TWI303300B - Heat exchange apparatus - Google Patents

Heat exchange apparatus Download PDF

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Publication number
TWI303300B
TWI303300B TW095108112A TW95108112A TWI303300B TW I303300 B TWI303300 B TW I303300B TW 095108112 A TW095108112 A TW 095108112A TW 95108112 A TW95108112 A TW 95108112A TW I303300 B TWI303300 B TW I303300B
Authority
TW
Taiwan
Prior art keywords
heat exchange
medium
heat
target
tube
Prior art date
Application number
TW095108112A
Other languages
Chinese (zh)
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TW200637993A (en
Inventor
Koda Mitsuo
Kawaharazaki Yoshinori
Owaki Yasushi
Original Assignee
Japan Steel Works Ltd
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Publication of TW200637993A publication Critical patent/TW200637993A/en
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Publication of TWI303300B publication Critical patent/TWI303300B/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/06Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with the heat-exchange conduits forming part of, or being attached to, the tank containing the body of fluid
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00Use of gas-solvents or gas-sorbents in vessels
    • F17C11/005Use of gas-solvents or gas-sorbents in vessels for hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/02Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled
    • F28D7/024Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled the conduits of only one medium being helically coiled tubes, the coils having a cylindrical configuration
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/10Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically
    • F28D7/106Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically consisting of two coaxial conduits or modules of two coaxial conduits
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D2021/0019Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
    • F28D2021/0047Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for hydrogen or other compressed gas storage tanks
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P90/00Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
    • Y02P90/45Hydrogen technologies in production processes

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Sorption Type Refrigeration Machines (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Description

: I 九、發明說明: 【發明所屬之技術領域】 本發明係關於一種熱交換裝置, 個其中容納有氫氣儲存合金:t二用於有效冷卻或加熱-【先前技術】 儲存容器。 虱氣儲存合金具有一項特點, 產生熱量,因此,除非熱量藉由一二“兔氣被吸收時, 無法繼續氫氣吸收作用,而且,气:方法加以移除’否貝1 受到熱移除速度的影響。關於;細 未具有使水等媒介從中通過的 下稱為仙壓力容器),則採用一種=:儲:容;(以 MH颅I ~部方法,用以透過 i力谷為的表面層之表面產生冷卻。 由於透過表面層表面的冷卻方法通常會採用以下的方 /將MU壓力容器的表面直接浸泡在空氣、水等的流體 内之方法;將流體吹送至MH壓力容器表面之方法;或是, 透過一冷卻夾套或類似物以實施冷卻的方法,其中之冷卻 夾套是由符合MH壓力容器形狀的金屬或類似物所形成7且 可供一媒介通過。 圖4是顯示一個使用媒介槽的直接冷卻裝置之範例。 媒介缸1 〇具有一個供液體媒介用的進入口 1 1,以及一 個供液體媒介用的排放口〗2,且,此兩部位係透過一媒 介官13而連接到一媒介槽〗5。泵1 6是設置在介於媒介 槽15與媒介管〗3中的進入口 π之間。上述的結構能使 液體媒介20在媒介槽15與媒介缸10之間產生循環。媒 3Ι2ΧΡ/發明說明書(補件)/95·〇6/951〇8】12 6 1303300 力容器的表面與冷卻夾办 會導致氫氣充填時 元全緊密的接觸,如此 螺絲等物加以固定:=而且’冷卻夹套可以藉由--項問題,不:二=加黏著程度。然而,如此又產生 驟的數目。 兀王取/肖空氣層’同時還增加工作步 【發明内容】 的SIC解決上述先前技術的問題,且其目 ^ …、種適用於一冷卻裝置的熱交換壯罟 二 改變央套的結構與 =、、衣,可藉由 染迎屡力容器的表面⑼風氣充填時間,且不會污 因此,根據本發明第一型態, 含一熱交換部,此熱交換部 ^^置,包 或圓筒狀熱交換目標的—外圍表置面成:用中=-圓柱狀 :包含-用以使熱媒介從中通過的中空空間,當 根據本發明第二型態,熱交換部 圍側^ 便捲繞在熱交換目標的外圍表面周圍。底為1狀’以 根據本發明第三型態,熱交換部係設 以便圍繞在熱交換目標的外圍表面周圍。 ®同狀, ^據本發明第四型態,熱交換目標係設計成外圍㈣ 根據本發明第五型態,一用以支撐熱交 體,係設置在熱交換部的外圍侧邊。 、"的圓同殼 根據本發明第六型態,熱交換目標是一氫氣儲存/排出 9 312ΧΡ/發明說明書(補件)/95-06/95108112 1303300 谷态’其中容納有氫氣儲存合金。 的冰St“戒父換部係設置成為用以圍繞熱交換目標 六 、面,且,熱媒介係引入到其中空空間内,致使熱 ^、部產生膨騰,且,熱交換部能夠與熱交換目標的外圍 ::產生緊密接觸,藉此,可大幅增進熱交換效率。例如, ^使用冷部媒介作為熱媒介,熱交換目標可以透過熱交 二I5有j地又到冷部。而且,藉由使用加熱媒介作為熱媒 春:| :熱交換目標可以透過熱交換部而有效地受到加熱。可 、藉由個如泵或類似物的供應裝置,執行將埶媒介引 ,交換部内:熱媒介是藉由供應裝置而連續 奐卩+且、纟工過熱父換的熱媒介是從熱交換部而連續地 排出,藉此,熱交換目標能夠連續地受到熱交換。 由於熱父換部是選擇一種在熱媒介的壓力下具有撓性 ^勺材貝,所以,具有撓性的材質可以使用作為整個熱交換 部,或者,僅作為熱交換部的内圍側邊。在本發明中,具 籲有撓性的材質並未侷限於特定的一種材質而已,也可以使 用樹脂或塗有樹脂的橡膠。 而+且,只有熱交換部係設置成圍繞熱交換目標的外圍表 面日才才足夠,且例如,可藉由將熱交換部設計成一管狀形 式,使得熱交換部係設置成能夠螺旋式地捲繞在熱交換目 払的外圍表面,或者,藉由將熱交換部設計成一圓筒狀, 致使它能牢牢裝配至熱交換目標。 而且,藉由引入到中空空間的熱媒介之壓力,使得熱交 換部能夠朝向内圍側邊膨脹,藉此,熱交換部能有效地與 312ΧΡ/發明說明書(補件)/95-06/95108112 10 1303300 • , 熱交換目標產生緊密接觸,以增進熱傳效率。於是 ί 熱交換目標的配置方式’寺量到膨脹程度:埶 …除或壓力減弱時,最的 是可以拆卸下來的,如此-來,在熱交=:::: 可以根據貫際情形的需要,鬆開熱交 間的配置。 ”,、又換目裇之 因此,最好是,熱交換部係設置在— ,稍微大於熱交換目標的外徑。為了峰;孰=到系 祕而與熱交換目標產生緊密接觸,最好是,敎交換 的形狀係設定成一圓筒或圓柱,且, = 可導致盘換部膨服到内圍側邊, 標的表面產生平坦的緊密接 拖L 外’空氣很容易能夠從熱交換部與執交 …來,藉此,達成-個^ 仁具有極佳黏者性的冷卻夾套。 二丄-個用於支禮熱交換部的圓筒殼體,可以設置在 =㈣外圍側邊。當熱交換部藉由熱 =側邊膨服時’圓筒殼體係用以限制有關的膨服,! 密接=換部朝向内圍侧邊膨服’並與熱交換目標直接緊 需要的話’熱交換目標是與外界產生熱交換(冷 :或力η口熱)’且可以應用至許多不同的領域上。然而,本 杳明取好是應用至氫氣儲存合金容器,此種容器可根據敎 312ΧΡ/發明說明書(補件)/95-〇6/95108112 11 1303300IX. EMBODIMENT DESCRIPTION OF THE INVENTION [Technical Field] The present invention relates to a heat exchange apparatus in which a hydrogen storage alloy is contained: t2 for effective cooling or heating-[Prior Art] storage container. Helium storage alloys have a characteristic that generates heat. Therefore, unless the heat is absorbed by one or two "rabbit gas, the hydrogen absorption cannot be continued, and the gas: method is removed." The influence of the fine; the fine does not have the medium such as water passing through it, called the sacral pressure vessel), then adopts a =: storage: capacity; (using the MH cranial I ~ part method, used to penetrate the surface of the i-grain The surface of the layer is cooled. The method of cooling through the surface of the surface layer usually adopts the following method: directly immersing the surface of the MU pressure vessel in a fluid such as air, water, etc.; method of blowing the fluid to the surface of the MH pressure vessel Or, by means of a cooling jacket or the like for carrying out cooling, wherein the cooling jacket is formed of metal or the like conforming to the shape of the MH pressure vessel 7 and is available for passage through a medium. Fig. 4 shows a An example of a direct cooling device using a media tank. The media cylinder 1 has an inlet port 1 for liquid medium and a discharge port 2 for liquid medium, and the two It is connected to a medium tank by a medium officer 13. The pump 16 is disposed between the medium tank 15 and the inlet port π in the medium tube 3. The above structure enables the liquid medium 20 to be in the medium tank. 15 Circulation occurs between the medium cylinder 10 and the medium cylinder 10. The medium 3Ι2ΧΡ/invention specification (supplement)/95·〇6/951〇8] 12 6 1303300 The surface of the force vessel and the cooling clamp will cause full close contact with the hydrogen filling. , such screws and other things are fixed: = and 'cooling jacket can be used by --- problem, no: two = plus adhesion degree. However, this produces a number of sudden. 兀王取 / 肖空气层' also increases The SIC of the working step [invention] solves the problems of the prior art described above, and the object thereof is applicable to the heat exchange of a cooling device, and the structure of the central sleeve and the clothing, can be changed by dyeing The surface of the force container (9) is filled with air and is not contaminated. Therefore, according to the first aspect of the present invention, the heat exchange portion, the heat exchange portion, the package or the cylindrical heat exchange target - the peripheral surface Face into: use medium = - cylindrical: contains - used to make the heat medium In the hollow space passing therethrough, when according to the second aspect of the present invention, the heat exchange portion is wound around the peripheral surface of the heat exchange target. The bottom is 1 'to the third type according to the present invention, the heat exchange portion Coupling so as to surround the peripheral surface of the heat exchange target. The same shape, according to the fourth mode of the present invention, the heat exchange target is designed as a periphery (4) according to the fifth aspect of the present invention, one for supporting the heat exchange body, The system is disposed on the outer side of the heat exchange portion. The circular shell of the " according to the sixth aspect of the present invention, the heat exchange target is a hydrogen storage/discharge 9 312 ΧΡ / invention specification (supplement) / 95-06/95108112 1303300 The valley state 'which contains the hydrogen storage alloy. The ice St "the father's replacement system is set to surround the heat exchange target six, the surface, and the heat medium is introduced into the hollow space, resulting in the generation of heat The entanglement, and the heat exchange portion can be brought into close contact with the periphery of the heat exchange target: whereby the heat exchange efficiency can be greatly improved. For example, ^ using the cold medium as the heat medium, the heat exchange target can pass through the hot cross two I5 and then go to the cold part. Further, by using a heating medium as a heat medium, spring:| : The heat exchange target can be efficiently heated by the heat exchange portion. The medium can be introduced by a supply device such as a pump or the like, and the heat medium is continuously supplied by the supply device, and the heat medium exchanged by the superheated father is replaced by the heat exchange unit. The discharge is continuously performed, whereby the heat exchange target can be continuously subjected to heat exchange. Since the hot-female change portion is a material having a flexible material under the pressure of the heat medium, the material having flexibility can be used as the entire heat exchange portion or only as the inner side of the heat exchange portion. In the present invention, the material which is flexible is not limited to a specific one, and a resin or a resin-coated rubber may be used. And +, only the heat exchange portion is set to surround the peripheral surface of the heat exchange target, and for example, the heat exchange portion can be designed to be spirally wound by designing the heat exchange portion into a tubular form. Wrap around the peripheral surface of the heat exchange target, or, by designing the heat exchange portion into a cylindrical shape, so that it can be firmly assembled to the heat exchange target. Moreover, by the pressure of the heat medium introduced into the hollow space, the heat exchange portion can be expanded toward the side of the inner circumference, whereby the heat exchange portion can effectively cooperate with the 312 ΧΡ / invention specification (supplement) / 95-06 / 95108112 10 1303300 • , Heat exchange targets produce close contact to improve heat transfer efficiency. Then ί heat exchange target configuration way 'the temple amount to the degree of expansion: 埶 ... except when the pressure is weakened, the most can be dismantled, so - come, in the hot intersection =:::: can be based on the needs of the situation , loosen the configuration of the hot junction. Therefore, it is better to change the heat exchange department to - slightly larger than the outer diameter of the heat exchange target. For the peak; 孰 = to the secret and close contact with the heat exchange target, preferably Yes, the shape of the 敎 exchange is set to a cylinder or cylinder, and = can cause the disk to be swollen to the side of the inner circumference, and the surface of the surface is flat and tightly attached to the outside of the air. The air is easily accessible from the heat exchange section. By hand, we can achieve a cooling jacket with excellent adhesion. Two cylinders - a cylindrical housing for the heat exchange part of the binding, can be placed on the outer side of the = (4). When the heat exchange part is swollen by heat = side, the 'cylinder shell is used to limit the relevant expansion,! The close connection = the change of the part toward the inner side of the side of the side and the heat exchange target is directly needed. The exchange target is to generate heat exchange with the outside world (cold: or force η mouth heat)' and can be applied to many different fields. However, the present invention is applied to a hydrogen storage alloy container, which can be based on 敎312 /Invention manual (supplement)/95-〇6/95108112 11 1303300

< I 父換效率而在氫氣儲存/排放效 氫氣儲存合金容器中,可以有效地4生人大:的差異。在 氫氣的健存或排放均可以有效地實;::或加熱’致使 且在:::!·’熱交換的目的可以是冷卻與加熱兩者,而 、、而要的活,冷卻與加熱可以彼此切換。 圍:一:根據本發明’設有熱交換部’係設置成用以 其;圓筒狀熱交換目標的外圍表面,此熱交換部 部且有Γ使熱媒介從中通過的中空空間,且熱交換 臉脹。:此’忐夠藉由熱媒介的壓力而朝向至少内圍側邊 二/可與熱交換目標有效地執行熱交換。而且, 可以獲侍以下的效果。 (二)當貫施與-氫氣儲存合金容器的熱交換時,可產生 2—效果,就是,可藉由沒有空氣層但具有極 熱交換部而縮域氣充填日寺㈤。 生的 ⑵具有液體媒介並未與熱交換目標產生接觸的效果, 且因此,可以藉由低溫用的濃鹽水輕易執行零度以下的冷 卻,此種冷卻方式以往須擦拭表面而相當麻煩。 〜 ()由於固疋熱父換目標的力量是藉由熱媒介的壓力導 致熱交換部膨脹而產生的’因此,可以防止熱交換目桿掉 落,因而可以產生固定。當媒介的流動停止時,液體=力 就失效,且,熱交換部的膨脹也停止,致使能夠輕易取出 熱交換目標。也就是說,能使熱交換目標帶有較高可 性的效果。 π卸 (4)不需要夾套緊定步驟或固定步驟,且因此可以減少 312ΧΡ/發明說明書(補件)/95-06/95108112 12 1303300 整個工作的步驟數目。 、欠媒介溫度而執行冷卻 以及加 (5)具有可藉由同樣地改 熱的效果。 同場域中有效的表面加熱/冷卻 (6)本發明有可用於不 之效果。 ⑺本發明有可用於定位並固定部件的效果。 【貫施方式】 以下’將麥考圖1說明本發明_實施例的冷卻裝置。 冷广裝置裝設有一圓筒殼體7,此殼體具有一液麵 用輸口 6,以及一液體媒介用的排放口 8,並且,一 媒’丨s 13疋從圓筒殼體7的外侧邊連接到進入口 6與排 放口 8。媒介管13係經由1 16而連接到媒介槽15,且, ^ j結構能夠使作為熱媒介的液體媒介2〇在媒介槽15與 圓同叙體7之間產生循環。一恆溫器裝置17係固定至媒 介槽15,且將液體媒介2〇的溫度調整至一預定溫度。由 兀件付號18所標示的一裝置組,可以藉由自來水供應裝 置加以取代。 ③置在圓筒殼體7内作為熱交換目標的一腿壓力容器 1,係設計成一圓筒形狀,且在其兩端被密封起來。其中 谷納有氫氣儲存合金(未顯示)。在腿壓力容器i中,氫 氣官2係從外界連接到MH壓力容器},致使能夠在氫氣 官2與氫氣儲存合金之間執行通風。氫氣管2係經由一斷 流閥3及一壓力調整閥4而連接到一氫氣供應裝置5。以 上述方式可構成一氫氣管系統。 312XP/發明說明書(補件)/95·06/951〇8Π2 1303300 ' ί 在圓筒殼體7中’作為—熱交換部的樹脂管9,係螺旋 式地捲、VO且叹置成圓筒形狀,以便達成一内圍直徑,此内 圍直徑是稍微大於_壓力容器1的外圍直徑,且,管9 的兩端部被連接到進入口 6與排放口 8。管9的外圍:則邊 ΐ:上是沿著圓筒殼體7的内圍表面,且,它是藉由圓筒 :又^加以支撐。官9具有這樣的撓性’致使藉由熱媒介 f經管9時’管9的直徑增加,且可藉由熱媒介的廢力而 膨脹。媒介管系統是藉由媒介槽15、媒介管13、泵16、 怪溫器襄置17、圓筒殼體7、與管9而構成的。 其次,將說明本裝置的操作。 首先MH壓力容器ί係設置在螺旋捲繞於圓筒殼體7中 的樹脂管9之内圍側邊中心。已經調整溫度或在恆溫器裝 置17中冷卻的液體媒介,係流經媒介管13,且藉由泵Μ 供應至螺旋捲繞的樹脂管9之—端。通過進人口 6且引入 到樹脂管9的中空空間之液體媒介20,可沿著管9的螺 旋路徑從另一端側邊流到排放口 8側邊。 由2泵16的排放作用,使得液體媒介2〇具有壓力,因 ^匕迠使具有撓性的樹脂管9之内徑伸展開來。於是, 樹脂管9的内圍側邊可與MH壓力容器1的外圍表面產生 接觸。此時,螺旋形樹脂f 9的相鄰轉彎部分同樣地合彼 此膨脹’且因此,樹脂管9的剖面係設計成為一半圓筒 狀,致使其迎壓力容器1侧邊是一平坦表面。此外,由 於在空氣排放性能與接觸面的液體壓力之間的關係,導致 整個螺旋形内部會有效地與MH壓力容器i的表面產生緊 312XP/發明說明書(補件)/95·06/95108112 14 1303300 故如:有助於防止熱傳面積的縮小,且由於緊密接 觸的、、彖故,而增加熱傳係數,致使可 2〇與壓力容器〗之間的有效熱交換。= 膨脹會受到圓筒殼體7的限制,且,可: 透過排放口 8與媒介您n, 臭的液體媒介20,可 恆溫器裝置17加以調整溫产而Π:槽15,且藉由 Η再度循環,且可二二:“:液體媒介會藉由栗 寺、、、只地冷卻ΜΗ壓力交哭1 在氯氣管系統中,從氫氣供應裝置5供鹿:上:厂 _)調整至某,的氫氣,=力調 日守,斷流閥3是開啟的。在土力合為1。此 合金,吸收了符合氫氣供應 1 态1中的氫氣儲存 關係的氫氣量,以便藉由::二;氣儲存合金溫度之間 用來填滿氫氣H θ H統的有效熱移除作 介引入到管9内,於是,解^ ^時’亦停止將液體媒 會減少成為原始尺寸。於曰了吕9的膨服’且管的直徑 時,可以輕易執行拆卸工需要拆卸贿屡力容器! 在上述實施例令,埶 — 的。在本發明中,熱交換猎㈣ί捲繞管而構成 可以藉由一圓筒狀構件構 可藉由官狀構件,而且還 明。與之述實施例相同的組成::=將參考圖2加以說 不,且簡化其相關說明。 二以相同的元件符號標 亦即,設計成圓筒狀且| “ σ圖2所示的底部之 3画發明說明書(補件)/95-06/95】_2 Τ 15 1303300 空的袋本體19,係製備成為一熱交換部,且以與上述實 施例相同的方式設置在圓筒殼體7内。袋本體丨9在其下 端處與進入口 7相通,且在其上端處與排放口a8相通'。 當操作上述裝置時,μη壓力容器丨係設置在袋本體19 的内圍側邊中心,致使MH壓力容器i的外圍係受到袋本 體1 士9的圍繞。當使液體媒介流經媒介管13而流入袋本體 19時,透過進入口 6引入到袋本體19的中空區域内之液 體媒介,能使袋本體19膨脹到内圍側邊,且與腿壓力容 器1的外圍表面產生緊密接觸。液體媒介通過中空區域且 從排放口 8排出。藉由隨後將液體媒介引入到袋本體19 内’可以保持與MH壓力容器i的外圍表面之緊密接觸, 且可以有效冷卻MH壓力容器卜此時,袋本體19到 侧邊的膨脹係受到圓筒殼體7的限制,這—點與上术每 相同。氮氣管系統的操作是與上述實施 ⑽元成此钿作之後停止將液體媒介弓|入到袋本體U 時’袋本體19的膨脹也會停止,且,可 輕易取出MH壓力容器丨。 ^ ^ 1 2 MH壓力容器係藉由使關i所示本發明 312XP/發明說明書(補件)/95-06/95108112 16 1 置:示的人直接冷卻裝置、以及金屬冷卻夹套為主心 置加以冷卻,且,測試在上述每 p衣 間:影響,其結果顯示於圖3的圖表内。橫= 填時間(分),而縱座標軸則代表氫氣充殖 、 2 是以相同的MH壓力容哭,且在上、f夂 )此測試 合〇° 在上述各種情形中氫氣供雁 厂…液體媒介溫度、以及液體媒介循環流量等各因素: 1303300 相等的條件下實施的。 — 裝置為主的結果,赴6 中的貫心線代表以直接冷卻 果,而單點鋒,‘,、線代表以本發明冷卻裝置為主的結 從圖表中可以於,曰^ 7 a人备忒置為主的結果。 直接、入门 見,本發明的冷卻裝置可以在大致上與 氣。^在填時間内,在MH壓力容器中填滿氫 時間的時Γ對應於間接冷卻的金屬冷卻央套之充填 示出本發明的效果/ 邊“異,因此可充分地顯 至用液體媒介,然而,它同樣地也可以應用 至個其中使用氣體媒介的情形。 二,據上述實施例來說明本發明。然而,本發明並未 上述的說明内容而已,且仍可以在本發明 產生出許多修改。 【圖式簡單說明】 圖1是顯示本發明一實施例的熱交換裝置之示意圖 圖2是顯示另一實施例的熱交換裝置之剖面圖。 圖3是顯示在本發明的冷卻裝置、直接冷卻裝置、與金 屬水冷卻夹套為主的冷卻裝置之間就氫氣充填量與充填 時間的比較之圖表。 〃 圖4是顯示使用一先前相關直接冷卻裝置的情形之示意 圖0 【主要元件符號說明】 (MH)壓力容器 氫氣管 312XP/發明說明書(補件)/95-06/95108112 17 1303300< I The father can change the efficiency in the hydrogen storage/emission effect hydrogen storage alloy container, which can effectively make the difference: The hydrogen storage or discharge can be effectively achieved;:: or heating 'causes and at:::!·' The purpose of heat exchange can be both cooling and heating, and the desired, cooling, heating You can switch between each other. Circumference: A: According to the present invention, 'providing a heat exchange portion' is provided for the peripheral surface of the cylindrical heat exchange target, and the heat exchange portion has a hollow space through which the heat medium passes, and the heat Exchange face swelling. : This is sufficient to effectively perform heat exchange with the heat exchange target by the pressure of the heat medium toward at least the inner side of the inner side. Moreover, the following effects can be obtained. (2) When the heat exchange with the hydrogen storage alloy container is carried out, a 2-effect can be produced, that is, the Japanese temple (5) can be filled by the air-reducing portion without the air layer but having the extremely heat exchange portion. The raw (2) has the effect that the liquid medium does not come into contact with the heat exchange target, and therefore, it is possible to easily perform cooling below zero degrees by the concentrated brine for low temperature, which has conventionally required to wipe the surface and is rather troublesome. ~ () Since the force of the target is changed by the pressure of the heat medium, the heat exchange unit is expanded. Therefore, the heat exchange rod can be prevented from falling, and thus the fixing can be caused. When the flow of the medium is stopped, the liquid = force is disabled, and the expansion of the heat exchange portion is also stopped, so that the heat exchange target can be easily taken out. In other words, the heat exchange target can be highly responsive. π unloading (4) does not require a jacket tightening step or a fixed step, and thus can reduce the number of steps of the entire work of 312 ΧΡ / invention specification (supplement) / 95-06/95108112 12 1303300. Performing cooling under the medium temperature and adding (5) have the effect of heating similarly. Effective surface heating/cooling in the same field (6) The present invention has an effect that can be used. (7) The present invention has an effect that can be used to position and fix components. [Communication Method] Hereinafter, the cooling device of the present invention will be described with reference to the McCaw chart 1. The cold and wide device is provided with a cylindrical casing 7 having a liquid level opening 6 and a discharge port 8 for liquid medium, and a medium '丨s 13疋' from the cylindrical casing 7 The outer side is connected to the inlet port 6 and the discharge port 8. The medium tube 13 is connected to the medium tank 15 via 161, and the structure j can cause the liquid medium 2 as a heat medium to circulate between the medium tank 15 and the circular symmetry body 7. A thermostat device 17 is fixed to the medium tank 15 and adjusts the temperature of the liquid medium 2 to a predetermined temperature. A device group indicated by the item number 18 can be replaced by a tap water supply device. 3 A leg pressure vessel 1 placed in the cylindrical casing 7 as a heat exchange target is designed in a cylindrical shape and sealed at both ends thereof. Among them, Guna has a hydrogen storage alloy (not shown). In the leg pressure vessel i, the hydrogen gas 2 is connected from the outside to the MH pressure vessel}, so that ventilation can be performed between the hydrogen gas 2 and the hydrogen storage alloy. The hydrogen pipe 2 is connected to a hydrogen supply device 5 via a shut-off valve 3 and a pressure regulating valve 4. A hydrogen tube system can be constructed in the above manner. 312XP/Invention Manual (Supplement)/95·06/951〇8Π2 1303300 ' ί In the cylindrical casing 7, the resin tube 9 as the heat exchange portion is spirally wound, VO and sinned into a cylinder. The shape is such that an inner diameter is obtained which is slightly larger than the outer diameter of the pressure vessel 1, and both ends of the tube 9 are connected to the inlet port 6 and the discharge port 8. The periphery of the tube 9 is: the side is the inner peripheral surface of the cylindrical casing 7, and it is supported by the cylinder: The officer 9 has such flexibility that the diameter of the tube 9 increases as the heat medium f passes through the tube 9, and can be expanded by the waste force of the heat medium. The media tube system is constructed by a medium tank 15, a medium tube 13, a pump 16, a temperature damper unit 17, a cylindrical housing 7, and a tube 9. Next, the operation of the apparatus will be explained. First, the MH pressure vessel ί is disposed at the center of the inner side of the resin tube 9 spirally wound in the cylindrical casing 7. The liquid medium which has been adjusted in temperature or cooled in the thermostat unit 17 flows through the medium tube 13 and is supplied to the end of the spirally wound resin tube 9 by means of a pump. The liquid medium 20 which enters the hollow space of the resin tube 9 by entering the population 6 can flow from the other end side to the side of the discharge port 8 along the spiral path of the tube 9. The discharge of the 2 pump 16 causes the liquid medium 2 to have a pressure, so that the inner diameter of the flexible resin tube 9 is extended. Thus, the inner side of the resin tube 9 can come into contact with the peripheral surface of the MH pressure vessel 1. At this time, the adjacent turning portions of the spiral resin f 9 are similarly expanded toward each other. Therefore, the cross section of the resin tube 9 is designed to be a semi-cylindrical shape so that the side of the pressure vessel 1 is a flat surface. In addition, due to the relationship between the air discharge performance and the liquid pressure of the contact surface, the entire spiral interior is effectively produced to the surface of the MH pressure vessel i. 312XP/Invention Manual (Supplement)/95·06/95108112 14 1303300 For example: to help prevent the shrinkage of the heat transfer area, and increase the heat transfer coefficient due to close contact, and cause efficient heat exchange between the 2 and the pressure vessel. = The expansion will be limited by the cylindrical housing 7, and: through the discharge port 8 and the medium, the odorous liquid medium 20, the thermostat device 17 can be adjusted to produce a temperature: 槽15, and by Η Cycle again, and can be two or two: ": The liquid medium will be crying by the chestnut, and only the cooling pressure. In the chlorine gas pipe system, the hydrogen supply device 5 is supplied to the deer: the factory: The hydrogen gas, = force regulation, the shut-off valve 3 is open. The earth force is 1. This alloy absorbs the hydrogen amount in accordance with the hydrogen storage relationship in the hydrogen supply state 1 to be used by: The effective heat removal between the gas storage alloy temperatures to fill the hydrogen H θ H system is introduced into the tube 9, so that when the solution is ^, the liquid medium is reduced to the original size. When Lu 9 is inflated 'and the diameter of the tube, the demolition worker can easily perform the disassembly of the bribe force container! In the above embodiment, the 埶-. In the present invention, the heat exchange hunting (four) 卷绕 winding tube can be borrowed The structure of a cylindrical member can be made by the official member, and it is also clear. The same composition::= will be referred to with reference to Figure 2, and the related description will be simplified. Second, the same component symbol, that is, designed into a cylindrical shape and | " σ Figure 2 shows the bottom of the 3 paintings Specification (Supplement)/95-06/95]_2 Τ 15 1303300 The empty bag body 19 is prepared as a heat exchange portion, and is disposed in the cylindrical casing 7 in the same manner as the above embodiment. The bag body 丨 9 communicates with the inlet port 7 at its lower end and communicates with the discharge port a8 at its upper end. When the above apparatus is operated, the μη pressure vessel is disposed at the center of the inner circumference side of the bag body 19, so that the periphery of the MH pressure vessel i is surrounded by the bag body 1. When the liquid medium flows through the medium tube 13 and flows into the bag body 19, the liquid medium introduced into the hollow region of the bag body 19 through the inlet port 6 enables the bag body 19 to be inflated to the inner side of the inner circumference and the leg pressure container The peripheral surface of 1 produces close contact. The liquid medium passes through the hollow region and is discharged from the discharge port 8. By introducing the liquid medium into the bag body 19, the intimate contact with the peripheral surface of the MH pressure vessel i can be maintained, and the MH pressure vessel can be effectively cooled. At this time, the expansion of the bag body 19 to the side is received by the cylinder. The limitation of the housing 7, this point is the same as the upper one. The operation of the nitrogen tube system is such that the expansion of the bag body 19 is stopped when the liquid medium is inserted into the bag body U after the above-described implementation (10), and the MH pressure container 可 can be easily taken out. ^ ^ 1 2 MH pressure vessel is based on the invention 312XP / invention manual (supplement) / 95-06/95108112 16 1: the human direct cooling device, and the metal cooling jacket It was cooled and tested in each of the above-mentioned rooms: effects, and the results are shown in the graph of FIG. Horizontal = fill time (minutes), while the ordinate axis represents hydrogen enrichment, 2 is crying with the same MH pressure, and on the top, f夂) This test is combined. In the above various situations, hydrogen is supplied to the wild plant... liquid Various factors such as media temperature and liquid medium circulation flow rate: 1303300 are implemented under equal conditions. - The result of the device-based, the line of the heart line going to 6 is to directly cool the fruit, and the single point front, ',, the line represents the knot based on the cooling device of the present invention, which can be used in the chart, 曰^ 7 a person Prepare for the primary result. Directly, as an introduction, the cooling device of the present invention can be substantially vented. ^ During the filling time, when the MH pressure vessel is filled with hydrogen time, the filling corresponding to the indirectly cooled metal cooling jacket shows that the effect/edge of the present invention is different, so that the liquid medium can be sufficiently exhibited. However, it can equally be applied to a case in which a gas medium is used. Second, the present invention will be described based on the above embodiments. However, the present invention does not have the above description, and many modifications can be made in the present invention. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing a heat exchange device according to an embodiment of the present invention. Fig. 2 is a cross-sectional view showing a heat exchange device according to another embodiment. Fig. 3 is a view showing the cooling device of the present invention directly. A graph comparing the hydrogen filling amount and the filling time between the cooling device and the metal water cooling jacket-based cooling device. 〃 Figure 4 is a schematic diagram showing the situation in which a previously related direct cooling device is used. 】 (MH) pressure vessel hydrogen tube 312XP / invention manual (supplement) / 95-06/95108112 17 1303300

3 斷流閥 4 壓力調整閥 5 氫氣供應裝置 6 進入口 7 圓筒殼體 8 排放口 9 樹脂管 10 媒介缸 11 進入口 12 排放口 13 媒介管 15 媒介槽 16 泵 17 恆溫器裝置 18 裝置組 19 袋本體 20 液體媒介 312XP/發明說明書(補件)/95-06/95108112 183 Shut-off valve 4 Pressure regulating valve 5 Hydrogen supply device 6 Access port 7 Cylinder housing 8 Discharge port 9 Resin tube 10 Media cylinder 11 Access port 12 Drain port 13 Media tube 15 Media tank 16 Pump 17 Thermostat device 18 Device group 19 bag body 20 liquid medium 312XP / invention manual (supplement) / 95-06/95108112 18

Claims (1)

1303300 十、申請專利範圍: 丄二種熱交換裝置,包含—熱交換部,而該熱交換部係 二成用以圍繞一熱交換目標的外圍表面, 八中°亥熱又換部内包含一用於使熱媒介通過的中空空 曰,且具有撓性,以便藉由熱媒介的壓力而朝向JL至少一 内圍侧邊膨脹。 2.如中睛專利範圍第}項之熱交換裝置,其中,該熱交 外2設計成為一管子形狀,以便捲繞在該熱交換目標的 外圍表面周圍。 換::::::域圍第1項之熱交換裝置,其中,該熱交 外圍表面又周^圓筒形狀’以便捲繞在該熱交換目標的 4.如申請專利範圍帛i項之熱交換 換部在外圍剖面係設計成圓形。 、中’该熱父 5·如申請專利範圍第1項之熱交換裝置,其中, =該熱交換部的圓筒殼體係設置在該熱交換部的:圍; 6·如申凊專利範圍第丨項之熱交換裝置,其中, 換目標是-氫氣儲存/排放容器,在該容器有 儲存合金。 、、巧有虱氧 7·如申睛專利範圍第丨項之熱交換裝置,其中, 換口ίΜ系口又置成用以圍繞一圓柱或圓筒狀熱交 二: 圍表面。 、曰私的外 8·如申凊專利範圍第1項之熱交換裝置,其中,該熱交 312ΧΡ/發明說明書(補件姊伐/吻⑽⑴ 19 1303300 ; I 換部係朝向其至少内圍側邊膨脹,以便藉由熱媒介的壓力 而與該熱交換目標的外圍表面產生接觸。 9.如申請專利範圍第1項之熱交換裝置,其中,該熱交 換部係設置在一大於熱交換目標的外徑之内徑上。1303300 X. Patent application scope: 丄 Two kinds of heat exchange devices, including - heat exchange part, and the heat exchange part is 20% for surrounding the outer surface of a heat exchange target, and the middle part of the heat exchange part is included in the The hollow space through which the heat medium passes is flexible and is expanded toward at least one inner side of the JL by the pressure of the heat medium. 2. The heat exchange device of the above-mentioned item, wherein the heat transfer 2 is designed to be in the shape of a tube so as to be wound around the peripheral surface of the heat exchange target. Change:::::: The heat exchange device of the first item, wherein the heat exchange peripheral surface is further cylindrically shaped to be wound around the heat exchange target. 4. As claimed in the patent scope 帛i The heat exchange change is designed to be circular in the peripheral profile. In the heat exchange device of the first aspect of the patent application, wherein the cylinder housing of the heat exchange portion is disposed in the heat exchange portion: The heat exchange device of the item, wherein the target is a hydrogen storage/discharge container in which the storage alloy is stored. The heat exchange device of the ninth item of the patent application scope, wherein the mouthpiece is further configured to be heated around a cylindrical or cylindrical shape: a surrounding surface.曰 的 外 · · · 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 凊 ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ ΧΡ Expanding to make contact with the peripheral surface of the heat exchange target by the pressure of the heat medium. 9. The heat exchange device of claim 1, wherein the heat exchange portion is disposed at a heat exchange target On the inner diameter of the outer diameter. 312XP/發明說明書(補件)/95-06/95108112 20312XP/Invention Manual (supplement)/95-06/95108112 20
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