TWI455821B - 具有改良抗毀損及刮傷性之用於裝飾金屬的塗料及應用方法 - Google Patents
具有改良抗毀損及刮傷性之用於裝飾金屬的塗料及應用方法 Download PDFInfo
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- TWI455821B TWI455821B TW97126528A TW97126528A TWI455821B TW I455821 B TWI455821 B TW I455821B TW 97126528 A TW97126528 A TW 97126528A TW 97126528 A TW97126528 A TW 97126528A TW I455821 B TWI455821 B TW I455821B
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4488—Cathodic paints
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/259—Silicic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/269—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31681—Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/31765—Inorganic-containing or next to inorganic-containing
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Polyurethanes Or Polyureas (AREA)
Claims (14)
- 一種在導電基板上形成抗磨損塗層之方法，其包含：(a)將包含以下各物之可固化可電沈積組合物電沈積於具有大於400之鏡面光澤之裝飾金屬基板上：(i)可固化樹脂黏合劑，(ii)無機粒子，(iii)表面活性劑；(b)使該組合物固化以在該基板上形成具有暴露於大氣之表面的連續透明塗層，其中在該固化塗層之暴露表面下方至少20奈米延伸至150奈米之該暴露表面區域中之粒子濃度係大於該固化塗層之表面區域下方延伸之主體區域。
- 如請求項1之方法，其中該可固化樹脂組合物包含：(a)含有反應性官能基之離子型成膜樹脂，(b)具有可與(a)之該等反應性官能基反應之官能基的固化劑。
- 如請求項2之方法，其中該離子型成膜樹脂含有陽離子基團。
- 如請求項2之方法，其中該等陽離子基團係選自胺鹽及鋶鹽基團。
- 如請求項4之方法，其中該離子型成膜樹脂為含有陽離子基團及活性氫基團之(甲基)丙烯酸系樹脂。
- 如請求項5之方法，其中該固化劑為聚異氰酸酯。
- 如請求項1之方法，其中該等無機粒子具有小於1000奈 米之粒度。
- 如請求項1之方法，其中該等無機粒子具有大於5之莫氏硬度值。
- 如請求項1之方法，其中該等無機粒子為膠狀二氧化矽。
- 如請求項1之方法，其中該等無機粒子以該組合物之總重量計係以0.5至10wt%之量存在於該組合物中。
- 如請求項1之方法，其中該表面活性劑為聚矽氧烷。
- 如請求項11之方法，其中該聚矽氧烷具有以下結構式：R1 R2 -SiO(4-n-m)2 ，其中可相同或不同之各R1 係選自H、OH、單價烴基或單價矽氧烷基；可相同或不同之各R2 為具有至少一個可與該樹脂黏合劑中之該等官能基反應之官能基的基團，其中0<n<4，0<m<4且2(m+n)<4。
- 如請求項11之方法，其中該聚矽氧烷具有以下結構式： 其中：m具有至少1之值；m'在0至75之範圍內； n在0至75之範圍內；n'在0至75之範圍內；可相同或不同之各R係選自H、OH、單價烴基、單價矽氧烷基及任何上述基團之混合物；且Ra 包含以下結構；-R3 -X，其中-R3 係選自伸烷基、氧基伸烷基、伸烷基芳基、伸烯基、氧基伸烯基及伸烯基芳基；且X表示包含至少一個選自以下之反應性官能基之基團：羥基、羧基、異氰酸酯基、封端聚異氰酸酯基、一級胺基、二級胺基、醯胺基、胺基甲酸酯基、脲基、胺甲酸酯基、乙烯基、不飽和酯基、順丁烯二醯亞胺基、反丁烯二酸酯基、酸酐基、羥基烷基醯胺基及環氧基。
- 如請求項1之方法，其中該表面活性劑以該組合物中固體之重量計係以0.5至10wt%之量存在於該組合物中。
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/776,102 US20090017294A1 (en) | 2007-07-11 | 2007-07-11 | Coating for decorative metals with improved mar and scratch resistance and methods of application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200918303A TW200918303A (en) | 2009-05-01 |
| TWI455821B true TWI455821B (zh) | 2014-10-11 |
Family
ID=39816859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW97126528A TWI455821B (zh) | 2007-07-11 | 2008-07-11 | 具有改良抗毀損及刮傷性之用於裝飾金屬的塗料及應用方法 |
Country Status (12)
| Country | Link |
|---|---|
| US (4) | US20090017294A1 (zh) |
| EP (1) | EP2173821A2 (zh) |
| JP (1) | JP5180301B2 (zh) |
| KR (1) | KR101183734B1 (zh) |
| CN (1) | CN101815760B (zh) |
| AR (1) | AR067524A1 (zh) |
| BR (1) | BRPI0812599A2 (zh) |
| HK (1) | HK1143389A1 (zh) |
| MY (1) | MY157931A (zh) |
| RU (1) | RU2437896C2 (zh) |
| TW (1) | TWI455821B (zh) |
| WO (1) | WO2009009641A2 (zh) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090017294A1 (en) * | 2007-07-11 | 2009-01-15 | Ppg Industries Ohio, Inc. | Coating for decorative metals with improved mar and scratch resistance and methods of application |
