CN107997986A - A kind of acidic hair coloring preparation and its hair colouring methods - Google Patents
A kind of acidic hair coloring preparation and its hair colouring methods Download PDFInfo
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- CN107997986A CN107997986A CN201711290812.4A CN201711290812A CN107997986A CN 107997986 A CN107997986 A CN 107997986A CN 201711290812 A CN201711290812 A CN 201711290812A CN 107997986 A CN107997986 A CN 107997986A
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- acid
- hair coloring
- coloring preparation
- acidic hair
- heating
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
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- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
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- Veterinary Medicine (AREA)
- Birds (AREA)
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- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of acidic hair coloring preparation, in percentage by weight, including following components：0.5 3wt% of cellulose thickener；5 15wt% of cyclic ketone；5 15wt% of aromatic alcohols；0.01 1wt% of acid dyes；0 1.5wt% of pH adjusting agent；0 2wt% of additive；Surplus is water.The acidic hair coloring preparation of the present invention has the advantages that quickly painting, colouring property is good, Washing is high, non-stimulated to scalp.The invention also discloses the painting methods of above-mentioned hair dye, which has the characteristics that colouring is fast, colouring property is good, Washing is high, does not stimulate scalp.
Description
Technical field
The present invention relates to biological technical field, more particularly to a kind of acidic hair coloring preparation and its hair colouring methods.
Background technology
Acidic hair coloring preparation is usually one-pack type product, generally the higher cream shape of viscosity, by paste extrusion during use, directly
Connect and be applied on hair, smearing can uniformly paint.As a kind of semipermanent hair dye, compared with oxidative hair dyes, do not have
Hydrogen peroxide is added, is only deposited on hair surface, much smaller relative to oxidative coloration of hair agent toxicity, the damage to hair is also opposite
Smaller, as the product of the cream kind of one-pack type, the characteristics of it need not be used in mixed way, has been also convenient for consumer's use.But acidity dye
The shortcomings of upper aberration for having of hair agent, fixation is bad, and washing is easily faded, it is necessary to use could repeatedly cause hair maintenance one compared with
Good colouring effect, this is greatly restricted its application so that consumer can still be inclined to oxidized form dye when selecting hair dyeing product
Send out agent.
Existing semipermanent acidic hair coloring preparation, it is more use xanthans thickening and with the short chain fatty alcohol such as ethanol as solvent,
Colouring property and Washing are general；A part of existing acidic hair coloring preparation good hair dyeing effect in order to obtain, its hair dye
PH value is adjusted to less than 3.0 even lower 2.5, so can bring excitement to the scalp of user.
The content of the invention
It is an object of the invention to overcome above technological deficiency, there is provided a kind of acidic hair coloring preparation, acidic hair coloring preparation tool
The advantages that having quickly to paint, and colouring property is good, Washing is high, non-stimulated to scalp.
Another object of the present invention is to provide the preparation method of the acidic hair coloring preparation.
A further object of the present invention is the hair colouring methods for providing the acidic hair coloring preparation.
Present invention is achieved through the following technical solutions：
A kind of acidic hair coloring preparation, in percentage by weight, including following components：
Cellulose thickener 0.5-3wt%；
Cyclic ketone 5-15wt%；
Aromatic alcohols 5-15wt%；
Acid dyes 0.01-1wt%；
PH adjusting agent 0-1.5wt%；
Additive 0-2wt%；
Surplus is water.
Wherein, the acidic hair coloring preparation pH scopes are 3.0-4.0；It is preferred that pH scopes are 3.0-3.5.
Wherein, it is fine to be selected from methylcellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl for the fibre bundle class thickener
Tie up at least one of materials such as element, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose.
Wherein, the cyclic ketone is selected from n-methyl-2-pyrrolidone, N- ethyl-2-pyrrolidones, N- propyl group -2- pyrroles
At least one of materials such as pyrrolidone, N- butyl -2-Pyrrolidone, n-cyclohexyl-2-pyrrolidone.
Wherein, the aromatic alcohols is selected from least one of materials such as phenmethylol, benzyl carbinol, phenoxetol.
Wherein, the acid dyes is selected from《Cosmetics safety technical specification》The acid that can be used in hair dye of defined
At least one of property dyestuff；Described《Cosmetics safety technical specification》The acid dyes that can be used in hair dye of defined
Selected from Indian yellow 1, acid orange 7, acid orange 10, azogeramine 55, Indian yellow 121, acid red 18 0, azogeramine 63, acid blue 6,
Acid green 9, acid green 22, acid red 52, acid red 50, Indian yellow 73, acid orange 11, acid red 87, acid blue 80, acid
At least one of materials such as property indigo plant 62, acid violet 50, acid red 95, acid red 92.
Wherein, pH adjusting agent is selected from hydrochloric acid, sulfuric acid, citric acid, glycolic, malic acid, lactic acid, careless stone acid, formic acid, acetyl
Propionic acid, sodium hydroxide, potassium hydroxide, monoethanolamine, triethanolamine, aminomethyl propanol, isopropylamine, 1,3- propane diamine, 1,2- third
In the materials such as diamines, tripropyl amine (TPA), butylamine, isobutyl amine, tert-butylamine, hexylamine, octylame, aniline, benzylamine, cyclohexylamine, pyridine at least
It is a kind of.
Wherein, the additive is selected from ultra-violet absorber, antioxidant, stabilizer, chelating agent, essence, plant and carries
Take at least one of materials such as thing.
The hair colouring methods of acidic hair coloring preparation of the present invention：Heated in hair dye, heating-up temperature is 30 DEG C -50
DEG C, heating time 10min-60min；It is preferred that heating-up temperature is 35 DEG C -50 DEG C, heating time 10-30min；Described adds
Hot mode includes at least one of heating cap heating, heat gun, the heating of hot towel.
The hair dye is painted at 30-50 DEG C, can quickly be painted, and colouring effect is good and Washing can also carry
It is high.
The preparation method of acidic hair coloring preparation of the present invention, specifically comprises the following steps：
A phases：Cellulose thickener, aromatic alcohols add beaker, and stir.
B phases：Water, acid dyes, the acid for adjusting pH, the alkali mixing for adjusting pH, dissolving is complete.
B is added in A phases, stirs 5-10min, cyclic ketone is added and continues to stir, discharge after 10min.
The hair colouring methods of acidic hair coloring preparation of the present invention, include the following steps：
Determine the amount of dye cream and dye cream be expressed into hair dyeing container to stir evenly according to the number of hairs of dye originator first, then
Dye cream is uniformly applied on hair, is covered with film after the completion of all smearing, is then heated with heating means.Its
Middle heating-up temperature is 30 DEG C -50 DEG C, heating time 10min-60min；It is preferred that heating-up temperature is 35 DEG C -50 DEG C, heating time
For 10-30min；The mode of heating includes at least one of heating cap heating, heat gun, the heating of hot towel.
The acidic hair coloring preparation of the present invention has the advantages that：
The present invention acidic hair coloring preparation, make solvent using cellulose thickener and with cyclic ketone, have colouring property it is good, washing color
The characteristics of fastness is high；PH value range is optimized in the present invention, further increases colouring property and Washing, also,
For pH in the gentle scope of 3.0-4.0, incorrect skin has stimulation；Hair colouring methods present invention is alternatively directed to the hair dye are changed
Into making the acidic hair coloring preparation colouring property of the present invention and Washing good, and proper temperature, time are short, the stimulation to scalp
It is minimum.
Embodiment
The present invention is further illustrated below by embodiment, and following embodiments are the preferable embodiment party of the present invention
Formula, but embodiments of the present invention and from the limitation of following embodiments.
Following raw material is raw materials used for the present invention, but to realize that the object of the invention is not limited to following raw material：
The preparation method of the acidic hair coloring preparation of embodiment 1-11 and comparative example 1-8：
A phases：Thickener（Cellulose thickener or xanthans）, aromatic alcohols add beaker, and stir.
B phases：Water, acid dyes, the acid for adjusting pH, the alkali mixing for adjusting pH, dissolving is complete.
B is added in A phases, stirs 5-10min, adds organic solvent（Cyclic ketone, ethanol or ethoxydiglycol）Continue
Stir, discharge after 10min.
The painting methods of the acidic hair coloring preparation of embodiment and comparative example：
It is 10cm to take length, and weight is the white topknot of 0.5g or so, takes 5g dye cream to be uniformly applied on topknot, after the completion of smearing
Design temperature simultaneously starts timing, and drying is cleaned after setting time.
Each method of evaluating performance：
（1）Colouring property：
The topknot after the completion of dyeing is taken, is contrasted with undyed white topknot and natural black topknot, and it is deep according to color
It is shallow to give a mark；1-5 points, marking is higher, represents that colouring is more obvious.
（2）Washing：
After hair colouring, water rinses 1min, washes 5min with no silicone oil shampoo, 1min is rushed with water, dry up, repeat the method,
Wash 5 times, and contrasted with the hair of unused hair washing washing before altogether, and give a mark according to this；1-5 points, marking is higher, represents water-fast
It is better to wash degree.
（3）Irritation evaluation method：
Hair dyeing is carried out on head, so the evaluation most correct method of hair dyeing product irritation is to make subject real on scalp
Border uses and is evaluated；
Test zone is：The 3cm*3cm regions of scalp side；
Test environment is：25 DEG C, humidity 50-55%, the sebum of experiment position is removed before experiment with wet towel, is adapted to 10 minutes
Afterwards, then tested；
Test method：A 3cm*3cm region is chosen in subject's scalp side, takes 2g hair dyeing products to be uniformly applied to region
In, testing time 30min.Test after side, identical test is carried out once again in scalp opposite side；
Subject is allowed to be scored according to the irritation of benchmark as shown in the table to hair dyeing product, average twice is recorded as piercing
Swash degree.
Table 1：The proportioning of embodiment 1-6 acidic hair coloring preparations（Percentage by weight）And the performance test results
Dye composite is described in upper table：0.10% acid violet 43,0.25% acid black 1 and 0.15% acid orange 7.
The proportioning of 2 comparative example 1-5 acidic hair coloring preparations of table（Percentage by weight）And the performance test results
Dye composite is described in upper table：0.10% acid violet 43,0.25% acid black 1 and 0.15% acid orange 7.
Table 3：The proportioning of embodiment 7-11 comparative example 6-8 acidic hair coloring preparations（Percentage by weight）And the performance test results
Dye composite is described in upper table：0.10% acid violet 43,0.25% acid black 1 and 0.15% acid orange 7.
As can be seen from Table 1 and Table 2, using cellulose thickener, Washing is better than traditional xanthans-second
The acidic hair coloring preparation of alcohol system；From embodiment 4, comparative example 3 and comparative example 4 as can be seen that doing solvent, colouring property using cyclic ketone
And Washing will be substantially better than common ethanol（Lower alcohol）Or ethoxydiglycol（Polyalcohol）Do the comparative example of solvent；
From embodiment 3-6 and comparative example 2 as can be seen that pH scopes are in 3.0-4.0, colouring property and Washing are preferable, pH scopes
In 3.0-3.5, colouring property and Washing are best；From comparative example 1 as can be seen that when pH is 2.5, to scalp during hair dyeing
There is obvious stimulation.
From table 3 and embodiment 4 as can be seen that heating-up temperature is 35 DEG C -50 DEG C, heating time is when being 10-30min, colouring
Property and Washing are good, non-stimulated to scalp；From comparative example 8 as can be seen that when temperature it is excessive, when reaching 60 DEG C, to scalp
There is obvious stimulation.
Claims (9)
- A kind of 1. acidic hair coloring preparation, it is characterised in that in percentage by weight, including following components：Cellulose thickener 0.5-3wt%；Cyclic ketone 5-15wt%；Aromatic alcohols 5-15wt%；Acid dyes 0.01-1wt%；PH adjusting agent 0-1.5wt%；Additive 0-2wt%；Surplus is water.
- 2. acidic hair coloring preparation according to claim 1, it is characterised in that the acidic hair coloring preparation pH scopes are 3.0- 4.0；It is preferred that pH scopes are 3.0-3.5.
- 3. acidic hair coloring preparation according to claim 1, it is characterised in that it is fine that the fibre bundle class thickener is selected from methyl Tie up element, hydroxypropyl methyl cellulose, hydroxyethylmethylcellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose Deng at least one of material.
- 4. acidic hair coloring preparation according to claim 1, it is characterised in that the cyclic ketone is selected from N- methyl -2- pyrroles Alkanone, N- ethyl-2-pyrrolidones, N- propyl group -2-Pyrrolidone, N- butyl -2-Pyrrolidone, N- cyclohexyl -2- pyrrolidines At least one of materials such as ketone.
- 5. acidic hair coloring preparation according to claim 1, it is characterised in that the aromatic alcohols is selected from phenmethylol, benzene second At least one of materials such as alcohol, phenoxetol.
- 6. acidic hair coloring preparation according to claim 1, it is characterised in that the acid dyes is selected from《Cosmetics safety Technical specification》At least one of acid dyes that can be used in hair dye of defined；Described《Cosmetics safety technology is advised Model》The acid dyes that can be used in hair dye of defined is selected from Indian yellow 1, acid orange 7, acid orange 10, azogeramine 55, acid Property Huang 121, acid red 18 0, azogeramine 63, acid blue 6, acid green 9, acid green 22, acid red 52, acid red 50, acid In the materials such as Huang 73, acid orange 11, acid red 87, acid blue 80, Acid blue 62, acid violet 50, acid red 95, acid red 92 At least one.
- 7. acidic hair coloring preparation according to claim 1, it is characterised in that the pH adjusting agent is selected from hydrochloric acid, sulfuric acid, lemon Lemon acid, glycolic, malic acid, lactic acid, careless stone acid, formic acid, levulic acid, sodium hydroxide, potassium hydroxide, monoethanolamine, three second Hydramine, aminomethyl propanol, isopropylamine, 1,3- propane diamine, 1,2- propane diamine, tripropyl amine (TPA), butylamine, isobutyl amine, tert-butylamine, hexylamine, At least one of materials such as octylame, aniline, benzylamine, cyclohexylamine, pyridine.
- 8. acidic hair coloring preparation according to claim 1, it is characterised in that the additive be selected from ultra-violet absorber, At least one of materials such as antioxidant, stabilizer, chelating agent, essence, plant extracts.
- 9. the hair colouring methods of claim 1-8 any one of them acidic hair coloring preparations, it is characterised in that carried out in hair dye Heat, heating-up temperature is 30 DEG C -50 DEG C, heating time 10min-60min；It is preferred that heating-up temperature is 35 DEG C -50 DEG C, adds The hot time is 10-30min；The mode of heating includes at least one in heating cap heating, heat gun, the heating of hot towel Kind.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711290812.4A CN107997986A (en) | 2017-12-08 | 2017-12-08 | A kind of acidic hair coloring preparation and its hair colouring methods |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711290812.4A CN107997986A (en) | 2017-12-08 | 2017-12-08 | A kind of acidic hair coloring preparation and its hair colouring methods |
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| CN107997986A true CN107997986A (en) | 2018-05-08 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115594987A (en) * | 2022-09-28 | 2023-01-13 | 金华恒利康化工有限公司（Cn） | Acid orange disazo dye and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1163747A (en) * | 1996-01-22 | 1997-11-05 | 花王株式会社 | Hair cosmetic composition |
| CN1346632A (en) * | 2000-09-22 | 2002-05-01 | 日本索希亚株式会社 | Acidic hair coloring preparation composition |
| CN102058514A (en) * | 2011-01-24 | 2011-05-18 | 珠海市时代经典化妆品有限公司 | Package type acid hair dye |
-
2017
- 2017-12-08 CN CN201711290812.4A patent/CN107997986A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1163747A (en) * | 1996-01-22 | 1997-11-05 | 花王株式会社 | Hair cosmetic composition |
| CN1346632A (en) * | 2000-09-22 | 2002-05-01 | 日本索希亚株式会社 | Acidic hair coloring preparation composition |
| CN102058514A (en) * | 2011-01-24 | 2011-05-18 | 珠海市时代经典化妆品有限公司 | Package type acid hair dye |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115594987A (en) * | 2022-09-28 | 2023-01-13 | 金华恒利康化工有限公司（Cn） | Acid orange disazo dye and preparation method thereof |
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Application publication date: 20180508 |