TWI489945B - Explosive agents for aquatic plants - Google Patents

Explosive agents for aquatic plants Download PDF

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TWI489945B
TWI489945B TW099128094A TW99128094A TWI489945B TW I489945 B TWI489945 B TW I489945B TW 099128094 A TW099128094 A TW 099128094A TW 99128094 A TW99128094 A TW 99128094A TW I489945 B TWI489945 B TW I489945B
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germination
magnesium oxide
oxide powder
sediment
aquatic plants
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TW099128094A
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TW201121425A (en
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明石一三
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宇部材料股份有限公司
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06Aluminium; Calcium; Magnesium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12Powders or granules
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/02Soil-conditioning materials or soil-stabilising materials containing inorganic compounds only
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • C09K17/48Organic compounds mixed with inorganic active ingredients, e.g. polymerisation catalysts
    • C09K17/50Organic compounds mixed with inorganic active ingredients, e.g. polymerisation catalysts the organic compound being of natural origin, e.g. cellulose derivatives

Description

水生植物的發芽防止劑Germination inhibitor for aquatic plants

本發明係有關挺水植物、浮葉植物及沉水植物等生根於淡水水域底泥中之水生植物的發芽防止劑,以及水生植物的防止發芽方法。The present invention relates to a germination preventing agent for aquatic plants rooted in the sediment of freshwater water, such as emergent plants, floating leaf plants and submerged plants, and a method for preventing germination of aquatic plants.

已知於河川及湖泊等淡水水域中,由於水生植物自水中或底泥中吸收磷及氮等營養鹽類後生長茂盛,具有抑制發生藻華(water bloom)之效果。It is known that in freshwater waters such as rivers and lakes, aquatic plants are rich in nutrients such as phosphorus and nitrogen from water or sediment, and have the effect of suppressing the occurrence of water bloom.

然而,當水生植物生長異常茂盛時,會發生因腐敗造成惡臭(對生活的不良影響)、船舶航行障礙、漁業障礙(漁場環境惡化)、湖底環境惡化(泥化、缺氧化)等對生態系產生不良影響的各式問題。However, when aquatic plants grow abnormally, there will be foul odors (adverse effects on life), ship navigation obstacles, fishery obstacles (deterioration of fishery environment), deterioration of lake bottom environment (mud, lack of oxidation), etc. It is a variety of problems that have an adverse effect.

去除茂盛生長於淡水水域之水生植物的方法,有將水生植物割除之方法。但該方法需要極大的勞動力,且存在必須處理割除的水生植物之問題。A method of removing aquatic plants that grow in freshwater waters has a method of cutting aquatic plants. However, this method requires a great labor force and there is a problem that it is necessary to deal with the sected aquatic plants.

專利文件1記載作為防止地面上的雜草繁殖之方法,係使地面硬化之方法。該專利文件1所記載之使地面硬化之方法,係供給地面含氧化鎂之雜草繁殖防止材,且將雜草繁殖防止材與土壤攪拌及混合後,澆水於土壤,使與土壤混合之氧化鎂與水產生反應而硬化之方法。Patent Document 1 describes a method of preventing the weeds on the ground from being propagated, and is a method of hardening the ground. The method for hardening the ground described in Patent Document 1 is to supply a weed propagation preventing material containing magnesium oxide on the ground, and to mix and mix the weed propagation preventing material with the soil, and then water the soil to mix with the soil. A method in which magnesium oxide reacts with water to harden.

[先前技術文件][Previous Technical Document]

[專利文件][Patent Document]

[專利文件1]特開2003-47388號公報[Patent Document 1] JP-A-2003-47388

前述專利文件1中所記載之使地面硬化的方法,對防止地面的雜草繁殖極為有效,但由於淡水水域的底泥棲息著許多種生物,使淡水水域的底泥硬化,恐將對淡水水域的生態係造成不良影響。The method of hardening the ground described in the aforementioned Patent Document 1 is extremely effective for preventing weed propagation on the ground, but since the sediment of the freshwater water is inhabited by many kinds of organisms, the sediment of the freshwater waters is hardened, and the freshwater waters may be feared. The ecosystem has an adverse effect.

