TWI549741B - 水泥工廠的汞排放的減少之方法 - Google Patents
水泥工廠的汞排放的減少之方法 Download PDFInfo
- Publication number
- TWI549741B TWI549741B TW100146501A TW100146501A TWI549741B TW I549741 B TWI549741 B TW I549741B TW 100146501 A TW100146501 A TW 100146501A TW 100146501 A TW100146501 A TW 100146501A TW I549741 B TWI549741 B TW I549741B
- Authority
- TW
- Taiwan
- Prior art keywords
- mercury
- heater
- kiln
- sorbent
- collected
- Prior art date
Links
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims description 135
- 229910052753 mercury Inorganic materials 0.000 title claims description 133
- 239000004568 cement Substances 0.000 title claims description 53
- 238000000034 method Methods 0.000 title claims description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 72
- 239000002594 sorbent Substances 0.000 claims description 58
- 239000002245 particle Substances 0.000 claims description 37
- 239000002994 raw material Substances 0.000 claims description 30
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 19
- 229910052794 bromium Inorganic materials 0.000 claims description 19
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 10
- 238000011144 upstream manufacturing Methods 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- 101150118484 Macf1 gene Proteins 0.000 claims description 5
- 238000002347 injection Methods 0.000 claims description 5
- 239000007924 injection Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000007789 gas Substances 0.000 description 21
- 238000004519 manufacturing process Methods 0.000 description 11
- 239000002250 absorbent Substances 0.000 description 9
- 230000002745 absorbent Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 239000000428 dust Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 229910052976 metal sulfide Inorganic materials 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 125000001246 bromo group Chemical group Br* 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000012717 electrostatic precipitator Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910052979 sodium sulfide Inorganic materials 0.000 description 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000007420 reactivation Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
- B01D53/10—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/364—Avoiding environmental pollution during cement-manufacturing
- C04B7/365—Avoiding environmental pollution during cement-manufacturing by extracting part of the material from the process flow and returning it into the process after a separate treatment, e.g. in a separate retention unit under specific conditions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0233—Other waste gases from cement factories
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Environmental Sciences (AREA)
- Ecology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201061424149P | 2010-12-17 | 2010-12-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201226038A TW201226038A (en) | 2012-07-01 |
| TWI549741B true TWI549741B (zh) | 2016-09-21 |
Family
ID=45476601
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW100146501A TWI549741B (zh) | 2010-12-17 | 2011-12-15 | 水泥工廠的汞排放的減少之方法 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US8961654B2 (enExample) |
| EP (1) | EP2651534A1 (enExample) |
| JP (2) | JP2014501215A (enExample) |
| KR (1) | KR20140009252A (enExample) |
| CN (1) | CN103391803B (enExample) |
| AR (1) | AR084287A1 (enExample) |
| AU (1) | AU2011344213A1 (enExample) |
| BR (1) | BR112013013990A2 (enExample) |
| CA (1) | CA2815385A1 (enExample) |
| CL (1) | CL2013001683A1 (enExample) |
| CO (1) | CO6710948A2 (enExample) |
| MY (1) | MY160669A (enExample) |
| PH (1) | PH12013500781A1 (enExample) |
| RU (1) | RU2013132974A (enExample) |
| TW (1) | TWI549741B (enExample) |
| WO (1) | WO2012082539A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI619550B (zh) | 2013-03-15 | 2018-04-01 | 亞比馬利股份有限公司 | 煙道氣吸附劑、其製造方法及其自氣流移除汞之用途 |
| MX2018002171A (es) | 2015-08-21 | 2018-06-15 | Ecolab Usa Inc | Complejacion y eliminacion del mercurio de sistemas de desulfuracion de gas de combustion. |
| WO2017035001A1 (en) | 2015-08-21 | 2017-03-02 | Ecolab Usa Inc. | Complexation and removal of mercury from flue gas desulfurization systems |
| DE102017104216A1 (de) * | 2017-03-01 | 2018-09-06 | Thyssenkrupp Ag | Verfahren und Anlage zur Herstellung von Zement |
| WO2018170255A1 (en) | 2017-03-17 | 2018-09-20 | Graymont (Pa) Inc. | Calcium hydroxide-containing compositions and associated systems and methods |
| WO2019010163A1 (en) | 2017-07-06 | 2019-01-10 | Ecolab USA, Inc. | IMPROVED INJECTION OF MERCURY OXIDANTS |
| WO2019027622A1 (en) | 2017-08-04 | 2019-02-07 | Graymont (Pa) Inc. | SYSTEMS AND METHODS FOR REMOVING MERCURY OR HYDROCHLORIC ACID FROM GAS STREAMS USING PARTICLES CONTAINING CALCIUM |
| CA3102270A1 (en) | 2018-06-01 | 2019-12-05 | Carbonxt, Inc. | Magnetic adsorbents and methods of their use for removal of contaminants |
| PL3747847T3 (pl) | 2019-06-05 | 2022-03-28 | Steinmüller Engineering GmbH | Wydzielanie rtęci przy wytwarzaniu klinkieru cementowego |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5264013A (en) * | 1991-06-19 | 1993-11-23 | Krupp Polysius Ag | Method and apparatus for purification of exit gases from kiln installations |
| JP2002355531A (ja) * | 2001-03-27 | 2002-12-10 | Taiheiyo Cement Corp | セメント製造排ガスの処理方法 |
| US20090193968A1 (en) * | 2008-02-05 | 2009-08-06 | Fl Smidth A/S | Method and apparatus for removing contaminants from industrial processing plants |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1984164A (en) | 1931-06-30 | 1934-12-11 | Degea Ag | Process and apparatus for purifying air vitiated with mercury vapors |
| AU559284B2 (en) | 1982-07-08 | 1987-03-05 | Takeda Chemical Industries Ltd. | Adsorption of mercury vapour |
| US6514907B2 (en) | 1997-07-25 | 2003-02-04 | Takeda Chemical Industries, Ltd. | Bromine-impregnated activated carbon and process for preparing the same |
| US5900042A (en) | 1997-08-18 | 1999-05-04 | The United States Of America As Represented By The United States Department Of Energy | Method for the removal of elemental mercury from a gas stream |
| US20020114749A1 (en) | 2000-12-22 | 2002-08-22 | Cole Jerald Alan | Process for removing mercury vapor from flue gas |
| US6808692B2 (en) | 2002-02-14 | 2004-10-26 | Oehr Klaus H | Enhanced mercury control in coal-fired power plants |
| DE60328489D1 (de) | 2002-05-06 | 2009-09-03 | Sorbent Technologies Corp | Verfahren zur entfernung von quecksilber aus verbrennungsgasen |
| US6878358B2 (en) | 2002-07-22 | 2005-04-12 | Bayer Aktiengesellschaft | Process for removing mercury from flue gases |
| US6818043B1 (en) | 2003-01-23 | 2004-11-16 | Electric Power Research Institute, Inc. | Vapor-phase contaminant removal by injection of fine sorbent slurries |
| US7435286B2 (en) * | 2004-08-30 | 2008-10-14 | Energy & Environmental Research Center Foundation | Sorbents for the oxidation and removal of mercury |
| US8069797B2 (en) | 2003-06-03 | 2011-12-06 | Alstom Technology Ltd. | Control of mercury emissions from solid fuel combustion |
| US6848374B2 (en) | 2003-06-03 | 2005-02-01 | Alstom Technology Ltd | Control of mercury emissions from solid fuel combustion |
| EP1737556A4 (en) | 2004-03-22 | 2009-03-25 | Babcock & Wilcox Co | DYNAMIC HALOGENATION OF SORBENTS FOR REMOVING MERCURY FROM COMBUSTION GASES |
| US7479263B2 (en) | 2004-04-09 | 2009-01-20 | The Regents Of The University Of California | Method for scavenging mercury |
| US20060205592A1 (en) | 2005-03-14 | 2006-09-14 | Chien-Chung Chao | Catalytic adsorbents for mercury removal from flue gas and methods of manufacture therefor |
| JP4710441B2 (ja) | 2005-07-05 | 2011-06-29 | 宇部興産株式会社 | セメントの製造方法、及び、セメント焼成設備から排出される排ガスに含まれる水銀含有物質の除去方法 |
