materials. In this experiment, sintered blended raw materials including magnetite-based finely powdered ore or sintered remineralized raw materials such as magnetite-based finely-powdered ore or sintered remineralized were prepared as shown in Table 3. Furthermore, the hopper provided above the simulator was filled with the sintered blended raw materials, and was loaded on a simulation trolley using a chute under the conditions shown in Table 4. The upper layer part, middle layer part, and lower layer part of the loading layer obtained from loading on the simulation trolley are respectively prepared by sintering and blending materials, and the segregation status of the magnetite composition (FeO) is investigated by chemical analysis. Then, the loaded sintering preparation materials were transferred to a sintering pot tester to perform a sintering test, and the influence on productivity was investigated.

該實施例的磁力(FM)與滑槽下層部的速度(νm)如表3所示,在適合於本發明的條件(T1~T6)下,為6.0×10-3N,且此時的速度νm為3/5ν1的條件。 The magnetic force (F M ) and the velocity (ν m ) of the lower part of the chute in this example are shown in Table 3. Under the conditions (T1 to T6) suitable for the present invention, it is 6.0 × 10 -3 N, and this The speed ν m is a condition of 3 / 5ν 1 .

算術平均徑:0.29mm Arithmetic mean diameter: 0.29mm

250μm以下:53質量% 250 μm or less: 53% by mass

*燒結返礦的FeO:5.69質量% * Sintered FeO: 5.69% by mass

算術平均徑:2.25mm Arithmetic mean diameter: 2.25mm

250μm以下:8質量% 250 μm or less: 8% by mass

*未賦予磁力時的滑槽下端部的速度(v1):3.0m/s * Speed at the lower end of the chute when no magnetic force is applied (v 1 ): 3.0 m / s

根據所述燒結鍋試驗裝置的裝入實驗的結果可確認:如圖12所示,藉由背面配置了磁鐵的滑槽,對調配了10質量%的磁鐵礦系微粉鐵礦石、20質量%的燒結返礦、且剩餘部分為粉狀鐵礦石與石灰石所得的燒結調配原料,進行適合於本發明的裝入例(T6)與未配置磁鐵的滑槽的裝入例即比較例(T8)中的起磁成分(FeO)的偏析狀況的比較後,在使用設置了磁鐵的滑槽而裝入的發明例(T6)中,含有起磁成分的燒結調配原料向裝入層的上層部偏析。 According to the results of the loading experiment of the sintering pot test device, as shown in FIG. 12, 10% by mass of the magnetite-based fine powder iron ore and 20% by mass were prepared by using a chute with a magnet disposed on the back surface. % Sintering returns, and the remainder is the sintered blended raw material obtained from powdered iron ore and limestone. A comparative example (a loading example suitable for the present invention (T6) and a chute without a magnet is provided) After comparing the segregation status of the magnetizing component (FeO) in T8), in the invention example (T6) incorporated using a chute provided with a magnet, the sintered blended raw material containing the magnetizing component was transferred to the upper layer of the loading layer. Department segregation.

進而,關於該實驗的發明例及比較例,將磁鐵礦系微粉 鐵礦石的調配比率引起的生產率的變化表示於圖13中。根據該圖所示的結果可知,相比於不包含起磁性微粉原料的情況(T1),在調配了5質量%的起磁性微粉原料的條件(T2)下,起磁成分少,無法充分獲得裝入速度的降低效果,燒結機中的生產性亦未怎麼變化。另一方面,在適合於本發明的示例(T3~T6)中,充分獲得起磁性微粉原料引起的裝入速度的降低效果,相比於不包含起磁性微粉原料的情況(T1)而生產性得到改善。另一方面,在調配了40質量%的起磁性微粉原料的條件(T7)下,微粉的比率增加,不僅上層部,中層部以下亦混入微粉,因而無法將生產性維持得高。因此,本發明中,燒結調配原料中的起磁性微粉原料的調配量在5質量%~30質量%,較佳為20質量%以上~30質量%以下時能夠顯著體現出效果。 Furthermore, regarding the invention examples and comparative examples of this experiment, magnetite-based fine powder was used. The change in productivity due to the iron ore blending ratio is shown in FIG. 13. According to the results shown in the figure, compared with the case where the magnetic fine powder raw material is not included (T1), under the condition (T2) in which the magnetic fine powder raw material is blended at 5% by mass, the magnetic generating component is small and cannot be obtained sufficiently. The effect of lowering the loading speed does not change much in the sintering machine. On the other hand, in the examples (T3 to T6) suitable for the present invention, the effect of reducing the loading speed caused by the magnetic fine powder raw material was sufficiently obtained, and the productivity was higher than that when the magnetic fine powder raw material was not included (T1). Improved. On the other hand, under the condition (T7) in which 40% by mass of the magnetic fine powder raw material was blended, the ratio of fine powder increased, and fine powder was mixed not only in the upper layer portion but below the middle layer portion, so the productivity could not be maintained high. Therefore, in the present invention, when the amount of the magnetic fine powder raw material in the sintered preparation raw material is 5 to 30% by mass, preferably 20 to 30% by mass, the effect can be significantly exhibited.

