TWI537616B - Infrared cut-off filter and photography device - Google Patents

Infrared cut-off filter and photography device Download PDF

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TWI537616B
TWI537616B TW100121238A TW100121238A TWI537616B TW I537616 B TWI537616 B TW I537616B TW 100121238 A TW100121238 A TW 100121238A TW 100121238 A TW100121238 A TW 100121238A TW I537616 B TWI537616 B TW I537616B
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infrared
wavelength
transmittance
light
cut filter
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TW201224533A (en
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Hideshi Saitoh
Manabu Ohnishi
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Daishinku Corp
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/208Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/26Reflecting filters
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/08Mirrors
    • G02B5/0816Multilayer mirrors, i.e. having two or more reflecting layers
    • G02B5/0825Multilayer mirrors, i.e. having two or more reflecting layers the reflecting layers comprising dielectric materials only
    • G02B5/0833Multilayer mirrors, i.e. having two or more reflecting layers the reflecting layers comprising dielectric materials only comprising inorganic materials only
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/22Absorbing filters

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  • Optics & Photonics (AREA)
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Description

紅外線截止濾鏡及攝影裝置 Infrared cut filter and photographing device

本發明係關於透過可見範圍的光線,且濾掉紅外線的紅外線截止(IR-cut)濾鏡。The present invention relates to an infrared cut-off (IR-cut) filter that transmits light in the visible range and filters out infrared light.

在一般的攝影機或者數位相機等具有代表性的電子攝影機的光學系統,係沿著光軸由被攝體側起依序配設成像光學系統、紅外線截止濾鏡、光學低通濾鏡、CCD(電荷耦合裝置)或者CMOS(互補金氧半導體)等攝影裝置(例如參照專利文獻1)。In an optical system of a representative electronic camera such as a general camera or a digital camera, an imaging optical system, an infrared cut filter, an optical low-pass filter, and a CCD are sequentially disposed from the object side along the optical axis. (Charge-coupled device) or photographic device such as CMOS (Complementary Metal Oxygen Semiconductor) (see, for example, Patent Document 1).

此處所稱的攝影裝置,係具有回應於比人眼可視覺確認的波長帶域(可見區域)的光線更寬的波長帶域的光線之感度特性,除了可見區域外,對紅外區域的光線也會回應。The photographing device referred to herein has a sensitivity characteristic of light in a wavelength band wider than light of a wavelength band (visible region) which is visually identifiable by the human eye, and the light in the infrared region is in addition to the visible region. Will respond.

具體而言,人眼在暗處可感應400nm~620nm程度的範圍的波長之光線,於亮處可感應420nm~700nm程度的範圍的波長之光線。對此,例如CCD,除了400nm~700nm範圍的波長的光線以外,進而對於超過700nm的波長的光線也會感應。Specifically, the human eye can induce light having a wavelength in the range of about 400 nm to 620 nm in the dark, and can induce light having a wavelength in the range of about 420 nm to 700 nm in a bright place. In this regard, for example, the CCD is inductive to light having a wavelength in the range of 400 nm to 700 nm, and further to light having a wavelength exceeding 700 nm.

因此,記載於下述專利文獻1的攝影裝置,除了攝影裝置之CCD以外還設了紅外線截止濾鏡,使紅外區域的光線不會到達攝影裝置,以得到接近於人眼的攝影影像。Therefore, the imaging device described in Patent Document 1 below is provided with an infrared cut filter in addition to the CCD of the imaging device, so that the light in the infrared region does not reach the imaging device to obtain a captured image close to the human eye.

[先前技術文獻][Previous Technical Literature] [專利文獻][Patent Literature]

[專利文獻1]日本特開2000-209510號公報[Patent Document 1] Japanese Patent Laid-Open Publication No. 2000-209510

然而,作為此處之紅外線截止濾鏡,到目前為止,有透過可見區域的光線(可見光)且吸收紅外區域的光線(紅外線)的紅外線吸收玻璃,或者透過可見光而反射紅外線的紅外線截止鍍層等。However, as the infrared cut filter herein, there are an infrared absorbing glass that transmits light (visible light) in the visible region and absorbs light (infrared rays) in the infrared region, or an infrared ray blocking coating that reflects infrared rays through visible light.

作為紅外線吸收玻璃,例如以揭示出使銅離子等色素分散之藍色玻璃。As the infrared absorbing glass, for example, a blue glass in which a dye such as copper ions is dispersed is disclosed.

作為紅外線截止鍍膜,以揭示出例如使TiO2、ZrO2、Ta2O5、Nb2O5等高折射率物質,與SiO2、MgF2等低折射率物質在透明基板上交互層積成數十層之介電質多層膜。As the infrared cut coating, for example, a high refractive index substance such as TiO 2 , ZrO 2 , Ta 2 O 5 or Nb 2 O 5 is deposited, and a low refractive index substance such as SiO 2 or MgF 2 is alternately laminated on a transparent substrate. Dozens of dielectric multilayer films.

以下使用圖7及圖8說明這些紅外線吸收玻璃與紅外線截止鍍層。These infrared absorbing glass and infrared cut plating are described below with reference to FIGS. 7 and 8.

圖7顯示厚度不同的2個紅外線吸收玻璃之透光特性L11、L12。具體而言,顯示L11的透光特性之紅外線吸收玻璃的厚度,為顯示L12的透光特性的紅外線吸收玻璃的厚度的一半以下。Fig. 7 shows light transmission characteristics L11 and L12 of two infrared absorbing glasses having different thicknesses. Specifically, the thickness of the infrared absorbing glass showing the light transmitting property of L11 is less than or equal to half the thickness of the infrared absorbing glass which exhibits the light transmitting property of L12.

作為紅外線截止濾鏡,使用紅外線吸收玻璃的場合,如圖7之L11及L12所示,由可見光區域跨至紅外線區域,可以得到接近於人眼的感度特性之「和緩地減少透過率的特性」。此外,由L11與L12的比較可以承認在紅外線吸收玻璃的可見光區域之透過率,特別是在600nm~700nm的波長帶域的透過率,是厚度越薄者越高。When the infrared ray absorbing glass is used as the infrared ray blocking filter, as shown by L11 and L12 in Fig. 7, the visible light region is crossed to the infrared ray region, and the sensitivity characteristic of the human eye can be obtained to "slowly reduce the transmittance." . Further, from the comparison of L11 and L12, the transmittance in the visible light region of the infrared absorbing glass, particularly the transmittance in the wavelength band of 600 nm to 700 nm, can be recognized as the thickness is thinner.

例如,具有圖7之L11所示的透光特性的紅外線吸收玻璃,對於700nm的波長的光線有約10%的透過率,透過750nm程度的波長的光線。因此,無法充分截止紅外線區域的光線,在攝影裝置會拍攝到人眼無法感知的紅外線區域的影像。For example, the infrared absorbing glass having the light transmitting property shown by L11 in Fig. 7 has a transmittance of about 10% for light having a wavelength of 700 nm and a light having a wavelength of about 750 nm. Therefore, the light in the infrared region cannot be sufficiently cut off, and an image of an infrared region that the human eye cannot perceive is captured by the photographing device.

對此,在具有L11所示的透光特性的紅外線吸收玻璃之2倍以上的厚度的紅外線吸收玻璃,如L12之透光特性所示,對於700nm的波長的光線之透過率約為0%,可以充分截止超過700nm的波長的光線。On the other hand, in the infrared absorbing glass having a thickness twice or more of the infrared absorbing glass having the light transmitting property indicated by L11, as shown by the light transmitting property of L12, the transmittance of light having a wavelength of 700 nm is about 0%. Light that exceeds the wavelength of 700 nm can be sufficiently cut off.

因而,從前的紅外線截止濾鏡,使用具有L12所示的透光特性的紅外線吸收玻璃。Therefore, in the former infrared cut filter, an infrared absorbing glass having a light transmitting property indicated by L12 is used.

但是,作為紅外線截止濾鏡,使用具有L12所示的透光特性的紅外線吸收玻璃的場合,在600nm的波長呈現透過率為約50%的透光特性,所以與在640nm之波長具有成為約50%之L11所示的透光特性的紅外線吸收玻璃的場合相比,對於波長600nm~700nm之紅色的可見光之透過率低,會產生無法使紅色的可見光線充分透過的不良情形。CCD或CMOS等攝影裝置的攝影元件,紅色的感度比藍色或綠色還低。因此,紅色的可見光線的透過若是不充分的話,無法以攝影元件充分感知紅色,以攝影裝置拍攝的影像會成為紅色減弱的暗的影像。However, when an infrared ray absorbing glass having a light transmitting property indicated by L12 is used as the infrared cut filter, the transmittance at a wavelength of 600 nm exhibits a light transmittance of about 50%, so that it has a wavelength of about 50 at a wavelength of 640 nm. In the case of the infrared absorbing glass having a light transmitting property indicated by L11 in %, the transmittance of red visible light having a wavelength of 600 nm to 700 nm is low, and a problem that the red visible light is not sufficiently transmitted may occur. For photographic elements such as CCD or CMOS, the red sensitivity is lower than blue or green. Therefore, if the transmission of the red visible light is insufficient, the red color cannot be sufficiently perceived by the imaging element, and the image captured by the imaging device becomes a dark image in which the red color is weakened.

如此,作為紅外線截止濾鏡使用紅外線吸收玻璃的場合,無法使紅色的可見光線充分透過,而使透過率成為0%之點配合於700nm。As described above, when the infrared ray absorbing glass is used as the infrared cut filter, it is not possible to sufficiently transmit red visible light, and the transmittance is set to 0% at a point where the transmittance is 0%.

其次,作為紅外線截止濾鏡,使用紅外線截止鍍層的場合,如圖8之L13所示,由可見區域跨至紅外區域可以得到「透過率急遽減少的特性」。因此,要使紅色的可見光線充分透過,而透過率成為約0%之點配合於700nm會變得容易。Next, when an infrared cut-off plating layer is used as the infrared cut filter, as shown by L13 in Fig. 8, a characteristic in which the transmittance is rapidly reduced can be obtained from the visible region to the infrared region. Therefore, it is easy to sufficiently transmit red visible light and to have a transmittance of about 0% in combination with 700 nm.

然而,紅外線截止鍍層,不是吸收紅外線而截止(遮斷),是反射紅外線而截止。因此,紅外線截止鍍層,會促進在該紅外線截止鍍層與成像光學系統之間因為光的反覆反射所導致的鬼影。However, the infrared cut-off plating does not absorb infrared rays and is cut off (interrupted), and is reflected by infrared rays. Therefore, the infrared cut-off plating promotes ghosting due to the repetitive reflection of light between the infrared cut-off plating and the imaging optical system.

本發明係有鑑於這樣的狀況而完成之發明,目的在於提供可以使波長600nm~700nm的紅色的可見光線充分透過,而截止波長超過700nm的光線,且可以抑制鬼影的發生之紅外線截止濾鏡。The present invention has been made in view of such circumstances, and an object of the invention is to provide an infrared cut filter capable of sufficiently transmitting red visible light having a wavelength of 600 nm to 700 nm and blocking light having a wavelength exceeding 700 nm and suppressing generation of ghosts. .

相關於本發明之紅外線截止濾鏡,係截止紅外線之紅外線截止濾鏡,其特徵為具備:吸收紅外線之紅外線吸收體,及反射紅外線的紅外線反射體;前述紅外線吸收體,具有620nm~670nm的波長帶域內的波長之透過率為50%之透光特性;前述紅外線反射體,具有670nm~690nm的波長帶域內的波長之透過率為50%之透光特性;前述紅外線反射體呈現50%的透過率之波長,比前述紅外線吸收體呈現50%的透過率的波長更長;藉由前述紅外線吸收體與前述紅外線反射體之組合,具有620nm~670nm之波長帶域內的波長的透過率為50%,700nm之波長的透過率為不滿5%之透光特性。The infrared cut filter according to the present invention is an infrared cut filter that cuts off infrared rays, and is characterized by comprising: an infrared absorber that absorbs infrared rays; and an infrared reflector that reflects infrared rays; and the infrared absorber has a wavelength of 620 nm to 670 nm. The transmittance of the wavelength in the band is 50% of the light transmission property; the infrared reflector has a transmittance of 50% in the wavelength band of 670 nm to 690 nm; the infrared reflector exhibits 50% The wavelength of the transmittance is longer than the wavelength at which the infrared absorbing body exhibits a transmittance of 50%; and the transmittance of the wavelength band in the wavelength range of 620 nm to 670 nm by the combination of the infrared absorbing body and the infrared ray reflector The transmittance of 50%, the wavelength of 700 nm is less than 5% of the light transmission property.

