1282289 Δ7 Α7 Β7 五、發明説明（1 ) 【發明之技術領域】 本發明係關於具有優異之染色性，對皮膚或衣服等無 印疵之酸性染髮料。 【先行技術】 有關酸性染髮料之建議很多，係色素濃度低之浸透劑 或酸濃度低者，其主要目的作爲整髮料等之用，對皮膚或 衣服等之印疵少，但極度缺乏掩蓋白髮或使白髮不明顯之 染髮力，缺乏作爲染髮料之實效。反之色素濃度高之浸透 劑或酸濃度高者，作爲整髮料等之用，對皮膚之污染度高 ，使用後對皮膚或衣服等之印疵強烈，作爲理美容等進行 專業染髮之用，又，對於一般家庭所用之商品亦須小心使 用使其不弄髒皮膚或衣服，要求使用後殘留之染髮料務必 淸洗之商品。 【發明所欲解決之課題】 本發明係提供雖爲強酸性領域（Ρ Η 1 · 5〜4 · 0 )但穩定，富流動性，並使用觸感優，且使用後沒有附於 皮膚及衣服等印疵，不須沖洗，施以黏稠手段使用1次可 掩蓋白髮使其不明顯，使用4〜5次可將白髮染成不明顯 之酸性染髮料組成物。 【用以解決課題之手段】 解決此課題本發明們銳意檢討之結果，找出藉由均勻 (請先閲讀背面之注意事項再填寫本頁) 、1Τ 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） -4 - 1282289 A7 B7 五、發明説明（2 ) (請先閲讀背面之注意事項再填寫本頁) 混合「色素」、「芳香醇」、「低碳醇」、「增稠劑」、 「水」之必須成分作爲酸性染髮料，使用1次可掩蓋白髮 使其不明顯，使用4〜5次可將白髮染成不明顯，使用後 對皮膚或衣服等無印疵，不須沖洗實效高之酸性染髮料組 成物。 本發明酸性染髮料組成物，其特徵爲：將0 . 〇 1〜 1 %之1種或2種以上之酸性染髮料，0 · 0 1〜1 0 % 作爲p Η調整劑之酸，1〜2 0 %作爲浸透劑之芳香醇， 1〜2 0 %作爲溶劑之低碳醇，〇 · 〇 1〜5 %作爲增稠 劑之高分子化合物混合所成。 本發明之酸性染髮料組成物，除以上述爲主要成分以 外，按實際需要，含一般使用於紫外線吸收劑、抗氧化劑 、安定劑等此類領域之助劑，剩餘部分由水所構成。 【發明之實施形態】 經濟部智慧財產局員工消費合作社印製 本發明之酸性染料，得使用一般用於酸化染髮劑或酸 性染髮料之法定色素。以焦油系色素爲宜，例如紅色2號 、紅色1 0 2號、紅色1 〇 6號、紅色2 1 3號、紅色 2 1 5 5虎、紅色2 2 7號、紅色4 0 1號、紅色5〇4號 、黃色4號、黃色5號、黃色2 0 3號、黃色2 0 5號、 綠色3號、綠色2 0 4號、綠色2 0 5號、藍色1號、藍 色2〇3號、藍色403號、黑色40 1號、紫色40 1 號、橘色2 0 5號、褐色2 0 1號等。此類色素可1種或 2種以上合併使用。 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 1282289 A7 _ B7 ___ 五、發明説明（3 ) (請先閲讀背面之注意事項再填寫本頁) 酸性染料爲對染髮料全體量之0 · 0 1〜1重量％ ’ 若加至0 · 05〜0 · 5重量％之範圍爲宜。0 · 01% 以下染髮次數須達1 0次以上才能達到希望之顏色’ 1 % 以上很難染成喜歡的顏色。 作爲P Η調整劑之酸，可使用無機酸及有機酸之任一 項，但以使用有機酸爲宜。例如檸檬酸、琥珀酸 '、酒石酸 、乳酸、蘋果酸、富馬酸、馬來酸、乙醇酸等有機酸’鹽 酸、硫酸、磷酸、硝酸等無機酸。又，附與緩衝能等目的 ，亦得使用此類酸與此類酸之鈉鹽、鉀鹽、銨鹽之組合此 類酸之混合量，作爲染髮料之用時，染髮液爲Ρ Η 1 · 5 〜4 · 〇，以ρ Η 1 · 5〜3 · 5左右之強酸性爲宜加以 選擇、混合。 作爲浸透劑之芳香醇，除增進染髮料對頭髮之浸透外 ，附與染髮後使頭髮滑順、濕潤感及適度的保濕性而加以 使用。例如可使用苯甲醇、苯基乙醇等。以苯甲醇爲宜。 經濟部智慧財產局員工消費合作社印製 作爲溶劑之低碳醇，得混合一般整髮料等所用者。得 使用碳數1〜4直鏈或支鏈醇，例如甲醇、乙醇、1 —丙 醇、異丙醇、丁醇、乙二醇、1 ，3 -丁二醇等，以使用 乙醇爲宜。低碳醇之混合量，根據其他之混合成分而異， 對染髮料全體量之1〜2 0 %之範圍加以使用。丨％以τ 因作爲溶劑之機能小，得見髮液之混濁或分離，2 %以 上會降低染色時之作業性。 本發明之染髮料，爲防止使用時染髮液不必胃之^落； 及易於處理而使用增稠劑。例如阿拉伯樹膠、瓜耳：_、胃 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐) 7〇1 - 1282289 A7 B7 五、發明説明（4 ) (請先閱讀背面之注意事項再填寫本頁) 叉菜膠、褐藻酸、咕噸橡膠、甲基纖維素、C M C、陽離 子化澱粉天然高分子、聚（異）丙烯酸、聚（異）丙烯酸 酯、聚乙烯醇等合成高分子、聚乙烯乙二醇高級脂肪酸酯 等高級脂肪酸酯。以使用咕噸橡膠等爲宜。 本發明之染髮料組成物，按實際需要，得混合此領域 所使用之濕潤劑、防霉劑、抗氧化劑、紫外線吸收劑、香 料等。 本發明之染髮料之目的非以1次染髮即染成所期之髮 ’乃藉由間隔3〜5次以上之染髮，染成濕潤漸深之髮色 。爲此，即使重覆染髮數次亦不傷頭髮，也不會對健康等 有不良之影響。 在前次染髮經過3 0分鐘以上，以經過1〜7日（一 星期）以上再染髮爲宜，例如每隔3星期再進行下次染髮 。染髮前先洗髮爲宜。 【實施例】 以下根據實施例說明本發明，但本發明並非限於這些 經濟部智慧財產局員工消費合作社印製 例示。 製劑例 使用咕噸橡膠作爲增稠劑，乙酸醇作爲ρ Η調整劑， 苯甲醇作爲芳香醇，乙醇作爲低碳醇，使用混合下記表1 所示之各染料之混合酸性色素作爲酸性染料。 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） _ 7 _ 1282289 A7 B7 五、發明説明（5 ) 表1 酸性染料合比率（重量比) 茶褐色系 藍色系 黑色系 黑色401號 1部 25部 14部 紫外401號 1部 15部 14部 橙色205號 3部 10部 22部 分別將上述各成分以表2及表3所示之比例混合，加 上精製水成爲全體量1 0 0表示重量％。 於實施例1及2試驗經製成之各染髮料之染髮性。 實施例1 調查表2所示之組成之實施例1及比較例1〜3之染 髮性及處理性等。混合酸性色素係使用表1所載之黑色系 色素。又，比較例1爲咕噸橡膠多之組成物例，比較例2 爲苯甲醇多之例，比較例爲乙醇多之例。 比較例2及3係組成物本身混合性不良’染髮髮亦不 佳。以上記載實施例1及比較例1〜3之染髮性。 (請先閲讀背面之注意事項再填寫本頁) 1« 經濟部智慧財產局員工消費合作社印製 尺 張 紙 本 準 標 家 國 國 中 用 適 公 97 2 1282289 A7 B7 五、發明説明（6 ) 表2 組成 實施例1 比較例（％) (%) 1 2 3 咕噸橡膠 0.5 7.0 0.5 0.5 乙醇酸 2.0 2.0 2.0 2.0 混合酸性色素 0.1 0.1 0.1 0.1 苯甲醇 10.0 10.0 30.0 1.0 乙醇 12.5 10.5 12.5 22.5 精製水 74.9 70.4 54.9 73.9 *1 *2 *3 * 4 洗髮後之著色性 佳1 ) 劣2 ) 劣3 ) 劣4 } (請先閲讀背面之注意事項再填寫本頁) 1«1282289 Δ7 Α7 Β7 V. DESCRIPTION OF THE INVENTION (1) Technical Field of the Invention The present invention relates to an acid dyeing material which has excellent dyeability and is free from marks on skin or clothes. [Advance technology] There are many suggestions for acid dyeing materials, such as a penetrating agent with low pigment concentration or a low acid concentration. The main purpose is to use it as a hair styling material, etc., which has less marks on skin or clothes, but is extremely lacking in masking. White hair or hair dye that makes white hair inconspicuous, lacks the effectiveness as a hair dye. On the other hand, if the concentration of the penetrating agent or the acid having a high concentration of the pigment is high, it is used as a hair styling material, and the skin is highly contaminated. After use, it is strongly printed on the skin or clothing, and is used as a professional hair dye for beauty and beauty. In addition, the products used in general households must also be carefully used so that they do not stain the skin or clothing, and the products that are required to be washed after use are required to be washed. [Problems to be Solved by the Invention] The present invention provides stability, fluidity, and excellent touch feeling although it is in the field of strong acidity (Ρ Η 1 · 5 to 4 · 0 ), and is not attached to skin and clothes after use. Wait for the enamel, do not need to rinse, apply a sticky means to cover the white hair to make it not obvious, use 4~5 times to dye the white hair into an insignificant acidic hair dye composition. [Means for Solving the Problem] To solve this problem, the present invention is keen to review the results and find out that it is uniform (please read the note on the back and fill out this page), 1印 Printed by the Intellectual Property Office of the Ministry of Economic Affairs Paper scale applicable to Chinese National Standard (CNS) Α4 specification (210X297 mm) -4 - 1282289 A7 B7 V. Invention description (2) (Please read the note on the back and fill in this page) Mix "Pigment", "Aromatic alcohol The essential components of "lower alcohol", "thickener" and "water" are used as acid dyeing materials. It can be used to cover white hair to make it not obvious. It can be used to dye white hair in 4~5 times. After use, it is not printed on the skin or clothes, and it is not necessary to wash the acidic dyeing composition with high effect. The acidic hair dye composition of the present invention is characterized in that: 0. 〇1~1% of one or more kinds of acid dyeing materials, 0 · 0 1~1 0 % as p Η adjusting agent acid, 1~ 20% is an aromatic alcohol as a penetrating agent, and 1 to 20% is a mixture of a lower alcohol of a solvent, and a polymer compound of 〜·〇1 to 5% as a thickener. The acidic hair dye composition of the present invention comprises, in addition to the above-mentioned main components, an auxiliary agent generally used in such fields as ultraviolet absorbers, antioxidants, stabilizers, etc., and the remainder consisting of water. [Embodiment of the Invention] Printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs, the acid dye of the present invention is a legal dye generally used for acidifying hair dyes or acid hair dyes. It is advisable to use tar pigments, such as red No. 2, red No. 1 0 2, red 1 〇 6 , red 2 1 3, red 2 1 5 5 tiger, red 2 2 7 , red 4 0 1 , red 5〇4, yellow 4, yellow 5, yellow 2 0 3, yellow 2 0 5, green 3, green 2 0 4, green 2 0 5, blue 1 , blue 2〇 No. 3, Blue No. 403, Black No. 40 No. 1, Purple No. 40 1 , Orange No. 2 0 5, Brown No. 2 0, and so on. These pigments may be used alone or in combination of two or more. This paper scale is applicable to China National Standard (CNS) Α4 specification (210Χ297 mm) 1282289 A7 _ B7 ___ V. Invention description (3) (Please read the note on the back and fill in this page) Acid dye is the total amount of dyeing and dyeing 0 · 0 1~1 wt% ' If added to 0 · 05~0 · 5 wt% range is appropriate. 0 · 01% The number of hair dyes must be more than 10 times to achieve the desired color ‘ 1 % or more is difficult to dye the favorite color. As the acid of the P Η adjusting agent, any of an inorganic acid and an organic acid can be used, but an organic acid is preferably used. For example, organic acids such as citric acid, succinic acid, tartaric acid, lactic acid, malic acid, fumaric acid, maleic acid, glycolic acid, etc., mineral acids such as hydrochloric acid, sulfuric acid, phosphoric acid, and nitric acid. In addition, for the purpose of buffering energy, etc., it is also necessary to use a combination of such an acid with a sodium salt, a potassium salt or an ammonium salt of such an acid, and when used as a hair dye, the hair dye is Ρ Η 1 · 5 ～ 4 · 〇, with ρ Η 1 · 5~3 · 5 or so strong acidity should be selected and mixed. The aromatic alcohol as a penetrating agent is used in addition to enhancing the penetration of the hair dye into the hair, and the hair is smoothed, moist, and moderately moisturized after dyeing. For example, benzyl alcohol, phenylethanol or the like can be used. It is preferred to use benzyl alcohol. Printed by the Ministry of Economic Affairs, the Intellectual Property Office, and the Consumer Cooperatives. As a solvent, the lower alcohol, it is used to mix the general hair and other materials. It is preferred to use a linear or branched alcohol having 1 to 4 carbon atoms such as methanol, ethanol, 1-propanol, isopropanol, butanol, ethylene glycol, 1,3-butanediol or the like to use ethanol. The blending amount of the lower alcohol is different depending on the other mixed components, and is used in the range of 1 to 20% of the total amount of the dyed hair.丨% has a small function as a solvent for τ, and it is found that the turbidity or separation of the hair liquid is more than 2%, which lowers the workability at the time of dyeing. The hair dye of the present invention is used in order to prevent the hair dye from being used at the time of use; and to use a thickener for easy handling. For example, gum arabic, guar: _, stomach paper size applicable to China National Standard (CNS) Α 4 specifications (210X297 mm) 7〇1 - 1282289 A7 B7 V. Invention description (4) (Please read the note on the back first Fill in this page) Synthetic polymers such as fork rubber, alginic acid, xanthan rubber, methyl cellulose, CMC, cationized starch natural polymer, poly(iso)acrylic acid, poly(iso)acrylate, polyvinyl alcohol, etc. Higher fatty acid esters such as polyethylene glycol higher fatty acid esters. It is advisable to use xanthene rubber or the like. The hair dye composition of the present invention may be mixed with a wetting agent, an antifungal agent, an antioxidant, an ultraviolet absorber, a fragrance or the like used in the field as needed. The purpose of the hair dye of the present invention is that it is dyed into a desired hair by one dyeing, and is dyed into a moistening and deepening hair color by dyeing hair at intervals of 3 to 5 times. For this reason, even if it is dyed several times without damaging the hair, it will not adversely affect health. After the previous dyeing for more than 30 minutes, it is advisable to dye the hair after 1 to 7 days (one week) or more, for example, every 3 weeks. It is advisable to shampoo before dyeing. [Examples] Hereinafter, the present invention will be described based on examples, but the present invention is not limited to the printing examples of the Intellectual Property Office employee consumption cooperatives of the Ministry of Economic Affairs. Formulation Example Using xanthan rubber as a thickener, acetic alcohol as a ρ Η adjuster, benzyl alcohol as an aromatic alcohol, and ethanol as a lower alcohol, a mixed acid dye of each dye shown in Table 1 below was used as an acid dye. This paper size is applicable to China National Standard (CNS) Α4 specification (210X297 mm) _ 7 _ 1282289 A7 B7 V. Invention description (5 ) Table 1 Acid dye combination ratio (weight ratio) Tea brown blue black black 401 1 part, 25 parts, 14 parts of ultraviolet 401, 1 part, 15 parts, 14 parts of orange, 205, 3 parts, 10 parts, 22 parts, and the above components are mixed in the ratios shown in Table 2 and Table 3, and the purified water is added to the total amount of 1 0. 0 represents weight %. The dyeing properties of each of the dyed hairs prepared in the tests of Examples 1 and 2 were tested. Example 1 The dyeing properties and handling properties of Example 1 and Comparative Examples 1 to 3 of the composition shown in Table 2 were investigated. The black pigment contained in Table 1 was used as the mixed acid dye. Further, Comparative Example 1 is an example of a composition of a lot of xanthan rubber, Comparative Example 2 is an example of a large amount of benzyl alcohol, and Comparative Example 2 is an example of a large amount of ethanol. In Comparative Examples 2 and 3, the composition itself was poorly mixed, and hair dyeing was also poor. The hair dyeing properties of Example 1 and Comparative Examples 1 to 3 are described above. (Please read the notes on the back and fill out this page) 1« Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumers Cooperatives, Printed Ruler, Paper, Standard, National, and China. 97 2 1282289 A7 B7 V. Inventions (6) 2 Composition Example 1 Comparative Example (%) (%) 1 2 3 xanthenium rubber 0.5 7.0 0.5 0.5 Glycolic acid 2.0 2.0 2.0 2.0 Mixed acid dye 0.1 0.1 0.1 0.1 Benzyl alcohol 10.0 10.0 30.0 1.0 Ethanol 12.5 10.5 12.5 22.5 Refined water 74.9 70.4 54.9 73.9 *1 *2 *3 * 4 Good coloring after shampooing 1) Bad 2) Bad 3) Bad 4 } (Please read the notes on the back and fill out this page) 1«
、1T 1·染髮性 * 1 :塗佈1 0分鐘後變乾，即使塗擦亦不沾手，白髮 亦均勻染黑，不濕黏，光滑的觸感，極佳。 * 2 :黏性高，易塗佈，白髮染黑，但經過3 0分鐘後 亦不會變乾而產生再次污染。 * 3 :髮液分離成2層，搖動後塗於白髮，因髮液易流 動造成使用上之不便，又，塗佈後白髮雖變黑，但經過 3 0分鐘後亦呈濕潤狀態，而產生髒污。 * 4 :塗佈後白髮染黑但不明顯，經過3 〇分鐘後亦濕 黏，色素再附著，乾燥後色素再附著。 2.洗髮後之著色性 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） _ g _ 線·· 經濟部智慧財產局員工消費合作社印製 1282289 A7 B7 五、發明説明（7 ) 1 )用市售洗髮精洗髮後，不掉色，白髮均勻地染黑 〇 2 )用洗髮精洗髮後，因洗髮部份發現部分掉色，白 髮的一部分呈淡黑色，但整體上是白髮明顯。 3 )用洗髮精洗髮後，若觀察白髮部分，部分性染黑 ’但亦可發明未染之部分，白髮明顯。 4 )用洗髮精洗髮後，若觀察白髮部分，因洗髮幾乎 掉色，白髮明顯，看不到色素之著色性。 ① 適用性：以有整頭白髮之男性爲被試驗者，用梳子 將實施例1之髮液全體塗佈於左側頭部。將比較例1之髮 液同量塗佈於右側頭部。 其結果，實施例1，髮液易擴散，可整體均勻地掩蓋 白髮，但比較例1時很難將髮液整體均勻地擴散，不易將 白髮整體掩蓋。 ② 再附著性：染髮後立即將手掌貼於實施例1及比較 例1之各塗佈部時，兩者皆因染料弄髒手掌，但較之比較 例1，實施例1之髒污輕微。 