TWI377914B - - Google Patents

Download PDF

Info

Publication number
TWI377914B
TWI377914B TW095120664A TW95120664A TWI377914B TW I377914 B TWI377914 B TW I377914B TW 095120664 A TW095120664 A TW 095120664A TW 95120664 A TW95120664 A TW 95120664A TW I377914 B TWI377914 B TW I377914B
Authority
TW
Taiwan
Prior art keywords
amount
vitamin
weight
protein
beverage
Prior art date
Application number
TW095120664A
Other languages
Chinese (zh)
Other versions
TW200715997A (en
Inventor
Satoshi Shinozaki
Toshimasa Higuchi
Ryoko Ishikawa
Original Assignee
Calpis Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Calpis Co Ltd filed Critical Calpis Co Ltd
Publication of TW200715997A publication Critical patent/TW200715997A/en
Application granted granted Critical
Publication of TWI377914B publication Critical patent/TWI377914B/zh

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/66Proteins
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/42Preservation of non-alcoholic beverages
    • A23L2/44Preservation of non-alcoholic beverages by adding preservatives
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/68Acidifying substances
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/15Vitamins
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/17Amino acids, peptides or proteins
    • A23L33/175Amino acids
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/17Amino acids, peptides or proteins
    • A23L33/18Peptides; Protein hydrolysates
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

Description

1377914 九、發明說明: 【發明所屬之技術領域】 其製造方法及其異臭 本發明係關於一種飲料用組合物 防止方法。 【先前技術】 維生素B2係作為黃素酶之辅酶 .^ ^ ^ 胞内之氧化還原系 或線粒體中之電子傳達系中發揮 枋^ 谭作用,且廣泛與糖質、脂1377914 IX. Description of the Invention: [Technical Field of the Invention] The manufacturing method thereof and the odor thereof The present invention relates to a method for preventing a composition for beverages. [Prior Art] Vitamin B2 acts as a coenzyme of flavoprotein. ^ ^ ^ Intracellular redox system or electron transport system in mitochondria plays a role in 谭^ 谭, and is widely associated with saccharides and lipids.

質、蛋白質等之生物體内代謝有關之維生素。維生素 有如下作用:有助於成長與生殖;保持健康之皮膚指 甲毛髮,緩和口腔内、唇、壬夕〆产 0 ^ 。舌之炎症;增進視力、減輕 眼睛疲勞;與其他物質一起進行糖、脂肪、蛋白質之新陳 代謝;有助於向細胞釋放能量;有助於形成紅血球,故而 作為營養補給食品之添加物而頻繁使用。 維生素B2具有水溶性,即使攝取過量,多於必需量者亦 會迅速排泄出體外,故而幾乎沒有過量攝取所導致之障 礙。又,並未確認維生素以具有毒性。因此,經常與其他 維生素Β類組合而用作補充品之成分。 蛋白質水解物具有優良之消化吸收性’廣泛用作營養補 助食品或功能性食品之原料。又,報告有··蛋白質水解物 中所含有之各種肽’具有抗高血壓作用、肌肉疲勞恢復、 促進脂質代謝作用、免疫活化作用等。 然而,發現會產生如下問題:若將蛋白f水解物與維生 素B2共同添加於飲料品中,則該飲料曝露於光下之情形 時’會產生異臭。於鍵劑或粉末形態時,乡見之組合^蛋 1119l5.doc 1377914 白質水解物+維生素B2+維生素c,故而一般認為此種異 臭問題為液體所特有者。 已知維生素B2具有水溶性,對於酸或熱具有較強性質, 但會由強光或驗而破壞。因此,僅含有維生素於之情形 時’可能產生維生素B2之光分解問題,但此時不會產:異 臭。又,若僅存有,維生素B2之光分解問題,可藉由茶瓶獲 得遮光效果,但無法解決異臭之問題。 • 因此’業者正尋求一種解決將添加有蛋白質水解物與維 生素B2之飲料曝露於光下時產生異臭的問題之方法。 於曰本專利特開2005-110649中揭示一種方法,其藉由 添加自羅漢果萃取之萃取物及海藻糖,而改善肽之臭味。 又,於日本專利特開2〇〇6_111566中揭示有一種方法其 藉由於含有蛋胺酸與維生素B2類之内服液劑中加入活性^ 產生抑制成分或聚甘油脂肪酸酯,而抑制不良氣味。 [專利文獻1]日本專利特開2005·110649 # [專利文獻2]日本專利特開2006-111566 [發明所欲解決之問題] 本發明之目的在於提供—種改善將蛋白質水解物與維生 素Β2之組合物曝露於光下時產生之異臭的技術。 【發明内容】 本發明者發現:藉由於添加有蛋白f水解物與維生素幻 之飲料中添加抗壞血酸,可獲得明顯改善異臭之效果, 而完成本發明。 本發明提供—種飲料用組合物’其含有蛋白質水解物與 111915.doc 問1。較好是抗壞血酸之量相對於胺基酸之量為*倍以上 (重量基準),更好是10倍以上(重量基準)。 蛋白質水解物係以蛋白質分解酶將蛋白質分解而獲得, 並含有肽及游離胺基酸之混合物。較好的是,蛋白質水解 物含有30%以上胺基酸。作為蛋白質水解物,若為純化至 °用作p…者,則可使用任—種,例如,可使用藉由以蛋 白質分解酶分解路蛋白或大豆蛋白質而獲得之蛋白質水解 物。作為蛋白質分解酶,若為可將蛋白質分解成狀,可使 用於食品製造用之等級之酶’則可使用任一種,例如,可 列舉來自米麴菌之蛋白質分解 刀鮮輙蛋白質水解物相對於 飲料品添加〇.01〜10.0重量%,較好是添加〇 〇5 %。 里 維生素Β2,若為純化至可用作食品添加物者,可使用市 ^之任—種。維生細相對於飲料品添加0.嶋〜0.02重 量%,較好是添加〇.〇〇〇1〜〇〇1重量%。 於添加有蛋白質水解物與維生素Β2之飲料中進而亦可 加入果汁、乳製品、糖類、甘味料、香料、增黏劑、pH調 郎劑、著色劑等。 於本說明書巾日月確引用之專利及參考讀之内容,全部 作為本說明書之-部分引用於此。又,作為本申請案主張 優先權之基礎的申請案之日本專利申請案蘭·ΐ7ΐ2_ 之說明書及圖式所揭示之内容’全部作為本說明書之一部 分而引用於此。 [實施例] H1915.doc C S ) 1377914 以下藉由實施例詳細說明本路 y Λ 〜μ +發明,但本發明並不限定於 該等實施例。再者,只要並+姓 禾特別言及下述揭示之處方的 單位,則%表示重量%。 實施例1 蛋白質水解物之製造 於99 g調整至約80〇C之墓餾水φ 士 λ ,山从> Α Α …糊八干加入1 g由牛乳而來之酪 蛋白(日本NZMP公司)’充分授拌後,加入1 _氧化納(和 光純藥公司製造)溶液製成ρΗ值7〇,又,將溫度調整至 2〇°C,製備基質溶液。 於所獲得之基質溶液中,以蛋白質分解酶/酪蛋白之重 量比為1/25之方式添加由米麴菌而來之蛋白質分解酶(斯米 ;^姆??(§主冊商標)、新曰本化學工業公司製造),於5〇<^ 反應14小時’繼而於110t:進行1〇分鐘高壓蒸氣滅菌處 理’使酶失活’而獲得路蛋白酶分解物溶液。其次,將獲 得之酶分解物溶液藉由喷霧乾燥機乾燥,製備粉末。 使用凱氏法、胺基酸分析裝置分析該酪蛋白酶分解物 時、確認粉末中含有35.8%胺基酸、45.7%肽。另,自蛋白 質量減去胺基酸量之差可計算肽含量。 含有蛋白質水解物之飲料之製造 製造含有下述成分之調合液。 111915.doc 1377914 [表i] 砂糖 12% 檸檬酸 0.75% 酪蛋白酶分解物 0.65% 核醣黃素磷酸酯鈉(維生素B2) 0.0078% 香料 0.15% 将樣酸三納 0.03% 計 100% 於根據上述表製備之調合液中,添加所定量之作為抗氧 化劑之抗壞血酸、芸香苷、楊梅萃取物、綠原酸或石榴萃 取物,溶解後,於96°C殺菌30秒,填充於100 mL茶褐色壇 中,藉此製備含有酪蛋白分解物及維生素B2之營養飲料。 官能評價 於15°C環境下,對各種飲料進行20000勒克斯χ7天之螢 光燈照射。香氣之劣化藉由1 〇名飲料研究員,與未添加抗 氧化劑而保存於冷暗所(5°C )之調合液(對照品)進行比較, 而實施官能評價。又,作為對照,對未添加酪蛋白酶分解 物而製備之調合液亦進行評價。根據以下評價基準,而算 出各試料之評價平均分。 評價基準 3分:與對照品比較,大致沒有變化。 2分:與對照品比較,有香味之變質。 1分:與對照品比較,有顯著之香味變質。 111915.doc 1377914 [表2] 抗氧化劑之種類 添加量(ppm) 平均評價分 (n=10) 抗壞血酸/ 胺基酸比 抗壞血酸 5000 2.3 21 2500 2.2 11 1000 1.6 4.3 500 1.3 2.1 芸香苷 100 1.0 - 揚梅萃取物 100 1.0 - 綠原酸 100 1.1 - 石榴萃取物 50 1.1 - 無添加 0 1.0 - 未添加酪蛋白分解物 0 2.8 - 根據以上結果可確認,藉由於添加有蛋白質水解物與維 生素B2之飲料中加入抗壞血酸,具有可改善曝露於光下時 產生之異臭之效果。 實施例2 形成異臭之原因之肽原料之研究 製備與添加維生素B2 —併添加肽原料之飲料,調查曝露 於光下時產生之異臭。作為肽原料,可使用酪蛋白肽及大 豆肽。 [表3] 原料 添加量 砂糖 5 g 檸檬酸 0.35 g 磷酸核醣黃素鈉 0.007766 g 狀原料 各種狀原料· 0.65 g 檸檬酸三鈉 0.18 g 水 使全量符合100 ml 製備含有上述成分之調合液,於96°C殺菌30秒,填充於 100 ml茶褐色壇中。 111915.doc 12· 1377914 於15°C環境下,對各種飲料進行20000勒克斯χ5天之螢 光燈照射。香氣之劣化藉由1 〇名飲料研究員,與保存於冷 暗所(5°C)之調合液(對照品)進行比較,而實施官能評價。 根據以下評價基準,算出各試料之評價平均分。 評價基準 3分:與對照品比較,大致沒有變化。 2分:與對照品比較,有香味之變質。 1分:與對照品比較,有顯著之香味變質。 結果示於表4。 [表4] 原料 胺基酸含量 平均評價分(n= 10) 狀原料 酪蛋白肽 36% 0.5 大豆肽 77% 0.1 根據以上結果,一般認為,含有胺基酸之肽原料與維生 素B2之組合藉由光而劣化,因此產生異臭。 [產業上之可利用性] 本發明係對製造含有維生素B2之飲料有用者。 111915.doc -13A vitamin related to the metabolism of a substance such as a substance or a protein. Vitamins have the following effects: help to grow and reproduce; maintain healthy skin nails, and ease the production of oral, lip, and sputum 0 ^. Inflammation of the tongue; improve vision, reduce eye fatigue; carry out metabolism of sugar, fat and protein together with other substances; help release energy to cells; help to form red blood cells, and therefore frequently used as an additive to nutritional supplement foods. Vitamin B2 is water-soluble, and even if it is ingested excessively, more than necessary amount is quickly excreted from the body, so there is almost no obstacle caused by excessive intake. Also, vitamins were not confirmed to be toxic. Therefore, it is often used as a supplement in combination with other vitamins. Protein hydrolysates have excellent digestive absorption' and are widely used as raw materials for nutritional supplements or functional foods. Further, various peptides contained in the protein hydrolyzate have been reported to have antihypertensive action, muscle fatigue recovery, promotion of lipid metabolism, and immune activation. However, it has been found that if the protein f hydrolyzate is added to the beverage product together with the vitamin B2, the beverage will be odorous when exposed to light. In the case of a key or powder form, the combination of the township ^1 1119l5.doc 1377914 white matter hydrolysate + vitamin B2 + vitamin c, it is generally considered that this problem of odor is liquid-specific. Vitamin B2 is known to be water-soluble and has strong properties for acid or heat, but is destroyed by strong light or by inspection. Therefore, when vitamins are only contained, the photodegradation of vitamin B2 may occur, but at this time, it will not produce: odor. Moreover, if there is only a problem of photolysis of vitamin B2, the shading effect can be obtained by the tea bottle, but the problem of the odor cannot be solved. • Therefore, the industry is seeking a solution to the problem of odor generated when a beverage containing protein hydrolysate and vitamin B2 is exposed to light. A method for improving the odor of a peptide by adding an extract extracted from Luo Han Guo and trehalose is disclosed in Japanese Laid-Open Patent Publication No. 2005-110649. Further, a method disclosed in Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. [Patent Document 1] Japanese Patent Laid-Open No. 2005-110649 # [Patent Document 2] Japanese Patent Laid-Open No. 2006-111566 [Problems to be Solved by the Invention] An object of the present invention is to provide an improved protein hydrolysate and vitamin Β2 A technique in which the composition is exposed to odor when exposed to light. SUMMARY OF THE INVENTION The present inventors have found that an effect of remarkably improving an offensive odor can be obtained by adding ascorbic acid to a beverage containing a protein f hydrolyzate and a vitamin phantom beverage, and the present invention has been completed. The present invention provides a beverage composition which contains a protein hydrolysate and 111915.doc. The amount of ascorbic acid is preferably * times or more (by weight), more preferably 10 times or more (by weight) based on the amount of the amino acid. The protein hydrolysate is obtained by decomposing a protein with a proteolytic enzyme and contains a mixture of a peptide and a free amino acid. Preferably, the protein hydrolysate contains more than 30% of the amino acid. As the protein hydrolyzate, any one may be used as the p to be purified, and for example, a protein hydrolyzate obtained by decomposing a road protein or a soybean protein with a protein decomposing enzyme may be used. As the proteolytic enzyme, any protein that can be used for the production of foods can be used as the protein-decomposing enzyme. For example, a protein-decomposing knife from rice bran bacteria can be used as a protein hydrolysate. The beverage product is added in an amount of 〇01 to 10.0% by weight, preferably 〇〇5%. Vitamin Β2, if purified for use as a food additive, can be used in the city. The vitamins are added in an amount of 0.1% by weight to 0.02% by weight, preferably 〇.〇〇〇1~〇〇1% by weight. Further, a juice, a dairy product, a saccharide, a sweetener, a flavoring agent, a tackifier, a pH adjusting agent, a coloring agent, or the like may be added to the beverage to which the protein hydrolyzate and the vitamin Β2 are added. The contents of the patents and referenced readings which are hereby incorporated by reference in this specification are hereby incorporated by reference. In addition, the contents disclosed in the specification and drawings of the Japanese Patent Application Laid-Open No. Hei. [Examples] H1915.doc C S ) 1377914 Hereinafter, the present invention is described in detail by way of examples, but the present invention is not limited to the examples. In addition, % means weight % as long as the + surname is specifically expressed in the unit of the following disclosure. Example 1 Production of protein hydrolysate was adjusted to 99 g to about 80 〇C of tomb water φ 士λ, mountain from > Α Α ... paste eight dry added 1 g of casein from milk (Japan NZMP) After the mixture was sufficiently mixed, a solution of 1 _ oxidized sodium (manufactured by Wako Pure Chemical Industries, Ltd.) was added to prepare a Η value of 7 〇, and the temperature was adjusted to 2 〇 ° C to prepare a matrix solution. In the obtained matrix solution, a proteolytic enzyme derived from rice bran bacteria is added in such a manner that the weight ratio of proteolytic enzyme/casein is 1/25 (Sm.; New 曰 化学 化学 化学 。 反应 反应 ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ Next, the obtained enzyme decomposition product solution was dried by a spray dryer to prepare a powder. When the casein decomposition product was analyzed by a Kjeldahl method or an amino acid analyzer, it was confirmed that the powder contained 35.8% of an amino acid and 45.7% of a peptide. Alternatively, the peptide content can be calculated from the difference in protein mass minus the amount of amino acid. Production of a beverage containing a protein hydrolyzate A blending solution containing the following components was produced. 111915.doc 1377914 [Table i] Sugar 12% Citric acid 0.75% Casein decomposition product 0.65% Sodium riboflavin phosphate (vitamin B2) 0.0078% Perfume 0.15% 100% sodium picoate 0.03% According to the above table The prepared preparation liquid is added with a predetermined amount of ascorbic acid, rutin, bayberry extract, chlorogenic acid or pomegranate extract as an antioxidant, dissolved, and sterilized at 96 ° C for 30 seconds, and filled in 100 mL of brown tea jar. Thereby, a nutrient drink containing casein decomposition product and vitamin B2 was prepared. Functional evaluation A variety of beverages were irradiated with 20,000 lux and 7 days of fluorescent light at 15 °C. The deterioration of the aroma was compared with a blending solution (reference) which was stored in a cold dark place (5 ° C) without adding an antioxidant, and a sensory evaluation was performed. Further, as a control, a preparation liquid prepared without adding a casein decomposition product was also evaluated. The evaluation average score of each sample was calculated based on the following evaluation criteria. Evaluation Criteria 3 points: There was almost no change compared with the control. 2 points: Compared with the control, there is a deterioration of the fragrance. 1 point: Compared with the control, there is significant deterioration of the flavor. 111915.doc 1377914 [Table 2] Antioxidant type addition amount (ppm) Average evaluation score (n=10) Ascorbic acid/amino acid ratio ascorbic acid 5000 2.3 21 2500 2.2 11 1000 1.6 4.3 500 1.3 2.1 Rutin 100 1.0 - Yang Plum extract 100 1.0 - Chlorogenic acid 100 1.1 - Pomegranate extract 50 1.1 - No added 0 1.0 - No casein decomposition product added 0 2.8 - Based on the above results, it was confirmed that the beverage was added with protein hydrolysate and vitamin B2 The addition of ascorbic acid has the effect of improving the odor generated when exposed to light. Example 2 Study of peptide raw materials for causing odor formation A beverage containing vitamin B2 and adding a peptide raw material was prepared, and the odor generated when exposed to light was investigated. As the peptide material, a casein peptide and a soybean peptide can be used. [Table 3] Raw material added amount of sugar 5 g Citric acid 0.35 g Phosphorus riboflavin sodium 0.007766 g Shaped raw materials Various raw materials · 0.65 g Trisodium citrate 0.18 g Water The whole amount is 100 ml Compatible to prepare a blending solution containing the above ingredients, Sterilize at 96 ° C for 30 seconds and fill in 100 ml tea brown jar. 111915.doc 12· 1377914 A variety of beverages were irradiated with 20,000 lux and 5 days of fluorescent light at 15 °C. The deterioration of the aroma was evaluated by a 1st drink researcher comparing with a blending solution (reference) stored in a cool dark (5 ° C). The evaluation average score of each sample was calculated based on the following evaluation criteria. Evaluation Criteria 3 points: There was almost no change compared with the control. 2 points: Compared with the control, there is a deterioration of the fragrance. 1 point: Compared with the control, there is significant deterioration of the flavor. The results are shown in Table 4. [Table 4] The average evaluation value of the amino acid content of the raw material (n = 10) The raw material casein peptide 36% 0.5 Soy peptide 77% 0.1 Based on the above results, it is generally considered that the combination of the amino acid-containing peptide raw material and the vitamin B2 is used. It is deteriorated by light, and thus an offensive odor is generated. [Industrial Applicability] The present invention is useful for producing a beverage containing vitamin B2. 111915.doc -13

