TWI553662B - Preparation of Carbon Nanotube Transparent Composite Electrode - Google Patents
Preparation of Carbon Nanotube Transparent Composite Electrode Download PDFInfo
- Publication number
- TWI553662B TWI553662B TW103100887A TW103100887A TWI553662B TW I553662 B TWI553662 B TW I553662B TW 103100887 A TW103100887 A TW 103100887A TW 103100887 A TW103100887 A TW 103100887A TW I553662 B TWI553662 B TW I553662B
- Authority
- TW
- Taiwan
- Prior art keywords
- carbon nanotube
- film
- transparent
- substrate
- composite electrode
- Prior art date
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims description 72
- 239000002041 carbon nanotube Substances 0.000 title claims description 68
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims description 67
- 239000002131 composite material Substances 0.000 title claims description 34
- 238000002360 preparation method Methods 0.000 title description 14
- 239000002238 carbon nanotube film Substances 0.000 claims description 34
- 239000000758 substrate Substances 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 25
- 229920001940 conductive polymer Polymers 0.000 claims description 21
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims description 7
- 229920000307 polymer substrate Polymers 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 claims description 6
- 229960002796 polystyrene sulfonate Drugs 0.000 claims description 5
- 239000011970 polystyrene sulfonate Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- -1 polyphenylene Polymers 0.000 claims description 4
- MIOPJNTWMNEORI-GMSGAONNSA-N (S)-camphorsulfonic acid Chemical compound C1C[C@@]2(CS(O)(=O)=O)C(=O)C[C@@H]1C2(C)C MIOPJNTWMNEORI-GMSGAONNSA-N 0.000 claims description 3
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 3
- CTIFKKWVNGEOBU-UHFFFAOYSA-N 2-hexadecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O CTIFKKWVNGEOBU-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- 229920000144 PEDOT:PSS Polymers 0.000 claims description 3
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 3
- 239000006184 cosolvent Substances 0.000 claims description 3
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 claims description 3
- 229920001197 polyacetylene Polymers 0.000 claims description 3
- 229920000767 polyaniline Polymers 0.000 claims description 3
- 229920000128 polypyrrole Polymers 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 230000003746 surface roughness Effects 0.000 claims description 3
- 210000003298 dental enamel Anatomy 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 2
- 229920000265 Polyparaphenylene Polymers 0.000 claims 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- 235000013877 carbamide Nutrition 0.000 claims 1
- 239000004202 carbamide Substances 0.000 claims 1
- 238000005520 cutting process Methods 0.000 claims 1
- HDZGCSFEDULWCS-UHFFFAOYSA-N monomethylhydrazine Chemical compound CNN HDZGCSFEDULWCS-UHFFFAOYSA-N 0.000 claims 1
- 239000010408 film Substances 0.000 description 53
- 239000010410 layer Substances 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000002834 transmittance Methods 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 4
- 239000004973 liquid crystal related substance Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000002109 single walled nanotube Substances 0.000 description 3
- DIIIISSCIXVANO-UHFFFAOYSA-N 1,2-Dimethylhydrazine Chemical compound CNNC DIIIISSCIXVANO-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000003698 laser cutting Methods 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000001308 synthesis method Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000001074 Langmuir--Blodgett assembly Methods 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001962 electrophoresis Methods 0.000 description 1
- 238000001652 electrophoretic deposition Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229920006302 stretch film Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
- G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
- G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0224—Electrodes
- H01L31/022466—Electrodes made of transparent conductive layers, e.g. TCO, ITO layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
- H01L31/1884—Manufacture of transparent electrodes, e.g. TCO, ITO
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F2203/00—Indexing scheme relating to G06F3/00 - G06F3/048
- G06F2203/041—Indexing scheme relating to G06F3/041 - G06F3/045
- G06F2203/04103—Manufacturing, i.e. details related to manufacturing processes specially suited for touch sensitive devices
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Theoretical Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Human Computer Interaction (AREA)
- Manufacturing & Machinery (AREA)
- Manufacturing Of Electric Cables (AREA)
- Non-Insulated Conductors (AREA)
- Carbon And Carbon Compounds (AREA)
- Electroluminescent Light Sources (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310012106.9A CN103928637B (zh) | 2013-01-14 | 2013-01-14 | 碳纳米管透明复合电极的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201432718A TW201432718A (zh) | 2014-08-16 |
| TWI553662B true TWI553662B (zh) | 2016-10-11 |
Family
ID=51146785
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW103100887A TWI553662B (zh) | 2013-01-14 | 2014-01-10 | Preparation of Carbon Nanotube Transparent Composite Electrode |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JP5965554B2 (ja) |
| KR (1) | KR101693774B1 (ja) |
| CN (1) | CN103928637B (ja) |
| DE (1) | DE112013006416T5 (ja) |
| HK (1) | HK1196996A1 (ja) |
| TW (1) | TWI553662B (ja) |
| WO (1) | WO2014108015A1 (ja) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105321592B (zh) * | 2014-08-01 | 2017-03-22 | 广东阿格蕾雅光电材料有限公司 | 碳纳米管‑高分子层状复合透明柔性电极及其制备方法 |
| CN105361977B (zh) * | 2014-08-26 | 2018-08-10 | 中国科学院苏州纳米技术与纳米仿生研究所 | 电阻式柔性透明关节部位电子皮肤及其制备方法和应用 |
| CN104465993A (zh) * | 2014-10-28 | 2015-03-25 | 南昌大学 | 一种碳基复合透明电极及制备方法 |
| CN104576321A (zh) * | 2015-01-30 | 2015-04-29 | 京东方科技集团股份有限公司 | 一种电极结构、其制作方法、显示基板及显示装置 |
| CN104616838B (zh) | 2015-02-10 | 2018-02-06 | 京东方科技集团股份有限公司 | 一种电子器件的制作方法及电子器件 |
| WO2016136685A1 (ja) * | 2015-02-23 | 2016-09-01 | リンテック オブ アメリカ インク | 粘着シート |
| CN105024015B (zh) * | 2015-06-24 | 2017-12-22 | 复旦大学 | 一种可拼接的钙钛矿太阳能电池及其制备方法 |
| CN106601329B (zh) * | 2016-08-18 | 2019-04-16 | 北京纳米能源与系统研究所 | 一种柔性纳米摩擦发电机、制备方法及制成的传感器 |
| CN106782774A (zh) * | 2017-01-10 | 2017-05-31 | 京东方科技集团股份有限公司 | 透明导电薄膜、其制备方法及装置 |
| CN109427982B (zh) * | 2017-08-30 | 2020-01-03 | 清华大学 | 有机发光二极管 |
| CN109428009B (zh) | 2017-08-30 | 2020-05-15 | 清华大学 | 有机发光二极管的制备方法 |
| CN109428006B (zh) | 2017-08-30 | 2020-01-07 | 清华大学 | 有机发光二极管 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086035A (zh) * | 2009-12-03 | 2011-06-08 | 北京富纳特创新科技有限公司 | 碳纳米管膜及其制备方法 |
| CN102321323A (zh) * | 2011-05-27 | 2012-01-18 | 清华大学 | 透明碳纳米管复合膜的制备方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100992154B1 (ko) * | 2008-09-19 | 2010-11-05 | 한국전자통신연구원 | 탄소나노튜브를 이용한 투명 전도성 박막 및 그 제조 방법 |
| JP5554552B2 (ja) * | 2009-12-09 | 2014-07-23 | アルプス電気株式会社 | 透明導電膜及びその製造方法 |
| CN101923912B (zh) * | 2010-06-18 | 2013-12-11 | 北京富纳特创新科技有限公司 | 碳纳米管膜及基于该碳纳米管膜的复合膜 |
| KR101272483B1 (ko) * | 2010-12-09 | 2013-06-10 | 한국과학기술원 | 탄소나노튜브와 전도성 고분자를 이용한 다층 구조의 투명 전도성 판재의 제조방법 |
| JP2015067483A (ja) * | 2013-09-30 | 2015-04-13 | 日立造船株式会社 | 繊維状カーボン材料の製造方法 |
-
2013
- 2013-01-14 CN CN201310012106.9A patent/CN103928637B/zh not_active Expired - Fee Related
- 2013-12-14 WO PCT/CN2013/089463 patent/WO2014108015A1/zh active Application Filing
- 2013-12-14 JP JP2015551963A patent/JP5965554B2/ja not_active Expired - Fee Related
- 2013-12-14 DE DE112013006416.2T patent/DE112013006416T5/de not_active Withdrawn
- 2013-12-14 KR KR1020157017465A patent/KR101693774B1/ko active IP Right Grant
-
2014
- 2014-01-10 TW TW103100887A patent/TWI553662B/zh not_active IP Right Cessation
- 2014-10-16 HK HK14110367.8A patent/HK1196996A1/zh not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086035A (zh) * | 2009-12-03 | 2011-06-08 | 北京富纳特创新科技有限公司 | 碳纳米管膜及其制备方法 |
| CN102321323A (zh) * | 2011-05-27 | 2012-01-18 | 清华大学 | 透明碳纳米管复合膜的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101693774B1 (ko) | 2017-01-06 |
| WO2014108015A1 (zh) | 2014-07-17 |
| HK1196996A1 (zh) | 2014-12-24 |
| CN103928637B (zh) | 2016-05-04 |
| JP2016504738A (ja) | 2016-02-12 |
| TW201432718A (zh) | 2014-08-16 |
| CN103928637A (zh) | 2014-07-16 |
| DE112013006416T5 (de) | 2015-10-15 |
| KR20150118583A (ko) | 2015-10-22 |
| JP5965554B2 (ja) | 2016-08-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |