TWI308560B - Refractory materials - Google Patents
Refractory materials Download PDFInfo
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- TWI308560B TWI308560B TW094147463A TW94147463A TWI308560B TW I308560 B TWI308560 B TW I308560B TW 094147463 A TW094147463 A TW 094147463A TW 94147463 A TW94147463 A TW 94147463A TW I308560 B TWI308560 B TW I308560B
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- 239000011819 refractory material Substances 0.000 title claims description 78
- 239000000463 material Substances 0.000 claims description 160
- 239000011521 glass Substances 0.000 claims description 155
- 229910052845 zircon Inorganic materials 0.000 claims description 94
- 238000012360 testing method Methods 0.000 claims description 79
- 238000000034 method Methods 0.000 claims description 71
- 239000013078 crystal Substances 0.000 claims description 53
- 238000000354 decomposition reaction Methods 0.000 claims description 50
- -1 Tb2〇3 Inorganic materials 0.000 claims description 46
- 239000000203 mixture Substances 0.000 claims description 42
- 238000004519 manufacturing process Methods 0.000 claims description 41
- 230000008569 process Effects 0.000 claims description 40
- 229910000164 yttrium(III) phosphate Inorganic materials 0.000 claims description 30
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 23
- 230000015572 biosynthetic process Effects 0.000 claims description 23
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims description 20
- 230000007547 defect Effects 0.000 claims description 18
- 239000002241 glass-ceramic Substances 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 18
- 238000007499 fusion processing Methods 0.000 claims description 15
- 239000006060 molten glass Substances 0.000 claims description 15
- WAKZZMMCDILMEF-UHFFFAOYSA-H barium(2+);diphosphate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O WAKZZMMCDILMEF-UHFFFAOYSA-H 0.000 claims description 14
- FNCNHALJTRAHOC-UHFFFAOYSA-N [PH4+].[PH4+].[PH4+].[O-]P([O-])([O-])=O Chemical compound [PH4+].[PH4+].[PH4+].[O-]P([O-])([O-])=O FNCNHALJTRAHOC-UHFFFAOYSA-N 0.000 claims description 13
- 229910000167 hafnon Inorganic materials 0.000 claims description 13
- 230000004927 fusion Effects 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 238000005452 bending Methods 0.000 claims description 9
- 230000009970 fire resistant effect Effects 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 8
- 241000282320 Panthera leo Species 0.000 claims description 7
- 238000003280 down draw process Methods 0.000 claims description 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 244000144730 Amygdalus persica Species 0.000 claims description 3
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims description 2
- 239000004575 stone Substances 0.000 description 114
- 239000000523 sample Substances 0.000 description 112
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 79
- 229910052902 vermiculite Inorganic materials 0.000 description 62
- 239000010455 vermiculite Substances 0.000 description 62
- 235000019354 vermiculite Nutrition 0.000 description 62
- 150000003839 salts Chemical class 0.000 description 46
- 238000006243 chemical reaction Methods 0.000 description 45
- 239000002253 acid Substances 0.000 description 36
- 239000000843 powder Substances 0.000 description 28
- 239000012925 reference material Substances 0.000 description 27
- UXBZSSBXGPYSIL-UHFFFAOYSA-K yttrium(iii) phosphate Chemical group [Y+3].[O-]P([O-])([O-])=O UXBZSSBXGPYSIL-UHFFFAOYSA-K 0.000 description 27
- 239000002245 particle Substances 0.000 description 24
- JOPDZQBPOWAEHC-UHFFFAOYSA-H tristrontium;diphosphate Chemical compound [Sr+2].[Sr+2].[Sr+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JOPDZQBPOWAEHC-UHFFFAOYSA-H 0.000 description 22
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- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 14
- 238000000462 isostatic pressing Methods 0.000 description 14
- 230000008859 change Effects 0.000 description 13
- KHKSXAYMYFVLBL-UHFFFAOYSA-N tris(phosphanyl) phosphate Chemical compound POP(=O)(OP)OP KHKSXAYMYFVLBL-UHFFFAOYSA-N 0.000 description 13
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- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 10
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- 238000004458 analytical method Methods 0.000 description 9
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 9
- 238000010587 phase diagram Methods 0.000 description 9
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- 238000002360 preparation method Methods 0.000 description 9
- 239000011435 rock Substances 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 239000002585 base Substances 0.000 description 8
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- 229910000166 zirconium phosphate Inorganic materials 0.000 description 7
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
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- 159000000008 strontium salts Chemical class 0.000 description 6
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- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical group OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 5
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical group [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 5
- 229910052727 yttrium Inorganic materials 0.000 description 5
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- 238000004364 calculation method Methods 0.000 description 4
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- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 4
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- QQZMWMKOWKGPQY-UHFFFAOYSA-N cerium(3+);trinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O QQZMWMKOWKGPQY-UHFFFAOYSA-N 0.000 description 3
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- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 3
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/447—Phosphates or phosphites, e.g. orthophosphate or hypophosphite
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- C04B2235/602—Making the green bodies or pre-forms by moulding
- C04B2235/6021—Extrusion moulding
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- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
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- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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- C04B2235/74—Physical characteristics
- C04B2235/76—Crystal structural characteristics, e.g. symmetry
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
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- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9669—Resistance against chemicals, e.g. against molten glass or molten salts
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Glass Compositions (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
Applications Claiming Priority (1)
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| US64068604P | 2004-12-30 | 2004-12-30 |
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| CN (2) | CN101094816B (enExample) |
| TW (1) | TWI308560B (enExample) |
| WO (1) | WO2006073841A1 (enExample) |
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-
2005
- 2005-12-21 US US11/922,580 patent/US8067326B2/en not_active Expired - Fee Related
- 2005-12-21 EP EP15151131.8A patent/EP2865655B1/en not_active Ceased
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- 2005-12-21 JP JP2007549484A patent/JP5173434B2/ja not_active Expired - Fee Related
- 2005-12-21 EP EP05855075.7A patent/EP1838633B1/en not_active Ceased
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2011
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2015
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Also Published As
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|---|---|
| WO2006073841A9 (en) | 2006-10-12 |
| USRE46072E1 (en) | 2016-07-19 |
| WO2006073841A1 (en) | 2006-07-13 |
| CN102584259B (zh) | 2014-06-18 |
| EP1838633A1 (en) | 2007-10-03 |
| CN101094816A (zh) | 2007-12-26 |
| US20120125048A1 (en) | 2012-05-24 |
| US8383537B2 (en) | 2013-02-26 |
| EP1838633B1 (en) | 2017-05-24 |
| EP2865655A1 (en) | 2015-04-29 |
| US8067326B2 (en) | 2011-11-29 |
| JP2008526671A (ja) | 2008-07-24 |
| EP2865655B1 (en) | 2017-07-26 |
| KR20070112119A (ko) | 2007-11-22 |
| CN102584259A (zh) | 2012-07-18 |
| JP5173434B2 (ja) | 2013-04-03 |
| US20090131241A1 (en) | 2009-05-21 |
| CN101094816B (zh) | 2012-02-29 |
| EP1838633A4 (en) | 2013-11-06 |
| TW200700348A (en) | 2007-01-01 |
| KR101232591B1 (ko) | 2013-02-12 |
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