TWI314118B - Process for applying a layer of polyamide to a substrate, laminate made of the process, use of the laminate and packaging for foodstuffs comprising the laminate - Google Patents

Process for applying a layer of polyamide to a substrate, laminate made of the process, use of the laminate and packaging for foodstuffs comprising the laminate Download PDF

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TWI314118B
TWI314118B TW92118508A TW92118508A TWI314118B TW I314118 B TWI314118 B TW I314118B TW 92118508 A TW92118508 A TW 92118508A TW 92118508 A TW92118508 A TW 92118508A TW I314118 B TWI314118 B TW I314118B
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amine
compound
carboxylic acid
functionality
polyamine
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TW92118508A
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TW200404708A (en
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Kroon Jan De
Ted Brink
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Dsm Ip Assets Bv
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/36—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino acids, polyamines and polycarboxylic acids
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/30—Polyamides; Polyimides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00—Metals, their alloys or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2317/00—Animal or vegetable based
    • B32B2317/12—Paper, e.g. cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/04—Polyethylene
    • B32B2323/043—HDPE, i.e. high density polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/04—Polyethylene
    • B32B2323/046—LDPE, i.e. low density polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2377/00—Polyamides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/46—Pouring or allowing the fluid to flow in a continuous stream on to the surface, the entire stream being carried away by the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31725—Of polyamide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Wrappers (AREA)
  • Photoreceptors In Electrophotography (AREA)
  • Organic Insulating Materials (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Polyamides (AREA)

Description

1314118 (1) 玖、發明說明 【發明所屬之技術領域】 本發明係關於一種製造積層體的方法，其至少包括將 一層聚醯胺施加於一基材之上。 【先前技術】 此種方法係已知者，例如，可參看W0 01/40055。於 此文件中係將一紙板基材利用擠壓塗覆從紙板向外看依序 塗覆以一耐綸（nylon)層，一黏結層和一聚乙嫌層。 該已知方法的缺點在於下述事實：在高生產速度之下 ，膜形擠壓件易於變得不穩定使得基材的塗覆厚度不均勻 。此種不穩定性表現在下述事實中：仍然呈熔融態的擠壓 件不會保持平坦反而會開始展現出不規則的波浪圖樣因而 形成局部的厚度差異。通常波的幅度在基材邊緣爲最大， 因此之故，經常必須在塗覆後切除掉某一不能用的寬度部 份。若同時擠壓數層之時，此種效應會發生到甚至更大的 程度。 【發明內容】 本發明的目標爲提出一種方法用以在高速度下用至少 一層聚醯胺塗覆基材。 此目標可根據本發明達成，其中使用的聚醯胺主要爲 分枝型聚醯胺’該聚醯胺爲至少由衍生自下列的單位所構 成者： -4- 1314118 (2) a ·ΑΒ單體，其據了解係指同時具有一羧酸基（A)和一胺基 (B)的單體， b.至少一化合物I，其爲具有官能度2的羧酸（Αν)或具 有吕目έ度2的胺（βλν)， c_至少一化合物π，其爲具有官能度V 2 3的羧酸（Αν)或具 有官能度W 2 3的胺（Bw)，於化合物I爲一胺時該化合物 Π爲一羧酸’或於該化合物I爲一羧酸時化合物II爲一 胺’其中在該聚醯胺中衍生自所有羧酸和胺的單位之量滿 足公式1 P<1/[(Fa-1).(Fb-1)] ⑴ 其中 分別對於所有羧酸（Fa)和胺（Fb) p = [2(ni.fj)]x/ [Σ(η).ί|)]γ (2) 其中PS1且X = A且Y = B’或者乂 = ：6或γ = Α;且 F = Σ (n,.fi2) / Σ (m.fi) ⑶ 其中fi爲殘酸官能度（ν〇或胺的官能度（Wi)，⑴爲羧酸或 胺的莫耳數且其該加和係對該聚醯胺中衍生自羧酸和胺的 所有單位進彳7的。 所述分枝型聚酿fe係得知自WO-00/35992且其中對上 面公式中的各成分所下的定義也應用於此處。特別者，化 合物I和化合物Π也據了解爲數種具有相同官能度的羧 1314118 (3) 酸之混合物或爲具有相同官能度的數種胺之混合物。 此種材料選擇顯然可導致明顯更穩定的擠壓件，意謂 著其可實際地保持平坦，即使是在高生產速度及即使是將 數層同時施加到基材上也一樣。其結果爲可以達到更高 50%的生產速度。 此種選擇可以進一步使聚醯胺層具有十分均勻的外觀 而沒有由凝膠所造成的不規則性。非常適用於本發明方法 中者爲分枝型聚醯胺，其中己內醯胺爲最常出現的單體單 位。 本發明方法的另一項優點爲可以達到以聚醯胺層切掉 部份的形式或以塗覆著具變異厚度的聚醯胺層之基材的形 式之邊緣廢料之減少。其結果爲需要較少的起始材料來製 造相同表面的積層基材且需要回收或破壞較少的材料。 【實施方式】 積層體於此意指全盤平坦的固體基材，例如紙，紙板 ’金屬箔或片或塑膠膜。該聚醯胺層係施加到該基材上作 爲賦與該積層體該聚醯胺性質之功能層。於紙或紙板的情 況中’特別是提供對空氣，氫氣和芳香物質的障壁。此外 ’也爲了減低對濕氣的穿透性，通常也在聚醯胺層和視情 況的其他功能層上施加至少一層高密度或低密度聚乙烯。 也可以在基材上相對於聚醯胺層的背側上施加功能層。不 同材料層的適當組合本身係已知者，以用於所得積層體的 各種預期應用。塗覆著數層的此種基材都廣用於食物包裝 -6-

Claims (1)

1314118 (1) 拾、申請專利範圍 1.一種製造積層體的方法，其至少包括將一層聚醯胺 施加到一基材之上，其特徵在於該聚醯胺主要爲分枝型聚 醯胺，該聚醯胺爲至少由衍生自下列的單位所構成者： a ·ΑΒ早體，其據了解係指同時具有—羧酸基（a)和一胺基 (B)的單體， b. 至少一化合物I ’其爲具有官能度2的羧酸（Av)或具 有官能度w g 2的胺（Bw)， c. 至少一化合物II，其爲具有官能度3的羧酸（Av)或具 有官能度W 2 3的胺（Bw)，於化合物！爲一胺時該化合物 II爲一羧酸，或於該化合物〗爲一羧酸時化合物π爲一 月女’其中在該聚醯胺中衍生自所有殘酸和胺的單位之量滿 足公式1 p<1/[(Fa-1).(Fb-1)] (1) 其中 分別對於所有羧酸（FA)和胺（F0 P = l2(ni.fi)]x/[I(ni.fi)]y (2) 其中PS]且X = A且Y = B，或者X二B或Y = A;且 Ρ = Σ_2)/Σ(Μ) ⑶ 其中f,爲羧酸官能度（Vi)或胺的官能度（Wi)，η,爲羧酸或 胺的莫耳數且其該加和係對該聚醯胺中衍生自羧酸和胺的 -9- 1314118 (2) 所有單位進行的。 2 .根據申請專利範圍第1項之方法，其中該聚醯胺層 係經·由擠壓塗覆施加者。 3 .根據申請專利範圍第1或2項之方法，其中該基材爲 金屬’紙或紙板’視情況覆蓋者一層金屬箔。 4·~種積層體’其包括一基材和一主要由分枝型聚隨 胺所構成的層，該聚醯胺爲至少由衍生自下列的單位所構 成者： a. A Β單體，其據了解係指同時具有一羧酸基（幻和—胺基 (B)的單體， b. 至少一化合物I’其爲具有官能度vg2的羧酸（Αν)或具 有官能度wg 2的胺（Bw)， c. 至少一化合物Π’其爲具有官能度V2 3的羧酸（Αν)或具 有官能度W 2 3的胺（Bw)，於化合物I爲一胺時該化合物 11爲一羧酸，或於該化合物I爲一羧酸時化合物11爲一 胺，其中在該聚醯胺中衍生自所有羧酸和胺的單位之量滿 足公式1 其中 分別對於所有駿酸（F A)和胺（F B) P = [Σ(Πί.ίι)]χ/ [Σ(Π|.ίί)]γ (2) 其中且乂二八且Υ = 或者Χ = Β或Υ = Α;且 -10- 1314118 (3) F = Z (ni.fi2)/Σ (rii.fi) ⑶ 其中匕爲羧酸官能度（Vi)或胺的官能度（Wi)，ni爲殘酸或 胺的莫耳數且其該加和係對該聚醯胺中衍生自羧酸和胺的 所有單位進行的。 5 · —種根據申請專利範圍第4項之積層體對於製造食 物包裝材之用途。 6.—種食物包裝材，其包括根據申請專利範圍第4項 之積層體。
-11 -
TW92118508A 2002-07-09 2003-07-07 Process for applying a layer of polyamide to a substrate, laminate made of the process, use of the laminate and packaging for foodstuffs comprising the laminate TWI314118B (en)

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NL1021031 2002-07-09

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TWI314118B true TWI314118B (en) 2009-09-01

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US (1) US20060166021A1 (zh)
EP (1) EP1519836B1 (zh)
JP (1) JP4317128B2 (zh)
CN (1) CN100482463C (zh)
AT (1) ATE339307T1 (zh)
AU (1) AU2003253496A1 (zh)
DE (1) DE60308376T2 (zh)
DK (1) DK1519836T3 (zh)
ES (1) ES2271647T3 (zh)
TW (1) TWI314118B (zh)
WO (1) WO2004005026A1 (zh)

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ATE502771T1 (de) * 2002-06-12 2011-04-15 Dsm Ip Assets Bv Verfahren zur herstellung einer mehrschichtigen flachfolie die ein intrinsisch gelfreies, zufällig verzweigtes polyamid enthält
US20040175464A1 (en) 2003-03-07 2004-09-09 Blemberg Robert J. Multilayer structures, packages, and methods of making multilayer structures
US20040175466A1 (en) 2003-03-07 2004-09-09 Douglas Michael J. Multilayer barrier structures, methods of making the same and packages made therefrom
US20100015423A1 (en) * 2008-07-18 2010-01-21 Schaefer Suzanne E Polyamide structures for the packaging of moisture containing products
NL2004974C2 (en) 2010-06-25 2011-12-28 Ar Metallizing N V Method for producing coated vacuum metallized substrates.
DE102011054629A1 (de) * 2011-10-20 2013-04-25 Minervius Gmbh Verfahren zur Herstellung von Gegenständen aus strahlenvernetztem Polyamid
KR102242839B1 (ko) * 2019-07-26 2021-04-21 한국과학기술연구원 화학사고 후 안정성동위원소 분석을 통한 토양내 화학물질 저감 양상 모니터링을 위한 모의 실험 시스템

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US6083585A (en) * 1996-09-23 2000-07-04 Bp Amoco Corporation Oxygen scavenging condensation copolymers for bottles and packaging articles
FR2766197B1 (fr) * 1997-07-17 1999-09-03 Nyltech Italia Copolyamide thermoplastique, composition a base de ce copolyamide thermoplastique
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DE19859929A1 (de) * 1998-12-23 2000-06-29 Bayer Ag Verfahren zur Herstellung von verzweigten Polyamiden
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DE10065177A1 (de) * 2000-12-23 2002-06-27 Degussa Mehrschichtverbund auf Polyamid/Polyolefin-Basis
US6541599B1 (en) * 2001-07-31 2003-04-01 Eastman Kodak Company Process for manufacture of soluble highly branched polyamides, and at least partially aliphatic highly branched polyamides obtained therefrom

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ATE339307T1 (de) 2006-10-15
DK1519836T3 (da) 2007-01-15
US20060166021A1 (en) 2006-07-27
CN1668464A (zh) 2005-09-14
JP4317128B2 (ja) 2009-08-19
DE60308376D1 (de) 2006-10-26
CN100482463C (zh) 2009-04-29
JP2005532194A (ja) 2005-10-27
AU2003253496A1 (en) 2004-01-23
EP1519836A1 (en) 2005-04-06
DE60308376T2 (de) 2007-09-20
TW200404708A (en) 2004-04-01
WO2004005026A1 (en) 2004-01-15
ES2271647T3 (es) 2007-04-16
EP1519836B1 (en) 2006-09-13

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