TWI295692B - Methods of processing nickel-titanium alloys - Google Patents
Methods of processing nickel-titanium alloys Download PDFInfo
- Publication number
- TWI295692B TWI295692B TW093112375A TW93112375A TWI295692B TW I295692 B TWI295692 B TW I295692B TW 093112375 A TW093112375 A TW 093112375A TW 93112375 A TW93112375 A TW 93112375A TW I295692 B TWI295692 B TW I295692B
- Authority
- TW
- Taiwan
- Prior art keywords
- nickel
- aging
- temperature
- phase transition
- titanium alloy
- Prior art date
Links
- 229910001000 nickel titanium Inorganic materials 0.000 title claims description 248
- 229910045601 alloy Inorganic materials 0.000 title claims description 241
- 239000000956 alloy Substances 0.000 title claims description 241
- 238000000034 method Methods 0.000 title claims description 94
- HZEWFHLRYVTOIW-UHFFFAOYSA-N [Ti].[Ni] Chemical compound [Ti].[Ni] HZEWFHLRYVTOIW-UHFFFAOYSA-N 0.000 title claims 8
- 238000012545 processing Methods 0.000 title description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 410
- 230000032683 aging Effects 0.000 claims description 262
- 230000007704 transition Effects 0.000 claims description 250
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 238
- 229910052742 iron Inorganic materials 0.000 claims description 205
- 229910052759 nickel Inorganic materials 0.000 claims description 122
- 238000010438 heat treatment Methods 0.000 claims description 65
- 229910010380 TiNi Inorganic materials 0.000 claims description 48
- 239000000203 mixture Substances 0.000 claims description 47
- HLXZNVUGXRDIFK-UHFFFAOYSA-N nickel titanium Chemical compound [Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni].[Ni] HLXZNVUGXRDIFK-UHFFFAOYSA-N 0.000 claims description 37
- 239000006104 solid solution Substances 0.000 claims description 35
- 239000007787 solid Substances 0.000 claims description 25
- 238000005275 alloying Methods 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- 229910001152 Bi alloy Inorganic materials 0.000 claims 1
- 239000011133 lead Substances 0.000 claims 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 53
- AGRZSLXZTRXJMD-UHFFFAOYSA-N nickel titanium Chemical compound [Ti].[Ni].[Ni] AGRZSLXZTRXJMD-UHFFFAOYSA-N 0.000 description 23
- 230000008859 change Effects 0.000 description 18
- 238000011282 treatment Methods 0.000 description 15
- 239000000523 sample Substances 0.000 description 14
- 239000002244 precipitate Substances 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 5
- KHYBPSFKEHXSLX-UHFFFAOYSA-N iminotitanium Chemical compound [Ti]=N KHYBPSFKEHXSLX-UHFFFAOYSA-N 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 4
- 229910052737 gold Inorganic materials 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 235000000396 iron Nutrition 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910004337 Ti-Ni Inorganic materials 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 229910011209 Ti—Ni Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000006911 nucleation Effects 0.000 description 3
- 238000010899 nucleation Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000005204 segregation Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 229910000640 Fe alloy Inorganic materials 0.000 description 2
- 229910000713 I alloy Inorganic materials 0.000 description 2
