JP4251951B2 - Acid hair dye composition - Google Patents
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- JP4251951B2 JP4251951B2 JP2003339016A JP2003339016A JP4251951B2 JP 4251951 B2 JP4251951 B2 JP 4251951B2 JP 2003339016 A JP2003339016 A JP 2003339016A JP 2003339016 A JP2003339016 A JP 2003339016A JP 4251951 B2 JP4251951 B2 JP 4251951B2
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Description
本発明は酸性染毛剤組成物に係り、詳しくは、毛髪への塗布時の延びが良く、垂れ落ちが無く、製剤の低温下及び高温下での安定性に優れ、しかも、染料の安定性にも優れる酸性染毛剤組成物に関する。 The present invention relates to an acidic hair dye composition, and more specifically, it has good elongation when applied to hair, does not sag, is excellent in stability at low and high temperatures of the preparation, and is stable in dye. It is related with the acidic hair dye composition which is also excellent.
一般に酸性染毛剤は、染料、有機溶剤、酸を主成分とし、染色能を向上させるために系のpHが1.5〜4.5程度に調整されている。そして、使用時に頭髪からの垂れ落ちを防止するために増粘剤が配合されるが、前記のような低pH領域においては使用できる増粘剤が限定される。このような低pH領域で酸性染毛剤を増粘する技術としては、増粘剤としてキサンタンガムを用いたもの(例えば、特許文献1参照)や、カルボキシビニルポリマーを用いたもの(例えば、特許文献2参照)が開示されている。 In general, an acidic hair dye contains a dye, an organic solvent, and an acid as main components, and the pH of the system is adjusted to about 1.5 to 4.5 in order to improve dyeing ability. And in order to prevent dripping from the hair at the time of use, a thickener is mix | blended, However, The thickener which can be used is limited in the above low pH area | regions. As a technique for thickening an acidic hair dye in such a low pH region, a technique using xanthan gum as a thickener (for example, see Patent Document 1) or a technique using a carboxyvinyl polymer (for example, Patent Document) 2).
しかし、キサンタンガムで系を増粘させると、流動性に乏しく、毛髪上の延びに問題を有していた。この問題を解決するために、特定量のキサンタンガムと特定量のベントナイトおよび/または架橋性ポリアクリル酸ナトリウムを配合した酸性染毛料が提案(特許文献3参照)されているが、未だ流動性の点で満足できないばかりか、製剤の保存安定性の点でも問題を有していた。
また、カルボキシビニルポリマーで系を増粘させると、キサンタンガムに比べて流動性に優れるものの、製剤の保存安定性に問題を有していた。
However, when the system is thickened with xanthan gum, the fluidity is poor and there is a problem with the elongation on the hair. In order to solve this problem, an acidic hair dye containing a specific amount of xanthan gum and a specific amount of bentonite and / or crosslinkable sodium polyacrylate has been proposed (see Patent Document 3). In addition, it was not satisfactory, and had a problem in terms of storage stability of the preparation.
Moreover, when the system was thickened with carboxyvinyl polymer, although it was excellent in fluidity compared to xanthan gum, it had a problem in the storage stability of the preparation.
一方、製剤の保存安定性に関する技術としては、カルボキシビニルポリマーおよびポリアクリル酸アミドを含有する染毛料組成物(特許文献4参照)や、カルボキシビニルポリマーおよび/またはアクリル酸・メタクリル酸アルキル共重合体と、ポリアクリル酸アミド共重合体を含有する染毛料組成物(特許文献5参照)が報告されている。特に、特許文献4の実施例5及び特許文献5の実施例5では、カルボキシビニルポリマーとキサンタンガムを含有した例が記載されている。しかし、これら技術により、高温時の保存安定性を改善することができたとしても、低温時の保存安定性について、依然として問題を有していた。 On the other hand, as a technique related to the storage stability of the preparation, a hair dye composition containing a carboxyvinyl polymer and a polyacrylic acid amide (see Patent Document 4), a carboxyvinyl polymer and / or an acrylic acid / alkyl methacrylate copolymer. A hair dye composition containing a polyacrylic acid amide copolymer has been reported (see Patent Document 5). In particular, Example 5 of Patent Document 4 and Example 5 of Patent Document 5 describe examples containing a carboxyvinyl polymer and xanthan gum. However, even if the storage stability at high temperature can be improved by these techniques, there is still a problem regarding the storage stability at low temperature.