| US7615101B2 (en) | 2005-09-07 | 2009-11-10 | Energy & Environmental Research Foundation | High energy dissociation for mercury control systems |
| US7858061B2 (en) | 2005-12-15 | 2010-12-28 | The United States Of America As Represented By The Administrator Of The United States Environmental Protection Agency | Compositions and methods for removing mercury from mercury-containing fluids |
| US20070254807A1 (en) | 2006-05-01 | 2007-11-01 | Ada Environmental Solutions, Llc | Process for the manufacture of carbonaceous mercury sorbent from coal |
| CA2670444C (en) * | 2006-11-22 | 2015-10-27 | Albemarle Sorbent Technologies Corp. | Compositions and methods to sequester flue gas mercury in concrete |
| JP4527139B2 (ja) * | 2007-07-27 | 2010-08-18 | 太平洋セメント株式会社 | 水銀除去装置及びセメント製造システム |
| JP2009203117A (ja) * | 2008-02-28 | 2009-09-10 | Taiheiyo Cement Corp | セメントキルン排ガスの処理装置及び処理方法 |
| JP5211757B2 (ja) | 2008-02-28 | 2013-06-12 | 三菱マテリアル株式会社 | キルン排ガスの処理方法 |
| US8133303B2 (en) | 2008-07-02 | 2012-03-13 | Schwab James J | Apparatus and method for controlling mercury pollution from a cement plant |
| JP2010116283A (ja) * | 2008-11-12 | 2010-05-27 | Taiheiyo Cement Corp | セメントキルン排ガスの処理装置及び処理方法 |
| TW201105406A (en) | 2009-03-10 | 2011-02-16 | Calera Corp | Systems and methods for processing CO2 |
| JP2010235334A (ja) | 2009-03-30 | 2010-10-21 | Taiheiyo Cement Corp | 水銀水溶化方法 |
-
2011
- 2011-12-09 RU RU2013132974/05A patent/RU2013132974A/ru not_active Application Discontinuation
- 2011-12-09 WO PCT/US2011/064093 patent/WO2012082539A1/en not_active Ceased
- 2011-12-09 KR KR1020137015448A patent/KR20140009252A/ko not_active Withdrawn
- 2011-12-09 CN CN201180060179.4A patent/CN103391803B/zh active Active
- 2011-12-09 JP JP2013544586A patent/JP2014501215A/ja active Pending
- 2011-12-09 AU AU2011344213A patent/AU2011344213A1/en not_active Abandoned
- 2011-12-09 PH PH1/2013/500781A patent/PH12013500781A1/en unknown
- 2011-12-09 EP EP11808029.0A patent/EP2651534A1/en not_active Ceased
- 2011-12-09 MY MYPI2013002166A patent/MY160669A/en unknown
- 2011-12-09 BR BR112013013990A patent/BR112013013990A2/pt not_active IP Right Cessation
- 2011-12-09 US US13/885,052 patent/US8961654B2/en active Active
- 2011-12-09 CA CA2815385A patent/CA2815385A1/en not_active Abandoned
- 2011-12-14 AR ARP110104680A patent/AR084287A1/es not_active Application Discontinuation
- 2011-12-15 TW TW100146501A patent/TWI549741B/zh not_active IP Right Cessation
-
2013
- 2013-05-09 CO CO13116423A patent/CO6710948A2/es active IP Right Grant
- 2013-06-12 CL CL2013001683A patent/CL2013001683A1/es unknown
-
2016
- 2016-10-07 JP JP2016198727A patent/JP2017039642A/ja not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5264013A (en) * | 1991-06-19 | 1993-11-23 | Krupp Polysius Ag | Method and apparatus for purification of exit gases from kiln installations |
| JP2002355531A (ja) * | 2001-03-27 | 2002-12-10 | Taiheiyo Cement Corp | セメント製造排ガスの処理方法 |
| US20090193968A1 (en) * | 2008-02-05 | 2009-08-06 | Fl Smidth A/S | Method and apparatus for removing contaminants from industrial processing plants |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2011344213A1 (en) | 2013-06-06 |
| CA2815385A1 (en) | 2012-06-21 |
| BR112013013990A2 (pt) | 2018-05-08 |
| JP2014501215A (ja) | 2014-01-20 |
| EP2651534A1 (en) | 2013-10-23 |
| RU2013132974A (ru) | 2015-01-27 |
| CL2013001683A1 (es) | 2013-12-13 |
| JP2017039642A (ja) | 2017-02-23 |
| MY160669A (en) | 2017-03-15 |
| CO6710948A2 (es) | 2013-07-15 |
| AR084287A1 (es) | 2013-05-08 |
| PH12013500781A1 (en) | 2013-06-03 |
| CN103391803A (zh) | 2013-11-13 |
| WO2012082539A1 (en) | 2012-06-21 |
| US20130220120A1 (en) | 2013-08-29 |
| KR20140009252A (ko) | 2014-01-22 |
| TW201226038A (en) | 2012-07-01 |
| US8961654B2 (en) | 2015-02-24 |
| CN103391803B (zh) | 2016-08-10 |
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| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |