CN102264871B - 烃的联合加氢裂化和脱蜡 - Google Patents

烃的联合加氢裂化和脱蜡 Download PDF

Info

Publication number
CN102264871B
CN102264871B CN200980150071.7A CN200980150071A CN102264871B CN 102264871 B CN102264871 B CN 102264871B CN 200980150071 A CN200980150071 A CN 200980150071A CN 102264871 B CN102264871 B CN 102264871B
Authority
CN
China
Prior art keywords
dewaxing
zsm
hydrocracking
surface area
effluent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN200980150071.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN102264871A (zh
Inventor
G·P·施莱克尔
S·J·麦卡锡
W·F·莱
K·M·普伦蒂斯
M·达格
C·G·奥利韦里
T·F·戴格南
J·G·桑蒂斯特班
A·B·单德卡尔
W·J·诺瓦克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Priority claimed from PCT/US2009/006738 external-priority patent/WO2010077352A1/en
Publication of CN102264871A publication Critical patent/CN102264871A/zh
Application granted granted Critical
Publication of CN102264871B publication Critical patent/CN102264871B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/12Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/04Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/207Acid gases, e.g. H2S, COS, SO2, HCN
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02Gasoline
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04Diesel oil
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10Lubricating oil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
CN200980150071.7A 2008-12-31 2009-12-30 烃的联合加氢裂化和脱蜡 Expired - Fee Related CN102264871B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US20405708P 2008-12-31 2008-12-31
US61/204,057 2008-12-31
US12/655,128 US8394255B2 (en) 2008-12-31 2009-12-23 Integrated hydrocracking and dewaxing of hydrocarbons
US12/655,128 2009-12-23
PCT/US2009/006738 WO2010077352A1 (en) 2008-12-16 2009-12-30 Integrated hydrocracking and dewaxing of hydrocarbons

Publications (2)

Publication Number Publication Date
CN102264871A CN102264871A (zh) 2011-11-30
CN102264871B true CN102264871B (zh) 2014-04-16

Family

ID=42353307

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200980150071.7A Expired - Fee Related CN102264871B (zh) 2008-12-31 2009-12-30 烃的联合加氢裂化和脱蜡

Country Status (8)

Country Link
US (1) US8394255B2 (enExample)
EP (1) EP2486108A4 (enExample)
JP (1) JP5584699B2 (enExample)
CN (1) CN102264871B (enExample)
BR (1) BRPI0922275A2 (enExample)
MY (1) MY152287A (enExample)
RU (1) RU2011129062A (enExample)
TW (1) TWI466995B (enExample)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8992764B2 (en) * 2010-06-29 2015-03-31 Exxonmobil Research And Engineering Company Integrated hydrocracking and dewaxing of hydrocarbons
US9200218B2 (en) 2011-03-31 2015-12-01 Exxonmobil Research And Engineering Company Fuels hydrocracking with dewaxing of fuel products
CA2842164C (en) * 2011-07-20 2018-04-17 Exxonmobil Research And Engineering Company Production of lubricating oil basestocks
CA2846456C (en) * 2011-09-13 2018-11-20 Exxonmobil Research And Engineering Company Process for the production of diesel fuel and lubricant base oil
US9809762B2 (en) * 2011-12-15 2017-11-07 Exxonmobil Research And Engineering Company Saturation process for making lubricant base oils
CN104114275B (zh) * 2011-12-23 2018-05-25 国际壳牌研究有限公司 制备加氢裂化催化剂的方法
US20130165717A1 (en) * 2011-12-23 2013-06-27 Exxonmobil Research And Engineering Company Process for increased production of fcc gasoline
CN103773467B (zh) * 2012-10-24 2015-12-02 中国石油化工股份有限公司 一种加氢异构脱蜡生产润滑油基础油的方法
CN107723022B (zh) 2013-03-14 2021-04-27 精炼技术解决方案有限责任公司 用于通过全液氢化处理和脱蜡改善中间馏分原料的冷流特性并增加其收率的方法
US9719034B2 (en) * 2013-12-23 2017-08-01 Exxonmobil Research And Engineering Company Co-production of lubricants and distillate fuels
WO2016041901A1 (en) * 2014-09-16 2016-03-24 Haldor Topsøe A/S Production of high quality diesel fuel and lubricant from high boiling aromatic carbonaceous material
US10227536B2 (en) 2014-12-01 2019-03-12 Uop Llc Methods for alternating production of distillate fuels and lube basestocks from heavy hydrocarbon feed
CN106675643B (zh) * 2015-11-11 2018-03-16 中国石油化工股份有限公司 一种劣质柴油降凝改质方法
CN106675642B (zh) * 2015-11-11 2018-03-16 中国石油化工股份有限公司 一种低凝柴油的生产方法
CN106675644B (zh) * 2015-11-11 2018-03-16 中国石油化工股份有限公司 一种低硫、低凝柴油的生产方法
CN106675641B (zh) * 2015-11-11 2018-03-16 中国石油化工股份有限公司 一种优质低凝柴油的生产方法
WO2017112558A1 (en) * 2015-12-21 2017-06-29 Exxonmobil Research And Engineering Company Trim dewaxing of distillate fuel
US10035962B2 (en) * 2015-12-21 2018-07-31 Exxonmobil Research And Engineering Company Trim dewaxing of distillate fuel
CA3009094A1 (en) 2015-12-21 2017-06-29 Exxonmobil Research And Engineering Company Base metal dewaxing catalyst
US10647925B2 (en) 2015-12-28 2020-05-12 Exxonmobil Research And Engineering Company Fuel components from hydroprocessed deasphalted oils
US20170183578A1 (en) 2015-12-28 2017-06-29 Exxonmobil Research And Engineering Company Bright stock production from low severity resid deasphalting
US10590360B2 (en) 2015-12-28 2020-03-17 Exxonmobil Research And Engineering Company Bright stock production from deasphalted oil
WO2017136637A1 (en) 2016-02-05 2017-08-10 Uop Llc Process for producing diesel from a hydrocarbon stream
US10457877B2 (en) * 2016-03-31 2019-10-29 Exxonmobil Research And Engineering Company Lubricant basestock production with enhanced aromatic saturation
US10494579B2 (en) 2016-04-26 2019-12-03 Exxonmobil Research And Engineering Company Naphthene-containing distillate stream compositions and uses thereof
JP2017218538A (ja) * 2016-06-09 2017-12-14 Jxtgエネルギー株式会社 潤滑油基油の製造方法
US10472581B2 (en) 2016-06-30 2019-11-12 Uop Llc Process and apparatus for hydrocracking and hydroisomerizing a hydrocarbon stream
CN114479983A (zh) 2016-08-03 2022-05-13 埃克森美孚研究工程公司 用于生产高性能基础油料的萃余油加氢转化
CA3038902A1 (en) * 2016-10-14 2018-04-19 Exxonmobil Research And Engineering Company Lubricant basestock production with enhanced aromatic saturation
EP3589401A1 (en) 2017-03-03 2020-01-08 Exxonmobil Research And Engineering Company Trimetallic base metal hdn+hds+dewaxing catalysts, their preparation and use
EP3618958A1 (en) 2017-05-05 2020-03-11 ExxonMobil Research and Engineering Company Noble metal and base metal dewaxing catalyst
CA3061358A1 (en) 2017-05-05 2018-11-08 Exxonmobil Research And Engineering Company Methods for regenerating and rejuvenating catalysts
JP7137585B2 (ja) * 2017-06-07 2022-09-14 エクソンモービル・テクノロジー・アンド・エンジニアリング・カンパニー 原油からのディーゼルおよびベースストックの製造
EP3681985B1 (en) 2017-09-11 2023-04-05 ExxonMobil Chemical Patents Inc. Hydrocarbon fluids and uses thereof
TWI891600B (zh) 2017-12-21 2025-08-01 美商艾克頌美孚技術工程公司 第ⅲ類基礎油及潤滑油組成物
TW201930575A (zh) 2017-12-21 2019-08-01 美商艾克頌美孚研究工程公司 具有經改善的低溫性能之潤滑劑組成物
TW201934734A (zh) 2017-12-21 2019-09-01 美商艾克頌美孚研究工程公司 具有改良的氧化效能之潤滑劑組成物
TWI873087B (zh) 2017-12-21 2025-02-21 美商艾克頌美孚技術工程公司 第ⅲ類基礎油及潤滑劑組成物
US10808189B2 (en) 2018-05-07 2020-10-20 Exxonmobil Research And Engineering Company Process for production of base stocks
EP3844249B1 (en) 2018-08-30 2025-09-10 Shell Internationale Research Maatschappij B.V. Process for producing hazy-free at 0°c heavy base oil
CN116056786A (zh) * 2020-07-29 2023-05-02 雪佛龙美国公司 进料灵活的加氢裂化操作

