TWI301481B - A catalyst system - Google Patents
A catalyst systemInfo
- Publication number
- TWI301481B TWI301481B TW092120692A TW92120692A TWI301481B TW I301481 B TWI301481 B TW I301481B TW 092120692 A TW092120692 A TW 092120692A TW 92120692 A TW92120692 A TW 92120692A TW I301481 B TWI301481 B TW I301481B
- Authority
- TW
- Taiwan
- Prior art keywords
- sup
- sub
- catalyst system
- catalyst
- compound
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 230000006315 carbonylation Effects 0.000 abstract 1
- 238000005810 carbonylation reaction Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000004437 phosphorous atom Chemical group 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
- B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
- B01J31/2457—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings, e.g. Xantphos
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5018—Cycloaliphatic phosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5027—Polyphosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5045—Complexes or chelates of phosphines with metallic compounds or metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/52—Halophosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B01J35/23—
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/56—Ring systems containing bridged rings
- C07C2603/58—Ring systems containing bridged rings containing three rings
- C07C2603/70—Ring systems containing bridged rings containing three rings containing only six-membered rings
- C07C2603/74—Adamantanes
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0218613.8A GB0218613D0 (en) | 2002-08-10 | 2002-08-10 | Process for the carbonylation of ethylenically unsaturated compounds |
GBGB0228018.8A GB0228018D0 (en) | 2002-11-30 | 2002-11-30 | Carbonylation of ester |
GB0316159A GB0316159D0 (en) | 2003-07-10 | 2003-07-10 | A catalyst system |
Publications (2)
Publication Number | Publication Date |
---|---|
TW200417542A TW200417542A (en) | 2004-09-16 |
TWI301481B true TWI301481B (en) | 2008-10-01 |
Family
ID=31721066
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW092120692A TWI301481B (en) | 2002-08-10 | 2003-07-29 | A catalyst system |
Country Status (16)
Country | Link |
---|---|
US (1) | US7371705B2 (zh) |
EP (1) | EP1534427B1 (zh) |
JP (1) | JP5101014B2 (zh) |
KR (1) | KR101035697B1 (zh) |
CN (1) | CN1674990B (zh) |
AT (1) | ATE446140T1 (zh) |
AU (1) | AU2003259322C1 (zh) |
BR (1) | BR0313289B1 (zh) |
CA (1) | CA2493250C (zh) |
DE (1) | DE60329764D1 (zh) |
ES (1) | ES2334222T3 (zh) |
IN (1) | IN227859B (zh) |
MY (1) | MY139539A (zh) |
PL (1) | PL374194A1 (zh) |
TW (1) | TWI301481B (zh) |
WO (1) | WO2004014552A1 (zh) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20060038961A (ko) | 2003-07-03 | 2006-05-04 | 루사이트 인터내셔널 유케이 리미티드 | 에틸렌으로 불포화된 화합물의 하이드로포르밀화 방법 |
GB0403592D0 (en) | 2004-02-18 | 2004-03-24 | Lucite Int Uk Ltd | A catalyst system |
GB0411951D0 (en) * | 2004-05-28 | 2004-06-30 | Lucite Int Uk Ltd | Carbonylation of ester |
GB0516556D0 (en) * | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
KR101633325B1 (ko) | 2005-11-17 | 2016-06-24 | 루사이트 인터내셔널 유케이 리미티드 | 에틸렌성 불포화 화합물의 카르보닐화 |
GB0607494D0 (en) | 2006-04-13 | 2006-05-24 | Lucite Int Uk Ltd | Metal complexes |
GB2437930A (en) * | 2006-05-10 | 2007-11-14 | Lucite Int Uk Ltd | Mixing apparatus |
CN105153241B (zh) * | 2006-12-02 | 2020-05-15 | 卢西特国际英国有限公司 | 羰基化配体及其在羰基化烯键式不饱和化合物中的用途 |
GB0625518D0 (en) * | 2006-12-21 | 2007-01-31 | Lucite Int Uk Ltd | Carbonylation of conjugated dienes |
GB0812297D0 (en) | 2008-07-04 | 2008-08-13 | Lucite Int Uk Ltd | Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds |
GB201000078D0 (en) | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
CA2981600C (en) * | 2015-04-10 | 2023-09-05 | Dow Global Technologies Llc | Butadiene telomerization catalyst and preparation thereof |
EP3441384B1 (de) * | 2017-08-08 | 2019-12-25 | Evonik Operations GmbH | Methoxycarbonylierung mit ameisensäure und methanol |
EP3441383B1 (de) * | 2017-08-08 | 2019-12-25 | Evonik Operations GmbH | Methoxycarbonylierung mit ameisensäure als co-quelle |
CN111087306B (zh) | 2019-12-27 | 2021-08-03 | 南京诚志清洁能源有限公司 | 芳基双齿膦配体组合催化制备有机羧酸酯的方法 |
CN113999262B (zh) * | 2021-12-31 | 2022-03-29 | 苏州欣诺科生物科技有限公司 | 二(1-金刚烷基)环烷基膦配体的制备方法 |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4377708A (en) | 1977-10-14 | 1983-03-22 | Monsanto Company | Hydrocarboxylation of vinyl alkanoates |
DE2824010A1 (de) | 1978-06-01 | 1979-12-13 | Metallgesellschaft Ag | Verfahren zur aufkonzentrierung von verduennter phosphorsaeure |
DE3175174D1 (en) | 1981-01-06 | 1986-09-25 | Shell Int Research | Process for the carbonylation of olefins |
CA1231346A (en) | 1982-09-30 | 1988-01-12 | Eit Drent | Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst |
GB8531624D0 (en) | 1985-12-23 | 1986-02-05 | Shell Int Research | Carbonylation of ethylenically unsaturated compounds |
GB8605034D0 (en) | 1986-02-28 | 1986-04-09 | Shell Int Research | Carbonylation of compounds |
KR880007426A (ko) | 1986-12-24 | 1988-08-27 | 오노 알버어스 | 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법 |
GB8705699D0 (en) | 1987-03-11 | 1987-04-15 | Shell Int Research | Carbonylation of olefinically unsaturated compounds |
US4960949A (en) * | 1988-12-22 | 1990-10-02 | Eastman Kodak Company | Low pressure rhodium catalyzed hydroformylation of olefins |
KR0144567B1 (ko) | 1989-03-03 | 1998-07-15 | 오노 알버어스 | 카르보닐화촉매시스템 |
CA2034971A1 (en) | 1990-02-05 | 1991-08-06 | Eit Drent | Carbonylation catalyst system |
CA2055628A1 (en) | 1990-12-03 | 1992-06-04 | Eit Drent | Carbonylation process and catalyst composition |
ES2077337T3 (es) | 1991-01-15 | 1995-11-16 | Shell Int Research | Procedimiento para la carbonilacion de olefinas. |
EP0495547B1 (en) | 1991-01-15 | 1996-04-24 | Shell Internationale Researchmaatschappij B.V. | Carbonylation of olefins |
KR100230139B1 (ko) | 1991-02-15 | 1999-11-15 | 오노 알버어스 | 카르보닐화 촉매 시스템 |
GB9425911D0 (en) | 1994-12-22 | 1995-02-22 | Ici Plc | Process for the carbonylation of olefins and catalyst system for use therein |
GB9705699D0 (en) | 1997-03-19 | 1997-05-07 | Ici Plc | Process for the carbonylation of ethylene |
GB9717059D0 (en) | 1997-08-13 | 1997-10-15 | Ici Plc | Method of manufacturing phosphine compound |