根據此紅外線截止濾鏡,藉由在620nm~670nm之波長帶域內的波長呈現透過率為50%的透光特性之紅外線吸收體與在670nm~690nm的波長帶域內的波長呈現透過率為50%的透光特性之紅外線反射體之組合,可以跨可見光區域至紅外線區域,使透過率和緩地減少,可得在700nm之波長的透過率成為約0%之接近於人眼的感度特性之透光特性。According to the infrared cut filter, the transmittance of the infrared absorber having a light transmittance of 50% in the wavelength range of 620 nm to 670 nm and the wavelength in the wavelength range of 670 nm to 690 nm The combination of 50% light-transmitting infrared reflectors can reduce the transmittance from the visible light region to the infrared region, and the transmittance at a wavelength of 700 nm becomes about 0%, which is close to the sensitivity characteristic of the human eye. Light transmission characteristics.

此外,於本發明之紅外線截止濾鏡,於紅外線吸收體,使用在620nm~670nm之波長帶域內的波長呈現透過率為50%的透光特性之紅外線吸收體,例如具有圖7之L11所示的透光特性的紅外線吸收玻璃,透過率成為約0%(不滿5%)之點,藉由組合紅外線吸收體之紅外線吸收作用與紅外線反射體之紅外線反射作用,可以配合於700nm。因此,本發明之紅外線截止濾鏡,與具有圖7之L12所示的透光特性的紅外線吸收玻璃所構成的從前的紅外線截止濾鏡相比,在可見光區域,特別是在600nm~700nm的波長帶域,可以維持高的透過率。總之,可以截止波長超過700nm的紅外線,而且可以使在攝影裝置之攝影元件可以感知的充分量之紅色光線(波長600nm~700nm的光線)透過。因而,於攝影裝置之紅外線截止濾鏡,藉由適用本發明之紅外線截止濾鏡,可以解消攝影元件的紅色感度較弱,以攝影裝置拍攝的畫面容易變成較暗的影像的缺點。Further, in the infrared cut filter of the present invention, an infrared absorber having a light transmission characteristic of a transmittance of 50% in a wavelength band of 620 nm to 670 nm is used for the infrared absorber, and for example, it has the L11 of FIG. The infrared ray absorbing glass having a light transmitting property has a transmittance of about 0% (less than 5%), and can be blended at 700 nm by combining the infrared absorbing effect of the infrared absorbing body with the infrared ray reflecting action of the infrared ray reflector. Therefore, the infrared cut filter of the present invention has a wavelength in the visible light region, particularly in the range of 600 nm to 700 nm, compared with the former infrared cut filter composed of the infrared absorbing glass having the light transmitting property shown in L12 of Fig. 7 . Banding can maintain high transmittance. In short, infrared rays having a wavelength exceeding 700 nm can be cut off, and a sufficient amount of red light (light having a wavelength of 600 nm to 700 nm) which can be perceived by the imaging element of the photographing device can be transmitted. Therefore, by applying the infrared cut filter of the present invention to the infrared cut filter of the photographing apparatus, it is possible to eliminate the disadvantage that the red sensitivity of the photographing element is weak and the picture taken by the photographing apparatus is likely to become a dark image.

此外,在本發明之紅外線截止濾鏡,藉由於紅外線反射體組合紅外線吸收體,抑制了藉由紅外線反射體反射的光之量。具體而言,紅外線反射體3之半值波長(透過率成為50%之波長)比紅外線吸收體2之半值波長更長,藉由在紅外線吸收體2之紅外線的吸收,抑制藉由紅外線反射體3反射的光(紅外光)之量。因此,可以抑制起因於紅外線反射體之光的反射導致的鬼影的產生。Further, in the infrared cut filter of the present invention, the amount of light reflected by the infrared reflector is suppressed by combining the infrared absorber with the infrared reflector. Specifically, the half-value wavelength of the infrared ray reflector 3 (the wavelength at which the transmittance is 50%) is longer than the half-value wavelength of the infrared absorbing body 2, and the infrared ray absorption in the infrared ray absorbing body 2 suppresses reflection by infrared rays. The amount of light (infrared light) reflected by the body 3. Therefore, generation of ghosts due to reflection of light by the infrared reflector can be suppressed.

此外,640nm的波長之透過率成為50%的具有圖7之L11所示的透光特性的紅外線吸收玻璃的厚度,如作為從前的紅外線截止濾鏡使用的具有圖7之L12所示的透光特性的紅外線吸收玻璃的厚度之一半以下所教示的,於構成本發明之紅外線截止濾鏡的具有在620nm~670nm的波長帶域內之波長的透過率成為50%的透光特性的紅外線吸收體,可以使用厚度比具有圖7之L12所示的透光特性的從前的紅外線吸收玻璃所構成的紅外線截止濾鏡更薄者。因此,能夠提供以與僅藉著紅外線吸收體構成的從前的紅外線截止濾鏡相同厚度或者比其更薄的厚度,充分透過紅色可見光線,而截止紅外線,且於可見光區域,具有接近於人眼的透光特性之紅外線截止濾鏡。Further, the transmittance at a wavelength of 640 nm is 50%, and the thickness of the infrared absorbing glass having the light transmitting property shown by L11 of FIG. 7 is used as the light transmission shown by L12 of FIG. 7 used as the former infrared cut filter. An infrared absorber having a light transmission characteristic in which the transmittance in the wavelength band of 620 nm to 670 nm is 50% in the wavelength range of 620 nm to 670 nm which is the infrared cut filter of the present invention, which is one of the thicknesses of the characteristic infrared absorbing glass. It is possible to use a thinner infrared cut filter which is thicker than the former infrared absorbing glass having the light transmitting property shown by L12 in Fig. 7 . Therefore, it is possible to provide a thickness which is the same as or thinner than the former infrared cut filter which is constituted only by the infrared absorber, and sufficiently transmits the red visible light to cut off the infrared rays, and in the visible light region, is close to the human eye. An infrared cut filter for light transmission characteristics.

此外,相關於本發明之紅外線截止濾鏡,亦可以是紅外線吸收體,具有700nm的波長之透過率成為10%~40%的透光特性,前述紅外線反射體,具有700nm的波長之透過率成為不滿15%的透光特性。Further, the infrared cut filter according to the present invention may be an infrared absorber having a light transmittance of 10% to 40% at a wavelength of 700 nm, and a transmittance of 700 nm at the infrared reflector. Less than 15% light transmission characteristics.

此紅外線截止濾鏡,藉由組合在700nm的波長之透過率呈現10%~40%的透光特性之紅外線吸收體,與在700nm的波長之透過率呈現不滿15%的透光特性之紅外線反射體,可以確實在紅色之可見光線的波長帶域(600nm~700nm)得到高的透過率。The infrared cut filter is an infrared absorber that combines a light transmittance of 10% to 40% with a transmittance at a wavelength of 700 nm, and an infrared reflection with a transmittance of less than 15% at a wavelength of 700 nm. The body can be surely obtained a high transmittance in the wavelength band of the red visible light (600 nm to 700 nm).

此外,相關於本發明之紅外線截止濾鏡,前述紅外線反射體,亦可具有在450nm~650nm的波長帶域內之各波長呈現80%以上之透過率,在450nm~650nm的波長帶域之透過率的平均在90%以上之透光特性。Further, in the infrared cut filter according to the present invention, the infrared reflector may have a transmittance of 80% or more at each wavelength in a wavelength range of 450 nm to 650 nm, and may be transmitted in a wavelength band of 450 nm to 650 nm. The average rate of light transmission is above 90%.

此紅外線截止濾鏡,可在450nm~650nm的波長帶域得到依存於紅外線吸收體的透光特性之透光特性,所以跨可見光區域至紅外線區域,透過率和緩地減少,在700nm的波長可得到透過率約為0%之接近於人眼的感度特性的透光特性,而且在可見光區域,特別是在紅色的可見光線的波長帶域(600nm~700nm)可得到高的透過率。The infrared cut filter can obtain a light transmitting property depending on the light transmitting property of the infrared absorbing body in a wavelength range of 450 nm to 650 nm, so that the transmittance is gradually reduced across the visible light region to the infrared ray region, and the wavelength can be obtained at a wavelength of 700 nm. The transmittance is about 0%, which is close to the light transmission characteristic of the sensitivity characteristic of the human eye, and a high transmittance can be obtained in the visible light region, particularly in the wavelength band of the red visible light (600 nm to 700 nm).

此外,於相關於本發明的紅外線截止濾鏡,亦可於一紅外線吸收體之一主面,設有一紅外線反射體。Further, in the infrared cut filter relating to the present invention, an infrared reflector may be provided on one main surface of an infrared absorber.

在此紅外線截止濾鏡,於一紅外線吸收體之一主面,設有一紅外線反射體,所以與紅外線吸收體與紅外線反射體為個別設置的紅外線截止濾鏡相比,可以薄型化,可以使內藏該紅外線截止濾鏡的攝影裝置薄型化。In this infrared cut filter, an infrared reflector is provided on one main surface of an infrared absorber, so that the infrared absorber and the infrared reflector can be thinned compared to the infrared cut filter provided separately. The imaging device that houses the infrared cut filter is thinned.

根據本發明的話,可以提供可以使波長600nm~700nm的紅色的可見光線充分透過,而截止波長超過700nm的光線,且可以抑制鬼影的發生之紅外線截止濾鏡。According to the present invention, it is possible to provide an infrared cut filter which can sufficiently transmit red visible light having a wavelength of 600 nm to 700 nm and cut off light having a wavelength exceeding 700 nm and suppress ghost generation.

以下,參照圖面說明本發明之實施型態。Hereinafter, embodiments of the present invention will be described with reference to the drawings.

<實施型態1><implementation type 1>

相關於本實施型態1之紅外線截止濾鏡1,如圖1所示,於攝影裝置,係被配置於沿著攝影光徑的光軸配置的成像光學系統4與攝影裝置5之間。As shown in FIG. 1, the infrared cut filter 1 according to the first embodiment is disposed between the imaging optical system 4 disposed along the optical axis of the imaging optical path and the imaging device 5 in the imaging device.

此紅外線截止濾鏡1,係由黏接透過可見光線,且吸收紅外線之紅外線吸收體2,與透過可見光線,且反射紅外線的紅外線反射體3而構成。總之,紅外線截止濾鏡1,為在一紅外線吸收體2之一主面(後述之紅外線吸收玻璃21之另一主面212)上,設一紅外線反射體3之構成。The infrared cut filter 1 is composed of an infrared absorber 3 that adheres to visible rays and absorbs infrared rays, and an infrared reflector 3 that transmits visible light and reflects infrared rays. In short, the infrared cut filter 1 has a configuration in which an infrared reflector 3 is provided on one main surface of one infrared ray absorbing body 2 (the other main surface 212 of the infrared absorbing glass 21 to be described later).

紅外線吸收體2,係在紅外線吸收玻璃21之一主面211形成防反射膜22(AR鍍膜)而構成。The infrared absorbing body 2 is configured by forming an anti-reflection film 22 (AR plating film) on one main surface 211 of the infrared absorbing glass 21.

作為紅外線吸收玻璃21,使用把銅離子等色素予以分散之藍色玻璃,例如厚度為0.2mm~1.2mm之方形薄板狀的玻璃。As the infrared absorbing glass 21, a blue glass in which a dye such as copper ions is dispersed, for example, a square thin plate glass having a thickness of 0.2 mm to 1.2 mm is used.

此外,防反射膜22,係對紅外線吸收玻璃21之一主面211,藉由習知的真空蒸鍍裝置(省略圖示)進行真空蒸鍍MgF2所構成的單層、Al2O2與ZrO2與MgF2所構成的多層膜、TiO2與SiO2所構成的多層膜之任一膜而形成的。又,防反射膜22,係藉由監視膜厚同時進行蒸鍍動作,在達到特定的膜厚時關閉設於蒸鍍源(省略圖示)附近的遮板(省略圖示)停止蒸鍍物質的蒸鍍而進行的。這樣的防反射膜22,係以大氣中之折射率N,比大氣的折射率(約1.0)更大,而且比紅外線吸收玻璃21的折射率更小的方式被形成的。 Further, the anti-reflection film 22 is a single layer or Al 2 O 2 which is formed by vacuum-depositing MgF 2 by a conventional vacuum vapor deposition apparatus (not shown) on one main surface 211 of the infrared absorbing glass 21. It is formed by any one of a multilayer film composed of ZrO 2 and MgF 2 and a multilayer film composed of TiO 2 and SiO 2 . In addition, the anti-reflection film 22 performs a vapor deposition operation while monitoring the film thickness, and when a specific film thickness is reached, the shutter (not shown) provided in the vicinity of the vapor deposition source (not shown) is closed to stop the vapor deposition material. The evaporation is carried out. Such an anti-reflection film 22 is formed such that the refractive index N in the atmosphere is larger than the refractive index of the atmosphere (about 1.0) and smaller than the refractive index of the infrared absorbing glass 21.

這樣的紅外線吸收體2,具有在620nm~670nm的波長帶域內之波長的透過率為50%,在700nm的波長之透過率成為10%~40%的透光特性。又,於這樣的紅外線吸收體2的透光特性,透過率在400nm~550nm之波長帶域內的波長成為90%以上之最大值。 The infrared absorber 2 has a light transmittance of 50% in a wavelength band of 620 nm to 670 nm and a light transmittance of 10% to 40% at a wavelength of 700 nm. Moreover, in the light transmission characteristics of the infrared absorber 2, the wavelength in the wavelength range of 400 nm to 550 nm is 90% or more.

紅外線反射體3,於透明基鈑31之一主面311被形成紅外線反射膜32。 The infrared reflecting body 3 is formed with an infrared reflecting film 32 on one main surface 311 of the transparent base 31.

作為透明基板31,使用透過可見光及紅外線的無色透明玻璃,例如厚度為0.2mm~1.0mm之方形薄板狀的玻璃。 As the transparent substrate 31, a colorless transparent glass that transmits visible light and infrared rays, for example, a square thin plate glass having a thickness of 0.2 mm to 1.0 mm is used.

紅外線反射膜32,如圖2所示,係高折射率材料構成的第1薄膜321,與低折射率材料構成的第2薄膜322交互被層積複數而成之多層膜。又,在此實施型態1,第1薄膜321使用TiO2,第2薄膜322使用SiO2,奇數層為TiO2,偶數層為SiO2,最終層為SiO2,但在膜設計上,最終層為SiO2的話,奇數層為SiO2,偶數層為TiO2亦可。 As shown in FIG. 2, the infrared reflecting film 32 is a multilayer film in which a first film 321 made of a high refractive index material and a second film 322 made of a low refractive index material are laminated to form a multilayer film. Further, in this embodiment 1, the first film 321 uses TiO 2 , the second film 322 uses SiO 2 , the odd layer is TiO 2 , the even layer is SiO 2 , and the final layer is SiO 2 , but in film design, finally When the layer is SiO 2 , the odd layer is SiO 2 and the even layer is TiO 2 .

作為此紅外線反射膜32之製造方法,對於透明基板31之一主面311,藉由周知之真空蒸鍍裝置(省略圖示)交互蒸鍍TiO2與SiO2,使用如圖2所示之形成紅外線反射膜32的方法。又,各薄膜321、322之膜厚調整,係藉由監視膜厚同時進行蒸鍍動作,在達到特定的膜厚時關閉設於蒸鍍源(省略圖示)附近的遮板(省略圖示)停止蒸鍍物質(TiO2、SiO2)的蒸鍍而進行的。 As a method of manufacturing the infrared ray reflection film 32, TiO 2 and SiO 2 are alternately vapor-deposited on one main surface 311 of the transparent substrate 31 by a known vacuum vapor deposition apparatus (not shown), and formed as shown in FIG. 2 . A method of infrared reflecting film 32. In addition, the film thickness of each of the films 321 and 322 is adjusted, and the vapor deposition operation is performed while monitoring the film thickness, and when a specific film thickness is reached, the shutter provided in the vicinity of the vapor deposition source (not shown) is closed (not shown) The vapor deposition of the vapor deposition material (TiO 2 , SiO 2 ) was stopped.

此外,紅外線反射膜32,如圖2所示,由透明基板31之一主面311側起依序以序數詞定義之複數層,在本實施型態1為1層、2層、3層......所構成。這些1層、2層、3層......分別之層,係第1薄膜321與第2薄膜322被層積而構成的。藉由使這些被層積的第1薄膜321與第2薄膜322之光學膜厚的不同,使得1層、2層、3層......分別之厚度不同。又,此處所謂的光學膜厚,係由下列數式1來求出。 In addition, as shown in FIG. 2, the infrared reflecting film 32 is a plurality of layers defined by an ordinal number sequentially from one side of the main surface 311 of the transparent substrate 31, and is one layer, two layers, and three layers in the present embodiment. ..... constituted. The layers of the first layer, the second layer, and the third layer are formed by laminating the first film 321 and the second film 322. By differentiating the optical film thicknesses of the laminated first film 321 and the second film 322, the thicknesses of the first layer, the second layer, and the third layer are different. Here, the optical film thickness referred to herein is obtained by the following formula 1.

[數式1]Nd=d×N×4/λ(Nd:光學膜厚、d:物理膜厚、N:折射率、λ:中心波長) [Formula 1] Nd=d×N×4/λ (Nd: optical film thickness, d: physical film thickness, N: refractive index, λ: center wavelength)

於本實施型態,紅外線反射體3,具有在450nm~650nm的波長帶域內之各波長呈現80%以上的透過率,在此450nm~650nm波長帶域呈現平均90%以上的透過率,在670nm~690nm之波長帶域內的波長之透過率成為50%,在700nm的波長之透過率成為不滿15%的透光特性。此外,此紅外線反射體3呈現50%之透過率的波長,比紅外線吸收體2呈現50%之透過率的波長更長。 In the present embodiment, the infrared reflector 3 has a transmittance of 80% or more for each wavelength in the wavelength range of 450 nm to 650 nm, and an average transmittance of 90% or more in the wavelength range of 450 nm to 650 nm. The transmittance at a wavelength in the wavelength band of 670 nm to 690 nm is 50%, and the transmittance at a wavelength of 700 nm is a light transmission characteristic of less than 15%. Further, the infrared ray reflector 3 exhibits a wavelength of 50% transmittance, which is longer than a wavelength at which the infrared absorbing body 2 exhibits a transmittance of 50%.

這樣的紅外線吸收體2與紅外線反射體3所構成的紅外線截止濾鏡1,例如具有0.4mm~1.6mm之厚度。總之,構成紅外線吸收體2的紅外線吸收體玻璃21的厚度,及構成紅外線反射體3的透明基板31的厚度,為紅外線吸收體2與紅外線反射體3的厚度之合計,例如為0.4mm~1.6mm。The infrared cut filter 1 composed of the infrared absorber 2 and the infrared reflector 3 has a thickness of, for example, 0.4 mm to 1.6 mm. In short, the thickness of the infrared absorber glass 21 constituting the infrared absorber 2 and the thickness of the transparent substrate 31 constituting the infrared reflector 3 are the total thickness of the infrared absorber 2 and the infrared reflector 3, and are, for example, 0.4 mm to 1.6. Mm.

接著,紅外線截止濾鏡1,藉由前述之紅外線吸收體2及紅外線反射體3之透光特性的組合,具有在450nm~550nm之波長帶域內的波長下透過率為90%以上,在620nm~670nm之波長帶域內的波長下透過率為50%,在700nm之波長下透過率未滿5%之透光性。Next, the infrared cut filter 1 has a transmittance of 90% or more at a wavelength in a wavelength range of 450 nm to 550 nm by a combination of the light transmitting characteristics of the infrared absorber 2 and the infrared reflector 3 described above, at 620 nm. The transmittance at a wavelength in the wavelength band of -670 nm is 50%, and the transmittance at a wavelength of 700 nm is less than 5%.

相關於此實施型態1的紅外線截止濾鏡1之具體例,作為實施例1~3顯示於下,相關於實施例1~3之各紅外線截止濾鏡1之波長特性及構成顯示輿圖3~5及下列之表1~2。Specific examples of the infrared cut filter 1 according to the first embodiment are shown as the first to third embodiments, and the wavelength characteristics and configuration of the infrared cut filter 1 according to the first to third embodiments are shown in FIG. 5 and Tables 1 to 2 below.

<實施例1><Example 1>

在實施例1,作為紅外線吸收玻璃21,使用把銅離子等色素予以分散之藍色玻璃,厚度為0.8mm,大氣中之折射率N約為1.5之玻璃板。接著,於此紅外線吸收玻璃21之一主面211,依照大氣中之折射率N為1.6之Al2O3膜,大氣中之折射率N為2.0之ZrO2膜、大氣中之折射率N為1.4之MgF2膜的順序,藉由真空蒸鍍形成構成防反射膜22之各膜而得紅外線吸收體2。In the first embodiment, as the infrared absorbing glass 21, a glass plate having a blue glass in which a dye such as copper ions is dispersed, a thickness of 0.8 mm, and a refractive index N in the atmosphere of about 1.5 is used. Next, on one main surface 211 of the infrared absorbing glass 21, an Al 2 O 3 film having a refractive index N of 1.6 in the atmosphere, a ZrO 2 film having a refractive index N of 2.0 in the atmosphere, and a refractive index N in the atmosphere are In the order of the MgF 2 film of 1.4, the respective films constituting the anti-reflection film 22 were formed by vacuum evaporation to obtain the infrared absorber 2.

此紅外線吸收體2,具有圖3之L1所示的透光特性。又,在此實施例1,光線的入射角為0度,亦即使光線垂直入射。This infrared absorbing body 2 has a light transmitting property as shown by L1 in Fig. 3 . Further, in this embodiment 1, the incident angle of the light is 0 degrees, even if the light is incident perpendicularly.

總之,紅外線吸收玻璃21,具有在400nm~550nm的波長帶域之透過率為90%以上,在550nm~700nm之波長帶域之透過率減少,約在640nm之波長透過率成為50%,在700nm之波長透過率成為約17%之透光特性。In short, the infrared absorbing glass 21 has a transmittance of 90% or more in a wavelength band of 400 nm to 550 nm, a transmittance in a wavelength band of 550 nm to 700 nm, and a transmittance of about 50% at a wavelength of about 640 nm at 700 nm. The wavelength transmittance is a light transmission characteristic of about 17%.

作為紅外線反射體3之透明基板31,使用大氣中之折射率N為1.5,厚度0.3mm之玻璃板。此外,作為構成紅外線反射膜32的第1薄膜321,使用大氣中之折射率N為2.30之TiO2,作為第2薄膜322,使用大氣中之折射率N為1.46之SiO2,這些之中心波長為688nm。As the transparent substrate 31 of the infrared reflector 3, a glass plate having a refractive index N of 1.5 in the atmosphere and a thickness of 0.3 mm was used. Further, as the first film 321 constituting the infrared ray reflection film 32, TiO 2 having a refractive index N of 2.30 in the atmosphere is used, and as the second film 322, SiO 2 having a refractive index N of 1.46 in the atmosphere is used, and the center wavelength thereof is used. It is 688nm.

這些各薄膜321、322分別之光學膜厚,藉由使成為表1所示的值的方式之前述的40層所構成的紅外線反射膜32的製造方法,對於透明基板31之一主面311,形成各薄膜321、322,而得到紅外線反射體3。The optical film thickness of each of the films 321 and 322 is a method for producing the infrared reflecting film 32 composed of the above-described 40 layers which is a value shown in Table 1, and is applied to one main surface 311 of the transparent substrate 31. Each of the films 321 and 322 is formed to obtain an infrared reflector 3.

表1顯示紅外線截止濾鏡1之紅外線反射膜32的組成及各薄膜(第1薄膜321、第2薄膜322)之光學膜厚。Table 1 shows the composition of the infrared reflecting film 32 of the infrared cut filter 1 and the optical film thickness of each of the films (the first film 321 and the second film 322).

此紅外線反射體3,具有圖3之L2所示的透光特性。總之,紅外線反射體3(紅外線反射膜32)之透光特性,具有在395nm~670nm的波長帶域(包含450nm~650nm之波長帶域的波長帶域)呈現約100%的透過率,波長超過約670nm時透過率急遽減少,約在680nm之波長透過率成為50%,在700nm之波長透過率成為約4%之透光特性。This infrared reflector 3 has a light transmitting property as shown by L2 in Fig. 3 . In short, the light transmitting property of the infrared reflector 3 (infrared reflecting film 32) has a transmittance of about 100% in a wavelength band of 395 nm to 670 nm (a wavelength band including a wavelength band of 450 nm to 650 nm), and the wavelength exceeds At about 670 nm, the transmittance is drastically reduced, the transmittance at a wavelength of about 680 nm is 50%, and the transmittance at a wavelength of 700 nm is about 4%.

接著,如圖1所示,於紅外線吸收玻璃21之另一主面212,藉由黏接透明基板31之另一主面312,得到厚度1.1mm之相關於實施例1之紅外線截止濾鏡1。Next, as shown in FIG. 1, the other main surface 212 of the infrared absorbing glass 21 is bonded to the other main surface 312 of the transparent substrate 31 to obtain an infrared cut filter 1 according to the first embodiment having a thickness of 1.1 mm. .

相關於此實施例1的紅外線截止濾鏡1,具有組合紅外線吸收體2及紅外線反射體3的透光特性之圖3的L3所示的透光特性。總之,實施例1之紅外線截止濾鏡1,具有在400nm~550nm的波長帶域之透過率為90%以上,在550nm~700nm之波長帶域之透過率減少,約在640nm之波長透過率成為50%,在700nm之波長透過率成為約0%之透光特性。The infrared cut filter 1 according to the first embodiment has light transmission characteristics as shown by L3 in Fig. 3 in which the light transmission characteristics of the infrared absorber 2 and the infrared reflector 3 are combined. In short, the infrared cut filter 1 of the first embodiment has a transmittance in a wavelength band of 400 nm to 550 nm of 90% or more, a transmittance in a wavelength band of 550 nm to 700 nm, and a transmittance at a wavelength of about 640 nm. 50%, the transmittance at a wavelength of 700 nm becomes a light transmission characteristic of about 0%.

<實施例2><Example 2>

在本實施例2,作為紅外線吸收玻璃21,使用把銅離子等色素予以分散之藍色玻璃,厚度為0.55mm,大氣中之折射率N約為1.5之玻璃板。接著,於此紅外線吸收玻璃21之一主面211,依照大氣中之折射率N為1.6之Al2O3膜,大氣中之折射率N為2.0之ZrO2膜、大氣中之折射率N為1.4之MgF2膜的順序,藉由真空蒸鍍形成構成防反射膜22之各膜而得紅外線吸收體2。In the second embodiment, as the infrared absorbing glass 21, a glass plate having a blue glass in which a dye such as copper ions is dispersed, a thickness of 0.55 mm, and a refractive index N in the atmosphere of about 1.5 is used. Next, on one main surface 211 of the infrared absorbing glass 21, an Al 2 O 3 film having a refractive index N of 1.6 in the atmosphere, a ZrO 2 film having a refractive index N of 2.0 in the atmosphere, and a refractive index N in the atmosphere are In the order of the MgF 2 film of 1.4, the respective films constituting the anti-reflection film 22 were formed by vacuum evaporation to obtain the infrared absorber 2.

此紅外線吸收體2,具有圖4之L5所示的透光特性。又,在此實施例2,光線的入射角為0度,亦即使光線垂直入射。This infrared absorbing body 2 has a light transmitting property as shown by L5 in Fig. 4 . Further, in this embodiment 2, the incident angle of the light is 0 degrees, even if the light is incident perpendicularly.

總之,紅外線吸收玻璃21,具有在400nm~550nm的波長帶域之透過率為90%以上,在550nm~700nm之波長帶域之透過率減少,約在650nm之波長透過率成為50%,在700nm之波長透過率成為約25%之透光特性。In short, the infrared absorbing glass 21 has a transmittance in a wavelength band of 400 nm to 550 nm of 90% or more, a transmittance in a wavelength band of 550 nm to 700 nm, and a transmittance at a wavelength of about 650 nm of 50% at 700 nm. The wavelength transmittance is about 25% of light transmission characteristics.

作為紅外線反射體3之透明基板31,使用大氣中之折射率N為1.5,厚度0.3mm之玻璃板。此外,作為構成紅外線反射膜32的第1薄膜321,使用大氣中之折射率N為2.30之TiO2,作為第2薄膜322,使用大氣中之折射率N為1.46之SiO2,這些之中心波長為748nm。As the transparent substrate 31 of the infrared reflector 3, a glass plate having a refractive index N of 1.5 in the atmosphere and a thickness of 0.3 mm was used. Further, as the first film 321 constituting the infrared ray reflection film 32, TiO 2 having a refractive index N of 2.30 in the atmosphere is used, and as the second film 322, SiO 2 having a refractive index N of 1.46 in the atmosphere is used, and the center wavelength thereof is used. It is 748 nm.

這些各薄膜321、322分別之光學膜厚,藉由使成為表2所示的值的方式之前述的40層所構成的紅外線反射膜32的製造方法,對於透明基板31之一主面311,形成各薄膜321、322,而得到紅外線反射體3。The optical film thickness of each of the films 321 and 322 is a method for producing the infrared reflecting film 32 composed of the above-described 40 layers which is a value shown in Table 2, and is applied to one main surface 311 of the transparent substrate 31. Each of the films 321 and 322 is formed to obtain an infrared reflector 3.

表2顯示紅外線截止濾鏡1之紅外線反射膜32的組成及各薄膜(第1薄膜321、第2薄膜322)之光學膜厚。Table 2 shows the composition of the infrared ray reflection film 32 of the infrared cut filter 1 and the optical film thickness of each of the films (the first film 321 and the second film 322).

此紅外線反射體3,具有圖4之L6所示的透光特性。總之,紅外線反射體3(紅外線反射膜32)之透光特性,具有在380nm~420nm的波長帶域之透過率為平均10%以下,波長超過約430nm時透過率急遽上升,在450nm~670nm的波長帶域(包含450nm~650nm之波長帶域的波長帶域)呈現約100%(平均90%以上)的透過率,超過波長670nm時透過率急遽減少而在約680nm之波長透過率成為50%,在700nm之波長透過率成為約3%之透光特性。This infrared reflector 3 has a light transmitting property as shown by L6 in Fig. 4 . In short, the light transmittance of the infrared reflector 3 (infrared reflecting film 32) has an average transmittance of 10% or less in a wavelength band of 380 nm to 420 nm, and a sharp increase in transmittance when the wavelength exceeds about 430 nm, and is in the range of 450 nm to 670 nm. The wavelength band (including the wavelength band of the wavelength band of 450 nm to 650 nm) exhibits a transmittance of about 100% (average 90% or more), and the transmittance decreases sharply when the wavelength exceeds 670 nm, and the transmittance becomes 50% at a wavelength of about 680 nm. The transmittance at a wavelength of 700 nm is about 3%.

接著,如圖1所示,於紅外線吸收玻璃21之另一主面212,藉由黏接透明基板31之另一主面312,得到厚度0.85mm之相關於實施例2之紅外線截止濾鏡1。Next, as shown in FIG. 1, the other main surface 212 of the infrared absorbing glass 21 is bonded to the other main surface 312 of the transparent substrate 31 to obtain an infrared cut filter 1 according to the second embodiment having a thickness of 0.85 mm. .

相關於此實施例2的紅外線截止濾鏡1,具有組合紅外線吸收體2及紅外線反射體3的透光特性之圖4的L7所示的透光特性。總之,實施例2之紅外線截止濾鏡1,為除了超過700nm的波長的光以外,還截止380nm~420nm的波長帶域的光之構成,具有在380nm~420nm的波長帶域之透過率為平均10%以下,波長超過約430nm時透過率急遽上升,在450nm~550nm的波長帶域透過率為90%以上,在550nm~700nm之波長帶域透過率減少,在波長約650nm透過率成為50%,在波長700nm透過率成為約0%之透光特性。The infrared cut filter 1 according to the second embodiment has the light transmission characteristics shown by L7 of Fig. 4 in which the light transmitting characteristics of the infrared absorber 2 and the infrared reflector 3 are combined. In short, the infrared cut filter 1 of the second embodiment is configured to cut light of a wavelength band of 380 nm to 420 nm in addition to light having a wavelength exceeding 700 nm, and has an average transmittance in a wavelength band of 380 nm to 420 nm. 10% or less, when the wavelength exceeds about 430 nm, the transmittance increases sharply, the transmittance in the wavelength band of 450 nm to 550 nm is 90% or more, the transmittance in the wavelength band of 550 nm to 700 nm decreases, and the transmittance at a wavelength of about 650 nm becomes 50%. The transmittance at a wavelength of 700 nm is about 0%.

<實施例3><Example 3>

在本實施例3,作為紅外線吸收玻璃21,使用把銅離子等色素予以分散之藍色玻璃,厚度為0.45mm,大氣中之折射率N約為1.5之玻璃板。接著,於此紅外線吸收玻璃21之一主面211,依照大氣中之折射率N為1.6之Al2O3膜,大氣中之折射率N為2.0之ZrO2膜、大氣中之折射率N為1.4之MgF2膜的順序,藉由真空蒸鍍形成構成防反射膜22之各膜而得紅外線吸收體2。In the third embodiment, as the infrared absorbing glass 21, a glass plate having a blue glass in which a dye such as copper ions is dispersed, a thickness of 0.45 mm, and a refractive index N in the atmosphere of about 1.5 is used. Next, on one main surface 211 of the infrared absorbing glass 21, an Al 2 O 3 film having a refractive index N of 1.6 in the atmosphere, a ZrO 2 film having a refractive index N of 2.0 in the atmosphere, and a refractive index N in the atmosphere are In the order of the MgF 2 film of 1.4, the respective films constituting the anti-reflection film 22 were formed by vacuum evaporation to obtain the infrared absorber 2.

此紅外線吸收體2,具有圖5之L8所示的透光特性。又,在此實施例3,光線的入射角為0度,亦即使光線垂直入射。This infrared absorber 2 has a light transmitting property as shown by L8 in Fig. 5 . Further, in this embodiment 3, the incident angle of the light is 0 degrees, even if the light is incident perpendicularly.

總之,紅外線吸收玻璃21,具有在400nm~550nm的波長帶域之透過率為90%以上,在550nm~700nm之波長帶域之透過率減少,約在670nm之波長透過率成為50%,在700nm之波長透過率成為約34%之透光特性。In short, the infrared absorbing glass 21 has a transmittance in a wavelength band of 400 nm to 550 nm of 90% or more, a transmittance in a wavelength band of 550 nm to 700 nm, and a transmittance at a wavelength of about 670 nm of 50% at 700 nm. The wavelength transmittance is about 34% of the light transmission property.

作為紅外線反射體3之透明基板31,與實施例1同樣,使用大氣中之折射率N為1.5,厚度0.3mm之玻璃板。此外,與實施例1同樣,作為構成紅外線反射膜32的第1薄膜321,使用大氣中之折射率N為2.30之TiO2,作為第2薄膜322,使用大氣中之折射率N為1.46之SiO2,這些之中心波長為688nm。As the transparent substrate 31 of the infrared reflector 3, a glass plate having a refractive index N of 1.5 and a thickness of 0.3 mm in the atmosphere was used in the same manner as in the first embodiment. In the same manner as in the first embodiment, as the first film 321 constituting the infrared ray reflection film 32, TiO 2 having a refractive index N of 2.30 in the atmosphere is used, and as the second film 322, SiO having a refractive index N of 1.46 in the atmosphere is used. 2 , the center wavelength of these is 688nm.

這些各薄膜321、322分別之光學膜厚,與實施例1同樣,藉由使成為前述表1所示的值的方式之前述的40層所構成的紅外線反射膜32的製造方法,對於透明基板31之一主面311,形成各薄膜321、322,而得到紅外線反射體3。In the same manner as in the first embodiment, the optical film thickness of each of the films 321 and 322 is the same as that of the first embodiment, and the method for producing the infrared reflecting film 32 composed of the above-described 40 layers which is the value shown in Table 1 above is applied to the transparent substrate. One of the main faces 311 of 31 forms each of the films 321, 322, and an infrared reflector 3 is obtained.

此紅外線反射體3,具有圖5之L9所示的透光特性。如前所述,在本實施例3,與實施例1同樣得到紅外線反射體3,但由於製造誤差,本實施例3之紅外線反射體3(紅外線反射膜32),具有與實施例1之紅外線反射體3(紅外線反射膜32)之透光特性L2(參照圖3)稍有不同的透光特性L9。具體而言,本實施例3之紅外線反射體3(紅外線反射膜32)的透光特性L9,於400nm~440nm之波長帶域呈現90%以上之透過率,在450nm~650nm之波長帶域內(具體而言在490nm~540nm之波長帶域)呈現波紋(ripple)的產生,而於這樣的波紋產生的帶域呈現80%以上的透過率,在450nm~650nm之波長帶域呈現平均90%以上之透過率。此外,紅外線反射體3(紅外線反射膜32)之透光特性,在波長超過約670nm時透過率急遽減少,在波長約680nm呈現50%之透過率,在波長700nm呈現約5%之透過率。This infrared reflector 3 has a light transmitting property as shown by L9 in Fig. 5 . As described above, in the third embodiment, the infrared ray reflector 3 is obtained in the same manner as in the first embodiment. However, the infrared ray reflector 3 (infrared reflection film 32) of the third embodiment has the infrared ray of the first embodiment due to manufacturing errors. The light transmitting property L2 (see FIG. 3) of the reflector 3 (infrared reflecting film 32) has slightly different light transmitting characteristics L9. Specifically, the light transmission characteristic L9 of the infrared ray reflector 3 (infrared reflection film 32) of the third embodiment exhibits a transmittance of 90% or more in a wavelength band of 400 nm to 440 nm, and is in a wavelength band of 450 nm to 650 nm. (specifically, in the wavelength band of 490 nm to 540 nm), the generation of ripples occurs, and the band generated by such a corrugation exhibits a transmittance of 80% or more, and an average of 90% in the wavelength range of 450 nm to 650 nm. The above transmittance. Further, the light-transmitting property of the infrared reflector 3 (infrared reflecting film 32) is drastically reduced when the wavelength exceeds about 670 nm, exhibits a transmittance of 50% at a wavelength of about 680 nm, and exhibits a transmittance of about 5% at a wavelength of 700 nm.

接著,如圖1所示,於紅外線吸收玻璃21之另一主面212,藉由黏接透明基板31之另一主面312,得到厚度0.75mm之相關於實施例3之紅外線截止濾鏡1。Next, as shown in FIG. 1, the other main surface 212 of the infrared absorbing glass 21 is bonded to the other main surface 312 of the transparent substrate 31 to obtain an infrared cut filter 1 according to the third embodiment having a thickness of 0.75 mm. .

相關於此實施例3的紅外線截止濾鏡1,具有組合紅外線吸收體2及紅外線反射體3的透光特性之圖5的L10所示的透光特性。總之,實施例3之紅外線截止濾鏡1,具有在400nm~550nm的波長帶域之透過率平均為90%以上,在550nm~700nm之波長帶域之透過率減少,在約670nm之波長透過率成為50%,在700nm之波長透過率成為約0%之透光特性。The infrared cut filter 1 according to the third embodiment has the light transmission characteristics shown by L10 of Fig. 5 in which the light transmitting characteristics of the infrared absorber 2 and the infrared reflector 3 are combined. In short, the infrared cut filter 1 of the third embodiment has an average transmittance of 90% or more in the wavelength band of 400 nm to 550 nm, a decrease in transmittance in the wavelength band of 550 nm to 700 nm, and a transmittance at a wavelength of about 670 nm. It is 50%, and the transmittance at a wavelength of 700 nm is about 0%.

如在前述之實施例1~3之紅外線截止濾鏡1的透光特性L3、L7、L10(參照圖3~5)所示,在相關於本實施型態1的紅外線截止濾鏡1,可得藉由紅外線吸收體2及紅外線反射體3之組合,具有在450nm~550nm之波長帶域內的波長下透過率為90%以上,在620nm~670nm之波長帶域內的波長下透過率為50%,在700nm之波長下透過率為約0%(未滿5%)之透光性。總之,可以得到由可見光區域跨至紅外線區域,和緩地減少透過率,在700nm的波長下透過率成為約0%之接近於人眼的感度特性的透光特性。特別是,在相關於實施例2之紅外線截止濾鏡1,如前所述,在380nm~420nm之波長帶域的透過率,具體而言,在人眼無法見到的紫外線造成影響的波長帶域之透過率被抑制為平均10%以下,所以與相關於實施例1及3之紅外線截止濾鏡相比,可以得到更接近於人眼的感度特性之透光特性。As shown in the light-transmitting characteristics L3, L7, and L10 (see FIGS. 3 to 5) of the infrared cut filter 1 of the above-described first to third embodiments, the infrared cut filter 1 according to the first embodiment can be used. The combination of the infrared absorber 2 and the infrared reflector 3 has a transmittance of 90% or more at a wavelength in a wavelength range of 450 nm to 550 nm, and a transmittance at a wavelength in a wavelength range of 620 nm to 670 nm. 50%, the transmittance at a wavelength of 700 nm is about 0% (less than 5%). In short, it is possible to obtain a light transmission characteristic which is close to the infrared ray region from the visible light region and which gently reduces the transmittance, and whose transmittance is about 0% at a wavelength of 700 nm which is close to the sensitivity characteristic of the human eye. In particular, in the infrared cut filter 1 according to the second embodiment, as described above, the transmittance in the wavelength band of 380 nm to 420 nm, specifically, the wavelength band affected by ultraviolet rays which are invisible to the human eye. Since the transmittance of the domain is suppressed to an average of 10% or less, the light transmission characteristics closer to the sensitivity characteristics of the human eye can be obtained as compared with the infrared cut filters according to the first and third embodiments.

藉由與從前的紅外線截止濾鏡之透光特性L4比較,更具體地說明圖3~5所示之相關於實施例1~3的紅外線截止濾鏡1之透光特性L3、L7、L10。The light transmission characteristics L3, L7, and L10 of the infrared cut filter 1 according to the first to third embodiments shown in Figs. 3 to 5 are more specifically described by comparison with the light transmission characteristic L4 of the conventional infrared cut filter.

具有圖3~5之L4所示的透光特性之從前的紅外線截止濾鏡,係以在紅外線吸收玻璃的兩面形成防反射膜而成的紅外線吸收體所構成的。在此從前的紅外線截止濾鏡,紅外線吸收體之紅外線吸收玻璃的厚度為1.6mm,透過率成為約0%之點配合於700nm。The former infrared cut filter having the light transmission characteristics shown by L4 in FIGS. 3 to 5 is composed of an infrared absorber having an antireflection film formed on both surfaces of the infrared absorbing glass. In the conventional infrared cut filter, the infrared absorbing glass of the infrared absorbing body has a thickness of 1.6 mm, and the transmittance is about 0% at 700 nm.

對此,實施例1~3之紅外線截止濾鏡1,為具有L4的透光特性的從前的紅外線截止濾鏡(紅外線吸收體)的一半以下的厚度,且於可見光區域,特別是600nm~700nm之波長帶域,在比從前的紅外線截止濾鏡呈現更高的透過率之紅外線吸收體2,亦即具有L1、L5或L8所示的透光特性之紅外線吸收體2上,組合紅外線反射體3,而使透過率成為約0%之點配合於700nm。On the other hand, the infrared cut filter 1 of the first to third embodiments has a thickness of half or less of the former infrared cut filter (infrared absorber) having the light transmission property of L4, and is in the visible light region, particularly 600 nm to 700 nm. In the wavelength band, the infrared absorber 2 exhibiting a higher transmittance than the former infrared cut filter, that is, the infrared absorber 2 having the light transmitting characteristics indicated by L1, L5 or L8, combined with the infrared reflector 3, and the point at which the transmittance is about 0% is matched to 700 nm.

因此,相關於實施例1~3的紅外線截止濾鏡1之透光特性L3、L7、L10,在可見光區域,特別是在600nm~700nm之波長帶域,與從前的紅外線截止濾鏡之透光特性L4相比呈現高的透過率。此外,相關於實施例1~3的紅外線截止濾鏡1之透光特性L3、L7、L10,對700nm之波長的光線之透過率,與從前的紅外線截止濾鏡之透光特性L4相比,更為接近0%。Therefore, the light-transmitting characteristics L3, L7, and L10 of the infrared cut filter 1 according to the first to third embodiments are transmitted in the visible light region, particularly in the wavelength band of 600 nm to 700 nm, and the light transmittance of the former infrared cut filter. The characteristic L4 exhibits a high transmittance. Further, with respect to the light transmission characteristics L3, L7, and L10 of the infrared cut filter 1 of the first to third embodiments, the transmittance of light having a wavelength of 700 nm is compared with the light transmission characteristic L4 of the former infrared cut filter. More close to 0%.

具體而言,在從前之紅外線截止濾鏡的透光特性L4,在波長600nm之透過率為約55%,波長約605nm之透過率成為50%,波長約675nm之透過率成為7.5%,在波長700nm透過率成為約3%之透光特性。Specifically, in the light transmission characteristic L4 of the former infrared cut filter, the transmittance at a wavelength of 600 nm is about 55%, the transmittance at a wavelength of about 605 nm is 50%, and the transmittance at a wavelength of about 675 nm is 7.5% at a wavelength. The 700 nm transmittance is about 3% of light transmission.

對此,相關於實施例1之紅外線截止濾鏡1的透光特性L3(參照圖3),在波長600nm之透過率為約75%,波長約640nm之透過率成為50%,波長約675nm之透過率成為20%,在波長700nm透過率成為約0%。此外,相關於實施例2之紅外線截止濾鏡1的透光特性L7(參照圖4),在波長600nm之透過率為約80%,波長約650nm之透過率成為50%,波長約675nm之透過率成為30%,在波長700nm透過率成為約0%。進而,相關於實施例3之紅外線截止濾鏡1的透光特性L10(參照圖5),在波長600nm之透過率為約85%,波長約670nm之透過率成為50%,波長約675nm之透過率成為40%,在波長700nm透過率成為約0%。On the other hand, with respect to the light transmission characteristic L3 (see FIG. 3) of the infrared cut filter 1 of the first embodiment, the transmittance at a wavelength of 600 nm is about 75%, the transmittance at a wavelength of about 640 nm is 50%, and the wavelength is about 675 nm. The transmittance was 20%, and the transmittance at a wavelength of 700 nm was about 0%. Further, with respect to the light transmission characteristic L7 (see FIG. 4) of the infrared cut filter 1 of the second embodiment, the transmittance at a wavelength of 600 nm is about 80%, the transmittance at a wavelength of about 650 nm is 50%, and the transmittance at a wavelength of about 675 nm. The rate was 30%, and the transmittance at a wavelength of 700 nm was about 0%. Further, with respect to the light transmission characteristic L10 (see FIG. 5) of the infrared cut filter 1 of the third embodiment, the transmittance at a wavelength of 600 nm is about 85%, the transmittance at a wavelength of about 670 nm is 50%, and the transmittance at a wavelength of about 675 nm. The rate was 40%, and the transmittance at a wavelength of 700 nm was about 0%.