塗佈經過1 0分鐘後，用手掌擦拭兩塗佈部時，比較 例1有黏稠感，染料相當附著於手掌，實施例1中，完全 乾燥狀態手掌無髒污，再用白布強力擦拭確認白布無髒污 〇 ③ 毛髮著色性：之後，使用市售精髮精洗髮，乾燥後 ’觀察頭部兩側染髮狀態之結果，比較例1使用部之白髮 依舊’觀察白髮狀態，實施例1使用部之白髮幾乎不存在 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） _ 1〇 · (請先閲讀背面之注意事項再填寫本頁) 1$·, 1T 1 · Hair dyeing * 1 : After drying for 10 minutes, it will dry out, even if it is rubbed, it will not touch your hands, and the white hair will be evenly blackened, not wet and sticky, and smooth touch is excellent. * 2 : High viscosity, easy to apply, white hair black, but after 30 minutes, it will not dry out and cause re-contamination. * 3: The hair solution is separated into 2 layers, and it is applied to the white hair after shaking. The hair is easy to flow and causes inconvenience in use. Moreover, the white hair becomes dark after coating, but it is also wet after 30 minutes. It is dirty. * 4: After application, the white hair is black but not obvious. After 3 minutes, it is also wet and sticky. The pigment reattaches and the pigment reattaches after drying. 2. Coloring after shampooing This paper scale applies to China National Standard (CNS) A4 specification (210X297 mm) _ g _ Line·· Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 1282289 A7 B7 V. Invention description (7 1) After shampooing with commercially available shampoo, it does not fade, white hair evenly stains black 〇 2) After shampooing, some of the shampoo is found to be partially faded, and part of the white hair is light black. But on the whole it is white invention. 3) After shampooing, if the white hair part is observed, it is partially blackened, but the unstained part can also be invented. 4) After shampooing, if the white hair part is observed, the shampoo is almost fading, and the white invention is obvious, and the coloring of the pigment is not observed. 1 Applicability: A male having a white hair was used as a test subject, and the entire hair solution of Example 1 was applied to the left head portion with a comb. The hair solution of Comparative Example 1 was applied to the right head portion in the same amount. As a result, in Example 1, the hair liquid was easily diffused, and the white hair was uniformly covered as a whole. However, in Comparative Example 1, it was difficult to uniformly spread the entire hair liquid, and it was difficult to cover the entire white hair. 2 Reattachability: When the palms were attached to the respective coated portions of Example 1 and Comparative Example 1 immediately after dyeing, both of them were stained with the dye by the dye, but the stain of Example 1 was slightly milder than Comparative Example 1. After 10 minutes of application, when the two coated portions were wiped with the palm of the hand, Comparative Example 1 had a sticky feeling, and the dye adhered to the palm of the hand. In Example 1, the palm was completely free of dirt, and the white cloth was strongly wiped to confirm the white cloth. No staining 3 Hair coloring property: After that, the hair was shampooed using a commercially available hair essence, and after drying, the results of the hair dyeing state on both sides of the head were observed, and the white hair of the portion used in Comparative Example 1 was observed to observe the white hair state. 1The white hair of the use part is almost non-existent. The paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) _ 1〇· (Please read the back note and fill out this page) 1$·