因此,本發明之目的係提供不會使淡水水域之底泥硬化,且可防止水生植物發芽之方法,以及適用於防止該水生植物發芽之水生植物的發芽防止劑。Accordingly, an object of the present invention is to provide a method for preventing the germination of aquatic plants without hardening the sediment of fresh water, and a germination preventing agent suitable for preventing aquatic plants from germination of the aquatic plants.

本發明團隊發現於淡水水域之底泥上散佈粒徑為1mm以下之氧化鎂粉末,可不使底泥硬化,且可防止水生植物發芽。The team of the present invention has found that magnesium oxide powder having a particle diameter of 1 mm or less is dispersed on the bottom mud of fresh water, so that the sediment can be hardened and the aquatic plants can be prevented from germinating.

因此,本發明係一種根系生根於淡水水域底泥中之水生植物的發芽防止劑,其係含有粒徑為1mm以下之氧化鎂粉末。Therefore, the present invention is a germination preventing agent for root plants rooted in the sediment of freshwater water, which contains magnesium oxide powder having a particle diameter of 1 mm or less.

適合本發明之水生植物的發芽防止劑的實施方式係如下所述。Embodiments of the germination inhibitor suitable for aquatic plants of the present invention are as follows.

(1) 氧化鎂粉末係含有80質量%以上之粒徑為1mm以下之粒子。(1) The magnesium oxide powder contains 80% by mass or more of particles having a particle diameter of 1 mm or less.

(2) 氧化鎂粉末係含有80質量%以上之粒徑為0.75mm以下之粒子。(2) The magnesium oxide powder contains 80% by mass or more of particles having a particle diameter of 0.75 mm or less.

(3) 氧化鎂粉末係顯示2.10g/cm3 以上之表觀密度。(3) The magnesium oxide powder showed an apparent density of 2.10 g/cm 3 or more.

(4) 氧化鎂粉末係燒硬氧化鎂粉末或電熔氧化鎂粉末。(4) Magnesium oxide powder is burnt hard magnesium oxide powder or fused magnesium oxide powder.

(5) 水生植物係菱科[Hydrocaryaceae family(亦稱Trapaceae family)]植物。(5) Plants of the family Hydrocaryaceae family (also known as Trapaceae family).

本發明進而係於淡水水域之底泥上散佈前述本發明之水生植物的發芽防止劑,防止挺水植物、浮葉植物及沉水植物等生根於淡水水域底泥中之水生植物發芽之方法。Further, the present invention is a method for dispersing the above-mentioned germination preventing agent for aquatic plants of the present invention on the sediment of fresh water, and preventing the germination of aquatic plants rooted in the sediment of freshwater water, such as water-producing plants, floating-leaf plants and submerged plants.

藉由將本發明之水生植物的發芽防止劑散佈於淡水水域之底泥上,可效率良好地防止特別為菱科植物的發芽。By displacing the germination inhibitor of the aquatic plant of the present invention on the sediment of the freshwater water, it is possible to efficiently prevent germination particularly in the plant.

[實施發明之最佳型態][Best form of implementing the invention]

本發明之發芽防止劑係含有粒徑為1mm以下較細微的氧化鎂粉末。氧化鎂粉末之平均粒徑以0.75mm以下為佳,0.03~0.5mm之範圍更佳。氧化鎂粉末之表觀密度(或體密度)以2.10 g/cm3 以上為佳,3.10~3.56 g/cm3 之範圍更佳,3.10~3.50 g/cm3 之範圍亦佳,3.15~3.30 g/cm3 之範圍特佳。氧化鎂粉末之表觀密度可以阿基米得原理為基礎之氣相取代法進行測定。The germination preventing agent of the present invention contains finely divided magnesium oxide powder having a particle diameter of 1 mm or less. The average particle diameter of the magnesium oxide powder is preferably 0.75 mm or less, more preferably in the range of 0.03 to 0.5 mm. The apparent density (or bulk density) of the magnesium oxide powder is preferably 2.10 g/cm 3 or more, more preferably 3.10 to 3.56 g/cm 3 , and preferably 3.10 to 3.50 g/cm 3 , and 3.15 to 3.30 g. The range of /cm 3 is particularly good. The apparent density of the magnesium oxide powder can be determined by a gas phase substitution method based on the principle of Archimedes.

