TWI521773B - 以矽爲基底的多孔性陽極活性材料、彼之製法、及含該陽極活性材料之鋰二次電池 - Google Patents
以矽爲基底的多孔性陽極活性材料、彼之製法、及含該陽極活性材料之鋰二次電池 Download PDFInfo
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- TWI521773B TWI521773B TW103118615A TW103118615A TWI521773B TW I521773 B TWI521773 B TW I521773B TW 103118615 A TW103118615 A TW 103118615A TW 103118615 A TW103118615 A TW 103118615A TW I521773 B TWI521773 B TW I521773B
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- Prior art keywords
- active material
- anode active
- ruthenium
- solution
- porous anode
- Prior art date
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- 239000006183 anode active material Substances 0.000 title claims description 109
- 238000000034 method Methods 0.000 title claims description 39
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims description 35
- 229910052744 lithium Inorganic materials 0.000 title claims description 35
- 229910021426 porous silicon Inorganic materials 0.000 title description 2
- 239000011866 silicon-based anode active material Substances 0.000 title 1
- 229910052707 ruthenium Inorganic materials 0.000 claims description 90
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 89
- 239000000243 solution Substances 0.000 claims description 56
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- 239000013078 crystal Substances 0.000 claims description 36
- 239000002923 metal particle Substances 0.000 claims description 34
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- 229910052715 tantalum Inorganic materials 0.000 claims description 30
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 30
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- 229910052738 indium Inorganic materials 0.000 description 1
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- 239000003112 inhibitor Substances 0.000 description 1
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- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
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- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- 229910021445 lithium manganese complex oxide Inorganic materials 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- VROAXDSNYPAOBJ-UHFFFAOYSA-N lithium;oxido(oxo)nickel Chemical compound [Li+].[O-][Ni]=O VROAXDSNYPAOBJ-UHFFFAOYSA-N 0.000 description 1
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 1
- URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 description 1
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- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/02—Silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Silicon Compounds (AREA)
Applications Claiming Priority (2)
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| KR20130061794 | 2013-05-30 | ||
| PCT/KR2014/004635 WO2014193124A1 (ko) | 2013-05-30 | 2014-05-23 | 다공성 실리콘계 음극 활물질, 이의 제조 방법, 및 이를 포함하는 리튬 이차전지 |
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| TW201515308A TW201515308A (zh) | 2015-04-16 |
| TWI521773B true TWI521773B (zh) | 2016-02-11 |
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| EP (1) | EP2863455B1 (enFirst) |
| JP (1) | JP6448057B2 (enFirst) |
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| CN (1) | CN104662715B (enFirst) |
| IN (1) | IN2015DN00810A (enFirst) |
| PL (1) | PL2863455T3 (enFirst) |
| TW (1) | TWI521773B (enFirst) |
| WO (1) | WO2014193124A1 (enFirst) |
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| US10637054B2 (en) * | 2013-06-06 | 2020-04-28 | Nec Corporation | Positive electrode material for lithium ion secondary batteries, and method for producing same |
| US9985318B2 (en) | 2015-06-22 | 2018-05-29 | Wildcat Discovery Technologies, Inc | Electrolyte formulations |
| KR102573163B1 (ko) | 2015-08-21 | 2023-08-30 | 삼성전자주식회사 | 이미지 센서 및 이를 포함하는 전자 장치 |
| KR101997746B1 (ko) | 2015-09-24 | 2019-07-08 | 삼성전자주식회사 | 전지 팩 및 이의 충/방전 제어 방법 |
| JP6535581B2 (ja) * | 2015-11-18 | 2019-06-26 | 信越化学工業株式会社 | 負極活物質、混合負極活物質材料、非水電解質二次電池用負極、リチウムイオン二次電池 |
| WO2017107766A1 (zh) * | 2015-12-25 | 2017-06-29 | 清华大学深圳研究生院 | 钠离子电池电极材料及其制备方法 |
| DE102016202458A1 (de) * | 2016-02-17 | 2017-08-17 | Wacker Chemie Ag | Verfahren zur Herstellung von Si/C-Kompositpartikeln |
| KR101889661B1 (ko) * | 2016-08-18 | 2018-08-17 | 주식회사 엘지화학 | 실리콘 플레이크를 포함하는 음극재 및 실리콘 플레이크의 제조방법 |
| US10199687B2 (en) | 2016-08-30 | 2019-02-05 | Wildcat Discovery Technologies, Inc | Electrolyte formulations for electrochemical cells containing a silicon electrode |
| KR20180027022A (ko) * | 2016-09-05 | 2018-03-14 | 지에스에너지 주식회사 | 이차전지용 음극활물질 및 이의 제조방법 |