如此,相關於實施例1~3的紅外線截止濾鏡1之透光特性L3、L7、L10,與從前的紅外線截止濾鏡的透光特性L4相比,對600nm~700nm之波長帶域,特別是在600nm~675nm之波長帶域透過率很高,且在波長700nm成為透過率接近0%者。總之,相關於實施例1~3的紅外線截止濾鏡1,與從前的紅外線截止濾鏡相比,被承認是可以充分截止超過700nm的紅外線,且可充分透過波長600nm~700nm之紅色的可見光線者。因此,相關於實施例1~3之紅外線截止濾鏡1被搭載於攝影裝置的話,在攝影裝置5,可以拍攝與從前相比,紅色成分較強的影像,可以明亮地拍攝暗處的影像。As described above, the light-transmitting characteristics L3, L7, and L10 of the infrared cut filter 1 according to the first to third embodiments are different from the light-transmitting characteristic L4 of the prior infrared cut filter for the wavelength band of 600 nm to 700 nm. The transmittance in the wavelength band of 600 nm to 675 nm is very high, and the transmittance is close to 0% at a wavelength of 700 nm. In short, the infrared cut filter 1 according to the first to third embodiments is recognized as being capable of sufficiently blocking infrared rays exceeding 700 nm and sufficiently transmitting red visible light having a wavelength of 600 nm to 700 nm as compared with the conventional infrared cut filter. By. Therefore, when the infrared cut filter 1 according to the first to third embodiments is mounted on the photographing device, the photographing device 5 can capture an image having a stronger red component than before, and can image the dark portion brightly.

此外,在相關於本實施型態1之紅外線截止濾鏡1,藉由於紅外線反射體3組合紅外線吸收體2,抑制了藉由紅外線反射體2反射的光之量。具體而言,於實施例1之紅外線截止濾鏡1,紅外線反射體3的半值波長,如圖3所示為約680nm,比紅外線吸收體2之半值波長(約640nm)更長。此外,於實施例2之紅外線截止濾鏡1,紅外線反射體3的半值波長,如圖4所示為約680nm,比紅外線吸收體2之半值波長(約650nm)更長。進而,於實施例3之紅外線截止濾鏡1,紅外線反射體3的半值波長,如圖5所示為約680nm,比紅外線吸收體2之半值波長(約670nm)更長。如此,於相關於實施例1~3之紅外線截止濾鏡1,紅外線反射體3之半值波長(透過率成為50%之波長),比紅外線吸收體2之半值波長更長,紅外線吸收體2之呈現透光特性L1、L5、L8的透過率曲線,與紅外線反射體3之呈現透光特性L2、L6、L9的透過曲線交叉的交叉點P之波長(紅外線吸收體2的透過率與紅外線反射體3的透過率成為相同的波長),比紅外線吸收體2的半值波長更長。此外,前述交叉點P的波長之紅外線吸收體2及紅外線反射體3之透過率為50%以下。因此,在相關於實施例1~3的紅外線截止濾鏡1,藉由在紅外線吸收體2之紅外線的吸收,抑制由紅外線反射體3反射的光之量,抑制紅外線反射體2之光反射導致之眩光及鬼影的發生。Further, in the infrared cut filter 1 according to the first embodiment, the infrared reflector 3 is combined with the infrared absorber 2, and the amount of light reflected by the infrared reflector 2 is suppressed. Specifically, in the infrared cut filter 1 of the first embodiment, the half value wavelength of the infrared reflector 3 is about 680 nm as shown in FIG. 3 and longer than the half value wavelength (about 640 nm) of the infrared absorber 2. Further, in the infrared cut filter 1 of the second embodiment, the half value wavelength of the infrared reflector 3 is about 680 nm as shown in FIG. 4 and longer than the half value wavelength (about 650 nm) of the infrared absorber 2. Further, in the infrared cut filter 1 of the third embodiment, the half value wavelength of the infrared reflector 3 is about 680 nm as shown in FIG. 5 and longer than the half value wavelength (about 670 nm) of the infrared absorber 2. Thus, in the infrared cut filter 1 according to the first to third embodiments, the half-value wavelength of the infrared reflector 3 (the wavelength at which the transmittance is 50%) is longer than the half-value wavelength of the infrared absorber 2, and the infrared absorber The transmittance curve of the light-transmitting characteristics L1, L5, and L8 of 2, and the wavelength of the intersection P of the infrared light-reflecting body 3 which exhibits the transmission curves of the light-transmitting characteristics L2, L6, and L9 (the transmittance of the infrared absorber 2 and The transmittance of the infrared reflector 3 is the same wavelength), and is longer than the half-value wavelength of the infrared absorber 2. Further, the transmittance of the infrared absorber 2 and the infrared reflector 3 at the wavelength of the intersection P is 50% or less. Therefore, in the infrared cut filter 1 according to the first to third embodiments, the amount of light reflected by the infrared ray reflector 3 is suppressed by the absorption of the infrared ray in the infrared ray absorbing body 2, and the light reflection of the infrared ray reflector 2 is suppressed. The occurrence of glare and ghosting.

此外,在相關於本實施型態1之實施例1~3的紅外線截止濾鏡1,紅外線反射體3的半值波長比紅外線吸收體2的半值波長更長,組合紅外線吸收體2與紅外線反射體3之紅外線截止濾鏡1的半值波長,以幾乎一致於紅外線吸收體2的半值波長的方式被構成。總之,藉由與紅外線反射體3相比設計誤差導致的透過率的差異很少的紅外線吸收體2,使紅外線截止濾鏡1的半值波長被設定的構成,所以於該紅外線截止濾鏡1的製造,可以減低製造時之設計誤差導致紅外線截止濾鏡之透光特性的差異。Further, in the infrared cut filter 1 according to the first to third embodiments of the first embodiment, the half value wavelength of the infrared reflector 3 is longer than the half value wavelength of the infrared absorber 2, and the infrared absorber 2 and the infrared rays are combined. The half-value wavelength of the infrared cut filter 1 of the reflector 3 is configured to be almost uniform to the half-value wavelength of the infrared absorber 2. In short, the infrared absorber 2 having a small difference in transmittance due to a design error compared with the infrared reflector 3 has a half-value wavelength of the infrared cut filter 1 set. Therefore, the infrared cut filter 1 is used. The manufacturing can reduce the difference in light transmission characteristics of the infrared cut filter caused by design errors during manufacturing.

此外,相關於本實施型態1之實施例1~3之紅外線截止濾鏡1,紅外線反射體3,具有在450nm~650nm的波長帶域內之各波長呈現80%以上之透過率,在450nm~650nm的波長帶域之透過率的平均在90%以上之透光特性。因此,紅外線截止濾鏡1,可在450nm~650nm的波長帶域得到依存於紅外線吸收體2的透光特性之透光特性,所以跨可見光區域至紅外線區域,透過率和緩地減少,在700nm的波長可得到透過率約為0%之接近於人眼的感度特性的透光特性,而且在可見光區域,特別是在紅色的可見光線的波長帶域(600nm~700nm)可得到高的透過率。Further, in the infrared cut filter 1 according to the first to third embodiments of the first embodiment, the infrared reflector 3 has a transmittance of 80% or more at each wavelength in the wavelength range of 450 nm to 650 nm, at 450 nm. The transmittance of the wavelength band of -650 nm is an average of 90% or more of light transmission characteristics. Therefore, the infrared cut filter 1 can obtain a light transmitting property depending on the light transmitting property of the infrared absorbing body 2 in a wavelength band of 450 nm to 650 nm, so that the transmittance is gradually reduced across the visible light region to the infrared ray region at 700 nm. The wavelength can obtain a light transmission characteristic having a transmittance of about 0% which is close to the sensitivity characteristic of the human eye, and a high transmittance can be obtained in the visible light region, particularly in the wavelength band of the red visible light (600 nm to 700 nm).

此外,以紅外線截止濾鏡1的半值波長與紅外線吸收體2的半值波長幾乎一致的方式,紅外線反射體3,對紅外線吸收體2的半值波長的光線呈現90%以上的透過率的方式構成,所以紅外線吸收體在波長550nm~700nm徐徐減少透過率之接近於人眼的感度特性的透光特性,具備於紅外線截止濾鏡1,可得到接近於人眼的感度特性的透光特性。Further, the infrared reflector 3 exhibits a transmittance of 90% or more for the half-value wavelength of the infrared absorber 2 such that the half-value wavelength of the infrared cut filter 1 almost coincides with the half-value wavelength of the infrared absorber 2. According to the configuration of the infrared absorber, the light-transmitting property of the infrared absorbing material which is close to the sensitivity characteristic of the human eye is gradually reduced at a wavelength of 550 nm to 700 nm, and is provided in the infrared cut filter 1 to obtain a light transmitting property close to the sensitivity characteristic of the human eye. .

進而,於相關於實施型態1的實施例1~3的紅外線截止濾鏡1,紅外線吸收體2,能夠以比具有L4所示的透光特性之從前的紅外線截止濾鏡更薄的厚度來構成。因此,可以使紅外線截止濾鏡1的厚度,構成為與從前的紅外線截止濾鏡相同厚度,或者比從前的紅外線截止濾鏡更薄。Further, in the infrared cut filter 1 according to the first to third embodiments of the first embodiment, the infrared absorber 2 can be made thinner than the former infrared cut filter having the light transmission characteristics indicated by L4. Composition. Therefore, the thickness of the infrared cut filter 1 can be made the same thickness as the former infrared cut filter or thinner than the former infrared cut filter.

<實施型態2><implementation type 2>

相關於本實施型態2之紅外線截止濾鏡1A,如圖6所示,於攝影裝置,係被配置於沿著攝影光徑的光軸配置的成像光學系統4與攝影裝置5之間。 In the infrared cut filter 1A according to the second embodiment, as shown in FIG. 6, the photographing device is disposed between the imaging optical system 4 disposed along the optical axis of the photographing optical path and the photographing device 5.

相關於本實施型態2的紅外線截止濾鏡1A,如圖6所示,由吸收紅外線的紅外線吸收體2A,與反射紅外線的紅外線反射體3A所構成。 The infrared cut filter 1A according to the second embodiment of the present invention is composed of an infrared absorber 2A that absorbs infrared rays and an infrared reflector 3A that reflects infrared rays, as shown in Fig. 6 .

於攝影裝置,紅外線吸收體2A與紅外線反射體3A,在沿著攝影光徑的光軸排列的成像光學系統4與攝影裝置5之間,係隔開配置的。又,紅外線吸收體2A,被配置於靠近成像光學系統4之側。 In the imaging device, the infrared ray absorbing body 2A and the infrared ray reflector 3A are disposed apart from each other between the imaging optical system 4 and the imaging device 5 which are arranged along the optical axis of the imaging optical path. Moreover, the infrared absorber 2A is disposed on the side close to the imaging optical system 4.

此紅外線吸收體2A,係在紅外線吸收玻璃21之兩主面211、212形成防反射膜22。 The infrared absorber 2A forms an anti-reflection film 22 on the two main faces 211 and 212 of the infrared absorbing glass 21.

作為紅外線吸收玻璃21,與實施型態1所示的紅外線吸收體2之紅外線吸收玻璃21同樣,使用把銅離子等色素予以分散之藍色玻璃,例如厚度為0.2mm~1.2mm之方形薄板狀的玻璃。 As the infrared absorbing glass 21, similar to the infrared absorbing glass 21 of the infrared absorbing body 2 shown in the first embodiment, a blue glass in which a dye such as copper ions is dispersed is used, for example, a square thin plate having a thickness of 0.2 mm to 1.2 mm. Glass.

此外,防反射膜22,係對紅外線吸收玻璃21之兩主面211、212,藉由習知的真空蒸鍍裝置(省略圖示)進行真空蒸鍍MgF2所構成的單層、Al2O2與ZrO2與MgF2所構成的多層膜、TiO2與SiO2所構成的多層膜之任一膜而形成的。又,防反射膜22,係藉由監視膜厚同時進行蒸鍍動作,在達到特定的膜厚時關閉設於蒸鍍源(省略圖示)附近的遮板(省略圖示)停止蒸鍍物質的蒸鍍而進行的。這樣的防反射膜22,係以大氣中之折射率N,比大氣的折射率(約1.0)更大,而且比紅外線吸收玻璃21的折射率更小的方 式被形成的。 Further, the anti-reflection film 22 is a single layer or Al 2 O formed by vacuum-depositing MgF 2 by a conventional vacuum vapor deposition apparatus (not shown) on the two main surfaces 211 and 212 of the infrared absorbing glass 21. 2 is formed by any one of a multilayer film composed of ZrO 2 and MgF 2 and a multilayer film composed of TiO 2 and SiO 2 . In addition, the anti-reflection film 22 performs a vapor deposition operation while monitoring the film thickness, and when a specific film thickness is reached, the shutter (not shown) provided in the vicinity of the vapor deposition source (not shown) is closed to stop the vapor deposition material. The evaporation is carried out. Such an anti-reflection film 22 is formed such that the refractive index N in the atmosphere is larger than the refractive index of the atmosphere (about 1.0) and smaller than the refractive index of the infrared absorbing glass 21.

這樣的紅外線吸收體2A,使用與實施型態1同樣的紅外線吸收玻璃21而構成,所以具有與實施型態1的紅外線吸收體2同樣的透光特性。總之,具有在620nm~670nm的波長帶域內之波長的透過率為50%,在700nm的波長之透過率成為10%~40%的透光特性。又,於這樣的紅外線吸收體2的透光特性,透過率在400nm~550nm之波長帶域內的波長成為90%以上之最大值。 Since the infrared absorber 2A is configured using the infrared absorbing glass 21 similar to that of the first embodiment, it has the same light transmission characteristics as the infrared absorbing body 2 of the first embodiment. In short, the transmittance at a wavelength in the wavelength band of 620 nm to 670 nm is 50%, and the transmittance at a wavelength of 700 nm is 10% to 40%. Moreover, in the light transmission characteristics of the infrared absorber 2, the wavelength in the wavelength range of 400 nm to 550 nm is 90% or more.

此外,紅外線反射體3A,於透明基鈑31之一主面311被形成紅外線反射膜32,於另一主面312被形成防反射膜33。此紅外線反射體3A,於攝影裝置,如圖6所示,以紅外線反射膜32側之面與攝影裝置5對向的方式被配置。 Further, the infrared reflector 3A is formed with an infrared reflection film 32 on one main surface 311 of the transparent substrate 31, and an anti-reflection film 33 is formed on the other main surface 312. The infrared ray reflector 3A is disposed on the imaging device as shown in FIG. 6 so that the surface on the side of the infrared ray reflection film 32 faces the imaging device 5.

作為透明基板31,使用與在實施型態1所示的透明基板31同樣的透過可見光及紅外線的無色透明玻璃,例如厚度為0.2mm~1.0mm之方形薄板狀的玻璃。 As the transparent substrate 31, a colorless transparent glass that transmits visible light and infrared light similarly to the transparent substrate 31 shown in Embodiment 1 is used, and for example, a square thin plate glass having a thickness of 0.2 mm to 1.0 mm is used.

紅外線反射膜32,使用與實施型態1所示的紅外線反射膜32同樣的高折射率材料構成的第1薄膜321,與低折射率材料構成的第2薄膜322交互被層積複數而成之多層膜。 The infrared ray reflection film 32 is formed by laminating a plurality of first films 321 made of a high refractive index material similar to the infrared ray reflection film 32 shown in Embodiment 1 and a second film 322 made of a low refractive index material. Multilayer film.

這樣的紅外線反射體3A,係與實施型態1同樣的紅外線反射膜32被形成於透明基板31,所以具有與實施型態1的紅外線反射體3同樣的透光特性。總之,紅外線反射體3A,具有在450nm~650nm的波長帶域內之各波長呈現80%以上的透過率,在此450nm~650nm波長帶域呈現平均90%以上的透過率,在670nm~690nm之波長帶域內的波長之 透過率成為50%,在700nm的波長之透過率成為不滿15%的透光特性。此外,此紅外線反射體3A呈現50%之透過率的波長,比紅外線吸收體2呈現50%之透過率的波長更長。 Since the infrared reflecting body 3A of the above-described embodiment 1 is formed on the transparent substrate 31, the infrared reflecting film 32 similar to that of the first embodiment has the same light transmitting characteristics as the infrared reflecting body 3 of the first embodiment. In short, the infrared reflector 3A has a transmittance of 80% or more at each wavelength in the wavelength range of 450 nm to 650 nm, and an average transmittance of 90% or more in the wavelength range of 450 nm to 650 nm, and is in the range of 670 nm to 690 nm. Wavelength in the wavelength band The transmittance was 50%, and the transmittance at a wavelength of 700 nm became a light transmission characteristic of less than 15%. Further, the infrared ray reflector 3A exhibits a wavelength of 50% transmittance, which is longer than a wavelength at which the infrared absorbing body 2 exhibits a transmittance of 50%.

防反射膜33,係對透明基板31之另一主面312,藉由習知的真空蒸鍍裝置(省略圖示)進行真空蒸鍍MgF2所構成的單層、Al2O2與ZrO2與MgF2所構成的多層膜、TiO2與SiO2所構成的多層膜之任一膜而形成的。又,防反射膜22,係藉由監視膜厚同時進行蒸鍍動作,在達到特定的膜厚時關閉設於蒸鍍源(省略圖示)附近的遮板(省略圖示)停止蒸鍍物質的蒸鍍而進行的。這樣的防反射膜33,係以大氣中之折射率N,比大氣的折射率(約1.0)更大,而且比透明基板31的折射率更小的方式被形成的。 The anti-reflection film 33 is a single layer, Al 2 O 2 and ZrO 2 which are vacuum-deposited with MgF 2 by a conventional vacuum vapor deposition apparatus (not shown) on the other main surface 312 of the transparent substrate 31. It is formed by any one of a multilayer film composed of MgF 2 and a multilayer film composed of TiO 2 and SiO 2 . In addition, the anti-reflection film 22 performs a vapor deposition operation while monitoring the film thickness, and when a specific film thickness is reached, the shutter (not shown) provided in the vicinity of the vapor deposition source (not shown) is closed to stop the vapor deposition material. The evaporation is carried out. Such an anti-reflection film 33 is formed such that the refractive index N in the atmosphere is larger than the refractive index of the atmosphere (about 1.0) and is smaller than the refractive index of the transparent substrate 31.

此外,這樣的紅外線吸收體2A的厚度與紅外線反射體3A的厚度的合計,例如為0.4~1.6mm。總之,構成紅外線吸收體2的紅外線吸收體玻璃21的厚度,及構成紅外線反射體3的透明基板31的厚度,為紅外線吸收體2與紅外線反射體3的厚度之合計,例如成為0.4mm~1.6mm的方式適當調整。 Further, the total thickness of the infrared absorber 2A and the thickness of the infrared reflector 3A is, for example, 0.4 to 1.6 mm. In short, the thickness of the infrared absorber glass 21 constituting the infrared absorber 2 and the thickness of the transparent substrate 31 constituting the infrared reflector 3 are the total thickness of the infrared absorber 2 and the infrared reflector 3, and are, for example, 0.4 mm to 1.6. The mode of mm is adjusted as appropriate.

接著,在紅外線截止濾鏡1A,藉由前述之紅外線吸收體2A及紅外線反射體3A的透光特性的組合,可得與相關於實施型態1的紅外線截止濾鏡1同樣的透光特性。亦即,可得在450nm~550nm波長帶域內的透過率為90%以上,在620nm~670nm之波長帶域內的波長之透過率成為50%,在700nm的波長之透過率成為不滿5%的透光特性。 Next, in the infrared cut filter 1A, by the combination of the light transmitting characteristics of the infrared absorber 2A and the infrared reflector 3A described above, the light transmission characteristics similar to those of the infrared cut filter 1 of the first embodiment can be obtained. That is, the transmittance in the wavelength range of 450 nm to 550 nm is 90% or more, the transmittance in the wavelength range of 620 nm to 670 nm is 50%, and the transmittance at the wavelength of 700 nm becomes less than 5%. Light transmission characteristics.

這樣,在相關於實施型態2的紅外線截止濾鏡1A,可得到與相關於實施型態1的紅外線截止濾鏡1同樣的透光特性,所以可發揮與相關於實施型態1的紅外線截止濾鏡1同樣的效果。 As described above, in the infrared cut filter 1A according to the embodiment 2, the same light transmission characteristics as those of the infrared cut filter 1 according to the first embodiment can be obtained, so that the infrared cutoff associated with the embodiment 1 can be exhibited. Filter 1 has the same effect.

又,在前述之實施型態1及2,作為透明基板31使用玻璃板,但不以此為限,只要是可以透過光線的基板即可,例如亦可為水晶板。此外,透明基板31亦可為複折射板,亦可為複數枚所構成的複折射板。此外,組合水晶板與玻璃板構成透明基板31亦可。 Further, in the above-described embodiments 1 and 2, a glass plate is used as the transparent substrate 31. However, it is not limited thereto, and may be a substrate that can transmit light, and may be, for example, a crystal plate. Further, the transparent substrate 31 may be a birefringent plate or a multi-refractive plate formed of a plurality of sheets. Further, the crystal plate and the glass plate may be combined to form the transparent substrate 31.

此外,在實施型態1及2,於第1薄膜321使用TiO2,但不以此為限,第1薄膜321只要由高折射率材料構成即可,例如使用ZrO2、TaO2、Nb2O2等亦可。此外,於第2薄膜322使用SiO2,但不以此為限,第2薄膜322只要由低折射率材料構成即可,例如使用MgF2等亦可。 Further, in Embodiments 1 and 2, TiO 2 is used for the first film 321, but the first film 321 is not limited thereto, and may be composed of a high refractive index material, for example, ZrO 2 , TaO 2 , and Nb 2 . O 2 and so on. In addition, SiO 2 is used for the second film 322. However, the second film 322 may be formed of a low refractive index material, for example, MgF 2 or the like may be used.

此外,實施型態1及2之紅外線截止濾鏡1、1A,於攝影裝置,紅外線吸收體2、2A係以位於靠成像光學系統4之側的方式配置,但不以此為限。亦即,紅外線截止濾鏡1、1A,以紅外線反射體3、3A位於靠近成像光學系統4之側的方式配置亦可。 Further, the infrared cut filters 1 and 1A of the first and second embodiments are disposed in the imaging device, and the infrared absorbers 2 and 2A are disposed on the side of the imaging optical system 4, but are not limited thereto. In other words, the infrared cut filters 1 and 1A may be disposed such that the infrared reflectors 3 and 3A are located closer to the side of the imaging optical system 4.

例如,於攝影裝置,使紅外線截止濾鏡1、1A,以紅外線吸收體2、2A位於成像光學系統4之側的方式配置的場合,藉由紅外線反射體3、3A反射的光可以藉紅外線吸收體2、2A吸收,所以與紅外線反射體3、3A位於成像光學系統4之側的方式配置的場合相比,可以減低藉由紅外線反射體3、3A反射而散射於成像光學系統4的光之量,可以抑制鬼影的發生。另一方面,使紅外線截止濾鏡1、1A,以紅外線反射體3、3A位於成像光學系統4之側的方式配置的場合,與紅外線吸收體2、2A位於成像光學系統4之側的方式配置的場合相比,紅外線反射體3、3A與攝影裝置5的距離,具體而言,在製造過程發生於紅外線反射體3、3A內的異物與攝影裝置5之距離會遠離,所以可抑制異物導致之影像的劣化。For example, in the imaging device, when the infrared ray blocking filters 1 and 2A are disposed such that the infrared absorbing bodies 2 and 2A are located on the side of the imaging optical system 4, the light reflected by the infrared ray reflectors 3 and 3A can be absorbed by infrared rays. Since the bodies 2 and 2A are absorbed, the light scattered by the infrared reflectors 3 and 3A and scattered by the imaging optical system 4 can be reduced as compared with the case where the infrared reflectors 3 and 3A are disposed on the side of the imaging optical system 4. The amount can suppress the occurrence of ghosts. On the other hand, when the infrared ray cut filters 1 and 3A are disposed such that the infrared ray reflectors 3 and 3A are located on the side of the imaging optical system 4, the infrared ray absorbing bodies 2 and 2A are disposed on the side of the imaging optical system 4. In contrast, the distance between the infrared reflectors 3 and 3A and the imaging device 5 is, in particular, the distance between the foreign matter generated in the infrared reflectors 3 and 3A during the manufacturing process and the imaging device 5 is distant, so that foreign matter can be suppressed. Degradation of the image.

此外,在實施型態1及2,作為紅外線吸收體2、2A,使用於紅外線吸收玻璃21之一主面211或者兩主面211、212形成防反射膜22者,但本發明之紅外線吸收體2、2A並不以此為限。例如,在紅外線吸收玻璃21之大氣中的折射率,與大氣的折射率幾乎相同的場合,亦可不形成防反射膜22。總之,把未被形成防反射膜的紅外線吸收玻璃作為紅外線吸收體使用亦可。Further, in the first and second embodiments, the infrared absorbing members 2 and 2A are used as the main surface 211 of the infrared absorbing glass 21 or the two main surfaces 211 and 212 to form the antireflection film 22, but the infrared absorbing body of the present invention is used. 2, 2A is not limited to this. For example, when the refractive index in the atmosphere of the infrared absorbing glass 21 is almost the same as the refractive index of the atmosphere, the antireflection film 22 may not be formed. In short, the infrared absorbing glass which is not formed with the antireflection film may be used as an infrared absorbing body.

此外,在實施型態1,作為紅外線反射體3,使用在被黏接於紅外線吸收玻璃21的另一主面212的透明基板31之一主面311上形成紅外線反射膜32者,在實施型態2,作為紅外線反射體3A,使用在透明基板31之一主面311形成紅外線反射膜32,於另一主面312形成防反射膜33者,但本發明之紅外線反射體3、3A不以此為限。例如,把被形成於紅外線吸收玻璃的表面之紅外線反射膜作為紅外線反射體亦可。Further, in the first embodiment, the infrared reflecting body 3 is used as the infrared reflecting body 3, and the infrared reflecting film 32 is formed on one main surface 311 of the transparent substrate 31 bonded to the other main surface 212 of the infrared absorbing glass 21. In the second embodiment, as the infrared reflector 3A, the infrared reflecting film 32 is formed on one main surface 311 of the transparent substrate 31, and the antireflection film 33 is formed on the other main surface 312. However, the infrared reflecting body 3, 3A of the present invention does not This is limited. For example, an infrared reflecting film formed on the surface of the infrared absorbing glass may be used as an infrared reflecting body.

總之,在實施型態1,在被黏接於紅外線吸收玻璃21的另一主面212的透明基板31之一主面311形成紅外線反射膜32,但在紅外線吸收玻璃21之另一主面212直接形成作為紅外線吸收體之紅外線反射膜32亦可。作為具體例,亦可於紅外線吸收玻璃21之另一主面212,藉由交互真空蒸鍍TiO2與SiO2,而把作為紅外線吸收體之紅外線反射膜32形成於紅外線吸收玻璃21之另一主面212。如此於紅外線吸收玻璃21之另一主面212直接形成紅外線反射膜32的話,可以使紅外線截止濾鏡1薄型化。In short, in the first embodiment, the infrared reflecting film 32 is formed on one main surface 311 of the transparent substrate 31 adhered to the other main surface 212 of the infrared absorbing glass 21, but the other main surface 212 of the infrared absorbing glass 21 is provided. The infrared reflection film 32 which is an infrared absorber can also be formed directly. As a specific example, the other main surface 212 of the infrared absorbing glass 21 may be formed by alternately vacuum-depositing TiO 2 and SiO 2 to form an infrared ray reflecting film 32 as an infrared absorbing body in the infrared absorbing glass 21. Main face 212. When the infrared reflecting film 32 is directly formed on the other main surface 212 of the infrared absorbing glass 21, the infrared cut filter 1 can be made thinner.

此外,在實施型態2,係於透明基板31之另一主面312形成防反射膜33,但是透明基板31在大氣中的折射率,與大氣的折射率幾乎相同的場合,亦可不形成防反射膜33。Further, in the second embodiment, the anti-reflection film 33 is formed on the other main surface 312 of the transparent substrate 31. However, when the refractive index of the transparent substrate 31 in the atmosphere is almost the same as the refractive index of the atmosphere, the anti-reflection film may not be formed. Reflective film 33.

又,本發明在不逸脫其精神或主要特徵的前提下,可以其他種種變形型態來實施。因此,前述實施例從各種觀點來看僅係例示而已,非供限定解釋本發明。本發明之範圍如申請專利範圍所示,不受說明書文本的各種拘束。進而,屬於申請專利範圍的均等範圍之變形或是變更,均屬於本發明之範圍。Further, the present invention can be implemented in various other modified forms without departing from the spirit or main features. The foregoing embodiments are, therefore, to be considered in a The scope of the present invention is shown by the scope of the claims, and is not limited by the text of the specification. Further, variations or modifications of the equivalent scope of the claims are intended to be within the scope of the invention.

此外,本申請,係根據2010年6月18日於日本提出申請之特願2010-139686號申請案主張優先權。藉由於此提及,將其所有內容包含於本申請案。In addition, the present application claims priority from Japanese Patent Application No. 2010-139686, filed on Jan. As a result of this reference, all of its contents are included in this application.

[產業上利用可能性][Industry use possibility]

本發明可以適用於透過可見範圍的光線,且濾掉紅外線的紅外線截止(IR-cut)濾鏡。The present invention can be applied to an infrared cut-off (IR-cut) filter that transmits light in a visible range and filters out infrared rays.

1,1A...紅外線截止濾鏡1,1A. . . Infrared cut filter

2,2A...紅外線吸收體2,2A. . . Infrared absorber

21...紅外線吸收玻璃twenty one. . . Infrared absorption glass

211,212...主面211,212. . . Main face

22...防反射膜twenty two. . . Anti-reflection film

3,3A...紅外線反射體3,3A. . . Infrared reflector

31...透明基板31. . . Transparent substrate

311,312...主面311,312. . . Main face

32...紅外線反射膜32. . . Infrared reflective film

321...第1薄膜321. . . First film

322...第2薄膜322. . . Second film

33...防反射膜33. . . Anti-reflection film

4...成像光學系統4. . . Imaging optical system

5...攝影裝置5. . . Photography device

圖1係顯示使用相關於實施型態1之紅外線截止濾鏡而成的攝影裝置之概略構成之概略模式圖。Fig. 1 is a schematic view showing a schematic configuration of an image pickup apparatus using an infrared cut filter according to an embodiment 1.

圖2係顯示相關於實施型態1之紅外線截止濾鏡的紅外線反射體的概略構成之部分擴大圖。Fig. 2 is a partially enlarged view showing a schematic configuration of an infrared reflector relating to the infrared cut filter of the first embodiment.

圖3係顯示相關於實施型態1的實施例1之紅外線截止濾鏡的透光特性之圖。Fig. 3 is a view showing the light transmission characteristics of the infrared cut filter of Example 1 relating to Embodiment 1.

圖4係顯示相關於實施型態1的實施例2之紅外線截止濾鏡的透光特性之圖。Fig. 4 is a view showing the light transmission characteristics of the infrared cut filter of Example 2 relating to Embodiment 1.

圖5係顯示相關於實施型態1的實施例3之紅外線截止濾鏡的透光特性之圖。Fig. 5 is a view showing the light transmission characteristics of the infrared cut filter of Example 3 relating to Embodiment 1.

圖6係顯示使用相關於實施型態2之紅外線截止濾鏡而成的攝影裝置之概略構成之概略模式圖。Fig. 6 is a schematic view showing a schematic configuration of an image pickup apparatus using an infrared cut filter according to the embodiment 2.

圖7係顯示紅外線吸收玻璃的透光特性之圖。Fig. 7 is a view showing the light transmission characteristics of the infrared absorbing glass.

圖8係顯示紅外線截止鍍層的透光特性之圖。Fig. 8 is a view showing the light transmission characteristics of the infrared cut coating.

1...紅外線截止濾鏡1. . . Infrared cut filter

2...紅外線吸收體2. . . Infrared absorber

21...紅外線吸收玻璃twenty one. . . Infrared absorption glass

211,212...主面211,212. . . Main face

22...防反射膜twenty two. . . Anti-reflection film

3...紅外線反射體3. . . Infrared reflector

31...透明基板31. . . Transparent substrate

311,312...主面311,312. . . Main face

32...紅外線反射膜32. . . Infrared reflective film

4...成像光學系統4. . . Imaging optical system

5...攝影裝置5. . . Photography device

Claims (5)

一種紅外線截止濾鏡,係截止紅外線之紅外線截止濾鏡,其特徵為具備:吸收紅外線之紅外線吸收體,及反射紅外線的紅外線反射體;前述紅外線吸收體,具有620nm~670nm的波長帶域內的波長之透過率為50%之透光特性;前述紅外線反射體,具有670nm~690nm的波長帶域內的波長之透過率為50%之透光特性;前述紅外線反射體呈現50%的透過率之波長,比前述紅外線吸收體呈現50%的透過率的波長更長;藉由前述紅外線吸收體與前述紅外線反射體之組合,具有620nm~670nm之波長帶域內的波長的透過率為50%,675nm之波長的透過率為20~40%,700nm之波長的透過率為不滿5%之透光特性。 An infrared cut-off filter is an infrared cut-off filter that cuts off infrared rays, and is characterized in that: an infrared absorber that absorbs infrared rays and an infrared reflector that reflects infrared rays; and the infrared absorber has a wavelength band of 620 nm to 670 nm. The transmittance of the wavelength is 50% of the light transmission property; the infrared reflector has a light transmittance of 50% in a wavelength band of 670 nm to 690 nm; and the infrared reflector exhibits a transmittance of 50%. The wavelength is longer than a wavelength at which the infrared ray absorbing body exhibits a transmittance of 50%; and the combination of the infrared ray absorbing body and the infrared ray reflector has a transmittance of 50% in a wavelength band of 620 nm to 670 nm, The transmittance at a wavelength of 675 nm is 20 to 40%, and the transmittance at a wavelength of 700 nm is less than 5%. 如申請專利範圍第1項之紅外線截止濾鏡,其中前述紅外線吸收體,具有700nm的波長之透過率成為10%~40%的透光特性,前述紅外線反射體,具有700nm的波長之透過率成為不滿15%的透光特性。 The infrared cut filter according to claim 1, wherein the infrared absorber has a light transmittance of 10% to 40% at a wavelength of 700 nm, and the infrared reflector has a transmittance of 700 nm. Less than 15% light transmission characteristics. 如申請專利範圍第1或2項之紅外線截止濾鏡,其中前述紅外線反射體,具有在450nm~650nm的波長帶域內之各波長呈現80%以上之透過率,在450nm~650nm的 波長帶域之透過率的平均在90%以上之透光特性。 The infrared cut filter according to claim 1 or 2, wherein the infrared reflector has a transmittance of 80% or more at each wavelength in a wavelength range of 450 nm to 650 nm, and is in a range of 450 nm to 650 nm. The transmittance of the wavelength band averages over 90% of the light transmission characteristics. 如申請專利範圍第1或2項之紅外線截止濾鏡,其中於一前述紅外線吸收體之一主面,設有一前述紅外線反射體。 An infrared cut filter according to claim 1 or 2, wherein one of the infrared radiation absorbers is provided on one main surface of the infrared absorber. 一種攝影裝置,其特徵為包含申請專利範圍第1或2項之紅外線截止濾鏡。 A photographic apparatus characterized by comprising an infrared cut filter of claim 1 or 2.
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