TWI313626B - - Google Patents

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Publication number
TWI313626B
TWI313626B TW096124461A TW96124461A TWI313626B TW I313626 B TWI313626 B TW I313626B TW 096124461 A TW096124461 A TW 096124461A TW 96124461 A TW96124461 A TW 96124461A TW I313626 B TWI313626 B TW I313626B
Authority
TW
Taiwan
Prior art keywords
water
adhesive
mentioned
heat exchange
exchange element
Prior art date
Application number
TW096124461A
Other languages
Chinese (zh)
Other versions
TW200900176A (en
Inventor
Takada Masaru
Arai Hidemoto
Imai Takanori
Murai Michio
Tokizaki Shinya
Original Assignee
Mitsubishi Electric Corp
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Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Publication of TW200900176A publication Critical patent/TW200900176A/en
Application granted granted Critical
Publication of TWI313626B publication Critical patent/TWI313626B/zh

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D9/0025Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being formed by zig-zag bend plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D53/00Making other particular articles
    • B21D53/02Making other particular articles heat exchangers or parts thereof, e.g. radiators, condensers fins, headers
    • B21D53/04Making other particular articles heat exchangers or parts thereof, e.g. radiators, condensers fins, headers of sheet metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F3/00Plate-like or laminated elements; Assemblies of plate-like or laminated elements
    • F28F3/02Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4935Heat exchanger or boiler making

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Laminated Bodies (AREA)

Description

Η 1313626 九、發明說明: 【發明所屬之技術領域】 本發明’係關於用於 ' ^ 9 ^ 、成I調機和換氣裝置之熱交換 态,於2種氣流間進杆、、既劫+ & 仃,日熱之交換及顯埶之交換之全埶交 換元件及其製造方法者 广、、之父換《王'、、' 又 55 -y ^ ^ - 44, - ^ α 。之,係用於靜止形的熱交換 裔之全熱父換70件及其製造方法。 【先前技術】 於構成空S周機或換氣奘罢哲 ,〃裝置專之熱交換器有旋轉形與靜 止形之2種,在於任何一 * % - II ,…、父換器,熱交換效率較僅 藉由進仃顯熱之交換之顯熱 >+ , . 、70件尚的全熱交換元件較 佳地使用。全熱交換元件, ^ 數情形’係將具有片狀的區 隔構件與波板狀的間隔保持 藉由片段瓦愣製_貼之構造之長條物 材料製造。早面瓦榜機)製作,將該長條物作為 用於旋轉形之熱交換器之全 _ …、交換几件’係於上述長 條物的既定面塗佈接著劑 述長 ^ m 將D亥長條物以輪狀捲取而製 &。’用於靜止形的熱交換器之全熱交換元件 述長條物裁切成既定的大小, ’ ,,, I 1乍複數個元件構成單元 後,藉由將各元件構成單 肩積方A相郝η 乂既疋的方向層積,即藉由向 層積方向相鄰之各元件構成 致互相正交的方向層積而製Π:隔保持構件之波紋大 元件構成單元,相互夢由接# 夺’向層積方向相鄰之 邗立猎由接著劑互相接合。 用於旋轉形的熱交換器 王…又換7L件與靜止形的熱 2111-8977-PF;Ahddub 5 1313626 父換器之全熱交換元件,埶 …又換益的動作原理,對區隔 構件及間隔保制件之各個 . ^ ^ 不同。大體而言, 用於紅轉形的熱交換器之埶 ^ ,, ^ …、父換凡件,對區隔構件及間 隔保持構件之分別要求蓄 一女 …裒熱性及畜濕.放濕性。另 面’於用於靜止形的敛交換界 ,、、、父換為之全熱交換元件,由於 在2種氣流間經由區隔 .^^ —構件進仃潛熱之交換及顯熱之交 換,故對於區隔構件要求傳埶 ,,,, 矛‘、、' 旺及遵濕性,對於間隔保持 要求保持區隔構件相互之間 田 n 1 义间U確保氣流之流路的作 用’及抑制氣流的洩漏之某種程度 又町孔體遮蔽性。本發明 係關於用於靜止形熱交換器 #, …乂換70件者,故以下針 對用於靜止形之孰交換哭夕入為> & 、 心,、、、又換态之全熱交換元件做說明。 構成全熱交換元件之區Ρ播放斗、ΒΒ 匚隔構件或間隔保持構件之素 紙、紙毅與樹脂混抄之材料、樹腊、金綱。 地交換潛熱,於區隔構件之素材預先添加 例Γ❹ 性吸濕劑(透濕劑)。作為水溶性吸濕劑, 篝,诛A 4 蜀疏次虱化鈣等鹼土類金屬鹽 ΛΛ ^ V ^ 使用矽膠或強酸性或強鹼性 的離子父換樹脂脂粉體等。 例如於專利文獻1, 在认规 D载有一種全熱交換體用紙,其 係於難然性基紙之單面或替 性歿W ^ /雙面5又以吸放濕性粉體(非水溶 與膠合劑為主體之吸放濕性塗佈層,並且於上述 = 之單面設熱接著性接著劑層者。又,於專利文 獻2,3己載有一種吸附片,1 八係將粒狀吸附體部分埋沒在 t成於片基材上之接著劑屏, 人 曰错由3有微粒子吸附劑(非水 6 2111~8977-PF/Ahddub !313626 溶性吸濕劑)之吸附劑層覆蓋上、+ 體。哕 盍上述接者劑層與粒狀吸附 ’心旋轉形全熱交換器或除濕轉子等。 紙戈=文獻3’記載有一種熱交換元件,其係以牛皮 紙或透濕性或者吸渴枓 反 声茂人 …、製作區隔構件(平板狀),此外以 ,,屬泊或合成樹脂膜製作間隔保持構件 、及狀扳),於區隔槿杜,夫丄,、& 4,4、°水浴性吸濕劑者。於專利文獻 屺載有一種複合傳熱基芯,i 劑或非水溶性的加水㈣的吸濕 屬簿製作門… 區隔構件(襯塾),藉由金 m作間IM呆持構件(皺 用於全熱交換器。 指板)者。•合傳熱基芯’係 點高It文:二記載有-種熱交換器’其係藉由軟化 抄紙之= )與較該纖維軟化點低的樹脂混合 杉紙之素材製作間隔保 作為膠合劑,由献μ W ’以上述樹脂使用 製作元件槿:保持構件與區隔構件互相接合 構成單元 炎’猎由將既定個數之元件 劑層積而製造。者劑,或者使用上述樹脂作為膠合 狀的6,記載有1熱交換器,其係藉由於板 狀的夕孔質構件的單面形成呈 且於另一二, /、有工軋遮蔽忐之透濕膜,並 兮巴隔槿朱形成吸濕劑層之氣體遮蔽物製作區隔構件,將 忒&隔構件與間隔 再干 然後,於專利文獻7己=劑互相接合者。 使間P伴括Μ 4 ζ载有一種熱交換元件,其係 h保持構件(間隔板)之 密著π夕π π 成為/'有空軋遮蔽性之薄膜 夕孔質材(織布、不織布、編布、紙等)之構成,藉 2111 — 8977-PF;Ahddub 1313626 隔構件之單面全體之熱接著性 由形成於間隔板持構件或區 之接著層接著該間隔保持構件與區隔構件(區隔板)製作元 件構成單凡(早位構件)後,藉由使用水系接著劑層積既定 個數之兀件構成單元而製作者。於該熱交換樹脂之區隔構 件之構《’係例如冑彳選擇十生穿透水蒸氣之透濕膜密著於 多孔質材之構成。Η 1313626 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to the heat exchange state for the '^9^, I-modulation and ventilator, and between the two airflows, + & 仃, the exchange of daily heat and the exchange of the 之 之 之 埶 及其 及其 及其 及其 及其 者 者 者 者 者 者 者 者 者 者 者 换 换 换 换 换 换 换 换 换 换 换 换 换 换 换 换 换 换 换 换 换 换It is used for the 70-piece full heat father of the heat exchange type of the stationary type and its manufacturing method. [Prior Art] In the formation of an empty S-week or a ventilator, the heat exchangers of the 〃 device are available in two types, a rotating type and a stationary type, in any one of the *% - II, ..., the parent exchanger, and the heat exchange. The efficiency is better than the sensible heat by the exchange of sensible heat into the gt;+, and 70 pieces of the total heat exchange element are preferably used. The total heat exchange element, in the case of "number", is made of a strip material having a sheet-like partition member and a wave-plate-like space, which is made of a strip material of a segment corrugated structure. In the early face of the Wajang machine), the long strip is used as the heat exchanger for the rotary shape, and several pieces are exchanged, and the predetermined surface of the long strip is coated with the adhesive agent. The long strips of the sea are made in a round shape. 'The total heat exchange element for the heat exchanger of the stationary type is cut into a predetermined size, ',,, I 1 乍 乍 个 构成 构成 构成 构成 构成 将 将 将 将 将 将 将 将 将 将 将 将 将 将 将The layering of the phase η 乂 乂 , , , , , , , , , , , , 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层 层#夺'In the direction of the stacking, the adjacent hunts are joined by the adhesive. The heat exchanger for the rotating shape...there is a 7L piece and the static heat 2111-8977-PF; Ahddub 5 1313626 The total heat exchange element of the parent converter, 埶...the operating principle of the benefit, the partitioning member And the interval protection parts. ^ ^ Different. In general, the heat exchanger used for the red-turning heat exchanger, ^, ^ ..., the father change the parts, the partition member and the space-retaining member are required to store a female... heat and wet. Dehumidification . The other side is used in the exchange of the static shape, and the father is replaced by the full heat exchange element. Because of the exchange between the two types of airflow, the exchange of latent heat and the exchange of sensible heat. Therefore, for the partition members, it is required to pass the 埶,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, The degree of leakage of the airflow is also somewhat concealed. The present invention relates to the use of a stationary heat exchanger #, ... 乂 70, so the following is for the static shape of the exchange of crying into the >&&, heart,,, and the state of the full heat Exchange components are explained. The material constituting the whole heat exchange element, the Ρ Ρ 匚 匚 或 或 或 或 或 或 或 、 、 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 The ground exchanges latent heat, and an example of a moisture absorbent (moisture permeable agent) is added to the material of the partition member. As a water-soluble moisture absorbent, 碱, 诛A 4 碱 碱 虱 虱 虱 碱 V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V V For example, in Patent Document 1, the standard D contains a paper for total heat exchanger, which is attached to a single side of a susceptibility base paper or a substitute 殁W ^ / double sided 5 and a moisture absorbing powder (non- The water-soluble and adhesive agent is a main body of the moisture-absorbing and coating layer, and a thermal adhesive layer is provided on one side of the above = 1. Further, in Patent Documents 2 and 3, an adsorption sheet is provided, and the The granular adsorbent is partially buried in the adhesive screen which is formed on the sheet substrate, and the adsorbent layer of the microparticle adsorbent (non-aqueous 6 2111~8977-PF/Ahddub !313626 soluble moisture absorbent) Covering, + body. 哕盍 The above agent layer and granular adsorption 'heart rotating total heat exchanger or dehumidification rotor, etc.. Paper Ge = Document 3' describes a heat exchange element, which is made of kraft paper or moisture permeable. Sex or thirst 枓 枓 枓 茂 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作& 4, 4, ° water bath hygroscopic agent. In the patent document, there is a composite heat transfer core, an agent or a water-insoluble water-absorbing (4) moisture-absorbing book to make a door... a partition member (liner), with gold m as an intervening member (wrinkle) For all heat exchangers. • The heat-transfer core is a high point of the article: the second type of heat exchanger is used to make a gap between the material of the resin mixed with the softening point of the softening paper. In the mixture, the component is produced by using the above resin. The holding member and the partition member are joined to each other to form a unit. The hunting is performed by laminating a predetermined number of component agents. In the case of using the above-mentioned resin as the gel-like type 6, there is described a heat exchanger which is formed by one side of a plate-shaped etching member and is formed by the other two. The moisture permeable film is formed, and the gas barrier of the moisture absorbent layer is formed to form a partition member, and the 忒& spacer member and the spacer are further dried, and then the patent document 7 has been joined to each other. Between the P 伴 Μ ζ ζ ζ ζ ζ ζ ζ ζ ζ ζ ζ ζ ζ ζ ζ ζ 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持 保持The composition of cloth, paper, etc., by the 2111-8977-PF; Ahddub 1313626, the thermal integrity of the single-sided whole of the spacer member is formed by the spacer layer formed on the spacer member or the region, and then the spacer member and the spacer member (division) The board) is made by using a water-based adhesive to laminate a predetermined number of pieces of the constituent unit. The structure of the partition member of the heat exchange resin is, for example, a structure in which a moisture permeable film which penetrates water vapor is adhered to the porous material.

專利文獻1 :特開平1 0-153398號公報 專利文獻2 :特開20 03-25 1 1 33號公報 專利文獻3 :特開平6-1 09395號公報 專利文獻4 :特開平7-1 9789號公報 專利文獻5 :特開平1 0-5469 1號公報 專利文獻6 :特開2〇〇1-27489號公報 專利文獻7 :特開平8-2 1 9676號公報 【發明内容】 [發明所欲解決的課題] 由抑制全熱交換元件之製造成本之觀點,較使用記載 於專利文獻1之域錢體用紙或記载於專散獻2用於 吸收片之非水溶性吸濕劑,❹水溶性的吸濕劑較佳。例 如二將水溶性的吸濕劑於紙塗佈、乾燥,即可容易地製作 可得添加吸濕劑之區隔構件之良好的素材。 惟,大部分的水溶性吸濕劑’溶解於水時發生電離等 使該水(水溶液)的導電度非常社,故在具備於區隔構件 添加水溶性的吸濕劑之全熱交換元件之空調機或換氣裝 2111-8977-PF;Ahddub 8 1313626 置水溶性的吸渴齊I可能,、交站+人士 7k " b /合解於熱交換時可能產生的結露 不、商而該結露水與充電部接觸而有產生過電現象等重大的 不適之可能性。 敎 卩制如此之不適上’較藉由如專利文獻3所記载之 屬=元件或專利文獻4所記載之複合傳熱基芯,使用金 二合成樹脂膜構成間隔保持構件,或如專利文獻5所 ::熱交換器,藉由含有樹脂之混抄紙形成間隔保持構 ’猎由紙等保水性材料形成間隔保持構件較佳。 /載於專利文獻6之熱交換n m粉糊或 曰文乙歸系轉等水系接著劑將區隔構件與間隔保持構件 =接,,則雖可提高製作全熱交換元件時之作業性及接 =之#作性,但有發生實際的潛熱交換效率較由區隔構 :位之透難能之測定結果所預測之潛熱交換效率低的 。此現象,以保水性低的樹脂片等製作區隔構件之全 $交換元件並不會發生,細紙等保水性材料製作區隔構 Γ全熱交換元件所固有者。在對區隔構件之水溶性吸濕 w的添加量多的全熱交換元件,該現象會顯著地發生。 =案發明者們,在反覆解明上述現象之原因之研究之 中’者眼於使用水系接著劑,將添加水溶性吸濕劑之區隔 構件,與以保水性材料製作之間隔保持構件互相接合,則 由水系接著劑之塗佈至該水系接著劑乾燥完成接合二間, 水系接著劑之溶劑之水渗入區隔構件與間隔保持構件之雙 方’此時區隔構件中的水溶性吸濕劑的—部分經由水系接 耆劑轉移到間隔保持構件。水溶性吸濕劑由區隔構件轉移 9 2111~8977-PF;Ahddub 1313626 權保持構件的結果’在組合全熱交換元件之階段,區 隔構件無法維持該區隔構件單獨時之透濕性能,而顯示可 能會降低潛熱交換效率。 例如專利文獻7所記載之熱交換器,於間隔保持構件 :戈區隔構件之單面全體錫成熱接著性接著劑,使用該接著 劑將間隔保持構件及區隔構件熱接著製作元件構成單元 貝二於區隔構件添加水溶性的吸濕劑,可防止水溶 劑由區隔構件對間隔保持構件之轉移。但; 所記載之埶交換考,士认7 製作八… 層積既定個數之元件構成單元 王,、、、又換70件時使用水系接著劑,故此時發生水容性 =由區隔構件對間隔保持構件之轉移,於組合全執交 、晶^段無法維持區隔構件在該區隔構件單獨時之透 濕性此,而降低潛熱交換效率。 遗 本發明係有鐘於上述情形完成者 潛熱的交換效率高,且可靠j 了谷易構成 入妯上 了罪度间的空調機或換氣裝置等之 王熱父換元件為目的。又,本發明,係以得到可容易2 潛熱的交換效率高,且 易構成 入舳丄从 度间的空调機或換氣裝置等之 王熱父換元件之製造方法為目的。 專之 [用以解決課題的手段] .本發明之全熱交換元件,其係具有將添加水溶性吸、'g &之片狀之區隔構件’及藉由接著劑 :’、 區隔構件一起形成翁^ 丨网構件接合與該 夕臨 ^之流路之㈣保持構件,交互芦藉 之層積構造者,其特徵在於:間隔保持構件呈有伴^積 接者劑,對於水溶性 ”水性, I亥水洛性° 及濕劑之水溶液顯 2Hl-8977-PF;Ahddub 10 1313626 示非溶解性。 本發明之全熱交換元件之製造 少 添加水溶性吸濕劑之片狀之’其係製造具有將 隔構件接合與該區隔 ,及藉由接著劑與區 構件,交互層積之層積構==氣流之流路之間隔保持 單元製作步驟,其係製數:寺徵在於·包含: 件與具有保水性之間隔 接者浏使區隔構 元;及 持構件互相接合之元件構成單 層積步驟,其係以接著 P不,丨成之凡件構成早元相互接人 侍到層積配置複數個元件 接σ, 々/ 干稱成早兀之全熱交換元件, 作步驟之接著劑及用於層積步驟U 者劑’對水溶性吸濕劑或該 …之接 溶解性。 次/然剤之水洛液顯示非 [發明效果] ;本發明之全熱父換元件’作為使添加水 之區隔構件與具有保水性之間隔保持構件 ::劑 查丨丨,田激, 丁僻1丁仲三赉合之接著 、7溶性吸濕劑或該水溶性吸濕劑之水溶液顯亍 =解性者。換言之,作為使區隔構件與間隔保持= ^合之接著劑’使用於未硬化之狀態下水溶性吸 曰溶解,於硬化後水溶性吸濕劑或該水溶性吸關之水冷 液不會浸入者。 心 口此,無淪在於該全熱交換元件之製造過程,在於掣 k後,可抑制水溶性吸濕劑由區隔構件經由接著劑轉移到 ]隔保持構件。結果,於本發明之全熱交換元件,容易於 2111-8977-PF;Ahddub 1313626 區隔構件添加所期雙旦 且亦可容劑以提高潛熱的交換效率, 〆q熱的父換效率之經時降低。 由於間隔保持構件具有保水 溶性吸濕劑溶解;^μ | 卩便路水 構件吸收,故使用二: :將該結露水以間隔保持 氣裝置算眭 明之全熱父換元件構成空調機或換 該充'電部而產Γ抑制溶解上述水溶性吸濕劑之結露水接觸 充電。F而產生過電現象等重大的不適。Patent Document 1: Japanese Laid-Open Patent Publication No. Hei No. Hei. No. Hei. No. Hei. No. Hei. [Patent Document 5: Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Problem] From the viewpoint of suppressing the manufacturing cost of the total heat exchange element, the water-soluble moisture absorbent described in Patent Document 1 or the water-soluble moisture absorbent described in the special dispersion 2 for the absorbent sheet is used. The moisture absorbent is preferred. For example, if a water-soluble moisture absorbent is applied to paper and dried, a good material which can provide a partition member to which a moisture absorbent is added can be easily produced. However, most of the water-soluble moisture absorbents are ionized when they are dissolved in water, so that the conductivity of the water (aqueous solution) is very high, so that a total heat exchange element having a water-soluble moisture absorbent added to the partition member is used. Air conditioner or ventilator 2111-8977-PF; Ahddub 8 1313626 Water soluble thirst quenching I may, delivery + person 7k " b / cohesion may not be caused by condensation during heat exchange The dew condensation water is in contact with the charging portion and there is a possibility of causing major discomfort such as an overcurrent phenomenon.如此 如此 如此 ' 较 较 较 较 较 较 较 较 较 较 较 较 较 较 较 较 较 较 较 较 较 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合 复合5: The heat exchanger is preferably formed by a water-repellent material such as paper, which is formed by a mixed paper containing a resin. / The heat exchange nm powder paste or the water-based adhesive agent contained in Patent Document 6 connects the partition member and the space-retaining member =, and the workability and the connection in the production of the total heat exchange element can be improved. = #的性, but the actual latent heat exchange efficiency is lower than the latent heat exchange rate predicted by the partition structure: the measurement result of the bite. In this case, the entire exchange element of the partition member is not formed in a resin sheet having a low water retention property, etc., and a water-repellent material production area such as a fine paper is inherently formed by the entire heat exchange element. This phenomenon occurs remarkably in the total heat exchange element in which the water-soluble moisture absorption w of the partition member is added in a large amount. The inventors of the present invention, in the study of the reasons for resolving the above phenomenon, have used the water-based adhesive to bond the partition member to which the water-soluble moisture absorbent is added and the spacer member made of the water-retaining material. Then, the water-based adhesive is applied to the water-based adhesive to dry the two joints, and the water of the solvent of the aqueous binder penetrates into both the partition member and the spacer member. The water-soluble moisture absorbent in the partition member at this time - Partial transfer to the spacer holding member via the aqueous binder. The water-soluble moisture absorbent is transferred from the partition member 9 2111~8977-PF; the result of the Ahddub 1313626 right retaining member 'in the stage of combining the total heat exchange elements, the partition member cannot maintain the moisture permeability of the partition member alone, The display may reduce the efficiency of latent heat exchange. For example, in the heat exchanger described in Patent Document 7, the spacer holding member: a single-sided tin-forming thermal adhesive for the entire surface of the spacer member, and the spacer member and the spacer member are thermally used to form the element constituent unit using the adhesive. The addition of a water-soluble moisture absorbent to the partition member prevents the transfer of the water solvent from the partition member by the partition member. However, the recorded exchange test, the scholar recognizes 7 to make eight... The number of elements of the predetermined number constitutes the unit king, and, when changing 70 pieces, the water-based adhesive is used, so water capacity occurs at this time = by the partition member The transfer of the spacer holding member can reduce the moisture permeability of the partition member when the partition member is alone, and reduce the latent heat exchange efficiency. The invention has the high exchange efficiency of latent heat, and is reliable. Further, the present invention has an object of obtaining a method of manufacturing a heat-replaceable element such as an air conditioner or a ventilator which is easy to be used for the latent heat and which is easy to constitute an air conditioner. [Special means for solving the problem] The total heat exchange element of the present invention has a partition member which is added with a water-soluble absorbing, 'g & sheet and 'by an adhesive:' The members together form a joint member of the 翁 丨 丨 构件 与 与 与 该 该 四 四 四 , , , , , , , , , , , , , , 四 四 四 四 四 四 四 四 四 四 四 四 四 水溶性 水溶性 水溶性 水溶性 水溶性 水溶性 水溶性 水溶性 水溶性"Aqueous, I hai shui ° ° and the aqueous solution of the wet agent show 2Hl-8977-PF; Ahddub 10 1313626 shows the non-solubility. The whole heat exchange element of the invention is manufactured with less added water-soluble moisture absorbing agent sheet-like' The method comprises the steps of: fabricating a spacer unit that joins the partition member to the partition, and alternately stacks the layer of the airflow by the adhesive agent and the zone member, and the number of the system is: · Included: a component and a water-repellent spacer are connected to each other; and the components that are joined to each other constitute a single-layering step, which is followed by P, and the composition of the components is combined with each other. Waiting for the layering configuration of a plurality of components connected to σ, 々 / dry weigh全Full heat exchange element, as an adhesive for the step and for the laminating step U agent's solubility to the water-soluble moisture absorbent or the like. The second / 剤 剤 水 水 水 shows no [invention effect] The all-hot parent-changing element of the present invention is used as a spacer member for adding water and a spacer member having water retention:: agent 丨丨, Tian Ji, Ding wei 1 ding zhong zhong 之, 7 soluble moisture absorbent Or the aqueous solution of the water-soluble moisture absorbent is 解 = dissolving. In other words, as an adhesive for keeping the partition member and the gap = ^ used in the uncured state, the water-soluble absorbing solution is dissolved, and the water is soluble after hardening. The moisture absorbent or the water-soluble liquid cooling liquid does not immerse. The heart is that the whole heat exchange element is manufactured in the process of inhibiting the water-soluble moisture absorbent from being separated by the partition member. The agent is transferred to the spacer member. As a result, in the total heat exchange element of the present invention, it is easy to use 2111-8977-PF; the Ahddub 1313626 partition member is added with the desired double denier and can also be used to improve the exchange efficiency of latent heat, 〆 q hot father change efficiency Because the spacer member has the water-soluble moisture absorbent dissolved; ^μ | 卩便路水 Member absorption, so use two: : the dew condensation water to keep the gas device at intervals to the full heat of the father to replace the components constitute an air conditioner or The charge is replaced by the electric charge, and the dew condensation water which dissolves the water-soluble moisture absorbent is prevented from coming into contact with the charge. F causes a major discomfort such as an overcharge phenomenon.

由該等理由,根據本發明,可容易地 熱交換效率高,且 易構成潛 交換元件。 了罪度⑽空調機或換氣裝置等之全熱 【實施方式】 以下,參照圖面詳細說明 及其製造方法之各個實施形態 以下說明之實施形態者。 關於本發明之全熱交換元件 。再者’本發明並非限定於 實施形態1. 圖1係概略表示全熱交換元 — 同圖之全熱交換元件2G,係具有;:例之立體圖。示於 間隔保持構件5交互層積之層積構、/隔構件1與波板狀 全熱父換το件20,藉由層積6個元 ^机型者。於該 成上述層積構造,於最上面的元件…成早元I〇a〜l〇f形 層積天板構件15。於1個元件構成n。成早兀1〇f上進—步 之波紋與其上或其下之元件構成單早7^之間隔保持構件5 波紋,由平面所視,大致正 之間隔保持構件5之 ,在某元件構成單 2111-8977-PF;Ahddub 12 1313626 元之波板狀的間隔保持構件5之山或谷之長邊方向,與其 上或其下之it件構成單元之波板狀的間隔保持構件$之山 或谷之長邊方向,由平面所視,大致正交。 各區隔構件1 ’具有基材及添加於該基材之水溶性吸 濕劑。作為區隔構件1之基材,使用可添加水溶性吸濕劑, 且可藉由後述之接著劑與間隔保持構件5互相接合者。&由 抑制進行熱交換之2種氣流間的氣體交換之觀點,作為上 述基材,與其使用低透氣阻抗度(指以Gurley試驗機之透 籲氣阻抗度,以下相同),使用透氣阻抗度為200秒程度以上 之高透氣阻抗度者較佳。使用低透氣阻抗度者時,於該低 透氣阻抗度的基材作為填塞劑含浸聚乙烯醇等的水溶性高 分子為佳。例如將纖維素纖維(紙漿)碎解加工施以可得高 透氣阻抗度之技巧之紙作為上述基材使用時,只要含浸水 溶性吸濕劑即可得到具有理想性能之區隔構件1。 作為上述水如性吸濕劑,可使用具有潮解性之氯化鋰 Φ等鹼金屬鹽、具有潮解性之氯化鈣等鹼土金屬鹽、藻酸或 其鹽、鹿角菜膠或甲殼素等多醣類,或者尿素等,該等以 外的物質’只要是具有水溶性及吸濕性者均可使用作為上 述水溶性吸濕劑。具有潮解性之鹼金屬鹽或鹼土金屬鹽, 較其他的吸濕劑水分吸附能力高,由於可依其添加量使全 熱父換元件2 0之性能急劇地變化,故特別適合作為上述水 溶性吸濕劑。 水溶性吸濕劑對上述基材之添加’可以例如調製水溶 性吸濕劑之水溶液’使基材含浸於該水溶液,於基材之單 2111-8977-PF;Ahddub 13 1313626 面或雙面使用凹板塗佈機等設備塗佈該水溶液而進行。 又’於上述水溶液’按照需要可添加膠合劑成分或填塞劑。 惟’依照膠合劑成分之種類,由於有因該膠合劑成分阻礙 水溶性吸濕劑對基材之含浸,故於上述水溶液添加膠合劑 成勿時,慎重選定其種類及添加量為佳。 區^構件1之厚度,雖依對該區隔構件i所要求的透 濕性能或基材的材料強度,-般過厚則將使區隔構件i之 吸濕性惡化,過薄則與間隔伴胜 一门隔保持構件5之平衡不良,或因 為材料強度低而於元件構成單元或全熱交換元件之製造過 程破損’故以20~ 1〇〇 # m裎声盔社 ㈣私度為佳。再者,天板構件15, 可以與區隔構件1同樣的素材製作。 使用具有保持構件5具有保水性’作為其材料 ^ = 素#(保水性材料)°作為保水性材料之 例,可舉紙,或對使用纖維素纖維之織布或 4 塗佈吸水性樹脂者等。由 ’、3汉或 …織布…塗…二::::= 之混抄紙等亦由於具有若干保水性 素纖、准與樹月曰 隔保持構件5,惟需要、、主立門 〜等亦可利用作為間 少之點。“要“間隔保持構件5之保水量會減 間隔保持構件5之厚度, 保水性或全埶交換元件八:確保该間隔保持構件5之 …又换兀件全體之強度之 使間隔保持構件5過厚,則與區隔構件為佳,惟僅 而會於元件構成單元或全熱交換元件 ^平衡不佳 形等不適。又,在火$ 過程中發生變 在火火專時可燃物變多雙 个佳,由於間隔 2111-8977-PF;Ahddub 14 1313626 保持構件5之厚肉化亦會 保持構件5之厚产:仏-成本之要因,故該間隔 予又乂 50〜250#m程度為佳。 再者’亦可於各間隔保 的範圍内預先# Λ M ρ 、、 ,在不阻礙其保水性 例如紙之難燃.㈣處理等^ 劑,可使用多用於 等之胍鹽類.胍、硫酸胍、磺胺酸胍 化鎮等無機鹽類。 从叙、硫酸錢、氯化舞、氯 稽由將各1個上述區隔構件j 著劑互相接合,形成1個元件構成單=持接 相鄰之元件槿点一, 仵構成早&°又’於層積方向 天板構:互及最上面的元件構成單元⑻與 為片狀 ㈣由接著劑互相接合。由於各區隔構件i =;_呆持構件5為波板狀,於各個元件構成:元 之Q隔構件1與間隔保持 -件構成單元HOe之間隔保持構件5 工間、各 ,單元⑽,之區隔構件〗之間的=:及其上之元件構 罩元10 f之間隔佯拄接钟c 及於元件構成 ί之間&保持構件5與天 別形成氣流之流路Ρ。 15之間的空間,分 全熱交換元件20’係於流於形成 下之流路ρ之氣流,與流於形成於形”m構件1之 之上之流路P之氣流之間,經由該區隔構:固區隔構件! 交換及顯熱之交換。進行熱交換之2種^進行潛熱之 係例如由屋外向室内曲入之空氣流(_次氣::中的:方, 虱流係由室内向屋外排出之空氣产 ^ L另一方的 圖1,經由元件構成單元1〇 再者,於 匕隔構件1進行熱交換之 2lll-8977-PF;Ahddub 15 1313626 乳流Af!與氣流Afz ’分別以實線的箭頭描繪。 具有如此之構成之全熱交換元件20,由於其特徵在 於:使區隔構件1與間隔保持構件5互相接合之上述接著 劑,以下,參照圖2詳述該接著劑。 圖2係概略表示於上述全熱交換元件2〇之元件構成單 兀10a與其上之元件構成單元1〇b之接合處及其附近之刊 面圖。如同圖所示’在於各元件構成單元i〇a、i〇b之區隔 構件1與間隔保持構件5,係藉由塗佈於間隔保持構件5 之谷部_R之背面側之接著劑3,互相接合,元件構成單元 1 〇a與το件構成單元i Qb ’係藉由塗佈於元件構成單元1 之間隔保持構件5之山部T之上面側之接著劑13互相接 合:圖1所示其他元件構成單元1〇c〜1〇f之區隔構件工與 間IM呆持構件5之接合,於層積方向相鄰之其他元 翠元相互之接合,及元件構成單幻_天板構 件15之接合,均分別與上述同樣地進行。 上述各接著劑3、13,係對添加於區隔構件丨之水溶 性吸濕劑或該水溶性吸濕劑之水溶液顯示非溶解性者。換 言之,於未硬化之狀態下含浸於區隔構件i之水溶性吸濕 d不會♦解’於硬化後上述水溶性吸濕劑或該水溶性吸译 劑之^溶液不會浸人者。作為如此之接著劑之具體例,可' 水作為溶劑之有機溶㈣接著劑(包含非水乳膠系 無'谷劑系反應型接著劑、及熱溶型接著劑。 區隔構件1與間隔保持構件5以上述接著劑3月、13互 相接合之全熱交換元件2G,無論在於其製造過程,在於製. 2111-8977-PF;Ahddub 16 1313626 造後,可抑制上述水溶性 3、13轉移 ‘、』由“構件1經由接著劑 主間保持構件5。於 水溶性吸濕劍。再者,各接著齊丨3:"、13不含上述 造時、保管時、或者使用時 ::例如在其製 的上述水溶性吸濕劑者,或者上之水分溶解微量 之狀態」於熱熔型接著劑,所謂「未硬化 於亥㈣型接著劑軟化或炫融之狀態之意思。 上W上㈣之構叙全熱交換元件20,由於使用 上述接著齊| 3、13接人* r :使用 故容易計 構件1與間隔保持構件5, 故-易對區隔構件i添加所期望量之冓:5 “π 易抑制该潛熱之交換效率經時降低。又, 由於可抑制吸渴劑由 - 可減少在得到料之^ ㈣隔保持構件5, 元养… 父換效率與先前同等程度之全執交換 兀件上所需的水溶性吸濕劑 ‘、、'父換 本。 里、·口果亦谷易圖謀降低成 持’由於可抑制吸濕劑由區隔構件1轉移至間隔伴 持構件5,故可抑制於製造全熱交換: 保持構件5吸渴 〈牡間搞 構件5八㈣ 區隔構件1與間隔保持 構件b分別因揭^ τ 元變开社要,“’、 引起強度變化而使元件構成單 …,可使製作元件構成單元時之作用性,或元 件構成單元之操作性、及製造全熱交換 或生產性良好。 t工作菜性 又由於間隔保持構件5具有保水性,即使於全熱交 換元件2◦發生結露而上述水溶性吸濕劑溶解於結露水:、由 2111-8977-PF/Ahddub 17 1313626 於可將該結露水以間隔伴拉播料c 保持構件5吸收,故於使用全执交 換元件20之空調機或換教 ’”、 …、、置等之機器,可抑制溶解水溶 性吸濕劑結露水與上述右堂加& 边充電部接觸而產生過電現象等重大 的不適。 由該等理由,於全埶夺姑_ …、、凡件2 0容易得到潛熱的交換 效率高者,且使用該全埶φ μ _ ^ 、町乂秧 熱乂換疋件2〇,容易構成可靠度高 的空調機或換氣裝置等。再 丹者,全熱交換元件20係用於处 調機或換氣裝置等設置於宮 、二 又置於至内之機器時,不回 的揮散或臭氣的逸散等,祛田风合力1 使用無溶劑系反應型接著劑或 熔型接著劑作為上述接著劑 有a飞… d 13為佳。使用熱熔型接著 二二於以溶融之熱溶型接著技之自然冷卻之硬化或以 人應之硬化完成區隔構件1與間隔保持構件5之接 :::無須設乾燥步驟。因此’容易圖謀縮短製造全敎交 =件別所需的時間或減少製造所需投人之能源,結果可 谷易圖謀降低成本或減少斜 X减^對周圍環境造成的環境負荷。 可奏上述技術之效果之 如,包人一 1 王熱又換兀件20,可藉由例 包含.早兀製作步驟,1 ,、係製作複數個,以接著劑祛 區隔構件與具有保水性之 按者州使 _ ^保持構件互相接合之元件構 取早7L,及層積步驟,豆俜 姑人 /、係以接者劑使元件構成單元相互 接5 ’得到層積配置複數個元件 構成早70之全熱交換元件 法I造。此時,於各個i i _ 、各個早70製作步驟及層積步驟,使 士水溶性吸濕劑或該水溶性 _ ^ ‘.、、W之水/合液顯不非溶解 者V】。換言之,使用於未硬 ^ 之狀恶下水溶性吸濕 月 自溶解,於硬化後水溶性、^ 叹瀹劑或该水溶性吸濕劑之 21H'8 977-PF;Ahddub 18 1313626 水岭液不會浸入之接著劑。以下詳述該方法之各步驟。 於上述單元製作步驟,例如可分為第1小步驟及第$ 1、步驟。於第1小步驟’首先,將成為具有保水性之間隔 '、、構件5 (參照圖1 )之基礎之長條素材成形為波板狀得 到長條的波板狀成形品。其次,於該波板狀成形品之單面 ,山頂部塗佈未硬化接著劑3(參照圖2)。之後,使成為區 冓件1 (參照Η 1)之基礎之長條素材(添加水溶性吸濕劑 者)/、上述波板狀成形品抵接使上述未硬化接著劑硬化,藉 此使兩者接合得到長條的元件構成單元材。 …於第2小步驟,係將第!小步驟所得之長條元件構成 單凡材’裁切成既定的大小,得到複數個具有以接著劑3 使區隔構件1與間隔保持構件5互相接合之構成之元件構 成单元m件構成單元,成為圖i所示元件構成單元 l〇a~l〇f 之任一。 、於早元製作步驟之後進行之層積步驟,係首先,於構For these reasons, according to the present invention, the heat exchange efficiency can be easily made high, and the latent exchange element can be easily formed. The degree of sin (10) The total heat of the air conditioner, the ventilator, etc. [Embodiment] Hereinafter, each embodiment of the manufacturing method and the manufacturing method thereof will be described in detail with reference to the drawings. Regarding the total heat exchange element of the present invention. Further, the present invention is not limited to the embodiment 1. Fig. 1 is a perspective view schematically showing a total heat exchange element - a total heat exchange element 2G of the same drawing. The layered structure of the spacer member 5 is alternately laminated, and the spacer member 1 and the corrugated all-heat-replacer member 20 are stacked by a six-element model. In the above-described laminated structure, the uppermost member is formed into a layered solar panel member 15 in the form of early elements I〇a to l〇f. One element constitutes n. The entanglement of the early 兀1〇f-step corrugation and the components above or below it constitute a single early interval 7^ to keep the member 5 corrugated, as viewed from the plane, substantially positively spaced apart from the member 5, forming a single 2111 in a certain component -8977-PF; Ahddub 12 1313626 element of the wave-shaped spacer holding member 5 in the direction of the long side of the mountain or valley, with the wave plate-like spacing of the upper or lower member thereof The longitudinal direction is generally orthogonal to the plane. Each of the partition members 1' has a base material and a water-soluble moisture absorbent added to the base material. As the base material of the partition member 1, a water-soluble moisture absorbent can be added, and the adhesive can be joined to the spacer member 5 by an adhesive to be described later. & From the viewpoint of suppressing gas exchange between two kinds of gas streams for heat exchange, as the above-mentioned substrate, a gas permeability resistance is used instead of using a low gas permeability resistance (refer to the gas permeability resistance of the Gurley test machine, the same applies hereinafter) It is preferred that the gas permeability is higher than 200 seconds. When a low gas permeability resistance is used, it is preferred that the substrate having a low gas permeability is impregnated with a water-soluble high molecular weight such as polyvinyl alcohol as a packing agent. For example, when the cellulose fiber (pulp) is pulverized and a paper having a high gas permeability resistance is used as the substrate, the partition member 1 having desired properties can be obtained by impregnating the water-soluble moisture absorbent. As the water-based moisture absorbent, an alkali metal salt such as deliquescent lithium chloride Φ, an alkaline earth metal salt such as deliquescent calcium chloride, alginic acid or a salt thereof, carrageenan or chitin can be used. A saccharide or a urea other than the above may be used as the water-soluble moisture absorbent as long as it has water solubility and hygroscopicity. The deliquescent alkali metal salt or alkaline earth metal salt has higher moisture adsorption capacity than other moisture absorbents, and is particularly suitable as the above water solubility because the performance of the all-heat parent-changing component 20 is drastically changed depending on the amount of addition. Moisture absorber. The addition of the water-soluble moisture absorbent to the above substrate can be performed, for example, by preparing an aqueous solution of a water-soluble moisture absorbent, so that the substrate is impregnated with the aqueous solution, and the substrate is used as a single 2111-8977-PF; Ahddub 13 1313626 or double-sided. The aqueous solution is applied by a device such as a gravure coater. Further, a binder component or a plugging agent may be added to the above aqueous solution as needed. However, depending on the type of the binder component, since the binder component hinders the impregnation of the water-soluble moisture absorbent onto the substrate, it is preferable to carefully select the type and amount of the binder when the binder is added to the aqueous solution. The thickness of the member 1 depends on the moisture permeability required for the partition member i or the material strength of the substrate, and the excessive thickness will deteriorate the hygroscopicity of the partition member i. The balance of the holding member 5 is poor, or the manufacturing process of the component unit or the total heat exchange element is broken due to low material strength. Therefore, it is better to use 20~1〇〇# m裎声帽社(4). . Further, the roof member 15 can be made of the same material as the partition member 1. An example in which the retaining member 5 has water retention capacity as its material ^=素# (water retaining material) ° as a water retaining material can be used, or paper or a water-absorbent resin coated with cellulose fibers or 4 Wait. By ', 3 Han or ... weaving... coated... 