TW200900176A - Total heat exchanger element and process for manufacturing the same - Google Patents

Total heat exchanger element and process for manufacturing the same Download PDF

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Publication number
TW200900176A
TW200900176A TW096124461A TW96124461A TW200900176A TW 200900176 A TW200900176 A TW 200900176A TW 096124461 A TW096124461 A TW 096124461A TW 96124461 A TW96124461 A TW 96124461A TW 200900176 A TW200900176 A TW 200900176A
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Taiwan
Prior art keywords
water
adhesive
heat exchange
total heat
exchange element
Prior art date
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TW096124461A
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Chinese (zh)
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TWI313626B (en
Inventor
Masaru Takada
Hidemoto Arai
Takanori Imai
Michio Murai
Shinya Tokizaki
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Mitsubishi Electric Corp
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Publication of TW200900176A publication Critical patent/TW200900176A/en
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Publication of TWI313626B publication Critical patent/TWI313626B/zh

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D9/0025Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being formed by zig-zag bend plates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D53/00Making other particular articles
    • B21D53/02Making other particular articles heat exchangers or parts thereof, e.g. radiators, condensers fins, headers
    • B21D53/04Making other particular articles heat exchangers or parts thereof, e.g. radiators, condensers fins, headers of sheet metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F3/00Plate-like or laminated elements; Assemblies of plate-like or laminated elements
    • F28F3/02Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4935Heat exchanger or boiler making

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Laminated Bodies (AREA)

Abstract

In the manufacturing of a total heat exchanger element of laminate structure composed of, alternately superimposed, sheet-shaped partition members having a water-soluble moisture absorbent added thereto and spacing members bonded with an adhesive to the partition members so as to provide a gas stream channel in cooperation with the partition members, water retentivity is imparted to the spacing members, and an adhesive being insoluble in the water-soluble moisture absorbent or aqueous solutions of the water-soluble moisture absorbent is used as the above adhesive. Accordingly, it can be facilitated to obtain a total heat exchanger element that facilitates buildup of, for example, a ventilator or air conditioner of high reliability realizing high latent heat exchange efficiency.

Description

200900176 九、發明說明: 【發明所屬之技術領域】 本發明,係關於用於 3!,於?接*,ώ叩 、構成二調機和換氣裝置之埶交換 為,於2種軋流間進行潛埶 …又換 換元件及其製造方法# :::、又、及顯熱之交換之全熱交 器之全熱交換元件及其製=二係用於靜止形的熱交換 【先前技術】 於構成空調機或換氣步上 止形之2種’在於任何 換父換“旋轉形與靜 藉由進行顯熱之交換之顯熱交換效率較僅 佳地使用。全熱交換元件二數广的全熱交換元件較 隔構件與波板狀的間隔保形’係將具有片狀的區 藉由片段瓦愣製造機(單面:楞 材料製造。 榜機)裳作’將該長條物作為 用於旋轉形之熱交換器之全熱交換元件 條物的既定面塗佈接著 ’、、上述長 造。 』冉將該長條物以輪狀捲取而製 :靜止形的熱交換器之全埶 述長條物裁切成既定的大小 複、、70 ’系將上 後,藉由將各元件構成單_作複數個元件構成單元 層積方… 既定的方向層積,即藉由向 層積方向相鄰之各元件構成單元 致互相-交的方向層積而製造。此時=構件之波紋大 元件椹士π- 此#,向層積方向相鄰之 冓成早兀’相互藉由接著劑互相接合。 用於旋轉形的熱交換器之全熱交換元件與靜止形的熱 2Ul-8977-PF;Ahddub 5 200900176 父換器之全熱交換元件,在熱交換 構件及間隔仵持構# 、 原理,對區隔 恥保持構件之各個要求之功能 。 用於旋轉形的熱交換器之全熱交換元件’對=而言, 隔保持構件之分別要长 、°°同冓件及間 J要求畜熱,放熱性及蓄濕. 方面,於用於靜止形的熱交換器之全熱交半另 在2種乳流間經由區隔構件進行潛 、 於 :件故對™要求傳熱性及透濕性 用要求保持區隔構件相互之間隔確保氣流之流路的作 传關於=流㈣漏之某種程度的氣體遮蔽性。本發明 係關於用於靜止形熱交換器之全熱交換元件者, 對用於靜止形之熱交換器之全熱交換元件做說明。 構成㈣交換元件之區隔構件或間隔保持構件 ::使用紙、紙聚與樹脂混抄之材料、樹脂、金屬箱等: 水二生Π有效地交換潛熱’於區隔構件之素材預先添加 ^或非水溶性吸濕劑(透濕劑)。作為水溶性吸濕劑, =使用氯化鍾等的鹼金屬鹽或氯化鈣等鹼土類金屬鹽 的^為非水溶性的吸濕劑,使用石夕膠或強酸性或強驗性 的離子交換樹脂脂粉體等。 〃例如於專利文獻1,記載有一種全熱交換體用紙,盆 係於難然性基紙之單面或雙面設以吸放濕性粉體(非水溶 性吸濕劑)與膠合劑為主體之吸放濕性塗佈層,並且於上述 難然性基紙之單面設熱接著性接著劑層者。又,於專利文 獻2,記載有一種吸附片,其係將粒狀吸附體部分埋沒在 形成於片基材上之接著劑層’藉由含有微粒子吸附劑(非水 6 2111-8977~PF;Ahddub 200900176 溶性吸濕劑)之吸附添丨 竹J層覆盍上述接著劑層與粒狀吸 體。該吸附片’用於旋轉形全熱交換器或除濕轉子等。 ^專利文獻3,記载有—種熱交換元件,其係以牛皮 紙或透濕性或者吸渴枓 ‘性膑製作區隔構件(平板狀),此外以 層壓合成樹脂膜之金屬笮 屬泊或合成樹脂膜製作間隔保持構件 (波狀板),於區隔槿杜 構件斗加水浴性吸濕劑者。於專利文獻 载有一種複合傳熱基芯,其係藉由添加水溶性的吸濕 劑或非水溶性的吸濕劑之紙製作區隔構件(襯塾)’藉由金 屬箱製作間隔保持構件f M 曰 用於全熱交換器。 板)者。該複合傳熱以,係 於專利文獻5,記载有一種熱交換器,其係藉由軟化 :占南的纖維(纖維素纖維)與較該纖維軟化點 抄紙之素材製作間隔保持構 樹月… 寸饵仵(間隔板),以上述樹脂接用 作為膠合劑藉由熱熔接使 保持構件與區隔構件互相接合 製作7G件構成單元(單位構 構成單元,使用水系接著初 疋個數之元件 劑層積而製造。’、或者使用上述樹脂作為膠合 :專:文獻6,記載有—種熱交換器,其係藉由於板 狀的多孔質構件的單面形成具 有工氣‘蔽成之透满膜,並 且於另一面形成吸濕劑声之洛麯产叶α A 立 ^層之虱體遮蔽物製作區隔構件,將 該區隔構件與間隔保持構件藉由水系接著劑互相接合者。 然後’於專利文獻7,記載有一種熱交換元件,其係 使間隔保持構件(間隔板)之構成 e ^ 密著於多孔質材(織布、不織布“ “生之薄膜 小為布、編布、紙等)之構成,藉 2Ul-897 7-PF;Ahddub η 200900176 由=於間隔板持構件或區隔構件之單面全體之哉接著性 層接著該間隔保持構件與區隔構件(區隔板)製作元 件構成單元(單位構件)後,藉由使用水系接著劑層= 成單元而製作者。於該熱交換樹脂之區隔構 仵構成,係例如將可撰潘神穿锈尤某# > 多孔質材之構成。 ’、’、軋、濕膜密著於 專利文獻1 :特開平1 0-1 53398號公報 專利文獻2 專利文獻3 專利文獻4200900176 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to the use of 3! After the *, ώ叩, 二 二 和 和 和 和 和 和 和 和 和 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶 埶The total heat exchange element of the full heat exchanger and its system = the second system is used for the heat exchange of the static shape. [Prior Art] The two types of the air conditioner or the air-conditioning step are in the form of any change of the parent shape. The sensible heat exchange efficiency of the exchange of sensible heat is better than that of the sensible heat exchange. The total heat exchange element of the total heat exchange element has a wide area of the partition member and the wave plate shape. By the segment corrugator manufacturing machine (single-sided: 楞 material manufacturing. The top machine) is used to 'coat the long strip as a predetermined surface of the strip of the total heat exchange element for the heat exchanger of the rotary shape, then', The above-mentioned long build. The 长 卷 冉 冉 冉 冉 冉 冉 冉 冉 冉 冉 冉 冉 冉 冉 冉 : : : : : : : : : : : : : : : : : : : : : : : : : : : : : By arranging each element as a single element to form a unit layering side... a given direction layering, that is, by The components in the direction of the product are laminated in the direction of mutual-intersection and are manufactured. At this time, the corrugated large component of the component is a 椹-π-#, which is adjacent to the stacking direction. The subsequent agents are joined to each other. The total heat exchange element for the rotating heat exchanger and the static heat 2Ul-8977-PF; Ahddub 5 200900176 The total heat exchange element of the parent exchanger, in the heat exchange member and the spacer structure # , Principle, function of each requirement for the shame-retaining member. The full heat exchange element for the rotating heat exchanger 'for the =, the separation member must be long, ° ° with the same piece and between J requires livestock heat, exothermic and moisture storage. In terms of the total heat transfer of the heat exchanger used for the stationary type, it is submerged between the two types of emulsions via the partition member. For the purpose of moisture and moisture permeability, it is required to keep the partition members apart from each other to ensure that the flow path of the air flow is related to a certain degree of gas shielding of the flow (four) leakage. The present invention relates to the full heat for the stationary heat exchanger. Exchange element, for the heat exchanger used for stationary The exchange element is described as being. (4) The partition member or the space-retaining member of the exchange element: a material that is mixed with a resin, a resin, a metal box, or the like is used: the water is effectively exchanged for latent heat' The material is pre-added with or a water-insoluble moisture-absorbing agent (moisture-permeable agent). As a water-soluble moisture absorbent, = an alkali metal salt such as a chlorinated clock or an alkaline earth metal salt such as calcium chloride is water-insoluble. As the moisture-absorbing agent, a gelatin powder or a strong acid or a strong ion exchange resin powder or the like is used. For example, Patent Document 1 discloses a paper for a total heat exchanger, and the pot is attached to one side of the urethane base paper. Or a double-layered moisture absorbing coating layer mainly comprising a moisture absorbing and releasing powder (water-insoluble moisture absorbent) and a binder, and a heat-adhesive adhesive agent on one side of the above-mentioned catastrophic base paper Layer. Further, Patent Document 2 discloses an adsorption sheet in which a granular adsorbent portion is buried in an adhesive layer formed on a sheet substrate by a microparticle adsorbent (not water 6 2111-8977 to PF; Ahddub 200900176 Soluble Moisture Resistant) Adhesive Addition J J layer covers the above adhesive layer and granular absorber. The adsorption sheet ' is used for a rotary total heat exchanger or a dehumidification rotor or the like. Patent Document 3 describes a heat exchange element which is made of kraft paper or moisture permeable or thirsty 膑 膑 膑 膑 膑 平板 平板 平板 , , , , , , , , , , , , , 层压 层压 层压 层压 层压 层压 层压 层压 层压 层压 层压 层压Or a synthetic resin film is used to form a spacer member (wave plate), and a water bathing hygroscopic agent is added to the partition member. The patent document contains a composite heat transfer core which is made of a water-repellent absorbent or a water-insoluble absorbent material to form a partition member (liner). f M 曰 is used in the total heat exchanger. Board). This composite heat transfer is disclosed in Patent Document 5, and discloses a heat exchanger which is constructed by softening: fibers occupying the south (cellulosic fibers) and making a space between the fibers of the softening point of the fibers. The inch bait (spacer) is made of the above-mentioned resin as a glue, and the holding member and the partition member are joined to each other by heat welding to form a 7G component unit (unit structure unit, and the water system is used for the number of elements) The agent is laminated and manufactured. 'Or the above resin is used for gluing: Special: Document 6 describes a heat exchanger which is formed by the formation of a single-sided porous member of a plate-like porous member. On the other side of the film, and forming a moisture absorbing agent, the scorpion mask of the granules α A 立 layer is used to form a partition member, and the partition member and the spacer member are joined to each other by a water-based adhesive. Then, in Patent Document 7, there is described a heat exchange element in which the structure of the spacer member (spacer) is adhered to the porous material (woven fabric, non-woven fabric) "the raw film is small cloth, braided , The composition of the other, by 2Ul-897 7-PF; Ahddub η 200900176 by = the spacer layer or the partitioning member of the single-sided whole layer of the adhesive layer followed by the spacer member and the partition member (region partition) After the element is composed of a unit (unit member), it is produced by using a water-based adhesive layer = unit. The structure of the heat-exchange resin is, for example, a smear-proof pan rust yu yu # > The structure of the material. ', ', rolling, and wet film are adhered to Patent Document 1: Japanese Laid-Open Patent Publication No. Hei No. Hei No. Hei No. Hei.

專利文獻5 專利文獻6 專利文獻7 特開2003-251 133號公報 特開平6-1 09395號公報 特開平7-1 9789號公報 特開平1 0-54691號公報 特開2001-27489號公報 特開平8-21 9676號公報 【發明内容】 [發明所欲解決的課題] 、由抑制全熱交換元件之製造成本之觀點,較使用記載 於專利文獻1之全熱交換體用紙或記载於專利文獻2用於 吸收片之非水溶性吸㈣,使用水溶性的㈣劑較佳。例 將Jc办)·生的吸濕劑於紙塗佈、乾燥,即可容易地製作 可得添加吸濕劑之區隔構件之良好的素材。 惟,大部分的水溶性吸濕劑,溶解於水時發生電離 使該水(水溶液)的導電度非常的大,故在具備於區隔構件 、v力K冷性的吸濕劑之全熱交換元件之空調機或換氣裝 2Hl-8977-PF;Ahddub 8 200900176 f,水溶性的吸濕劑可能溶解於熱交換時可能產生的結露 ;、二該結露水與充電部接觸而有產生過電現象等重大的 不適之可能性。 埶六:抑制如此之不適上’較藉由如專利文獻3所記载之 屬^2或專利文獻4所記載之複合傳熱基芯,使用金 Ϊ膜構成間隔保持構件,或如專利文獻5所 株盐1 # 3有樹月曰之混抄紙形成間隔保持構 件,藉由紙等保水性材料形成間隔保持構件較佳。 ^如記載於專利文獻6之熱交換器,使^粉㈣ 酉曰i乙烯糸乳膠等水系接著 者劑將區隔構件與間隔保持構件 =接:,則雖可提高製作全熱交換元件時之作業性及接 著劑之知作性,但有發生者取沾血 株1你" 潛熱交換效率較由區隔構 件早位之透濕性能之測定結果 潛熱交換效率低的 。此現象,以保水性低的樹腊片等製作區隔構件之全 熱交換7G件並不會發生,传 件之入執n 係、旧氏專保水性材料製作區隔構[Patent Document 5] Patent Document No. JP-A-2003-251 No. 2003-251 No. PCT Publication No. JP-A No. 6-1 09395. [Explanation of the Invention] [Problems to be Solved by the Invention] From the viewpoint of suppressing the manufacturing cost of the total heat exchange element, the paper of the total heat exchanger used in Patent Document 1 is used or described in the patent literature. 2 is used for the water-insoluble absorption of the absorbent sheet (4), and it is preferred to use a water-soluble (four) agent. For example, it is possible to easily produce a good material which can provide a partition member to which a moisture absorbent is added by applying and drying a raw moisture absorbent on a paper. However, most of the water-soluble moisture absorbents are ionized when dissolved in water, so that the conductivity of the water (aqueous solution) is extremely large, so that the heat-absorbing agent having the partition member, the v-force and the coldness is all-heated. Exchange unit air conditioner or ventilator 2Hl-8977-PF; Ahddub 8 200900176 f, water-soluble moisture absorbent may dissolve in condensation that may occur during heat exchange; second, the dew condensation water is in contact with the charging part The possibility of major discomfort such as electrical phenomena.埶6: Inhibition of such an inconvenience is made by using a metal tantalum film to form a space-receiving member, as in the composite heat transfer core described in Patent Document 3 or Patent Document 4, or as in Patent Document 5 The salt 1 #3 has a mixed paper of a tree sap, and forms a spacer member. It is preferable to form a spacer member by a water-repellent material such as paper. ^ As described in the heat exchanger of Patent Document 6, the water-based carrier agent such as the powder (4) 糸i vinyl lanthanum latex is used to connect the partition member to the space-retaining member = to improve the production of the total heat exchange element. The workability and the adhesive are known, but there are those who take the blood strain 1 and you have a low latent heat exchange efficiency compared with the moisture permeability of the early components. In this phenomenon, the 7G pieces of the whole heat exchange of the partition members made of the water-retaining tree wax sheets and the like do not occur, and the transfer of the parts to the n-series and the old-purpose water-repellent material production area partition structure

熱父換件所固有者。在對區隔構件之水溶性吸渴 劑的添加量多的全熱交換元件,該現象會顯著地發I 本案發明者們,在反覆解明上述現象之原因之研究之 中’著眼於使用水系接著劑,腺 爐… 矛接者y將添加水溶性吸濕劑之區隔 構件’與以保水性材料製作之間隔保持構件互相接人,則 由水系接著劑之塗佈至該水系接著劑乾燥完成接合之間, 水系接著劑之溶劑之水滲入區隔構件與間隔保持構件之錐 方’此時區隔構件中的水溶性吸濕劑的_部分 2 著劑轉移到間隔保持構件。水溶性吸濕劑由區隔構件轉移 2111-8977-PF;Ahddub 9 200900176 至間隔保持構件的社果,/4入 p椹株盔、主, 在Λ s全熱交換元件之階段,區 二降; 區隔構件單獨時之透難能1顯干; 此會降低潛熱交換效率。 向顯不可 或區_ =全7::::二交換器,於間隔保持構件 編隔保持構件及區隔 則即於區隔構件添加水溶性早二 劑由區隔構件對間隔保持構件之轉移。但b 7:性吸澡 :記載之熱交換器,由於在層積既定個數:元件:二7 製作全熱交換元件時使用水糸…要文之兀件構成早凡 二、:由“構件對間隔保持構件之轉移,於 軌交 換-件之階段無法維持區隔構件單: 濕性龅,;收4 Μ〒苒件早獨時之透 腐Γ生此而降低潛熱交換效率。 本發明係有鑑於上述情 、 潛熱的交換效率高,且可靠度::以得到可容易構成 全熱交換元件為目的。又,:一周機或換氣裝置等之 潛熱的交換效率高,且可靠声係以得到可容易構成 入批 靠度南的空調機或換翁获罢笼之 全熱交換元件之製造方法為目的。 、風裝置4之 [用以解決課題的手段] 本發明之全熱交換元株 劑之片狀之區隔構件,:;由::具有將添加水溶祕 區隔構件-起形成氣产之^ “劑與區隔構件接合與該 之層積構造者,其特I在:路=:持構件,交互層積 接著劑’對於水溶性吸濕劑^ = 2件具有保水性, m合性°及濕劑之水溶液顯 2Hl-8977-PF;Ahddub 10 200900176 示非溶解性。 本發明之+教# …交換元件之势接 添加水溶性吸濕劑之片 ^ ' ,/、係製造具有將 隔構件接合與該區隔:區隔構件,及藉由接著劑與區 構件,交互層積之層:起形成氣流之流路之間隔保持 單元製作步驟,其她./、特徵在於:包含·· 件與具有保水性之門/ 複數個’以接著劑使區隔構 元;及 仏保持構件互相接合之元件構成單 f 層積步驟,其係以接著劑使元件構成單 得到層積配置複數個元件 接口, 各個用於單元製作之全熱交換元件, 著劑,針Π '驟之接著劑及用於層積步驟之接 者劑’對水溶性吸濕劑, 牧 溶解性。 以料吸濕劑之水溶液顯示非 [發明效果] 於本發明之全熱交換元件,作為使添加水溶性 :區隔構件與具有保水性之間隔保持構件相互接合之接; ^使用對水溶性吸濕劑或該水溶性吸濕劑之水溶液顯示 奋解I·生者& s之’作為使區隔構件與間隔保持構件相 互接合之接著劑’使用於未硬化之狀態下水溶性吸濕劑不 會溶解’於硬化後水溶性吸濕劑或該水溶性吸濕劑之水溶 液不會浸入者。 因此,無論在於該全熱交換元件之製造過程,在於製 造後,可抑制水溶性吸濕劑由區隔構件經由接著劑轉移^ 間隔保持構件。結果,於本發明之全熱交換元件,容易於 2111-g977-PF;Ahddub 11 200900176 區隔構件添加所期望量 且亦可宏篇士 a <及濕剤以楗馬潛熱的交換效率, 了-易抑制該潛熱的交換效率之經時降低。 又由於間隔保持構件具有保水性· 溶性吸濕劑溶解於結露水, 吏產生、,·口路水 構件吸收,故使 \ H露水以間隔保持 氣穿置等日丰 "之王”,、父換元件構成空調機或換 風衣置專時,可抑制 該充雷邱% # 土 k ^合性及濕劑之結露水接觸 充電而產生過電現象等重大的不適。 由該等理由,根據本發明, 赦交換#I * 易地侍到容易構成潛 …、又換效羊向’且可靠度高 交換元件。 风义換乳震置等之全熱 【實施方式】 以下,參照圖面詳細說明關於本發明 及其製造方法之各個實施形態。再者,本王'”、父、凡件 以下說明之實《態者。本發明並非限定於 實施形態1. 圖1係概略表示全熱交換元件 — 干之—例之立體圖。干於 同圖之全熱交換元件20,係且有 ^不於The one that is intrinsic to the hot parent. In the case of the total heat exchange element in which the amount of the water-soluble stimulating agent added to the partition member is large, the phenomenon is remarkably made. The inventors of the present invention have focused on the use of the water system in the study of the reasons for resolving the above phenomenon. Agent, gland furnace... The spear y is to add the partition member of the water-soluble moisture absorbent to the spacer member made of the water-retaining material, and the water-based adhesive is applied to the water-based adhesive to be dried. Between the joints, the water of the solvent of the aqueous binder penetrates into the taper of the partition member and the spacer member. At this time, the portion 2 of the water-soluble moisture absorbent in the partition member is transferred to the spacer member. The water-soluble moisture absorbent is transferred from the partition member 2111-8977-PF; Ahddub 9 200900176 to the spacer retaining member, /4 into the p椹 helmet, the main, at the stage of the Λ s full heat exchange element, the second drop ; The partitioning member alone can be difficult to dry; this will reduce the latent heat exchange efficiency. To the invisible zone _ = all 7:::: two exchangers, in the spacer retaining member, the spacer member and the partition are added to the partition member, the water-soluble early two agent is transferred by the partition member to the spacer member . But b 7: Sexual bath: The heat exchangers listed are due to the number of layers in the stratification: Components: 2: 7 The use of water rafts when making full heat exchange elements... The components of the text are composed of two parts: For the transfer of the spacer member, the partition member can not be maintained at the stage of the rail exchange-piece: wet enthalpy, and the entanglement of the Μ〒苒 早 早 早 早 早 早 早 早 早 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 In view of the above situation, the exchange efficiency of latent heat is high, and the reliability is: for the purpose of easily forming a total heat exchange element. Moreover, the exchange efficiency of latent heat such as one-week or ventilator is high, and the reliable sound system is The purpose of the present invention is to provide a method for manufacturing a total heat exchange element that can be easily formed into an air conditioner in the south of the batch. The sheet-shaped partition member of the agent::; has: a layered structure in which the agent is added to the partition member and the layered structure is formed by adding a water-soluble secret partition member, and the special structure is: =: holding member, interactive layering adhesive 'for water-soluble moisture absorption ^ 2 = water-retentive, aqueous m-wetting and adhesion of the significant ° 2Hl-8977-PF; Ahddub 10 200900176 shown insolubility. The surface of the + teaching element of the present invention is characterized in that a sheet of water-soluble moisture absorbent is added, and the partition member is joined to the partition member: a partition member, and an adhesive agent and a region member. The layer of the interactive layer: the step of forming the interval maintaining unit for forming the flow path of the air flow, the other is characterized by: comprising: a member and a door having water retention / a plurality of 'adhesives to make the partitioning element; And the components in which the holding members are joined to each other constitute a single f-stacking step, which is formed by laminating the components to form a plurality of component interfaces, each of which is used for the whole heat exchange component of the unit, the agent, and the needle ' The adhesive and the carrier used in the lamination step are 'soluble in water-soluble moisture absorbent. The aqueous solution of the moisture absorbent shows no effect of the invention. The total heat exchange element of the present invention is used as a joint for bonding water-soluble partition members and spacer members having water retention; The wet agent or the aqueous solution of the water-soluble moisture absorbent shows that the 'antibiotic for the joint member and the spacer member' is used as the water-soluble moisture absorbent in the unhardened state. It will dissolve in the water-soluble moisture absorbent after hardening or the aqueous solution of the water-soluble moisture absorbent will not be immersed. Therefore, regardless of the manufacturing process of the total heat exchange element, it is possible to suppress the water-soluble moisture absorbent from being transferred from the partition member via the adhesive agent to the spacer holding member after the production. As a result, in the total heat exchange element of the present invention, it is easy to add the desired amount to the 2111-g977-PF; Ahddub 11 200900176 partition member, and it is also possible to exchange the efficiency of the latent heat of the thrips. - It is easy to suppress the decrease in the exchange efficiency of the latent heat over time. Further, since the spacer member has the water retention property and the soluble moisture absorbent is dissolved in the dew condensation water, the crucible is generated, and the water member of the mouth is absorbed, so that the dew of the water is kept at intervals to maintain the gas, such as the "King of Nikko". When the father replaces the components to form an air conditioner or a windshield, it is possible to suppress major discomfort such as overheating caused by the contact of the water and the dew condensation water of the wet agent. According to the present invention, the 赦 exchange #I * is easy to serve, and it is easy to form a latent ..., and the sheep is changed to a 'high reliability exchange element. The full heat of the wind and the like is changed. [Embodiment] The following is a detailed description with reference to the drawings. Various embodiments of the present invention and the method of manufacturing the same will be described. Further, the "the king", the father, and the other are described below. The present invention is not limited to the embodiment 1. Fig. 1 is a perspective view schematically showing an example of a total heat exchange element. Drying in the same heat exchange element 20 of the same figure,

