TWI495765B - Plating device - Google Patents

Plating device Download PDF

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TWI495765B
TWI495765B TW099129112A TW99129112A TWI495765B TW I495765 B TWI495765 B TW I495765B TW 099129112 A TW099129112 A TW 099129112A TW 99129112 A TW99129112 A TW 99129112A TW I495765 B TWI495765 B TW I495765B
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plating
chamber
plating solution
plating chamber
cathode
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TW099129112A
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TW201109479A (en
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Motoyuki Itoh
Kyoko Takeda
Hajime Hayakawa
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Hitachi Metals Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/16Apparatus for electrolytic coating of small objects in bulk
    • C25D17/18Apparatus for electrolytic coating of small objects in bulk having closed containers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/02Tanks; Installations therefor
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/08Electroplating with moving electrolyte e.g. jet electroplating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/60Electroplating characterised by the structure or texture of the layers
    • C25D5/605Surface topography of the layers, e.g. rough, dendritic or nodular layers
    • C25D5/611Smooth layers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)

Description

電鍍裝置Plating device

本發明是有關於一種表面具有導電性的基材粒子的電鍍裝置。The present invention relates to a plating apparatus for a substrate particle having conductivity on a surface.

作為對表面具有導電性的基材粒子實施電鍍的技術之一例,有一種在以Cu為主體的芯球的表面電鍍焊錫而形成焊錫被覆Cu芯球(core ball)(以下簡記作Cu芯球)的技術。再者,為了明確先前技術的問題,以Cu芯球為例說明了電鍍技術,但本發明並不限定於Cu芯球。As an example of a technique of performing electroplating on a substrate particle having conductivity on the surface, there is a method of forming a solder-coated Cu core ball (hereinafter abbreviated as a Cu core ball) by plating a solder on a surface of a core ball mainly composed of Cu. Technology. Further, in order to clarify the problems of the prior art, the electroplating technique is described by taking a Cu core ball as an example, but the present invention is not limited to the Cu core ball.

在近年來的藉由多間距(pitch)化、狹間距化而在高密度封裝方面有所進展的球柵陣列(Ball Grid Array,BGA)或晶片尺寸封裝(Chip Scale Package,CSP)等半導體封裝中,作為輸出入端子用凸塊,應用有小徑的Cu芯球。In recent years, semiconductor packages such as Ball Grid Array (BGA) or Chip Scale Package (CSP) have been advanced in high-density packaging by multi-pitch and narrow pitch. In the case of the bump for the input/output terminal, a Cu core ball having a small diameter is applied.

Cu芯球由於其芯球在回流焊時不會熔融,因此可在半導體元件與基板之間維持固定的距離,可確保對因半導體元件的起動、停止所產生的熱循環(cycle)負載等的連接可靠性。Since the Cu core ball does not melt during reflow soldering, it can maintain a fixed distance between the semiconductor element and the substrate, and can secure a thermal cycle load due to starting and stopping of the semiconductor element. Connection reliability.

作為Cu芯球製造技術,眾所周知有一種筒式(barrel)電鍍法:在具有電鍍液可流通的多個開口的筒內收納芯球,藉由使筒配置於電鍍浴中自轉而被覆焊錫。然而,尤其當製造直徑為100 μm以下的小徑的Cu芯球時,由與筒的自轉相伴的芯球的轉動所引起的芯球的攪拌不夠充分。其結果,芯球彼此經由電鍍層而連結並凝聚,或者電鍍層的表面粗面化,從而產生電鍍層的厚度局部地變得不均勻,而導致良率下降的問題。As a Cu core ball manufacturing technique, a barrel plating method is known in which a core ball is housed in a cylinder having a plurality of openings through which a plating liquid can flow, and the tube is covered by soldering in a plating bath. However, especially when a Cu core ball having a small diameter of 100 μm or less is manufactured, the agitation of the core ball caused by the rotation of the core ball accompanying the rotation of the cylinder is insufficient. As a result, the core balls are connected and aggregated via the plating layer, or the surface of the plating layer is roughened, and the thickness of the plating layer is locally uneven, resulting in a problem of a decrease in yield.

消除該筒式電鍍法的問題的技術的一例在專利文獻1中有所記載。專利文獻1中揭示有一種小型的旋轉電鍍裝置:為了以短時間獲得充分且均勻的電鍍層,「將接觸環(contact ring)與多孔環(porous ring)一體結合而形成單元(cell),上述接觸環將被電鍍物在旋轉過程中按壓於上端開放的下開口碗形的樹脂圓罩(doom)的外周部下表面與樹脂底板的外周部上表面之間,上述多孔環使處理液流通飛散,將與不可相對旋轉地支持上述單元並與接觸環通電的導電轉盤(rotary plate)的中央部下表面垂直的導電驅動軸(shaft)的上端予以固定,將接觸電刷(contact brush)按壓至上述軸並連接於負(minus)極,在上述圓罩內配置陽極籃(anode basket),並設置覆蓋單元的罩(cover)」。並且記載有:根據該構成的旋轉電鍍裝置,收納於單元內的被電鍍物在因單元的旋轉而產生的離心力的作用下會被強制按壓至接觸環,藉由反覆單元的旋轉與停止或減速而得到均勻混合,被電鍍物的表面上的電鍍液的更新亦變得活躍,從而可形成均勻的厚度的電鍍層。An example of a technique for eliminating the problem of the barrel plating method is described in Patent Document 1. Patent Document 1 discloses a small-sized rotary plating apparatus in which a contact ring and a porous ring are integrally joined to form a cell in order to obtain a sufficient and uniform plating layer in a short time. The contact ring presses the plated material between the lower surface of the outer peripheral portion of the lower open bowl-shaped doom having the open upper end and the upper surface of the outer peripheral portion of the resin base plate during the rotation, and the porous ring circulates the treatment liquid. Fixing the upper end of a conductive drive shaft that is perpendicular to the lower surface of the central portion of the conductive plate that supports the unit and that is electrically connected to the contact ring, and presses a contact brush to the shaft And connected to a minus pole, an anode basket is disposed in the above-mentioned dome, and a cover covering the unit is provided. Further, according to the rotary plating apparatus having such a configuration, the object to be plated stored in the unit is forcibly pressed to the contact ring by the centrifugal force generated by the rotation of the unit, and the rotation or stop or deceleration of the reverse unit is performed. With uniform mixing, the renewal of the plating solution on the surface of the plated material also becomes active, so that a plating layer having a uniform thickness can be formed.

然而,專利文獻1的旋轉電鍍裝置在工業生產效率方面存在問題。亦即,該旋轉電鍍裝置為了攪拌被電鍍物而使電鍍液充分於其表面流通,需要反覆進行單元的旋轉、停止或減速。並且,對被電鍍物的實際的電鍍處理僅在單元旋轉而被電鍍物在離心力的作用下與接觸環接觸的期間進行,而在停止或減速的期間並不進行,因此與電鍍處理時間相比,整體的製造時間較長。進而,在電鍍處理中,由於球的攪拌力不產生作用,因此,尤其在半導體封裝中所用的直徑為100 μm以下的小徑的Cu芯球的情況下,芯球在單元內的凝聚變得顯著,電鍍處理後的Cu芯球的表面的平滑性亦發生劣化。為了消除該凝聚,雖亦存在頻繁地反覆進行單元的旋轉、停止或減速的方法,但會導致電鍍效率進一步下降的問題。However, the rotary plating apparatus of Patent Document 1 has a problem in industrial production efficiency. That is, in order to stir the electroplated material, the electroplating apparatus sufficiently circulates the plating liquid to the surface thereof, and it is necessary to repeatedly rotate, stop, or decelerate the unit. Further, the actual plating treatment of the object to be plated is performed only during the period in which the unit is rotated and the plated material is in contact with the contact ring by the centrifugal force, and is not performed during the period of stopping or decelerating, so that compared with the plating treatment time The overall manufacturing time is longer. Further, in the plating treatment, since the stirring force of the ball does not function, in particular, in the case of a Cu core ball having a diameter of 100 μm or less used in a semiconductor package, the aggregation of the core ball in the cell becomes Significantly, the smoothness of the surface of the Cu core ball after the plating treatment also deteriorated. In order to eliminate the aggregation, there is a method in which the rotation, stop, or deceleration of the unit is frequently repeated, but the plating efficiency is further lowered.

而且,消除筒式電鍍法的問題的技術的另一例在專利文獻2中有所記載。於專利文獻2中記載有一種電鍍裝置:其目的在於防止尤其具備易彎曲性質的工件(work)在電鍍時的變形等,該電鍍裝置的特徵在於,「具有作為上表面開口的電鍍槽以及閉塞該電鍍槽的上表面開口的裝卸蓋,於上述電鍍槽的底面具備陰極,於裝卸蓋的背面具備陽極,並且於沿著上述電鍍槽的底面的周壁上,具備朝向該周壁的內面方向的電鍍液的噴射噴嘴(nozzle)」。並且,於專利文獻2中記載有:藉由採用該構成,被投入電鍍槽內的工件與自噴射噴嘴噴射出的電鍍液一同在電鍍槽內轉動,隨著該旋轉而被實施電鍍處理,因此不存在會造成彎曲或變形的碰撞等,可使所有工件在保持原形的狀態下結束電鍍加工處理。Further, another example of a technique for eliminating the problem of the barrel plating method is described in Patent Document 2. Patent Document 2 discloses an electroplating apparatus which aims to prevent deformation of a work having particularly flexible properties during plating, and the like, which is characterized in that "the plating chamber having the opening as the upper surface and the occlusion are provided The loading and unloading cover having an open upper surface of the plating tank includes a cathode on a bottom surface of the plating tank, an anode on a back surface of the loading and unloading cover, and a circumferential wall facing the bottom surface of the plating tank. Spray nozzle (nozzle) of the plating solution. Further, Patent Document 2 discloses that the workpiece placed in the plating tank is rotated in the plating tank together with the plating solution sprayed from the injection nozzle, and is subjected to plating treatment in accordance with the rotation. There is no collision or the like which causes bending or deformation, and all the workpieces can be finished in the state of maintaining the original shape.

然而,該專利文獻2的電鍍裝置於在基材粒子上形成均勻的厚度的電鍍層這一點上不夠充分。亦即,當利用專利文獻2的電鍍裝置來對基材粒子進行電鍍時,基材粒子一方面受到在電鍍槽內回旋的電鍍液而攪拌,一方面作回旋運動,但由於粒子乘著液流而移動,因此配置於底面的電極與粒子相接觸的概率較小,該概率對於每個粒子亦不均勻。其結果,有可能產生對於各種基材粒子而電鍍層的厚度不同的問題。However, the plating apparatus of Patent Document 2 is insufficient in forming a plating layer having a uniform thickness on the substrate particles. That is, when the substrate particles are plated by the plating apparatus of Patent Document 2, the substrate particles are stirred by the plating solution swirled in the plating tank on the one hand, and the swirling motion is performed on the one hand, but the particles are multiplied by the liquid flow. When moving, the probability that the electrode disposed on the bottom surface is in contact with the particles is small, and the probability is not uniform for each particle. As a result, there is a possibility that the thickness of the plating layer is different for various substrate particles.

進而,於下述專利文獻3中,作為於粒徑為0.1 μm~10 μm的範圍的金屬、無機物質等的微粉末的表面,利用電鍍法來均勻且高收率地被覆金屬的裝置,揭示有一種「微粉末的電鍍裝置,其包括:收容電鍍液且使軸成縱向的筒狀容器、於該容器的底部使電導表面橫向配設的陰極板、靠近該電鍍液的液面而配設的陽極、對該陰極板與陽極之間賦予規定電位的電源裝置、於該陰極板與陽極之間的液中具備吸入用開口的吸入管、於該陰極板與陽極之間的液中具備噴出用開口的噴出管、自該吸入管通向噴出管的流體的循環路徑以及介裝於該循環路徑中的流體循環用泵(pump),將該噴出管的噴出用開口朝向陰極板的電導表面的方向而朝下設置,並且將上述吸入管的吸入用開口設置於較陽極下端更下方,使作為被電鍍品的粒徑0.1 μm至10.0 μm範圍的導電性微粉末與電鍍液一同在上述循環路徑內循環,同時連續碰撞至該陰極板」。並且記載有:根據該電鍍裝置,使電鍍液中強制形成在電鍍液中微粉末具備規定的懸濁濃度而懸濁且具備規定的方向及速度的微粉末懸濁液,使微粉末懸濁流實質上不與陽極接觸,而僅以規定的速度成分循環碰撞至陰極板,因此可均勻且高收率地對每一粒微粉末的表面進行電鍍。Furthermore, in the following Patent Document 3, a device for coating a metal on a surface of a fine powder such as a metal or an inorganic material having a particle diameter of 0.1 μm to 10 μm in a uniform and high-yield manner by a plating method is disclosed. There is a "micro-powder electroplating apparatus comprising: a cylindrical container for accommodating a plating solution and longitudinally arranging a shaft, a cathode plate for arranging a conductive surface at a bottom portion of the container, and a liquid surface adjacent to the plating solution; The anode, a power supply device that supplies a predetermined potential between the cathode plate and the anode, and a suction pipe having a suction opening in the liquid between the cathode plate and the anode, and a liquid is discharged from the liquid between the cathode plate and the anode. a discharge passage of the opening, a circulation path of the fluid from the suction pipe to the discharge pipe, and a pump for fluid circulation interposed in the circulation path, the discharge opening of the discharge pipe is directed toward the conduction surface of the cathode plate The direction of the suction pipe is set downward, and the suction opening of the suction pipe is disposed below the lower end of the anode, so that the conductive fine powder having a particle diameter of 0.1 μm to 10.0 μm as an electroplated product and plating are provided. Together circulates in the circulation path, while continuously to the cathode collision plate. " Further, according to the plating apparatus, it is described that a fine powder suspension having a predetermined suspension concentration and having a predetermined suspension concentration in the plating solution is suspended in the plating solution, and the fine powder suspension liquid is substantially formed. The upper surface is not in contact with the anode, but only collides with the cathode plate at a predetermined speed component, so that the surface of each fine powder can be plated uniformly and in high yield.

然而,根據該專利文獻3的電鍍裝置,由於微粉末僅乘著微粉末懸濁流而流動,因此與陰極板接觸的概率在微粉末間並不均勻,由於與專利文獻2的電鍍裝置同樣的理由,於在各個基材粒子上形成均勻的厚度的電鍍層這一點上不夠充分。However, according to the plating apparatus of Patent Document 3, since the fine powder flows only by the fine powder suspension flow, the probability of contact with the cathode plate is not uniform between the fine powders, and the reason is the same as that of the plating apparatus of Patent Document 2. It is not sufficient to form a plating layer having a uniform thickness on each of the substrate particles.

[先行技術文獻][Advanced technical literature] [專利文獻][Patent Literature]

[專利文獻1]日本專利特開平8-239799號公報[Patent Document 1] Japanese Patent Laid-Open No. Hei 8-239799

[專利文獻2]日本專利實開平7-6267號公報[Patent Document 2] Japanese Patent Publication No. 7-6267

[專利文獻3]日本專利特開平1-272792號公報[Patent Document 3] Japanese Patent Laid-Open No. 1-272792

本發明是有鑒於上述先前技術的問題而完成的發明,其目的在於提供一種可在表面具有導電性的基材粒子上有效率地形成均勻的厚度的電鍍層的電鍍裝置。The present invention has been made in view of the above problems of the prior art, and an object thereof is to provide a plating apparatus capable of efficiently forming a plating layer having a uniform thickness on a substrate particle having conductivity on a surface.

解決上述問題的本發明的電鍍裝置是表面具有導電性的基材粒子的電鍍裝置,其包括:電鍍槽,具有電鍍室,該電鍍室具備上述基材粒子可接觸並轉繞的底面以及沿著該底面的周緣而立設的周壁面,且可收納包含上述基材粒子的粒子群及電鍍液;電鍍液供給管,具有自上述電鍍室的底面向上方開口的供給口,且以沿著上述電鍍室的周壁面而回旋的方式自上述供給口供給電鍍液;電鍍液排出管,具有向上述電鍍室開口的排出口;陰極,與配置於上述電鍍室的底面的上述基材粒子接觸;陽極,配置在浸漬於上述電鍍室內所收納的電鍍液中的位置;以及電源,連接於上述陰極及陽極。An electroplating apparatus of the present invention which solves the above problems is an electroplating apparatus having surface-conducting substrate particles, comprising: a plating bath having a plating chamber having a bottom surface on which the substrate particles can be contacted and circulated, and along a peripheral wall surface of the bottom surface of the bottom surface, and a particle group including the substrate particles and a plating solution; the plating solution supply pipe having a supply port opened upward from a bottom surface of the plating chamber, and along the plating a plating solution is supplied from the supply port by a circumferential wall surface of the chamber; a plating solution discharge pipe having a discharge port opening to the plating chamber; and a cathode contacting the substrate particles disposed on a bottom surface of the plating chamber; A position is placed in the plating solution accommodated in the plating chamber; and a power source is connected to the cathode and the anode.

該電鍍裝置起到如下所述的作用。亦即,自電鍍液供給管的供給口所供給的電鍍液沿著電鍍室的周壁面而回旋並且朝向其底面側流下。並且,當電鍍室被電鍍液充滿時,通過向電鍍室開口的排出口而自電鍍液排出管予以排出,並自電鍍液供給管供給新的電鍍液,藉此,電鍍室始終被新鮮的電鍍液所充滿。The plating apparatus functions as described below. That is, the plating solution supplied from the supply port of the plating solution supply pipe is swirled along the peripheral wall surface of the plating chamber and flows downward toward the bottom surface side thereof. Further, when the plating chamber is filled with the plating solution, it is discharged from the plating solution discharge pipe through the discharge port opened to the plating chamber, and a new plating solution is supplied from the plating solution supply pipe, whereby the plating chamber is always freshly plated. The liquid is full.

到達電鍍室底面的回旋流動的電鍍液使電鍍室內收納的粒子群接觸電鍍室的底面並且回旋運動。於該底面接觸陰極的基材粒子在配置於浸漬在電鍍液中的位置處的陽極之間得到電鍍處理,從而於基材粒子的表面形成電鍍層。此處,藉由回旋流動的電鍍液,粒子群不會分散而彼此混合,並且接觸底面而轉動並在底面上作回旋運動。因而,基材粒子的凝聚得到抑制,並且基材粒子的表面的各部位接觸電鍍液的機會變得均等,其結果,可形成均勻的厚度的電鍍層。再者,一旦開始回旋運動的粒子不會浮游,而是反覆與底面間歇性地接觸,並且持續回旋運動。The swirling flowing plating solution that reaches the bottom surface of the plating chamber causes the particle group accommodated in the plating chamber to contact the bottom surface of the plating chamber and to rotate. The substrate particles that are in contact with the cathode on the bottom surface are plated between the anodes disposed at the positions immersed in the plating solution to form a plating layer on the surface of the substrate particles. Here, by swirling the flowing plating solution, the particle groups do not disperse and mix with each other, and contact the bottom surface to rotate and perform a whirling motion on the bottom surface. Therefore, the aggregation of the substrate particles is suppressed, and the chances of the respective portions of the surface of the substrate particles contacting the plating solution become equal, and as a result, a plating layer having a uniform thickness can be formed. Furthermore, once the particles that begin the convoluted motion do not float, they repeatedly contact the bottom surface intermittently and continue to rotate.

進而,藉由電鍍液的回旋流,使基材粒子接觸電鍍室的底面並且轉動,因此基材粒子與其他基材粒子接觸的概率提高,因而,可高頻率地與接觸陰極的基材粒子電性連接,而進行接近連續電鍍的處理,從而可有效率地在基材粒子上形成電鍍層,進而,藉由基材粒子彼此的接觸,所形成的電鍍層得到平滑化,從而可形成表面極為平滑且均勻的厚度的電鍍層。Further, by the swirling flow of the plating solution, the substrate particles are brought into contact with the bottom surface of the plating chamber and rotated, so that the probability of the substrate particles coming into contact with the other substrate particles is increased, and thus the substrate particles contacting the cathode can be electrically exchanged at a high frequency. The connection is performed, and the treatment of the continuous plating is performed, so that the plating layer can be efficiently formed on the substrate particles, and further, the formed plating layer is smoothed by the contact of the substrate particles, and the surface can be formed extremely A smooth and uniform thickness of the plating layer.