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1032810A (zh) * 1987-10-22 1989-05-10 无比石油公司 催化加氢脱蜡的方法
US5603824A (en) * 1994-08-03 1997-02-18 Mobil Oil Corporation Hydrocarbon upgrading process
CN1210881A (zh) * 1997-09-10 1999-03-17 中国石油化工总公司 一种生产中间馏份油的加氢裂化催化剂

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US659313A (en) * 1900-02-07 1900-10-09 Einar Morterud Apparatus for manufacturing cellulose.
US3900427A (en) * 1970-12-28 1975-08-19 Exxon Research Engineering Co Hydroprocessing catalyst
US4397827A (en) * 1979-07-12 1983-08-09 Mobil Oil Corporation Silico-crystal method of preparing same and catalytic conversion therewith
US4575416A (en) * 1984-07-16 1986-03-11 Mobil Oil Corporation Hydrodewaxing with mixed zeolite catalysts
US4599162A (en) * 1984-12-21 1986-07-08 Mobil Oil Corporation Cascade hydrodewaxing process
US4784745A (en) * 1987-05-18 1988-11-15 Mobil Oil Corporation Catalytic upgrading of FCC effluent
US6569313B1 (en) * 1995-12-22 2003-05-27 Exxonmobil Research And Engineering Company Integrated lubricant upgrading process
CZ303253B6 (cs) * 1998-11-06 2012-06-20 Institut Francais Du Petrole Zpusob výroby oleju a stredních destilátu vysoké kvality a zarízení k provádení tohoto zpusobu
US6534437B2 (en) * 1999-01-15 2003-03-18 Akzo Nobel N.V. Process for preparing a mixed metal catalyst composition
CA2391272A1 (en) * 1999-07-28 2001-02-08 Dinah C. Huang Hydrogenation catalysts
US6652735B2 (en) * 2001-04-26 2003-11-25 Exxonmobil Research And Engineering Company Process for isomerization dewaxing of hydrocarbon streams
US20040108250A1 (en) * 2002-10-08 2004-06-10 Murphy William J. Integrated process for catalytic dewaxing
US6787026B2 (en) * 2002-10-28 2004-09-07 Chevron U.S.A. Inc. Process for the production of high quality base oils
US7638667B2 (en) * 2003-03-21 2009-12-29 Uop Llc Hydrocarbon conversion processes using a catalyst comprising a UZM-8HS composition
US7179365B2 (en) * 2003-04-23 2007-02-20 Exxonmobil Research And Engineering Company Process for producing lubricant base oils
TWI450762B (zh) * 2005-12-13 2014-09-01 Exxonmobil Res & Eng Co 具有高活性之zsm-48及用以去蠟之方法
US7482300B2 (en) * 2005-12-13 2009-01-27 Exxonmobil Research And Engineering Company High activity ZSM-48 and methods for dewaxing
US7594991B2 (en) * 2007-12-28 2009-09-29 Exxonmobil Research And Engineering Company All catalytic medicinal white oil production

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1032810A (zh) * 1987-10-22 1989-05-10 无比石油公司 催化加氢脱蜡的方法
US5603824A (en) * 1994-08-03 1997-02-18 Mobil Oil Corporation Hydrocarbon upgrading process
CN1210881A (zh) * 1997-09-10 1999-03-17 中国石油化工总公司 一种生产中间馏份油的加氢裂化催化剂

Also Published As

Publication number Publication date
EP2486108A4 (en) 2013-01-16
CN102264871A (zh) 2011-11-30
JP5584699B2 (ja) 2014-09-03
BRPI0922275A2 (pt) 2019-09-24
RU2011129062A (ru) 2013-02-10
JP2012514052A (ja) 2012-06-21
TWI466995B (zh) 2015-01-01
US20100187155A1 (en) 2010-07-29
US8394255B2 (en) 2013-03-12
MY152287A (en) 2014-09-15
EP2486108A1 (en) 2012-08-15
TW201035303A (en) 2010-10-01

Similar Documents

Publication Publication Date Title
CN102264871B (zh) 烃的联合加氢裂化和脱蜡
CN102971401B (zh) 烃类的联合加氢裂化和脱蜡
AU2009333803B2 (en) Integrated hydrocracking and dewaxing of hydrocarbons
CN102959054B (zh) 烃的联合加氢裂化和脱蜡
CN102264872B (zh) 用于润滑剂基油生产的酸性作业氢加工
US7625478B2 (en) Hydroprocessing with blended ZSM-48 catalysts
KR101671545B1 (ko) 탄화수소의 통합된 수첨분해 및 탈랍 방법

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140416

Termination date: 20201230