本發明之發芽防止劑所使用之氧化鎂粉末,亦可含有較粒徑為1mm大的粗顆粒。但氧化鎂粉末以含有80質量%以上之粒徑1mm以下之細微粒子為佳,含有90質量%以上特佳。進而氧化鎂粉末以含有80質量%以上之粒徑為0.75mm以下之粒子為佳,含有90質量%以上特佳。另外,以含有80質量%以上之粒徑較0.005mm為大之粒子為佳,含有90質量%以上特佳。The magnesium oxide powder used in the germination preventing agent of the present invention may contain coarse particles having a larger particle diameter of 1 mm. However, the magnesium oxide powder is preferably fine particles having a particle diameter of 1 mm or less of 80% by mass or more, and particularly preferably 90% by mass or more. Further, the magnesium oxide powder is preferably a particle having a particle diameter of 80% by mass or more and 0.75 mm or less, and particularly preferably 90% by mass or more. In addition, it is preferable that the particles having a particle diameter of 80% by mass or more are larger than 0.005 mm, and more preferably 90% by mass or more.

本發明之發芽防止劑所使用之氧化鎂粉末,以燒硬氧化鎂粉末及電熔氧化鎂粉末為佳。The magnesium oxide powder used in the germination preventing agent of the present invention is preferably a calcined magnesia powder or an fused magnesia powder.

本發明中燒硬氧化鎂粉末,可藉由將氫氧化鎂及碳酸鎂等鎂化合物以900℃以上,更佳以1600℃以上之溫度,特佳以1700~2100℃之溫度,進行燒成後所得之氧化鎂燒成物,直接使用或使其經破碎處理後,以篩子等一般分級的方法調整粒度之方法製造。In the present invention, the burnt hard magnesium oxide powder can be obtained by firing a magnesium compound such as magnesium hydroxide or magnesium carbonate at a temperature of 900 ° C or higher, more preferably 1600 ° C or higher, and particularly preferably at a temperature of 1700 to 2100 ° C. The obtained magnesium oxide fired product is used as it is, or it is subjected to crushing treatment, and then it is produced by a method of adjusting the particle size by a general classification method such as a sieve.

本發明中電熔氧化鎂粉末,可藉由將氧化鎂或氫氧化鎂及碳酸鎂等鎂化合物,進行電熔後所得之氧化鎂溶融固化物,直接使用或使其經破碎處理後,以篩子等一般分級的方法調整粒度之方法製造。In the present invention, the fused magnesia powder may be directly used or crushed by a magnesium oxide compound such as magnesium oxide, magnesium hydroxide or magnesium carbonate, and then subjected to crushing, and then sieved. It is manufactured by a method of adjusting the particle size by a general classification method.

使用為燒硬氧化鎂粉末及電熔氧化鎂粉末之製造原料的氫氧化鎂,可舉出例如藉由將熟石灰加入海水、或含鎂鹽的鹽滷及鹽水中後,使析出之氫氧化鎂乾燥而獲得氫氧化鎂粉末。碳酸鎂可舉出例如天然的菱鎂礦。使用為電熔氧化鎂粉末之製造原料的氧化鎂,可舉出例如燒輕氧化鎂粉末、燒硬氧化鎂粉末以及燒結氧化鎂。The magnesium hydroxide which is a raw material for the production of the hard magnesium oxide powder and the fused magnesium oxide powder can be dried, for example, by adding slaked lime to seawater or a salt of a magnesium salt and brine, and drying the precipitated magnesium hydroxide. The magnesium hydroxide powder was obtained. The magnesium carbonate may, for example, be natural magnesite. Examples of the magnesium oxide used as a raw material for producing the fused magnesium oxide powder include calcined light magnesium oxide powder, burnt hard magnesium oxide powder, and sintered magnesium oxide.