Claims (1)

質水解物與維生素B2之混合物,該混合物含有相對於胺 L377914 •十、申請專利範圍: 1. 一種飲料用組合物 第095120664號專利申請案1(P^·鼻6日夢ιΤ弋 中文申請專利範圍替換本(l〇j年2^ >二+ 基酸之量為4倍以上(重量基準)、相對於飲料用組合物之 量為0.1〜3.0重量%之抗壞血酸。 2. 如咕求項1之飲料用組合物,其中蛋白質水解物係以蛋 白質分解酶水解酪蛋白而複得者。 3. 一種含有蛋白質水解物與維生素Β2之飲料組合物之異臭 防止方法’其特徵在於:於包含3 0%以上胺基酸之蛋白 質水解物與維生素Β2之混合物中,加入相對於胺基酸之 量為4倍以上(重量基準)、相對於飲料用組合物之量為 0.1〜3.0重量%之抗壞血酸。 4. 如請求項3之方法,其中蛋白質水解物係以蛋白質分解 酶水解酪蛋白而獲得者。 5. 一種含有蛋白質水解物與維生素Β2之飲料用組合物之製 造方法’其特徵在於:於包含3〇%以上胺基酸之蛋白質 水解物與維生素Β2之混合物中,加入相對於胺基酸之量 為4倍以上(重量基準)、相對於飲料用組合物之量為 〜3.0重量%之抗壞血酸。 6.如睛求項5之方法,其中蛋白質水解物係以蛋白質分解 酶水解酪蛋白而獲得者。 一種含有包含30。/。以上胺基酸之蛋白質水解物與維生素 Β2之飲料用組合物之異臭防止劑,其以相對於胺基酸之 量為4倍以上(重量基準)、相對於飲料用組合物之量為 111915-1010206.doc 1377914 0.1〜3.0重量%之抗壞血酸為主要成分。 8.如請求項7之異臭防止劑,其中蛋白質水解物係以蛋白 質分解酶水解酷蛋白而獲得者。 111915-1010206.doca mixture of a hydrolysate and a vitamin B2, the mixture containing relative to the amine L377914 • Ten, the scope of the patent application: 1. A beverage composition No. 095120664 Patent Application 1 (P^·Nose 6 Days Dream Τ弋 Chinese application for patent The range is replaced by the amount of ascorbic acid in an amount of from 0.1 to 3.0% by weight based on the amount of the composition for beverages, which is 4 times or more (by weight), and the amount of the composition for beverages. A beverage composition according to claim 1, wherein the protein hydrolyzate is obtained by hydrolyzing casein with a proteolytic enzyme. 3. A method for preventing malodor of a beverage composition containing protein hydrolysate and vitamin Β2, characterized in that it comprises 3 The mixture of the protein hydrolyzate of 0% or more of the amino acid and the vitamin Β2 is added in an amount of 4 times or more (by weight) based on the amount of the amino acid, and the amount of the ascorbic acid is 0.1 to 3.0% by weight based on the amount of the beverage composition. 4. The method of claim 3, wherein the protein hydrolysate is obtained by hydrolyzing casein with a proteolytic enzyme. 5. A beverage group containing protein hydrolysate and vitamin Β2. The method for producing a composition is characterized in that a mixture of a protein hydrolyzate containing 3% by weight or more of an amino acid and a vitamin Β2 is added in an amount of 4 times or more (by weight) relative to the amount of the amino acid, relative to the beverage. The amount of the composition is -3.0% by weight of ascorbic acid. 6. The method of claim 5, wherein the protein hydrolysate is obtained by hydrolyzing casein with a proteolytic enzyme. One contains an amino acid containing 30% or more. The odor preventing agent for the beverage composition of the protein hydrolyzate and the vitamin Β2 is 4 times or more (by weight) based on the amount of the amino acid, and the amount of the composition for the beverage is 111915-1010206.doc 1377914 0.1 to 3.0% by weight of ascorbic acid is a main component. 8. The odor preventing agent according to claim 7, wherein the protein hydrolyzate is obtained by hydrolyzing a cool protein with a proteolytic enzyme. 111915-1010206.doc
TW095120664A 2005-06-10 2006-06-09 Method for prevention of formation of abnormal odor in beverage composition TW200715997A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005171227 2005-06-10