[產業上之可利用性] [Industrial availability]

在裝入比本發明中指定的粒徑大且起磁性微粉原料的量少或量多的燒結調配原料的情況下,雖有效果上的差異,但均可應用本發明的技術。 When a sintered blended raw material having a larger particle size than that specified in the present invention and a small amount or a large amount of magnetic fine powder raw material is loaded, the technology of the present invention can be applied although the effect is different.

Claims (5)

一種燒結機的操作方法,將燒結調配原料經由背面配設磁鐵而成的滑槽裝入至燒結機的台車上而進行燒結,所述燒結機的操作方法的特徵在於:所述燒結調配原料中的5質量%~30質量%為起磁性微粉原料,所述起磁性微粉原料中的FeO的含量為4.5質量%以上,所述起磁性微粉原料的粒徑以算術平均徑計具有0.2mm~2.5mm的大小,且其中250μm以下的微粉量以重量比例計為5質量%以上且60質量%以下,在將所述起磁性微粉原料裝入至台車上時,在將未對所述滑槽賦予磁力(FM)時(FM=0)的滑槽下端部的所述燒結調配原料的速度設為ν1時,以所述滑槽下端部的所述起磁性微粉原料的速度νm成為1/5ν1~4/5ν1的速度的方式,對所述磁鐵的磁力FM進行調整。 A method for operating a sintering machine, wherein the sintering and preparing raw materials are loaded on a trolley of the sintering machine and sintered through a chute formed with a magnet on the back side. The operating method of the sintering machine is characterized in that: 5 mass% to 30 mass% is a magnetic fine powder raw material, the content of FeO in the magnetic fine powder raw material is 4.5 mass% or more, and the particle size of the magnetic fine powder raw material has an arithmetic mean diameter of 0.2 mm to 2.5 mm, and the amount of fine powder below 250 μm is 5 mass% or more and 60 mass% or less by weight. When the magnetic fine powder raw material is loaded on a trolley, When the magnetic force (F M ) is applied to the groove (F M = 0), the speed of the sintered blended raw material at the lower end of the chute is set to ν 1 , and the speed of the magnetically finely powdered raw material at the lower end of the chute is ν A mode in which m becomes a speed of 1 / 5ν 1 to 4 / 5ν 1 is to adjust the magnetic force F M of the magnet. 如申請專利範圍第1項所述的燒結機的操作方法,其中所述滑槽下端部的所述起磁性微粉原料的速度νm為2/5ν1~3/5ν1的速度。 The method for operating a sintering machine according to item 1 of the scope of the patent application, wherein the speed ν m of the magnetic fine powder raw material at the lower end of the chute is a speed of 2 / 5ν 1 to 3 / 5ν 1 . 如申請專利範圍第1項或第2項所述的燒結機的操作方法,其中所述滑槽下端部的所述起磁性微粉原料的速度νm在0.0004N~0.01N的範圍內調整所述磁鐵的磁力FMThe method for operating a sintering machine according to item 1 or item 2 of the scope of patent application, wherein the speed ν m of the magnetically fine powdered raw material at the lower end of the chute is adjusted within a range of 0.0004N to 0.01N. The magnetic force F M of the magnet. 如申請專利範圍第1項或第2項所述的燒結機的操作方法,其中所述磁鐵的磁力FM為由下述式求出的數值, m:質量(kg)g:重力加速度(m/s2)θ:滑槽角度(rad)μ:原料與滑槽的摩擦係數(-)kv2:空氣阻力(N)v0:初始速度(m/s)v1:滑槽下端的速度(m/s)L:滑槽長度(m)LM:磁鐵板的長度(m)FM:磁力(N)。 According to the method of operating a sintering machine according to the first or second scope of the patent application, wherein the magnetic force F M of the magnet is a value obtained by the following formula, m: mass (kg) g: gravitational acceleration (m / s 2 ) θ: chute angle (rad) μ: coefficient of friction between raw material and chute (-) kv 2 : air resistance (N) v 0 : initial speed ( m / s) v 1 : speed (m / s) at the lower end of the chute L: chute length (m) L M : length of the magnet plate (m) F M : magnetic force (N). 如申請專利範圍第1項或第2項所述的燒結機的操作方法,其中所述起磁性微粉原料中,所述原料中的至少5質量%~15質量%為燒結返礦,剩餘部分包含磁鐵礦系微粉鐵礦石、軋屑及煉鐵塵中的任一種以上。 The method for operating a sintering machine as described in item 1 or 2 of the scope of the patent application, wherein at least 5 mass% to 15 mass% of the raw material of the magnetic fine powder is sintering remineralization, and the remaining part contains Any one or more of magnetite-based fine iron ore, crumbs, and ironmaking dust.
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CN1175981A (en) * 1995-12-22 1998-03-11 川崎制铁株式会社 Method of feeding sintering material by use of magnetic forces
JP2003105449A (en) * 2001-09-26 2003-04-09 Kawasaki Steel Corp Method and apparatus for charging raw material for sintering

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JP3201726B2 (en) * 1995-12-22 2001-08-27 川崎製鉄株式会社 Loading method of sintering raw material using magnetic force
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CN1175981A (en) * 1995-12-22 1998-03-11 川崎制铁株式会社 Method of feeding sintering material by use of magnetic forces
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