GB9722733D0 (en) | 1997-10-29 | 1998-10-28 | Ici Plc | Production of esters |
GB9805348D0 (en) | 1998-03-16 | 1998-05-06 | Ici Plc | Compound |
GB9918229D0 (en) * | 1999-08-04 | 1999-10-06 | Ici Plc | Improvements relating to metal-compound catalysed processes |
US6743911B2 (en) | 2000-03-14 | 2004-06-01 | Shell Oil Company | Process for the carbonylation of pentenenitrile |
US6706912B2 (en) * | 2000-03-14 | 2004-03-16 | Shell Oil Company | Process for the carbonylation of ethylenically unsaturated compounds |
ATE552907T1 (de) * | 2002-02-19 | 2012-04-15 | Lucite Int Uk Ltd | Verfahren zur carbonylierung ethylenisch ungesättigter verbindungen und zugehöriger katalysator |
KR20060038961A (ko) | 2003-07-03 | 2006-05-04 | 루사이트 인터내셔널 유케이 리미티드 | 에틸렌으로 불포화된 화합물의 하이드로포르밀화 방법 |
-
2003
- 2003-07-29 TW TW092120692A patent/TWI301481B/zh not_active IP Right Cessation
- 2003-08-06 PL PL03374194A patent/PL374194A1/xx unknown
- 2003-08-06 ES ES03784257T patent/ES2334222T3/es not_active Expired - Lifetime
- 2003-08-06 WO PCT/GB2003/003419 patent/WO2004014552A1/en active Application Filing
- 2003-08-06 EP EP03784257A patent/EP1534427B1/en not_active Expired - Lifetime
- 2003-08-06 JP JP2005506118A patent/JP5101014B2/ja not_active Expired - Fee Related
- 2003-08-06 AT AT03784257T patent/ATE446140T1/de not_active IP Right Cessation
- 2003-08-06 BR BRPI0313289-7A patent/BR0313289B1/pt not_active IP Right Cessation
- 2003-08-06 DE DE60329764T patent/DE60329764D1/de not_active Expired - Lifetime
- 2003-08-06 US US10/524,023 patent/US7371705B2/en not_active Expired - Lifetime
- 2003-08-06 CN CN038190796A patent/CN1674990B/zh not_active Expired - Lifetime
- 2003-08-06 KR KR1020057002048A patent/KR101035697B1/ko not_active IP Right Cessation
- 2003-08-06 AU AU2003259322A patent/AU2003259322C1/en not_active Ceased
- 2003-08-06 IN IN333DE2005 patent/IN227859B/en unknown
- 2003-08-06 CA CA2493250A patent/CA2493250C/en not_active Expired - Fee Related
- 2003-08-08 MY MYPI20033011A patent/MY139539A/en unknown
Also Published As
Publication number | Publication date |
---|---|
PL374194A1 (en) | 2005-10-03 |
ES2334222T3 (es) | 2010-03-08 |
CN1674990A (zh) | 2005-09-28 |
MY139539A (en) | 2009-10-30 |
AU2003259322C1 (en) | 2010-10-21 |
IN227859B (zh) | 2009-02-13 |
AU2003259322A1 (en) | 2004-02-25 |
ATE446140T1 (de) | 2009-11-15 |
AU2003259322B2 (en) | 2009-02-12 |
CA2493250C (en) | 2012-09-11 |
DE60329764D1 (de) | 2009-12-03 |
JP5101014B2 (ja) | 2012-12-19 |
BR0313289B1 (pt) | 2013-04-02 |
KR20050028056A (ko) | 2005-03-21 |
AU2003259322B8 (en) | 2009-02-26 |
WO2004014552A1 (en) | 2004-02-19 |
JP2005535455A (ja) | 2005-11-24 |
US7371705B2 (en) | 2008-05-13 |
KR101035697B1 (ko) | 2011-05-19 |
EP1534427A1 (en) | 2005-06-01 |
BR0313289A (pt) | 2005-07-12 |
TW200417542A (en) | 2004-09-16 |
CN1674990B (zh) | 2010-04-14 |
CA2493250A1 (en) | 2004-02-19 |
US20060106259A1 (en) | 2006-05-18 |
EP1534427B1 (en) | 2009-10-21 |
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Legal Events
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MM4A | Annulment or lapse of patent due to non-payment of fees |