TWI466995B - 烴類之經整合加氫裂解與脫蠟法 - Google Patents
烴類之經整合加氫裂解與脫蠟法 Download PDFInfo
- Publication number
- TWI466995B TWI466995B TW98145896A TW98145896A TWI466995B TW I466995 B TWI466995 B TW I466995B TW 98145896 A TW98145896 A TW 98145896A TW 98145896 A TW98145896 A TW 98145896A TW I466995 B TWI466995 B TW I466995B
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- Prior art keywords
- dewaxing
- zsm
- hydrocracking
- hydrotreating
- effluent
- Prior art date
Links
- 238000004517 catalytic hydrocracking Methods 0.000 title claims description 85
- 229930195733 hydrocarbon Natural products 0.000 title description 6
- 150000002430 hydrocarbons Chemical class 0.000 title description 6
- 239000003054 catalyst Substances 0.000 claims description 156
- 238000000034 method Methods 0.000 claims description 89
- 229910052717 sulfur Inorganic materials 0.000 claims description 73
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 69
- 239000011593 sulfur Substances 0.000 claims description 69
- 239000011230 binding agent Substances 0.000 claims description 58
- 229910052751 metal Inorganic materials 0.000 claims description 58
- 239000002184 metal Substances 0.000 claims description 58
- 239000010457 zeolite Substances 0.000 claims description 40
- 239000007789 gas Substances 0.000 claims description 37
- 229910021536 Zeolite Inorganic materials 0.000 claims description 36
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 36
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical group [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 36
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 35
- 230000003197 catalytic effect Effects 0.000 claims description 34
- 238000000926 separation method Methods 0.000 claims description 33
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 31
- 230000001050 lubricating effect Effects 0.000 claims description 30
- 229910044991 metal oxide Inorganic materials 0.000 claims description 29
- 150000004706 metal oxides Chemical class 0.000 claims description 29
- 239000001257 hydrogen Substances 0.000 claims description 28
- 229910052739 hydrogen Inorganic materials 0.000 claims description 28
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 26
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- 239000002283 diesel fuel Substances 0.000 claims description 17
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 16
- 239000011148 porous material Substances 0.000 claims description 15
- 239000000446 fuel Substances 0.000 claims description 14
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 13
- 239000002808 molecular sieve Substances 0.000 claims description 12
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052684 Cerium Inorganic materials 0.000 claims description 11
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 10
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- 229910052697 platinum Inorganic materials 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
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- 125000001741 organic sulfur group Chemical group 0.000 claims description 4
- 230000009970 fire resistant effect Effects 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- 238000006477 desulfuration reaction Methods 0.000 claims description 2
- 238000002955 isolation Methods 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 239000007767 bonding agent Substances 0.000 claims 1
- 230000023556 desulfurization Effects 0.000 claims 1
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- 239000000203 mixture Substances 0.000 description 30
- 239000002585 base Substances 0.000 description 26
- 238000006243 chemical reaction Methods 0.000 description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
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- 238000005984 hydrogenation reaction Methods 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 12
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- 229910052757 nitrogen Inorganic materials 0.000 description 11
- 229910000510 noble metal Inorganic materials 0.000 description 11
- 239000000356 contaminant Substances 0.000 description 10
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- 239000003921 oil Substances 0.000 description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 9
- 239000011733 molybdenum Substances 0.000 description 9
- 229910052721 tungsten Inorganic materials 0.000 description 9
- -1 fluorine Chemical class 0.000 description 8
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- 239000010937 tungsten Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
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- 230000002378 acidificating effect Effects 0.000 description 3
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- 238000011282 treatment Methods 0.000 description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 2
- XYUINKARGUCCQJ-UHFFFAOYSA-N 3-imino-n-propylpropan-1-amine Chemical compound CCCNCCC=N XYUINKARGUCCQJ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- NDYYRETYXBJDGQ-UHFFFAOYSA-N [O-2].[Ce+3].[O-2].[Ce+3] Chemical compound [O-2].[Ce+3].[O-2].[Ce+3] NDYYRETYXBJDGQ-UHFFFAOYSA-N 0.000 description 2
- 150000004645 aluminates Chemical class 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
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- 230000000052 comparative effect Effects 0.000 description 2
- VLXBWPOEOIIREY-UHFFFAOYSA-N dimethyl diselenide Natural products C[Se][Se]C VLXBWPOEOIIREY-UHFFFAOYSA-N 0.000 description 2
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 2
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- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
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- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000006317 isomerization reaction Methods 0.000 description 2
- 230000011987 methylation Effects 0.000 description 2
- 238000007069 methylation reaction Methods 0.000 description 2
- 125000001477 organic nitrogen group Chemical group 0.000 description 2
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- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
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- 150000003839 salts Chemical class 0.000 description 2
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- 239000011734 sodium Substances 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
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- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
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- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
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- 239000002253 acid Substances 0.000 description 1
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- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
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- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
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- 238000004364 calculation method Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- TZIBOXWEBBRIBM-UHFFFAOYSA-N cerium(3+) oxygen(2-) titanium(4+) Chemical compound [O--].[O--].[Ti+4].[Ce+3] TZIBOXWEBBRIBM-UHFFFAOYSA-N 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
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- 239000011280 coal tar Substances 0.000 description 1
- 238000011284 combination treatment Methods 0.000 description 1
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- 238000007796 conventional method Methods 0.000 description 1
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- 239000011258 core-shell material Substances 0.000 description 1
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- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
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- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 230000008821 health effect Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
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- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- PYIHTIJNCRKDBV-UHFFFAOYSA-L trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;dichloride Chemical group [Cl-].[Cl-].C[N+](C)(C)CCCCCC[N+](C)(C)C PYIHTIJNCRKDBV-UHFFFAOYSA-L 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
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- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
- C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/10—Lubricating oil
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
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| US20405708P | 2008-12-31 | 2008-12-31 | |
| US12/655,128 US8394255B2 (en) | 2008-12-31 | 2009-12-23 | Integrated hydrocracking and dewaxing of hydrocarbons |
