CN1346632A - Acidic hair coloring preparation composition - Google Patents
Acidic hair coloring preparation composition Download PDFInfo
- Publication number
- CN1346632A CN1346632A CN01140802A CN01140802A CN1346632A CN 1346632 A CN1346632 A CN 1346632A CN 01140802 A CN01140802 A CN 01140802A CN 01140802 A CN01140802 A CN 01140802A CN 1346632 A CN1346632 A CN 1346632A
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- China
- Prior art keywords
- hair
- acid
- poliosis
- coloring preparation
- hair coloring
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
A hair-dyeing acidic dye comprises 0.01 to 1% of one or two or more kinds of acidic dyes, 0.1 to 10% of an acid as a pH-adjusting agent, 1 to 20% of aromatic alcohol as a penetrating agent, 1 to 20% of lower alcohol as a solvent and 0.01 to 5% of a polymeric compound as a thickener. Although it is strong acidity, but very stable, rich in fluidity and excellent in availability without dye color staining and migrating to skin and clothes after the hair is dyed, and does not need washing off the dye, white hair is made inconspicuous by only one application of the dye composition and can be dyed in a balanced color after 4 to 5 times.
Description
Technical field
The present invention relates to dyeability acidic hair coloring preparation good, that can not shift to skin or medicated clothing color.
Background technology
The motion of relevant acidic hair coloring preparation is a lot, but pigment concentration is low, penetrating agent or acid the low material of concentration be mainly used in purposes such as hair mousse, though the color transfer to skin or medicated clothing is few, hides poliosis or the inapparent hair dyeing power of poliosis is lacked very much, does not have the actual effect as hair dye.On the contrary, if the high material of concentration of pigment concentration height, penetrating agent or acid, when using as hair dye, dustiness height to skin, use the back serious to the gamut of skin or medicated clothing, can only be resonable appearance institute etc. have the place of particular facility to have hair dyed, to pay special attention to not pollute skin or medicated clothing when using in the general family, and remaining hair dye must be rinsed out after using.
Invent problem to be solved
The invention provides a kind of acidic hair coloring preparation composition, this hair dye is stable at highly acid field (pH1.5-4.0), good fluidity, usability is good, after the use not to the gamut that adheres to of skin and medicated clothing etc., only use to make poliosis no longer showy 1 time, and these tackify means do not need to wash, use poliosis be can't see fully with the tackify means.
The means of dealing with problems
The inventor addresses the above problem to have carried out research with keen determination, found that, as acidic hair coloring preparation, by cooperate pigment, acid, aromatic alcohols, lower alcohol, viscosifier and water with good balance as necessary composition, can realize that 1 use can make poliosis no longer obvious, 4-5 use can make poliosis can't see fully, after the use not to the gamut of skin and medicated clothing etc., not having necessity of flushing, is the very high acidic hair coloring preparation composition of a kind of actual effect.
Acidic hair coloring preparation of the present invention is characterised in that, the acid stain more than a kind or 2 kinds by 0.01-1%, the acid of 0.1-10% as pH adjustment agent, the aromatic alcohols of 1-20% as penetrating agent, the lower alcohol as solvent of 1-20%, the macromolecular compound cooperation as viscosifier of 0.01-5% forms.
In the acidic hair coloring preparation composition of the present invention, except that above-mentioned main component, also can contain the auxiliary agent commonly used in this area such as UV absorbent, antioxidant, stabilizing agent as required, remainder is a water.
The form that carries out an invention
As the acid stain that uses among the present invention, can use in acidify hair dye or the acidic hair coloring preparation in legal pigment commonly used.Preferred tar class pigment is for example by No. 201, red No. 2, red No. 102, red No. 106, red No. 213, red No. 215, red No. 227, red No. 401, red No. 504, yellow No. 4, yellow No. 5, yellow, No. 203, yellow No. 205, green No. 3, green No. 204, green No. 205, No. 1, blue color, No. 203, blue color, No. 403, blue color, No. 401, black, No. 401, purple, orange No. 205, brown etc.These pigments can only use more than a kind or 2 kinds and use., acid stain is 0.01-1 weight % with respect to the total amount of hair dye, preferred 0.05-0.5 weight %.As be below the 0.01 weight %, then having hair dyed can not reach the color of wanting more than 10 times, as is more than the 1 weight %, then is difficult to dye ideal color.
The acid of adjusting agent as pH can be used the arbitrary substance in mineral acid and the organic acid, preferred organic acid.Organic acid such as citric acid, succinic acid, tartaric acid, lactic acid, malic acid, fumaric acid, maleic acid, glycolic for example, mineral acids such as hydrochloric acid, sulphuric acid, phosphoric acid, nitric acid.For giving buffer capacity, these acid and these sour sodium salts, potassium salt or ammonium salt can be used in combination.
The use level of acid, the pH of hair rinse was 1.5-4.0 when hair dye was used, the degree that preferred pH is 1.5-3.5 is selected to use.
As the aromatic alcohols of penetrating agent,, also should be able to give hair after the hair dyeing with the moisture retention of level and smooth sense, moist feeling and humidity except encouraging the infiltration of dyestuff in hair.For example can use benzyl alcohol, phenethanol etc., preferred benzyl alcohol.
As the lower alcohol of solvent, can use the material that is usually used in the hair mousse.Can use the alcohol of the straight or branched of carbon number 1-4,, preferably use ethanol as methanol, ethanol, propanol, isopropyl alcohol, butanols, ethylene glycol, 1,3, butanediol etc.The use level of lower alcohol, different because of other gradation compositions, but be 1-20% with respect to the hair dye total amount.As below 1%, then as the function minimizing of solvent, can see the muddy or separation of liquid, as be more than 20%, the operability when then dyeing reduces.
Hair dye of the present invention is that the unnecessary drippage of hair rinse has used viscosifier when preventing to use, and makes operability good.As the macromolecular compound of viscosifier, can use natural or synthetic macromolecular compound.For example, natural polymers such as arabic gum, guaiac gum (guagum), antler glue, sodium alginate, Xanthan gum, methylcellulose, CMC, cationic starch, synthetic high polymers such as poly-(methyl) acrylic acid, poly-(methyl) acrylate, polyvinyl alcohol, senior fatty acid esters such as Polyethylene Glycol high-grade aliphatic ester etc.Preferred Xanthan gum etc.
Hair coloring preparation composition of the present invention can be engaged in the wetting agent that this field uses, anti-dandruff dose, antioxidant, UV absorbent, spice etc. as required.
Hair dye of the present invention only dyes 1 time and can not reach the color of wanting, and hair dyeing can obtain the deep color development that dyes more than 3-5 time during the interval was certain.Even, health is also had no adverse effects so hair dye of the present invention hair dyeing can not injure hair for several times yet.
During hair dyeing, after the 1st hair dyeing, through more than 30 minutes, preferably through 1 day-7 days (1 week) above after, for example 3 weeks at interval, carry out hair dyeing next time again.After hair dyeing before can have one's hair wash.
Embodiment
Below with embodiment the present invention is described, but the present invention is not subjected to the qualification of embodiment.
Formulation example
Viscosifier use Xanthan gum, and pH adjusts agent and uses glycolic, and aromatic alcohols uses benzyl alcohol, and lower alcohol uses ethanol, and acid stain uses the composite acidic dye of each dyestuff shown in the tabulation 1 down.
Table 1 acid stain blending ratio (weight portion)
Dark brown colour system | Blue colour system | Black system | |
No. 401, black | 1 part | 25 parts | 14 parts |
No. 401, purple | 1 part | 15 parts | 14 parts |
Orange No. 205 | 3 parts | 10 parts | 22 parts |
Above-mentioned each composition is pressed the mixed shown in table 2 and the table 3, and it is 100 that the adding Purified Water makes total amount, and wherein % represents weight %.
Each hair dye that obtains is carried out the hair dyeing test of embodiment 1 and 2.
Embodiment 1
Embodiment 1 and comparative example 1-3 hair dyeing property and the operability formed shown in the application form 2.As mixing acidic dye, the black of record is pigment in the use table 1.
Comparative example 1 is the example of the many compositionss of Xanthan gum, and comparative example 2 is examples of the many compositionss of benzyl alcohol, and comparative example 3 is examples of the many compositionss of ethanol.
The conformability of comparative example 2 and 3 compositions itself is bad, and hair dyeing property is bad.The below hair dyeing of record embodiment 1 and comparative example 1-3.
Table 2
1. hair dyeing
Form | Embodiment 1 (%) | Comparative example (%) | ||
?????1 | ?????2 | ?????3 | ||
Xanthan gum | ????0.5 | ????7.0 | ????0.5 | ????0.5 |
Glycolic | ????2.0 | ????2.0 | ????2.0 | ????2.0 |
Mix acidic dye | ????0.1 | ????0.1 | ????0.1 | ????0.1 |
Benzyl alcohol | ????10.0 | ????10.0 | ????30.0 | ????1.0 |
Ethanol | ????12.5 | ????10.5 | ????12.5 | ????22.5 |
Purified Water | ????74.9 | ????70.4 | ????54.9 | ????73.9 |
Hair dyeing property | ???? *1 | ???? *2 | ???? *3 | ???? *4 |
Dying property after the hair washing | Well 1) | Difference 2) | Difference 3) | Difference 4) |
*1: be coated with exsiccation after 10 minutes, even wiping can not polluted hands yet, poliosis is dyed black equably, does not have the sense of being clamminess, and sense of touch is level and smooth, and is very good.
*2: the viscosity height, difficult coating, the poliosis blackening, but also do not do after 30 minutes, can take place to pollute once more.
*3: fluid separation applications is 2 layers, coats after vibration mixes that back liquid easily trickles on the poliosis, uses inconvenience, the poliosis blackening of coating back, but through also still wetting state after 30 minutes, pollute.
*4: after the coating, poliosis becomes black, and is no longer showy, but through after 30 minutes, the sense of being clamminess arranged, and pigment adheres to again, still has pigment to adhere to after the drying again.2. the dying property after having one's hair wash
1) with after the commercially available shampoo hair washing, do not have decolouring, poliosis is dyed black equably.
2) after the hair washing, because hair washing causes fading of part, the part of poliosis becomes light black, sees that on the whole poliosis is more showy.
3) after the hair washing, observe the poliosis part, part is dyed black, can see the part of not catching, and poliosis is showy.
4) after the hair washing, observe the poliosis part, almost all fade because of hair washing, poliosis is showy, does not see the dying property of pigment.
(1) suitability: complete white male is the testee with hair, the liquid of embodiment 1 is placed comb, in the whole coating of left side head.Be coated with the liquid of the comparative example 1 of equivalent equally at the right side head.
As a result, the liquid of embodiment 1 is whole to launch easily, can hide poliosis on the whole equably, and under the situation of comparative example 1, liquid integral body is difficult to even expansion, is not easy to hide on the whole poliosis.
(2) tack again: immediately with each coated portion of palm contact embodiment 1 and comparative example 1, palm is all stain by dyestuff after the hair dyeing, but embodiment 1 is slight than comparative example 1.
Be coated with after 10 minutes, rub two coated portion of palm, the thickness sense is arranged in the comparative example 1, the dyestuff that adheres on palm is quite a lot of, in embodiment 1, the pollution of palm does not take place under the state of bone dry, promptly uses calico to rub with strength also and can not pollute calico.
(3) dying property of hair: afterwards with commercially available shampoo hair washing, after the drying, observe the hair dyeing state of head both sides, the poliosis of the use portion of comparative example 1 does not almost change as a result, use part almost not have the existence sense of poliosis among the embodiment 1, poliosis is colored.
Afterwards, haircut with commercially available hair oil, hair washing in 2 days 1 time have one's hair wash after 3 times, and the hair dyeing part does not fade, and uses the poliosis part of embodiment 1 to compare with the part of use comparative example 1, and poliosis is unshowy.
Acidic hair coloring preparation of the present invention is at back about the 10 minutes short time inner drying of hair dyeing, dyestuff can not pollute palm or medicated clothing, can directly be maintained to the state of haircuting, poliosis after the hair washing does not fade, also can obtain sufficient hair dyeing effect even repeat hair washing, will place the inconvenience of cleaning again after 30-40 minute when not having to use acidic hair coloring preparation usually, coating the present invention product, under this state, put hair style in order, can obtain hair dyeing effect.
Embodiment 2
Embodiment 2 that forms shown in the his-and-hers watches 3 and comparative example 4 carry out the dyeability test, simultaneously comparative example 5 and 6 are tested.As mixing acidic dye, use the dark brown colour system pigment of record in the table 1.
Comparative example 4 is the many examples of water.Comparative example 5 is examples that benzyl alcohol is many, ethanol is few.Comparative example 6 is examples that ethanol is few, water is many.These fluid,matchings all cause hair dyeing property bad owing to unstable.Table 3
1. hair dyeing
Form | Embodiment 2 (%) | Comparative example (%) | ||
?????4 | ?????5 | ?????6 | ||
Xanthan gum | ????0.3 | ????0.3 | ????0.5 | ????0.5 |
Glycolic | ????2.0 | ????2.0 | ????2.0 | ????2.0 |
Mix acidic dye | ????0.2 | ????0.2 | ????0.2 | ????0.2 |
Benzyl alcohol | ????10.0 | ????0.5 | ????30.0 | ????12.5 |
Ethanol | ????15.0 | ????15.5 | ????2.5 | ????0.5 |
Purified Water | ????72.5 | ????81.5 | ????64.8 | ????84.3 |
Hair dyeing property | ???? *5 | ???? *6 | ???? *7 | ???? *8 |
Dying property after the hair washing | Well 5) | Difference 6) | Difference 7) | Difference 8) |
*5: be coated with exsiccation after 10 minutes, even wiping can not polluted hands yet, poliosis is dyed dark brown equably, does not have the sense of being clamminess, and sense of touch is level and smooth, and poliosis is unshowy, and is very good.
*6: coating back poliosis partly becomes dark brown, and poliosis is unshowy, but does not do after 30 minutes yet, and pigment adheres to again, also has pigment to adhere to after doing again.
*7: fluid separation applications is 2 layers, and vibration mixes the back coating, but unshowy will the vibration repeatedly of poliosis mixed for several times, and the coating number of times is more, very inconvenience.After 30 minutes still is wetting state also, pollutes.
*8: liquid is released state, and coating back poliosis becomes dark brown, and is no longer showy, but through after 30 minutes, the sense of being clamminess is arranged, and pigment adheres to again, still has pigment to adhere to after the drying again.2. the dying property after having one's hair wash
5) with after the commercially available shampoo hair washing, do not have decolouring, poliosis is dyed dark brown equably.
6) hair washing back poliosis is dyed the weak tea brown, fades because hair washing causes, and sees that on the whole poliosis is more showy.
7) after the hair washing, observe the poliosis part, part is dyed dark brown, and it is uneven to see dyeing.
8) after the hair washing, observe the poliosis part, almost all fade because of hair washing, poliosis is showy, does not see the dying property of pigment.
(1) suitability: similarly to Example 1, be subjects but mix 0 years old the women in ground, with hair rinse separate application and the left side and the right side of embodiment 2 and comparative example 4 with poliosis.
As a result, the liquid of embodiment 2 is whole to launch easily, can hide poliosis on the whole equably, under the situation of comparative example 4, and the separation of visible benzyl alcohol, liquid integral body is difficult to even expansion, is not easy to hide on the whole poliosis.
(2) tack again: immediately with each coated portion of palm contact embodiment 2 and comparative example 4, palm is all stain by dyestuff after the hair dyeing, but embodiment 2 is slight than comparative example 4.
Be coated with after 10 minutes, rub two coated portion of palm, the thickness sense is arranged in the comparative example, the dyestuff that adheres on palm is quite a lot of, in an embodiment, the pollution of palm does not take place under the state of bone dry, promptly uses calico to rub with strength also and can not pollute calico.
(3) dying property of hair: with commercially available shampoo hair washing, after the drying, observe the hair dyeing state of head both sides afterwards, though the use portion of comparative example 4 can not see poliosis partially as a result, poliosis is showy on the whole.Use part almost to can't see poliosis among the embodiment 1, poliosis is colored.
Same with the result of embodiment 1, the acidic hair coloring preparation of the present invention of embodiment 2 is at back about the 10 minutes short time inner drying of hair dyeing, and dyestuff can not pollute palm or medicated clothing, can directly be maintained to the state of haircuting, poliosis after the hair washing does not fade, and can obtain sufficient hair dyeing effect even repeat hair washing yet
(4) hair dyeing property again: for through the women of above-mentioned hair dyeing every repeating hair dyeing 3 weeks, dyeing portion before and dyeing portion afterwards are as broad as long, even dyeing, can obtain darker color after the hair dyeing once more, the sensation (bristleization) of also not hardening even repeat to have hair dyed, to the hair not damaged, be sense of touch smoothly, the hair condition of haircuting easily.
Hair coloring preparation composition of the present invention, by the result of above each embodiment, comparative example as can be known, benzyl alcohol and alcoholic acid ratio of components are 1: 0.25-4.0, preferred 1: 1.25-1.5, and benzyl alcohol and alcoholic acid mixed liquor are 1 with the ratio of water: 2.3-41.0, preferred 1: 2.9-3.4, the separation of benzyl alcohol does not take place in this scope, the usability the when tack of dyestuff, coating is good.