、1T 經濟部智慧財產局員工消費合作社印製 1282289 A7 B7 五、發明説明（8 ) ，呈現白髮染黑之狀態。 (請先閲讀背面之注意事項再填寫本頁) 之後’用市售髮油護髮，每2天1次，反覆洗3次頭 髮，但染髮部分無掉色，使用實施例丨之白髮部分，較之 使用比較例1之部分，全體白髮不明顯。 根據本發明之酸性染髮料，染髮後短短1 〇分鐘左右 變乾’並無產生染料對手掌或衣服之髒污，得於該狀態保 持整髮狀態，又洗髮後再染髮，即使多次洗髮亦可完全達 到染髮效果’使用酸性染髮料時通常爲染髮後放置3 〇〜 4 0分，無之後洗淨之類之不便，塗佈本發明品，於此狀 態僅梳整髮型即可達染髮效果。 實施例2 試驗表3所示之組成之實施例2及比較例4之染髮性 ’及試驗比較例5及6。混合酸性色素係使用表1所載之 茶褐色系色素。 比較例4爲表示水多之例，比較例6爲乙醇少，水多 之例示’兩者中任一項之混合液因不穩定其結果係染髮性 經濟部智慧財產局員工消費合作社印製 不佳。 -11 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210x297公釐） 1282289 A7 B7 五、發明説明（9 ) 表3 組成 實施例2 比較例（％) (%) 4 5 」 6 咕噸橡膠 0.3 0.3 0.5 0.5 乙醇酸 2.0 2.0 2.0 2.0 混合酸性色素 0.2 0.2 0.2 0.2 苯甲醇 10.0 0.5 30.0 12.0 乙醇 15.0 15.5 2.5 0.5 精製水 72.5 81.5 64.8 84.3 染髮性 *5 *6 * η *8 洗髮後之著色性 佳5) 劣6) 劣7) 一劣8) (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 3.染髮性 * 5 :塗佈1 0分鐘後變乾，即使塗擦亦不沾手，白髮 亦均勻染成茶褐色，不濕黏，光滑的觸感，白髮亦不明顯 效果極佳。 * 6 :塗佈後，白髮部分變成茶褐色，白髮不再明顯， 經過3 0分鐘後亦不會變乾’色素再附著，乾燥後色素再 附著。 * 7 :髮液分離成2層，搖動後塗於白髮，爲使白髮不 明顯須經數次搖動，因塗佈次數變多造成不便，但經過 3 0分鐘後亦呈濕潤狀態，而產生髒污。 * 8 :髮液呈分離狀態，塗佈後白髮染成茶褐色不明顯 ，經過3 0分鐘後亦濕黏’色素再附著，乾燥後色素再附 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） _ _ 1282289 A7 B7 _乂 五、發明説明（10) 著。 2 ·洗髮後之著色性 5 )用市售洗髮精洗髮後，不掉色，白髮均勻染成茶 褐色。 6 )用洗髮精洗髮後，白髮被染上薄薄的茶褐色，因 洗髮有掉色，整體上是白髮明顯。 7 )用洗髮精洗髮後，若觀察白髮部分，部分性染成 茶褐色，看到染色不均。 8 )用洗髮精洗髮後，若觀察白髮部分，因洗髮幾乎 掉色，白髮明顯，看不到色素之著色性。 ① 適用性：與實施例相同以白髮交織之女性爲對象， 將實施例2與比較例4分別塗佈於左側、右側。 其結果，實施例2，髮液易擴散，可整體均勻地掩蓋 白髮，但比較例4時看到苯甲醇之分離，很難將髮液整體 均句地擴散，無法將白髮整體掩蓋。 ② 再附著性：染髮後立即將手掌貼於實施例2及比較 例4之各塗佈部時，兩者皆因染料弄髒手掌，但較之比較 例4，實施例1之髒污輕微。 塗佈經過1 0分鐘後，用手掌擦拭兩塗佈部時，比較 例有黏稠感，染料相當附著於手掌，實施例中，完全乾燥 狀態手掌無髒污，再用白布強力擦拭確認白布無髒污。 ③ 毛髮著色性：之後，使用市售精髮精洗髮，乾燥後 ，觀察頭部兩側染髮狀態之結果，比較例4使用部部分性 本紙張尺度適用中國國家標準（CNS ) A4規格（210><297公釐） :13 _ "~~ (請先閲讀背面之注意事項再填寫本頁) 1^.1T Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 1282289 A7 B7 V. Invention description (8), showing the state of white hair black. (Please read the precautions on the back and then fill out this page.) Then 'Use commercial hair oil hair care, once every 2 days, wash the hair 3 times, but the hair dyed parts are not faded, use the white hair part of the example, Compared with the part using Comparative Example 1, all white hair was not obvious. According to the acidic hair dye of the present invention, it is dried in about 1 minute after dyeing, and there is no stain on the palm or clothes of the dye. It is maintained in the state of hair, and then dyed after shampooing, even if it is repeated. Shampoo can also fully achieve the hair dyeing effect. When using acid dyeing hair, it is usually placed after dyeing for 3 〇 to 40 minutes. After washing without any inconvenience, the present invention can be applied. In this state, only the hair style can be combed. Achieve the dyeing effect. Example 2 The hair dyes of Examples 2 and 4 of the compositions shown in Table 3 and Test Comparative Examples 5 and 6 were tested. For the mixed acid coloring matter, the brownish-brown coloring matter shown in Table 1 was used. Comparative Example 4 is an example of water, Comparative Example 6 is less ethanol, and water is exemplified. 'The mixture of either of them is unstable. The result is that the Department of Hair Coloring, Intellectual Property Bureau, Staff Consumer Cooperative, does not print. good. -11 - This paper size is applicable to China National Standard (CNS) A4 specification (210x297 mm) 1282289 A7 B7 V. Invention description (9) Table 3 Composition example 2 Comparative example (%) (%) 4 5 ” 6 咕Rubber 0.3 0.3 0.5 0.5 Glycolic acid 2.0 2.0 2.0 2.0 Mixed acid pigment 0.2 0.2 0.2 0.2 Benzyl alcohol 10.0 0.5 30.0 12.0 Ethanol 15.0 15.5 2.5 0.5 Refined water 72.5 81.5 64.8 84.3 Hair coloring *5 *6 * η *8 Coloring after shampooing Goodness 5) Inferior 6) Inferior 7) Inferior 8) (Please read the notes on the back and fill out this page) Printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs 3. Hair Color* 5: After 10 minutes of coating Dry, even if it is rubbed, it will not touch your hands, and the white hair will be evenly dyed into brownish brown, not wet and sticky, smooth touch, and the white hair is not obvious. * 6 : After application, the white hair part becomes brownish brown, the white hair is no longer obvious, and it will not dry after 30 minutes. The pigment reattaches and the pigment reattaches after drying. * 7 : The hair is separated into 2 layers, and then applied to the white hair after shaking. In order to make the white hair not obvious, it has to be shaken several times, which is inconvenient due to the increased number of coatings, but it is also wet after 30 minutes. Produce dirt. * 8 : The hair is in a separated state. After the application, the white hair is dyed into brownish brown. It is not wet after 30 minutes. The pigment is reattached after 30 minutes. After drying, the pigment is attached to the paper. The Chinese National Standard (CNS) A4 specification is applicable. (210X297 mm) _ _ 1282289 A7 B7 _ 乂 five, invention description (10). 2 · Coloring after shampooing 5) After shampooing with commercially available shampoo, it does not fade, and white hair is evenly dyed into tea brown. 6) After shampooing, the white hair is dyed with a thin brownish brown color, which is faded due to shampooing. 7) After shampooing, if the white hair part is observed, it is partially dyed into brownish brown and uneven dyeing is observed. 8) After shampooing, if the white hair part is observed, the shampoo is almost fading, and the white color is invented, and the coloring of the pigment is not observed. 1 Applicability: Example 2 and Comparative Example 4 were applied to the left side and the right side, respectively, in the same manner as in the examples. As a result, in Example 2, the hair liquid was easily diffused, and the white hair was uniformly masked as a whole. However, in Comparative Example 4, the separation of benzyl alcohol was observed, and it was difficult to spread the hair liquid as a whole, and the entire white hair could not be covered. 2 Reattachability: When the palms were attached to the respective coated portions of Example 2 and Comparative Example 4 immediately after dyeing, both of them were stained with the dye by the dye, but the stain of Example 1 was slightly milder than Comparative Example 4. After 10 minutes of coating, when the two coated portions were wiped with the palm of the hand, the comparative example had a sticky feeling, and the dye adhered to the palm of the hand. In the example, the palm was completely free of dirt in the dry state, and then the white cloth was strongly wiped to confirm that the white cloth was not dirty. Sewage. 3 Hair coloring: Afterwards, using commercially available hair essence shampoo, after drying, observe the results of hair dyeing on both sides of the head. Comparative Example 4 uses the partial national paper scale to apply the Chinese National Standard (CNS) A4 specification (210> ;<297 mm) :13 _ "~~ (Please read the notes on the back and fill out this page) 1^.
、1T 經濟部智慧財產局員工消費合作社印製 1282289 A7 _ B7 五、發明説明（11 ) 看不見白髮，但整體上是白髮明顯，經觀察爲白髮狀態， 實施例1使用部之白髮幾乎不存在，呈現白髮染黑之狀態 〇 根據與實施例1結果相同之實施例2之本發明之酸性 染髮料，染髮後短時間變乾，並無因染料對手掌或衣服之 髒污，得於該狀態保持整髮狀態，又洗髮後再染髮，即使 多次洗髮亦可完全達到染髮效果。 ④再染髮性：對於依上述已染髮之女性，每隔3週反 覆染髮時，並無先前之染色部與之後之染色部之區別，可 染成均勻的髮色，又，多染數次可染成深沉的髮色，即使 反覆使用，亦無僵硬感（硬髮化），亦不損傷毛髮，平滑 的觸感，爲易整髮之毛髮狀態。 本發明染髮料組成物由上述各實施例、比較例之結果 ，認定： 苯甲醇與乙醇之組成比爲1 : 〇 · 2 5〜4 · 0 ，以1 : 1 · 2 5〜1 · 5爲宜，且苯甲醇·乙醇之混合液與水之 組成比爲1 ·· 2 · 3〜4 1 ，以1 ·· 2 · 9〜3 · 4之範 圍爲宜，苯甲醇無分離，染料之吸附性，塗佈時之使用感 亦良好。 本發明之組成範圍 適當範圍 (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 酸性色素 0 . 