氧化鎂燒成物以及氧化鎂溶融固化物其體密度以2.10 g/cm3 以上為佳,3.10~3.50 g/cm3 之範圍更佳,3.10~3.30 g/cm3 之範圍特佳。且氧化鎂燒成物以及氧化鎂溶融固化物之體密度,可使用媒介為煤油並利用阿基米得法進行測定。The bulk density of the magnesium oxide calcined product and the magnesia molten solidified product is preferably 2.10 g/cm 3 or more, more preferably 3.10 to 3.50 g/cm 3 , and particularly preferably 3.10 to 3.30 g/cm 3 . Further, the bulk density of the magnesium oxide fired product and the magnesia molten solidified product can be measured by using the medium as kerosene and using the Archimedes method.

藉由將本發明之發芽防止劑散佈於淡水水域之底泥上,可防止挺水植物(例如蘆葦、香蒲、蓮花、茭白筍、水蔥、萍蓬草)、浮葉植物(例如菱角、大王蓮、睡蓮、眼子菜)、以及沉水植物(例如水蘭、水蘊草、聚藻、馬藻、輪藻)等根系生根於淡水水域底泥中之水生植物發芽。By dispersing the germination preventing agent of the present invention on the sediment of the freshwater water, it is possible to prevent the emergent plants (for example, reed, cattail, lotus, white bamboo shoots, scallions, puppies), and floating leaf plants (for example, water chestnut, big king lotus) , water lily, eye dish), and submerged plants (such as water blue, water grass, polyalga, algae, Chara) and other roots rooted in the freshwater waters of the aquatic plants sprouted.

發芽防止劑之散佈量係相對於面積1m2 之底泥,以0.1~10kg之範圍為佳,0.5~5kg之範圍特佳。發芽防止劑之散佈時期,以水生植物開始發芽期的1週~3個月前為佳。The amount of the germination preventing agent to be dispersed is preferably in the range of 0.1 to 10 kg, and particularly preferably in the range of 0.5 to 5 kg, with respect to the sediment having an area of 1 m 2 . The spreading period of the germination inhibitor is preferably from 1 week to 3 months before the germination period of the aquatic plant begins.

並未特別限制發芽防止劑之散佈方法。例如可將發芽防止劑以粉末狀態散佈於淡水水域的水面,或可將使發芽防止劑分散於水中後,以分散液的狀態注入淡水水域的水中。The method of dispersing the germinating agent is not particularly limited. For example, the germination preventing agent may be dispersed in the water state of the fresh water area in a powder state, or the germination preventing agent may be dispersed in the water and then injected into the fresh water water in the state of the dispersion.

被散佈於淡水水域之發芽防止劑,會沉降至淡水水域中而快速到達底泥的表面。由於到達底泥表面的發芽防止劑(氧化鎂粉末)屬於微小粉末,迅速溶解於水使周圍的底泥變質為弱鹼性的同時,溶解的鎂離子會與底泥周圍的磷化物產生反應,形成難溶性的磷酸鎂。藉由使底泥變質為弱鹼性,進而使底泥周圍的磷化物成為難溶於水的磷酸鎂加以固定,可有效地抑制水生植物的發芽。The germination inhibitor dispersed in the freshwater water will settle to the freshwater waters and quickly reach the surface of the sediment. Since the germination preventing agent (magnesium oxide powder) reaching the surface of the sediment is a minute powder, it is rapidly dissolved in water to deteriorate the surrounding sediment to be weakly alkaline, and the dissolved magnesium ions react with the phosphide around the sediment. Forms poorly soluble magnesium phosphate. The germination of aquatic plants can be effectively suppressed by degrading the bottom mud to be weakly alkaline and further fixing the phosphide around the sediment into magnesium phosphate which is poorly soluble in water.

[實施例][Examples]

[實施例1][Example 1]

採取湖中菱角茂盛生長的底泥與湖水,使透明塑膠箱(長18 cm×寬30 cm×高23 cm)中,底泥深度為約3cm,湖水深度為約9cm。其次將54g(底泥每1m2 面積之量為1kg)之燒硬氧化鎂粉末(粒徑:0.75mm以下,表觀密度:3.23 g/cm3 ),以均勻堆積於底泥全體上之方式進行散佈,並靜置。圖1係顯示經3週後自透明塑膠箱的上方進行攝影之相片。如圖1所示,即使經過3星期亦未有菱角生長。另外,以玻璃棒穿刺經過3星期後之底泥,未發現底泥有硬化現象。Take the sediment and lake water that grows in the lake's water chestnut, so that the transparent plastic box (length 18 cm × width 30 cm × height 23 cm), the depth of the sediment is about 3 cm, and the depth of the lake is about 9 cm. Next, 54 g (1 kg per 1 m 2 of the amount of the bottom mud) of the calcined magnesium oxide powder (particle size: 0.75 mm or less, apparent density: 3.23 g/cm 3 ) was uniformly deposited on the entire sediment. Spread and stand still. Figure 1 shows a photograph taken from above the transparent plastic box after 3 weeks. As shown in Fig. 1, there was no water chestnut growth even after 3 weeks. In addition, the sediment was passed through the glass rod after 3 weeks, and no cracking of the sediment was observed.

[比較例1][Comparative Example 1]

除未散佈氧化鎂粉末之外,進行與實施例1相同之實驗,將底泥與湖水置入透明塑膠箱後並靜置。圖2係顯示經3週後自透明塑膠箱的上方進行攝影之相片。如圖2所示,經過3星期後菱角生長茂盛。Except that the magnesium oxide powder was not dispersed, the same experiment as in Example 1 was carried out, and the sediment and the lake water were placed in a transparent plastic box and allowed to stand. Figure 2 shows photographs taken from above the transparent plastic box after 3 weeks. As shown in Figure 2, after 3 weeks, the water chestnut grows lush.

[圖1]自實施例1透明塑膠箱的上方進行攝影之相片。[Fig. 1] Photographs taken from above the transparent plastic case of Example 1.

[圖2]自比較例1透明塑膠箱的上方進行攝影之相片。Fig. 2 is a photograph taken from above the transparent plastic case of Comparative Example 1.

Claims (7)

一種根系生根於淡水水域底泥中之水生植物的發芽防止劑,其係含有粒徑為1mm以下,表觀密度為3.10~3.56g/cm3 之範圍之氧化鎂粉末。A germination preventing agent for an aquatic plant rooted in a sediment of a freshwater water, which comprises a magnesium oxide powder having a particle diameter of 1 mm or less and an apparent density of 3.10 to 3.56 g/cm 3 . 如申請專利範圍第1項之水生植物的發芽防止劑,其中氧化鎂粉末係含有80質量%以上之粒徑為1mm以下之粒子。 The germination preventing agent for aquatic plants according to the first aspect of the invention, wherein the magnesium oxide powder contains 80% by mass or more of particles having a particle diameter of 1 mm or less. 如申請專利範圍第1項之水生植物的發芽防止劑,其中氧化鎂粉末係含有80質量%以上之粒徑為0.75mm以下之粒子。 The germination preventing agent for aquatic plants according to the first aspect of the invention, wherein the magnesium oxide powder contains 80% by mass or more of particles having a particle diameter of 0.75 mm or less. 如申請專利範圍第1項之水生植物的發芽防止劑,其中氧化鎂粉末係燒硬氧化鎂粉末或電熔氧化鎂粉末。 The germination preventing agent for aquatic plants according to the first aspect of the invention, wherein the magnesium oxide powder is a burnt hard magnesium oxide powder or an fused magnesium oxide powder. 如申請專利範圍第1項之水生植物的發芽防止劑,其中水生植物係菱科植物。 The germination preventing agent for aquatic plants according to the first aspect of the patent application, wherein the aquatic plant is a plant of the family Lingaceae. 一種防止根系生根於淡水水域底泥中之水生植物發芽之方法,其係於淡水水域之底泥上散佈如申請專利範圍第1~5項中任一項之水生植物的發芽防止劑。 A method for preventing germination of an aquatic plant rooted in a sediment of a freshwater water, which is a germination preventing agent for an aquatic plant according to any one of claims 1 to 5, which is applied to a sediment of a freshwater water. 如申請專利範圍第6項之防止水生植物發芽之方法,其中水生植物的發芽防止劑之散佈量,係相對於面積1m2 之底泥為0.1~10kg之範圍。For example, in the method of preventing the germination of aquatic plants according to Item 6 of the patent application, the amount of the germination inhibitor of the aquatic plants is in the range of 0.1 to 10 kg with respect to the sediment having an area of 1 m 2 .
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