Publications (2)

Publication Number Publication Date
TW200715997A TW200715997A (en) 2007-05-01
TWI377914B true TWI377914B (en) 2012-12-01

Family

ID=37498547

Family Applications (1)

Application Number Title Priority Date Filing Date
TW095120664A TW200715997A (en) 2005-06-10 2006-06-09 Method for prevention of formation of abnormal odor in beverage composition

Country Status (7)

Country Link
US (1) US8128978B2 (en)
EP (1) EP1894478A4 (en)
JP (1) JP5248109B2 (en)
CN (1) CN101193562B (en)
CA (1) CA2615651A1 (en)
TW (1) TW200715997A (en)
WO (1) WO2006132353A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5359218B2 (en) * 2007-11-22 2013-12-04 大正製薬株式会社 Beverage
JP5739166B2 (en) * 2011-01-07 2015-06-24 ハウス食品グループ本社株式会社 Onion beverage composition with reduced odor
PL2920052T3 (en) 2012-11-14 2017-07-31 Waterbox Oy Arrangement and method for underwater activities
WO2016042634A1 (en) * 2014-09-18 2016-03-24 花王株式会社 5-caffeoylquinic acid-containing bottled beverage
JP2019062784A (en) * 2017-09-29 2019-04-25 株式会社 伊藤園 Container packed beverage, manufacturing method therefor and nasty smell generation inhibition method thereof

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60203174A (en) * 1984-03-28 1985-10-14 Karupisu Shokuhin Kogyo Kk Preparation of milk-containing acidic drink having high preservability
JP2945995B2 (en) * 1989-05-12 1999-09-06 大塚製薬株式会社 Oligopeptide mixture, production thereof and nutrition feeding composition for patient of heptic disease
JPH03272643A (en) * 1990-03-20 1991-12-04 Calpis Food Ind Co Ltd:The Acid drink containing milk
US5641531A (en) * 1995-09-28 1997-06-24 Abbott Laboratories Nutritional liquid supplement beverage and method of making same
US6077828A (en) 1996-04-25 2000-06-20 Abbott Laboratories Method for the prevention and treatment of cachexia and anorexia
JPH1084866A (en) * 1996-09-13 1998-04-07 Kankoku Shokuhin Kaihatsu Kenkyuin Improvement of oxidation stability of dairy products
JPH1150828A (en) * 1997-07-31 1999-02-23 Mitsubishi Motors Corp Oil pan structure
US6207208B1 (en) 1997-10-07 2001-03-27 Labatt Brewing Company Limited Absorptive treatments for improved beer flavor stability
JPH11243866A (en) * 1998-03-05 1999-09-14 Morinaga Milk Ind Co Ltd Casein hydrolyzate and its production
US6194379B1 (en) 1998-05-01 2001-02-27 Abbott Laboratories Elemental enteral formula
CN1256954A (en) * 1998-12-17 2000-06-21 天津三凌环保技术研究所有限公司 Deodorisation filter agent
SE523771C2 (en) 1999-05-21 2004-05-18 Probi Ab Sports drinks containing micronutrients in combination with live lactobacilli
JP3983951B2 (en) * 1999-10-20 2007-09-26 株式会社 伊藤園 Nourishing tonic and nourishing tonic food and drink
JP2002119250A (en) 2000-10-17 2002-04-23 Nisshin Pharma Inc Nutritive composition
US7074881B2 (en) 2001-02-06 2006-07-11 Folia, Inc Methods of synthesis of polysuccinimide, copolymers of polysuccinimide and derivatives thereof
JP2002255846A (en) * 2001-02-26 2002-09-11 Sunstar Inc Oral composition
JPWO2002094039A1 (en) * 2001-05-18 2004-09-02 日清オイリオ株式会社 Foods for improving protein / energy undernutrition
BR0210680A (en) 2001-07-18 2004-09-21 Dsm Ip Assets Bv Process for the hydrolysis of milk proteins
US20030099753A1 (en) * 2001-11-20 2003-05-29 Yang Baokang Juice based beverage compositions
JP2003304847A (en) * 2002-04-11 2003-10-28 Tamura Pharmaceutical Co Ltd Liquid drinking composition containing coenzyme q10
JP3899436B2 (en) * 2002-05-10 2007-03-28 フォーデイズ株式会社 Healthy drink with water soluble nucleoprotein
JP4684525B2 (en) * 2002-10-31 2011-05-18 アサヒ飲料株式会社 Micronutrient enriched food and drink
JP2005110649A (en) 2003-10-03 2005-04-28 Sansho Kk Beverage added with peptide
JP5040060B2 (en) 2004-10-14 2012-10-03 大正製薬株式会社 Methionine combination oral solution
JP4505322B2 (en) * 2004-12-28 2010-07-21 焼津水産化学工業株式会社 Jelly drink

