TWI502012B - 含氟聚合物乳化物 - Google Patents
含氟聚合物乳化物 Download PDFInfo
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- TWI502012B TWI502012B TW099137546A TW99137546A TWI502012B TW I502012 B TWI502012 B TW I502012B TW 099137546 A TW099137546 A TW 099137546A TW 99137546 A TW99137546 A TW 99137546A TW I502012 B TWI502012 B TW I502012B
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- polymer
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- 239000001257 hydrogen Substances 0.000 claims description 12
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- 125000005647 linker group Chemical group 0.000 claims description 10
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
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- 125000004429 atom Chemical group 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- 125000001165 hydrophobic group Chemical group 0.000 claims description 3
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- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 2
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- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
- C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
- C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
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- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
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| US12/614,488 US8329822B2 (en) | 2009-11-09 | 2009-11-09 | Fluoropolymer emulsions |
| US12/614,482 US8507601B2 (en) | 2009-11-09 | 2009-11-09 | Method using fluoropolymer emulsions |
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|---|---|
| TW201122049A TW201122049A (en) | 2011-07-01 |
| TWI502012B true TWI502012B (zh) | 2015-10-01 |
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| TW099137546A TWI502012B (zh) | 2009-11-09 | 2010-11-01 | 含氟聚合物乳化物 |
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| EP (1) | EP2499198B1 (enExample) |
| JP (1) | JP5876415B2 (enExample) |
| KR (1) | KR101768241B1 (enExample) |
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| CA (1) | CA2777028C (enExample) |
| MY (1) | MY157297A (enExample) |
| TW (1) | TWI502012B (enExample) |
| WO (1) | WO2011056525A1 (enExample) |
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| US9534343B2 (en) * | 2012-10-18 | 2017-01-03 | The Chemours Company Fc, Llc | Partially fluorinated copolymer emulsions containing fatty acids and esters |
| JP6124992B2 (ja) * | 2013-03-06 | 2017-05-10 | ユニマテック株式会社 | 含フッ素オリゴマー、それを用いたナノシリカコンポジット粒子およびそれらの製造法 |
| US9988536B2 (en) * | 2013-11-05 | 2018-06-05 | E I Du Pont De Nemours And Company | Compositions for surface treatments |
| CN107108455A (zh) | 2014-12-19 | 2017-08-29 | 默克专利股份有限公司 | 含氟化合物 |
| WO2019172021A1 (ja) * | 2018-03-08 | 2019-09-12 | Ａｇｃ株式会社 | 撥水撥油剤組成物の製造方法及び撥水撥油性物品の製造方法 |
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| TW544444B (en) * | 2000-05-11 | 2003-08-01 | Ppg Ind Ohio Inc | Impregnated glass fiber strands and products including the same |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US3282905A (en) | 1961-05-03 | 1966-11-01 | Du Pont | Fluorine containing esters and polymers thereof |
| CA1022182A (en) | 1972-09-19 | 1977-12-06 | Horst Jager | Process for the manufacture of perfluoroalkyl esters |
| CA1023768A (en) | 1972-12-21 | 1978-01-03 | Horst Jager | Polyfluoroalkyl iodides, process for their manufacture, and their use |
| US4564561A (en) * | 1985-03-27 | 1986-01-14 | E. I. Du Pont De Nemours And Company | Fluorine-containing polymer compositions and their preparation |
| JPH06192342A (ja) * | 1992-12-25 | 1994-07-12 | Mitsui Toatsu Chem Inc | コアシェル型含フッ素重合体およびその製造方法 |
| DE69413985T2 (de) | 1993-07-29 | 1999-04-22 | E.I. Du Pont De Nemours And Co., Wilmington, Del. | Verfahren zur herstellung von perfluoroalkyljodid |
| WO1995011877A1 (fr) | 1993-10-27 | 1995-05-04 | Elf Atochem S.A. | Alcools polyfluores et leurs procedes de preparation |
| US6326447B1 (en) * | 1998-06-19 | 2001-12-04 | E. I. Du Pont De Nemours And Company | Polymeric compositions for soil release on fabrics |
| US7485588B2 (en) * | 2003-01-10 | 2009-02-03 | Yunzhang Wang | Method for making textile substrates having layered finish structure for improving liquid repellency and stain release |
| JP4329559B2 (ja) * | 2003-05-02 | 2009-09-09 | ダイキン工業株式会社 | 含フッ素重合体を含んでなる表面処理剤 |
| CN1493601A (zh) * | 2003-07-23 | 2004-05-05 | 华东理工大学 | 一种水乳型含氟拒水拒油剂及其制备方法 |
| US20050095933A1 (en) | 2003-11-03 | 2005-05-05 | Kimbrell William C. | Textile substrates, compositions useful for treating textile substrates, and related methods |
| EP1533356A1 (en) * | 2003-11-24 | 2005-05-25 | 3M Innovative Properties Company | Fluorochemical composition for rendering substrates oil and/or water repellent |
| US7344758B2 (en) * | 2004-09-07 | 2008-03-18 | E.I. Du Pont De Nemours And Company | Hydrocarbon extenders for surface effect compositions |
| CN1958937A (zh) * | 2005-11-02 | 2007-05-09 | 巨化集团公司 | 一种含氟织物整理剂水乳液 |
| US20080202384A1 (en) * | 2007-02-28 | 2008-08-28 | Sheng Peng | Fluoropolymer compositions and method of use |
| US20090030114A1 (en) * | 2007-07-25 | 2009-01-29 | Ying Wang | Fluoropolymer emulsions |
| US20090148653A1 (en) * | 2007-12-07 | 2009-06-11 | E.I. Du Pont De Nemours And Company | Fluoropolymer emulsions |
| JP5262108B2 (ja) * | 2007-12-28 | 2013-08-14 | ダイキン工業株式会社 | 水性重合体分散組成物および撥水撥油剤 |
-
2010
- 2010-10-26 CN CN201080050694.XA patent/CN102597101B/zh not_active Expired - Fee Related
- 2010-10-26 WO PCT/US2010/054006 patent/WO2011056525A1/en not_active Ceased
- 2010-10-26 JP JP2012538836A patent/JP5876415B2/ja not_active Expired - Fee Related
- 2010-10-26 BR BR112012010860-3A patent/BR112012010860A2/pt not_active IP Right Cessation
- 2010-10-26 CA CA2777028A patent/CA2777028C/en not_active Expired - Fee Related
- 2010-10-26 KR KR1020127014776A patent/KR101768241B1/ko not_active Expired - Fee Related
- 2010-10-26 AU AU2010315636A patent/AU2010315636B2/en not_active Ceased
- 2010-10-26 EP EP10773498.0A patent/EP2499198B1/en not_active Not-in-force
- 2010-10-27 MY MYPI2010005048A patent/MY157297A/en unknown
- 2010-11-01 TW TW099137546A patent/TWI502012B/zh not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW544444B (en) * | 2000-05-11 | 2003-08-01 | Ppg Ind Ohio Inc | Impregnated glass fiber strands and products including the same |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2777028A1 (en) | 2011-05-12 |
| CA2777028C (en) | 2016-09-06 |
| BR112012010860A2 (pt) | 2020-12-08 |
| WO2011056525A1 (en) | 2011-05-12 |
| EP2499198A1 (en) | 2012-09-19 |
| CN102597101A (zh) | 2012-07-18 |
| AU2010315636B2 (en) | 2015-03-26 |
| CN102597101B (zh) | 2014-09-17 |
| AU2010315636A1 (en) | 2012-04-26 |
| JP2013510232A (ja) | 2013-03-21 |
| KR101768241B1 (ko) | 2017-08-30 |
| KR20120104569A (ko) | 2012-09-21 |
| HK1173463A1 (en) | 2013-05-16 |
| EP2499198B1 (en) | 2013-07-17 |
| JP5876415B2 (ja) | 2016-03-02 |
| TW201122049A (en) | 2011-07-01 |
| MY157297A (en) | 2016-05-31 |
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