2::::= Mixed paper, etc., also has a number of water-retaining plain fiber, quasi-and tree-tree separation holding member 5, but need, main door ~ Can also be used as a point of spamming. "The amount of water retention of the spacer member 5 is reduced by the thickness of the spacer member 5, and the water retaining or full-twisting member 8 is ensured that the spacer member 5 is replaced by the strength of the entire member. Thick, it is better with the partition member, but only the component constituent unit or the total heat exchange element ^ poor balance and other discomfort. Also, during the fire $ process, the combustible material becomes more and more good in the fire, because the interval 2111-8977-PF; Ahddub 14 1313626, the thick meat of the holding member 5 will also maintain the thick production of the member 5: - The reason for the cost, so the interval is preferably 50~250#m. In addition, it is also possible to use ## M ρ , , in the range of each interval, without hindering its water retention, for example, paper is not flammable. (4) Treatment, etc., can be used for cesium salts. Inorganic salts such as barium sulfate and sulfamate. From the narration, sulphuric acid money, chlorinated dance, and chlorine, each of the above-mentioned partition members j is joined to each other to form a single component constituting a single piece; the adjacent element is held one point, and the 仵 constitutes early & Further, in the direction of the lamination direction, the inter- and upper-most component constituent units (8) and the sheet-like (four) are bonded to each other by an adhesive. Since each of the partition members i =; _ the holding member 5 is in the shape of a corrugated plate, each element is composed of: a partition member Q of the element and a spacer holding member 5 of the space-holding member-constituting unit HOe, each unit, (10), Between the partition members ???, and the interval between the component constituting members 10 f and the splicing clocks c and the components ί, the holding member 5 forms a flow path with the air. The space between the 15 and the total heat exchange element 20' is connected to the air flow flowing through the flow path ρ formed, and the air flow flowing through the flow path P formed on the "m member 1", via Zone partition: solid partition member! Exchange and sensible heat exchange. Two types of heat exchange are carried out. For example, the system of latent heat, such as the air flow from the outside to the inside of the room (_secondary gas:: medium: square, turbulent flow) Fig. 1 of the other side of the air discharged from the room to the outside of the room, through the component constituting unit 1 〇, the heat exchange of the spacer member 1 2l ll-8977-PF; Ahddub 15 1313626 milk flow Af! and the air flow Afz' is drawn by solid arrows, respectively. The total heat exchange element 20 having such a configuration is characterized in that the above-mentioned adhesive that bonds the partition member 1 and the spacer member 5 to each other is hereinafter described in detail with reference to FIG. Fig. 2 is a schematic view showing the joint between the component constituent unit 10a of the total heat exchange element 2A and the component constituent unit 1bb thereon, and the vicinity thereof. Component constituting unit i〇a, i〇b, partition member 1 and spacer structure 5, by bonding to the adhesive 3 applied to the back side of the valley portion_R of the spacer member 5, the element constituent unit 1 〇a and the τ block member unit i Qb ' are formed by coating the member. The adhesives 13 on the upper side of the mountain portion T of the space holding member 5 of the unit 1 are joined to each other: the joining of the partitioning members of the other component forming units 1〇c to 1〇f shown in Fig. 1 to the intermediate holding member 5 The joining of the other elements in the stacking direction and the joining of the elements constituting the phantom scorpion member 15 are performed in the same manner as described above. The above-mentioned respective adhesives 3 and 13 are added to the area. The water-soluble moisture absorbent of the partition member or the aqueous solution of the water-soluble moisture absorbent exhibits non-solubility. In other words, the water-soluble moisture absorption d impregnated into the partition member i in the unhardened state is not solved. After the hardening, the above-mentioned water-soluble moisture absorbent or the water-soluble aqueous solution can not be infiltrated. As a specific example of such an adhesive, an organic solvent (four) adhesive which can be used as a solvent (including a non-aqueous latex system) There is no 'troreal agent type reactive adhesive, and hot melt type adhesive. The total heat exchange element 2G in which the member 1 and the spacer member 5 are joined to each other by the above-mentioned adhesives at March, 13 is manufactured in the process of manufacturing 2111-8977-PF; Ahddub 16 1313626 can suppress the above water solubility. 3, 13 transfer ',' from the "member 1 through the adhesive main holding member 5. In the water-soluble moisture-absorbing sword. Furthermore, each of the following 3:", 13 does not contain the above-mentioned time, storage, or When used: for example, in the case of the above-mentioned water-soluble moisture absorbent prepared by the above, or in a state in which the water is dissolved in a small amount, in a state in which the hot-melt type adhesive is used, the "unhardened in the (four) type type adhesive is softened or dazed. meaning. The upper heat exchange element 20 of the above (4) is configured to be easy to count the member 1 and the space maintaining member 5 by using the above-mentioned splicing | 3, 13 to receive the *r: it is easy to add the desired component to the partition member i.量 冓: 5 “π 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易The degree of the full-scale exchange of the required water-soluble moisture absorbent ', 'Father's change. Li, · Guoguo is also easy to reduce the holdings' because it can inhibit the transfer of moisture-absorbing agent from the partition member 1 The spacer member 5 is spaced apart, so that it can be suppressed from manufacturing the total heat exchange: the holding member 5 is squeezing the thirst, and the spacer member 1 and the spacer member b are separately opened due to the removal of the τ element. In order to cause a change in strength and to form a single member, the operability of the component to form the unit, or the operability of the component constituent unit, and the overall heat exchange or productivity of the manufacturing can be improved. t working dish and because the spacer member 5 has water retention, even if condensation occurs in the total heat exchange element 2, the water-soluble moisture absorbent is dissolved in dew condensation water: 2111-8977-PF/Ahddub 17 1313626 The dew condensation water is absorbed by the holding member 5 at intervals, so that the dew condensation water of the water-soluble moisture absorbent can be suppressed by using the air conditioner of the full exchange component 20 or the machine of the teaching, ",", etc. A major discomfort such as an overcharge phenomenon caused by the contact with the right side of the upper side and the side charging unit. For these reasons, the exchange efficiency of the latent heat is easily obtained by using The full 埶φ μ _ ^, 乂秧 乂秧 乂秧 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 。 。 。 。 。 。 。 。 。 。 。 When a gas device or the like is installed in a machine that is placed in the palace or the second, the volatilization or the odor is not returned, and the wind force 1 uses a solventless reactive adhesive or a molten adhesive as the above. The agent has a fly... d 13 is better. Use hot melt type followed by two two The hardening of the melt-dissolved hot-melt type of natural cooling or the hardening of the partition member 1 and the spacer member 5 are completed::: no drying step is required. Therefore, it is easy to shorten the manufacturing process. Do not take the time required or reduce the energy required to manufacture the investment. As a result, you can reduce the cost or reduce the environmental load caused by the X-ray reduction. The effect of the above technology can be used as a package. The hot change of the member 20 can be carried out by the method of prematurely preparing the first part, and the plurality of parts are formed by the adhesive agent and the member having the water retention state. The structure is 7L early, and the lamination step is carried out. The bean curd is used to connect the component constituent units to each other 5' to obtain a layered arrangement of a plurality of components to form the full heat exchange element method of the early 70. In each ii _ , each early 70 production steps and lamination steps, the water-soluble moisture absorbent or the water-soluble _ ^ '., W water / liquid is not dissolved V]. In other words, use Water-soluble hygroscopic self-dissolving under the condition of not being hard , after the hardening, water-soluble, sighing agent or the water-soluble moisture absorbent 21H'8 977-PF; Ahddub 18 1313626 water-repellent liquid will not be immersed in the adhesive. The steps of the method are detailed below. The unit production step can be divided into, for example, the first small step and the first step, and the step is 1. In the first small step, 'first, the interval between the water retention interval' and the member 5 (see FIG. 1) is the long material. The corrugated sheet-like molded article is formed into a corrugated sheet shape. Next, on the single side of the corrugated sheet-like molded article, the unhardened adhesive 3 is applied to the top of the mountain (see Fig. 2). 1 (refer to Η 1), a long strip material (adding a water-soluble moisture absorbent) /, the corrugated sheet-shaped molded article is brought into contact with each other to cure the unhardened adhesive, thereby joining the two to obtain a long strip Form the unit. ...in the second small step, the system will be the first! The elongate member obtained in the small step constitutes a single material 'cut to a predetermined size, and a plurality of component constituent units m having a constitution in which the partition member 1 and the spacer member 5 are joined to each other by the adhesive 3 are obtained. It becomes any one of the component constituent units l〇a to l〇f shown in Fig. i. The layering step performed after the early element production step is first

成上述元件構成單元之間隔佯拷播杜ς — , s A h保符構件5之山頂部塗佈未 化接著劑13(參照圖2)。i次 ”人使在於1個7C件構成粟; =門保持構件5之波紋與其上或其下之元件構成單元之 =?件5之波紋,由平面所視,大致正交地選定各 兀仟構成早7G之方向,脾涂^士 ,I佈有未硬化接著劑(接著劑工3 之未硬化物)依序層積,於最 面的凡件構成早几上層積天 板構件1 5 (參照圖1)。此後 使上述未硬化接著劑硬化使 層積方向相鄰之元件構成單 如-&amp; , 互及最上面的元件構成 早兀與天板構件丨5互相接合 什幻圖1所不全熱交換元件 2111-8977-PF;Ahddub 1313626 20 〇 再者,在於上述單元製作步驟 製作,例如可使用圖3所示設Μ:::成單元之 =持構件之基礎之長條素材及成為區隔構件=為間 條素材,分別預先成形成n i楚之長 圖3係表示於上述單元製作步驟 成單元時所使用之設備之一例之概略圖。同圆:,牛構 係單面瓦楞裝置,於該單面瓦榜裝 〜備120 5夕Α μ 成為間隔保持構件 ιΓ,!/ 一、圖1)之基礎之長條素材1Afi先成形為捲筒R” 於設請由捲筒R1拉出之素材5A,首先送至且有一 十瓦楞輥l〇la、101b之瓦愣機⑻。於瓦愣基1〇1, 輪狀的上段輥101a與齒輪狀的下段輥⑺化互相咬 =,於該等瓦愣輥购、麗互相咬合之未置依序料材 成形為波板狀。結果連續地製作波板狀成形品Μ。 接著,板狀成形品5B,藉由下段輥1〇lb向既定方向 輸送,在途中於該波板狀成形品5B藉由塗佈輥ι〇3塗佈未 硬化接著劑3a。未硬化接著劑3a係儲存於接著劑槽1〇5, 塗佈輥103之周面部分浸潰於接著劑槽1〇5。又,於塗佈 輥103之周面,有與下段輥1〇lb之齒頂部略接觸。 藉由塗佈輥103向既定方向旋轉使未硬化接著劑仏附 著於塗佈輥1 03之周面,進一步塗佈於波板狀成形品5B之 單面。為使未硬化接著劑3a不致過剩附著於塗佈輥ι〇3之 周面’於該塗佈輥丨0 3附近配置擠水輥丨〇 7。可藉由調整 2111-8977-PF;Ahddub 20 J313626 下段輥1 Q1 b與擠水輥 ▼一叫叹双狀风形品 5B之未硬化接著劑%之塗佈量。再者,作為接著齊&quot;(參 照圖2)使用熱熔型接著劑時,例如於接著_ ι〇5附設加 熱器(無圖示),以該加熱器使熱熔型接著劑熔融成未硬化 接著劑3a。 另-方面’由捲筒r2拉出之素材u,藉由2個導輥 uia、mb導向壓製輥113。壓製輥113,其周面略與下 段輥HUb之齒頂接觸地配置,藉由該廢製輥113使素材 1A在向既定方向輸送的過程將該素材接於波板狀成 形品5B。 由於在波板㈣形口口口 5B如上所述塗佈有未硬化接著 劑仏’故將素材1A壓接於波板狀成形品5B後以既定的手 (…圖示)例如加熱器、放射既定波長光之人工光源、 =出溫風之送封機、或者吹出冷風之送風機等使未硬化接 著劑3a硬化’藉由硬化後硬化劑3(參照圖2)使波板狀成 开彡品5\與素材u互相接合。結果’可連續地製作成為元 t構成單元之基礎之長條元件構成單元材10A。再者,各 輕101a l〇lb與壓製輥113,為容易調整波板狀成形品 5 B之形狀’例如》、、w么 /皿為150C程度以上之既定溫度。於圖 匕將各輥之旋轉方向’及各素材u、5a之搬送方向以實線 箭頭表示。 、此後藉由裁切機將元件構成單元1G A由其端依序裁 成无疋的大小,連續地製作成為元件構成單元 (參照圖n之元件構成單元。 2Hl-8 977-PF;Ahddub 21 1313626 換元如上述製作之複數個元件構成單元得到全数交 換凡件之層積步驟,對各元件構 】王…又 如可使用椒畋 平几之接著劑塗佈,例 使用概略表示於圖4之設備進行。 圖4所示設備130,具備:—對幸昆mam 硬化接著劑丨3a之接著劑 擠水請;及省略圖示之搬送,置配置:輥咖附近之 係以區隔構件!為上,間隔保持:冓 搬送裝置搬送至一對觀ma、mb牛=的方向,藉由 劑…。隔著既定間隔,對一對親1 21在此㈣未硬化接著 數個元件構成單元1G。 依序搬送複 上述一對輥121a、121b之中,μ加 # ^ . .. . 1 上側輥1213作為將元 =成…0向既定方向搬送之搬送輥之作用,下侧輥 部分浸潰於接著劑槽123,作為對元件構成單 ^塗佈未硬化接著劑13a之塗佈輥之作用。藉由滾咖 向既定方向旋轉未硬化接著劑13a附著於輕12心周面, 進-步塗佈於元件構成單元1()之間隔料構件5。擠水輕 125係配置於輥121b附近,去除過剩附著於輥⑵匕之未 硬化接著劑13a。藉由調整輥mb與擠水輥125之間卜 可調整對元件構成單元1°之未硬化接著劑13a之塗/量 再者,作為接著劑3(參照圖2)使用熱溶型接著劑時,例如 於接㈣槽123附設加熱器(無圖示),以該加熱器使熱熔 型接著劑熔融成未硬化接著劑1 3a。 藉由設備130塗佈未硬化接著劑13a之各元件構成單 元10,如已說明者’以既定的方向層積,於最上面的元件 2111-8977-PF;Ahddub 22 1313626 構成早元進一步藉工_ι θ天板構件15(參照圖υ。此後,以省 略圖不之手段,例如 。 u σ ‘、、、益、放射既定波長光之人工光 源、〇人出溫風之送封 、、、或者吹出冷風之送風機等施以使 未硬化接著劑13a硬 從 更化之硬化處理。藉由進行到該硬化處 理’仔到於層積方向★日彻* _ 郇之凡件構成單元10相互以接著劑 13(參照圖2)互相接人+人上 相接口之全熱交換元件20(參照圖丨及圖 4)〇 再者,於單元製作步驟使用熱熔型接著劑時,亦可使 用概略表示於圖5之設備14。製作元件構成單元i〇A。同 圖斤丁 D又備140係代替圖3所示接著劑槽及擠水親 1〇7,具備:供料輥133,其係配置成與塗佈請之周面 接觸於該塗佈輥1G3之周面供給未硬化接著劑%,即溶融 之熱炫型接著劑者;供給管135,其係對塗佈親盘供 料輥133之摺接區域由其上方供給溶融之減型接著劑; 及接著劑供給源(無圖示)’其係將熱炫型接著劑向供給管 135送出者。除了此點,設備14Q之構成與圖3所示設備 120之構成相同,故圖5所示構成之中與圖3所示設備丘 通者,附以與圖3所使用之參照符號之參照符號省略說明。 又,於層積步驟使用熱熔型接著劑時,亦可使用概略 f示於圖6之設備15G對各元件構成單元10塗佈未硬化接 著劑13a,即熔融之熱熔型接著劑。同圖所示設備15〇,具 備··一對輥141a、14〗b;配置於輥141b附近對輥1411)之 周面供給儲存未硬化接著劑13a之供料輥143 ;於輥 與供料輥143的境界區域由其上方供給熔融之熱熔型接著 2111-8977-PF;Ahddub 23 1313626 劑之供給管145;將熱炫型接著劑送出至供給管接著劑供 給源(無圖示);及搬送裝置。 —上述—對輥141a、141b之中,下側之幸昆14u作為將 疋件構成單元1G向既定方向搬送之搬送輕之作用,上側輥 Ulb作為對元件構成單元1Q塗佈未硬化接著劑13a之塗 佈氈之作用。凡件構成單元i 〇,係以區隔構件1為下,門 隔保持構件5為上之方向以搬送裝置,搬送至__ 1 41 a、141 b,在此塗佈未硬化之接著劑丨3a。 實施形態2. 亦可將在於構成全熱交換元件之各個元件溝成單元之 區隔構件與間隔保持構件之接合,或元件構成單元相互之 接合,藉由基材與熱接著性樹脂層構成間隔保持構件,將 構成該間隔保持構件之熱接著性樹脂層使用作 =行。具有如此之接合形態之全熱交換元件之全體形狀 1而 ΠΓ與圖1所示之全熱交換元件2°之全體形狀相 同’故在此省略其圖示。 圖7係概略表示具有上述接合形態之全熱交換 —例之1個元件構成單元與其上之元㈣成單元之接合處 及其附近之剖面圖。於同圖 _ 表7^件構成單元恤、及 了其上接合之元件構成單元4Qb。圖7所示構成構件 2圖2所示構成構件共通者,附以與圖2所使用之表 號相同的參照符號,省略其說明。 /… 各個上述元件權志g ; &lt; Λ 拉人 件構成早凡40a、傷’具有區隔構件!及 5於,亥區隔構们之間隔保持構件Μ,於各間隔保持構 2111-8977-PF;Ahddub 24 1313626 件 35,呈古, ,、有以保水性材料製作之美 35A之下面全體之敎接著: ,⑨於該基材 35B &gt; ^ ,.. 子月曰層35B。熱接著性樹脂層 等熱接著性樹稀Λ乙稀錯酸乙稀共聚合物(则 ^述膜可Π : :Τ基材35Α之單面而形 多孔質之膜質者,亦可為非多孔質者。使用 ”h 形成熱接著性樹脂層35Β時,可容易提 錢保持構件35之保水性。 ::… 成熱接著性樹使用非多孔質膜或片形 |氣阻抗度。a咖時,容易提高間隔保持構件35之透 在於各個元件構成單元4〇a、4〇b 保持構件”,係將熱接著性樹脂層35^=1與間隔 你田# 曰增作為熱熔型接著劑 使用,於間隔保持構 接者 件構成單元40a與元件構成輩一 ^面側互相接合’元 欉忐1 一 λ η 70 4〇b,係藉由塗佈於元件 構成早MGa之間隔保持構件35之山部 凡件 劑13互相接合。作為 貝1J之接者 脂層咖,用之上述熱接著性樹 、1 添加於區隔構件1之水溶性吸濕劑切水 之狀態; = = 性者。換言之,於未硬化 硬m + ^之水溶性吸濕劑不會溶解-於 浸入^述水溶性吸濕劑或該水溶性吸濕劑之水溶液不會 :::使用單面瓦愣裝置製作各元件構成單元•、條 用將在於該單面瓦榜裝置之瓦楞機或麼製輕作為熱源使 可使上述熱接著性樹脂層35β熔融。一二二 因吸濕之伸縮小,故使埶接著性丹Β 瓜私Η曰由於 …接者性树脂層35Β較厚較可抑制 2111-8977-PF;Ahddub 25 1313626 起因於間隔保持構件35 時之作業性。 牛構成早兀製作全熱交換元件 區隔構件1與間隔保持構件 食熱交換元件,由於與實施形態二述:接:形態之 20相同的理由,容易γ f 之王熱父換π件 &gt; 由令易侍到潛熱交換效率高者,且使用兮八 熱父換7〇件,則可容易 -王 皆。又,T —且 城了罪度阿的空調機或換氣裝 置 谷易縮短製造全熱交換元件所需之時門^ 少製造所需要投入之能源,择…而之時間,或減 m m ^ 、 、’°果可谷易地圖謀降低成本或 減低對周圍環境造成之環境負荷。 - 實施例 以下舉實施例及比較例 元件及其製造方法。 〈實施例1&gt; 具體說明本發明之全熱交換 首先’使用於碎解加卫纖維素纖維(紙幻而得之厚約 3〇〇em,透氣阻抗度5000秒以上之特殊加工紙含浸既定量 之水溶性吸濕劑之氣化鋰之長條物作為區隔構件素材,使 用厚約80# m之白色單光澤上質紙之長條物作為間隔保持 構件之素材,藉由與圖3所示設備120同樣的設備製作長 條之元件構成單元材。此時,作為使藉由瓦愣機成形間隔 保持構件之素材而得之波板狀成形品,與上述區隔構件之 素材互相接合之接著劑,使用可使用時間(〇pen time)為數 秒程度之EVA(乙烯醋酸乙烯共聚合樹脂)系熱熔型接著 劑’將該熱溶型接著劑加溫為約15(rc,以成為熔融物 2111-8977-PF;Ahddub 26 1313626 2 5g/m2程度之涂优至 ^ ^ 里也'主佈上述波板狀成形品。 將元件構成單元材裁切成既定的大小得到複數 =構f單元,將該等元件構成單元以可使用時間為 y私度之SEBS(苯乙稀-乙烯-丁烯-苯乙稀散段共聚 彈性體所構成之熱炫型接著劑,藉由與圖4所示設 。0问樣的設備塗佈。此時,熱熔型接著劑係加溫為約 c之熔融物’其塗佈量為45g/m2程度。 I苴’、丨個元件構成單元之間隔保持構件之波紋盥 ,、上或其下之71件構成單元之間隔保持構件之波紋,由i 面所視,大致正交地依序層積各元件構成單元,於最上面 構成單元上進—步層積天板構件之後,使上述㈣ 糸彈十體所構成之熱炫型接著劑之溶融物硬化,得到呈有 與圖1所示全熱交換元件2Μ目同外觀之全 料熱交換元件,以與圖2所示接合形態相同的形=合 區隔構件與間隔保持構件。 〈實施例2 &gt; 百先,準備碎解加工纖維素纖維(紙漿)而得之厚約 透氣阻抗度5_秒以上之特殊加工紙含浸既定量 之欠冷!生吸濕劑之就化鐘之長條物作為區隔構件素材,又 準=約…m之耐水紙構成之基材之單面熱融接有以聚 ,三力刀之厚約】5 &quot; m之膜之長條物作為間隔保持構 之”材。上述膜,作為熱接著性樹腊層作用。接著將間 隔保持構件之素材由端依序,以瓦愣機成形為波板狀成形 品’由成形為波板狀成形品之處使用上述膜作為熱溶型接 2111-8977^PF;Ahddub 27 1313626 元件構成單 著劑與區隔構件之素材互相接合,得到長條之 •^G 材。 ,凡件構成早元材裁切成既定 個元件槿忐— 的大小仔到複數 件椹士时- 们條件之下將該等元 手構成早兀層積,得到與圖! 觀之入刼丄认 ‘、,、乂換凡件20相同外 王…父換兀件。於該全熱交換元件, ^ ^ ^ J-rt Γ-1 /、圖7所不接 〜〜、相同的形態接合區隔構件與間隔保持構 〈比較例〉 使用厚約7—之長條難燃紙(相 W乍為間隔保持構件之素材,且 之難 i» v. OT , ( F句表作長條之元件 =早兀料之接㈣及層積複數個元件構成單 :’使用於醋酸乙稀系乳膠接著劑加入調整黏度之水: 者二與實施例1同樣的條件下製作全熱交換元件。再 使製作長條元件構成單元材時 刊砰;^上述接著旦 二“广層積複數個元件構成單元時之上述接著劑之: 佈2:為29g/m2。 玉 〈評價&gt; 對於實施例1、2及比較例所朴七办 .v 例所I作之各個全熱交換元 件’分別測定於高濕度環境下之⑽ μ η &amp;卜之,皿度父換效率(顯熱之交換 效率)、濕度交換效率(潛熱之交換 、 換政羊)、及全熱交換效率 以及於低濕度環境下之溫度交換效 干 属度父換效率、及 全熱交換效率。於高濕度環境下 分父換率效率之測定信 於遵照JIS B8628 (全熱交換器)之交 ’、 又換效率測定條件(夏曰 條件)之條件下’又在於低濕度環境上 r &lt;各父換效率之測定 2111-8977-PF;Ahddub 28 1313626 係於遵照ARI(美國空調冷凍協會)i〇6〇 Rating Air-to、AirAt the interval between the above-mentioned component constituting units, the top of the mountain of the s A h retaining member 5 is coated with an unadhered adhesive 13 (see Fig. 2). The i-time "personality" consists of one 7C piece forming a millet; = the corrugation of the door holding member 5 and the corrugation of the element 5 of the element forming unit thereon or below, as viewed from a plane, the respective sides are selected substantially orthogonally In the direction of the early 7G, the spleen is coated with a spleen, and the I cloth has an unhardened adhesive (the unhardened material of the medicinal worker 3) is laminated in sequence, and the outermost parts are formed on the upper layer of the upper slab member 1 5 ( Referring to Fig. 1), the above-mentioned unhardened adhesive is hardened so that the elements adjacent to each other in the stacking direction constitute a single---, and the uppermost element constitutes an early joint with the sky-plate member 丨5. Incomplete heat exchange element 2111-8977-PF; Ahddub 1313626 20 Furthermore, in the above-mentioned unit production step, for example, it can be used as shown in Fig. 3::: into a unit = the base material of the holding member and becomes The partition member = is a strip material, and each of them is formed in advance. FIG. 3 is a schematic diagram showing an example of a device used in the unit making step unit. The same circle: the cow structure single-face corrugated device , in the single-sided tile list ~ preparation 120 5 Α Α μ becomes the spacer holding member Γ,!/ I. Figure 1) The base material 1Afi is first formed into a roll R". The material 5A pulled out by the roll R1 is first sent to a ten-watt roll l〇la, 101b. Corrugated machine (8). In the corrugated base 101, the wheel-shaped upper roll 101a and the gear-shaped lower roll (7) are bitten each other, and the unsorted material which is entangled with each other is formed into a corrugated shape. As a result, a corrugated sheet product was continuously produced. Then, the plate-shaped molded product 5B is conveyed in a predetermined direction by the lower roll 1 lb, and the unhardened adhesive 3a is applied to the wave-shaped molded product 5B by the coating roll 10 in the middle. The unhardened adhesive 3a is stored in the adhesive tank 1〇5, and the peripheral surface of the coating roll 103 is partially impregnated in the adhesive tank 1〇5. Further, on the circumferential surface of the coating roller 103, there is a slight contact with the top of the tooth of the lower roller 1〇1b. The coating roller 103 is rotated in a predetermined direction to attach the uncured adhesive agent to the peripheral surface of the coating roller 203, and is further applied to one surface of the corrugated sheet 5B. In order to prevent the unhardened adhesive 3a from adhering excessively to the circumferential surface of the coating roll 10, a water squeezing roll 7 is disposed in the vicinity of the coating roll 丨0. By adjusting 2111-8977-PF; Ahddub 20 J313626 lower roller 1 Q1 b and water squeezing roller ▼ a sigh of the amount of unhardened adhesive % of the double winded product 5B. In addition, when a hot-melt type adhesive is used as the following (see FIG. 2), for example, a heater (not shown) is attached to the _ 〇 〇 5, and the hot-melt type adhesive is melted into the heater by the heater. The adhesive 3a is hardened. On the other hand, the material u pulled out by the reel r2 is guided to the pressing roller 113 by two guide rollers uia and mb. The pressing roller 113 is disposed such that its circumferential surface is slightly in contact with the tooth top of the lower roller HUb, and the material 1A is attached to the corrugated molded article 5B by the waste roller 113 in a predetermined direction. Since the wave plate (four)-shaped mouth port 5B is coated with the unhardened adhesive agent 如上' as described above, the material 1A is crimped to the wave-plate-shaped molded article 5B, and the predetermined hand (...illustration) such as a heater or a radiation is used. The uncured adhesive 3a is cured by an artificial light source of a predetermined wavelength of light, a blower of a warm air blower, or a blower that blows out a cold air, and the corrugated sheet is opened by the hardener 3 (see FIG. 2) after hardening. 5\ and the material u are joined to each other. As a result, the elongated element constituting unit 10A which is the basis of the constituent unit of the element t can be continuously produced. In addition, each of the light 101a l lb and the press roll 113 is a predetermined temperature which is easy to adjust the shape of the wave-plate-shaped molded product 5 B, for example, "w", or a dish of about 150C or more. In the drawing, the direction of rotation of each roller and the direction in which the respective materials u and 5a are conveyed are indicated by solid arrows. Then, the component constituent unit 1G A is sequentially cut into a flawless size by the cutting machine, and is continuously formed into an element constituent unit (refer to the component constituent unit of FIG. 2) 2Hl-8 977-PF; Ahddub 21 1313626 The replacement unit is made up of a plurality of component forming units as described above to obtain a step of laminating the entire number of parts, and the composition of each component is as follows: and the coating can be applied as an adhesive of a squid, and the example is schematically shown in FIG. The device 130 is shown in Fig. 4. The device 130 is provided with: - the squeezing of the adhesive for the singular mam hardening adhesive 丨 3a; and the arbitrarily arranging the transfer, and the arrangement: the structure near the roller coffee is a partition member! For the above, the interval is maintained: the transport device is transported to the direction of a pair of ma, mb cattle = by the agent. The pair of parents 1 21 is here (four) is not hardened by a predetermined interval, and then several components are formed. In the above-described pair of rollers 121a and 121b, the upper roller 1213 functions as a conveying roller for conveying the element to the predetermined direction, and the lower roller portion is partially impregnated. In the adhesive tank 123, as a component of the component, the coating is not hardened. The action of the application roller of the agent 13a is performed by rotating the unhardened adhesive 13a in a predetermined direction by attaching to the center of the light 12, and applying it to the spacer member 5 of the component constituting unit 1 (). The water light 125 is disposed in the vicinity of the roller 121b, and removes the unhardened adhesive 13a which is excessively adhered to the roller (2). The unhardened adhesive for the component constituent unit can be adjusted by adjusting the roller mb and the water squeezing roller 125. When the hot-melt type adhesive is used as the adhesive 3 (see FIG. 2), for example, a heater (not shown) is attached to the (four) tank 123, and the heater is used to make a hot-melt adhesive. Melting into an uncured adhesive 13a. The components 10 of the unhardened adhesive 13a are coated by the device 130, as described above, 'layered in a predetermined direction, at the uppermost component 2111-8977-PF; Ahddub 22 1313626 constitutes the early element further borrowing _ ι θ sky plate member 15 (refer to Figure 此. After that, to omit the figure, such as u σ ',,, benefit, radiation artificial light source of a given wavelength, swearing The wind blower, the blower, or the blower that blows out the cold air The hardening adhesive 13a is hardened from the hardening treatment. By performing the hardening treatment, the bonding direction is in the direction of the stacking. The Japanese-made components 10 are mutually connected by the adhesive 13 (refer to FIG. 2). The total heat exchange element 20 of the human + human upper phase interface (see FIG. 4 and FIG. 4). Further, when a hot melt type adhesive is used in the unit fabrication step, the device 14 schematically shown in FIG. 5 can also be used. The constituent unit i〇A. The same figure is provided with a 140-series instead of the adhesive tank and the water-squeezing parent 7 shown in Fig. 3, and is provided with a supply roller 133 which is arranged to be in contact with the circumferential surface of the coating. The uncoated adhesive % is supplied to the peripheral surface of the coating roller 1G3, that is, the molten heat-sensitive adhesive; the supply tube 135 is supplied with the folded region of the coated parent-feeding roller 133 from above. The reduced-type adhesive; and the adhesive supply source (not shown) are sent to the supply tube 135 by the heat-sensitive adhesive. Except for this point, the configuration of the device 14Q is the same as that of the device 120 shown in FIG. 3. Therefore, among the components shown in FIG. 5 and the device shown in FIG. 3, the reference symbols used in FIG. 3 are attached. The description is omitted. Further, when a hot-melt type adhesive is used in the laminating step, the unhardened adhesive 13a, that is, the molten hot-melt type adhesive, may be applied to each of the element constituent units 10 by means of the apparatus 15G shown in Fig. 6 . The apparatus shown in the figure is provided with a pair of rollers 141a and 14b; and a supply roller 143 for storing the unhardened adhesive 13a is disposed on the circumferential surface of the roller 1411) in the vicinity of the roller 141b; a boundary region of the roller 143 is supplied with a molten hot melt type from the top thereof to a supply tube 145 of 2111-8977-PF; Ahddub 23 1313626; and a hot-type adhesive is sent to the supply tube adhesive supply source (not shown); And transport device. - In the above-mentioned - between the opposite rollers 141a and 141b, the lower side of the kiln 14u functions as a transporting means for transporting the element constituting unit 1G in a predetermined direction, and the upper side roller U1b applies the unhardened adhesive 13a to the element constituting unit 1Q. The role of the coating felt. The unit constituting unit i 系 is disposed with the partition member 1 as the lower side, and the door partition holding member 5 is conveyed to the __ 1 41 a, 141 b in the upward direction, and the unhardened adhesive is applied thereto. 3a. Embodiment 2. It is also possible to join the partition members constituting the respective element groove forming units of the total heat exchange element with the spacer member, or the element constituent units are joined to each other by the substrate and the thermal adhesive resin layer. The holding member uses the thermal adhesive resin layer constituting the spacer member as a row. The overall shape of the total heat exchange element having such a joint shape is the same as that of the entire heat exchange element of Fig. 1 (the entire shape of the whole heat exchange element is 2°), and thus the illustration thereof is omitted here. Fig. 7 is a cross-sectional view schematically showing the joint between the one element constituent unit having the above-described joint form and the element (four) forming unit and its vicinity. The same figure _ table 7 constitutes a unit shirt, and the component forming unit 4Qb joined thereto. The components shown in Fig. 7 are the same as those of the components shown in Fig. 2, and the same reference numerals as those used in Fig. 2 are attached, and the description thereof is omitted. /... Each of the above-mentioned components has the right to g; &lt; Λ Pulling the person to make up the 40a, the injury' has the partitioning member! And 5, the partitions of the partitions of the sea are kept at intervals, and the structure is maintained at 2111-8977-PF; Ahddub 24 1313626 pieces 35, which are ancient, and have the following beauty of 35A made of water-repellent materials. Next: , 9 is on the substrate 35B &gt; ^ , .. A thermally-adhesive resin layer or the like is a thermal-adhesive tree-dilute ethylene-diethyl methacrylate co-polymer (the film can be Π : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : When using "h to form the thermal adhesive resin layer 35", it is easy to increase the water retention of the member 35. ::... The heat-generating tree uses a non-porous film or sheet shape|gas resistance. It is easy to increase the penetration of the spacer member 35 in the respective element constituting units 4a, 4b, and the holding member", and the heat-adhesive resin layer 35^=1 and the spacer 你田# as a hot-melt type adhesive. The spacer member 40a and the component forming unit are joined to each other by a spacer 欉忐 一 η 70 〇 , , , , , , , , , , , , , , MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG The mountain parts 13 are joined to each other. As a pick-up of the shell 1J, the above-mentioned thermal adhesive tree, 1 is added to the water-soluble moisture absorbent of the partition member 1 to cut water; = = sex. In other words, the water-soluble moisture absorbent which is not hardened hard m + ^ does not dissolve - in the immersion The aqueous solution of the wet agent or the water-soluble moisture absorbent does not::: use a single-faced corrugating device to make each component constituent unit, and the strip can be used as a heat source in the single-sided tile assembly device or as a heat source. The heat-adhesive resin layer 35β is melted. Since the expansion and contraction of the heat-absorbing adhesive layer is small, the adhesiveness of the tantalum-like tannins is inhibited by the thickness of the contact resin layer 35Β, and the 2111-8977-PF can be inhibited; Ahddub 25 1313626 is caused by the workability of the spacer member 35. The cow constitutes the full heat exchange element partitioning member 1 and the spacer holding member food heat exchange element, which is the same as the embodiment 2: Reason, easy to γ f king hot father to change π pieces> From the easy to serve to the latent heat exchange efficiency, and use the eight hot father for 7 pieces, it can be easy - Wang are. Also, T - and the city The air conditioner or ventilator of the crime degree is easy to shorten the time required to manufacture the full heat exchange element. The energy required for the manufacturing is less, and the time is chosen, or minus mm ^, , '°果可谷易Map to reduce costs or reduce the environment caused by the surrounding environment EXAMPLES Hereinafter, examples and comparative examples and methods for producing the same will be described. <Example 1> DETAILED DESCRIPTION The total heat exchange of the present invention is first used to disintegrate and cure cellulose fibers (the paper is illusory and thick) 3〇〇em, special processing paper with a gas permeability of 5000 seconds or more is impregnated with a long-term strip of vaporized lithium with a certain amount of water-soluble moisture absorbent as a material for the partitioning member, and a white single-gloss upper paper with a thickness of about 80# m is used. The long strip is used as a material for the spacer member, and a long strip of the element is formed by the same apparatus as the apparatus 120 shown in Fig. 3. At this time, as a material for holding the spacer by the corrugator molding interval In the wave-plate-shaped molded article, an adhesive which is bonded to the material of the partition member is an EVA (ethylene vinyl acetate copolymer resin)-based hot-melt type adhesive which can be used for a period of several seconds. The hot-melt type adhesive was heated to about 15 (rc, to be a melt 2111-8977-PF; and Ahddub 26 1313626 2 5 g/m2 was coated to the extent that it was also the main wave-shaped plate-shaped molded article. The component constituting unit material is cut into a predetermined size to obtain a complex number = f unit, and the element constituting unit is SEBS (styrene-ethylene-butylene-styrene-styrene dispersion copolymerization elasticity) with a usable time of y. The hot-type adhesive composed of the body is coated by a device of the same type as shown in Fig. 4. At this time, the hot-melt type adhesive is heated to a melt of about c. The degree of 45g/m2. I苴', the corrugation of the spacer member of the element-constituting unit, and the corrugation of the spacer member of the 71-member unit above or below, viewed from the i-plane, substantially orthogonally Each layer of the constituent elements of the layer stacking unit is formed by stepping on the uppermost constituent unit and then laminating the molten material of the hot-type adhesive composed of the above-mentioned (4) 糸 十 10 10 10 10 10 10 10 The full heat exchange element 2 is shown in the same manner as the full heat exchange element of the same appearance, and has the same shape and joint member as the joint shape shown in Fig. 2. <Example 2 &gt; Processing cellulose fiber (pulp) to obtain a thickness of about 5 sec or more The special processing paper is impregnated with a certain amount of undercooling! The raw material of the raw hygroscopic agent is used as the material of the partitioning member, and the single-sided heat-melting of the substrate composed of the water-resistant paper is about The thickness of the three-force knife is about 5} the strip of m film is used as the material of the spacer structure. The above film acts as a thermal adhesive tree layer. Then the material of the spacer member is sequentially ordered. The corrugated machine is formed into a corrugated sheet-shaped product. The film is formed into a corrugated sheet-like molded product, and the film is used as a hot-melt type 2111-8977^PF; Ahddub 27 1313626 element constitutes a material for a single agent and a partition member. Join each other to get the long strips of ^^G. The pieces that make up the early yuan are cut into the established components 槿忐 - the size of the squad - a number of gentlemen - under the conditions of these elements constitute early The stratification, get the picture! The view into the 刼丄 ' ',, 乂 凡 凡 凡 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 7 are not connected ~ ~, the same form of joint partition members and spacing structure <comparative example> use a thickness of about 7 - strip Paper burning (phase W 乍 is the material of the spacer holding member, and it is difficult i» v. OT, (F sentence table for the long strip of components = early picking material (four) and stratification of multiple components constitute a single: 'Used in Ethyl acetate emulsion adhesive was added to adjust the viscosity of the water: 2, the whole heat exchange element was fabricated under the same conditions as in Example 1. When the long strip element was made into a unit material, the above was published; When the plurality of elements are combined to form a unit, the above-mentioned adhesive agent is: cloth 2: 29 g/m 2 . Jade <Evaluation> For the examples 1, 2 and the comparative example, Park No. 1 and the comparative example, each of the total heat exchanges The components 'measured in a high-humidity environment (10) μ η &amp; Bu, parental efficiency (sensible heat exchange efficiency), humidity exchange efficiency (latent heat exchange, exchange of sheep), and total heat exchange efficiency and The temperature exchange effect in the low humidity environment is the father's efficiency, and the total heat exchange efficiency. The measurement of the efficiency of the divisional rate in the high-humidity environment is based on the JIS B8628 (total heat exchanger) and the conditions for measuring the efficiency (summer conditions), and in the low humidity environment, r &lt; The measurement of each parent's efficiency is 2111-8977-PF; Ahddub 28 1313626 is based on ARI (American Air Conditioning and Refrigeration Association) i〇6〇Rating Air-to, Air

Energy Recovery Ventilation Equipment(通風設備氣斜 氣能量回收指標)之交換效率測定條件(冷氣條件)之條件 下’分別以遵照J IS B 8 6 2 8 (全熱交換器)之方法進行。將 該等之測定結果以清單示於圖8。 由圖8明顯可知,在於高濕度環境下的溫度交換效率 及濕度父換效率以及在於低溫環境下之溫度交換效率,實 施例卜2之各全熱交換元件與比較例之全熱交換元件大致 相等,惟在於低濕度環境下之濕度交換效率,實施例1、2 之各全熱交換元件大幅地較比較例之全熱交換元件高。此 可認為係由於相對於比較例之全熱交換元件,水溶性吸濕 劑(氯化鋰)由區隔構件轉移至間隔保持構件於元件之h 過程及製造後均有發生’而實施例卜2之各全熱交換: 件,於疋件之製造過程及製造後均幾乎沒有發生水溶性吸 氯化鐘)由區隔構件轉移至間隔保持構件。於實施例 2之各全熱交換元件,幾力 之轉移之社果,姓 手^又有&amp;生上述水溶性吸濕劑 、口 寺別是改善了在於低濕度環境下之水八 附特性,可推測因此而增加了濕度。 之“吸 以上’舉實施例說明關於本發 造方法以關於熱交換換氣裝置之實施形二=其製 限定於上述形態者。例如,未硬化接著;、之=發明並非 佈輥谁弁夕从 设考知j之塗佈,使用塗 一,亦可依照其材質以噴灑塗佈等方法進一。 又,間隔保持構件只要是可將2個區隔構件伴仃。 的間隔者即可,亦^ 隔構件保持既定 '、°使用彎曲為矩形波狀或三角波狀之 2Hl-8977-PF;Ahddub 1313626 片,或將複數枚板片等作為間 於各個元件構成單元或全埶交換’、持構件使用。然後,關 照對所欲製造之全敎交換元:…牛之全體形狀’亦可按 所求之性能―或對該全熱交換元件 製造方法,於上述形態以外可右夂“之全熱交換元件及其 各種變形、修飾、組合等。 [產業上的可利性] 本發明,只要是用於靜止形之 件,任何形態均可使用,可 、《之全熱乂換凡 進行办% 施a 用於建築物或車輛、船舶等 适仃二凋或換氣之各種裝置。 τ 【圖式簡單說明】 圖1係概略表示本發明之全 圖。 入状几件之一例之立體 圖2係概略表示圖j所示 成單元與其上之元件構… 件之1個元件構 圖。 丧σ處及其附近之剖面 …圖3係表示在於本發明之全熱交換元件之製造 作步驟,連續製作長條之元件構成單元材時所使 之S又備之一例之概略圖。 用 圖4係表示在於本發明之全熱交換元件 層積步驟,對各元件槿忐°方法之 ^各70件構成早兀塗佈接著料所使用之設傷 之一例之概略圖。 備 圖5係表示在於本發明之全熱交換元件之製造方法之 2111-8977-PF;Ahddub 30 i3j3626 早及*製作步驟,使用熱熔 成單元材時所使用之設備之一::=^ 層積步本發明之全熱交換元件之製造方法之 之設備⑦構成早凡塗佈熱熔型接著劑時所使用 两之―例之概略圖。 ® 7係概略表示本發明之埶 ― 成間隔伴持M彼 ,.,、乂換凡件之中,使用構 保持構件盥區曰作為接耆劑,使該間隔 元件構成單元之接人&quot;甘 ㈤几件構成與其上之 平兀之接合處及其附近之剖面圖。 圖8係表示各個實施例〗、2 換元件,分別… 2及比較例所製作之全熱交 刀別在於咼濕度環境下及低渴 度交換效率、濕度交換效率、及全執兄下,測定溫 表。 H熱父換S率之結果之圖 【主要元件符號說明】 1〜區隔構件; 3〜接著劑; 5 3 5〜間隔保持構件; 、10a〜l〇f〜元件構成單元; 13〜接著劑; 2 〇〜全熱交換元件; 3 5 A〜間隔保持構件之基材,· 35B〜熱接著性樹脂層。 2111-8977-PF;Ahddub 31The conditions for the exchange efficiency measurement (air-conditioning conditions) of the Energy Recovery Ventilation Equipment are carried out in accordance with JIS B 8 6 2 8 (total heat exchanger). The results of these measurements are shown in Figure 8 as a list. As is apparent from Fig. 8, the temperature exchange efficiency and the humidity replacement efficiency in a high-humidity environment and the temperature exchange efficiency in a low-temperature environment, the total heat exchange elements of the embodiment 2 are substantially equal to the total heat exchange elements of the comparative example. However, in the humidity exchange efficiency in a low humidity environment, the total heat exchange elements of Examples 1 and 2 were significantly higher than the total heat exchange elements of the comparative example. This is considered to be due to the fact that the water-soluble moisture absorbent (lithium chloride) is transferred from the partition member to the spacer member in the h process and after the manufacture with respect to the total heat exchange element of the comparative example. 2, the total heat exchange: the piece, almost no water-soluble chlorination clock occurs in the manufacturing process and after the manufacture of the element) is transferred from the partition member to the space-retaining member. In the total heat exchange element of the embodiment 2, the effect of the transfer of several forces, the surname of the hand ^ and the above-mentioned water-soluble moisture absorbent, the mouth temple is improved in the low humidity environment of the water eight characteristics It can be speculated that this increases the humidity. The embodiment of the present invention relates to the implementation of the heat exchange ventilating device. The second embodiment is limited to the above-mentioned form. For example, it is not hardened; then, the invention is not the cloth roll. From the application of the test, the application of the coating may be carried out by spraying or coating according to the material. Further, the spacer member may be provided with two spacer members. ^ The spacer member is kept ', '°2Hl-8977-PF, which is curved into a rectangular wave shape or a triangular wave shape; Ahddub 1313626 piece, or a plurality of plates, etc., as a component or a full-twisting unit Then, take care of the whole exchange element that you want to manufacture: ...the overall shape of the cow' can also be based on the desired performance - or the method of manufacturing the full heat exchange element, except for the above form Exchange elements and their various variations, modifications, combinations, and the like. [Industrial Applicability] The present invention can be used in any form as long as it is used for a stationary shape, and can be used for buildings, vehicles, ships, etc.仃Two withered or ventilated various devices. τ [Simplified Description of the Drawings] Fig. 1 is a schematic view showing the entire drawing of the present invention. Fig. 2 is a schematic view showing a component configuration of the unit shown in Fig. j and the component structure thereof. Fig. 3 is a schematic view showing an example of S in the process of manufacturing the full heat exchange element of the present invention, in which a continuous element is continuously formed into a unit material. Fig. 4 is a schematic view showing an example of a total heat exchange element stacking step of the present invention, in which each of the 70 members of the method of the present invention constitutes an early wound coating. Figure 5 shows one of the devices used in the method of manufacturing the total heat exchange element of the present invention, 2111-8977-PF; Ahddub 30 i3j3626, and * fabrication steps, using hot-melt into a unit: :=^ The apparatus 7 of the method for producing the total heat exchange element of the present invention constitutes an outline of two examples used in the application of the hot-melt type adhesive. The ® 7 series schematically shows the 埶 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成 成A few sections of Gan (5) that form the junction with the flat above it and its vicinity. Figure 8 shows the various embodiments, 2 replacement components, respectively... 2 and the comparative example of the full heat transfer knife in the humidity environment and low-thirty exchange efficiency, humidity exchange efficiency, and the full control, measured Thermometer. H heat father change S rate results [main component symbol description] 1 ~ partition member; 3 ~ adhesive; 5 3 5 ~ spacer holding member; 10a ~ l〇f ~ component constituent unit; 13 ~ adhesive 2 〇 ~ total heat exchange element; 3 5 A ~ spacer holding member substrate, · 35B ~ thermal adhesive resin layer. 2111-8977-PF; Ahddub 31

Claims (1)

1313626 十、申請專利範圍: i. 一種全熱交換元件,具有·. 區隔構件,將添加水溶性 層積構造,藉由接著劑鱼=之片狀:及 一起形成氣流之流路之間隔保件接合與該區隔構件 其特徵在於: ' 乂互層積, 上述間隔保持構件具有保水性; 上述接著劑,對於上述 ☆ &gt;劑之水溶液顯示非溶解性。^ °及濕劑或該水溶性吸濕 2.如申請專利範圍第!項所述的 上述接著劑係有機溶劑系 、.、、、乂換兀件’其中 劑 '或熱熔型接著劑。 W、無溶劑系反應型接著 3·如申請專利範圍第!項所述的 上述區隔構件,包含 …又換兀件,其中 料。 π上述水溶性吸濕劑之保水性材 I :·如申請專利範圍第〗項所述的全 =隔!持構件具有:包含保水性材料之基材;及;: 該基材之早面之熱接著性樹脂層, π ; 塌接著性樹腊層’係作為接合上述間隔 上述區隔構件之接著劑之作用。 ' 牛 、5.:申請專利範圍第i項所述的全熱交換元件 ^述水浴性吸濕劑,係具有潮解性的鹼金屬鹽或驗土金屬 6. 一種全 交換元件 之製造方法,製造具有將添加水 2111-8977-PF;Ahddub 32 1313626 生吸濕劑之片狀之區隔構件 接合與該區隔構件 錯由接者劑與區隔構件 交互層積之層積構造者,/ 4流之流路之間隔保持構件, 其特徵在於包含·· 早凡製作步驟,其係製 隔構件與藉由保水性材料==,以接著劑使上述區 合之元件構成單元;及’ 述間隔保持構件互相接 層積步驟,其細接著i 合,得到層積配置複數個上述元件構::構成…互接 件, 牛構成早兀之全熱交換元 各個用於上述單元絮 層積步驟夕卜+ 乍乂驟之上述接著劑及用於上述 ,上述接著劑,對上述水 吸濕劑之水溶液顯示㈣解性。 水冷性 7.如申請專利範圊笛β α 方丰甘 項所述的全熱交換元件之製造 方法,其中各個用於上 於上述層積步驟之上述接二步驟之上述接著劑及用 tI. 攻接者劑,係有機溶劑系接著劑、| 溶劑系反應型接著劑、或熱_接著劑。 … =請專利範圍第6項所述的全熱交換元件之製造 方去,其中上述區隔構件,包 之保水性材料。 1改上述水溶性吸濕劑 9.如申請專利範圍第6項所述的全熱交換元件之製造 Μ ’其中上制隔保㈣件具有:包含保水性材料之基 材’及设於該基材之單面之熱接著性樹脂層, 上述熱接著性樹脂層’係用於作為上述單元製作步驟 33 2111-8977-PF;Ahddub 1313626 之上述接著劑。 1 0.如申請專利範圍第6項所述的全熱交換元件之製 造方法,其中上述水溶性吸濕劑,係具有潮解性的驗金屬 鹽或驗土金屬鹽。1313626 X. Patent application scope: i. A total heat exchange element with a partitioning member, which will be added with a water-soluble laminated structure, which is formed by the adhesive fish = sheet form: The joining member and the partitioning member are characterized in that 'the 乂 interlaminates, the spacer member has water retention property; and the above-mentioned adhesive exhibits insolubility with respect to the aqueous solution of the ☆ &gt; agent. ^ ° and the wet agent or the water-soluble moisture absorption 2. As claimed in the scope of the patent! The above-mentioned adhesive agent is an organic solvent system, a resin, a silicone resin, or a hot melt adhesive. W, solvent-free reaction type followed by 3. As claimed in the scope of patents! The above-mentioned partition member described in the item includes, in turn, a piece of material. π The water-retaining material of the above-mentioned water-soluble moisture absorbent I: The full-gap member according to the above-mentioned patent application scope has: a substrate comprising a water-retaining material; and: an early surface of the substrate The heat-adhesive resin layer, π; the collapsed wax layer' serves as an adhesive for bonding the above-mentioned spacer members. '牛, 5.. The total heat exchange element described in the scope of claim i is a water-bathing moisture-absorbing agent, which is a deliquescent alkali metal salt or a soil-measuring metal. 6. A method for manufacturing a full-exchange element, manufactured a laminated structure having a sheet-shaped partition member to which water 2111-8977-PF; Ahddub 32 1313626 raw moisture absorbent is joined, and a partitioning structure in which the partition member is alternately laminated by the joint agent and the partition member, / 4 An interval maintaining member for a flow path, characterized by comprising: an early manufacturing step of forming a spacer member and a component constituting the above-mentioned region by a water-repellent material ==; and an interval The steps of stacking the components to each other, and then merging them together to obtain a plurality of the above-mentioned components are arranged in a layered manner: the constituents are interconnected, and the full heat exchange elements of the cows are used for each of the above-mentioned unit flocculation steps. The above-mentioned adhesive agent and the above-mentioned adhesive agent exhibit a (four) solution to the aqueous solution of the water-absorbing agent. Water-cooling property 7. The method for manufacturing a total heat exchange element as described in the patent application Fan Yidi β α Fang Feng Gan, wherein each of the above-mentioned adhesives used in the above two steps of the above-mentioned stacking step and tI. The attacker agent is an organic solvent-based adhesive, a solvent-based reactive adhesive, or a thermal_adhesive. ... = Please refer to the manufacture of the full heat exchange element described in the sixth paragraph of the patent, wherein the above-mentioned partition member, the water retaining material of the package. (1) modifying the above-mentioned water-soluble moisture absorbent 9. The manufacture of the total heat exchange element according to claim 6 of the patent application Μ 'wherein the upper insulation (four) member has: a substrate comprising a water retentive material' and is provided on the base The one-side thermal adhesive resin layer of the material, the above-mentioned thermal adhesive resin layer ' is used as the above-mentioned adhesive for the above-mentioned unit production step 33 2111-8977-PF; Ahddub 1313626. The method for producing a total heat exchange element according to claim 6, wherein the water-soluble moisture absorbent is a deliquescent metal salt or a soil metal salt. 2111-8977-PF;Ahddub 342111-8977-PF; Ahddub 34
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