| CN110679013B (zh) * | 2017-09-07 | 2023-04-25 | 华盛顿州立大学 | 具有碳涂覆宏观孔的硅的阳极的电池 |
| GB201803983D0 (en) | 2017-09-13 | 2018-04-25 | Unifrax I Llc | Materials |
| US11233288B2 (en) | 2018-07-11 | 2022-01-25 | International Business Machines Corporation | Silicon substrate containing integrated porous silicon electrodes for energy storage devices |
| KR102254126B1 (ko) | 2018-09-12 | 2021-05-20 | 연세대학교 산학협력단 | 다공성 실리콘 구조체, 이를 포함하는 2차전지용 음극 활물질 및 이의 제조방법 |
| KR102598178B1 (ko) | 2018-10-10 | 2023-11-03 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 음극의 제조방법 |
| US20200119337A1 (en) * | 2018-10-15 | 2020-04-16 | Nanotek Instruments, Inc. | Electrochemically stable anode particulates for lithium secondary batteries and method of production |
| US12444744B2 (en) * | 2018-10-15 | 2025-10-14 | Honeycomb Battery Company | Electrochemically stable anode particulates for lithium secondary batteries |
| CN109461881B (zh) * | 2018-10-17 | 2020-07-03 | 宁德时代新能源科技股份有限公司 | 负极极片及二次电池 |
| US11239459B2 (en) * | 2018-10-18 | 2022-02-01 | GM Global Technology Operations LLC | Low-expansion composite electrodes for all-solid-state batteries |
| US12080916B2 (en) * | 2019-02-08 | 2024-09-03 | Panasonic Energy Co., Ltd. | Cylindrical battery |
| WO2020184917A1 (ko) * | 2019-03-08 | 2020-09-17 | 주식회사 엘지화학 | 황-도핑 실리콘 음극재, 그의 제조방법, 상기 음극재를 포함하는 리튬 이차 전지 음극, 및 상기 음극을 포함하는 리튬 이차 전지 |
| CN112840484B (zh) | 2019-03-08 | 2024-10-11 | 株式会社Lg新能源 | 硫掺杂硅负极材料、其制备方法、包含负极材料的锂二次电池负极和包含负极的锂二次电池 |
| CN113597686B (zh) * | 2019-03-19 | 2024-12-20 | 松下知识产权经营株式会社 | 非水电解液二次电池用负极及非水电解液二次电池 |
| US11404717B2 (en) | 2020-03-23 | 2022-08-02 | Techtronic Cordless Gp | Lithium-ion batteries |
| JP7431082B2 (ja) * | 2020-03-27 | 2024-02-14 | トヨタ自動車株式会社 | 活物質、負極層、電池およびこれらの製造方法 |
| TWI854491B (zh) * | 2022-02-17 | 2024-09-01 | 南韓商大洲電子材料股份有限公司 | 矽碳混合物、其製備方法以及包含其之負極活性材料與鋰二次電池 |
| US20250070146A1 (en) * | 2022-06-23 | 2025-02-27 | Lg Energy Solution, Ltd. | Negative electrode for lithium secondary battery, and lithium secondary battery comprising negative electrode |
| CN118676354B (zh) * | 2023-03-17 | 2026-01-27 | 宁德时代新能源科技股份有限公司 | 硅基材料及其制备方法、复合负极材料、二次电池和用电装置 |
| CN121528879B (zh) * | 2025-11-07 | 2026-07-14 | 哈尔滨工业大学 | 一种硫化物固态电池硅基负极的制备方法 |
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| US20040214085A1 (en) | 2003-01-06 | 2004-10-28 | Kyou-Yoon Sheem | Negative active material for rechargeable lithium battery, method of preparing same, and rechargeable lithium battery |
| JP3827642B2 (ja) * | 2003-01-06 | 2006-09-27 | 三星エスディアイ株式会社 | リチウム二次電池用負極活物質及びその製造方法並びにリチウム二次電池 |
| KR100818263B1 (ko) * | 2006-12-19 | 2008-03-31 | 삼성에스디아이 주식회사 | 다공성 음극 활물질, 그 제조 방법 및 이를 채용한 음극과리튬 전지 |
| KR101103841B1 (ko) | 2009-05-27 | 2012-01-06 | 한국과학기술연구원 | 금속이온 이용 무전해 에칭법에 의한 다발구조의 실리콘 나노로드 제조방법 및 이를 함유하는 리튬이차전지용 음극 활물질 |
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| CN102157731B (zh) * | 2011-03-18 | 2015-03-04 | 上海交通大学 | 一种锂离子电池硅碳复合负极材料及其制备方法 |
| KR101114492B1 (ko) | 2011-04-15 | 2012-02-24 | 세진이노테크(주) | 리튬 이차전지용 음극 활물질, 이의 제조 방법 및 이를 포함하는 리튬 이차전지 |
| KR101708360B1 (ko) * | 2011-10-05 | 2017-02-21 | 삼성에스디아이 주식회사 | 음극 활물질 및 이를 채용한 리튬 전지 |
| GB201117279D0 (en) | 2011-10-06 | 2011-11-16 | Nexeon Ltd | Etched silicon structures, method of forming etched silicon structures and uses thereof |
-
2014
- 2014-05-23 CN CN201480002484.1A patent/CN104662715B/zh active Active
- 2014-05-23 JP JP2015527410A patent/JP6448057B2/ja active Active
- 2014-05-23 PL PL14805120T patent/PL2863455T3/pl unknown
- 2014-05-23 EP EP14805120.4A patent/EP2863455B1/en active Active
- 2014-05-23 IN IN810DEN2015 patent/IN2015DN00810A/en unknown
- 2014-05-23 WO PCT/KR2014/004635 patent/WO2014193124A1/ko not_active Ceased
- 2014-05-27 KR KR1020140063807A patent/KR101588954B1/ko active Active
- 2014-05-28 TW TW103118615A patent/TWI521773B/zh active
- 2014-09-11 US US14/483,283 patent/US9843034B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2863455A1 (en) | 2015-04-22 |
| CN104662715B (zh) | 2018-09-28 |
| JP6448057B2 (ja) | 2019-01-09 |
| WO2014193124A1 (ko) | 2014-12-04 |
| KR101588954B1 (ko) | 2016-01-26 |
| EP2863455A4 (en) | 2015-07-01 |
| US20140377643A1 (en) | 2014-12-25 |
| CN104662715A (zh) | 2015-05-27 |
| PL2863455T3 (pl) | 2019-11-29 |
| TW201515308A (zh) | 2015-04-16 |
| EP2863455B1 (en) | 2019-07-31 |
| US9843034B2 (en) | 2017-12-12 |
| JP2015524993A (ja) | 2015-08-27 |
| KR20140141488A (ko) | 2014-12-10 |
| IN2015DN00810A (enFirst) | 2015-06-12 |
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