Ba 有月狀區隔構件1盥浊拓肋 間隔保持構件5交互層積 /、波板狀 入…, 層積構造之正交流型者。於亨 王…父換το件20,藉由層積6個元 _ ' ,、 1干攝成單π 1 0 a〜1 Π f 成上述層積構造,於最上面 7 a社 楫成早70 1 〇f上進一牛 曰積天板構件15。於i個元件 / 干兀之間隔保持構件r 之波紋與其上或其下之元件構 姑对士工 苒成早70之間隔保持構件5之 波 文,由平面所視’大致正交。士 5之,在某元件構成單 2111-8977-PF;Ahddub 12 200900176 元之波板狀的間隔 〇 '保持構件5之山或谷之長邊方向,盥立 上或其下之元件椹忐留- 丄,, 成早凡之波板狀的間隔保持構件 或谷之長邊方向,由平丄 干。之山 田十面所視,大致正交。 各區隔構件1,且古 /、有基材及添加於該基材之水溶性吸 濕劑4為區隔構件1之基材,使用可添加水溶性吸濕劑, 且可藉由後述之接著劑與間隔保持構件5互相接合者。由 抑制進行熱交換之2種氣流間的氣體交換之觀點,作為上 述基材,與其使用低透氣阻抗度(指上乂 Gurley試驗機之透 氣阻抗度,以下相同),使用透氣阻抗度為200秒程度以上 之高透氣阻抗度者較佳。使用低透氣阻抗度者時,於該低 透氣阻抗度的基材作料塞劑含浸聚乙烯料的水溶性高 分子為佳。例如將纖維素纖維(紙漿)碎解加工施以可得高 透氣阻抗度之技巧之紙作為上述基材使用時,只要含浸水 溶性吸濕劑即可得到具有理想性能之區隔構件工。 作為上述水如性吸濕劑,可使用具有潮解性之氯化鋰 等鹼金屬鹽、具有潮解性之氣化鈣等鹼土金屬鹽、藻酸或 其鹽、鹿角菜膠或甲殼素等多醣類,或者尿素等,該等以 外的物質’只要是具有水溶性及吸濕性者均可使用作為上 述水溶性吸濕劑。具有潮解性之鹼金屬鹽或鹼土金屬鹽, 較其他的吸濕劑水分吸附能力高’由於可依其添加量使全 熱交換元件20之性能急劇地變化,故特別適合作為上述水 溶性吸濕劑。 水溶性吸濕劑對上述基材之添加,可以例如調製水溶 性吸濕劑之水溶液,使基材含浸於該水溶液,於基材之單 13 2111-8977-PF;Ahddub 200900176 面或雙面“凹板㈣機等設備塗佈該水溶液而進行。 ;上述水/谷液,按照需要可添加膠合劑成分或填塞劑。 惟,依照膝合劑成分之種類,由於有因該勝合劑成分阻礙 水:性吸濕劑對基材之含浸,故於上述水溶液添加膠合劑 成分時’慎重選定其種類及添加量為佳。 、、…“構件1之厚度’雖依對該區隔構件1所要求的透 :、、’此或基材的材料強度’―般過厚則將使區隔構件1之 過薄則與間隔保持構件5之平衡不良,或因 破 、冓成早70或王熱交換元件之製造過 程破知,故以2(Μ〇—程度為佳。再者,天板構件15, 可以與區隔構件Ϊ同樣的素材製作。 另-方面,間隔保持構件5具有保水 使用具有保水性辛 作為其材枓 例,可舉紙,= 材料)。作為保水性材料之 5 ί使用纖維素纖維之織布或不 * 塗佈吸水性樹脂者等。 、布3汉或 布或不織布含浸或塗佈== …之合成纖維之織 …紙等亦由於具有若干Π:者纖維與樹脂 隔保持構件5,惟需要注意心用料間 少之點。 之保水罝會減 間隔保持構件5之厚度, 保水性或全熱交換元件 …“隔保持構件5之 又俠凡件全體之強度 使間隔保持構件5過厚, ,,較厚為佳,惟僅 取序,則與區隔構件1 而會於元件構成單元或全熱㈣4 ^度平衡不佳 形等不適。又,在火 灰&過程中發生變 …可燃物變多並不佳,由於間隔 2111-8977-pF;Ahddub 14 200900176 付偁件5之厚 保持構件5之厚度以^2:提=本之 ㈧“•"程度為佳 _内預先L::i:保::二:在_其保水性 =:Γ,處…鹽 4之胍鹽類;或續胺酸錄 以脈 化鎂等無機鹽類。 、、度酉夂銨、氯化鈣、氯 藉由將各丨個上述 著劑互相接A Η ^構件1與間隔保持構件5以接 相接合,形成1個元件構虚罝分 接 相鄰之元件構成單元相互及最上面成厂。又,於層積方向 天板構件心亦夢由接// 的元件構成單元⑻與 為片狀,間隔保持構件 由於各£隔構件】 】〇a~10f之區隔構件丨 ' 、’於各個元件構成單元 一 广構件1與間隔保持構件5 兀:構成早π 1〇3〜1〇6之間隔保持構件$與其上::株各 成早兀i〇b〜10f之區隔構件/構 單元i Of之間隔保掊椹杜ς * 及於几件構成 別形成氣流之流路ρ。 天板構件15之間的",分 ^熱交換元件2G,係於流於形成於各 下之流路P之氣流,與 _ 1之 之上之流路P… 成於形成於各個區隔構件1 交換及顯熱之交換。進行熱交換之2種氣 2潛熱之 係例如由屋外向室内曲人之空氣=方’ ’、’IL、—二人軋流)。 由凡件構成單力刚之區隔構進行熱交換之 圖 氣流係由室内向屋外排出之空氣流(二次氣-方的 1,經由元件構成單元10d之區; 再者,於 2111-8977-PF;Ahddub 15 200900176Ba has a moon-shaped partition member 1 turbidity ribs. The interval holding member 5 is alternately laminated, and the wave plate is in..., and the laminated structure is a positive alternating type. Yu Hengwang...the father changed το20, by stacking 6 yuan _ ', , 1 dry into a single π 1 0 a~1 Π f into the above-mentioned layered structure, at the top 7 a community into 70 1 〇f up into a cattle hoarding slab member 15. The corrugations of the spacer members r of the i elements/drys are spaced apart from the components on or below the spacers by a distance of 70, which is substantially orthogonal to the plane viewed from the plane.士5, in a certain component constitutes a single 2111-8977-PF; Ahddub 12 200900176 yuan wave-shaped spacer 〇 'maintenance member 5 in the long side of the mountain or valley, standing on or below the component retention - 丄,, into the shape of the wave-shaped spacer to keep the member or the long side of the valley, dry by the flat. The mountain is viewed from the ten sides of the field and is roughly orthogonal. Each of the partition members 1 and the ancient/, base material and the water-soluble moisture absorbent 4 added to the substrate are the base material of the partition member 1, and a water-soluble moisture absorbent can be added, and can be added as described later. The subsequent agent and the spacer member 5 are joined to each other. From the viewpoint of suppressing gas exchange between the two types of gas streams for heat exchange, as the substrate, a low gas permeability resistance (the same as the gas permeability resistance of the upper Gurley test machine, the same applies hereinafter) is used, and the gas permeability resistance is 200 seconds. A high gas permeability resistance above the degree is preferred. When a low gas permeability resistance is used, it is preferred that the low gas permeability resistance substrate is a water-soluble high molecular weight impregnated with a polyethylene material. For example, when a cellulose fiber (pulp) is pulverized and a paper having a high gas permeability resistance is used as the substrate, a partition member having a desired performance can be obtained by impregnating a water-soluble moisture absorbent. As the water-based moisture absorbent, an alkali metal salt such as deliquescent lithium chloride, an alkaline earth metal salt such as deliquescent vaporized calcium, alginic acid or a salt thereof, carrageenan or chitin can be used. As the water-soluble moisture absorbent, any substance other than these may be used as long as it has water solubility and hygroscopicity. The deliquescent alkali metal salt or alkaline earth metal salt has higher moisture adsorption capacity than other moisture absorbents. It is particularly suitable as the above water-soluble moisture absorption because the performance of the total heat exchange element 20 can be drastically changed depending on the amount of addition. Agent. For the addition of the water-soluble moisture absorbent to the above substrate, for example, an aqueous solution of a water-soluble moisture absorbent can be prepared, and the substrate is impregnated with the aqueous solution, and the substrate is 13 2111-8977-PF; Ahddub 200900176 or both sides. The water/cold solution may be added to the water/cold solution by adding a binder component or a plugging agent as needed. However, depending on the type of the knee component, the water is blocked by the component of the mixture: The impregnating agent is impregnated with the substrate, so it is preferable to carefully select the type and the amount of the binder when the binder component is added to the above aqueous solution. The thickness of the member 1 is required for the partition member 1 Permeability: ', or the material strength of the substrate' is too thick to make the partition member 1 too thin and the balance with the spacer member 5 is poor, or due to breakage, smashing early 70 or Wang heat exchange element Since the manufacturing process is broken, it is preferably 2 (Μ〇-degree). Further, the roof member 15 can be made of the same material as the partition member. In addition, the spacer member 5 has water retention and water retention. Xin as a material example, can lift paper , = material). As a water-retaining material, we use a woven fabric of cellulose fibers or a non-aqueous absorbent resin. The woven paper or the like of the synthetic fiber which is impregnated or coated with the cloth or the non-woven fabric is also provided with a plurality of enamel fibers and a resin spacer member 5, but it is necessary to pay attention to the point between the materials. The water retaining layer reduces the thickness of the spacer member 5, the water retaining member or the full heat exchange member. "The strength of the spacer member 5 is such that the interval holding member 5 is too thick, and thicker is preferable, but only In the order, it will be discomfort with the component member unit or the elemental unit or the total heat (4) 4^ degree balance. In addition, the change occurs in the process of the ash & the flammable material is not good, due to the interval. 2111-8977-pF; Ahddub 14 200900176 The thickness of the thickness of the holding member 5 is 2^: 提=本本(八) "•"degree is better _ within the pre-L::i: insurance:: two: in _ its water retention =: Γ, at ... salt 4 胍 salt; or reductive acid recorded inorganic salts such as pulverized magnesium. , 酉夂 ammonium, calcium chloride, and chlorine are connected to each other by a plurality of the above-mentioned agents. The member 1 and the spacer member 5 are joined to each other to form one element. The component constituent units are factory-to-one and top-of-the-line. Further, in the stacking direction, the member of the slab member is also composed of the component constituting unit (8) and the sheet-like member, and the spacer member is separated by a member 】a~10f. Element constituting unit A wide member 1 and a space maintaining member 5 兀: a spacer member constituting an interval π 1 〇 3 〜 1 〇 6 and a partition member/construction unit of the above: 株i〇b~10f The interval of i Of is guaranteed by the rhododendron * and the flow path ρ which forms a flow of air. The ", heat exchange element 2G between the top plate members 15 is connected to the air flow formed in each of the lower flow paths P, and is formed in each of the flow paths P above the _1 Component 1 exchange and sensible heat exchange. The two kinds of heat and the latent heat of the heat exchange system are, for example, air from the outside to the indoor songs = square '', 'IL, and two people are rolled. The airflow that is formed by the partitioning structure of the single-component block is the airflow that is discharged from the room to the outside of the room (the secondary gas-to-side 1, via the component forming unit 10d; further, at 2111-8977 -PF;Ahddub 15 200900176

氣流Ah與氣流A 2 ’刀別以霄線的箭頭描繪。 此之構成之全熱交換元件2 0 , i # 於:使區隔構件】盥 ,由於其特徵在 間隔保持構件5互相接人 劑,以下,參照圖2詳述該接著劑。接口之上述接著 圓2係概略表示於上述全熱交 —與其上之元件構成單元10b之接合處及早 面圖。如同圖所示,在於各元件構成單元…、肌= 構件1與間隔保持構件5 區h 之谷部R之〜, 係'藉由塗伟於間隔保持構件5 之月面側之接著齊&quot;,互相接合,元件構… 1 0 a盥元株諶氺- 凡仔構成早兀 件構成早-1〇b,係藉由塗佈於元件構成單元】n 之間隔保持構件5之山部τ之 a 合。圖1所示其他元件構成…7接著劑13互相接 門P伴括ϋ杜、 早兀10c〜10f之區隔構件i與 間保持構件5之接合, /、 留m , 層積方向相鄰之其他元件構成 兀c〜Of相互之接合,及元件構成單元…與天 件15之接合,均分別與上述同樣地進行。 上述各接著劑3、13,係對添加於區 性吸濕劑或該水溶性吸濕劑之水溶液顯示非it::水: 吕之,於未硬化之狀態下含浸於區隔構件】之水溶性吸、、县 劑不會溶解,於硬化後上述水溶性吸濕劑或該水溶性吸= 劑之水溶液不會浸人者。作為如此之接著劑之具體例^ 舉步含水作為溶劑之有機溶劑系接著劑(包含非水乳膠系 接著劑)、無溶劑系反應型接著劑、及熱熔型接著劑广、 區隔構件1與間隔保持構件5以上述接著劑3、Μ互 相接合之全熱交換元件2〇,無論在於其製造過程,在於【 2111-8977-PF;Ahddub 200900176 造後,可抑制μ 3、13轉移至間二劑由區隔構件1經由接著劑 水溶性吸濕齊卜^持t於各接著劑3、]3不含上述 造時、保營時、=各接著劑3、]3’可為例如在其裂 的上述水溶性吸用時由空氣中吸附之水分溶解微量 入者。又,於太J ,或者上述水溶性吸濕劑會微量浸 之狀態」…::書關於熱溶型接著齊丨,所謂「未硬化 於、曰〜熱溶型接著劑軟化或炼融之狀態之意思。 上述接著二:::構成之全熱交換元件2〇,由於使用 故容易對^ 區隔構件1與間隔保持構件5, 交換效率件1添加所期望量之吸濕劑以提高潛熱之 ^抑制該潛熱之交換效率經時降低。又, 劑由區隔構件1轉移至間隔保持構“ 元件上所: 熱之父換效率與先前同等程度之全熱交換 本。1水冷性吸濕劑之量’結果亦容易圖謀降低成 持構Π,’::可:卩制吸濕劑由區隔構件1轉移至間隔保 保:制於製造全熱交換元件2〇之過程,間隔 構件5八^而軟化’或起因於區隔構件1與間隔保持 - ^因吸屬而伸縮或引起強度變化而使元件構成單 結果:可使製作元件構成單元時之作用性,或元 或生產操作性、及製造全熱交換元件2Q時之作業性 又’由於間隔保持構件5具有保水性,即使於全熱交 、兀件20發生結露而上述水溶性吸濕劑溶解於結露水,由 2lll-8977-PF;Ahddub 17 200900176 於可將該結露水以間隔保持構件 換元件20之空調機或換* ,故於使用全熱交 性吸濕劑結露水血上述、:雷等之機器,可抑制溶解水溶 的不適。 。卩接觸而產生過電現象等重大 由该專理由,於令獻山 效率高者,且#用I… 件2〇容易得到潛熱的交換 ° 吏用该全熱交換元件20,容易構成可靠产古 的空調機或換氣裝置等。 筹成了罪度阿 ^ 再者,全熱交換元件20係用於空 凋機或換軋裝置等設置於 的揮散或臭氣的逸散等,使用^騎’不回有有機溶劑 熔型接著劑作Α卜+ 用無溶劑系反應型接著劑或熱 洛型接者劑作為上述接著劑3 η主 ,.. _ 3為&lt;土。使用熱熔型接著 夺,由於以炼融之埶炫# ϋ in …、π型接者技之自然冷卻之硬化 化學反應之硬化完成區隔禮杜 二 與間隔保持構件5之接 合,故無須設乾燥步驟。因 ^ 接 換元件20所需的時間或減 王熱又 〜ρ面 裂&quot;&quot;所需投入之能源,結果可 合易圖謀降低成本或減少對 J国衣楗造成的環境負荷。 可奏上述技術之效果之人# &amp; 如七人n 果之王熱父換元件20,可藉由例 如’包含:皁元製作步驟,盆俜 /、係製作複數個,以接著劑傕 區隔構件與具有保水性之間 _ ”之間隔保持構件互相接合之元件構 成早兀;及層積步驟,j:係以蛀 再 &amp;人 以接者劑使几件構成單元相互 接δ,得到層積配置複數個 兀件構成早兀之全熱交換元件 去製&amp;此時’於各個單元製作步驟及層積步驟,使 用對水溶性吸濕劑或該水溶性吸濕劑之水溶液顯示非溶解 :之接著劑。換言之,使用於未硬化之狀態下水溶性吸濕 撕溶解’於硬化後水溶性吸濕、劑或該水溶性吸濕劑; 2111-8977-PF;Ahddub 18 200900176 水办液不會浸人之接著劑。以下料該方法之各步驟。 於上述早7〇製作步驟,例如可分為第)小步驟及 小步驟。於第1小步驟,首先,將成為具有保水性之間隔 保持構件參照圖丨)之基礎之長條素材成形為波板狀^ 到長條的波板狀成形品。其次,於該波板狀成形品之^ 之山頂部塗佈未硬化接㈣3(參照圖2)。之後,使成為區 2構件U參照圖!)之基礎之長條素材(添加水溶性吸Μ 者)與上逑波板狀成形品抵接使上述未硬化接著劑硬化 此使兩者接合得到長條的元件構成單元材。 9 :第2小步驟,係將D小步驟所得之長條 ^材,裁切成既U大小,得到複數個具有以接著劑成3 區隔構^㈣隔料構件5互相接合之構成之元件構 l〇a]〇f 儿件構成早疋,成為圖1所示元件構成單元 =單元製作步驟之後進行之層積步驟,係首先, …牛構成單元之間隔保持構件5 :著劑13(參照叫其次,使在…元件構 之間隔保持構件5之波纹 成早兀 間隔保持構件5之、波纹,I 之元件構成單元之 元件構成翠元之方二二見,大致正交地選定各 之未硬化物)依序層積,: = 板構件15(參照圖η :件構成…層積天 層積方向相鄰之元件構^述未硬化接著劑硬化使 單元與天板構件15互相接合,二m面的-件構成 仔到圖1所示全熱交換元件 2111-8977-PF.Ahddub 19 200900176 再者,在於上述單元製作步驟之長條元件構成單一 製作,例如可使用圖3所示設備連續進 早兀之 隔保持構件之基礎之長條素材及成為區隔構件之美礎之S 條素材,分別預先成形成捲筒。 1 長 圖3係表示於上述單元製作步驟連續製作長條_ 成單元時所使用之設備之一例之概略圖。同圖所示机=件1構 係單面瓦愣裝置,於該單面瓦愣裝置,成為間隔保又持構1 = 5之基礎之長條素材5A預先成形為捲筒Ri,成為區隔構件 U參照圖1)之基礎之長條素材1A預先成形為捲筒r” 於設備120由捲筒L拉出之素材5A,首先送至具有一 對瓦楞報101a、l〇lb之瓦愣機m。於瓦愣基⑻,以齒 輪狀的上段輥1〇la與齒輪狀的下段輕1〇lb互相咬合旋 轉’於該等瓦愣幸昆101a、1011)互相咬合之未置依序將= 5A成形為波板狀、结果連續地製作波板狀成形品μ。 接著,板狀成形品5Β,藉由下段輥1〇lb向既定方向 輸送,在途中於該波板狀成形品5β藉由塗佈幸昆1〇3塗佈未 硬化接著们a。未硬化接著劑3a係儲存於接著劑槽1〇5, 塗佈輥⑽之周面部分浸潰於接著劑槽m。又,於塗佈 輥103之周面,有與下段輕1〇lb之齒頂部略接觸。 “藉由塗佈輥1G3向既定方向旋轉使未硬化接著劑^附 著於塗佈輕b 103之周面’進一步塗佈於波板狀成形品之 單面為使未硬化接著劑3a不致過剩附著於塗佈輕⑽之 周面’於該塗佈親103附近配置擠水輥1〇卜可藉由調整 2111-8977-PF;Ahddub 20 200900176 下段輥101b與擠水輥1〇7之間隔,調整 5B之未硬化接著劑3a之塗佈量。再、、形0口 ==用㈣型接著劑時,例如於接著劑槽咖附設加 接著ΙτΓ 該加熱器使絲型接著劑㈣成未硬化 另-方面’由捲筒r2拉出之素材1Α,藉由2個導輥 a、11 lb導向壓製輥i丨3。壓製 iniu ^ 衣祝丨13,其周面略與下 ““㈣之齒頂接觸地配置,藉由該壓製輥113使素材 ^在向Μ方向輸送的過程將該素材u壓接心皮板狀成 形品5B。 由於在波板狀成形品5B如上所述塗佈有未硬化接著 ^ 故將㈣U壓接於波板狀成形品5B後以既定的手 奴(無圖不)’例如加熱器、放射既定波長光之人工光源、 溫風之送封機、或者吹出冷風之送風機等使未硬化接 2 33硬化猎由硬化後硬化劑3(參照圖2)使波板狀成 形品5B與素材ία互相接人 έ士里 接σ。、·、α果,可連續地製作成為元 件構成早元之基礎之長條元件構成單元材m。再者,各 :報HU、1〇lb與壓製輥113,為容易調整波板狀成形品 5B之形狀,例如加溫為15吖程度以上之既定溫度。於圖 報之旋轉方向,及各素材1A、5A之搬送方向以實線 箭碩表示。 此後,藉由裁切機將元件構成單元m由其端依序裁 成既疋的大小,連續地製作成為元件構成單元 l〇a〜l〇f(參照圖υ之元件構成單元。 2111-8977-PF;Ahddub 200900176 於層積如上述製作之複數 π 換元件之層積步驟,對 牛構成早凡得到全熱交 如可使用概$ &amp; _ π、 70構成單元之接著劑塗佈,例 如Η更用概略表不於圖4之設備進行。 圖4所示設備13〇,具備:—對 未硬化接著劑13a之接著 〗2ib,储存 擠水輥125;及省略H J 配置於輥i21b附近之 传以…广 送裝置。元件構成單元1〇, 係以^構件1為上,間隔保持 — f' 搬送裝置搬送至一對輥121 ”,、,方向,藉由 „ 1q 對輕12U、12lb,在此塗佈未硬化接著 鈉13a。隔著既定間隔,對一 數個元件構成單元1(3。 tb a、叫依序搬送複 件構:二對輥121二121b之中,上側輥121a作為將元 121b之::二向既疋方向搬送之搬送觀之作用,下側報 之周面P刀浸潰於接著劑槽123,作為對元件構成單 ^塗佈未硬化接著劑13a之塗佈輥之作用。藉由们叫 向既定方向旋轉未硬化接著劑13a附著於報12化之周面, 進一步塗佈於元件構成單元1()之間隔保持構件5。掛水報 ⑶係配置於輥121b附近,去除過剩附著於輥之未 硬化接著劑13a。藉由調整輥121]3與擠水輥125之間^, 可調整對元件構成單元10之未硬化接著劑…之塗佈:。 再者,作為接著劑3(參照圖2)使用熱炫型接著劑時,例如 於接著劑槽123附設加熱器(無圖示),以該加熱器使熱溶 型接著劑溶融成未硬化接著劑1 3 a。 藉由設備130塗佈未硬化接著劑13a之各元件構成單 凡’如已說明者’以既定的方向層積,於最上面的元件 2111-8977-PF;Ahddub 22 200900176 構成早元進一步層藉妥4c 4·杜 ,層積天板構件15(參照 略圖示之手段,例如Μ以名 力熟态、放射既定波長 源、吹出溫風之送封旛、斗、土 又尤之人工先 k封機或者吹出冷風之送風機算施以栋 未硬化接著劑1 3 a硬化之廊彳h ♦ 朴 ^ , # f^ ^ ^ , 处王。藉由進行到該硬化處 理付到於層積方向相鄰之 lSr^as FI , „ λ 偁珉早兀10相互以接著劑 4)/,、、、 目3之全熱交換元件2〇(參照圖!及圖 ,#者:於單元製作步驟使用熱溶型接著劑時,亦可使 用概略^於圖5之設備14〇製作元件構成單元⑽。同 圖所不设備1 4 0係代替圖ς私- 纟代#圖3所不接著劑槽!05及擠水輕 1 07,具備:供料輥丨33,兑 系配置成與塗佈輥1 03之周面 接觸於該塗佈輥i 03之周 门w供、,Ό未硬化接著劑3a,即熔融 之熱熔型接著劑者;供給管 具係對塗佈輥103與供 料輥133之摺接區域由i上 、 万熔融之熱熔型接著劑; 及接著劑供給源(無圖示),1係 /、係將熱熔型接著劑向供給管 ^ 135送出者。除了此點,設備⑷之構成與W 3所^備 12〇之構成相同’故圖5所示構成之中與圖3所示設備共 通者,附以與圖3所使用之參照符號之參照符號省略說明。 又,於層積步驟使用熱溶型接著劑時,亦可使用概略 表示於圖6之設備150對各元件構成單元】0塗佈未硬化接 著劑…,即炫融之熱炼型接著劑。同圖所示設備15〇,且 備:一對輥14la、141b;配置於輥⑷_近對輥⑷匕之 周面供給儲存未硬化接著劑i3a之供料輥HI·於輕⑷匕 ,、供料輥143的境界區域由其上方供給熔融之熱熔型接著 2111-8977-PF/Ahddub 23 200900176 :丨::共給管145;將熱溶型接著劑送出至供給管接著劑供 …源(無圖示);及搬送裝置。 上述-對輥141a、141b之中,下侧之輥⑷a作為將 …牛構成單元10向既定方向搬送之搬送輥之作用, “lb作為對元件構成單元1〇塗佈未硬化接著劑…之冷 佈親之作用。元件構成單元1(),係以區隔構们為下,: 隔保持構件5兔μ + + ^ 午5為上之方向以搬送裝置,搬送至—對 141a、141b,在此塗佈未硬化之接著劑ua。 比 實施形態2. 亦可將在於構成全熱交換元件之各個元件溝成單元之 區隔料與間隔保持構件之接合,或元件構成單元相互之 接。’精由基材舆熱接著性樹月旨層構成間隔保持構件 構成該間隔保持構件之熱接著性樹脂層使用作為接著南!而 進行。具有如此之接合形態之全熱交換元件之全體形:, 由於可例如盘圖1祕-&gt; λ 2 不王,、、、交換元件20之全體形狀相 冋’故在此省略其圖示。 圖7係概略表示具有上述接合形態之全熱交換元件之 —例之1個元件構成單元與其上之元件構成單元之接合卢 及其附近之剖面圖。於同圖,表示元件構成單A 4〇a 於其上接合之元件構成單元働。圖7所示構成構件之中 與圖2所示構成構件共通者,附以與圖2所使用之灸昭j 號相同的參照符號,省略其說明。 〜付 各個上述元件;jr盖占留— 霉成早το 40a、40b,具有區隔構件〗 接合於該區隔構件1夕pE| 千1之間隔保持構件35,於各間隔保持構 2lll-8977-PF;Ahddub 24 200900176 材料製作之基請,及設於該基材 挪,係例如藉由::接者性樹脂I 35β。熱接著性樹脂層 等熱接乙㈣酸乙歸共聚合物(EVA) …可為= : = 一形 高門nr形成熱接著性樹脂層咖時,可容易提 成構件35之保水性。又,使用非多孔質膜或片形 ί阻tr層咖時,容易提高間隔保持構件35之透 保持ίΓ各個70件構成單元40a、4〇b之區隔構件1與間隔 35 ’係將熱接著性樹脂層作為熱溶型接著劑 :用::間隔保持構件35之谷部R的背面側互相接合,元 :::早⑦4〇a與元件構成單元_,係藉由塗佈於元件 早凡術之間隔保持構㈣之山部T之上面側之接著 ㈣互相接° °作為熱溶型接著劑作用之上述熱接著性樹 斯曰層35Β,係對添加於區隔構件1之水溶性吸濕劑或該水 命性吸濕劑之水溶液顯示非溶解性者。換言之,於未硬化 之狀態下含浸於區隔構件!之水溶性吸濕劑不會溶解,於 硬化後上述水溶性吸濕劑或該水溶性吸濕劑之水溶液不會 浸入者。 士例如使用單面瓦楞裝置製作各元件構成單元4〇a、4〇b 時’將在於該單面瓦楞裝置之瓦楞機或壓製報作為熱源使 用,可使上述熱接著性樹脂層35B熔融。一般,樹脂由於 因吸濕之伸縮小,故使熱接著性樹脂層35B較厚較可抑制 2lll-8977-PF;Ahddub 25 200900176 起因於間隔保持構株 付偁件35之伸縮之變形,可 A留_务η主._l、《 〇、押-〇士 〜文取 J扠咼裂作元件槿 早70時,或層積複數個元件椹&amp; w ^ 時之作業性。 数個7&quot;件構成早-製作全熱交換元件 八二隔構件1與間隔保持構件35採取上述之接合形態之 全熱父換元件,由於你6 貫%形態1所說明之全熱交換元件 2 0相同的理由,宏县γ #上 谷易侍到潛熱父換效率高者,且使用該全 ’’、、乂、兀件,則可容易構成可靠度高的空調機或換氣妒 ί二所:容易:縮短製造全熱交換元件所需之時間,或減 二低:月二要技入之能源,結果可容易地圖謀降低成本或 減低對周圍環境造成之環境負荷。 實施例 以下舉實施例及比較例 元件及其製造方法。 具體說明本發明之全熱交換 〈實施例1 &gt; 首先,使用於碎解加工纖維素纖維(紙漿)而得之户約 (透氣阻抗度5_秒以上之特殊加工紙含浸既:量 之水溶性吸濕劑之氯化鋰之長條物作為區隔構件素材,使 θ勺8 0 # m之白色單光澤上質紙之長條物作為間隔保持 構件之素材,藉由與圖3所示設備12〇同樣的設備製作長 條之7L件構成單元材。此時,作為使藉由瓦愣機成形間隔 保持構件之素材而得之波板狀成形品,與上述區隔構件2 素材互相接合之接著劑,使用可使用時間(open time)為數 ^程度之EVA(乙烯醋酸乙烯共聚合樹脂)系熱熔型接著 劑,將該熱熔型接著劑加溫為約15〇C,以成為熔融物 21U-8977-PF;Ahddub 26 200900176 25g/m2程度之塗佈詈妯 ^ 也皇佈上述波板狀成形品。 接著,將元件椹赤藍&amp; u 冓成早7L材裁切成既定的大 個元件構成單元,將 ^ J ^ ' 70件構成單元以可使用時間為 =rrsm(苯…乙烯-丁烯-苯乙_共聚 二=所構成之㈣型接著劑,藉由與圖4所示設 備7㈣的設備塗佈。此時,熱㈣接著劑係加溫為約 之熔融物,其塗佈量為45g/m2程度。 之後,以1個凡件構成單元之間隔保持構件之波紋盘 其上或其下之元件構成單元之間隔保持構件之波紋,由^ 面所視,大致正交地依序層積各元件構成單元,於最上面 的7G件構成單元上進一步声The air flow Ah and the air flow A 2 ' are not depicted by the arrows of the 霄 line. The total heat exchange element 20, i# of the above configuration is such that the partition member 盥 is attached to the spacer member 5 due to its characteristics. Hereinafter, the adhesive will be described in detail with reference to Fig. 2 . The above-described circle 2 of the interface is schematically shown at the junction and the front view of the above-described total heat-crossing element assembly unit 10b. As shown in the figure, the respective components constituting the unit, the muscle = the member 1 and the valley portion R of the spacer holding member 5 region h are "by the coating of the moon-side side of the spacer member 5". , inter-joining, component construction... 1 0 a 盥 谌氺 谌氺 , , , , , , , , , , , , , , , , , , , , , , a. The other components shown in Fig. 1 are composed of: 7 the adhesive 13 is connected to the door P, and the partition member i of the early 兀 10c 1010f is joined to the intermediate holding member 5, and m is left adjacent to the stacking direction. The joining of the other elements 兀c to Of to each other, and the joining of the element forming unit and the daypiece 15 are performed in the same manner as described above. Each of the above-mentioned adhesives 3 and 13 is a water-soluble solution which is added to the aqueous solution of the zonal moisture absorbent or the water-soluble moisture absorbing agent and which is not hydrated in the uncured state. Sexual absorption, the county agent will not dissolve, after the hardening, the above water-soluble moisture absorbent or the aqueous solution of the water-soluble absorption agent will not be infiltrated. Specific examples of such an adhesive agent include an organic solvent-based adhesive containing a water as a solvent (including a non-aqueous emulsion-based adhesive), a solvent-free reactive adhesive, and a hot-melt adhesive, a partition member 1 and The total heat exchange element 2〇 in which the spacer member 5 is bonded to each other by the above-mentioned adhesive 3 and ruthenium, regardless of the manufacturing process thereof, is [2111-8977-PF; after Ahddub 200900176 is manufactured, it is possible to suppress the transfer of μ 3 and 13 to the second The agent may be made by the partition member 1 via the adhesive water-soluble moisture absorption, and each of the adhesives 3, 3 may not contain the above-mentioned time, the time of the protection, and the respective adhesives 3, 3' may be, for example, The above-mentioned water-soluble absorption of the crack is dissolved by the moisture adsorbed in the air. In addition, Yu Tai J, or the above-mentioned water-soluble moisture absorbent will be in a state of micro-dipping.":: The book is about the hot-melt type, and the so-called "unhardened, 曰~ hot-dissolved adhesive softening or smelting state" In the above-mentioned second::: total heat exchange element 2, it is easy to add a desired amount of moisture absorbent to the exchange efficiency member 1 to improve latent heat due to use. ^ The exchange efficiency of suppressing the latent heat is lowered over time. Further, the agent is transferred from the partition member 1 to the spacer structure "on the component: the heat exchange efficiency is the same as the previous full heat exchange. 1 The amount of water-cooling hygroscopic agent' is also easy to reduce the formation of the structure, ':: can be: the moisture-absorbing agent is transferred from the partition member 1 to the interval guarantee: manufactured to manufacture the whole heat exchange element 2 a process in which the spacer member 5 is softened or caused by the partition member 1 and the gap-maintaining - the expansion or contraction of the member due to suction or the change in strength causes the component to constitute a single result: the action at which the component can be made into a unit, or The workability of the element or the production operability, and the production of the total heat exchange element 2Q is further because the water-repellent moisture absorbent is dissolved in the dew condensation water even if the dehydration occurs in the entire heat and the element 20 due to the water retention of the spacer member 5. , by 2lll-8977-PF; Ahddub 17 200900176, the dew condensation water can be replaced by the air conditioner or the component of the component 20 at intervals, so that the whole heat exchange moisture absorbent is used to dew the blood, the thunder, etc. The machine can suppress the discomfort of dissolved water. .卩 卩 而 产生 产生 产生 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩 卩Air conditioner or ventilator, etc. In addition, the total heat exchange element 20 is used for the dissipation of the volatilization or odor set by the empty machine or the rolling mill, etc., and is used without the organic solvent melting type. The agent is used as a buffer + a solvent-free reactive adhesive or a hot-type acceptor as the above-mentioned adhesive 3 η main, .. _ 3 is &lt; soil. The use of the hot-melt type is followed by the hardening, and the hardening of the hardening chemical reaction by the natural cooling of the 炼 埶 埶 、 、 、 、 、 、 、 与 与 与 与 与 与 与 与 与 与 与 与 与 与 与 与 与Drying step. Because of the time required to replace the component 20 or the energy required to reduce the heat, the result can be easily reduced to reduce the cost or reduce the environmental load on the country. The person who can play the effect of the above technology # &amp; If the seven people n king of the king of the hot father change the component 20, can be made by, for example, 'contains: soap making steps, pots /, the system to make a plurality of The spacer member and the member having the gap between the water retaining members and the water retaining member are configured to be joined together; and the laminating step, j: is to connect the constituent units to each other by the pick-up agent. Laminating a plurality of components to form a full heat exchange element for early processing and & at this time, in each unit fabrication step and lamination step, using a water-soluble moisture absorbent or an aqueous solution of the water-soluble moisture absorbent Dissolving: the adhesive. In other words, it is used in the uncured state, the water-soluble moisture-absorbing tear dissolves the water-soluble moisture-absorbing agent or the water-soluble moisture absorbent after curing; 2111-8977-PF; Ahddub 18 200900176 The adhesive is not immersed in the following steps. The steps of the method are as follows. The above steps can be divided into the first small step and the small step. In the first small step, first, it will become water-repellent. Interval holding member reference figure 丨) The base material is formed into a corrugated sheet to a long corrugated sheet. Next, an unhardened joint (4) 3 is applied to the top of the wave-shaped molded article (see Fig. 2). The long material (the water-soluble absorbent) which is the basis of the region 2 member U is referred to the upper wave-wave-shaped molded article, and the unhardened adhesive is hardened to bond the two to obtain a long strip. The component constitutes a unit material. 9: The second small step is to cut the long strip material obtained in the D small step into a U-size, and obtain a plurality of separators having a partitioning structure into three partitions. The component structure of the joint structure is formed as a component of the component shown in Fig. 1 = a layering step performed after the step of fabricating the unit, firstly, the spacer holding member 5 of the bovine constituent unit: The primer 13 (refer to the second embodiment, the corrugation of the spacer member 5 in the element structure is formed into the corrugation of the spacer member 5, and the component of the component unit of the I constitutes the side of the emerald element, which is substantially orthogonal. The selected uncured materials are layered in sequence, : = plate member 15 (reference Figure η: part of the composition...layered adjacent layers in the direction of the layer structure, the unhardened adhesive hardens to bond the unit to the slab member 15, and the two m-faces are formed into the full heat exchange shown in Fig. 1. Element 2111-8977-PF.Ahddub 19 200900176 Furthermore, the long element of the above-mentioned unit fabrication step constitutes a single production, and for example, the long material of the basis of the holding member can be continuously used in the apparatus shown in FIG. Each of the S materials of the partition member is formed into a roll in advance. 1 Long Fig. 3 is a schematic view showing an example of a device used for continuously producing a long_unit in the unit making step. The machine 1 is a single-face corrugating device. In the single-face corrugating device, the long material 5A which is the basis of the spacing and holding 1 = 5 is pre-formed into a reel Ri, and becomes a sectional member U. The base material 1A based on 1) is pre-formed into a roll r". The material 5A pulled out by the roll L in the apparatus 120 is first sent to a corrugator m having a pair of corrugated sheets 101a, 101b. In the corrugated base (8), the gear-shaped upper roller 1〇la and the gear-shaped lower segment are lightly twisted and twisted together to rotate each other in the same order as the 5A. In the form of a corrugated plate, the corrugated sheet molded product μ was continuously produced as a result. Then, the sheet-like molded product 5Β is conveyed in a predetermined direction by the lower roll 1〇1b, and the plate-shaped molded product 5β is applied to the wave-shaped molded product 5β by coating the unhardened one. The unhardened adhesive 3a is stored in the adhesive tank 1〇5, and the peripheral surface of the coating roll (10) is partially impregnated in the adhesive tank m. Further, on the circumferential surface of the coating roller 103, there is a slight contact with the top of the tooth which is lighter than 1 lb in the lower stage. "The coating roll 1G3 is rotated in a predetermined direction so that the uncured adhesive agent is adhered to the peripheral surface of the coating light b 103" is further applied to one side of the wave-shaped molded article so that the unhardened adhesive 3a does not excessively adhere. The water squeezing roller 1 is disposed near the coated pro-103 on the circumferential surface of the coating light (10), and can be adjusted by adjusting the interval between the lower roller 101b and the water squeezing roller 1〇7 by adjusting 2111-8977-PF; Ahddub 20 200900176 The coating amount of the unhardened adhesive 3a of 5B. Further, the shape of the 0 port == when using the (4) type adhesive, for example, the adhesive agent is added and then ΙτΓ, the heater makes the wire type adhesive (4) unhardened. - Aspect 'The material pulled out by the reel r2 is 1 Α, guided by two guide rolls a, 11 lb to the pressing roll i丨3. Pressing iniu ^ 衣祝丨13, its circumference is slightly lower than the top of the "(4) In the contact arrangement, the material u is pressed against the core sheet-like molded product 5B by the pressing roller 113 in the direction of the weir direction. Since the wave-shaped molded product 5B is coated as described above, it is not hardened. Then ^ (4) U is crimped to the corrugated sheet-shaped molded product 5B, and the given hand slave (no picture is not) 'for example, heater, radiation is set The artificial light source of the long light, the warm air sealer, or the blower that blows out the cold air, etc., the unhardened joint 2 33 hardened by the hardened hardener 3 (refer to FIG. 2) to make the wave-shaped molded product 5B and the material ία In the person's gentleman, the sigma, the y, and the y, the squirrel, the squirrel, the squirrel, the squirrel, the squirrel, the squirrel, the squirrel, the squirrel, the It is easy to adjust the shape of the wave-plate-shaped molded product 5B, for example, a predetermined temperature of about 15 Torr. The direction of rotation of the image and the direction of conveyance of the respective materials 1A and 5A are indicated by solid arrows. The cutting device divides the component constituent unit m into a size of the same by its end, and continuously manufactures the component constituent units l〇a to l〇f (refer to the component constituent unit of Fig. 2111-8977-PF; Ahddub) 200900176 In the layering step of laminating the plurality of π-changing elements produced as described above, the bovine composition is used to obtain the full heat of the bovine, such as the adhesive composition of the unit of $ &amp; _ π, 70, for example, The table is not shown in the device of Figure 4. The device shown in Figure 4 is 13〇, with: The squeezing roller 125 is stored for the uncured adhesive 13a, and the squeezing roller 125 is omitted; and the HJ is disposed in the vicinity of the roller i21b to transmit the squeezing device. The component constituting unit 1 is connected to the component 1 and is kept at intervals. f' The conveying device is conveyed to the pair of rolls 121", and the direction is applied by „1q to the light 12U and 12lb, and the uncoated yellow 13a is applied here. The unit 1 is composed of a plurality of elements at predetermined intervals ( 3. tb a, in order to transport the duplex structure: among the two pairs of rollers 121 and 121b, the upper roller 121a serves as a transfer mechanism for transferring the element 121b to: the two-way direction, and the lower side reports the circumferential surface. The P blade is immersed in the adhesive agent groove 123, and functions as a coating roller for coating the uncoated adhesive 13a. By the rotation of the unhardened adhesive 13a to the predetermined circumferential surface, it is further applied to the spacer holding member 5 of the element constituting unit 1 (). The hanging water (3) is disposed in the vicinity of the roller 121b to remove the unhardened adhesive 13a which is excessively attached to the roller. The coating of the uncured adhesive of the component constituting unit 10 can be adjusted by adjusting the gap between the roller 121]3 and the water squeezing roller 125. When a heat-sensitive adhesive is used as the adhesive 3 (see FIG. 2), for example, a heater (not shown) is attached to the adhesive tank 123, and the hot-melt adhesive is melted to be uncured by the heater. Agent 1 3 a. The components of the unhardened adhesive 13a coated by the device 130 constitute a single layer, as described, stacked in a predetermined direction, on the uppermost component 2111-8977-PF; Ahddub 22 200900176 constitutes a further layer of the early element妥4c 4·杜, laminated sky plate member 15 (refer to the means shown in the figure, for example, Μ Μ 名 名 、 、 、 、 、 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射 放射The sealing machine or the blowing fan that blows out the cold air is applied to the unhardened adhesive 1 3 a hardened gallery 朴 朴 , # f ^ ^ ^ , 处王. By the hardening treatment, it is paid in the direction of the stacking. lSr^as FI , λ λ 偁珉 兀 10 相互 相互 相互 相互 相互 相互 ) ) 相互 相互 相互 〇 〇 〇 〇 〇 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照 参照In the case of the subsequent agent, the component constituting unit (10) can also be fabricated using the apparatus 14 of Fig. 5. The same figure does not have the device 1 4 0 system instead of the ς ς - 纟 # # Figure 3 is not the adhesive groove! 05 and The water squeezing light 107 has a feeding roller 丨 33, and the matching system is disposed in contact with the circumferential surface of the coating roller 103 to the circumference of the coating roller i 03 w, , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , And the adhesive supply source (not shown), the 1 system/, the hot-melt type adhesive is sent to the supply pipe 135. In addition to this, the structure of the device (4) and the composition of the W 3 device 12 In the configuration shown in FIG. 5, which is common to the device shown in FIG. 3, the reference numerals used in the reference numerals in FIG. 3 are omitted, and the heat-soluble adhesive is used in the lamination step. It is possible to use a device 150 schematically shown in Fig. 6 for each element constituent unit to apply an unhardened adhesive agent, i.e., a hot-melt type adhesive for smelting. The device shown in the figure is 15 〇, and a pair of rollers 14la are provided. 141b; disposed on the circumferential surface of the roll (4)_near pair of rolls (4), and supplies the supply roll HI of the unhardened adhesive i3a to the light (4) 匕, and the boundary area of the supply roll 143 is supplied with molten hot melt from above. Type 2111-8977-PF/Ahddub 23 200900176 : 丨:: co-feed tube 145; send hot-melt type adhesive to the supply tube In the above-mentioned pair of rollers 141a and 141b, the lower roller (4)a functions as a conveying roller that conveys the bovine constituent unit 10 in a predetermined direction, "lb as a pair The component constituting unit 1 〇 applies the function of the cold cloth of the unhardened adhesive agent. The component constituting unit 1 () is divided into the following structures: the spacer member 5 is rabbit μ + + ^ No. 5 The direction is transported to the pair of 141a and 141b by the transfer device, and the unhardened adhesive ua is applied thereto. In contrast to the second embodiment, the spacers of the respective elements constituting the total heat exchange element may be joined to the spacer member or the element constituent units may be connected to each other. 〈Finishing the spacer by the substrate and the layer of the heat-retaining layer. The heat-adhesive resin layer constituting the spacer member is used as the south! And proceed. The overall shape of the total heat exchange element having such a joint shape is as follows: for example, the disk pattern 1 -> λ 2 is not king, and the entire shape of the exchange element 20 is opposite, so the illustration thereof is omitted here. Fig. 7 is a cross-sectional view schematically showing the joint element of the one element constituent unit of the all-heat exchange element having the above-described joint form and the element constituent unit thereon, and its vicinity. In the same figure, the component constituting unit A on which the component A 4 4a is bonded is shown. The components shown in Fig. 7 that are the same as those of the components shown in Fig. 2 are denoted by the same reference numerals as those used in Fig. 2, and the description thereof will be omitted. ~ each of the above-mentioned components; jr cover occupancy - mold into early το 40a, 40b, with a partition member 〗 〖 joined to the partition member 1 p pE| thousand 1 interval holding member 35, at each interval to maintain 2ll-8977 - PF; Ahddub 24 200900176 The basis for material preparation, and the substrate is set, for example, by: : Contact resin I 35β. The heat-adhesive resin layer or the like is thermally bonded to the ethyl (tetra) acid-based copolymer (EVA) ... which can be = : = a shape. When the high-gate nr forms a thermal adhesive resin layer, the water retention of the member 35 can be easily obtained. Further, when a non-porous film or a sheet-shaped resist layer is used, it is easy to increase the penetration retention of the spacer member 35. The partition member 1 and the spacer 35' of each of the 70 constituent units 40a, 4b are heated. The resin layer is used as a hot-melt type adhesive: the back side of the valley portion R of the spacer member 35 is joined to each other, and the element::: 74 〇a and the element constituting unit _ are coated on the component The interval between the upper and lower sides of the mountain portion T of the structure (4) is the same as that of the upper side of the mountain portion T (4). The above-mentioned thermal adhesive tree layer 35 作为 acts as a hot-melt type adhesive, and is added to the water-soluble suction added to the partition member 1. The wet agent or the aqueous solution of the water-based hygroscopic agent shows non-dissolving. In other words, it is impregnated with the partition member in an unhardened state! The water-soluble moisture absorbent does not dissolve, and the water-soluble moisture absorbent or the aqueous solution of the water-soluble moisture absorbent is not immersed after hardening. For example, when the respective component constituting units 4a, 4b are produced by using a single-face corrugating apparatus, the corrugating machine or the press of the single-face corrugating device is used as a heat source, and the thermal adhesive resin layer 35B can be melted. In general, since the resin has small expansion and contraction due to moisture absorption, the thickness of the heat-adhesive resin layer 35B can be suppressed to inhibit 2lll-8977-PF; Ahddub 25 200900176 is caused by the deformation of the stretch-retaining member 35, which can be deformed. _ η η 主 主 主 主 主 主 主 主 主 主 主 主 主 主 主 主 主 主 主 主 主 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ A plurality of 7&quot;pieces are formed early-made full heat exchange element 82 partition member 1 and spacer holding member 35 adopts the above-described joint form of the full heat father replacement element, since the full heat exchange element 2 described in the form 1 0 For the same reason, Hongxian γ #上谷易侍到潜热父换换高高, and using the full '', 乂, 兀, can easily constitute a highly reliable air conditioner or ventilation 妒 二:Easy: Shorten the time required to manufacture a full heat exchange component, or reduce the second: the energy to be used in the second month, the result can be easily reduced to reduce costs or reduce the environmental load on the surrounding environment. EXAMPLES Examples and comparative examples and methods for producing the same are given below. DETAILED DESCRIPTION OF THE INVENTION The whole heat exchange of the present invention <Example 1> First, it is used for disintegrating and processing cellulose fibers (pulp), and the special processing paper having a gas permeability of 5 sec or more is impregnated with water: The long strip of lithium chloride of the hygroscopic agent is used as the material of the partition member, and the strip of the white single-gloss upper paper of the θ scoop 80 0 m is used as the material of the spacer holding member, by the device shown in FIG. 12 〇 〇 〇 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 As a subsequent agent, an EVA (ethylene vinyl acetate copolymer resin)-based hot-melt type adhesive having an open time of several degrees is used, and the hot-melt type adhesive is heated to about 15 〇C to become a melt. 21U-8977-PF; Ahddub 26 200900176 25g/m2 coating 詈妯^ Also the above-mentioned wave-shaped plate-shaped molded article. Next, the component 椹 蓝 &&amp; u 冓 早 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 Each component constitutes a unit, and ^ J ^ ' 70 pieces constitute a unit The use time is =rrsm (benzene ... ethylene - butene - phenethyl - copolymerized two = formed by the type (4) type of adhesive, by coating with the apparatus of apparatus 7 (4) shown in Figure 4. At this time, the thermal (four) adhesive system plus The temperature of the melt is about 45 g/m 2 . Thereafter, the corrugated disk of the spacer member of the spacer member is a corrugated disk of the spacer member of the spacer member. ^ As seen from the surface, the components are layered in a substantially orthogonal manner, and further on the uppermost 7G component.

系彈性體所構成之埶熔:」 〜,使上述SEBS …、V i接者劑之熔融物硬化,得 與圖1所示全執交拖开技9nj_ 姑入也▲/、、、纟件20相肖外觀之全熱交換元件。於 ^ t…又換疋件’以與圖2所示接合形態相同的形態接合 區隔構件與間隔保持構件。 σ 〈實施例2&gt; 首先’準備碎解加工纖維素纖維(紙漿)而得之厚約 透氣阻抗度5_秒以上之特殊加工紙含浸既定量 、水浴性吸濕劑之氯化鐘之長條物作為區隔構件素材,又 準備厚約85㈣之耐水紙構成之基材之單面熱融接有以聚 件成7刀之厚約15“之膜之長條物作為間隔保持構 ,、。上述膜,作為熱接著性樹脂層作用。接著將間 ^呆持構件之素材由端依序,以瓦愣機成形為波板狀絲 -,由成形為波板狀成形品之處使用上述膜作為熱熔型接 2111-8977-PF;Ahddub 27 200900176 著劑與區隔構件之素材互 元材。 D仟到長條之元件構成單 個元^成,疋件構成單元材裁切成既定的大小得到複數 件構成單-1凡’以與實施例1同樣的條件之下將該等元 齒入層積’得到與圖1所示全熱交換元件20相同外 合奐元:。於該全熱交換元件’以與圖7所示接 …匕、目同的形態接合區隔構件與間隔保持構件。 〈比較例〉 使用厚約7—之長條難燃紙(相當於川所規定之難 =2,)作為間隔保持構件之素材q作為製作長條之元件 '早凡材時之接著劑及層積複數個元件構成單元時之接 著劑,使用於醋酸乙稀系乳膠接著劑加入調整黏度之水者 以外,以與實施例1同樣的條件下製作全熱交換元件。再 者’使製作長條元件構成單元材時之上述接著劑之塗佈量 為W/m2’層積複數個元件構成單元時之上述接著劑 佈量為29g/m\ 〈評價〉 對於實施例1、2及比較例所製作之各個全埶交換元 件,分別測定於高濕度環境下之溫度交換效率(顯熱之交換 效率)、濕度交換效率(潛熱之交換效率)、及全熱交換效率 以及於低濕度環境下之溫度交換效率、濕度交換效率、及 全熱交換效率。於高濕度環境下之各交換率效率之測定係 於遵照JIS B8628 (全熱交換器)之交換效率測定條件(夏日 條件)之條件下,又在於低濕度環境下之各交換效率之測定 2111-8977-PF;Ahddub 28 200900176 係於遵照ARI(美國空調冷凍協會)1 060 Rating υ A1埶 弹性 弹性 : : : 」 」 」 」 」 」 弹性 弹性 弹性 SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE SE Full heat exchange element with 20 phase appearance. The spacer member and the spacer member are joined in the same manner as the joint form shown in Fig. 2. σ <Example 2> First, a special processing paper having a thickness of about 5 sec or more, which is prepared by disintegrating and processing cellulose fibers (pulp), is impregnated with a chlorination clock of a quantitative, water-bathing hygroscopic agent. As a material for the partition member, a single surface of the substrate made of water-resistant paper having a thickness of about 85 (four) is further provided with a long strip of a film of about 15" thick by a piece of material as a spacer structure. The film acts as a thermal adhesive resin layer. Then, the material of the holding member is formed into a corrugated wire by a corrugating machine, and the film is formed into a corrugated molded article. As a hot-melt type 2111-8977-PF; Ahddub 27 200900176 The material of the agent and the partition member is a mutual element. The component of the D仟 to the long strip constitutes a single element, and the element is cut into a predetermined size. A plurality of constituent parts are obtained. The same external conditions are obtained as in the case of the total heat exchange element 20 shown in Fig. 1 under the same conditions as in the first embodiment: The exchange element 'joins the partition member in the same manner as shown in Fig. 7 <Comparative Example> A long-term flame retardant paper (corresponding to the difficulty of 2, which is specified by Kawasaki) is used as the material q of the spacer member as a component for making a long strip. A total heat exchange element was produced under the same conditions as in Example 1 except that the adhesive agent and the adhesive for laminating a plurality of components constitute a unit, and the use of a vinyl acetate emulsion adhesive to add a viscosity-adjusting water. When the coating amount of the above-mentioned adhesive agent for forming the long-length element is W/m2', the above-mentioned adhesive agent amount is 29 g/m\ <evaluation> for Examples 1 and 2 And the full-scale exchange elements produced in the comparative example, respectively, measure the temperature exchange efficiency (sensible heat exchange efficiency), the humidity exchange efficiency (the latent heat exchange efficiency), the total heat exchange efficiency, and the low humidity in a high humidity environment. Temperature exchange efficiency, humidity exchange efficiency, and total heat exchange efficiency in the environment. The efficiency of each exchange rate in a high humidity environment is determined by the exchange efficiency in accordance with JIS B8628 (total heat exchanger). The member (summer conditions) of the condition, and wherein each exchange efficiency was measured under the low-humidity environment 2111-8977-PF; Ahddub 28 200900176 system in accordance with the ARI (American Association of air conditioning and refrigeration) 1 060 Rating υ A1

Energy Recovery ventiiati〇n Equipment(通風設備氣對 氣能量回收指標)之交換效率測定條件(冷氣條件)之條件 下,分別以遵照JIS B8628(全熱交換器)之方法進 J 〇將 該等之測定結果以清單示於圖8。 时團δ明顯可知,在於高濕度環境下的溫度交換致率 及濕度交換效率以及在於低温環境下之溫度交換效率,每 施例1、2之各全熱交換元件與比較例之全熱交換元件大2 相等,惟在於低濕度環境下之濕度交換效率,實施例1、大 之各全熱交換元件大幅地較比較例之全熱交換元件高。 可認為係由於相對於比較例之全熱交換元件,水溶 劑(氯化鋰)由區隔構件轉移至間隔保持構件於元件 ~ 過程及製造後均有發生,而實施例卜2之各全熱4造 件,於τΜ牛之製造過程及製造後均幾乎沒有發生水溶、疋 濕劑(氯化經)由區隔構件轉移至間隔保持 =吸 卜2之各全熱交換元件,幾乎沒有發生上…、霄施例 之轉移之結果,特別水溶性吸濕、劑 特別疋改善了在於低濕度環境Energy recovery ventiiati〇n Equipment (air-conditioning gas energy recovery index) exchange efficiency measurement conditions (air-conditioning conditions), respectively, in accordance with JIS B8628 (total heat exchanger) method J 〇 these measurements The results are shown in Figure 8 in the list. The time group δ is clearly known as the temperature exchange rate and humidity exchange efficiency in a high humidity environment and the temperature exchange efficiency in a low temperature environment, and the total heat exchange elements of each of the examples 1 and 2 and the total heat exchange element of the comparative example. The large 2 is equal, but in the humidity exchange efficiency in a low humidity environment, the total heat exchange elements of the first embodiment and the larger ones are substantially higher than the total heat exchange elements of the comparative example. It can be considered that since the water solvent (lithium chloride) is transferred from the partition member to the spacer member in the component-process and after the manufacture with respect to the total heat exchange element of the comparative example, the total heat of the embodiment 2 4 Ingredients, almost no water-soluble, hygroscopic agent (chlorinated warp) was transferred from the partition member to the interval-maintaining = all-heat exchange element in the manufacturing process and after manufacture of the τ yak cattle, almost no occurrence occurred. ..., the result of the transfer of the application, especially the water-soluble moisture absorption, the special agent improved in the low humidity environment

附特性,可推測因此而增加了濕度。 H :上,舉實施例說明關於本發明之熱交換元件 ' 關於熱交換換氣裝置之實施形態,惟本笋明 限疋於上述形態者。例如,未硬化 X亚非 佈輥進行之外,介叮 &gt; 疋塗佈,使用塗 亦可依照其材質以喷灑塗 又,間隔保持構件只要是可將2抑5寺方法進行。 的間隔者即可,# , &quot;隔構件保持既定 亦可使用彎曲為矩形波狀或三角波狀: 2111-8977-PF;Ahddub Δ 9 200900176 片,或將複數枚板月等作為間p ^ J ί网保持構件使用。然後,關 於各個元件構成單元或全埶交- …又換π件之全體形狀,亦可按 照對所欲製造之全熱交換元件 1于之用途或對該全熱交換元件 所求之性能等適宜選定。關^Λ , 今、且您疋關於本發明之全熱交換元件及其 製造方法’於上述形態以外可右夂 J有各種變形、修飾、組合等。 [產業上的可利性] 本發明,只要是用於靜止形之熱交換器之全熱交換元 件:任何形態均可使用,可使用於建築物或車輛、船舶等 進行空調或換氣之各種裝置。 圖 圖式簡單說明】 圖1係概略表示本發明之全熱交換元件 之一例之立體 …圖2係概略表示圖1所示全熱交換元件之!個元件構 附近之剖面 成早凡與其上之元件構成單,元之接合處及其 圖。 :3係表示在於本發明之全熱交換元件之製造方法之 单兀I作步驟’連續製作長 ^ 卜贲怿之70件構成早兀材時所使用 之°又備之一例之概略圖。 圖4係表示在於本發明之全熱交換元件之 :積二驟’對各元件構成單元塗佈接著劑時所使用之設備 之一例之概略圖。 之製造方法之 圖5係表示在於本發明之全熱交換元件 2111-8977-PF;Ahddub 200900176 早,製作步,使用熱熔型接著劑連續製#長條之元件構 成單元材時所使用之設備之一例之概略圖。 圖6係表不在於本發明之全熱交換元件之製造方法 層積步驟,對各开杜播士 ί各凡件構成早凡塗佈熱熔型接著 之設備之一例之概略圓。 于所使用 圖7係概略表示本發明之全熱交換元件 成間隔保持構件之熱接著性樹脂層作為接著劑^用構 保持構件與區_件互 _ I亥間隔 ,-&amp; « 较考之】個70件構成i i 凡件構成單元之接合處及其附近之剖面圖。、其上之 圖8係表示各個實施例卜2及比較 換元件,分別在於高濕度環境下及低濕度^作之全熱交 度父換效率、濕度交換效率、 =兄下’測定溫 表。 …、又換致率之結果之圖 【主要元件符號說明】 1〜區隔構件; 3〜接著劑; 5、3 5〜間隔保持構件; 10、l〇a~l〇f〜元件構成單元,· 13〜接著劑; 2 0〜全熱交換元件; 3 5 A ~間隔保持構件之基材. 35B〜熱接著性樹脂層。 2111-8977-PF;Ahddub 31With the characteristics, it can be speculated that the humidity is increased. H: The embodiment of the present invention relates to a heat exchange element of the present invention. The embodiment of the heat exchange ventilator is limited to the above. For example, in the case of an unhardened X-Asian cloth roll, the coating may be applied by spraying, and the coating may be spray-coated according to the material thereof, and the spacer member may be carried out as long as it can be carried out. The spacer can be, # , &quot; spacers can be used to bend or rectangular wave or triangle wave: 2111-8977-PF; Ahddub Δ 9 200900176, or multiple boards, etc. as inter-p ^ J The ί network keeps the components in use. Then, regarding the overall shape of each component constituting unit or the 埶-- and π-piece, the shape of the total heat exchange element 1 to be manufactured or the performance of the total heat exchange element may be suitable. Selected. The present invention relates to the total heat exchange element of the present invention and the method of manufacturing the same, which can be modified, modified, combined, and the like in addition to the above-described embodiments. [Industrial Applicability] The present invention can be used in any form as long as it is a total heat exchange element for a heat exchanger of a stationary type, and can be used for air conditioning or ventilation of buildings, vehicles, ships, and the like. Device. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing an example of a full heat exchange element of the present invention. Fig. 2 is a schematic view showing the total heat exchange element shown in Fig. 1! The section near the component structure is formed into a single, a joint of the element and its figure. The term "3" is a schematic view showing an example of the method of manufacturing the total heat exchange element of the present invention, which is used in the step of "continuously producing a length of 70 pieces of the material". Fig. 4 is a schematic view showing an example of an apparatus used for applying an adhesive to each element constituent unit in the total heat exchange element of the present invention. Figure 5 is a diagram showing the apparatus used in the whole heat exchange element 2111-8977-PF of the present invention; Ahddub 200900176, the production step, using the hot-melt type adhesive to continuously manufacture the elements of the strip; An overview of one example. Fig. 6 is a view showing a lamination step of the method of manufacturing the total heat exchange element of the present invention, which constitutes a schematic circle of an example of a device which is coated with a hot-melt type. Fig. 7 is a schematic view showing that the heat-exchangeable resin layer of the total heat exchange element of the present invention as the spacer member is used as the adhesive member and the spacer member is separated from each other, -&amp; « A 70-section ii is a cross-sectional view of the joint of the unit and its vicinity. Fig. 8 shows the various embodiments and comparison components in the high humidity environment and the low humidity, the total heat exchange efficiency, the humidity exchange efficiency, and the lower temperature measurement. ..., the result of the change rate [main component symbol description] 1 ~ partition member; 3 ~ adhesive; 5, 3 5 ~ spacing holding member; 10, l〇a ~ l〇f ~ component building unit, 13~Binder; 2 0~ total heat exchange element; 3 5 A ~ substrate of spacer member. 35B~ thermal adhesive resin layer. 2111-8977-PF; Ahddub 31

Claims (1)

200900176 十、申晴專利範圍: I —種全熱交換元件,具有: 將添加水溶性吸濕劑之片狀;及 -起:成氣:之::接著劑與區隔構件接合與該區隔構件 其f間隔保持構件,交互層積, 上述間隔保持構件具有保水性; 上述接著劑,對於上述太 边水/合性吸濕劑或該水溶性吸濕 知】之水’谷液顯示非溶解性。 ’、 :申請專利範圍第丨項所述的全熱交換元件,其中 上述接著劑係有機溶劑系接荖 „ Μ系獲者劑、無溶劑系反應型接著 劑、或熱熔型接著劑。 # 、、3.如申請專利範圍第1項所述的全熱交換元件,其中 上述區隔構件,包合.合、'君μ、+、 . 上述水溶性吸濕劑之保水性材 料。 刊 添加水 2111-8977-PF;Ahddub 32 200900176 接著劑與區隔構件 之間隔保持構件, 溶性吸濕劑之H &amp; 剮之月狀之區隔構件,及藉由 接合與該區隔構件一 _ 1干起形成氣流之流路 父互層積之層積構造者, 其特徵在於包含: 以接著劑使上述區 搞保持構件互相接 _早70製作步驟,其係製作複數個, 隔構件與藉由保水性材料形成之上述間 合之元件構成單元;及 件構成單元相互接 單元之全熱交換元 層積步驟,其係以接著劑使上述元 合,得到層積配置複數個上述元 件, 各们用於上述單元製作步驟之上述接著劑及用 層積步驟之上述接荖;^丨 :上述 m 對上述水溶性吸濕劑或該水溶性 二、蜊之水溶液顯示非溶解性。 專利範圍第6項所述的全熱交換元件之製造 於i过用於上述單元製作步驟之上述接著劑及用 =述層積步驟之上述接著劑,係有機溶 溶劑系反應型接著劑、或熱溶型接著劑。 8·如中請專利範圍第6項所述的全熱交換元件之製造 方法,其中上述區隔構件,包含.人* 之保水性材料。 .水溶性吸濕劑 9.如申凊專利範圍第6項所述的全熱交換元件之製造 方法,其中上述間隔保持構件具有:包含保水性材料之基 材’及設於該基材之單面之熱接著性樹脂層, 上述熱接著性樹脂層,係用於作為上述單元製作步驟 2111-8977-PF;Ahddub 33 200900176 .之上述接著劑。 1 〇.如申請專利範圍第6項所述的全熱交換元件之製 造方法,其中上述水溶性吸濕劑,係具有潮解性的驗金屬 鹽或驗土金屬鹽。 2111-8977~PF/Ahddub 34200900176 X. Shen Qing Patent Range: I - a type of total heat exchange element, having: a sheet of water-soluble moisture absorbent added; and - from: gas::: the bonding agent and the partition member are joined to the partition The member has an interval-retaining member, which is alternately laminated, and the spacer member has water retention property; and the adhesive agent is insoluble for the water-cold liquid of the tarpaulin water/hygroscopic absorbent or the water-soluble moisture absorption Sex. The total heat exchange element according to the above-mentioned claim, wherein the above-mentioned adhesive is an organic solvent-based adhesive, a solvent-free reactive adhesive, or a hot-melt adhesive. 3. The total heat exchange element according to claim 1, wherein the partition member comprises a combination of a water-repellent material of a water-soluble moisture absorbent. Water 2111-8977-PF; Ahddub 32 200900176 The spacing member of the spacer and the partition member, the H &amp; 剐 月 区 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔 隔A laminated structure for forming a flow path of a parent flow layer forming a gas flow, comprising: bonding the holding members of the above-mentioned regions with an adhesive to each other to form a plurality of steps, the plurality of partition members and the water retaining member The above-mentioned inter-component component forming unit formed by the material; and the total heat exchange element laminating step of the component forming unit interconnecting unit, wherein the element is combined by an adhesive to obtain a plurality of the above-mentioned components in a layered arrangement, The above-mentioned adhesive agent in the above-mentioned unit production step and the above-mentioned bonding step in the laminating step; ^: The above m shows insolubleness to the water-soluble moisture absorbent or the water-soluble aqueous solution of cerium and lanthanum. Patent No. 6 The total heat exchange element is manufactured by using the above-mentioned adhesive agent used in the above-described unit production step and the above-mentioned adhesive agent in the step of laminating, which is an organic solvent-based reactive adhesive or a hot-melt adhesive. 8. The method for manufacturing a total heat exchange element according to the sixth aspect of the invention, wherein the partition member comprises a water retaining material of a person*. A water-soluble moisture absorbent 9. The method for producing a total heat exchange element according to the item 6, wherein the spacer member comprises: a substrate comprising a water retentive material; and a thermal adhesive resin layer provided on one side of the substrate, the thermal adhesive resin The layer is used as the above-mentioned unit manufacturing step 2111-8977-PF; Ahddub 33 200900176. The above-mentioned adhesive agent. The manufacturing method of the full heat exchange element according to claim 6, wherein Soluble moisture-absorbing agent, a test based deliquescent metal salt or earth metal test. 2111-8977 ~ PF / Ahddub 34
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