また、配合される染料の製剤中での安定性についても、問題を有していた。すなわち、酸性染毛剤は、通常、クエン酸等の酸を用いて系のpHを1.5〜4.5程度の酸性に調整されているために、染料を長期間保存すると、製剤中の香料等の配合成分と反応を起こし、配合した染料の当初の色調が変化してしまい、予定していた色調に毛髪を染色できない場合があるといった問題を有していた。 In addition, there is a problem with respect to the stability of the blended dye in the preparation. That is, the acid hair dye is usually adjusted to an acidity of about 1.5 to 4.5 using an acid such as citric acid. It reacts with blending components such as fragrances, and the initial color tone of the blended dye changes, and there is a problem that hair may not be dyed to the planned color tone.
本発明は前記従来技術に鑑みてなされたものであって、毛髪への塗布時の延びが良く、垂れ落ちが無く、製剤の低温下及び高温下での安定性に優れ、しかも、染料の安定性にも優れる酸性染毛剤組成物を提供することを課題とする。 The present invention has been made in view of the above prior art, and has good elongation when applied to hair, no dripping, excellent stability at low and high temperatures of the preparation, and stability of the dye. An object of the present invention is to provide an acidic hair dye composition that is also excellent in properties.
すなわち、本発明は、
(1)染料、カルボキシビニルポリマー1〜10重量%、キサンタンガム0.02〜0.2重量%、グリコール酸及び界面活性剤を含有することを特徴とする酸性染毛剤組成物、及び
(2)更に、N−アルキルピロリドン、芳香族アルコール及び脂肪族低級アルコールからなる群から選ばれる1種以上を含有する前記(1)に記載の酸性染毛剤組成物
に関する。
That is, the present invention
(1) An acidic hair dye composition comprising dye, carboxyvinyl polymer 1 to 10% by weight, xanthan gum 0.02 to 0.2% by weight , glycolic acid and a surfactant , and (2) Furthermore, it is related with the acidic hair dye composition as described in said (1) containing 1 or more types chosen from the group which consists of N-alkyl pyrrolidone, an aromatic alcohol, and an aliphatic lower alcohol.
本発明は、酸性染毛剤組成物に、染料と、増粘剤としてカルボキシビニルポリマー1〜10重量%及びキサンタンガム0.02〜0.2重量%、並びに酸としてグリコール酸及び界面活性剤を含有させることにより、毛髪への塗布時に延びが良く、垂れ落ちが無く、製剤の低温下及び高温下での安定性に優れ、しかも、染料の安定性にも優れる酸性染毛剤組成物を提供することができる。 The present invention contains an acid hair dye composition containing a dye, 1 to 10% by weight of carboxyvinyl polymer and 0.02 to 0.2% by weight of xanthan gum as a thickener, and glycolic acid and a surfactant as an acid. To provide an acidic hair dye composition that has good elongation at the time of application to hair, does not sag, is excellent in stability at low and high temperatures of the preparation, and is excellent in dye stability. be able to.
以下、本発明に係る酸性染毛剤組成物について詳述する。本発明に係る酸性染毛剤組成物は、必須成分として、染料、カルボキシビニルポリマー、キサンタンガム及びグリコール酸を含有する。 Hereinafter, the acidic hair dye composition according to the present invention will be described in detail. The acidic hair dye composition according to the present invention contains a dye, a carboxyvinyl polymer, xanthan gum and glycolic acid as essential components.
本発明に用いることができる染料としては、本発明の効果を発揮するものであれば特に限定されないが、酸性染料を用いるのが好ましい。用いられる酸性染料としては染毛剤に用いられるものであれば特に限定されず、例えば、赤色2号、赤色3号、赤色102号、赤色104号、赤色105号、赤色106号、黄色4号、黄色5号、緑色3号、青色1号、赤色201号、赤色227号、赤色220号、赤色230号、赤色231号、赤色232号、橙色205号、橙色207号、黄色202号、黄色203号、緑色201号、緑色204号、緑色205号、青色202号、青色203号、青色205号、褐色201号、赤色401号、赤色502号、赤色503号、赤色504号、赤色506号、橙色402号、黄色402号、黄色403号、黄色406号、黄色407号、緑色401号、緑色402号、紫色401号、黒色401号等を挙げることができる。これらの染料は一種を単独で又は二種以上を混合して用いることもできる。 Although it will not specifically limit as a dye which can be used for this invention if the effect of this invention is exhibited, It is preferable to use an acidic dye. The acid dye used is not particularly limited as long as it is used for hair dyes. For example, Red No. 2, Red No. 3, Red No. 102, Red No. 104, Red No. 105, Red No. 106, Yellow No. 4 Yellow No. 5, Green No. 3, Blue No. 1, Red No. 201, Red No. 227, Red No. 220, Red No. 230, Red No. 231, Red No. 232, Orange No. 205, Orange No. 207, Yellow No. 202, Yellow 203, green 201, green 204, green 205, blue 202, blue 203, blue 205, brown 201, red 401, red 502, red 503, red 504, red 506 Orange 402, yellow 402, yellow 403, yellow 406, yellow 407, green 401, green 402, purple 401, black 401 and the like. These dyes may be used alone or in combination of two or more.
染料の配合量は、本発明の効果を発揮されれば特に限定されないが、好ましくは組成物中0.001〜2重量%、より好ましくは0.05〜1重量%とされる。配合量が0.001重量%未満の場合には、毛髪を十分に染毛することができず、また、2重量%を超えて配合すると、それ以上の染毛効果が望めなく、均染性に劣る場合がある。 Although the compounding quantity of dye will not be specifically limited if the effect of this invention is exhibited, Preferably it is 0.001-2 weight% in a composition, More preferably, it is 0.05-1 weight%. If the blending amount is less than 0.001% by weight, the hair cannot be dyed sufficiently. If the blending amount exceeds 2% by weight, no further hair dyeing effect can be expected and leveling is possible. May be inferior.
本発明では、系を増粘させるために増粘剤としてカルボキシビニルポリマー及びキサンタンガムを共に配合する。両増粘剤を併用することで、低温から高温における幅広い温度範囲で製剤の保存安定性に優れるからである。本発明で用いられるカルボキシビニルポリマーの市販品としては、商品名ハイビスワコー104、105(いずれも和光純薬社製)、商品名カーボポール934、940、941、980、981(いずれもグッドリッチ社製)、商品名カーボポールULTREZ10(ノベオン社製)等を、キサンタンガムの市販品としては、商品名ケルトロールT(第日本製薬工業社製)等を挙げることができる。 In the present invention, carboxyvinyl polymer and xanthan gum are blended together as a thickener to thicken the system. This is because by using both thickeners together, the storage stability of the preparation is excellent over a wide temperature range from low temperature to high temperature. Commercially available products of the carboxyvinyl polymer used in the present invention include trade names Hibiswako 104 and 105 (all manufactured by Wako Pure Chemical Industries), trade names Carbopol 934, 940, 941, 980 and 981 (all Goodrich) As a commercial product of xanthan gum, the trade name Celtrol T (manufactured by Dainippon Pharmaceutical Co., Ltd.) and the like can be mentioned.
カルボキシビニルポリマーの配合量は、本発明の効果が発揮されれば特に限定されないが、好ましくは組成物中1〜10重量%、より好ましくは、1.5〜3重量%とすれば良い。配合量が1重量%未満の場合は、施術時に液だれを生じるために、また、10重量%を超えて配合すると、粘度が高くなりすぎ施術し難くなるため、いずれの場合にも好ましくない。
また、キサンタンガムの配合量は、本発明の効果が発揮されれば特に限定されないが、好ましくは組成物中0.005〜0.4重量%、より好ましくは、0.02〜0.2重量%である。配合量が0.005重量%未満の場合は、低温下での製剤の安定性に劣るために、また、0.4重量%を超えて配合すると、高温下において粘度上昇が生じるため、いずれの場合にも好ましくない。
Although the compounding quantity of a carboxy vinyl polymer will not be specifically limited if the effect of this invention is exhibited, Preferably it is 1-10 weight% in a composition, More preferably, what is necessary is just to be 1.5-3 weight%. When the blending amount is less than 1% by weight, dripping occurs during the treatment, and when the blending amount exceeds 10% by weight, the viscosity becomes too high to be difficult to perform the treatment.