- 229910010381 TiNi3 Inorganic materials 0.000 description 2
- 229910000905 alloy phase Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000007734 materials engineering Methods 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 238000004881 precipitation hardening Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 229910001257 Nb alloy Inorganic materials 0.000 description 1
- 229910003298 Ni-Ni Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 230000018199 S phase Effects 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- WCERXPKXJMFQNQ-UHFFFAOYSA-N [Ti].[Ni].[Cu] Chemical compound [Ti].[Ni].[Cu] WCERXPKXJMFQNQ-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000012417 linear regression Methods 0.000 description 1
- 210000001161 mammalian embryo Anatomy 0.000 description 1
- 229910000734 martensite Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- XIKYYQJBTPYKSG-UHFFFAOYSA-N nickel Chemical compound [Ni].[Ni] XIKYYQJBTPYKSG-UHFFFAOYSA-N 0.000 description 1
- FEBJSGQWYJIENF-UHFFFAOYSA-N nickel niobium Chemical group [Ni].[Nb] FEBJSGQWYJIENF-UHFFFAOYSA-N 0.000 description 1
- DEPMYWCZAIMWCR-UHFFFAOYSA-N nickel ruthenium Chemical compound [Ni].[Ru] DEPMYWCZAIMWCR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229910002059 quaternary alloy Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910001285 shape-memory alloy Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000004781 supercooling Methods 0.000 description 1
- 229910002058 ternary alloy Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/007—Alloys based on nickel or cobalt with a light metal (alkali metal Li, Na, K, Rb, Cs; earth alkali metal Be, Mg, Ca, Sr, Ba, Al Ga, Ge, Ti) or B, Si, Zr, Hf, Sc, Y, lanthanides, actinides, as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/006—Resulting in heat recoverable alloys with a memory effect
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Heat Treatment Of Nonferrous Metals Or Alloys (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Heat Treatment Of Steel (AREA)
- Investigating And Analyzing Materials By Characteristic Methods (AREA)
- Adornments (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/427,783 US7192496B2 (en) | 2003-05-01 | 2003-05-01 | Methods of processing nickel-titanium alloys |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200513541A TW200513541A (en) | 2005-04-16 |
| TWI295692B true TWI295692B (en) | 2008-04-11 |
Family
ID=33310255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW093112375A TWI295692B (en) | 2003-05-01 | 2004-04-30 | Methods of processing nickel-titanium alloys |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US7192496B2 (cg-RX-API-DMAC7.html) |
| EP (2) | EP2818565A1 (cg-RX-API-DMAC7.html) |
| JP (2) | JP5535426B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR101048531B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN1780924B (cg-RX-API-DMAC7.html) |
| AU (1) | AU2004236647B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0409953A (cg-RX-API-DMAC7.html) |
| CA (1) | CA2522217C (cg-RX-API-DMAC7.html) |
| HK (1) | HK1201891A1 (cg-RX-API-DMAC7.html) |
| IL (3) | IL171390A (cg-RX-API-DMAC7.html) |
| MX (1) | MXPA05011265A (cg-RX-API-DMAC7.html) |
| NO (1) | NO20055684L (cg-RX-API-DMAC7.html) |
| NZ (1) | NZ543066A (cg-RX-API-DMAC7.html) |
| RU (1) | RU2344196C2 (cg-RX-API-DMAC7.html) |
| TW (1) | TWI295692B (cg-RX-API-DMAC7.html) |
| UA (1) | UA85384C2 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2004099456A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006523770A (ja) * | 2003-04-18 | 2006-10-19 | ザ ユニバーシティ オブ ホンコン | 形状記憶材料、およびこれを製造する方法 |
| ES2249757T5 (es) * | 2003-05-14 | 2010-08-23 | Kilian Kraus | Implante ajustable en altura para su colocacion entre vertebras dorsales y herramienta de manipulacion. |
| ES2279985T3 (es) * | 2003-08-08 | 2007-09-01 | Biorthex Inc | Material poroso de ti-ni biocompatible. |
| DE20320974U1 (de) | 2003-12-11 | 2005-08-25 | Deltacor Gmbh | Längenverstellbares Wirbelsäulen-Implantat |
| EP1804698B1 (en) * | 2004-10-04 | 2012-07-04 | Saint Louis University | Intramedullary nail device for repairing long bone |
| US20070073374A1 (en) * | 2005-09-29 | 2007-03-29 | Anderl Steven F | Endoprostheses including nickel-titanium alloys |
| CA2658580C (en) * | 2006-09-06 | 2016-11-22 | Cook Incorporated | Nickel-titanium alloy including a rare earth element |
| EP3296413A1 (en) * | 2007-12-21 | 2018-03-21 | Cook Medical Technologies LLC | Radiopaque alloy and medical device made of this alloy |
| US8225478B2 (en) * | 2008-01-30 | 2012-07-24 | The Boeing Company | Memory shape bushings and bearings |
| US20090205826A1 (en) * | 2008-02-19 | 2009-08-20 | Alejandro Rodriguez | Method for Increasing the Fluid Productivity of a Hydraulically Fractured Well |
| RU2374356C1 (ru) * | 2008-04-28 | 2009-11-27 | Закрытое акционерное общество "Промышленный центр МАТЭКС" | Способ термомеханической обработки изделий из сплава на основе никелида титана |
| GB2467584B (en) * | 2009-02-10 | 2010-12-29 | Rolls Royce Plc | An assembly |
| US9186853B2 (en) | 2009-08-07 | 2015-11-17 | Smarter Alloys Inc. | Methods and systems for processing materials, including shape memory materials |
| GB2475340B (en) | 2009-11-17 | 2013-03-27 | Univ Limerick | Nickel-titanium alloy and method of processing the alloy |
| US8216398B2 (en) * | 2010-05-17 | 2012-07-10 | Saint Louis University | Method for controlling phase transformation temperature in metal alloy of a device |
| DE102010026048A1 (de) * | 2010-07-03 | 2012-01-05 | Mtu Aero Engines Gmbh | Nickelbasis-Lotlegierung |
| US8475711B2 (en) | 2010-08-12 | 2013-07-02 | Ati Properties, Inc. | Processing of nickel-titanium alloys |
| GB2495772B (en) | 2011-10-21 | 2014-02-12 | Univ Limerick | Method of forming a sintered nickel-titanium-rare earth (Ni-Ti-RE) alloy |
| WO2013109846A1 (en) | 2012-01-18 | 2013-07-25 | Cook Medical Technologies Llc | Mixture of powders for preparing a sintered nickel-titanium-rare earth metal (ni-ti-re) alloy |
| US20130239565A1 (en) * | 2012-03-16 | 2013-09-19 | GM Global Technology Operations LLC | Spatially graded sma actuators |
| US9279171B2 (en) | 2013-03-15 | 2016-03-08 | Ati Properties, Inc. | Thermo-mechanical processing of nickel-titanium alloys |
| CN104099544A (zh) * | 2013-04-07 | 2014-10-15 | 北京有色金属研究总院 | 形状记忆合金获得全程记忆效应的方法 |
| CN103422038B (zh) * | 2013-09-04 | 2015-04-08 | 上海康晟特种合金有限公司 | 用于高温铜合金挤压机的内衬模套的热处理方法 |
| WO2015035165A1 (en) | 2013-09-06 | 2015-03-12 | Ormco Corporation | Orthodontic appliances and methods of making and using same |
| US9982330B2 (en) * | 2013-11-27 | 2018-05-29 | University Of Florida Research Foundation, Inc. | Nickel titanium alloys, methods of manufacture thereof and article comprising the same |
| US10138414B2 (en) * | 2014-02-24 | 2018-11-27 | Halliburton Energy Services, Inc. | Propping subterranean formation fractures using memory particulates |
| FR3033487B1 (fr) * | 2015-03-11 | 2021-01-08 | Soprane | Perfectionnements aux aiguilles hyper elastiques |
| WO2018076010A1 (en) | 2016-10-21 | 2018-04-26 | Confluent Medical Technologies, Inc. | Materials having superelastic properties including related methods of fabrication and design for medical devices |
| CN110465662B (zh) * | 2019-08-09 | 2021-01-19 | 华南理工大学 | 一种原位调控镍钛合金功能特性的4d打印方法及应用 |
| CN113235028B (zh) * | 2021-04-06 | 2022-06-14 | 华南理工大学 | 一种高马氏体相变温度的镍钛形状记忆合金的训练方法 |
| CN113308656B (zh) * | 2021-05-28 | 2022-05-03 | 中国石油大学(北京) | 增材制造超弹镍钛合金的后处理方法及其应用 |
| CN115233122A (zh) * | 2022-07-27 | 2022-10-25 | 天津大学 | 一种NiTi合金双程形状记忆效应的训练方法及其产品 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4283233A (en) * | 1980-03-07 | 1981-08-11 | The United States Of America As Represented By The Secretary Of The Navy | Method of modifying the transition temperature range of TiNi base shape memory alloys |
| JPS58151445A (ja) * | 1982-02-27 | 1983-09-08 | Tohoku Metal Ind Ltd | 可逆形状記憶効果を有するチタンニツケル合金およびその製造方法 |
| US4654092A (en) * | 1983-11-15 | 1987-03-31 | Raychem Corporation | Nickel-titanium-base shape-memory alloy composite structure |
| US4533411A (en) * | 1983-11-15 | 1985-08-06 | Raychem Corporation | Method of processing nickel-titanium-base shape-memory alloys and structure |
| US4770725A (en) * | 1984-11-06 | 1988-09-13 | Raychem Corporation | Nickel/titanium/niobium shape memory alloy & article |
| US4631094A (en) * | 1984-11-06 | 1986-12-23 | Raychem Corporation | Method of processing a nickel/titanium-based shape memory alloy and article produced therefrom |
| SU1431353A1 (ru) * | 1987-10-31 | 1995-06-09 | Московский авиационный технологический институт им.К.Э.Циолковского | Способ термической обработки сплавов на основе никелида титана |
| JPH09511281A (ja) * | 1994-03-31 | 1997-11-11 | エー． ベッセリンク，ペトルス | Ｎｉ−Ｔｉ−Ｎｂ合金の処理方法と該合金から作られた物品 |
| US5624508A (en) * | 1995-05-02 | 1997-04-29 | Flomenblit; Josef | Manufacture of a two-way shape memory alloy and device |
| US5882444A (en) * | 1995-05-02 | 1999-03-16 | Litana Ltd. | Manufacture of two-way shape memory devices |
| JP2899682B2 (ja) * | 1996-03-22 | 1999-06-02 | 科学技術庁金属材料技術研究所長 | Ｔｉ−Ｎｉ系形状記憶合金とその製造方法 |
| US5843244A (en) * | 1996-06-13 | 1998-12-01 | Nitinol Devices And Components | Shape memory alloy treatment |
| CN1170834A (zh) * | 1996-07-16 | 1998-01-21 | 中国科学院固体物理研究所 | 具有反常记忆效应钛镍弹簧及制备 |
| FR2758338B1 (fr) * | 1997-01-16 | 1999-04-09 | Memometal Ind | Procede de fabrication d'une piece superelastique en alliage de nickel et de titane |
| CN1084800C (zh) * | 1997-04-25 | 2002-05-15 | 利塔那有限公司 | 双程形状记忆合金及器件的制造方法 |
| AU742141B2 (en) * | 1997-04-25 | 2001-12-20 | Litana Ltd. | Manufacture of two-way shape memory devices |
| RU2201470C2 (ru) * | 1997-04-25 | 2003-03-27 | Литана Лтд. | Способ получения сплава с двойной памятью формы и способ изготовления устройств из этого сплава |
| US6106642A (en) * | 1998-02-19 | 2000-08-22 | Boston Scientific Limited | Process for the improved ductility of nitinol |