[發明的效果][Effects of the Invention]

如上述說明所示,根據本發明的電鍍裝置,可達成本發明的目的,即:解決先前技術的問題,提供一種可有效率地在表面具有導電性的基材粒子上形成表面平滑且均勻的厚度的電鍍層的電鍍裝置。再者,以下,對上述電鍍裝置的較佳形態及其效果進行詳細說明。As described in the above description, the electroplating apparatus according to the present invention can attain the object of the invention, that is, to solve the problems of the prior art, and to provide a surface which can be efficiently and smoothly formed on the surface of the substrate having conductivity on the surface. Electroplating device for the thickness of the plating layer. In the following, preferred embodiments of the plating apparatus and effects thereof will be described in detail.

為讓本發明之上述和其他目的、特徵和優點能更明顯易懂,下文特舉較佳實施例,並配合所附圖式,作詳細說明如下。The above and other objects, features and advantages of the present invention will become more <RTIgt;

以下,根據該第1~第6實施形態,參照圖式來說明本發明的電鍍裝置。下述的實施形態中,以在將基材粒子即Cu作為主體的球形的芯球的表面被覆以Sn為主體的電鍍層的電鍍裝置為例進行了說明,但本發明並不限定於此,例如可適用於如下情況,即:在已利用無電電鍍而在表面形成有鎳等具有導電性的金屬層的樹脂或陶瓷(ceramics)粒子及其他在表面具有導電性的基材粒子的表面,利用電鍍法來形成金屬被覆層的情況。而且,不僅可適用於如芯球般為球狀的基材粒子,亦可適用於例如具有長軸及短軸的針狀的基材粒子或無形狀特徵的不定形的基材粒子。進而,下述說明的電鍍裝置的各構成要素可單獨或適當組合而使用。Hereinafter, the plating apparatus of the present invention will be described with reference to the drawings based on the first to sixth embodiments. In the following embodiments, a plating apparatus in which a plating layer mainly composed of Sn is a surface of a spherical core ball having Cu as a main component is described as an example. However, the present invention is not limited thereto. For example, it can be applied to a surface of a resin or ceramics particle having a conductive metal layer such as nickel formed on the surface by electroless plating, and other surface of the substrate particle having conductivity on the surface. A case where a metal coating layer is formed by electroplating. Further, it can be applied not only to substrate particles having a spherical shape like a core ball but also to needle-shaped substrate particles having a long axis and a short axis or amorphous substrate particles having no shape characteristics. Further, each component of the plating apparatus described below may be used singly or in an appropriate combination.

[第1實施形態][First Embodiment]

如表示第1形態的電鍍裝置的概略構成的正面圖即圖1以及拆除圖1的密閉蓋1L後的狀態的平面圖即圖2(a)所示,電鍍裝置1具備本體部1a、經由電鍍液供給管1e及電鍍液排出管1c而連接於本體部1a的電鍍液循環機構1b、以及直流電源電路1h來作為基本構成,作為更為理想的構成,電鍍裝置1具備芯球供給機構1g、振動機構1i及磁力產生機構1s。FIG. 1 is a front view showing a schematic configuration of a plating apparatus according to a first embodiment, and FIG. 2(a) is a plan view showing a state in which the sealing lid 1L of FIG. 1 is removed. The plating apparatus 1 includes a main body 1a and a plating solution. The plating pipe 1e and the plating liquid discharge pipe 1c are connected to the plating liquid circulation mechanism 1b of the main body 1a and the DC power supply circuit 1h as a basic configuration. The plating apparatus 1 is provided with a core ball supply mechanism 1g and vibration. Mechanism 1i and magnetic force generating mechanism 1s.

在本體部1a中,符號1j是形成有電鍍室1m的電鍍槽,該電鍍室1m具有圓形狀的底面1p以及朝向該底面1p而縮徑的圓錐台形狀的周壁面1q。由對電鍍液具有耐蝕性的非導電性絕緣物即樹脂等構成的電鍍槽1j具有:上部開口的碗型的容器1k;以及以閉塞上部開口的方式而緊貼於容器1k的上表面的密閉蓋1L。由該容器1k及密閉蓋1L所形成的空間構成電鍍室1m,包含多個芯球91的球群(粒子群)9及規定量的電鍍液L被收納於電鍍室1m中。In the main body portion 1a, reference numeral 1j is a plating tank in which a plating chamber 1m is formed, and the plating chamber 1m has a circular bottom surface 1p and a truncated cone-shaped peripheral wall surface 1q which is reduced in diameter toward the bottom surface 1p. The plating tank 1j which consists of a resin which is a non-conductive insulating material which has corrosion resistance to a plating liquid, has the bowl-shaped container 1k of the upper opening, and the sealing of the upper surface of the container 1k so that the upper opening may be closed. Cover 1L. The space formed by the container 1k and the sealing lid 1L constitutes a plating chamber 1m, and a ball group (particle group) 9 including a plurality of core balls 91 and a predetermined amount of plating liquid L are accommodated in the plating chamber 1m.

電鍍液供給管1e的一端以其軸心沿著電鍍室1m的周壁面1q的切線方向,且電鍍液供給口1f在電鍍室1m的上部開口的方式而水平地連接於電鍍槽1j,其另一端則連接於電鍍液循環機構1b。電鍍液排出管1c的一端以電鍍液排出口1d在密閉蓋1L的中央部與電鍍室1m的軸芯成同軸地向電鍍室1m開口的方式而連接於電鍍槽1j,而其另一端連接於電鍍液循環機構1b。電鍍液循環機構1b由未圖示的電鍍液貯藏槽(tank)、電鍍液循環用泵、電鍍液淨化用過濾器(filter)及流量控制閥等構成,自電鍍液循環機構1b送出的電鍍液L在電鍍液供給管1e內流通,自電鍍液供給口1f被供給至電鍍室1m,並如圖1、圖2(a)中虛線a所示,沿著電鍍室1m的周壁面1q而回旋流下。而且,可調整電鍍液循環機構1b的電鍍液循環用泵或流量控制閥,以使供給至電鍍室1m的電鍍液L的流速或流量隨時間發生變化。再者,電鍍液循環機構1b亦可設置成,不僅通過電鍍液供給管1e來供給電鍍液L,而且可通過電鍍液排出管1c自電鍍室1m抽吸電鍍液L。進而,亦可設置多根上述電鍍液供給管1e。此時,既可將電鍍液供給管配置成,在電鍍室1m的周壁面1q的同一圓周上,多個電鍍液供給口1f例如以固定的角度間距而開口,亦可如圖4(c)所示的電鍍裝置22般而將電鍍液供給管22e配置成,多個電鍍液供給口22f沿著回旋流下的電鍍液L的螺旋狀的流動a而開口。藉由以上的構成,電鍍液L如圖1所示,一方面沿著向下方傾斜的周壁面1q而回旋流動,一方面呈螺旋狀流下,並到達電鍍室1m的底面1p,隨後,如圖中虛線b所示般成為上升流,並通過電鍍液排出口1d自電鍍液排出管1c排出而返回電鍍液循環機構1b。One end of the plating solution supply pipe 1e is horizontally connected to the plating tank 1j so that its axial center is along the tangential direction of the peripheral wall surface 1q of the plating chamber 1m, and the plating solution supply port 1f is opened at the upper portion of the plating chamber 1m. One end is connected to the plating liquid circulation mechanism 1b. One end of the plating solution discharge pipe 1c is connected to the plating tank 1j so that the plating liquid discharge port 1d is opened to the plating chamber 1m coaxially with the core of the plating chamber 1m at the center portion of the sealing lid 1L, and the other end thereof is connected to Plating solution circulation mechanism 1b. The plating solution circulation mechanism 1b is composed of a plating liquid storage tank (not shown), a plating liquid circulation pump, a plating liquid purification filter (filter), a flow rate control valve, and the like, and a plating liquid sent from the plating liquid circulation mechanism 1b. L flows through the plating solution supply pipe 1e, is supplied from the plating solution supply port 1f to the plating chamber 1m, and swirls along the peripheral wall surface 1q of the plating chamber 1m as indicated by a broken line a in Fig. 1 and Fig. 2(a). Flow down. Further, the plating solution circulation pump or the flow rate control valve of the plating solution circulation mechanism 1b can be adjusted so that the flow rate or flow rate of the plating solution L supplied to the plating chamber 1m changes with time. Further, the plating solution circulation mechanism 1b may be provided so that the plating solution L can be supplied from the plating chamber 1m not only by the plating solution supply pipe 1e but also by the plating solution discharge pipe 1c. Further, a plurality of the plating solution supply pipes 1e may be provided. In this case, the plating solution supply pipe may be disposed such that the plurality of plating solution supply ports 1f are opened at a fixed angular interval on the same circumference of the peripheral wall surface 1q of the plating chamber 1m, as shown in FIG. 4(c). In the plating apparatus 22 as shown, the plating solution supply pipe 22e is disposed such that the plurality of plating solution supply ports 22f are opened along the spiral flow a of the plating solution L under the swirling flow. According to the above configuration, as shown in FIG. 1, the plating solution L swirls along the peripheral wall surface 1q which is inclined downward, and flows downward in a spiral shape to reach the bottom surface 1p of the plating chamber 1m, and then, as shown in FIG. As shown by the broken line b, the upward flow is formed, and is discharged from the plating solution discharge pipe 1c through the plating solution discharge port 1d, and is returned to the plating solution circulation mechanism 1b.

再者,芯球91亦可開閉密閉蓋1L而隨時供給至電鍍室1m,但亦可如圖1所示,在由電鍍液供給管1e構成的供給系統中,設置截出規定數量的芯球91的供給機構1g,通過電鍍液供給管1e的管路而將芯球91與電鍍液L一同供給至電鍍室1m。該供給機構1g的具體構成將在第4形態的電鍍裝置中作詳細說明。Further, the core ball 91 may be opened and closed to the plating chamber 1m at any time, but as shown in FIG. 1, a predetermined number of core balls may be provided in the supply system including the plating solution supply pipe 1e. The supply mechanism 1g of 91 supplies the core ball 91 together with the plating solution L to the plating chamber 1m through the piping of the plating solution supply pipe 1e. The specific configuration of the supply mechanism 1g will be described in detail in the plating apparatus of the fourth aspect.

符號1n是配置在容器1k的底部的圓板狀的陰極,陰極1n的上表面設置成電鍍室1m的底面1p。連接於直流電源電路1h的負極的陰極1n例如由不鏽鋼(stainless steel)、鈦、電鍍有鉑的鈦等所形成。球群9藉由在電鍍室1m內回旋流動的電鍍液L,而如圖中符號C所示般,自外周端沿著半徑方向而在規定的範圍中一方面與底面1p接觸一方面回旋運動,藉此,芯球91在底面1p之上,一邊被攪拌一邊轉動。Reference numeral 1n is a disk-shaped cathode disposed at the bottom of the container 1k, and the upper surface of the cathode 1n is provided as a bottom surface 1p of the plating chamber 1m. The cathode 1n connected to the negative electrode of the DC power supply circuit 1h is formed of, for example, stainless steel, titanium, titanium plated with platinum, or the like. The ball group 9 is rotated by the plating liquid L in the plating chamber 1m, as shown by the symbol C in the figure, and is in contact with the bottom surface 1p on the one hand in the predetermined range from the outer peripheral end in the radial direction. Thereby, the core ball 91 is rotated above the bottom surface 1p while being stirred.

此處,既可如圖3(a)所示,將陰極3n配置成露出於電鍍室1m的底面3p的一部分,亦可如該圖3(b)所示,將陰極3m配置成與配置於底面3p上的芯球91相接觸。然而,當如此般將陰極3n、3m配置成僅與多個芯球91中的極少部分接觸時,不與陰極3n、3m接觸的芯球91會經由與陰極3n、3m接觸的芯球91而通電,因此,有可能會因芯球91彼此的接觸電阻而導致處於遠離陰極3n的位置處的芯球91的電位下降,該芯球91中的電流密度變低,從而電鍍效率下降。因此,較佳為,平面觀察時,陰極與球群9具有充分的接觸面積,較為理想的是,如本實施形態般形成為圓板形狀。此時,亦可設置成:使容器1k本身由陰極材料所形成,並對容器1k的側面實施具有耐蝕性及絕緣性的樹脂被覆,從而使容器1k的底面作為陰極1n而發揮作用。Here, as shown in FIG. 3(a), the cathode 3n may be disposed to be exposed to a part of the bottom surface 3p of the plating chamber 1m, or the cathode 3m may be disposed and disposed as shown in FIG. 3(b). The core balls 91 on the bottom surface 3p are in contact. However, when the cathodes 3n, 3m are disposed so as to be in contact with only a very small portion of the plurality of core balls 91, the core balls 91 not in contact with the cathodes 3n, 3m pass through the core balls 91 in contact with the cathodes 3n, 3m. When the current is applied, there is a possibility that the potential of the core ball 91 at a position away from the cathode 3n is lowered due to the contact resistance of the core balls 91, and the current density in the core ball 91 becomes low, so that the plating efficiency is lowered. Therefore, it is preferable that the cathode and the ball group 9 have a sufficient contact area in plan view, and it is preferable to form a disk shape as in the present embodiment. In this case, the container 1k itself may be formed of a cathode material, and the side surface of the container 1k may be coated with a resin having corrosion resistance and insulation, so that the bottom surface of the container 1k functions as the cathode 1n.

另一方面,如圖1及圖2(a)所示,當電鍍室1m的底面1p全部由陰極1n構成時,電鍍層的形成速度有可能會下降。亦即,球群9利用回旋流動的電鍍液L而在底面1p(陰極1n的上表面)的外周緣部的規定區域C作回旋運動,因此在不存在球群9的陰極1n的上表面的中央部亦會無端地析出電鍍。因此,較佳為,如在圖2(b)及沿著其中心線的剖面圖即圖2(c)中以符號2n所示,陰極與球群9作回旋運動的區域對應地呈圓環狀設置於底面2p的外周緣,且底面2p的中央部2z由電性絕緣材料構成。再者,在圖2(b)、圖2(c)的情況下,中央部2z是與容器1k一體地構成,但例如亦可使中央部2z由絕緣性陶瓷等而異體地形成,並裝入容器1k中。On the other hand, as shown in Fig. 1 and Fig. 2(a), when the bottom surface 1p of the plating chamber 1m is entirely composed of the cathode 1n, the formation speed of the plating layer may be lowered. In other words, the ball group 9 is swirled in the predetermined region C of the outer peripheral edge portion of the bottom surface 1p (the upper surface of the cathode 1n) by the swirling flowing plating liquid L, and therefore the upper surface of the cathode 1n of the ball group 9 is not present. The central government will also unconditionally deposit plating. Therefore, it is preferable that, as shown by the symbol 2n in FIG. 2(b) and a cross-sectional view along the center line thereof, FIG. 2(c), the region where the cathode and the ball group 9 make a whirling motion corresponds to a ring. The outer peripheral edge of the bottom surface 2p is provided, and the central portion 2z of the bottom surface 2p is made of an electrically insulating material. In the case of FIG. 2(b) and FIG. 2(c), the central portion 2z is integrally formed with the container 1k. For example, the central portion 2z may be formed separately from an insulating ceramic or the like. Into the container 1k.

進而,如圖2(c)所示,陰極2n亦可在容器1k的基端部不僅具備其表面以形成與底面2p為同一平面之方式而露出的第1陰極2y,還具備其表面以形成與周壁面1q為同一內周面之方式而露出的第2陰極2x。該陰極2x與2y如圖所示,可作為以橫剖面呈「<」字狀之方式而在各自的一端相結合的陰極2n而裝入容器1k中。藉由設置該第2陰極2x,能夠使隨電鍍液流動而在底面2p的周緣部呈旋迴運動的球群9也可接觸到第2陰極2x,所以球群9可接觸的陰極2n的面積得到增加,可在維持高電鍍效率的狀態下,在芯球91上形成均勻的電鍍層。此外,藉由與後述的第6實施形態的電鍍裝置的陽極構造的組合,可降低陽極與陰極之間的電阻,可形成空隙(void)等缺陷減少的良質電鍍層。再者,為了防止陰極2n的表面上的電鍍的析出以提高電鍍效率,較為理想的是如圖2(c)所示,陰極2n被包含於球群9作回旋流動的範圍C之中。而且,圖2(b)所示的陰極2n是形成為在圓周方向上連續的圓環形狀,但即便一部分存在不連續部分,只要實質上形成為圓環狀即可。Further, as shown in FIG. 2(c), the cathode 2n may have not only the first cathode 2y which is exposed on the surface of the container 1k so as to form the same plane as the bottom surface 2p, but also the surface thereof to be formed. The second cathode 2x is exposed so that the peripheral wall surface 1q is the same inner peripheral surface. As shown in the figure, the cathodes 2x and 2y can be placed in the container 1k as cathodes 2n joined at their respective ends in a "<" shape in a cross section. By providing the second cathode 2x, the ball group 9 that reciprocates in the peripheral portion of the bottom surface 2p as the plating liquid flows can be brought into contact with the second cathode 2x, so that the area of the cathode 2n that the ball group 9 can contact can be made. When the increase is made, a uniform plating layer can be formed on the core ball 91 while maintaining high plating efficiency. Further, by combining with the anode structure of the plating apparatus according to the sixth embodiment to be described later, the electric resistance between the anode and the cathode can be reduced, and a favorable plating layer having reduced defects such as voids can be formed. Further, in order to prevent deposition of plating on the surface of the cathode 2n to improve plating efficiency, it is preferable that the cathode 2n is included in the range C in which the cluster 9 is swirled as shown in Fig. 2(c). Further, the cathode 2n shown in Fig. 2(b) is formed in a circular ring shape continuous in the circumferential direction. However, even if a portion has a discontinuous portion, it may be formed substantially in an annular shape.

進而,為了藉由促進芯球91的轉動而使芯球91的表面上形成的電鍍層的外周面彼此摩擦,以提高該外表面的平滑性,可將電鍍室1m的底面1p(亦即陰極1n的上表面)設定固定的粗面。另一方面,就防止因與電鍍室1m的底面1p摩擦而產生的芯球91表面或電鍍層表面的損傷的觀點而言,該底面1p亦可設為平滑的面。而且,如圖3(c)所示,為了使芯球91在電鍍室1m的底面1p之上的回旋運動得到穩定化,較為理想的是在底面1p上形成圓環狀的導引溝4y,該導引溝4y是沿著電鍍液L的回旋方向而形成,以導引芯球91。Further, in order to improve the smoothness of the outer surface by rubbing the outer peripheral surfaces of the plating layer formed on the surface of the core ball 91 by the rotation of the core ball 91, the bottom surface 1p of the plating chamber 1m (that is, the cathode) can be used. The upper surface of 1n) sets a fixed rough surface. On the other hand, from the viewpoint of preventing damage to the surface of the core ball 91 or the surface of the plating layer caused by friction with the bottom surface 1p of the plating chamber 1m, the bottom surface 1p may be a smooth surface. Further, as shown in Fig. 3(c), in order to stabilize the swirling motion of the core ball 91 on the bottom surface 1p of the plating chamber 1m, it is preferable to form an annular guide groove 4y on the bottom surface 1p. The guide groove 4y is formed along the swirling direction of the plating solution L to guide the core ball 91.

於圖1中,符號1o是在電鍍室1m的上部與陰極1n相對而配置的包含錫的陽極。陽極1o以位於浸漬在充滿電鍍室1m的電鍍液L中的位置之方式,而經由不鏽鋼、鈦、經鉑電鍍的鈦等的支持構件1r而固定於密閉蓋1L,並連接於直流電源電路1h的正極。In Fig. 1, reference numeral 1o is an anode containing tin disposed opposite to the cathode 1n in the upper portion of the plating chamber 1m. The anode 1o is fixed to the hermetic cover 1L via a support member 1r such as stainless steel, titanium, or platinum-plated titanium, and is connected to the DC power supply circuit 1h so as to be immersed in the plating solution L filled in the plating chamber 1m. The positive pole.

此處,以下對陽極的較佳形態進行說明。當對多個芯球91進行電鍍時,所有芯球91的表面積之和會變得非常大。為了使固定的電流流經該多個芯球91與陽極之間,並確保規定的電流密度(即,將電流值除以芯球91的表面積之和所得的值),藉此於芯球91上均勻且有效率地形成電鍍層,較佳為,將陽極1o的下表面與陰極1n的上表面以相對的方式而配置,並以包含在陰極1n上作回旋運動的球群9的範圍C的方式而呈圓環形狀形成陽極1o。進而,如本體部1a的上部右側部分的正剖視即圖4(a)所示,藉由在與陰極相對的陽極14o的底面上設置凹凸,可在陽極14o上形成與芯球91的表面積相應的面積。而且,當欲進一步增加陽極的表面積時,亦可如圖4(b)般構成陽極部15o。該陽極部15o具有:連接於直流電源電路的正極且由多個導電性粒子15y所構成的陽極、以及經由支持構件而固定於密閉蓋1L並收納多個導電性粒子15y的大致圓環形狀的導電性粒子收納容器15x。較佳為,由樹脂等非導電性材料所構成的呈網(mesh)狀的導電性粒子收納容器15x具有多個導電性粒子15y無法通過而電鍍液可流通的開口,且底面與未圖示的陰極相對,並以不會妨礙所供給的電鍍液的流動的方式而配置於較電鍍液供給口1f更上方。再者,導電性粒子收納容器15x亦可由不鏽鋼、鈦、經鉑電鍍的鈦等的導電性材料所構成。導電性粒子收納容器15x中收納的導電性粒子15y可根據欲對芯球電鍍的材料而適當選擇,例如當對芯球電鍍錫時,選擇由錫構成的粒子。根據該形態的陽極部15o,由於藉由多個導電性粒子15y來構成陽極,因此與上述平板狀的陽極的情況相比,可形成緊湊(compact)但具有大的表面積的陽極,進而,藉由調整各個導電性粒子15y的大小或收納的個數,可自如地調整陽極的表面積。Here, a preferred embodiment of the anode will be described below. When the plurality of core balls 91 are plated, the sum of the surface areas of all the core balls 91 becomes very large. In order to allow a fixed current to flow between the plurality of core balls 91 and the anode, and to ensure a prescribed current density (ie, a value obtained by dividing the current value by the sum of the surface areas of the core balls 91), the core ball 91 is thereby used. The plating layer is uniformly and efficiently formed, and preferably, the lower surface of the anode 1o and the upper surface of the cathode 1n are disposed in an opposing manner, and the range C of the cluster 9 including the swirling motion on the cathode 1n is disposed. In the manner of a ring shape, the anode 1o is formed. Further, as shown in Fig. 4(a), a front cross section of the upper right portion of the main body portion 1a, a surface area with the core ball 91 can be formed on the anode 14o by providing irregularities on the bottom surface of the anode 14o opposed to the cathode. The corresponding area. Further, when it is desired to further increase the surface area of the anode, the anode portion 15o may be formed as shown in Fig. 4(b). The anode portion 15o has an anode which is connected to the positive electrode of the DC power supply circuit and is composed of a plurality of conductive particles 15y, and a substantially annular shape which is fixed to the sealing lid 1L via a support member and accommodates the plurality of conductive particles 15y. Conductive particle storage container 15x. Preferably, the mesh-shaped conductive particle storage container 15x made of a non-conductive material such as a resin has an opening through which the plurality of conductive particles 15y cannot pass, and the plating solution can flow, and the bottom surface and the bottom surface are not shown. The cathodes are opposed to each other and are disposed above the plating solution supply port 1f so as not to impede the flow of the supplied plating solution. Further, the conductive particle storage container 15x may be made of a conductive material such as stainless steel, titanium, or platinum-plated titanium. The conductive particles 15y accommodated in the conductive particle storage container 15x can be appropriately selected depending on the material to be plated on the core ball. For example, when the core ball is plated with tin, particles made of tin are selected. According to the anode portion 15o of this aspect, since the anode is constituted by the plurality of conductive particles 15y, an anode having a compact but large surface area can be formed as compared with the case of the flat anode. The surface area of the anode can be freely adjusted by adjusting the size or the number of the respective conductive particles 15y.

在圖1中,符號1i是配置於容器1k的底面側的振動機構。作為本發明的電鍍裝置的較佳形態,所裝入的振動機構1i具體而言是以規定的頻率來對容器1k施加振動的振動機構,藉由該振動,預防芯球91彼此的附著或芯球91與底面1p的附著,並且將已附著的芯球91予以分離,以防止芯球91的凝聚。In Fig. 1, reference numeral 1i is a vibration mechanism disposed on the bottom surface side of the container 1k. In a preferred embodiment of the plating apparatus of the present invention, the vibration mechanism 1i to be incorporated is specifically a vibration mechanism that applies vibration to the container 1k at a predetermined frequency, and the vibration or the core ball 91 is prevented from adhering to each other or the core. The ball 91 is attached to the bottom surface 1p, and the attached core ball 91 is separated to prevent aggregation of the core ball 91.

符號1s是配置於電鍍槽1j的下方的磁力產生機構。磁力產生機構1s是在芯球91具有磁性的情況下或被覆於芯球91的電鍍層例如為Ni或Fe等而具有磁性的情況下有效的構成要素,利用磁力來使芯球91或形成有電鍍層的芯球91吸引至下方,以接觸電鍍室1m的底面1p(陰極1n的上表面)並作回旋運動。再者,磁力產生機構1s亦可設置於電鍍槽1j的下方外周。進而,為了將球群9停留在回旋區域C之中而防止芯球91分散,磁力產生機構1s較佳為由與該回旋範圍C對應大小的大致圓環形狀的永久磁鐵等構成。The symbol 1s is a magnetic force generating mechanism disposed below the plating tank 1j. The magnetic force generating means 1s is a component which is effective when the core ball 91 has magnetism or when the plating layer coated on the core ball 91 is magnetic, for example, Ni or Fe, and the core ball 91 is formed by magnetic force. The core ball 91 of the plating layer is attracted downward to contact the bottom surface 1p of the plating chamber 1m (the upper surface of the cathode 1n) and to perform a whirling motion. Further, the magnetic force generating mechanism 1s may be provided on the outer periphery of the lower side of the plating tank 1j. Further, in order to prevent the core ball 91 from being dispersed by the ball group 9 staying in the swirling region C, the magnetic force generating mechanism 1s is preferably constituted by a substantially annular permanent magnet having a size corresponding to the swirling range C.

對上述電鍍裝置1的動作進行說明。首先是準備步驟。在準備步驟中,打開密閉蓋1L,將規定數量的芯球91載置於電鍍室1m的底面1p(陰極1n的上表面),將電鍍液L貯藏於電鍍液循環機構1b的電鍍液貯藏槽內。再者,作為芯球91,亦可使用經酸洗處理而使表面得到潔淨化的芯球,還可使用視需要而在表面形成有鎳電鍍層作為基底層的芯球。而且,用於進行焊錫電鍍的電鍍液例如可在具有Sn-Ag-Cu系的液組成的大和化成製的商品名「DAIN TINSIL SBB 2」或Rohm and Haas製的商品名「SOLDERON BP SAC5000」等中添加添加劑,並適當調整為例如硼氟化浴等眾所周知的電鍍浴來使用。構成球群9的粒子並不限定於芯球91,例如亦可適量添加以焊錫或鋼為主體的導電性鍚球(dummy ball)、以樹脂或陶瓷等為主體的非導電性鍚球,以作為例如用於促進球群9的攪拌的攪拌促進物。The operation of the plating apparatus 1 described above will be described. The first is the preparation step. In the preparation step, the sealing cover 1L is opened, a predetermined number of core balls 91 are placed on the bottom surface 1p of the plating chamber 1m (the upper surface of the cathode 1n), and the plating solution L is stored in the plating solution storage tank of the plating liquid circulation mechanism 1b. Inside. Further, as the core ball 91, a core ball which is cleaned by pickling treatment may be used, and a core ball having a nickel plating layer as a base layer formed on the surface as needed may be used. In addition, the plating solution for solder plating can be, for example, a product of the product "DAIN TINSIL SBB 2" manufactured by Yamato Chemical Co., Ltd. having a liquid composition of Sn-Ag-Cu type, or a product name "SOLDERON BP SAC5000" manufactured by Rohm and Haas. An additive is added thereto, and is appropriately adjusted to be used in a well-known plating bath such as a borofluoride bath. The particles constituting the ball group 9 are not limited to the core ball 91. For example, a conductive ball mainly composed of solder or steel or a non-conductive ball containing resin or ceramics may be added in an appropriate amount. As a stirring accelerator for promoting the stirring of the ball group 9, for example.

關閉密閉蓋1L而使電鍍室1m成為密閉空間之後,使電鍍裝置1作動。電鍍裝置1使電鍍液循環機構1b作動,以通過電鍍液供給管1e而以規定的流量向電鍍室1m供給電鍍液L。當電鍍室1m被電鍍液L充滿時,電鍍液L成為沿著電鍍室1m的周壁面1q而回旋,並且沿著周壁面1q的傾斜而朝向底面1p呈螺旋狀流下的回旋流a。再者,在電鍍液L的供給的初期階段,由於電鍍液L的流動並不穩定,因此芯球91有時會乘著不穩定的電鍍液L的流動而流出至電鍍室1m之外。為了防止該芯球91的流出,較佳為可在準備步驟中,使電鍍室1m預先充滿電鍍液L,隨後再向電鍍室1m供給電鍍液L。而且,較佳為,在電鍍液L的供給的初期階段,可減小電鍍液L的流量,並逐漸增加至規定的流量。After the sealing lid 1L is closed and the plating chamber 1m is placed in a sealed space, the plating apparatus 1 is actuated. The plating apparatus 1 operates the plating liquid circulation mechanism 1b to supply the plating liquid L to the plating chamber 1m at a predetermined flow rate through the plating liquid supply pipe 1e. When the plating chamber 1m is filled with the plating solution L, the plating solution L is swirled along the peripheral wall surface 1q of the plating chamber 1m, and swirls a downwardly flowing toward the bottom surface 1p along the inclination of the peripheral wall surface 1q. Further, in the initial stage of the supply of the plating solution L, the flow of the plating solution L is unstable, and therefore the core ball 91 may flow out of the plating chamber 1m by the flow of the unstable plating solution L. In order to prevent the outflow of the core ball 91, it is preferable that the plating chamber 1m is previously filled with the plating solution L in the preparation step, and then the plating solution L is supplied to the plating chamber 1m. Further, it is preferable that the flow rate of the plating solution L can be reduced and gradually increased to a predetermined flow rate in the initial stage of the supply of the plating solution L.

沿著呈朝向下方縮徑的圓錐台形狀的電鍍室1m的周壁面1q而在電鍍室1m內回旋流下的電鍍液L隨著接近底面1p而回旋速度增加,並到達底面1p。到達底面1p的電鍍液L的回旋流a使接觸底面1p的球群9按壓於該底面1p並作回旋運動。此處,球群9中所含的芯球91接觸至底面1p,亦即接觸至與直流電源電路1h的負極連接的陰極1n的上表面,因此在陽極1o之間得到電鍍處理,從而在芯球91的表面形成電鍍層。並且,到達電鍍室1m的底面1p的電鍍液L在底面1p的中央部成為上升流b,通過電鍍液排出口1d而自電鍍液排出管1c排出並返回電鍍液循環機構1b,因此始終有新鮮的電鍍液L被供給至電鍍室1m,從而可使電鍍室1m中的電鍍液L的狀態始終固定,其結果,可在芯球91的表面形成均勻的厚度的電鍍層。再者,較為理想的是,在電鍍室1m由電鍍液L充滿之後,通過電鍍液排出管1c來抽吸電鍍液L,其原因在於,如此可使電鍍液L的回旋流得到進一步整流化,從而使得芯球91的回旋運動穩定。The plating solution L swirling in the plating chamber 1m along the peripheral wall surface 1q of the plating chamber 1m having a truncated cone shape which is reduced in diameter downward increases the swirling speed as it approaches the bottom surface 1p, and reaches the bottom surface 1p. The swirling flow a of the plating solution L reaching the bottom surface 1p presses the ball group 9 contacting the bottom surface 1p against the bottom surface 1p and performs a swirling motion. Here, the core ball 91 contained in the ball group 9 is in contact with the bottom surface 1p, that is, the upper surface of the cathode 1n connected to the negative electrode of the DC power supply circuit 1h, so that plating treatment is performed between the anodes 1o, thereby being in the core The surface of the ball 91 forms a plating layer. In addition, the plating liquid L that has reached the bottom surface 1p of the plating chamber 1m becomes the upward flow b in the central portion of the bottom surface 1p, is discharged from the plating liquid discharge pipe 1c through the plating liquid discharge port 1d, and is returned to the plating liquid circulation mechanism 1b, so that there is always freshness. The plating solution L is supplied to the plating chamber 1m, so that the state of the plating solution L in the plating chamber 1m can be always fixed, and as a result, a plating layer having a uniform thickness can be formed on the surface of the core ball 91. Further, it is preferable that after the plating chamber 1m is filled with the plating solution L, the plating solution L is sucked by the plating solution discharge pipe 1c because the swirling flow of the plating solution L can be further rectified. Thereby, the whirling motion of the core ball 91 is stabilized.

接觸電鍍室1m的底面1p並作回旋運動的芯球91在底面1p上轉動,且芯球91以彼此摩擦的方式而碰撞,因此芯球91彼此難以附著,從而防止芯球91的凝聚,且藉由轉動而使芯球91的表面接觸底面1p的機會變得均等,因此可形成均勻的厚度的電鍍層。此處可推定:在電鍍處理的過程中,電鍍層在直接地或經由其他芯球91而間接地接觸陰極1n時逐漸形成於芯球91的表面。因此,在電鍍處理的初期階段,成為僅在表面的一部分上形成有電鍍層的狀態。若芯球91的轉動不夠充分,則有時會如圖14(a)所示般形成突起的電鍍層m被覆於芯球91上的糖果狀的Cu芯球。可料想的是,該電鍍層的突起的部分是以初期形成於芯球91的表面的一部分上的電鍍層為起點而選擇性地形成電鍍層的結果。然而,藉由使芯球91充分轉動,使芯球91以彼此摩擦的方式而碰撞,可如圖14(b)所示般產生電鍍層表面的平滑化效果,即,利用轉動的其他芯球91b來對芯球91a的表面的一部分上所形成的電鍍層m1進行摩擦而使其鋪開,以防止在表面的一部分上選擇性地形成電鍍層,從而可形成表面極為平滑且電鍍層內部空隙(void)較少的均勻厚度的電鍍層。此種具有電鍍層且球度極高的Cu芯球在用作覆晶晶片(flip chip)用連接構件時尤其適合。The core ball 91 that contacts the bottom surface 1p of the plating chamber 1m and rotates is rotated on the bottom surface 1p, and the core balls 91 collide with each other in a frictional manner, so that the core balls 91 are hard to adhere to each other, thereby preventing aggregation of the core ball 91, and The chance of the surface of the core ball 91 contacting the bottom surface 1p by rotation is made uniform, so that a plating layer having a uniform thickness can be formed. Here, it can be presumed that the plating layer is gradually formed on the surface of the core ball 91 when it is indirectly contacted with the cathode 1n directly or via other core balls 91 during the plating process. Therefore, in the initial stage of the plating treatment, a plating layer is formed only on a part of the surface. If the rotation of the core ball 91 is insufficient, a plated Cu core ball may be coated on the core ball 91 by forming a plating layer m having a projection as shown in Fig. 14(a). It is conceivable that the protruding portion of the plating layer is a result of selectively forming a plating layer starting from a plating layer initially formed on a part of the surface of the core ball 91. However, by causing the core ball 91 to rotate sufficiently to cause the core balls 91 to collide with each other, the smoothing effect of the surface of the plating layer can be produced as shown in FIG. 14(b), that is, other core balls that utilize rotation 91b to rub the plating layer m1 formed on a part of the surface of the core ball 91a to spread it to prevent selective formation of a plating layer on a part of the surface, so that the surface can be formed extremely smooth and the internal void of the plating layer (void) less uniform thickness of the plating layer. Such a Cu core ball having a plating layer and having a very high sphericity is particularly suitable when it is used as a connecting member for a flip chip.

再者,當使用圖1所示的芯球供給機構1g來將芯球91供給至電鍍室1m時,芯球91藉由回旋流動的電鍍液L而進行回旋運動,在離心力的作用下被按壓於周壁面1q並下降,並下降至電鍍室1m的底面1p,因此可持續穩定的回旋運動。Further, when the core ball 91 is supplied to the plating chamber 1m by using the core ball supply mechanism 1g shown in Fig. 1, the core ball 91 is rotated by the swirling flowing plating liquid L, and is pressed by the centrifugal force. It is lowered by 1q on the peripheral wall surface and descends to the bottom surface 1p of the plating chamber 1m, so that a stable and stable swirling motion can be maintained.

在上述狀態下,以規定時間對芯球91進行電鍍處理,形成具有規定厚度的焊錫電鍍層的Cu芯球。就防止芯球91凝聚的觀點而言,有利的是適當調整電鍍液循環機構1b的電鍍液循環用泵或流量調整閥,使在電鍍處理中所供給的電鍍液L的流量或流速隨時間發生變化,或者經由容器1k而利用振動機構1i來對球群91施加振動。In the above state, the core ball 91 is subjected to a plating treatment for a predetermined period of time to form a Cu core ball having a solder plating layer having a predetermined thickness. From the viewpoint of preventing aggregation of the core ball 91, it is advantageous to appropriately adjust the plating solution circulation pump or the flow rate adjustment valve of the plating solution circulation mechanism 1b so that the flow rate or flow rate of the plating solution L supplied in the plating process occurs over time. The vibration is applied to the ball group 91 by the vibration mechanism 1i via the container 1k.

參照圖5及圖6(a)、圖6(b),對上述電鍍裝置1的更佳形態的電鍍裝置進行說明。再者,在圖5及圖6(a)、圖6(b)中,對於與上述電鍍裝置1相同的構成要素標註相同符號,並省略詳細說明。A plating apparatus of a preferred embodiment of the plating apparatus 1 will be described with reference to Figs. 5 and 6(a) and 6(b). In FIGS. 5 and 6(a) and 6(b), the same components as those of the plating apparatus 1 are denoted by the same reference numerals, and detailed description thereof will be omitted.

