TWI484010B - 用於水泥及混凝土應用之特製無機聚合物(geopolymer)複合黏合劑 - Google Patents
用於水泥及混凝土應用之特製無機聚合物(geopolymer)複合黏合劑 Download PDFInfo
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- TWI484010B TWI484010B TW099101842A TW99101842A TWI484010B TW I484010 B TWI484010 B TW I484010B TW 099101842 A TW099101842 A TW 099101842A TW 99101842 A TW99101842 A TW 99101842A TW I484010 B TWI484010 B TW I484010B
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- 239000011230 binding agent Substances 0.000 title claims description 75
- 239000004567 concrete Substances 0.000 title claims description 53
- 239000002131 composite material Substances 0.000 title claims description 8
- 229920000876 geopolymer Polymers 0.000 title claims description 3
- 239000004568 cement Substances 0.000 title description 20
- 239000000203 mixture Substances 0.000 claims description 198
- 239000010881 fly ash Substances 0.000 claims description 172
- 239000003623 enhancer Substances 0.000 claims description 111
- 239000000463 material Substances 0.000 claims description 62
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 56
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 49
- 239000000243 solution Substances 0.000 claims description 46
- 239000011575 calcium Substances 0.000 claims description 44
- 239000002893 slag Substances 0.000 claims description 42
- 238000000034 method Methods 0.000 claims description 40
- 239000004570 mortar (masonry) Substances 0.000 claims description 40
- 239000007787 solid Substances 0.000 claims description 38
- 239000000292 calcium oxide Substances 0.000 claims description 37
- 239000011734 sodium Substances 0.000 claims description 37
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 32
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 30
- 229920000592 inorganic polymer Polymers 0.000 claims description 30
- 239000012190 activator Substances 0.000 claims description 29
- 239000000853 adhesive Substances 0.000 claims description 29
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- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 19
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 19
- 239000003607 modifier Substances 0.000 claims description 19
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 18
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- 239000002956 ash Substances 0.000 claims description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 16
- 238000007711 solidification Methods 0.000 claims description 16
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- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims description 13
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- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 12
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- 239000004327 boric acid Substances 0.000 claims description 7
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 claims description 7
- 229910052676 chabazite Inorganic materials 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
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- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 5
- 239000010882 bottom ash Substances 0.000 claims description 5
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
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- 229910002651 NO3 Inorganic materials 0.000 claims description 3
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- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- ZUGAOYSWHHGDJY-UHFFFAOYSA-K 5-hydroxy-2,8,9-trioxa-1-aluminabicyclo[3.3.2]decane-3,7,10-trione Chemical compound [Al+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O ZUGAOYSWHHGDJY-UHFFFAOYSA-K 0.000 claims description 2
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- 239000000499 gel Substances 0.000 description 29
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
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- 230000004913 activation Effects 0.000 description 25
- 229910052783 alkali metal Inorganic materials 0.000 description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 239000010754 BS 2869 Class F Substances 0.000 description 19
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- 238000010586 diagram Methods 0.000 description 16
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 11
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- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
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- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 229910052678 stilbite Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000003476 subbituminous coal Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/006—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B12/00—Cements not provided for in groups C04B7/00 - C04B11/00
- C04B12/005—Geopolymer cements, e.g. reaction products of aluminosilicates with alkali metal hydroxides or silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/24—Cements from oil shales, residues or waste other than slag
- C04B7/243—Mixtures thereof with activators or composition-correcting additives, e.g. mixtures of fly ash and alkali activators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Civil Engineering (AREA)
- Combustion & Propulsion (AREA)
- Dispersion Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14649409P | 2009-01-22 | 2009-01-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW201037046A TW201037046A (en) | 2010-10-16 |
TWI484010B true TWI484010B (zh) | 2015-05-11 |
Family
ID=42356385
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW099101842A TWI484010B (zh) | 2009-01-22 | 2010-01-22 | 用於水泥及混凝土應用之特製無機聚合物(geopolymer)複合黏合劑 |
Country Status (10)
Country | Link |
---|---|
US (2) | US20120024196A1 (de) |
EP (1) | EP2389345B1 (de) |
CN (1) | CN102348660B (de) |
CA (1) | CA2768626C (de) |
ES (1) | ES2788084T3 (de) |
IL (1) | IL214200A (de) |
MX (1) | MX354642B (de) |
RU (1) | RU2517729C2 (de) |
TW (1) | TWI484010B (de) |
WO (1) | WO2010085537A2 (de) |
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2010
- 2010-01-21 EP EP10733839.4A patent/EP2389345B1/de active Active
- 2010-01-21 WO PCT/US2010/021605 patent/WO2010085537A2/en active Application Filing
- 2010-01-21 CA CA2768626A patent/CA2768626C/en active Active
- 2010-01-21 CN CN201080011820.0A patent/CN102348660B/zh active Active
- 2010-01-21 US US13/138,233 patent/US20120024196A1/en not_active Abandoned
- 2010-01-21 RU RU2011134840/03A patent/RU2517729C2/ru active
- 2010-01-21 ES ES10733839T patent/ES2788084T3/es active Active
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WO2003078349A1 (de) * | 2002-03-20 | 2003-09-25 | Universität Für Chemie Und Technologie, Prag | Geopolymeres bindemittel auf basis von flugasche |
US20050160946A1 (en) * | 2003-01-31 | 2005-07-28 | Comrie Douglas C. | Cementitious materials including stainless steel slag and geopolymers |
US20070125272A1 (en) * | 2003-11-19 | 2007-06-07 | Rocla Pty Ltd | Geopolymer concrete and method of preparation and casting |
CN101321710A (zh) * | 2005-10-28 | 2008-12-10 | Excell技术有限责任公司 | 混合水泥组合物 |
Also Published As
Publication number | Publication date |
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IL214200A (en) | 2017-01-31 |
MX2011007683A (es) | 2011-09-30 |
RU2517729C2 (ru) | 2014-05-27 |
CN102348660B (zh) | 2015-08-26 |
EP2389345A2 (de) | 2011-11-30 |
MX354642B (es) | 2018-03-14 |
WO2010085537A2 (en) | 2010-07-29 |
US20160152521A1 (en) | 2016-06-02 |
CN102348660A (zh) | 2012-02-08 |
IL214200A0 (en) | 2011-08-31 |
CA2768626C (en) | 2021-11-02 |
US20120024196A1 (en) | 2012-02-02 |
WO2010085537A3 (en) | 2010-11-18 |
TW201037046A (en) | 2010-10-16 |
EP2389345A4 (de) | 2013-08-14 |
RU2011134840A (ru) | 2013-02-27 |
ES2788084T3 (es) | 2020-10-20 |
CA2768626A1 (en) | 2010-07-29 |
US9834479B2 (en) | 2017-12-05 |
EP2389345B1 (de) | 2020-03-04 |
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