| US6149742A (en) * | 1998-05-26 | 2000-11-21 | Lockheed Martin Corporation | Process for conditioning shape memory alloys |
| JP3782289B2 (ja) * | 2000-07-06 | 2006-06-07 | トキコーポレーション株式会社 | 形状記憶合金の処理方法および形状記憶合金 |
| US6416564B1 (en) * | 2001-03-08 | 2002-07-09 | Ati Properties, Inc. | Method for producing large diameter ingots of nickel base alloys |
-
2003
- 2003-05-01 US US10/427,783 patent/US7192496B2/en not_active Expired - Fee Related
-
2004
- 2004-04-07 EP EP14184480.3A patent/EP2818565A1/en not_active Withdrawn
- 2004-04-07 KR KR1020057020630A patent/KR101048531B1/ko not_active Expired - Fee Related
- 2004-04-07 BR BRPI0409953-2A patent/BRPI0409953A/pt not_active Application Discontinuation
- 2004-04-07 WO PCT/US2004/010758 patent/WO2004099456A1/en not_active Ceased
- 2004-04-07 MX MXPA05011265A patent/MXPA05011265A/es active IP Right Grant
- 2004-04-07 RU RU2005137319/02A patent/RU2344196C2/ru not_active IP Right Cessation
- 2004-04-07 JP JP2006509794A patent/JP5535426B2/ja not_active Expired - Fee Related
- 2004-04-07 UA UAA200511376A patent/UA85384C2/ru unknown
- 2004-04-07 CN CN2004800117842A patent/CN1780924B/zh not_active Expired - Fee Related
- 2004-04-07 AU AU2004236647A patent/AU2004236647B2/en not_active Ceased
- 2004-04-07 EP EP04749864A patent/EP1623050A1/en not_active Withdrawn
- 2004-04-07 NZ NZ543066A patent/NZ543066A/xx not_active IP Right Cessation
- 2004-04-07 CA CA2522217A patent/CA2522217C/en not_active Expired - Fee Related
- 2004-04-30 TW TW093112375A patent/TWI295692B/zh active
-
2005
- 2005-10-11 IL IL171390A patent/IL171390A/en not_active IP Right Cessation
- 2005-12-01 NO NO20055684A patent/NO20055684L/no not_active Application Discontinuation
-
2006
- 2006-03-22 HK HK15102262.0A patent/HK1201891A1/en unknown
-
2007
- 2007-02-19 US US11/676,348 patent/US7628874B2/en not_active Expired - Fee Related
-
2010
- 2010-01-06 IL IL203162A patent/IL203162A/en not_active IP Right Cessation
- 2010-01-06 IL IL203166A patent/IL203166A/en not_active IP Right Cessation
-
2013
- 2013-07-12 JP JP2013146206A patent/JP2014015681A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU2004236647A1 (en) | 2004-11-18 |
| RU2344196C2 (ru) | 2009-01-20 |
| CA2522217C (en) | 2011-07-19 |
| CA2522217A1 (en) | 2004-11-18 |
| RU2005137319A (ru) | 2006-04-27 |
| US20040216816A1 (en) | 2004-11-04 |
| NZ543066A (en) | 2009-02-28 |
| UA85384C2 (ru) | 2009-01-26 |
| JP5535426B2 (ja) | 2014-07-02 |
| CN1780924B (zh) | 2010-12-15 |
| IL171390A (en) | 2011-03-31 |
| HK1089793A1 (en) | 2006-12-08 |
| US7192496B2 (en) | 2007-03-20 |
| HK1201891A1 (en) | 2015-09-11 |
| US20070163688A1 (en) | 2007-07-19 |
| JP2014015681A (ja) | 2014-01-30 |
| WO2004099456A1 (en) | 2004-11-18 |
| CN1780924A (zh) | 2006-05-31 |
| TW200513541A (en) | 2005-04-16 |
| AU2004236647B2 (en) | 2009-10-22 |
| JP2006525430A (ja) | 2006-11-09 |
| IL203166A0 (en) | 2011-08-01 |
| EP2818565A1 (en) | 2014-12-31 |
| MXPA05011265A (es) | 2006-01-24 |
| IL203162A (en) | 2011-09-27 |
| EP1623050A1 (en) | 2006-02-08 |
| IL203162A0 (en) | 2011-08-01 |
| KR20060004970A (ko) | 2006-01-16 |
| US7628874B2 (en) | 2009-12-08 |
| KR101048531B1 (ko) | 2011-07-11 |
| IL203166A (en) | 2011-09-27 |
| BRPI0409953A (pt) | 2006-04-25 |
| NO20055684L (no) | 2005-12-01 |
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