By this result as can be known, each components in proportions of the present invention is summarized as follows.
Compositing range of the present invention | Preferable range | |
Acidic dye | ????0.01-1% | ????0.05-0.5% |
Acid | ????0.1-10% | ????1.0-5.0% |
Aromatic alcohols | ????1.0-20% | ????5.0-15.0% |
Lower alcohol | ????1.0-20% | ????10.0-15.0% |
Macromolecular compound | ????0.01-5% | ????0.3-1.0% |
Purified Water | ????44.0-97.88% | ????59.5-74.45% |
Acidic hair coloring preparation composition of the present invention, thus because be using easily of a fluidity, have the viscosity and the drying property of appropriateness good, in the time of can not using to the unnecessary pollution of medicated clothing.The composition of hair dye of the present invention, pigment are not limited to dark system such as black, dark brown, and the pigment of random color is all applicable, and not only are applicable to person's at advanced age poliosis dyeing, can satisfy too the needs of youthful popular color development.
Claims (7)
1. acidic hair coloring preparation composition, by the acid stain more than a kind or 2 kinds of 0.01-1%, the acid of 0.1-10%, the aromatic alcohols of 1-20% as penetrating agent as pH adjustment agent, the lower alcohol as solvent of 1-20%, the macromolecular compound cooperation as viscosifier of 0.01-5% forms.
2. the acidic hair coloring preparation composition of claim 1 record, by the acid stain of 0.05-0.5%, 1-5% adjusts the acid of agent as pH, and the aromatic alcohols of 5-15%, the lower alcohol of 10-15%, the macromolecular compound as viscosifier of 0.3-1% cooperate and form.
3. the acidic hair coloring preparation compositions of claim 1 or 2 records, wherein acid stain is a tar colorant, and the acid of adjusting agent as pH is glycolic, and aromatic alcohols is a benzyl alcohol, and lower alcohol is an ethanol, macromolecular compound is an Xanthan gum.
4. the acidic hair coloring preparation compositions of claim 1 or 2 records, wherein acid stain is a tar colorant, and the acid of adjusting agent as pH is citric acid, and aromatic alcohols is a benzyl alcohol, and lower alcohol is an ethanol, macromolecular compound is an Xanthan gum.
5. the acidic hair coloring preparation compositions of claim 3 or 4 records, wherein benzyl alcohol is 1 with alcoholic acid ratio: 0.25-4.0, and the ratio of benzyl alcohol and alcoholic acid mixed liquor and water is 1: 2.3-41.0.
6. hair colouring methods is characterised in that the hair rinse of the pH1.5-4.0 of the acidic hair coloring preparation composition that uses each record of claim 1-5 kind dyes.
7. the hair colouring methods of claim 6 record is characterised in that the interval with at least 1 day-7 days, dyes 3-5 time, dyes desirable color.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000289510A JP3619988B2 (en) | 2000-09-22 | 2000-09-22 | Acid hair dye composition |
JP289510/2000 | 2000-09-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1346632A true CN1346632A (en) | 2002-05-01 |
CN100528124C CN100528124C (en) | 2009-08-19 |
Family
ID=18772895
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB011408022A Expired - Fee Related CN100528124C (en) | 2000-09-22 | 2001-09-21 | Acidic hair coloring preparation composition |
Country Status (7)
Country | Link |
---|---|
JP (1) | JP3619988B2 (en) |
KR (1) | KR100786903B1 (en) |
CN (1) | CN100528124C (en) |
HK (1) | HK1045808B (en) |
MY (1) | MY149838A (en) |
SG (1) | SG89421A1 (en) |
TW (1) | TWI282289B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103957872A (en) * | 2011-11-28 | 2014-07-30 | 花王株式会社 | Hair cleaning agent composition |
CN106236663A (en) * | 2016-08-31 | 2016-12-21 | 郭迎庆 | A kind of preparation method of high colouring natural botanical hair dye |