| CN102443834A (zh) * | 2011-12-12 | 2012-05-09 | 南昌航空大学 | 钕铁硼永磁材料表面颗粒增强有机防腐涂层的制备方法 |
| US20140072815A1 (en) * | 2012-09-12 | 2014-03-13 | Ppg Industries Ohio, Inc. | Curable film-forming compositions demonstrating burnish resistance and low gloss |
| US10093829B2 (en) * | 2012-10-19 | 2018-10-09 | Ppg Industries Ohio, Inc. | Curable film-forming compositions demonstrating burnish resistance and low gloss, and methods of improving burnish resistance of a substrate |
| CN103333532A (zh) * | 2013-07-11 | 2013-10-02 | 合肥旭阳铝颜料有限公司 | 水性铜金粉的制备方法 |
| DE202015004389U1 (de) * | 2015-06-20 | 2015-07-09 | Rolf Espe | Beschichtung von Holzwerkstoffplatten mit Aminoplastharzfilmen, die mit einer abriebfesten, easy clean und hydrophoben Oberfläche ausgerüstet sind |
| MX2018011790A (es) | 2016-03-30 | 2018-12-17 | Ppg Coatings Tianjin Co Ltd | Revestimientos difusores y reflectantes de luz. |
| US11008453B2 (en) * | 2018-01-16 | 2021-05-18 | Arkema France | Polymeric composite articles comprising the heterogeneous surface/bulk distribution of discrete phase |
| WO2020066597A1 (ja) * | 2018-09-26 | 2020-04-02 | 富士フイルム株式会社 | 積層体 |
| KR20230096703A (ko) | 2021-12-23 | 2023-06-30 | 원광대학교산학협력단 | 블록이소시아네이트 그룹이 그라프팅된 실리카 나노입자 및 이를 포함하는 코팅 조성물 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1376175A (zh) * | 1999-07-30 | 2002-10-23 | 匹兹堡玻璃板工业俄亥俄股份有限公司 | 具有改进抗刮性的固化涂层、涂覆基材及其有关方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54101795A (en) * | 1978-01-30 | 1979-08-10 | Toyo Soda Mfg Co Ltd | Hydrophobic rendering method for oxide fine powder |
| US4881975A (en) * | 1986-12-23 | 1989-11-21 | Albright & Wilson Limited | Products for treating surfaces |
| GB8729797D0 (en) * | 1987-12-22 | 1988-02-03 | Ici Plc | Co-polymer |
| DE3803628A1 (de) * | 1988-02-06 | 1989-08-17 | Bayer Ag | Verwendung von aminogruppen aufweisenden polysiloxanen als zusatzmittel in kunststofflacken |
| US5063254A (en) * | 1988-04-04 | 1991-11-05 | Loctite Corporation | MTQ/polysiloxane hybrid resins, method of making the same, and coating/potting compositions containing the same |
| JPH11137097A (ja) * | 1997-11-14 | 1999-05-25 | Achilles Corp | 農業用合成樹脂製フィルム |
| JP3919915B2 (ja) * | 1997-12-16 | 2007-05-30 | 神東塗料株式会社 | 耐擦り傷性に優れた電着塗料組成物およびその電着塗装方法 |
| JP2001158953A (ja) * | 1999-12-03 | 2001-06-12 | Nkk Corp | 高光沢Ａｌ−Ｚｎ系合金めっき鋼板及びその製造方法 |
| JP2001246433A (ja) * | 2000-03-02 | 2001-09-11 | Shigeru Co Ltd | 耐傷付き性に優れたステンレスエンボス鋼板及びその製造方法 |
| US6902828B2 (en) * | 2001-04-09 | 2005-06-07 | Alcoa Inc. | Bright products obtained by continuous casting |
| JP4017477B2 (ja) * | 2001-09-14 | 2007-12-05 | 新日鉄マテリアルズ株式会社 | シリカ系コーティング液、およびそれを用いたシリカ系コーティング膜ならびにシリカ系コーティング膜被覆基材 |
| JP2003129005A (ja) * | 2001-10-19 | 2003-05-08 | Kansai Paint Co Ltd | アニオン電着塗料 |
| US6790904B2 (en) * | 2002-06-03 | 2004-09-14 | Ppg Industries Ohio, Inc. | Liquid coating of film-forming resin and particles chemically modified to lower surface tension |