Also Published As

Publication number Publication date
EP1894478A4 (en) 2011-02-02
US8128978B2 (en) 2012-03-06
CA2615651A1 (en) 2006-12-14
US20090220647A1 (en) 2009-09-03
JP5248109B2 (en) 2013-07-31
CN101193562A (en) 2008-06-04
TW200715997A (en) 2007-05-01
EP1894478A1 (en) 2008-03-05
CN101193562B (en) 2012-10-10
JPWO2006132353A1 (en) 2009-01-08
WO2006132353A1 (en) 2006-12-14

Similar Documents

Publication Publication Date Title
TW200848064A (en) Process for producing osteocalcin-containing extract
WO2011108692A1 (en) Agent for preventing muscular atrophy
WO2013051556A1 (en) Drink composition
TWI377914B (en)
TW201041524A (en) Lipid metabolism-improving agent
JP2002034592A (en) Method for producing protein-zinc readily absorbable in body
JP4642321B2 (en) Method for producing tryptophan-rich peptide
JP2006514550A (en) Nutritional supplement compositions and methods
WO2007090504A1 (en) Hydrolysed collagen and uses therof
JP5044957B2 (en) Copper compound composition
JPWO2005087022A1 (en) Food composition having anti-stress effect
WO1990013228A1 (en) Oligopeptide mixture and composition containing the same
JP5355809B1 (en) Beverage
KR20100114974A (en) A functional beverage comprising deep sea water, extract of black garlic, extract of jujubae fructus and organic acid
JPWO2006115153A1 (en) Food composition for improving skin condition
JP4712256B2 (en) High-grade chicken extract-containing functional food and method for producing the same
JP4781970B2 (en) Method for masking unpleasant odor and unpleasant taste of nutritional supplements
JP2006199641A (en) Iron-adsorbing polymer substance, iron-containing polymer substance and method for producing the same
JP6803796B2 (en) Offensive taste improver and offensive odor improver derived from protein or peptide
WO2008049942A1 (en) Enzymatic collagen hydrolysate and method for obtaining same
JPH07215851A (en) Antiallergic agent and its production
JP2001046016A (en) Yeast-incorporated mineral-enriched liquid food
JP2019041696A (en) Oral composition
JP3905989B2 (en) Water for food and drink
JP2808281B2 (en) Protein foods and physiological supplements

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees