TWI352096B - - Google Patents
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- Publication number
- TWI352096B TWI352096B TW096132724A TW96132724A TWI352096B TW I352096 B TWI352096 B TW I352096B TW 096132724 A TW096132724 A TW 096132724A TW 96132724 A TW96132724 A TW 96132724A TW I352096 B TWI352096 B TW I352096B
- Authority
- TW
- Taiwan
- Prior art keywords
- modified
- expanded graphite
- thermosetting polymer
- group
- composite material
- Prior art date
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 84
- 229910002804 graphite Inorganic materials 0.000 claims description 69
- 239000010439 graphite Substances 0.000 claims description 69
- 229920001187 thermosetting polymer Polymers 0.000 claims description 55
- 239000004634 thermosetting polymer Substances 0.000 claims description 43
- 239000002131 composite material Substances 0.000 claims description 39
- 238000006243 chemical reaction Methods 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 26
- 239000003607 modifier Substances 0.000 claims description 25
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 23
- 239000000178 monomer Substances 0.000 claims description 16
- 239000002243 precursor Substances 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 8
- 125000003545 alkoxy group Chemical group 0.000 claims description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
- XRNDMACZMJPCRX-UHFFFAOYSA-N C(CC)C(C(OCC)(OCC)OCC)CCCCCCCC Chemical compound C(CC)C(C(OCC)(OCC)OCC)CCCCCCCC XRNDMACZMJPCRX-UHFFFAOYSA-N 0.000 claims description 3
- LAENUTMFTKEICI-UHFFFAOYSA-N N(=C=O)CCCC(C(OCC)(OCC)OCC)CCCCCCCC Chemical compound N(=C=O)CCCC(C(OCC)(OCC)OCC)CCCCCCCC LAENUTMFTKEICI-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 125000003700 epoxy group Chemical group 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 239000004640 Melamine resin Substances 0.000 claims description 2
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 2
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical group CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 125000000466 oxiranyl group Chemical group 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- FXPCFGZWQHOKJF-UHFFFAOYSA-N 4-(1,1-diethoxyethyl)dodecan-1-amine Chemical compound NCCCC(C(OCC)(OCC)C)CCCCCCCC FXPCFGZWQHOKJF-UHFFFAOYSA-N 0.000 claims 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims 2
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 claims 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims 2
- AGGJWJFEEKIYOF-UHFFFAOYSA-N 1,1,1-triethoxydecane Chemical compound CCCCCCCCCC(OCC)(OCC)OCC AGGJWJFEEKIYOF-UHFFFAOYSA-N 0.000 claims 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- JHSSAIPXYATQGW-UHFFFAOYSA-N NCCCC(CCCCCCCCC)(OCC)OCC Chemical compound NCCCC(CCCCCCCCC)(OCC)OCC JHSSAIPXYATQGW-UHFFFAOYSA-N 0.000 claims 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000006612 decyloxy group Chemical group 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 229920001568 phenolic resin Polymers 0.000 claims 1
- 239000005011 phenolic resin Substances 0.000 claims 1
- 239000012704 polymeric precursor Substances 0.000 claims 1
- 230000035939 shock Effects 0.000 claims 1
- 125000003396 thiol group Chemical group [H]S* 0.000 claims 1
- 229920006337 unsaturated polyester resin Polymers 0.000 claims 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 229920000620 organic polymer Polymers 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000003063 flame retardant Substances 0.000 description 6
- 239000002861 polymer material Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- 239000011147 inorganic material Substances 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 239000012769 display material Substances 0.000 description 2
- 239000000383 hazardous chemical Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910021382 natural graphite Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- LNOLJFCCYQZFBQ-BUHFOSPRSA-N (ne)-n-[(4-nitrophenyl)-phenylmethylidene]hydroxylamine Chemical compound C=1C=C([N+]([O-])=O)C=CC=1C(=N/O)/C1=CC=CC=C1 LNOLJFCCYQZFBQ-BUHFOSPRSA-N 0.000 description 1
- YMTRNELCZAZKRB-UHFFFAOYSA-N 3-trimethoxysilylaniline Chemical compound CO[Si](OC)(OC)C1=CC=CC(N)=C1 YMTRNELCZAZKRB-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- DYFFAVRFJWYYQO-UHFFFAOYSA-N n-methyl-n-phenylaniline Chemical compound C=1C=CC=CC=1N(C)C1=CC=CC=C1 DYFFAVRFJWYYQO-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 125000005429 oxyalkyl group Chemical group 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- FRGPKMWIYVTFIQ-UHFFFAOYSA-N triethoxy(3-isocyanatopropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCN=C=O FRGPKMWIYVTFIQ-UHFFFAOYSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
- C08K5/5455—Silicon-containing compounds containing nitrogen containing at least one group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
- Fireproofing Substances (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW096132724A TW200904878A (en) | 2007-07-17 | 2007-09-03 | Composite material of modified expansible graphite /modified thermosetting polymer |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW96126008 | 2007-07-17 | ||
| TW096132724A TW200904878A (en) | 2007-07-17 | 2007-09-03 | Composite material of modified expansible graphite /modified thermosetting polymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200904878A TW200904878A (en) | 2009-02-01 |
| TWI352096B true TWI352096B (enExample) | 2011-11-11 |
Family
ID=40472411
Family Applications (6)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW096132719A TWI385203B (zh) | 2007-07-17 | 2007-09-03 | The modified graphite with modified double - key siloxane modifier and its preparation method |
| TW096132720A TW200904877A (en) | 2007-07-17 | 2007-09-03 | Composite material of modified expansible graphite /modified thermoplastic polymer |
| TW096132725A TW200904955A (en) | 2007-07-17 | 2007-09-03 | Flame retarding composition of composite material containing modified expansible graphite/ thermosetting polymer |
| TW096132723A TW200904909A (en) | 2007-07-17 | 2007-09-03 | Modified expansible graphite by silane modifying agent and producing method thereof |
| TW096132722A TW200904954A (en) | 2007-07-17 | 2007-09-03 | Flame retarding composition of composite material containing modified expansible graphite/ thermoplastic polymer |
| TW096132724A TW200904878A (en) | 2007-07-17 | 2007-09-03 | Composite material of modified expansible graphite /modified thermosetting polymer |
Family Applications Before (5)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW096132719A TWI385203B (zh) | 2007-07-17 | 2007-09-03 | The modified graphite with modified double - key siloxane modifier and its preparation method |
| TW096132720A TW200904877A (en) | 2007-07-17 | 2007-09-03 | Composite material of modified expansible graphite /modified thermoplastic polymer |
| TW096132725A TW200904955A (en) | 2007-07-17 | 2007-09-03 | Flame retarding composition of composite material containing modified expansible graphite/ thermosetting polymer |
| TW096132723A TW200904909A (en) | 2007-07-17 | 2007-09-03 | Modified expansible graphite by silane modifying agent and producing method thereof |
| TW096132722A TW200904954A (en) | 2007-07-17 | 2007-09-03 | Flame retarding composition of composite material containing modified expansible graphite/ thermoplastic polymer |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US20090082500A1 (enExample) |
| TW (6) | TWI385203B (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011094324A2 (en) * | 2010-01-27 | 2011-08-04 | Intellectual Property Holdings, Llc | Fire -retardant polyurethane foam and process for preparing the same |
| EP2847279B1 (en) * | 2012-05-09 | 2018-11-28 | Sun Chemical Corporation | Surface modified pigment particles, method of preparation and application thereof |
| WO2013169413A1 (en) | 2012-05-09 | 2013-11-14 | Laird Technologies, Inc. | Polymer matrices functionalized with carbon-containing species for enhanced thermal conductivity |
| CN103319915B (zh) * | 2013-05-14 | 2014-07-23 | 北京理工大学 | 可膨胀石墨的改性方法 |
| WO2015175029A1 (en) * | 2014-01-30 | 2015-11-19 | University Of Houston System | Graphitic nanocomposites in solid state matrices and methods for making same |
| CN103804621B (zh) * | 2014-02-19 | 2016-03-16 | 哈尔滨工业大学 | 一种含插层石墨的阻燃聚氨酯泡沫的制备方法 |
| JP2019131765A (ja) * | 2018-02-02 | 2019-08-08 | 積水化学工業株式会社 | エポキシ樹脂組成物 |
| EP3837318B1 (en) * | 2018-08-15 | 2025-10-29 | 3M Innovative Properties Company | Silicone sealer compositions |
| CN112778754B (zh) * | 2021-01-28 | 2022-04-05 | 浙江工业大学 | 一种抗静电阻燃尼龙6复合材料的制备方法 |
| CN114213058B (zh) * | 2021-12-01 | 2022-08-09 | 青阳绿能粒子开发有限公司 | 一种改性无机粉体材料及其制备方法 |
| TWI802522B (zh) * | 2022-11-03 | 2023-05-11 | 亞東學校財團法人亞東科技大學 | 易於清理之防淹水水溝蓋結構 |
| CN118165599B (zh) * | 2024-03-22 | 2024-11-15 | 深圳嘉德高新材料有限公司 | 一种自修复阻燃涂料及其制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5760115A (en) * | 1995-03-03 | 1998-06-02 | Tosoh Corporation | Fire-retardant polymer composition |
| US5942561A (en) * | 1995-03-03 | 1999-08-24 | Tosoh Corporation | Fire-retardant polymer composition |
| EP0794229B1 (en) * | 1996-03-08 | 2006-06-07 | Tosoh Corporation | Flame retardant engineering plastic composition |
| GB0229810D0 (en) * | 2002-12-20 | 2003-01-29 | Vantico Ag | Flame retardant polymer compositions |
| EP1641425A1 (en) * | 2003-07-04 | 2006-04-05 | Nanon A/S | A method of producing a silanized composite filler and a method of producing a composite material |
| US7271206B2 (en) * | 2003-12-23 | 2007-09-18 | Industrial Technology Research Institute | Organic-inorganic hybrid compositions with sufficient flexibility, high dielectric constant and high thermal stability, and cured compositions thereof |
-
2007
- 2007-09-03 TW TW096132719A patent/TWI385203B/zh not_active IP Right Cessation
- 2007-09-03 TW TW096132720A patent/TW200904877A/zh not_active IP Right Cessation
- 2007-09-03 TW TW096132725A patent/TW200904955A/zh not_active IP Right Cessation
- 2007-09-03 TW TW096132723A patent/TW200904909A/zh not_active IP Right Cessation
- 2007-09-03 TW TW096132722A patent/TW200904954A/zh not_active IP Right Cessation
- 2007-09-03 TW TW096132724A patent/TW200904878A/zh not_active IP Right Cessation
-
2008
- 2008-06-24 US US12/145,315 patent/US20090082500A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| TWI352114B (enExample) | 2011-11-11 |
| TWI385203B (zh) | 2013-02-11 |
| TWI352104B (enExample) | 2011-11-11 |
| TW200904876A (en) | 2009-02-01 |
| TW200904955A (en) | 2009-02-01 |
| TWI352095B (enExample) | 2011-11-11 |
| TW200904877A (en) | 2009-02-01 |
| US20090082500A1 (en) | 2009-03-26 |
| TW200904909A (en) | 2009-02-01 |
| TW200904878A (en) | 2009-02-01 |
| TW200904954A (en) | 2009-02-01 |
| TWI352113B (enExample) | 2011-11-11 |
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