圖5所示的電鍍裝置5呈如下狀態:以成為貫穿密閉蓋1L的中央部而突出至電鍍室1m之中的狀態的方式配置電鍍液排出管5c,使電鍍液排出口5d在軸芯方向上位於電鍍室1m的中間部,具體而言,使電鍍液排出口5d位於較電鍍液供給口1f更下方,進而,使電鍍液排出管5c可如箭頭d所示般沿著軸心方向而移動。如圖5所示,當在電鍍液排出管5c的外周面配置陽極5o時,較為理想的是配置成不會自電鍍液排出管5c的外周面而突出。根據該電鍍裝置5,電鍍液排出口5d接近電鍍室1m的底面1p,因此電鍍液L的上升流b會在底面1p的附近被排出,上升流b對回旋流a造成的影響得到抑制,可使芯球91在底面1p上的回旋運動穩定。進而,在電鍍液L的供給的初期階段,縮短電鍍液排出管5c自密閉蓋1L的突出長度,直至電鍍室1m的回旋流a穩定為止,在回旋流穩定後,使電鍍液排出管5c向下方移動而加長自密閉蓋1L的突出長度並定位至規定位置,藉此,自向電鍍室1m導入電鍍液L的電鍍處理前的階段直至電鍍處理完成為止,可防止芯球91流出至電鍍室1m之外。再者,在如後述的第2~第4形態的電鍍裝置般,具備對在電鍍室內作回旋流動的電鍍液進行整流化的構成或向電鍍室供給芯球的構成的電鍍裝置的情況下,電鍍液排出管5c亦可不沿上下方向移動,而如圖所示般以在底面1p的上方附近配置電鍍液排出口5d的方式而固定於密閉蓋1L。The plating apparatus 5 shown in FIG. 5 is in a state in which the plating liquid discharge pipe 5c is disposed so as to protrude into the plating chamber 1m through the center portion of the sealing cover 1L, and the plating liquid discharge port 5d is oriented in the axial direction. The upper portion of the plating chamber 1m is located, specifically, the plating solution discharge port 5d is located below the plating solution supply port 1f, and further, the plating solution discharge pipe 5c can be along the axial direction as indicated by the arrow d. mobile. As shown in FIG. 5, when the anode 5o is disposed on the outer peripheral surface of the plating solution discharge pipe 5c, it is preferable that the anode 5o is disposed so as not to protrude from the outer peripheral surface of the plating solution discharge pipe 5c. According to the plating apparatus 5, since the plating solution discharge port 5d is close to the bottom surface 1p of the plating chamber 1m, the upward flow b of the plating solution L is discharged in the vicinity of the bottom surface 1p, and the influence of the upward flow b on the swirling flow a is suppressed. The whirling motion of the core ball 91 on the bottom surface 1p is stabilized. Further, in the initial stage of the supply of the plating solution L, the protruding length of the plating solution discharge pipe 5c from the sealing lid 1L is shortened until the swirling flow a of the plating chamber 1m is stabilized, and after the swirling flow is stabilized, the plating liquid discharge pipe 5c is turned to Moving downward and lengthening the protruding length of the self-sealing cover 1L and positioning it to a predetermined position, thereby preventing the core ball 91 from flowing out to the plating chamber from the stage before the plating process of the plating solution L to the plating chamber 1m until the plating process is completed. 1m away. In the case of a plating apparatus that rectifies a plating solution that swirls in a plating chamber or a plating apparatus that supplies a core ball to a plating chamber, as in the plating apparatus of the second to fourth aspects, which will be described later, The plating solution discharge pipe 5c may be fixed to the sealing cover 1L so as to be disposed in the vertical direction as shown in the figure, so that the plating solution discharge port 5d is disposed in the vicinity of the upper surface of the bottom surface 1p.

圖6(a)所示的電鍍裝置為如下形態:在電鍍室1m內呈圓錐形狀形成有底面6p(陰極6n的上表面),以使得在半徑方向上中心部相對於周緣部而較高。根據該形態的電鍍裝置,球群9在底面6p的高度較低的周緣部穩定地進行回旋運動,藉此可提高底面6p上的球的濃度。再者,如該圖6(b)所示,在電鍍室1m內形成具有圓柱狀突起7y的底面7p(陰極7n的上表面),以使得在半徑方向上中央部相對於周緣部而較高,亦可發揮同樣的作用效果,但此時較為理想的是,以不會妨礙電鍍液L的流動的方式而在突起7y的上部周緣形成錐(taper)面。The plating apparatus shown in Fig. 6(a) is a form in which a bottom surface 6p (an upper surface of the cathode 6n) is formed in a conical shape in the plating chamber 1m so that the central portion is higher in the radial direction with respect to the peripheral portion. According to the plating apparatus of this aspect, the ball group 9 stably swings at the peripheral portion where the height of the bottom surface 6p is low, whereby the concentration of the ball on the bottom surface 6p can be increased. Further, as shown in FIG. 6(b), the bottom surface 7p (the upper surface of the cathode 7n) having the columnar projections 7y is formed in the plating chamber 1m so that the central portion is higher in the radial direction with respect to the peripheral portion. The same effect can be exerted. However, in this case, it is preferable to form a taper surface on the upper periphery of the projection 7y so as not to impede the flow of the plating solution L.

[第2實施形態][Second Embodiment]

以下,根據圖7(a)、圖7(b)及圖8(a)、圖8(b),對第2形態的電鍍裝置進行說明。再者,在圖7(a)、圖7(b)及圖8(a)、圖8(b)中,對於與上述第1形態的電鍍裝置1及其較佳形態的電鍍裝置5等相同的構成要素標註相同符號,並省略詳細說明(以下對於第3~第6形態的電鍍裝置亦相同)。Hereinafter, a plating apparatus according to a second embodiment will be described with reference to FIGS. 7(a), 7(b), 8(a), and 8(b). Further, in FIGS. 7(a), 7(b), 8(a), and 8(b), the plating apparatus 1 of the first aspect and the plating apparatus 5 of the preferred embodiment are the same. The constituent elements are denoted by the same reference numerals, and detailed descriptions thereof will be omitted (the same applies to the plating apparatuses of the third to sixth aspects).

如圖7(a)所示,第2形態的電鍍裝置8與第1形態的電鍍裝置1的不同之處在於:在與第1形態同樣地形成的電鍍室1m中具有導引機構8v。圖7(a)的導引機構8v設置成將通過電鍍液供給口1f而供給的電鍍液L朝向電鍍室1m的底面1p予以導引。亦即,導引機構8v是由形成有螺旋的非導電性材料構成的導引板8w,該螺旋是在順著沿電鍍室1m的周壁面1q而回旋並朝向底面1p流下的電鍍液L的流線a的方向上延伸。上部8x配置於電鍍液供給口1f的下方且下部8y與電鍍室1m的底面1p隔開規定的間隙而配置的導引板8w,在中央捲繞縱向貫穿密閉蓋1L的電鍍液排出管5c且其外周面密接於周壁面1q。再者,為了使電鍍液L順暢地自電鍍室1m排出,導引機構8x的下端較佳為位於電鍍液排出口更上方。As shown in Fig. 7 (a), the plating apparatus 8 of the second embodiment is different from the plating apparatus 1 of the first embodiment in that the plating chamber 1m formed in the same manner as the first embodiment has a guiding mechanism 8v. The guiding mechanism 8v of Fig. 7(a) is provided to guide the plating liquid L supplied through the plating solution supply port 1f toward the bottom surface 1p of the plating chamber 1m. That is, the guiding mechanism 8v is a guiding plate 8w made of a non-conductive material formed with a spiral which is a plating liquid L which swirls along the peripheral wall surface 1q of the plating chamber 1m and flows down toward the bottom surface 1p. The flow line a extends in the direction. The upper portion 8x is disposed below the plating solution supply port 1f, and the guide plate 8w disposed at a predetermined gap between the lower portion 8y and the bottom surface 1p of the plating chamber 1m is wound around the plating solution discharge pipe 5c of the sealing cover 1L in the longitudinal direction. The outer peripheral surface is in close contact with the peripheral wall surface 1q. Further, in order to smoothly discharge the plating solution L from the plating chamber 1m, the lower end of the guiding mechanism 8x is preferably located above the plating solution discharge port.

根據該導引板8w,自電鍍液供給口1f所供給的電鍍液L在藉由導引板8w、電鍍液排出管5c的外周面及電鍍室1m的周壁面1q而劃分的螺旋狀的流通通路8z之中,如虛線a所示般自上方朝向下方而流動,並被導引至電鍍室1m的底面1p。此處,導引板8w沿著自電鍍液供給口1f所供給並回旋流下的電鍍液L的流線a而形成螺旋狀,且流通通路8z形成為一條被密閉的通路,因此,不會因自電鍍液供給口1f所供給的電鍍液L或流動的電鍍液L的相互干涉而使回旋流下的電鍍液L產生紊流,而經整流化的電鍍液L將到達底面1p。進而,如圖中以符號b2所示,即使由於自電鍍液排出管5c排出而作為上升流朝向電鍍液排出口的電鍍液L的流動b的一部分存在於電鍍液排出管5c之外時,其流動亦會被導引板8w的下部8y所阻擋,因此不會擾亂回旋流下的電鍍液L的流動a。其結果,球群在底面1p上的回旋運動穩定,從而可形成具有均勻的電鍍層的Cu芯球。According to the guide plate 8w, the plating solution L supplied from the plating solution supply port 1f is spirally branched by the guide plate 8w, the outer peripheral surface of the plating solution discharge pipe 5c, and the peripheral wall surface 1q of the plating chamber 1m. Among the passages 8z, as shown by a broken line a, the flow flows from the upper side toward the lower side, and is guided to the bottom surface 1p of the plating chamber 1m. Here, the guide plate 8w is formed in a spiral shape along the flow line a of the plating solution L supplied from the plating solution supply port 1f and swirled down, and the flow path 8z is formed as a closed passage, and therefore, The plating solution L supplied from the plating solution supply port 1f or the flowing plating solution L interfere with each other to cause turbulent flow of the plating solution L under the swirling flow, and the rectified plating solution L reaches the bottom surface 1p. Further, as shown by the symbol b2 in the figure, even if a part of the flow b of the plating solution L which is an upward flow toward the plating solution discharge port exists outside the plating solution discharge pipe 5c due to the discharge from the plating solution discharge pipe 5c, The flow is also blocked by the lower portion 8y of the guide plate 8w, so that the flow a of the plating solution L under the swirling flow is not disturbed. As a result, the swirling motion of the ball group on the bottom surface 1p is stabilized, so that a Cu core ball having a uniform plating layer can be formed.

再者,亦可如電鍍裝置8的變形例即圖7(b)所示的電鍍裝置16般,藉由電鍍液L在周壁面1q上回旋的形態,導引板16w於半徑方向,以在電鍍液排出管5c的外周面之間形成固定的間隙16z之方式而構成,並配置於電鍍室1m內。然而,為了把電鍍液L的回旋流a平順地引導至底面1p的導引板16w的功能發揮,期望的是,以回旋流a不會從間隙16z漏出的方式,不隨意使間隙16z的寬度變大,且流通電鍍液L的通路要構成儘可能的密閉。Further, as in the plating apparatus 16 shown in FIG. 7(b), which is a modification of the plating apparatus 8, the plating liquid L may be swirled on the peripheral wall surface 1q, and the guide plate 16w may be in the radial direction to A fixed gap 16z is formed between the outer peripheral surfaces of the plating solution discharge pipe 5c, and is disposed in the plating chamber 1m. However, in order to function to smoothly guide the swirling flow a of the plating solution L to the guide plate 16w of the bottom surface 1p, it is desirable that the width of the gap 16z is not arbitrarily made so that the swirling flow a does not leak from the gap 16z. The passage is made larger, and the passage through which the plating solution L flows is formed as close as possible.

圖8(a)、圖8(b)所示的電鍍裝置10是第2形態的電鍍裝置的另一例,作為導引機構10v,具有導引體10w。具有底面10z且由大致圓錐台形狀的非導電性材料構成的導引體10w具有沿著朝向底面1p縮徑的大致圓錐形狀的電鍍室1m的周壁面1q的外周面10x。上部接合於密閉蓋1L的導引體10w在中央部具有固定於密閉蓋1L且縱向延伸的電鍍液排出管5c,且外周面10x包圍著該電鍍液排出管5c。並且,導引體10w在水平方向上,以其外周面10x隔著固定尺寸g的間隙10y而與電鍍室1m的周壁面1q相對的方式配置於電鍍室1m之中。而且,在縱向上,由於設置球群9可在電鍍室1m的底面1p上進行回旋運動的區域,因此,導引體10w的底面10z以相對於電鍍室1m的底面1p而具有規定間隙的方式而配置。再者,本形態的電鍍裝置10中,以錫為主體而構成的陽極10o被設於導引體10w的底面10z上。The plating apparatus 10 shown in FIGS. 8(a) and 8(b) is another example of the plating apparatus of the second aspect, and has a guide body 10w as the guide mechanism 10v. The guide body 10w having the bottom surface 10z and being made of a non-conductive material having a substantially truncated conical shape has an outer peripheral surface 10x of the peripheral wall surface 1q of the plating chamber 1m having a substantially conical shape which is reduced in diameter toward the bottom surface 1p. The guide body 10w which is joined to the sealing lid 1L at the upper portion has a plating solution discharge pipe 5c which is fixed to the sealing lid 1L and extends in the longitudinal direction at the center portion, and the plating liquid discharge pipe 5c is surrounded by the outer peripheral surface 10x. Further, the guide body 10w is disposed in the plating chamber 1m in the horizontal direction so that the outer peripheral surface 10x faces the peripheral wall surface 1q of the plating chamber 1m via the gap 10y of the fixed dimension g. Further, in the longitudinal direction, since the ball group 9 is provided in a region where the swirling motion can be performed on the bottom surface 1p of the plating chamber 1m, the bottom surface 10z of the guide body 10w has a predetermined gap with respect to the bottom surface 1p of the plating chamber 1m. And configuration. Further, in the plating apparatus 10 of the present embodiment, the anode 10o mainly composed of tin is provided on the bottom surface 10z of the guide body 10w.

藉由將作為上述導引機構的導引體10w配置於電鍍室1m的中央部,可發揮與上述導引板8w同樣的作用。亦即,自電鍍液供給口1f所供給的電鍍液L在由導引體10w的外周面10x與電鍍室1m的周壁面1q所形成的間隙10y內,如虛線a所示般自上方朝向下方而回旋流下,並被導引至電鍍室1m的底面1p。回旋流下的電鍍液L由於是在由導引體10w的外周面10x與電鍍室1m的周壁面1q所圍成的相對較窄的間隙10y之中流動,因此不會因自電鍍液供給口1f所供給的電鍍液L或流動的電鍍液L的相互干涉而使回旋流下的電鍍液L產生紊流,而經整流化的電鍍液L將到達底面1p。進而,如圖示b2所示,即使由於自電鍍液排出管5c排出而作為上升流朝向電鍍液排出口5d的電鍍液L的流動b的一部分存在於電鍍液排出管5c之外時,其流動亦會被導引體10w的底面10z所阻擋,因此不會擾亂回旋流下的電鍍液L的流動a。其結果,球群在底面1p上的回旋運動穩定,從而可形成具有均勻的電鍍層的Cu芯球。再者,亦可將上述導引板8w裝入上述導引體10w與周壁面1q的間隙10y內。By arranging the guide body 10w as the above-described guide mechanism in the central portion of the plating chamber 1m, the same function as the above-described guide plate 8w can be exhibited. In other words, the plating solution L supplied from the plating solution supply port 1f is in the gap 10y formed by the outer peripheral surface 10x of the guide body 10w and the peripheral wall surface 1q of the plating chamber 1m, as shown by a broken line a, from the upper side toward the lower side. The swirling flow is carried out and guided to the bottom surface 1p of the plating chamber 1m. Since the plating solution L under the swirling flow flows in the relatively narrow gap 10y surrounded by the outer peripheral surface 10x of the guide body 10w and the peripheral wall surface 1q of the plating chamber 1m, it is not caused by the plating solution supply port 1f. The supplied plating solution L or the flowing plating solution L interfere with each other to cause turbulent flow of the plating solution L under the swirling flow, and the rectified plating solution L reaches the bottom surface 1p. Further, as shown in the diagram b2, even if a part of the flow b of the plating solution L which is the upward flow toward the plating solution discharge port 5d is discharged from the plating solution discharge pipe 5c, the flow is present outside the plating solution discharge pipe 5c. It is also blocked by the bottom surface 10z of the guide body 10w, so that the flow a of the plating solution L under the swirling flow is not disturbed. As a result, the swirling motion of the ball group on the bottom surface 1p is stabilized, so that a Cu core ball having a uniform plating layer can be formed. Further, the guide plate 8w may be incorporated in the gap 10y between the guide body 10w and the peripheral wall surface 1q.

而且,可將參照圖4(b)所說明的陽極部裝入具有上述導引體的電鍍裝置內。亦即,如圖8(b)的電鍍裝置21所示,由網狀的非導電性材料所構成的導引體21w兼作陽極部的導電性粒子收納容器,於其內部收納構成陽極的多個導電性粒子21o,且具有多個導電性粒子21o無法通過而電鍍液可稍許流通的微小開口。再者,導引體21w上所設的開口小於導電性粒子21o的大小而極小,因而電鍍液貫流時的阻力較大,因此電鍍液的上升流將在保持流速的狀態下通過導引體21w,而不會擾亂電鍍液的回旋流。Further, the anode portion described with reference to Fig. 4 (b) can be incorporated in a plating apparatus having the above-described guide body. In other words, as shown in the plating apparatus 21 of Fig. 8(b), the guide body 21w composed of a mesh-shaped non-conductive material also serves as a conductive particle storage container of the anode portion, and accommodates a plurality of anodes constituting the anode therein. The conductive particles 21o have a small opening in which the plurality of conductive particles 21o cannot pass and the plating solution can slightly flow. Further, the opening provided in the guide body 21w is smaller than the size of the conductive particles 21o, and the resistance during the flow of the plating solution is large, so that the upward flow of the plating solution will pass through the guide body 21w while maintaining the flow rate. Without disturbing the swirling flow of the plating solution.

[第3實施形態][Third embodiment]

以下,根據圖9(a)、圖9(b)、圖9(c)說明第3形態的電鍍裝置及其變形例。第3形態的電鍍裝置與第1形態的電鍍裝置1的不同之處在於,在與第1形態同樣地形成的電鍍室1m中具有整流機構。以下,對整流機構的各種形態進行說明。Hereinafter, a plating apparatus according to a third embodiment and a modification thereof will be described with reference to FIGS. 9(a), 9(b), and 9(c). The plating apparatus of the third embodiment is different from the plating apparatus 1 of the first embodiment in that a plating chamber 1m formed in the same manner as the first embodiment has a rectifying mechanism. Hereinafter, various aspects of the rectifying mechanism will be described.

圖9(a)的整流機構17v是由非導電性材料構成的板狀構件17w,該板狀構件17w將自電鍍液供給口1f所供給並沿著電鍍室1m的周壁面1q而回旋並流下的電鍍液L的流動整理成固定的方向而進行整流。形成有在順著沿電鍍室1m的周壁面1q而回旋流下的電鍍液L的流線的方向上延伸的螺旋的板狀構件17w,其上部17x配置於電鍍液供給口1f的下方,且下部17y與電鍍室1m的底面1p隔開規定的間隙而以外周面密接於周壁面1q之方式而配置。根據該板狀構件17w,以沿著電鍍室1m的周壁面1p而回旋的方式自電鍍液供給口1f所供給的電鍍液L,其回旋流下的流動藉由板狀構件17w而得到整流並被穩定地維持而到達底面1p,使接觸電鍍室1m的底面1p的球群按壓至該底面1p並作回旋運動。且,為了將對沿著周壁面1q的電鍍液L的旋回流進行整流的整流構件17w發揮功能,需使旋回流下的電鍍液L的流動不受到整流構件17w妨礙的方式來配置整流構件17w。也就是說,期望的是如圖所示,整流構件17w與電鍍液排出管5c,於半徑方向兩者之間是配置成形成有充分的間隙。The rectifying mechanism 17v of Fig. 9(a) is a plate-like member 17w made of a non-conductive material, which is supplied from the plating solution supply port 1f and swirls and flows down along the peripheral wall surface 1q of the plating chamber 1m. The flow of the plating solution L is rectified in a fixed direction. A spiral plate-like member 17w extending in the direction of the flow line of the plating solution L swirling down along the peripheral wall surface 1q of the plating chamber 1m is formed, and the upper portion 17x is disposed below the plating solution supply port 1f, and the lower portion 17y is disposed so as to be spaced apart from the bottom surface 1p of the plating chamber 1m by a predetermined gap and the outer peripheral surface is in close contact with the peripheral wall surface 1q. According to the plate-like member 17w, the plating liquid L supplied from the plating solution supply port 1f so as to swirl around the peripheral wall surface 1p of the plating chamber 1m is rectified by the plate-like member 17w. It is stably maintained and reaches the bottom surface 1p, and the ball group contacting the bottom surface 1p of the plating chamber 1m is pressed against the bottom surface 1p and is rotated. In order to function as the rectifying member 17w that rectifies the swirling reflow of the plating liquid L along the peripheral wall surface 1q, the rectifying member 17w is disposed so that the flow of the plating liquid L under the swirling flow is not hindered by the rectifying member 17w. That is, it is desirable that the rectifying member 17w and the plating solution discharge pipe 5c are arranged to have a sufficient gap formed therebetween in the radial direction as shown in the drawing.

再者,亦可如上述整流機構17v的變形例即圖9(b)所示,隔著間隙部18t而將多個葉片(fin)狀的板狀構件18q、18r、18s與上述板狀構件17w同樣地沿著電鍍液L的回旋流的流線而呈螺旋狀配置成一列,以構成整流機構18v。而且,亦可如圖9(c)所示般構成整流機構19v,即:將多個板狀構件19q~19r沿著電鍍液L的回旋流的流線而呈螺旋狀配置成一列,並且,在板狀構件19q~19r的下方,以填埋板狀構件19q~19r彼此的間隙部19u的方式而將板狀構件19s~19t呈鋸齒狀配置成一列,藉此具有二列板狀構件。Further, as shown in FIG. 9(b), which is a modification of the rectifying mechanism 17v, a plurality of fin-shaped plate-like members 18q, 18r, and 18s and the above-described plate-like member may be interposed between the gap portions 18t. Similarly to 17w, the 17w is spirally arranged in a line along the flow line of the swirling flow of the plating solution L to constitute the rectifying mechanism 18v. Further, as shown in FIG. 9(c), the rectifying mechanism 19v may be configured such that the plurality of plate-like members 19q to 19r are spirally arranged in a line along the flow line of the swirling flow of the plating solution L, and Below the plate-like members 19q to 19r, the plate-like members 19s to 19t are arranged in a zigzag shape so as to fill the gap portions 19u between the plate-like members 19q to 19r, thereby having two rows of plate-like members.

[第4實施形態][Fourth embodiment]

以下,根據圖10(a)、圖10(b)~圖12來說明第4形態的電鍍裝置及其變形例。第4形態的電鍍裝置與第1形態的電鍍裝置的不同之處在於,具有向電鍍室供給球群的供給機構及回收該球群的回收機構。以下,以供給機構及回收機構為中心來說明第4形態的電鍍裝置。再者,供給機構與回收機構亦可各自單獨地裝入電鍍裝置。Hereinafter, a plating apparatus according to a fourth embodiment and a modification thereof will be described with reference to FIGS. 10(a) and 10(b) to 12. The plating apparatus of the fourth aspect is different from the plating apparatus of the first aspect in that it has a supply mechanism that supplies a ball group to the plating chamber and a recovery mechanism that collects the ball group. Hereinafter, the plating apparatus of the fourth aspect will be described centering on the supply mechanism and the recovery mechanism. Further, the supply mechanism and the recovery mechanism may each be separately loaded into the plating apparatus.

首先,對供給機構進行說明。如圖10(a)的正面剖面圖以及自該圖10(a)的容器1k拆除密閉蓋1L後的狀態的平面圖即圖10(b)所示,本形態的供給機構11q具有:收納應供給至電鍍室1m的多個芯球92的收納部11r、以及各自的一端連接於收納部11r而另一端連接於電鍍槽1j的電鍍液流入管11u及球供給管11v。再者,在圖10(a)中,A-A線之上是觀察圖10(b)所示的電鍍槽11的中心線E上側的B箭頭圖,A-A線之下是觀察中心線E下側的C箭頭圖。First, the supply mechanism will be described. 10(a) is a front cross-sectional view and a plan view showing a state in which the sealing lid 1L is removed from the container 1k of FIG. 10(a), that is, FIG. 10(b), the supply mechanism 11q of the present embodiment has a storage supply. The accommodating portion 11r of the plurality of core balls 92 to the plating chamber 1m and the plating liquid inlet pipe 11u and the ball supply pipe 11v whose one end is connected to the accommodating portion 11r and the other end thereof is connected to the plating tank 1j. Further, in Fig. 10(a), above the AA line is a B arrow diagram on the upper side of the center line E of the plating tank 11 shown in Fig. 10(b), and below the AA line is the lower side of the observation center line E. C arrow diagram.

收納部11r由可收納多個芯球92的容器11s以及閉塞容器11s的上部開口的蓋11t所構成,藉由開閉蓋11t,將芯球92供給至容器11s。於該收納部11r的側壁上,經由閥(valve)11w而連接有電鍍液流入管11u的一端,進而,電鍍液流入管11u的另一端以其開口(電鍍液流入口)11y向電鍍室1m開口的方式而連接於電鍍槽1j。此處,電鍍液流入管11u被配置成,其軸心位於與電鍍液供給管1e為大致同一線上,亦即在電鍍槽1j的上部且沿著電鍍室1m的周壁面1q的切線方向,其電鍍液流入口11y迎入回旋的電鍍液的流動a。藉此,平面觀察時,電鍍液流入口11y與電鍍液供給口1f成為隔著電鍍室1m的中心線F而相對的狀態,因此,如圖示虛線a所示般自電鍍液供給口1f以沿著周壁面1q而回旋的方式所供給的電鍍液通過電鍍液流入口11y而流入電鍍液流入管11u。The accommodating portion 11r is composed of a container 11s that can accommodate the plurality of core balls 92 and a lid 11t that closes the upper portion of the closing container 11s, and the core ball 92 is supplied to the container 11s by the opening and closing cover 11t. One end of the plating solution inflow pipe 11u is connected to the side wall of the accommodating portion 11r via a valve 11w, and the other end of the plating solution inflow pipe 11u is opened (plating solution inlet) 11y to the plating chamber 1m. The opening is connected to the plating tank 1j. Here, the plating solution inflow pipe 11u is disposed such that its axial center is located substantially on the same line as the plating solution supply pipe 1e, that is, in the upper portion of the plating tank 1j and along the tangential direction of the peripheral wall surface 1q of the plating chamber 1m. The plating solution inflow port 11y welcomes the flow a of the swirling plating solution. Therefore, in the plan view, the plating solution inlet port 11y and the plating solution supply port 1f are opposed to each other via the center line F of the plating chamber 1m. Therefore, the plating solution supply port 1f is formed from the plating solution supply port 1f as indicated by a broken line a. The plating solution supplied so as to swirl along the peripheral wall surface 1q flows into the plating solution inflow pipe 11u through the plating solution inflow port 11y.

於收納部11r的底部,連接有球供給管11v的一端,球供給管11v的另一端以其開口(球供給口)11z向電鍍室1m的底部開口的方式而連接於電鍍槽1j。此處,如圖10(b)所示,球供給管11v被配置成,平面觀察時,在隔著電鍍室1m的中心線E而與電鍍液流入管11u相反的位置上,其軸心沿著電鍍室1m的切線方向,其球供給口11z沿著回旋的電鍍液的流動a。藉此,可順暢地乘著自電鍍液供給口1f所供給並沿著周壁面1q而流下且在底面1p上回旋流動的電鍍液的流動a來供給芯球92。再者,圖中,符號11x是用於將欲供給的芯球92保持於收納部11r中的間隔閥。該間隔閥11x是為了將芯球92自動供給至電鍍室1m而設的較佳構成,在手動供給芯球時未必需要該間隔閥11x。One end of the ball supply tube 11v is connected to the bottom of the accommodating portion 11r, and the other end of the ball supply tube 11v is connected to the plating tank 1j so that the opening (ball supply port) 11z opens to the bottom of the plating chamber 1m. Here, as shown in Fig. 10 (b), the ball supply tube 11v is disposed such that its axial edge is opposite to the plating solution inflow pipe 11u at the center line E of the plating chamber 1m when viewed in plan. In the tangential direction of the plating chamber 1 m, the ball supply port 11z is along the flow a of the swirling plating solution. Thereby, the core ball 92 can be supplied by the flow a of the plating liquid supplied from the plating solution supply port 1f and flowing down along the peripheral wall surface 1q and swirling on the bottom surface 1p. In the figure, reference numeral 11x is a space valve for holding the core ball 92 to be supplied in the accommodating portion 11r. The spacer valve 11x is preferably configured to automatically supply the core ball 92 to the plating chamber 1m, and the spacer valve 11x is not necessarily required when the core ball is manually supplied.

其次,對包含電鍍處理後的芯球91的球群9的回收機構11a進行說明。本形態的陰極11n作為回收機構11a的構成要素的一部分,可滑動地嵌合於容器1k的下部所形成的圓筒狀部11L的內面,在呈圓板狀的其外周面,設有用於防止電鍍液漏出的未圖示的O型環(ring)。並且,在圓筒狀部11L的內面,開設有將包含形成有電鍍層的芯球的球群予以回收的球回收管11b的一端的開口(球回收口)11c,球回收管11b的另一端連接於回收容器11e。再者,如圖10(b)所示,球回收管11b被配置成,平面觀察時,在隔著電鍍室1m的中心線F而與上述球供給管11v相反的位置上,其軸心沿著電鍍室1m的切線方向,其球回收口11c迎入回旋的電鍍液的流動a。Next, the recovery mechanism 11a including the ball group 9 of the core ball 91 after the plating treatment will be described. The cathode 11n of the present embodiment is slidably fitted to the inner surface of the cylindrical portion 11L formed in the lower portion of the container 1k as a part of the components of the recovery mechanism 11a, and is provided on the outer peripheral surface of the disk having a disk shape. An O-ring (not shown) that prevents the plating solution from leaking out. Further, on the inner surface of the cylindrical portion 11L, an opening (ball recovery port) 11c for the one end of the ball recovery tube 11b including the ball group in which the core ball of the plating layer is formed is opened, and the ball recovery tube 11b is further provided. One end is connected to the recovery container 11e. Further, as shown in Fig. 10 (b), the ball collecting tube 11b is disposed so as to be axially edged at a position opposite to the ball supply tube 11v across the center line F of the plating chamber 1m in plan view. In the tangential direction of the plating chamber 1 m, the ball recovery port 11c welcomes the flow a of the swirling plating solution.

此處,陰極11n藉由氣缸(air cylinder)等上下驅動部11d,沿著符號h所示的上下方向而在圓筒狀部11L中進行移動,在上升端的位置,其上表面11p(亦成為電鍍室1m的底面)接觸電鍍室1m的周壁面1q的下端緣,並且利用其外周面來關閉球回收口11c,而在下方端的位置打開球回收口11c。再者,本形態的電鍍裝置11中,如同閥一般使用陰極11n,藉由使陰極11n上下移動而開閉球回收口11c,但亦可如第1形態的電鍍裝置1般將回收機構設置成將陰極固定於電鍍室的底部,並經由閥來將球回收管連接於電鍍槽,並且使球回收口直接向電鍍室開口,從而藉由閥的開閉來回收芯球。此時,較佳為以不會妨礙在電鍍室的底面上回旋的芯球的運動的方式,而將球回收口配置於電鍍室的底面更上方。Here, the cathode 11n is moved in the cylindrical portion 11L in the vertical direction indicated by the symbol h by the vertical drive unit 11d such as an air cylinder, and the upper surface 11p is also at the position of the rising end. The bottom surface of the plating chamber 1m is in contact with the lower end edge of the peripheral wall surface 1q of the plating chamber 1m, and the ball recovery port 11c is closed by the outer peripheral surface thereof, and the ball recovery port 11c is opened at the lower end position. Further, in the plating apparatus 11 of the present embodiment, the cathode 11n is generally used as a valve, and the ball recovery port 11c is opened and closed by moving the cathode 11n up and down. However, the recovery mechanism may be provided as in the plating apparatus 1 of the first aspect. The cathode is fixed to the bottom of the plating chamber, and the ball recovery tube is connected to the plating tank via a valve, and the ball recovery port is directly opened to the plating chamber, thereby recovering the core ball by opening and closing the valve. At this time, it is preferable to arrange the ball recovery port above the bottom surface of the plating chamber so as not to hinder the movement of the core ball which is swirled on the bottom surface of the plating chamber.

參照圖11(a)、圖11(b)、圖11(c),對包含上述供給機構11q及回收機構11a的電鍍裝置11的動作進行說明。打開圖11(a)所示的收納部11r的蓋11t,將規定數量的芯球92供給至容器11s,隨後關閉蓋11t。此時,閥11w及間隔閥11x為關閉狀態。而且,藉由上下驅動部11d而上升的陰極11n處於上升端的位置,球回收口11c成為關閉狀態。The operation of the plating apparatus 11 including the supply mechanism 11q and the recovery mechanism 11a will be described with reference to Figs. 11(a), 11(b), and 11(c). The lid 11t of the accommodating portion 11r shown in Fig. 11(a) is opened, a predetermined number of core balls 92 are supplied to the container 11s, and then the lid 11t is closed. At this time, the valve 11w and the interval valve 11x are in a closed state. Further, the cathode 11n which is raised by the vertical driving portion 11d is at the rising end position, and the ball recovery port 11c is in the closed state.

繼而,使電鍍裝置11作動而自電鍍液供給口1f供給電鍍液L。當經過固定時間後電鍍室1m被電鍍液L充滿時,如圖11(a)所示,電鍍液L成為沿著電鍍室1m的周壁面1q而回旋,並且沿著周壁面1q的傾斜而朝向底面11p呈螺旋狀流下的穩定的回旋流a。Then, the plating apparatus 11 is actuated to supply the plating solution L from the plating solution supply port 1f. When the plating chamber 1m is filled with the plating solution L after a fixed period of time, as shown in Fig. 11 (a), the plating solution L is swirled along the peripheral wall surface 1q of the plating chamber 1m, and is oriented along the inclination of the peripheral wall surface 1q. The bottom surface 11p has a stable swirling flow a flowing downward in a spiral shape.

在供給電鍍液L並經過固定時間而電鍍室1m內的電鍍液L的流動狀態穩定後,電鍍裝置11打開閥11w,使圖11(b)中如箭頭e般回旋流動的電鍍液L的一部分自電鍍液流入管11u通過電鍍液流入口11y而流入收納部11r,並且打開間隔閥11x。於是,收納部11r中收納的芯球92藉由流入的電鍍液L而自收納部11r被擠出,與電鍍液L一同在球供給管11v的管路中流動,並如箭頭f般自球供給口11z排出而供給至電鍍室1m。電鍍裝置11在所有芯球92被供給至電鍍室1m之後,關閉閥11w及間隔閥11x。此處,球供給管11v是如上所述般配置著,因此自球供給口11z所供給的芯球92將乘著電鍍液L的回旋流a,隨後在電鍍室1m的底面11p上順暢地回旋運動並得到電鍍處理。如此,在將電鍍液L供給至電鍍室1m後經過固定時間,而電鍍室內的電鍍液的回旋流動穩定化之後,將芯球92供給至電鍍室1m,因此芯球91自電鍍室1m流出的情況較少,能夠以較高的良率來對芯球91進行電鍍。After the plating solution L is supplied and the flow state of the plating solution L in the plating chamber 1m is stabilized for a fixed period of time, the plating apparatus 11 opens the valve 11w to partially swirl the plating liquid L as shown by the arrow e in Fig. 11(b). The plating solution inflow pipe 11u flows into the accommodating portion 11r through the plating liquid inflow port 11y, and opens the interval valve 11x. Then, the core ball 92 accommodated in the accommodating portion 11r is extruded from the accommodating portion 11r by the plating solution L that has flowed in, flows through the tube of the ball supply tube 11v together with the plating solution L, and is self-balling as the arrow f The supply port 11z is discharged and supplied to the plating chamber 1m. The plating apparatus 11 closes the valve 11w and the interval valve 11x after all the core balls 92 are supplied to the plating chamber 1m. Here, since the ball supply tube 11v is disposed as described above, the core ball 92 supplied from the ball supply port 11z is multiplied by the swirling flow a of the plating solution L, and then smoothly swirled on the bottom surface 11p of the plating chamber 1m. Exercise and get electroplated. In this manner, after the plating solution L is supplied to the plating chamber 1m for a fixed period of time, and the swirling flow of the plating solution in the plating chamber is stabilized, the core ball 92 is supplied to the plating chamber 1m, so that the core ball 91 flows out from the plating chamber 1m. The case is small, and the core ball 91 can be plated with a high yield.

再者,當手動供給芯球92時,不在球供給管11v的路徑中設置間隔閥11x,於電鍍液L的流動狀態穩定化之後,打開閥11w,利用電鍍液流入管11u、收納部11r及球供給管11v的路徑而使電鍍液L流通之後,再將規定數量的芯球92供給至收納部11r即可。When the core ball 92 is manually supplied, the interval valve 11x is not provided in the path of the ball supply tube 11v, and after the flow state of the plating solution L is stabilized, the valve 11w is opened, and the plating liquid inflow pipe 11u and the storage portion 11r are used. After the plating liquid L flows through the path of the ball supply tube 11v, a predetermined number of core balls 92 may be supplied to the accommodating portion 11r.

繼而,如圖11(c)所示,當電鍍裝置11藉由上下驅動部11d而使陰極11n下降至下降端為止並打開球回收口11c時,包含形成有電鍍層的芯球91的球群9通過球回收口11c而如箭頭i所示般流入球回收管11b,隨後被回收至回收容器11e內。再者,若在電鍍液排出管5c內設置閥,並與陰極11n的下降一同收緊該閥,則電鍍液L的多數部分將通過球回收管11b而排出,因此可更順暢地回收球群9。Then, as shown in FIG. 11(c), when the plating apparatus 11 lowers the cathode 11n to the lower end by the vertical driving portion 11d and opens the ball recovery port 11c, the ball group including the core ball 91 on which the plating layer is formed is formed. 9 passes through the ball recovery port 11c and flows into the ball recovery pipe 11b as indicated by an arrow i, and is then recovered into the recovery container 11e. Further, when a valve is provided in the plating solution discharge pipe 5c and the valve is tightened together with the lowering of the cathode 11n, most of the plating solution L is discharged through the ball recovery pipe 11b, so that the ball group can be more smoothly recovered. 9.

圖12所示的電鍍裝置12是第4形態的電鍍裝置的另一例,具有在電鍍液供給管1e的路徑上所設的供給機構12q。亦即,呈如下構成:供給機構12q的電鍍液流入管11u的一端連接於電鍍液供給管1e的上游側,球供給管11v的一端連接於電鍍液供給管1e的下游側,該些管的另一端經由閥11w及間隔閥11x而連接於收納部11r。根據該供給機構12q,當在電鍍液L於電鍍室1m內的流動狀態穩定後打開閥11w及間隔閥11x時,於電鍍液供給管1e內流動的電鍍液L的一部分通過電鍍液流入管11u而流入收納部11r。於是,收納部11r中收納的芯球92藉由流入的電鍍液L而被擠出,通過球供給管11v而流入電鍍液供給管1e,並與電鍍液L一同自電鍍液供給口1f供給至電鍍室1m。再者,為了在供給機構12q中使電鍍液順暢地流通,較為理想的是,加粗電鍍液流入管11u所連接的電鍍液供給管1e的上游側的內徑,並使球供給管11v所連接的下游側的內徑細於上游側。進而,為了使芯球92不會滯留於供給機構12q中而流入電鍍液供給管1e,較為理想的是使收納部11r的底面與電鍍液流入管11u及球供給管11v的底面之間不存在段差。The plating apparatus 12 shown in FIG. 12 is another example of the plating apparatus of the fourth aspect, and has a supply mechanism 12q provided on the path of the plating solution supply pipe 1e. In other words, one end of the plating solution inflow pipe 11u of the supply mechanism 12q is connected to the upstream side of the plating solution supply pipe 1e, and one end of the ball supply pipe 11v is connected to the downstream side of the plating solution supply pipe 1e, and the tubes are The other end is connected to the accommodating portion 11r via a valve 11w and a space valve 11x. According to the supply mechanism 12q, when the valve 11w and the space valve 11x are opened after the flow state of the plating solution L in the plating chamber 1m is stabilized, a part of the plating solution L flowing in the plating solution supply pipe 1e passes through the plating solution into the pipe 11u. The flow enters the storage unit 11r. Then, the core ball 92 accommodated in the accommodating portion 11r is extruded by the inflowing plating solution L, flows into the plating solution supply pipe 1e through the ball supply tube 11v, and is supplied from the plating solution supply port 1f together with the plating solution L. The plating chamber is 1m. Further, in order to smoothly flow the plating solution in the supply mechanism 12q, it is preferable to thicken the inner diameter of the plating solution into the upstream side of the plating solution supply pipe 1e to which the tube 11u is connected, and to supply the ball supply tube 11v. The inner diameter of the downstream side of the connection is thinner than the upstream side. Further, in order to prevent the core ball 92 from remaining in the supply mechanism 12q and flowing into the plating solution supply pipe 1e, it is preferable that the bottom surface of the accommodating portion 11r does not exist between the plating liquid inflow pipe 11u and the bottom surface of the ball supply pipe 11v. The difference is the segment.

[第5實施形態][Fifth Embodiment]

以下,參照圖13(a)、圖13(b)、圖13(c)、圖13(d)來說明第5形態的電鍍裝置。再者,圖13(a)是表示第5形態的一例的電鍍裝置的概略構成的正面剖面圖,圖13(b)是圖13(a)的D箭頭圖,圖13(c)是表示第5形態的電鍍裝置的另一例的概略構成的正面剖面圖,圖13(d)是圖13(c)的E箭頭圖。Hereinafter, a plating apparatus according to a fifth aspect will be described with reference to FIGS. 13(a), 13(b), 13(c), and 13(d). Fig. 13 (a) is a front cross-sectional view showing a schematic configuration of a plating apparatus as an example of a fifth embodiment, wherein Fig. 13 (b) is a D arrow diagram of Fig. 13 (a), and Fig. 13 (c) is a A front cross-sectional view showing a schematic configuration of another example of the plating apparatus of the fifth embodiment, and (d) of FIG. 13 is an E-arrow diagram of FIG. 13(c).

上述第1~第4形態的電鍍裝置中,對具有電鍍室、電鍍液供給管及沿著電鍍室的軸心而配置的電鍍液排出管的各構成要素的電鍍裝置進行了說明,但本發明並不限定於該些理想形態,第5形態的電鍍裝置亦可實現,上述電鍍室具備圓形狀的底面作為芯球可接觸並轉繞的電鍍室的底面以及以朝向底面而縮徑的方式立設於底面周緣的大致圓錐台形狀的周壁面,上述電鍍液供給管將軸心水平配置成,電鍍液供給口沿著剖面圓形狀的電鍍室的切線方向而開口。In the plating apparatus according to the first to fourth aspects, the plating apparatus having the plating chamber, the plating solution supply pipe, and the respective components of the plating liquid discharge pipe disposed along the axis of the plating chamber has been described. The plating apparatus of the fifth aspect is not limited to the preferred embodiment, and the plating chamber has a circular bottom surface as a bottom surface of the plating chamber in which the core ball can be contacted and wound, and the diameter is reduced toward the bottom surface. The plating liquid supply pipe is disposed horizontally on the substantially truncated conical shape of the periphery of the bottom surface, and the plating solution supply port is opened in a tangential direction of the plating chamber having a circular cross section.

第5形態的一例的電鍍裝置13如圖13(b)所示,具有大致橢圓形狀的底面13p作為芯球91可轉繞的底面,且以立設於底面13p的周緣的周壁面13q在縱向上呈同一剖面,亦即呈直管狀的方式而形成著電鍍室13m。進而,向電鍍室13m供給電鍍液L的電鍍液供給管13e為了產生沿著周壁面13q而回旋流下的電鍍液L的流動,而以其軸心朝向下方的狀態連接於電鍍槽1j。再者,較佳為,經由可自如地設定對周壁面13q的安裝角度的接頭等來將電鍍液供給管13e連接於電鍍槽1j,其原因在於,如此便可根據欲進行電鍍處理的芯球的大小及數量等來適當設定電鍍液L回旋流下的角度。而且,為了使電鍍液L的上升流b順暢地自電鍍室13m排出,自電鍍室13m排出電鍍液L的電鍍液排出管1c較佳為與第1形態的電鍍裝置1同樣地設於密閉蓋1L的中央部,但電鍍液排出管的配置並不限定於此,亦可如圖示虛線所示的電鍍液排出管13c般,設於密閉蓋1L的外周而使自電鍍室13m溢出(overflow)的電鍍液L予以排出。As shown in Fig. 13 (b), the plating apparatus 13 of the fifth embodiment has a substantially elliptical bottom surface 13p as a bottom surface on which the core ball 91 can be wound, and a peripheral wall surface 13q which is erected on the periphery of the bottom surface 13p in the longitudinal direction. The plating chamber 13m is formed in the same cross section, that is, in a straight tubular shape. Further, the plating solution supply pipe 13e that supplies the plating solution L to the plating chamber 13m is connected to the plating tank 1j with its axial center facing downward in order to generate a flow of the plating solution L that swirls down along the peripheral wall surface 13q. In addition, it is preferable that the plating solution supply pipe 13e is connected to the plating tank 1j via a joint or the like which can freely set the attachment angle to the peripheral wall surface 13q, because the core ball to be subjected to the plating treatment can be thus obtained. The size and number of the plating etc. are appropriately set to the angle under which the plating liquid L swirls. In order to smoothly discharge the upward flow b of the plating solution L from the plating chamber 13m, the plating solution discharge pipe 1c for discharging the plating solution L from the plating chamber 13m is preferably provided in the sealing cover in the same manner as the plating device 1 of the first embodiment. In the central portion of the 1L, the arrangement of the plating solution discharge pipe is not limited thereto, and may be provided on the outer periphery of the sealing lid 1L to overflow the plating chamber 13m as in the plating liquid discharge pipe 13c shown by a broken line (overflow) The plating solution L is discharged.

對上述電鍍裝置13的動作進行說明。將球群9載置於電鍍室13m的底面13p上,隨後關閉密閉蓋1L而使電鍍室13m成為密閉空間,並使電鍍裝置13作動。電鍍裝置13通過電鍍液供給管13e向電鍍室13m供給電鍍液L。當電鍍室13m被電鍍液L充滿時,自以上述方式配置的電鍍液供給管13e所供給的電鍍液L成為沿著電鍍室13m的周壁面13q而呈螺旋狀回旋流下的回旋流a。回旋流下並到達底面13p的電鍍液L使接觸底面13p的球群9按壓至該底面13p並作回旋運動,使芯球91的表面形成電鍍層。與上述第1形態的電鍍裝置1同樣地,接觸電鍍室13m的底面13p並作回旋運動的芯球91在底面13p上轉動,因此芯球91彼此難以附著,從而防止芯球91的凝聚,且藉由轉動而使芯球91的表面接觸底面13p的機會變得均等,因此可形成均勻的厚度的電鍍層。由於供給至電鍍室13m的電鍍液L自電鍍液排出管1c被排出,因此始終有新鮮的電鍍液L被供給至電鍍室13m,從而可形成均勻的厚度的電鍍層。The operation of the plating apparatus 13 described above will be described. The ball group 9 is placed on the bottom surface 13p of the plating chamber 13m, and then the sealing lid 1L is closed to make the plating chamber 13m a sealed space, and the plating apparatus 13 is actuated. The plating apparatus 13 supplies the plating solution L to the plating chamber 13m through the plating solution supply pipe 13e. When the plating chamber 13m is filled with the plating solution L, the plating solution L supplied from the plating solution supply pipe 13e arranged as described above becomes the swirling flow a which spirally flows down along the peripheral wall surface 13q of the plating chamber 13m. The plating solution L which swirls down and reaches the bottom surface 13p presses the ball group 9 contacting the bottom surface 13p to the bottom surface 13p and performs a swirling motion to form a plating layer on the surface of the core ball 91. Similarly to the plating apparatus 1 of the first embodiment, the core ball 91 that is in contact with the bottom surface 13p of the plating chamber 13m and rotates on the bottom surface 13p is rotated, so that the core balls 91 are hard to adhere to each other, thereby preventing aggregation of the core ball 91, and The chance of the surface of the core ball 91 contacting the bottom surface 13p by rotation is made uniform, so that a plating layer having a uniform thickness can be formed. Since the plating solution L supplied to the plating chamber 13m is discharged from the plating solution discharge pipe 1c, fresh plating solution L is always supplied to the plating chamber 13m, so that a plating layer having a uniform thickness can be formed.

圖13(c)、圖13(d)所示的第5形態的另一例的電鍍裝置20具有電鍍室20m,且以電鍍室20m的剖面在縱向上相同的方式形成電鍍室20m,該電鍍室20m具有圓環狀的底面20p作為芯球91可轉繞的底面、沿著底面20p的外周緣而立設的外周壁面20q、以及沿著內周緣而立設的內周壁面20x。在該電鍍裝置20中,基本上亦以與上述電鍍裝置13同樣的動作而於芯球91上形成電鍍層,但構成底面20p的陰極20n自身形成為圓環狀,因此可發揮與參照圖2(b)、圖2(c)所說明的陰極構造同樣地提高電鍍效率的作用效果。The plating apparatus 20 of another example of the fifth aspect shown in FIGS. 13(c) and 13(d) has a plating chamber 20m, and a plating chamber 20m is formed in the same manner in the longitudinal direction in the cross section of the plating chamber 20m. The bottom surface 20p having an annular shape of 20 m serves as a bottom surface that can be wound by the core ball 91, an outer peripheral wall surface 20q that stands up along the outer peripheral edge of the bottom surface 20p, and an inner peripheral wall surface 20x that is erected along the inner peripheral edge. In the plating apparatus 20, a plating layer is formed on the core ball 91 substantially in the same manner as the plating apparatus 13, but the cathode 20n constituting the bottom surface 20p itself is formed in an annular shape, so that it can be used as shown in FIG. (b) The cathode structure described in Fig. 2(c) similarly improves the effect of plating efficiency.

[第6實施形態][Sixth embodiment]

以下,根據圖15(a)、圖15(b)~圖16(a)、圖16(b)來說明第6形態的電鍍裝置及其變形例。如圖15(a)、圖15(b)~圖16(a)、圖16(b)所示,在第6形態的電鍍裝置23~26中,參照圖2(b)、圖2(c)所說明的具有第2陰極2x的陰極2n是配置在容器1k的底部。與第1形態的電鍍裝置的不同之處在於,陽極23o~26o是對與此周壁面1q構成同一面的第2陰極2x的內周面2z(芯球91所接觸的接觸面)呈一定的間隙c的方式配置在外周面(表面)23v~26v。以下,按照電鍍裝置23~26的順序來說明陽極23o~26o的構造。Hereinafter, a plating apparatus according to a sixth aspect and a modification thereof will be described with reference to FIGS. 15(a), 15(b) to 16(a), and 16(b). As shown in Fig. 15 (a), Fig. 15 (b) to Fig. 16 (a), and Fig. 16 (b), in the plating apparatuses 23 to 26 of the sixth embodiment, reference is made to Fig. 2 (b) and Fig. 2 (c). The cathode 2n having the second cathode 2x described above is disposed at the bottom of the vessel 1k. The difference from the plating apparatus of the first aspect is that the anodes 23o to 26o are constant for the inner peripheral surface 2z of the second cathode 2x (the contact surface contacted by the core ball 91) which is flush with the peripheral wall surface 1q. The gap c is arranged on the outer peripheral surface (surface) 23v to 26v. Hereinafter, the structures of the anodes 23o to 26o will be described in the order of the plating apparatuses 23 to 26.

如圖15(a)的電鍍裝置23所示,以錫為主體形成的陽極23o,是以豎起軸芯的姿勢從容器1k的底面1p的方向,構成可插入電鍍液排出口1d的大小的略圓柱形狀。陽極23o的直徑,是小到不會阻礙從電鍍液排出管1c而來的電鍍液的程度,且比電鍍液排出口1d的直徑還要充份地小。圖中符號23t是定位陽極23o的上下方向的位置,且同時供電給陽極23o的給電電極。由具有略平坦上面23x的略圖柱狀的鈦所形成的給電用電極23t是嵌入到配置在容器1k的底面中央部的裝著構件23s的中央,並連接到未圖示的直流電源電路的正極。且嵌入了給電用電極23t的裝著構件23s,是由與連接到負極的陰極2n、及給電電極23t呈絕緣的樹脂等的非導電材料所構成,在其上面,與第1陰極2y的上面位於同一平面上的方式固定在容器1k的底面。在此,陽極23o是呈軸芯豎立的狀態,其底面23w則是在與比容器1k的底面1p僅只高出距離d而配置的給電用電極23t的上面23x連接的狀態下配置著。藉由這樣的配置方式,可以把上下方向中的陽極23o予以定位,且陽極23o的下部的外周面23v則呈與第2陰極2x的內周面2z接近且對向的狀態。再者,陽極23o雖不需配置在比容器1k的底面1p只僅高出距離d,然而較佳的是,當第1陰極2y與陽極23o接近的場合仍可抑制過度的電流流過兩者之間,如此則可謀求各球上所形成的電鍍層的品質均一化。As shown in the plating apparatus 23 of Fig. 15 (a), the anode 23o formed mainly of tin has a size in which the plating core discharge port 1d is inserted from the bottom surface 1p of the container 1k in a posture in which the core is erected. Slightly cylindrical shape. The diameter of the anode 23o is so small that it does not hinder the plating solution from the plating solution discharge pipe 1c, and is sufficiently smaller than the diameter of the plating solution discharge port 1d. The symbol 23t in the figure is a position in which the anode 23o is positioned in the up and down direction, and is simultaneously supplied to the feeding electrode of the anode 23o. The power supply electrode 23t formed of titanium having a slightly columnar shape of a slightly flat upper surface 23x is fitted into the center of the attachment member 23s disposed at the central portion of the bottom surface of the container 1k, and is connected to the positive electrode of a DC power supply circuit (not shown). . The mounting member 23s in which the power supply electrode 23t is embedded is composed of a non-conductive material such as a resin insulated from the cathode 2n and the feeding electrode 23t connected to the negative electrode, and the upper surface of the first cathode 2y is formed thereon. The manner of being located on the same plane is fixed to the bottom surface of the container 1k. Here, the anode 23o is in a state in which the axis core is erected, and the bottom surface 23w is disposed in a state of being connected to the upper surface 23x of the power supply electrode 23t disposed only at a distance d higher than the bottom surface 1p of the container 1k. According to such an arrangement, the anode 23o in the vertical direction can be positioned, and the outer peripheral surface 23v of the lower portion of the anode 23o is in a state of being close to and facing the inner peripheral surface 2z of the second cathode 2x. Further, although the anode 23o does not need to be disposed only at a distance d higher than the bottom surface 1p of the container 1k, it is preferable to suppress excessive current flow when the first cathode 2y and the anode 23o are close to each other. In this way, the quality of the plating layer formed on each ball can be made uniform.

圖15(a)中的符號23r是保持構件,在水平面中把陽極23o定位在電鍍室1m的中央,且具有多個開口,不讓芯球91通過但能夠讓電鍍液流通。作為浸透膜的保持構件23r,是由樹脂等非導電材料構成不讓芯球91通過網眼的網狀。具有讓陽極23o在軸方向可插通的貫通孔的略圓筒狀的保持構件23r的大小是,以軸芯豎立的姿勢可從容器1k的底面1p的方向插入電鍍液排出口1d的大小,且其徑是不妨礙電鍍液從電鍍液排出管1c的排出且又比電鍍液排出口1d的直徑更充份地小。再者,保持構件23r是以其軸芯在水平面內與電鍍室1m的軸心約略一致的方式,其上部插入到電鍍液排出口1d中的狀態下被配置,由配置在電鍍液排出口1d的內部的支持構件23u所支持。這個保持構件23r的底部,被嵌入到在裝著構件23s的上面以圍住的給電用電極23t的方式所形成的圓環溝,且對於在底面23p旋廻的電鍍液的流動呈不動的方式被固定著。把陽極23o以軸方向插入這樣配置的保持構件23u的貫通孔,藉此,固定陽極23o的水平面的位置。結果是,利用上述給電用電極23t定位上下方向的位置,並在靠近配置的陽極23o的外周面23v與第1陰極2x的內周面2z之間沿全周形成一定的間隙c,使流過兩面之間的電流的密度呈均一。且,本形態的保持構件23r,從電鍍液的液流a、b呈固定強度的觀念看來,雖利用電鍍液排出口1d所設的支持構件23u及裝著構件23s使上下固定,但若保持構件23r的底部僅固定就能夠使強度充份的場合,也可以省略支持構件23u,而僅以裝著構件23s來固定保持構件23r的底部。The symbol 23r in Fig. 15(a) is a holding member, and the anode 23o is positioned in the center of the plating chamber 1m in the horizontal plane, and has a plurality of openings, so that the core ball 91 is not allowed to pass but the plating liquid can be circulated. The holding member 23r as the permeation film is formed of a non-conductive material such as a resin and does not allow the core ball 91 to pass through the mesh. The size of the substantially cylindrical holding member 23r having the through hole through which the anode 23o can be inserted in the axial direction is such that the plating liquid discharge port 1d can be inserted from the direction of the bottom surface 1p of the container 1k in a posture in which the axis core is erected. Further, the diameter does not hinder the discharge of the plating solution from the plating solution discharge pipe 1c and is sufficiently smaller than the diameter of the plating solution discharge port 1d. Further, the holding member 23r is disposed such that its axial center substantially coincides with the axial center of the plating chamber 1m in the horizontal plane, and the upper portion thereof is inserted into the plating solution discharge port 1d, and is disposed at the plating solution discharge port 1d. The internal support member 23u is supported. The bottom of the holding member 23r is fitted into the annular groove formed so as to surround the power supply electrode 23t on the upper surface of the mounting member 23s, and the flow of the plating liquid that is rotated on the bottom surface 23p is immobile. Fixed. The anode 23o is inserted into the through hole of the holding member 23u thus arranged in the axial direction, whereby the position of the horizontal plane of the anode 23o is fixed. As a result, the position of the vertical direction is set by the above-described power supply electrode 23t, and a predetermined gap c is formed along the entire circumference between the outer peripheral surface 23v of the anode 23o and the inner peripheral surface 2z of the first cathode 2x. The density of the current between the two faces is uniform. In addition, the holding member 23r of the present embodiment is fixed to the upper and lower sides by the support member 23u and the attachment member 23s provided by the plating solution discharge port 1d from the viewpoint of the fixing strength of the liquid streams a and b of the plating solution. When the bottom of the holding member 23r is fixed only to make the strength sufficient, the support member 23u may be omitted, and the bottom of the holding member 23r may be fixed only by the attachment member 23s.

在此,保持構件23r具有不讓芯球91通過但可讓電鍍液流通的浸透膜的功能,利用電鍍液於底面1p進行旋迴運動的芯球91就算接近陽極23o也可防止它接觸到陽極23o。然而,只利用如圖6(a)~圖6(b)所說明的底面6p或7p的周緣部來限定球群9的旋迴運動的電鍍裝置中,如果當旋迴運動的芯球91接觸到陽極的可能性低的場合,保持構件23r就不是必要的。在此場合,水平面內的陽極23o的定位用的陽極23o的底部也可以固定在容器1k。Here, the holding member 23r has a function of allowing the core ball 91 to pass but allowing the plating solution to flow, and the core ball 91 which is rotated by the plating solution on the bottom surface 1p can prevent it from coming into contact with the anode even if it is close to the anode 23o. 23o. However, only the peripheral portion of the bottom surface 6p or 7p as illustrated in Figs. 6(a) to 6(b) is used to define the reciprocating motion of the ball group 9, if the core ball 91 is in contact with the revolving motion. When the possibility of the anode is low, the holding member 23r is not necessary. In this case, the bottom of the anode 23o for positioning the anode 23o in the horizontal plane may be fixed to the container 1k.

再,如圖15(b)的電鍍裝置24所示,陽極24o的外周面24v,期望的是與第2陰極2x的內周面2z在同一角度下構成縮徑至下方的圓錐狀。以此方式,兩面之間的間隙c在上下方向呈一定,所以電流密度在面全體都是均一的。Further, as shown in the plating apparatus 24 of Fig. 15 (b), the outer peripheral surface 24v of the anode 24o is desirably formed into a conical shape having a reduced diameter to the lower side at the same angle as the inner peripheral surface 2z of the second cathode 2x. In this way, the gap c between the both faces is constant in the up and down direction, so the current density is uniform throughout the entire surface.

具有上述構成的陽極結構的第6實施形態的電鍍裝置23的動作,基本上與上述第1~第5實施形態相同因而省略。依照本電鍍裝置23,不會防礙電鍍液L的流動a、b,且可使陽極23o與陰極2n之間的電阻下降,且可抑制電鍍液L的液溫的上昇或劣化,因而可形成空隙(void)等的缺陷少的良質電鍍層。也就是說,為了使陽極與陰極之間的電阻下降,需使陽極與陰極的各作用面對向,同時把兩作用面儘可能地接近配置。在此,參照圖1所說明的電鍍裝置1的場合,當為了使陽極1o與陰極1n接近,而相對於容器1k的底部所配置的陰極1n把陽極1o的位置配置在下方時,於電鍍室1m的周壁面1q旋迴流下的電鍍液的流動a便有可能受到陽極1o的阻礙。再參照圖5說明的電鍍裝置5的場合,當為了使電鍍液排出管5c的先端外周面所配置的陽極5o與陰極1n相接近,而以電鍍液排出口5d接近底面1p的方式,使電鍍液排出管5c往更下方伸出時,於電鍍室1m的底面1p之上進行旋迴運動的芯球91有可能會隨著朝向電鍍液排出管5c的電鍍液的上昇流b從電鍍室1m被排出。這些問題,雖可利用陽極1o、5o及陰極1n的形狀或配置位置等的最佳化來獲得解決,但是仍需要視欲處理的芯球的規格(尺寸、質量)或處理量等的其他條件而作各別的最佳化。The operation of the plating apparatus 23 of the sixth embodiment having the anode structure having the above-described configuration is basically the same as that of the above-described first to fifth embodiments, and thus will not be described. According to the plating apparatus 23, the flow a and b of the plating solution L are not hindered, and the electric resistance between the anode 23o and the cathode 2n can be lowered, and the liquid temperature of the plating solution L can be suppressed from rising or deteriorating, so that it can be formed. A good quality plating layer having few defects such as voids. That is to say, in order to lower the electric resistance between the anode and the cathode, it is necessary to face the respective roles of the anode and the cathode while arranging the two acting surfaces as close as possible. Here, in the case of the plating apparatus 1 described with reference to Fig. 1, when the anode 1o and the cathode 1n are brought close to each other, and the cathode 1n disposed at the bottom of the container 1k is disposed below the anode 1o, the plating chamber is placed. The flow a of the plating solution under the 1 m circumferential wall surface 1q may be hindered by the anode 1o. In the case of the plating apparatus 5 described with reference to Fig. 5, the anode 5o disposed on the outer peripheral surface of the tip end of the plating solution discharge pipe 5c is close to the cathode 1n, and the plating liquid discharge port 5d is close to the bottom surface 1p. When the liquid discharge pipe 5c protrudes further downward, the core ball 91 which is rotated over the bottom surface 1p of the plating chamber 1m may flow upward from the plating chamber 1m with the plating liquid b toward the plating liquid discharge pipe 5c. It is discharged. These problems can be solved by optimizing the shape or arrangement position of the anodes 1o, 5o, and the cathode 1n, but still require other conditions such as the specification (size, quality) or throughput of the core ball to be processed. And for each individual optimization.

另一方,依照圖15(a)、圖15(b)的第6實施形態的電鍍裝置,相對於以形成與容器1k的周壁面1q同一的內周面2z的方式配置在容器1k的基端部的第2陰極2x,如上述方式配置陽極23o,並使陽極23o的外周面23v與第2陰極2x的內周面2z對向,在兩面之間形成間隙,所以不會妨礙沿著周壁面1q旋迴流下的電鍍液L的液流a。又陽極23o,沿著朝向電鍍液排出管1c上昇的電鍍液L的液流b軸芯是呈豎立配置,所以不會阻礙該上昇液流b,使電鍍室1m中的電鍍液L一邊循環,一邊在底面1p之上讓芯球91旋迴運動,可以平順地進行電鍍處理。第6實施形態的電鍍裝置,在不會阻礙電鍍液的流動的狀態下,使陽極23o與陰極2n呈接近的構造,所以可使兩者間的電阻下降,因而可形成非常良質的電鍍層。In the other hand, the plating apparatus according to the sixth embodiment of FIGS. 15(a) and 15(b) is disposed at the base end of the container 1k so as to form the inner peripheral surface 2z which is the same as the peripheral wall surface 1q of the container 1k. In the second cathode 2x of the portion, the anode 23o is disposed as described above, and the outer peripheral surface 23v of the anode 23o faces the inner peripheral surface 2z of the second cathode 2x, and a gap is formed between the both surfaces, so that the peripheral wall surface is not hindered. 1q is a liquid flow a of the plating solution L under reflux. Further, the anode 23o is disposed so as to be vertically aligned along the liquid flow b-axis of the plating solution L that rises toward the plating solution discharge pipe 1c, so that the plating liquid L in the plating chamber 1m is circulated without blocking the rising liquid flow b. The core ball 91 is rotated back and forth on the bottom surface 1p, and the plating treatment can be smoothly performed. In the plating apparatus of the sixth embodiment, since the anode 23o and the cathode 2n are brought into close contact with each other without hindering the flow of the plating solution, the electric resistance between the two can be lowered, so that a very good plating layer can be formed.

關於上述電鍍裝置23的變形例將參照圖16(a)、圖16(b)來說明。圖16(a)的電鍍裝置25與上述的電鍍裝置23的不同點在於,具有陽極25o,此陽極25o是以先端部朝下的姿勢在電鍍液排出管1c內從上方延伸的略圓柱狀,此先端部具有應該與第2陰極2x的內周面2z呈一定間隙c相對的外周面25v。此外,不同點在於,電鍍裝置25還具有未圖示的供給裝置,此供給裝置會追蹤陽極25o的外周面25v隨時間經過的均一消耗量,而把陽極25o往下方(箭頭e)運送,此消耗是因隨著電鍍處理的進行,構成陽極25o的鍚被吸入到電鍍液L所產生的。且,在陽極25o的外周面25v,與參照圖15(b)所說明的陽極24o的外周面24v同樣的,是與第2陰極2x的內周面2z在同一角度下往下方縮徑的圓錐狀。陽極25o是以具有外周面25v的先端部在軸方向往保持構件23r的貫通孔插入,以此方式在水平方向被定位,且追蹤在電鍍處理過程中外周面25v隨著時間經過而被均一消耗的量,維持著其先端與容器1k的底面1p之間的距離d的方式,使兩者不會衝突的狀態,由供給裝置進行控制,以定位上下方向的位置。這樣構成的電鍍裝置25,特別適於處理多量的芯球91、形成厚鍍層而處理時間長且無法忽略陽極25o的消耗的場合等。A modification of the plating apparatus 23 described above will be described with reference to FIGS. 16(a) and 16(b). The plating apparatus 25 of Fig. 16 (a) is different from the above-described plating apparatus 23 in that it has an anode 25o which is a columnar shape extending upward from the plating liquid discharge pipe 1c in a posture in which the tip end portion faces downward. The tip end portion has an outer peripheral surface 25v that faces the inner peripheral surface 2z of the second cathode 2x with a constant gap c. Further, the plating apparatus 25 further includes a supply device (not shown) that tracks the uniform consumption of the outer peripheral surface 25v of the anode 25o over time and transports the anode 25o downward (arrow e). The consumption is caused by the fact that the crucible constituting the anode 25o is sucked into the plating solution L as the plating treatment proceeds. In the outer peripheral surface 25v of the anode 25o, similarly to the outer peripheral surface 24v of the anode 24o described with reference to Fig. 15(b), the taper is reduced downward at the same angle as the inner peripheral surface 2z of the second cathode 2x. shape. The anode 25o is inserted into the through hole of the holding member 23r in the axial direction by the tip end portion having the outer peripheral surface 25v, and is positioned in the horizontal direction in this manner, and the outer peripheral surface 25v is uniformly consumed as time passes during the plating process. The amount is maintained such that the distance d between the tip end and the bottom surface 1p of the container 1k is maintained, and the state in which the two do not collide is controlled by the supply device to position the vertical direction. The plating apparatus 25 configured as described above is particularly suitable for a case where a large number of core balls 91 are processed, a thick plating layer is formed, a processing time is long, and the consumption of the anode 25o cannot be ignored.

圖16(b)的電鍍裝置26與上述的電鍍裝置23的不同點在於,電鍍液排出管1c的下方配置的略圓環形的陽極26o、包覆該陽極26o表面所形成的保持構件26r、支撐著從電鍍液排出管1c的下端面伸出的保持構件26r的支持構件26u。在此,將其軸芯與電鍍室1m的軸芯對準配置的陽極26o的外周面26v,為與第2陰極2x的內周面2z同一角度下縮徑到下方的略圓錐形,當該外周面26v對向於第2陰極2x的內周面2z,以此方式由上下方向被定位的支持構件26u所支撐。藉此,與上述陽極23o~25o同樣地,陽極26o的外周面26v與第2陰極2x的內周面2z之間形成一定的間隙c。且因為陽極26o呈圓環形,朝向電鍍液排出口1d上昇的電鍍液的液流也不會被妨礙。依照本實施形態的陽極26o,與在電鍍液排出口1d中配置著陽極23o~25o的上述電鍍裝置23~25相比,陽極配置的自由度高,且可使陽極26o更接近陰極2n,適於為處理多個芯球91而具有大容量電鍍室1m的電鍍裝置。The plating apparatus 26 of FIG. 16(b) is different from the above-described plating apparatus 23 in that a ring-shaped anode 26o disposed below the plating solution discharge pipe 1c, a holding member 26r formed to cover the surface of the anode 26o, The support member 26u of the holding member 26r that protrudes from the lower end surface of the plating solution discharge pipe 1c is supported. Here, the outer peripheral surface 26v of the anode 26o whose axial core is aligned with the axial core of the plating chamber 1m is a slightly conical shape which is reduced in diameter to the lower side at the same angle as the inner peripheral surface 2z of the second cathode 2x. The outer peripheral surface 26v is opposed to the inner peripheral surface 2z of the second cathode 2x, and is supported by the support member 26u positioned in the vertical direction in this manner. Thereby, similarly to the above-described anodes 23o to 25o, a constant gap c is formed between the outer peripheral surface 26v of the anode 26o and the inner peripheral surface 2z of the second cathode 2x. Further, since the anode 26o has a circular shape, the flow of the plating solution rising toward the plating solution discharge port 1d is not hindered. According to the anode 26o of the present embodiment, the degree of freedom in the anode arrangement is higher than that of the plating apparatuses 23 to 25 in which the anodes 23o to 25o are disposed in the plating solution discharge port 1d, and the anode 26o can be brought closer to the cathode 2n. A plating apparatus having a large-capacity plating chamber 1 m for processing a plurality of core balls 91.

[實施例][Examples]

在第1形態的電鍍裝置1中,投入50萬個直徑50μm的芯球,以厚度20μm作為目標值,藉由上述說明的方法,以規定的條件來進行電鍍處理,獲得形成有Sn-Ag-Cu系的電鍍層的Cu芯球。自50萬個芯球及Cu芯球中抽選600個標本,將測定出的直徑及圓度的分布示於圖17(a)、圖17(b)。而且,將利用第1形態的電鍍裝置1來進行電鍍時的Cu芯球及利用先行技術文獻1的電鍍裝置來進行電鍍時的Cu芯球的外觀照片及剖面照片示於圖18(a)、圖18(b)、圖18(c)、圖18(d)。In the plating apparatus 1 of the first embodiment, 500,000 core balls having a diameter of 50 μm are placed, and a thickness of 20 μm is used as a target value, and plating treatment is performed under predetermined conditions by the method described above to obtain Sn-Ag-formed. A Cu core ball of a Cu-based plating layer. 600 specimens were selected from 500,000 core balls and Cu core balls, and the measured diameter and roundness distributions are shown in Fig. 17 (a) and Fig. 17 (b). Further, an appearance photograph and a cross-sectional photograph of the Cu core ball at the time of plating using the plating apparatus 1 of the first embodiment and the plating apparatus using the plating apparatus of the prior art document 1 are shown in Fig. 18 (a). 18(b), 18(c), and 18(d).

如圖17(a)、圖17(b)所示,相對於芯球直徑的平均值50.4 μm,Cu芯球直徑的平均值為大致90 μm,形成有目標值即20 μm厚度的電鍍層。而且,Cu芯球的圓度為0.9965,形成了具有超過基材粒子即芯球的圓度0.9960的高圓度的Cu芯球。除此以外,Cu芯球的直徑及圓度的標準偏差分別為1.776、0.0018,低於芯球的2.108、0.0075,可獲得直徑及圓度的偏差較少的Cu芯球。As shown in Fig. 17 (a) and Fig. 17 (b), the average value of the diameter of the Cu core ball was approximately 90 μm with respect to the average value of the core ball diameter of 50.4 μm, and a plating layer having a target value of 20 μm was formed. Further, the Cu core ball has a roundness of 0.9965, and a Cu core ball having a roundness of more than 0.9960, which is a core particle of the substrate particle, is formed. In addition, the standard deviation of the diameter and roundness of the Cu core ball is 1.776 and 0.0018, respectively, which is lower than 2.108 and 0.0075 of the core ball, and a Cu core ball having a small variation in diameter and roundness can be obtained.

如圖18(a)、圖18(b)所示,利用第1形態的電鍍裝置1而形成有電鍍層的Cu芯球的表面非常光滑而得到平滑化,且在芯球的表面均勻地形成有電鍍層,進而電鍍層的內部未產生空隙。另一方面,如該圖16(c)、圖16(d)所示,利用先行技術文獻1的電鍍裝置而形成有電鍍層的Cu芯球經確認,在電鍍層的表面產生了成為空隙的原因的凹凸,由於該凹凸,圓度低且直徑及圓度的偏差亦大。As shown in Fig. 18 (a) and Fig. 18 (b), the surface of the Cu core ball in which the plating layer is formed by the plating apparatus 1 of the first embodiment is very smooth and smoothed, and is uniformly formed on the surface of the core ball. There is an electroplated layer, and thus no void is generated inside the plating layer. On the other hand, as shown in Fig. 16 (c) and Fig. 16 (d), the Cu core ball in which the plating layer was formed by the plating apparatus of the prior art document 1 was confirmed to have voids on the surface of the plating layer. The unevenness of the cause is low in roundness and large in variation in diameter and roundness due to the unevenness.

雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明,任何熟習此技藝者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。While the present invention has been described in its preferred embodiments, the present invention is not intended to limit the invention, and the present invention may be modified and modified without departing from the spirit and scope of the invention. The scope of protection is subject to the definition of the scope of the patent application.

1、5、8、10、11、12、13、16、17、18、19、20、21、22、23、24、25、26...電鍍裝置1, 5, 8, 10, 11, 12, 13, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26. . . Plating device

1a、5a...本體部1a, 5a. . . Body part

1b...電鍍液循環機構1b. . . Plating solution circulation mechanism

1c、5c、13c...電鍍液排出管1c, 5c, 13c. . . Electroplating solution discharge pipe

1d、5d...電鍍液排出口1d, 5d. . . Plating solution discharge

1e、13e、22e...電鍍液供給管1e, 13e, 22e. . . Plating solution supply tube

1f、22f...電鍍液供給口1f, 22f. . . Plating solution supply port

1g、11q、12q...供給機構1g, 11q, 12q. . . Supply agency

1h...直流電源電路1h. . . DC power circuit

1i...振動機構1i. . . Vibration mechanism

1j...電鍍槽1j. . . Plating tank

1k...容器1k. . . container

1L...密閉蓋1L. . . Sealing cover

1m、13m、20m...電鍍室1m, 13m, 20m. . . Plating chamber

1n、2n、3n、3m、6n、7n、11n、13n、20n...陰極1n, 2n, 3n, 3m, 6n, 7n, 11n, 13n, 20n. . . cathode

1o、5o、10o、14o、15o、23o、24o、25o、26o...陽極1o, 5o, 10o, 14o, 15o, 23o, 24o, 25o, 26o. . . anode

1p、2p、3p、6p、7p、10z、13p、20p...底面1p, 2p, 3p, 6p, 7p, 10z, 13p, 20p. . . Bottom

1q、13q...周壁面1q, 13q. . . Wall surface

1r...支持構件1r. . . Support component

1s...磁力產生機構1s. . . Magnetic generating mechanism

2x...第2陰極2x. . . Second cathode

2y...第1陰極2y. . . First cathode

2z...中央部2z. . . Central department

4y...導引溝4y. . . Guide groove

7y...突起7y. . . Protrusion

8v、10v、16v...導引機構8v, 10v, 16v. . . Guiding mechanism

8w、16w...導引板8w, 16w. . . Guide plate

8x、17x...上部8x, 17x. . . Upper

8y、17y...下部8y, 17y. . . Lower part

8z...流通通路8z. . . Flow path

9...球群9. . . Ball group

10w、21w...導引體10w, 21w. . . Guide body

10x...外周面10x. . . Peripheral surface

10y、16z...間隙10y, 16z. . . gap

11a...回收機構11a. . . Recycling agency

11b...球回收管11b. . . Ball recovery tube

11c...球回收口11c. . . Ball recovery port

11d...上下驅動部11d. . . Upper and lower drive

11e...回收容器11e. . . Recycling container

11L...圓筒狀部11L. . . Cylindrical part

11p...上表面11p. . . Upper surface

11q...供給機構11q. . . Supply agency

11r...收納部11r. . . Storage department

11s...容器11s. . . container

11t...蓋11t. . . cover

11u...電鍍液流入管11u. . . Plating solution inflow tube

11v...球供給管11v. . . Ball supply tube

11w‧‧‧閥11w‧‧‧ valve

11x‧‧‧間隔閥11x‧‧‧ interval valve

11y‧‧‧電鍍液流入口11y‧‧‧ plating solution inlet

11z‧‧‧球供給口11z‧‧‧ ball supply port

15x‧‧‧導電性粒子收納容器15x‧‧‧Electrical particle storage container

15y、21o‧‧‧導電性粒子15y, 21o‧‧‧ conductive particles

17v、18v、19v‧‧‧整流機構17v, 18v, 19v‧‧ ‧ rectification mechanism

17w、18w、19w、18q、18r、18s、19q、19r、19s、19t‧‧‧板狀構件17w, 18w, 19w, 18q, 18r, 18s, 19q, 19r, 19s, 19t‧‧‧ plate-like members

18t、19u‧‧‧間隙部18t, 19u‧‧‧ gap

20q‧‧‧外周壁面20q‧‧‧outer wall

20x‧‧‧內周壁面20x‧‧‧ inner wall

91、91a、91b、92‧‧‧芯球91, 91a, 91b, 92‧‧ ‧ core ball

a、b‧‧‧流動a, b‧‧‧ flow

d、e、f‧‧‧箭頭d, e, f‧‧‧ arrows

F‧‧‧中心線F‧‧‧ center line

g‧‧‧固定尺寸g‧‧‧Fixed size

L‧‧‧電鍍液L‧‧‧ plating solution

m1‧‧‧電鍍層M1‧‧‧ plating layer

圖1是表示本發明的第1實施形態的電鍍裝置的概略構成的圖。FIG. 1 is a view showing a schematic configuration of a plating apparatus according to a first embodiment of the present invention.

圖2(a)、圖2(b)、圖2(c)是圖1的電鍍裝置及其較佳形態的電鍍裝置的平面圖。2(a), 2(b), and 2(c) are plan views of the plating apparatus of Fig. 1 and a plating apparatus of a preferred embodiment.

圖3(a)、圖3(b)、圖3(c)是圖1的電鍍裝置的另一較佳形態的電鍍裝置的局部放大圖。3(a), 3(b), and 3(c) are partially enlarged views of a plating apparatus according to another preferred embodiment of the plating apparatus of Fig. 1.

圖4(a)、圖4(b)、圖4(c)是圖1的電鍍裝置的另一較佳形態的電鍍裝置的局部放大圖。4(a), 4(b), and 4(c) are partially enlarged views of a plating apparatus according to another preferred embodiment of the plating apparatus of Fig. 1.

圖5是圖1的電鍍裝置的另一較佳形態的電鍍裝置的正面圖。Fig. 5 is a front elevational view showing a plating apparatus of another preferred embodiment of the plating apparatus of Fig. 1.

圖6(a)、圖6(b)是圖1的電鍍裝置的另一較佳形態的電鍍裝置的放大正面圖。6(a) and 6(b) are enlarged front views of a plating apparatus according to another preferred embodiment of the plating apparatus of Fig. 1.

圖7(a)、圖7(b)是本發明的第2實施形態的電鍍裝置的立體圖。7(a) and 7(b) are perspective views of a plating apparatus according to a second embodiment of the present invention.

圖8(a)、圖8(b)是表示第2實施形態的電鍍裝置的另一例的概略構成的圖。(a) and (b) of FIG. 8 are views showing a schematic configuration of another example of the plating apparatus of the second embodiment.

圖9(a)、圖9(b)、圖9(c)是本發明的第3實施形態的電鍍裝置的立體圖。9(a), 9(b), and 9(c) are perspective views of a plating apparatus according to a third embodiment of the present invention.

圖10(a)、圖10(b)是本發明的第4實施形態的電鍍裝置的立體圖。10(a) and 10(b) are perspective views of a plating apparatus according to a fourth embodiment of the present invention.

圖11(a)、圖11(b)、圖11(c)是說明圖10(a)、圖10(b)的電鍍裝置的動作的圖。11(a), 11(b), and 11(c) are views for explaining the operation of the plating apparatus of Figs. 10(a) and 10(b).

圖12是表示第4實施形態的電鍍裝置的另一例的概略構成的圖。FIG. 12 is a view showing a schematic configuration of another example of the plating apparatus of the fourth embodiment.

圖13(a)、圖13(b)、圖13(c)、圖13(d)是表示本發明的第5實施形態的電鍍裝置的概略構成的圖。(a), (b), (c), and (d) of FIG. 13 are views showing a schematic configuration of a plating apparatus according to a fifth embodiment of the present invention.

圖14(a)、圖14(b)是說明芯球的電鍍中的行為的圖。14(a) and 14(b) are diagrams for explaining behavior in plating of a core ball.

圖15(a)、圖15(b)是表示本發明的第6實施形態的電鍍裝置的概略構成的圖。(a) and (b) of FIG. 15 are views showing a schematic configuration of a plating apparatus according to a sixth embodiment of the present invention.

圖16(a)、圖16(b)是表示本發明的第6實施形態的電鍍裝置的另一例的概略構成的圖。(a) and (b) of FIG. 16 are views showing a schematic configuration of another example of the plating apparatus according to the sixth embodiment of the present invention.

圖17(a)、圖17(b)是說明圖1的電鍍裝置的實例的圖。17(a) and 17(b) are views for explaining an example of the plating apparatus of Fig. 1.

圖18(a)、圖18(b)、圖18(c)、圖18(d)是說明圖1的電鍍裝置的實例的另一圖。18(a), 18(b), 18(c), and 18(d) are other views for explaining an example of the plating apparatus of Fig. 1.

1...電鍍裝置1. . . Plating device

1a...本體部1a. . . Body part

1b...電鍍液循環機構1b. . . Plating solution circulation mechanism

1c...電鍍液排出管1c. . . Electroplating solution discharge pipe

1d...電鍍液排出口1d. . . Plating solution discharge

1e...電鍍液供給管1e. . . Plating solution supply tube

1f...電鍍液供給口1f. . . Plating solution supply port

1g...供給機構1g. . . Supply agency

1h...直流電源電路1h. . . DC power circuit

1i...振動機構1i. . . Vibration mechanism

1j...電鍍槽1j. . . Plating tank

1k...容器1k. . . container

1L...密閉蓋1L. . . Sealing cover

1m...電鍍室1m. . . Plating chamber

1n...陰極1n. . . cathode

1o...陽極1o. . . anode

1p...底面1p. . . Bottom

1q...周壁面1q. . . Wall surface

1r...支持構件1r. . . Support component

1s...磁力產生機構1s. . . Magnetic generating mechanism

9...球群9. . . Ball group

91...芯球91. . . Core ball

a、b...流動a, b. . . flow

L...電鍍液L. . . Plating solution

Claims (22)

一種電鍍裝置,其是表面具有導電性的基材粒子的電鍍裝置,其包括:電鍍槽,具有電鍍室,該電鍍室具備上述基材粒子可接觸並轉繞的底面以及沿著該底面的周緣而立設的周壁面,且可收納包含上述基材粒子的粒子群及電鍍液;電鍍液供給管,具有自上述電鍍室的底面向上方開口的供給口,且以沿著上述電鍍室的周壁面而回旋的方式自上述供給口供給電鍍液;電鍍液排出管,具有與上述電鍍室的軸芯成同軸地向上述電鍍室開口的排出口;陰極,與配置於上述電鍍室的底面的上述基材粒子接觸;陽極,配置在浸漬於上述電鍍室內所收納的電鍍液中的位置;以及電源,連接於上述陰極及陽極。 An electroplating apparatus is an electroplating apparatus having substrate particles having conductivity on a surface, comprising: a plating tank having a plating chamber having a bottom surface on which the substrate particles can be contacted and circulated, and a periphery along the bottom surface And a standing wall surface, and a particle group including the substrate particles and a plating solution; the plating solution supply pipe having a supply port opened upward from a bottom surface of the plating chamber and having a peripheral wall surface along the plating chamber And the method of swirling supplies the plating solution from the supply port; the plating solution discharge pipe has a discharge port that is open to the plating chamber coaxially with the axis of the plating chamber; and a cathode and the base disposed on the bottom surface of the plating chamber The material particles are in contact; the anode is disposed at a position immersed in the plating solution contained in the plating chamber; and a power source is connected to the cathode and the anode. 如申請專利範圍第1項所述之電鍍裝置,其中上述電鍍室的底面為圓形狀,並且上述電鍍室的周壁面呈朝向上述電鍍室的底面而縮徑的圓錐形狀,上述電鍍液排出管是與上述電鍍室的軸芯成同軸地配置著。 The plating apparatus according to claim 1, wherein a bottom surface of the plating chamber has a circular shape, and a peripheral wall surface of the plating chamber has a conical shape which is reduced in diameter toward a bottom surface of the plating chamber, and the plating liquid discharge pipe is It is disposed coaxially with the axis of the plating chamber. 如申請專利範圍第2項所述之電鍍裝置,其中上述排出口配置於較上述供給口更下方。 The plating apparatus according to claim 2, wherein the discharge port is disposed below the supply port. 如申請專利範圍第2項所述之電鍍裝置,其中上述電鍍液排出管是設置成可沿著上述電鍍室的軸芯 方向而移動。 The electroplating apparatus according to claim 2, wherein the electroplating liquid discharge pipe is disposed to be along a core of the plating chamber Move in the direction. 如申請專利範圍第2項所述之電鍍裝置,其中上述陰極呈大致圓環狀配置於上述電鍍室的底面的周緣部。 The plating apparatus according to claim 2, wherein the cathode is disposed in a substantially annular shape at a peripheral portion of a bottom surface of the plating chamber. 如申請專利範圍第2項所述之電鍍裝置,其中上述陰極呈大致圓環狀配置於上述電鍍室的周壁面的基端部。 The plating apparatus according to claim 2, wherein the cathode is disposed in a substantially annular shape at a base end portion of a peripheral wall surface of the plating chamber. 如申請專利範圍第6項所述之電鍍裝置,其中上述陽極所具有的表面是設置成:與上述電鍍室的周壁面的基端部上配置成略呈圓環狀的陰極中與上述基材粒子接觸的接觸面具有一定的間隙。 The plating apparatus according to claim 6, wherein the anode has a surface provided in a cathode which is disposed in a substantially annular shape on a base end portion of a peripheral wall surface of the plating chamber, and the substrate The contact surface where the particles are in contact has a certain gap. 如申請專利範圍第2項所述之電鍍裝置,其中上述電鍍室的底面形成為,在其半徑方向上,其中心部相對於周緣部而較高。 The plating apparatus according to claim 2, wherein the bottom surface of the plating chamber is formed such that a central portion thereof is higher with respect to the peripheral portion in a radial direction thereof. 如申請專利範圍第1項所述之電鍍裝置,其中上述陽極由連接於上述電源的多個導電性粒子構成。 The plating apparatus according to claim 1, wherein the anode is composed of a plurality of conductive particles connected to the power source. 如申請專利範圍第1項至第9項中任一項所述之電鍍裝置,其中上述電鍍室內具有導引機構,該導引機構將自上述電鍍液供給管的供給口所供給的電鍍液朝向上述電鍍室的底面而導引。 The plating apparatus according to any one of the items 1 to 9, wherein the plating chamber has a guiding mechanism that directs a plating liquid supplied from a supply port of the plating solution supply pipe Guided by the bottom surface of the plating chamber. 如申請專利範圍第10項所述之電鍍裝置,其中上述導引機構是呈螺旋狀設置的導引板。 The electroplating apparatus according to claim 10, wherein the guiding mechanism is a guiding plate disposed in a spiral shape. 如申請專利範圍第10項所述之電鍍裝置,其中 上述導引機構是沿著上述電鍍室的周壁面而形成有外周面的導引體,且在上述周壁面與上述外周面之間具有規定的間隙。 The electroplating apparatus according to claim 10, wherein The guide means is a guide body having an outer peripheral surface formed along a peripheral wall surface of the plating chamber, and has a predetermined gap between the peripheral wall surface and the outer peripheral surface. 如申請專利範圍第1項至第9項中任一項所述之電鍍裝置,其中上述電鍍室內具有整流機構,該整流機構對自上述電鍍液供給管的供給口所供給的電鍍液進行整流。 The plating apparatus according to any one of the items 1 to 9, wherein the plating chamber has a rectifying mechanism that rectifies a plating solution supplied from a supply port of the plating solution supply pipe. 如申請專利範圍第13項所述之電鍍裝置,其中上述整流機構是設置於上述電鍍室的周壁面的板狀構件。 The plating apparatus according to claim 13, wherein the rectifying means is a plate-like member provided on a peripheral wall surface of the plating chamber. 如申請專利範圍第1項至第9項中任一項所述之電鍍裝置,其中該電鍍裝置是設置成可從上述電鍍液排出管的排出口抽吸電鍍液。 The electroplating apparatus according to any one of claims 1 to 9, wherein the electroplating apparatus is provided to suction the plating solution from the discharge port of the electroplating liquid discharge pipe. 如申請專利範圍第1項至第9項中任一項所述之電鍍裝置,其中該電鍍裝置是設置成自上述電鍍液供給管所供給的電鍍液的流速或流量隨時間發生變化。 The plating apparatus according to any one of the items 1 to 9, wherein the plating apparatus is configured such that a flow rate or a flow rate of the plating solution supplied from the plating solution supply tube changes with time. 如申請專利範圍第1項至第9項中任一項所述之電鍍裝置,其中於上述電鍍室的底面形成有導引溝,該導引溝沿著自上述電鍍液供給管所供給的電鍍液的回旋方向而形成,以導引上述粒子群。 The plating apparatus according to any one of the items 1 to 9, wherein a guide groove is formed on a bottom surface of the plating chamber, and the guide groove is supplied along a plating solution supplied from the plating solution supply tube. The direction of the whirling is formed to guide the above-mentioned particle group. 如申請專利範圍第1項至第9項中任一項所述之 電鍍裝置,包括連接於上述電鍍槽的振動機構。 As described in any one of claims 1 to 9 The plating apparatus includes a vibration mechanism connected to the plating tank. 如申請專利範圍第1項至第9項中任一項所述之電鍍裝置,包括配置於上述電鍍室的下部或下方側部的磁力產生機構,且設置成藉由上述磁力產生機構的磁力而將具有軟磁性的上述基材粒子拉向電鍍室的底面。 The plating apparatus according to any one of claims 1 to 9, comprising a magnetic force generating mechanism disposed at a lower portion or a lower side portion of the plating chamber, and configured to be magnetically generated by the magnetic force generating mechanism The substrate particles having soft magnetic properties are pulled toward the bottom surface of the plating chamber. 如申請專利範圍第1項至第9項中任一項所述之電鍍裝置,包括供給機構,該供給機構直接地或經由上述電鍍液供給管而間接地連接於上述電鍍室,以向上述電鍍室供給上述粒子群。 The plating apparatus according to any one of claims 1 to 9, comprising a supply mechanism that is indirectly connected to the plating chamber directly or via the plating liquid supply tube to perform the plating The chamber supplies the above-mentioned particle group. 如申請專利範圍第20項所述之電鍍裝置,其中上述供給機構具有:收納部,收納上述粒子群;基材粒子供給管,一端連接於上述收納部,並且另一端連接於上述電鍍室的周壁面且上述底面側;以及電鍍液流入管,一端連接於上述收納部,並且另一端連接於上述電鍍室的周壁面且較上述基材粒子供給管的另一端更上方。 The plating apparatus according to claim 20, wherein the supply mechanism includes a accommodating portion that accommodates the particle group, and a substrate particle supply tube that has one end connected to the accommodating portion and the other end connected to the periphery of the plating chamber And a plating liquid inflow pipe having one end connected to the storage portion and the other end connected to a peripheral wall surface of the plating chamber and being higher than the other end of the substrate particle supply pipe. 如申請專利範圍第1項至第9項中任一項所述之電鍍裝置,其中包括回收機構,該回收機構回收上述電鍍室內所收納的上述粒子群。The electroplating apparatus according to any one of claims 1 to 9, further comprising a recovery mechanism that recovers the particle group accommodated in the plating chamber.
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Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011230065A (en) * 2010-04-28 2011-11-17 Hitachi Metals Ltd Apparatus for treatment of solid particle
JP5440958B2 (en) * 2010-08-16 2014-03-12 日立金属株式会社 Plating equipment
JP6129497B2 (en) * 2011-09-29 2017-05-17 アルメックスPe株式会社 Continuous plating equipment
JP5643239B2 (en) * 2012-01-30 2014-12-17 株式会社荏原製作所 Substrate holder and plating apparatus
CN103668406B (en) * 2012-09-17 2016-05-11 郑振华 Spray-sucking type electroplating bath
CA2895934C (en) 2013-01-11 2017-11-07 Honda Motor Co., Ltd. Hybrid vehicle and control method therefor
WO2014109064A1 (en) 2013-01-11 2014-07-17 本田技研工業株式会社 Hybrid vehicle and method for controlling same
JP6157873B2 (en) * 2013-02-21 2017-07-05 株式会社イデヤ Electroplating apparatus and electroplating method
JP6168389B2 (en) * 2013-03-05 2017-07-26 日立金属株式会社 Plating equipment
CN104988572B (en) * 2015-07-29 2017-09-29 俞雄飞 Plating line steel ball recovery system
JP6607001B2 (en) * 2015-11-27 2019-11-20 株式会社村田製作所 Plating apparatus and plating method
KR101899678B1 (en) * 2016-12-21 2018-09-17 주식회사 포스코 Filter unit and coating apparatus having thereof
WO2018189901A1 (en) * 2017-04-14 2018-10-18 Ykk株式会社 Plated material and manufacturing method therefor
CN107552779B (en) * 2017-09-11 2019-05-28 中国科学院过程工程研究所 A kind of intermittent electro-deposition prepares the device and its processing method of micron order and/or grade Coated powder
WO2021130874A1 (en) * 2019-12-24 2021-07-01 Ykk株式会社 Electroplating device and method for manufacturing plated product
CN111041534A (en) * 2019-12-25 2020-04-21 戚英奎 Tin plating solution
CN113430635B (en) * 2021-06-28 2023-04-14 江苏澳光电子有限公司 Transverse drive formula electroplating ion supplementing device for plating bath
CN113463168B (en) * 2021-06-28 2023-04-14 江苏澳光电子有限公司 Electroplating ion supplementing device for electroplating bath

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06116795A (en) * 1992-10-02 1994-04-26 Matsushita Electric Works Ltd Continuous plating device
TW459072B (en) * 1997-04-17 2001-10-11 Sekisui Chemical Co Ltd Conductive particles and method and device for manufacturing the same, anisotropic conductive adhesive and conductive connection structure, and electronic circuit components and method of manufacturing the same
JP2006509108A (en) * 2002-12-05 2006-03-16 サーフェクト テクノロジーズ インク. Encapsulation of submicron and nano-sized particles by electrochemical processes and equipment

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS592759B2 (en) * 1981-12-10 1984-01-20 文弥 後藤 Plating processing equipment
JP2628184B2 (en) * 1988-04-25 1997-07-09 日新製鋼株式会社 Method of electroplating metal on fine powder
JPH0544083A (en) * 1991-08-13 1993-02-23 Nisshin Steel Co Ltd Elctroplating method for powder
JP2745892B2 (en) * 1991-09-13 1998-04-28 株式会社村田製作所 How to plating small parts
JPH076267U (en) * 1993-06-29 1995-01-27 新共立化工株式会社 Plating equipment
JP3128459B2 (en) * 1995-02-28 2001-01-29 上村工業株式会社 Rotary plating equipment for small items
US5911865A (en) * 1997-02-07 1999-06-15 Yih; Pay Method for electroplating of micron particulates with metal coatings
CN1222205A (en) * 1996-04-26 1999-07-07 材料革新公司 Electrochemical fluidized bed coating of powders
JP4023526B2 (en) * 1997-10-09 2007-12-19 株式会社Neomaxマテリアル Method for producing fine metal sphere
JP3694249B2 (en) * 2001-04-25 2005-09-14 積水化学工業株式会社 Fine particle plating method, conductive fine particles, and connection structure
US6942765B2 (en) * 2001-05-31 2005-09-13 Surfect Technologies, Inc. Submicron and nano size particle encapsulation by electrochemical process and apparatus
DE10296936T5 (en) * 2001-07-31 2004-07-29 Sekisui Chemical Co., Ltd. Process for the production of electroconductive particles
JP4235980B2 (en) * 2001-11-19 2009-03-11 株式会社村田製作所 Small plating object plating equipment
JP4832970B2 (en) * 2006-07-06 2011-12-07 上村工業株式会社 Small surface treatment equipment
CN101503816B (en) * 2009-01-22 2010-08-18 海南丰兴精密产业股份有限公司 Precise nickel plating vibration swinging machine for miniature parts
JP2010285663A (en) * 2009-06-12 2010-12-24 Hitachi Metals Ltd Apparatus for producing metal-coated particle

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06116795A (en) * 1992-10-02 1994-04-26 Matsushita Electric Works Ltd Continuous plating device
TW459072B (en) * 1997-04-17 2001-10-11 Sekisui Chemical Co Ltd Conductive particles and method and device for manufacturing the same, anisotropic conductive adhesive and conductive connection structure, and electronic circuit components and method of manufacturing the same
JP2006509108A (en) * 2002-12-05 2006-03-16 サーフェクト テクノロジーズ インク. Encapsulation of submicron and nano-sized particles by electrochemical processes and equipment

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