0 1 〜1 % 0 · 05 〜0 · 5% 酸 0 · 1 〜1 0 % 1 · 0 〜5 · 0 % 芳香醇 1 · 0〜20% 5 · 0〜15 · 0% 低碳醇 1 · 0 〜2 0 % 10 · 0〜15 · 0% 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇 X 297公釐） · 14 - 1282289 A7 B7 五、發明説明（12) 高分子化合物0 · 0 1〜5 % 0 · 3〜1 · 〇 % 精製水 44.0〜97.88% 5 9 .5 〜74.45 % 【發明之效果】 本發明酸性染髮料組成物，係爲單液性故易於使用， 因具有適度之黏性，乾燥性亦佳故使用時不致弄髒衣服等 多項優點。又，本發明染髮料之組成，因色素不限於黑色 、茶褐色等寒色系，亦可使用任意色系之色素，不僅是適 用於高齡者之白髮染黑，亦適用於染成配合年輕人流行之 髮色。 (請先閲讀背面之注意事項再填寫本頁) 丁 k 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）1T Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1282289 A7 _ B7 V. Invention description (11) Can not see white hair, but overall it is white invention, observed as white hair state, the use of white in the embodiment 1 The hair is almost absent, and the white hair is blackened. According to the acidic hair dye of the present invention of Example 2 which is the same as the result of Example 1, it is dried shortly after dyeing, and there is no stain on the palm or clothes of the dye. It is necessary to maintain the hair styling state in this state, and then dye the hair after shampooing, even if the hair is shampooed multiple times, the hair dyeing effect can be fully achieved. 4 re-dyeing: For women who have been dyed according to the above, every 3 weeks of repeated dyeing, there is no difference between the previous dyeing department and the subsequent dyeing department, can be dyed into uniform hair color, and more than several times. Dyed into a deep hair color, even if used repeatedly, there is no stiffness (hard hair), no damage to the hair, smooth touch, easy to hair. The hair dye composition of the present invention is determined from the results of the above respective examples and comparative examples: the composition ratio of benzyl alcohol to ethanol is 1: 〇· 2 5~4 · 0 , with 1: 1 · 2 5 to 1 · 5 Preferably, the composition ratio of the mixture of benzyl alcohol and ethanol to water is 1 ·· 2 · 3~4 1 , preferably in the range of 1 ·· 2 · 9~3 · 4 , no separation of benzyl alcohol, adsorption of dye Sexuality, and the feeling of use during coating is also good. The scope of the composition of the present invention is appropriate (please read the notes on the back and fill out this page). The Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, prints acid pigments. 0 1 ~1 % 0 · 05 〜0 · 5% Acid 0 · 1 ～1 0 % 1 · 0 〜5 · 0 % Aromatic alcohol 1 · 0~20% 5 · 0~15 · 0% Lower alcohol 1 · 0 〜2 0 % 10 · 0~15 · 0% Paper The scale applies to the Chinese National Standard (CNS) A4 specification (21〇X 297 mm) · 14 - 1282289 A7 B7 V. Description of invention (12) Polymer compound 0 · 0 1~5 % 0 · 3~1 · 〇% Refined Water 44.0~97.88% 5 9 .5 to 74.45 % [Effect of the Invention] The acidic hair dye composition of the present invention is easy to use because of its single liquid property, and has good viscosity and good drying property, so that it does not cause use when used. Dirty clothes and many other advantages. Moreover, the composition of the hair dye of the present invention is not limited to a cool color such as black or brown, and a pigment of any color can be used, which is not only suitable for white hair dyeing of the elderly, but also suitable for dyeing into young people. Hair color. (Please read the notes on the back and fill out this page.) D. k Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperative Printed This paper scale applies to China National Standard (CNS) A4 specification (210X297 mm)