Further, the amount of xanthan gum is not particularly limited as long as the effect of the present invention is exerted, but preferably 0.005 to 0.4% by weight, more preferably 0.02 to 0.2% by weight in the composition. It is. When the blending amount is less than 0.005% by weight, the stability of the preparation at low temperature is poor, and when the blending amount exceeds 0.4% by weight, the viscosity increases at high temperature. In some cases, it is not preferable.
本発明では、酸としてグリコール酸が用いられる。前記増粘剤と共にグリコール酸を用いることにより、製剤の低温下及び高温下での保存安定性に加え、染料の保存安定性にも優れた効果を発揮させることができる。特に黒色401号、赤色227号、黄色403号などの染料と香料とを共に配合した場合に、これら染料の安定性に優れる。
グリコール酸の配合量は染色能を向上させる観点から、系のpHが1.5〜4.5程度になるように調整すれば良く、具体的には、0.2〜10重量%、好ましくは、1〜5重量%程度配合すれば良い。
In the present invention, glycolic acid is used as the acid. By using glycolic acid together with the thickener, it is possible to exert an excellent effect on the storage stability of the dye in addition to the storage stability of the preparation at low and high temperatures. In particular, when dyes such as black 401, red 227, and yellow 403 are combined with a fragrance, the stability of these dyes is excellent.
The blending amount of glycolic acid may be adjusted so that the pH of the system is about 1.5 to 4.5 from the viewpoint of improving the dyeing ability, specifically 0.2 to 10% by weight, preferably 1 to 5% by weight may be blended.
また、本発明に係る酸性染毛剤組成物には、染料の毛髪中への浸透性を向上させる観点から有機溶媒を含有させることができる。用いられる有機溶媒としては、N−アルキルピロリドン、芳香族アルコール、脂肪族低級アルコールを挙げることができる。具体的には、1-メチル-2-ピロリドン、1-エチル-2-ピロリドン等のN-アルキルピロリドン;ベンジルアルコール、2−ベンジルオキシエタノール等の芳香属アルコール;エチルアルコール、ブチルアルコール等の脂肪族低級アルコールを例示することができる。これら有機溶媒は一種を単独で又は二種以上を混合して用いることもできる。 Moreover, the acidic hair dye composition according to the present invention can contain an organic solvent from the viewpoint of improving the permeability of the dye into the hair. Examples of the organic solvent used include N-alkylpyrrolidone, aromatic alcohol, and aliphatic lower alcohol. Specifically, N-alkylpyrrolidones such as 1-methyl-2-pyrrolidone and 1-ethyl-2-pyrrolidone; aromatic alcohols such as benzyl alcohol and 2-benzyloxyethanol; aliphatics such as ethyl alcohol and butyl alcohol A lower alcohol can be exemplified. These organic solvents may be used alone or in combination of two or more.
有機溶媒の配合量は特に限定されないが、組成物中5〜60重量%とするのが好ましく、15〜45重量%とするのがより好ましい。配合量が5重量%未満の場合、染色性向上に寄与しないために、また、60重量%を超えて配合すると、製剤の安定性が低下するため、いずれの場合にも好ましくない。 Although the compounding quantity of an organic solvent is not specifically limited, It is preferable to set it as 5 to 60 weight% in a composition, and it is more preferable to set it as 15 to 45 weight%. When the blending amount is less than 5% by weight, it does not contribute to improvement of dyeability, and when the blending amount exceeds 60% by weight, the stability of the preparation is lowered.
尚、本発明の酸性染毛剤組成物には、本発明の効果を損なわない範囲であれば、上記した成分の他、シリコーン類、炭化水素類、油脂類、ロウ類、エステル類、界面活性剤、多価アルコール、キレート剤、酸化防止剤、動植物抽出液、防腐剤、紫外線吸収剤、香料、精製水等を目的に応じて適宜配合することができる。 In addition, in the acidic hair dye composition of the present invention, as long as the effects of the present invention are not impaired, silicones, hydrocarbons, oils and fats, waxes, esters, surfactants, in addition to the above-described components Agents, polyhydric alcohols, chelating agents, antioxidants, animal and plant extracts, preservatives, ultraviolet absorbers, fragrances, purified water, and the like can be appropriately blended depending on the purpose.
以下、本発明を実施例に基づき更に詳細に説明するが、本発明はこれらの実施例により何ら限定されるものではない。尚、配合量は重量%である。
(試料の調製)
表1〜2に記した組成に従い、定法により実施例1〜9及び比較例1〜8のゲル状の酸性染毛剤を調製し、下記評価試験に供した。
EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited at all by these Examples. In addition, a compounding quantity is weight%.
(Sample preparation)
According to the composition that describes in Table 1-2, the gelled acidic hair dye of Example 1-9 and Comparative Example 1-8 were prepared by a conventional method and subjected to the following evaluation tests.
(試験例1;延びの評価)
各試料0.5gをガラス板上に塗布し、激しく振動させて試料の流動性変化を観察することにより、延びについての評価を行った。評価は、下記評価基準に従って実施し、結果を表1〜2に記した。
<評価基準>
◎:非常に延びが良い
○:延びが良い
△:やや延びが悪い
×:延びが悪い
(Test Example 1: Evaluation of elongation)
Elongation was evaluated by applying 0.5 g of each sample on a glass plate and oscillating vigorously to observe the change in fluidity of the sample. Evaluation was performed according to the following evaluation criteria, and the results are shown in Tables 1 and 2.
<Evaluation criteria>
◎: Very good stretch ○: Good stretch △: Slightly poor stretch ×: Bad stretch
(試験例2;垂れ落ちの評価)
各試料0.5gをガラス板上に塗布し、ガラス板を地面に対して垂直に1分間固定し、垂れ落ちの度合いを下記評価基準に従い評価した。結果を表1〜2に記した。
<評価基準>
◎:垂れ落ちない
○:やや垂れ落ちる
△:垂れ落ちる
×:激しく垂れ落ちる
(Test Example 2: Evaluation of dripping)
0.5 g of each sample was applied on a glass plate, the glass plate was fixed perpendicular to the ground for 1 minute, and the degree of dripping was evaluated according to the following evaluation criteria. The results are shown in Tables 1-2.
<Evaluation criteria>
◎: Does not sag ○: Slightly △: Sags x: Sags violently
(試験例3;製剤安定性の評価)
各試料を透明の広口瓶に充填し、−18℃、25℃、50℃の各温度で保存した。保存期間は、−18℃の場合は2日間、25℃及び50℃は8週間実施した。保存後の各試料について、製剤の分離、生地荒れ等の外観変化を下記評価基準に従い目視で評価した。結果を表1〜2に示す。
<評価基準>
◎:外観変化がない
○:外観変化が殆どない
△:やや外観変化がある
×:明らかな外観変化がある
(Test Example 3; Evaluation of formulation stability)
Each sample was filled in a transparent jar and stored at temperatures of -18 ° C, 25 ° C and 50 ° C. The storage period was 2 days for -18 ° C and 8 weeks for 25 ° C and 50 ° C. About each sample after a preservation | save, appearance changes, such as isolation | separation of a formulation and rough cloth, were evaluated visually according to the following evaluation criteria. The results are shown in Tables 1-2.
<Evaluation criteria>
◎: No change in appearance ○: Little change in appearance △: Some change in appearance ×: Clear change in appearance
(試験例4;染料安定性の評価)
各試料を透明の広口瓶に充填し、50℃の温度で4週間保存した。保存後の各試料について、色調の変化を保存初期の色調と比較して評価した。評価は下記評価基準に従って実施し、結果を表1〜2に記した。
<評価基準>
◎:色調変化がない
○:殆ど色調変化がない
△:やや色調変化がある
×:明らかな色調変化がある
(Test Example 4; Evaluation of dye stability)
Each sample was filled into a transparent jar and stored at a temperature of 50 ° C. for 4 weeks. About each sample after a preservation | save, the change of the color tone was evaluated in comparison with the color tone of the preservation | save initial stage. Evaluation was performed according to the following evaluation criteria, and the results are shown in Tables 1 and 2.
<Evaluation criteria>
◎: No change in color tone ○: Little change in color tone △: Some change in color tone ×: Clear change in color tone
表1及び表2の結果から、本発明に係る酸性染毛剤組成物は、毛髪への塗布時の延びが良く、垂れ落ちが無く、製剤の低温下及び高温下での安定性に優れ、しかも、染料の安定性にも優れることが分かる。 From the results of Table 1 and Table 2, the acidic hair dye composition according to the present invention has good elongation at the time of application to hair, no dripping, and excellent stability at low and high temperatures of the preparation, Moreover, it can be seen that the dye stability is also excellent.
以下、本発明に係る酸性染毛剤組成物の処方例を示す。尚、POEは、ポリオキシエチレンの略である。
(処方例1)
キサンタンガム 0.1
カルボキシビニルポリマー 2.0
べンジルアルコール 12.0
エタノール 15.0
N−メチルピロリドン 6.0
POE(20)オクチルドデシルエーテル 0.2
グリコール酸 3.0
橙色205号 0.2
赤色102号 0.02
黄色4号 0.05
黒色401号 0.02
紫色401号 0.05
香料 0.1
精製水 残分
合 計 100.0重量%
Hereinafter, the formulation example of the acidic hair dye composition which concerns on this invention is shown. POE is an abbreviation for polyoxyethylene.
(Prescription Example 1)
Xanthan gum 0.1
Carboxyvinyl polymer 2.0
Benzyl alcohol 12.0
Ethanol 15.0
N-methylpyrrolidone 6.0
POE (20) octyldodecyl ether 0.2
Glycolic acid 3.0
Orange 205 No.0.2
Red No. 102 0.02
Yellow No. 0.05
Black 401 0.02
Purple 401 No. 0.05
Fragrance 0.1
Purified water residue
Total 100.0% by weight
(処方例2)
キサンタンガム 0.02
カルボキシビニルポリマー 2.5
べンジルアルコール 10.0
エタノール 20.0
POE(20)オクチルドデシルエーテル 0.2
グリコール酸 3.0
橙色205号 0.1
赤色227号 0.02
黄色406号 0.03
黒色401号 0.02
香料 0.1
精製水 残分
合 計 100.0重量%
(Prescription example 2)
Xanthan gum 0.02
Carboxyvinyl polymer 2.5
Benzyl alcohol 10.0
Ethanol 20.0
POE (20) octyldodecyl ether 0.2
Glycolic acid 3.0
Orange 205 No.0.1
Red No. 227 0.02
Yellow No. 406 0.03
Black 401 0.02
Fragrance 0.1
Purified water residue
Total 100.0% by weight
本発明の酸性染毛剤組成物には、染料、カルボキシビニルポリマー、キサンタンガム及びグリコール酸が含有されているので、毛髪への塗布時の延びが良く、垂れ落ちが無く、低温から高温の幅広い温度範囲で優れた製剤の保存安定性を示し、しかも、染料の安定性にも優れる。したがって、本発明の酸性染毛剤組成物は、染毛剤製品に用いることができ、頭髪の染毛に好適に使用することができる。
Since the acidic hair dye composition of the present invention contains a dye, a carboxyvinyl polymer, xanthan gum and glycolic acid, it has good elongation when applied to hair, does not sag, and has a wide range of temperatures from low to high. Excellent storage stability of the preparation in the range, and also excellent dye stability. Therefore, the acidic hair dye composition of the present invention can be used for hair dye products and can be suitably used for hair dyeing.
Claims (2)
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JP2003339016A JP4251951B2 (en) | 2003-09-30 | 2003-09-30 | Acid hair dye composition |
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JP4251951B2 true JP4251951B2 (en) | 2009-04-08 |
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JPH08165226A (en) * | 1994-12-09 | 1996-06-25 | Nonogawa Shoji Kk | Acidic hair dye composition |
JPH10330224A (en) * | 1997-06-02 | 1998-12-15 | Lion Corp | Gel composition for cosmetic |
JP3699574B2 (en) * | 1997-10-30 | 2005-09-28 | ホーユー株式会社 | Hair dye composition |
JP2000344639A (en) * | 1999-03-26 | 2000-12-12 | Kanebo Ltd | Acid hair dye for wet hair and method of hair dyeing |
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