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| US8992764B2 (en) * | 2010-06-29 | 2015-03-31 | Exxonmobil Research And Engineering Company | Integrated hydrocracking and dewaxing of hydrocarbons |
| US9200218B2 (en) | 2011-03-31 | 2015-12-01 | Exxonmobil Research And Engineering Company | Fuels hydrocracking with dewaxing of fuel products |
| CA2842164C (en) * | 2011-07-20 | 2018-04-17 | Exxonmobil Research And Engineering Company | Production of lubricating oil basestocks |
| CA2846456C (en) * | 2011-09-13 | 2018-11-20 | Exxonmobil Research And Engineering Company | Process for the production of diesel fuel and lubricant base oil |
| US9809762B2 (en) * | 2011-12-15 | 2017-11-07 | Exxonmobil Research And Engineering Company | Saturation process for making lubricant base oils |
| CN104114275B (zh) * | 2011-12-23 | 2018-05-25 | 国际壳牌研究有限公司 | 制备加氢裂化催化剂的方法 |
| US20130165717A1 (en) * | 2011-12-23 | 2013-06-27 | Exxonmobil Research And Engineering Company | Process for increased production of fcc gasoline |
| CN103773467B (zh) * | 2012-10-24 | 2015-12-02 | 中国石油化工股份有限公司 | 一种加氢异构脱蜡生产润滑油基础油的方法 |
| CN107723022B (zh) | 2013-03-14 | 2021-04-27 | 精炼技术解决方案有限责任公司 | 用于通过全液氢化处理和脱蜡改善中间馏分原料的冷流特性并增加其收率的方法 |
| US9719034B2 (en) * | 2013-12-23 | 2017-08-01 | Exxonmobil Research And Engineering Company | Co-production of lubricants and distillate fuels |
| WO2016041901A1 (en) * | 2014-09-16 | 2016-03-24 | Haldor Topsøe A/S | Production of high quality diesel fuel and lubricant from high boiling aromatic carbonaceous material |
| US10227536B2 (en) | 2014-12-01 | 2019-03-12 | Uop Llc | Methods for alternating production of distillate fuels and lube basestocks from heavy hydrocarbon feed |
| CN106675643B (zh) * | 2015-11-11 | 2018-03-16 | 中国石油化工股份有限公司 | 一种劣质柴油降凝改质方法 |
| CN106675642B (zh) * | 2015-11-11 | 2018-03-16 | 中国石油化工股份有限公司 | 一种低凝柴油的生产方法 |
| CN106675644B (zh) * | 2015-11-11 | 2018-03-16 | 中国石油化工股份有限公司 | 一种低硫、低凝柴油的生产方法 |
| CN106675641B (zh) * | 2015-11-11 | 2018-03-16 | 中国石油化工股份有限公司 | 一种优质低凝柴油的生产方法 |
| WO2017112558A1 (en) * | 2015-12-21 | 2017-06-29 | Exxonmobil Research And Engineering Company | Trim dewaxing of distillate fuel |
| US10035962B2 (en) * | 2015-12-21 | 2018-07-31 | Exxonmobil Research And Engineering Company | Trim dewaxing of distillate fuel |
| CA3009094A1 (en) | 2015-12-21 | 2017-06-29 | Exxonmobil Research And Engineering Company | Base metal dewaxing catalyst |
| US10647925B2 (en) | 2015-12-28 | 2020-05-12 | Exxonmobil Research And Engineering Company | Fuel components from hydroprocessed deasphalted oils |
| US20170183578A1 (en) | 2015-12-28 | 2017-06-29 | Exxonmobil Research And Engineering Company | Bright stock production from low severity resid deasphalting |
| US10590360B2 (en) | 2015-12-28 | 2020-03-17 | Exxonmobil Research And Engineering Company | Bright stock production from deasphalted oil |
| WO2017136637A1 (en) | 2016-02-05 | 2017-08-10 | Uop Llc | Process for producing diesel from a hydrocarbon stream |
| US10457877B2 (en) * | 2016-03-31 | 2019-10-29 | Exxonmobil Research And Engineering Company | Lubricant basestock production with enhanced aromatic saturation |
| US10494579B2 (en) | 2016-04-26 | 2019-12-03 | Exxonmobil Research And Engineering Company | Naphthene-containing distillate stream compositions and uses thereof |
| JP2017218538A (ja) * | 2016-06-09 | 2017-12-14 | Ｊｘｔｇエネルギー株式会社 | 潤滑油基油の製造方法 |
| US10472581B2 (en) | 2016-06-30 | 2019-11-12 | Uop Llc | Process and apparatus for hydrocracking and hydroisomerizing a hydrocarbon stream |
| CN114479983A (zh) | 2016-08-03 | 2022-05-13 | 埃克森美孚研究工程公司 | 用于生产高性能基础油料的萃余油加氢转化 |
| CA3038902A1 (en) * | 2016-10-14 | 2018-04-19 | Exxonmobil Research And Engineering Company | Lubricant basestock production with enhanced aromatic saturation |
| EP3589401A1 (en) | 2017-03-03 | 2020-01-08 | Exxonmobil Research And Engineering Company | Trimetallic base metal hdn+hds+dewaxing catalysts, their preparation and use |
| EP3618958A1 (en) | 2017-05-05 | 2020-03-11 | ExxonMobil Research and Engineering Company | Noble metal and base metal dewaxing catalyst |
| CA3061358A1 (en) | 2017-05-05 | 2018-11-08 | Exxonmobil Research And Engineering Company | Methods for regenerating and rejuvenating catalysts |
| JP7137585B2 (ja) * | 2017-06-07 | 2022-09-14 | エクソンモービル・テクノロジー・アンド・エンジニアリング・カンパニー | 原油からのディーゼルおよびベースストックの製造 |
| EP3681985B1 (en) | 2017-09-11 | 2023-04-05 | ExxonMobil Chemical Patents Inc. | Hydrocarbon fluids and uses thereof |
| TWI891600B (zh) | 2017-12-21 | 2025-08-01 | 美商艾克頌美孚技術工程公司 | 第ⅲ類基礎油及潤滑油組成物 |
| TW201930575A (zh) | 2017-12-21 | 2019-08-01 | 美商艾克頌美孚研究工程公司 | 具有經改善的低溫性能之潤滑劑組成物 |
| TW201934734A (zh) | 2017-12-21 | 2019-09-01 | 美商艾克頌美孚研究工程公司 | 具有改良的氧化效能之潤滑劑組成物 |
| TWI873087B (zh) | 2017-12-21 | 2025-02-21 | 美商艾克頌美孚技術工程公司 | 第ⅲ類基礎油及潤滑劑組成物 |
| US10808189B2 (en) | 2018-05-07 | 2020-10-20 | Exxonmobil Research And Engineering Company | Process for production of base stocks |
| EP3844249B1 (en) | 2018-08-30 | 2025-09-10 | Shell Internationale Research Maatschappij B.V. | Process for producing hazy-free at 0°c heavy base oil |
| CN116056786A (zh) * | 2020-07-29 | 2023-05-02 | 雪佛龙美国公司 | 进料灵活的加氢裂化操作 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002088279A1 (en) * | 2001-04-26 | 2002-11-07 | Exxonmobil Research And Engineering Company | Process for isomerization dewaxing of hydrocarbon streams |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US659313A (en) * | 1900-02-07 | 1900-10-09 | Einar Morterud | Apparatus for manufacturing cellulose. |
| US3900427A (en) * | 1970-12-28 | 1975-08-19 | Exxon Research Engineering Co | Hydroprocessing catalyst |
| US4397827A (en) * | 1979-07-12 | 1983-08-09 | Mobil Oil Corporation | Silico-crystal method of preparing same and catalytic conversion therewith |
| US4575416A (en) * | 1984-07-16 | 1986-03-11 | Mobil Oil Corporation | Hydrodewaxing with mixed zeolite catalysts |
| US4599162A (en) * | 1984-12-21 | 1986-07-08 | Mobil Oil Corporation | Cascade hydrodewaxing process |
| US4784745A (en) * | 1987-05-18 | 1988-11-15 | Mobil Oil Corporation | Catalytic upgrading of FCC effluent |
| IN171776B (enExample) * | 1987-10-22 | 1993-01-02 | Mobil Oil Corp | |
| US5603824A (en) * | 1994-08-03 | 1997-02-18 | Mobil Oil Corporation | Hydrocarbon upgrading process |
| US6569313B1 (en) * | 1995-12-22 | 2003-05-27 | Exxonmobil Research And Engineering Company | Integrated lubricant upgrading process |
| CN1054153C (zh) * | 1997-09-10 | 2000-07-05 | 中国石油化工总公司 | 一种生产中间馏份油的加氢裂化催化剂 |
| CZ303253B6 (cs) * | 1998-11-06 | 2012-06-20 | Institut Francais Du Petrole | Zpusob výroby oleju a stredních destilátu vysoké kvality a zarízení k provádení tohoto zpusobu |
| US6534437B2 (en) * | 1999-01-15 | 2003-03-18 | Akzo Nobel N.V. | Process for preparing a mixed metal catalyst composition |
| CA2391272A1 (en) * | 1999-07-28 | 2001-02-08 | Dinah C. Huang | Hydrogenation catalysts |
| US20040108250A1 (en) * | 2002-10-08 | 2004-06-10 | Murphy William J. | Integrated process for catalytic dewaxing |
| US6787026B2 (en) * | 2002-10-28 | 2004-09-07 | Chevron U.S.A. Inc. | Process for the production of high quality base oils |
| US7638667B2 (en) * | 2003-03-21 | 2009-12-29 | Uop Llc | Hydrocarbon conversion processes using a catalyst comprising a UZM-8HS composition |
| US7179365B2 (en) * | 2003-04-23 | 2007-02-20 | Exxonmobil Research And Engineering Company | Process for producing lubricant base oils |
| TWI450762B (zh) * | 2005-12-13 | 2014-09-01 | Exxonmobil Res & Eng Co | 具有高活性之ｚｓｍ-４８及用以去蠟之方法 |
| US7482300B2 (en) * | 2005-12-13 | 2009-01-27 | Exxonmobil Research And Engineering Company | High activity ZSM-48 and methods for dewaxing |
| US7594991B2 (en) * | 2007-12-28 | 2009-09-29 | Exxonmobil Research And Engineering Company | All catalytic medicinal white oil production |
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- 2009-12-30 BR BRPI0922275A patent/BRPI0922275A2/pt not_active IP Right Cessation
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- 2009-12-30 RU RU2011129062/04A patent/RU2011129062A/ru not_active Application Discontinuation
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Patent Citations (1)
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| WO2002088279A1 (en) * | 2001-04-26 | 2002-11-07 | Exxonmobil Research And Engineering Company | Process for isomerization dewaxing of hydrocarbon streams |
Also Published As
| Publication number | Publication date |
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| EP2486108A4 (en) | 2013-01-16 |
| CN102264871A (zh) | 2011-11-30 |
| JP5584699B2 (ja) | 2014-09-03 |
| BRPI0922275A2 (pt) | 2019-09-24 |
| RU2011129062A (ru) | 2013-02-10 |
| JP2012514052A (ja) | 2012-06-21 |
| CN102264871B (zh) | 2014-04-16 |
| US20100187155A1 (en) | 2010-07-29 |
| US8394255B2 (en) | 2013-03-12 |
| MY152287A (en) | 2014-09-15 |
| EP2486108A1 (en) | 2012-08-15 |
| TW201035303A (en) | 2010-10-01 |
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