CN107997986A (en) * | 2017-12-08 | 2018-05-08 | 花安堂生物科技集团有限公司 | A kind of acidic hair coloring preparation and its hair colouring methods |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
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DE602004029763D1 (en) | 2003-02-21 | 2010-12-09 | Mitsubishi Pencil Co | HAIR COLOUR |
JP4251951B2 (en) * | 2003-09-30 | 2009-04-08 | 株式会社マンダム | Acid hair dye composition |
CN100384945C (en) * | 2006-01-16 | 2008-04-30 | 大连理工大学 | Acid dye composition |
JP4985926B2 (en) * | 2006-09-15 | 2012-07-25 | 株式会社加美乃素本舗 | Photosensitive acid hair dye composition |
JP5495475B2 (en) | 2007-02-23 | 2014-05-21 | 三菱鉛筆株式会社 | Hair dye and hair applicator using the same |
US7766978B2 (en) | 2007-10-18 | 2010-08-03 | Kokyu Alcohol Kogyo Co., Ltd. | Acidic hair dyeing method |
CN101177546B (en) * | 2007-11-30 | 2011-02-23 | 上虞新晟化工工业有限公司 | Acid blue dye composition |
JP5009193B2 (en) * | 2008-02-29 | 2012-08-22 | ホーユー株式会社 | Hair dye composition and hair dyeing method |
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JPH02262509A (en) * | 1989-03-31 | 1990-10-25 | Serutetsuku Lab Kk | Hair dyeing agent |
US5254333A (en) * | 1990-07-10 | 1993-10-19 | Kao Corporation | Hair treatment composition and hair dye composition |
JPH0737370B2 (en) * | 1991-09-20 | 1995-04-26 | 花王株式会社 | Hair dye composition |
EP0547790B1 (en) * | 1991-12-18 | 1995-08-23 | Kao Corporation | Dye composition for Keratinous fibers |
JPH07187969A (en) * | 1993-12-27 | 1995-07-25 | Kao Corp | Hair dyeing agent composition and method for dyeing hair |
JPH08165226A (en) * | 1994-12-09 | 1996-06-25 | Nonogawa Shoji Kk | Acidic hair dye composition |
JP3765857B2 (en) * | 1994-12-22 | 2006-04-12 | サンスター株式会社 | Acid hair composition |
JP3480165B2 (en) * | 1995-12-23 | 2003-12-15 | 花王株式会社 | Acidic semi-permanent hair dye composition for aerosol injection |
JPH08268849A (en) * | 1996-05-02 | 1996-10-15 | Shiseido Co Ltd | Acidic hair-dyeing agent composition for head hair |
AU734805B2 (en) * | 1997-01-21 | 2001-06-21 | Shiseido Company Ltd. | Hairdye compositions |
JP3884818B2 (en) * | 1997-03-03 | 2007-02-21 | ライオン株式会社 | Hair dye composition |
JPH11263716A (en) * | 1998-03-13 | 1999-09-28 | Mirubon:Kk | Acid hair dye |
JP3694593B2 (en) * | 1998-08-12 | 2005-09-14 | 株式会社資生堂 | Acid hair dye composition |
JP2000344639A (en) * | 1999-03-26 | 2000-12-12 | Kanebo Ltd | Acid hair dye for wet hair and method of hair dyeing |
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2000
- 2000-09-22 JP JP2000289510A patent/JP3619988B2/en not_active Expired - Lifetime
-
2001
- 2001-09-12 TW TW090122642A patent/TWI282289B/en not_active IP Right Cessation
- 2001-09-17 KR KR1020010057240A patent/KR100786903B1/en active IP Right Grant
- 2001-09-18 SG SG200105700A patent/SG89421A1/en unknown
- 2001-09-19 MY MYPI20014393A patent/MY149838A/en unknown
- 2001-09-21 CN CNB011408022A patent/CN100528124C/en not_active Expired - Fee Related
-
2002
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103957872A (en) * | 2011-11-28 | 2014-07-30 | 花王株式会社 | Hair cleaning agent composition |
CN106236663A (en) * | 2016-08-31 | 2016-12-21 | 郭迎庆 | A kind of preparation method of high colouring natural botanical hair dye |
CN107997986A (en) * | 2017-12-08 | 2018-05-08 | 花安堂生物科技集团有限公司 | A kind of acidic hair coloring preparation and its hair colouring methods |
Also Published As
Publication number | Publication date |
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SG89421A1 (en) | 2002-06-18 |
MY149838A (en) | 2013-10-31 |
JP3619988B2 (en) | 2005-02-16 |
TWI282289B (en) | 2007-06-11 |
JP2002104942A (en) | 2002-04-10 |
KR20020023121A (en) | 2002-03-28 |
CN100528124C (en) | 2009-08-19 |
KR100786903B1 (en) | 2007-12-17 |
HK1045808B (en) | 2010-04-16 |
HK1045808A1 (en) | 2002-12-13 |
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