| CN100376646C (zh) * | 2002-08-21 | 2008-03-26 | 捷时雅株式会社 | 涂料组合物 |
| JP2005113030A (ja) * | 2003-10-08 | 2005-04-28 | Asahi Kasei Chemicals Corp | 水性汚染防止被覆組成物 |
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| US7247697B2 (en) * | 2004-10-22 | 2007-07-24 | Acushnet Company | Coating compositions for use in golf balls |
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| US20090017294A1 (en) * | 2007-07-11 | 2009-01-15 | Ppg Industries Ohio, Inc. | Coating for decorative metals with improved mar and scratch resistance and methods of application |
| JP5581311B2 (ja) * | 2008-04-22 | 2014-08-27 | ボストン サイエンティフィック サイムド，インコーポレイテッド | 無機材料のコーティングを有する医療デバイス及びその製造方法 |
-
2007
- 2007-07-11 US US11/776,102 patent/US20090017294A1/en not_active Abandoned
-
2008
- 2008-07-10 CN CN2008801020664A patent/CN101815760B/zh not_active Expired - Fee Related
- 2008-07-10 BR BRPI0812599 patent/BRPI0812599A2/pt not_active IP Right Cessation
- 2008-07-10 RU RU2010104667A patent/RU2437896C2/ru not_active IP Right Cessation
- 2008-07-10 WO PCT/US2008/069602 patent/WO2009009641A2/en active Application Filing
- 2008-07-10 KR KR1020107002869A patent/KR101183734B1/ko active IP Right Grant
- 2008-07-10 JP JP2010516237A patent/JP5180301B2/ja not_active Expired - Fee Related
- 2008-07-10 EP EP20080781592 patent/EP2173821A2/en not_active Withdrawn
- 2008-07-10 MY MYPI2010000026A patent/MY157931A/en unknown
- 2008-07-11 AR ARP080103000 patent/AR067524A1/es unknown
- 2008-07-11 TW TW97126528A patent/TWI455821B/zh not_active IP Right Cessation
-
2010
- 2010-08-04 US US12/850,135 patent/US9045655B2/en not_active Expired - Fee Related
- 2010-08-04 US US12/850,155 patent/US8377577B2/en active Active
- 2010-10-18 HK HK10109822A patent/HK1143389A1/xx not_active IP Right Cessation
-
2012
- 2012-11-02 US US13/667,002 patent/US8632895B2/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1376175A (zh) * | 1999-07-30 | 2002-10-23 | 匹兹堡玻璃板工业俄亥俄股份有限公司 | 具有改进抗刮性的固化涂层、涂覆基材及其有关方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US8377577B2 (en) | 2013-02-19 |
| KR101183734B1 (ko) | 2012-09-17 |
| JP2010533088A (ja) | 2010-10-21 |
| WO2009009641A3 (en) | 2009-03-05 |
| CN101815760A (zh) | 2010-08-25 |
| EP2173821A2 (en) | 2010-04-14 |
| US20090017294A1 (en) | 2009-01-15 |
| TW200918303A (en) | 2009-05-01 |
| KR20100039399A (ko) | 2010-04-15 |
| BRPI0812599A2 (pt) | 2015-02-18 |
| US20100294668A1 (en) | 2010-11-25 |
| RU2437896C2 (ru) | 2011-12-27 |
| US20100316867A1 (en) | 2010-12-16 |
| AR067524A1 (es) | 2009-10-14 |
| US9045655B2 (en) | 2015-06-02 |
| US20130056356A1 (en) | 2013-03-07 |
| HK1143389A1 (en) | 2010-12-31 |
| CN101815760B (zh) | 2013-07-17 |
| US8632895B2 (en) | 2014-01-21 |
| WO2009009641A2 (en) | 2009-01-15 |
| RU2010104667A (ru) | 2011-08-20 |
| JP5180301B2 (ja) | 2013-04-10 |
| MY157931A (en) | 2016-08-15 |
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