JPH0737370B2 - Hair dye composition - Google Patents

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair dye composition, and more particularly to a hair dye that can be used with bare hands without using tools such as gloves, which is used from application to hair to washing. The present invention relates to a hair dye composition which has a short standing time and is easy to operate.

[0002]

2. Description of the Related Art Hair dyes containing acid dyes are widely used at home and in beauty salons because they have less damage to hair than other hair dyes. However, the acid dye-containing hair dye, when applied with bare hands without using a tool,
It significantly stains the skin of the hands. Therefore, when a beautician applies a treatment, apply a protective cream or the like on the edges in advance to prevent hair dye from adhering to the skin, apply it with a tool such as gloves or a comb, and heat it. 10-30
A high hair dyeing effect is obtained by leaving it for a minute. On the other hand, when dyeing hair at home, use a tool such as a glove or comb, and be careful not to stain your hands, and after applying 10
It is performed by leaving it for 30 minutes.

As described above, the conventional acid dye-containing hair dye is
Since it has drawbacks such as soiling the hand skin and complicated operation, various studies have been made in recent years to solve the problems. As one of them, a means for gradually making the gray hair less noticeable has been developed by using a hair dye having a low acid dye concentration in the same manner as hair rinse. This hair dye has advantages that it is less contaminated even when it is used with bare hands, and that the standing time from application of the hair dye to washing is about 5 minutes, which is relatively short.

[0004]

However, since this hair dye also requires a leaving time of about 5 minutes, it is still not sufficiently satisfactory in its simplicity as compared with a usual hair rinse agent. Therefore, it is an object of the present invention to provide a hair dye composition which has less stains on the skin even when used with bare hands, and which has an excellent hair dyeing effect such that gray hair gradually becomes inconspicuous in a shorter standing time.

[0005]

As a result of intensive investigations by the present inventors in such an actual situation, as a result, it is quite surprising that the acidic dye and the organic solvent at low concentrations are contained and the pH is adjusted to 2.0 to 4.5.
Further, it has been found that a hair dye composition having a certain buffering ability has less stains on the skin of the hand, and is excellent in the effect of gradually making the gray hair inconspicuous in a short standing time of 120 seconds or less, and the present invention. Completed

That is, the present invention contains the following components (A) and (B) (A) acid dye 0.01 to 0.2 wt% (B) organic solvent 0.5 to 50 wt% and pH 2.0 to 4.5 and a buffer capacity of 0.0
The present invention provides a hair dye composition, which has a content of 1 to 0.2 gram equivalent / l.

Examples of the acid dye which is the component (A) of the hair dye composition of the present invention include nitro dyes, azo dyes, nitroso dyes, triphenylmethane dyes, xanthene dyes, quinoline dyes, anthraquinone dyes and indigo dyes. Specifically, Red No. 2, Red No. 3, Red No. 102,
Red No. 104, Red No. 105, Red No. 106, Yellow 4
No. 5, Yellow No. 5, Green No. 3, Blue No. 1, Blue No. 2, Red 2
01, red 227, red 220, red 230,
Red 231, Red 232, Orange 205, Orange 20
No. 7, Yellow No. 202, Yellow No. 203, Green No. 201, Green No. 204, Green No. 205, Blue No. 202, Blue No. 203
No. 205, Blue No. 205, Brown No. 201, Red No. 401, Red No. 502, Red No. 503, Red No. 504, Red No. 506.
No., Orange No. 402, Yellow No. 402, Yellow No. 403, Yellow No. 406, Yellow No. 407, Green No. 401, Green No. 402
No. 401, purple No. 401, black No. 401, etc. are used. Among these, the acidic dye which is preferable from the viewpoint of hair dyeing power is yellow 4
No. 2, Green No. 204, Red No. 2, Red No. 102, Green No. 3
No. 1, Blue No. 1, Blue No. 205, Yellow No. 403, Red No. 10
No. 6, Red No. 201, Orange No. 205, Black No. 401, Green No. 201 or Purple No. 401, among which Black 401
No. 401, purple No. 401, orange No. 205, yellow No. 403 or red No. 106 are particularly preferable. These acidic dyes can be used alone or in combination of two or more.

The above-mentioned acid dye is added in an amount of 0.0
It is 1 to 0.2% by weight (hereinafter, simply indicated by%), but from the viewpoint of achieving both hair dyeing power and suppression of stains on the hand skin, 0.0
2 to 0.1%, particularly 0.03 to 0.08% is preferable.
If the content of the acid dye is less than 0.01%, a sufficient hair dyeing effect cannot be obtained after a short standing time, and if it exceeds 0.2%, the hand skin is markedly soiled, which is a problem in practical use.

As the organic solvent which is the component (B), a compound represented by the following formula (1) and N represented by the following formula (2) are given.
-Alkylpyrrolidone or alkylene carbonates having 1 to 4 carbon atoms.

[0010]

[Chemical 1]

[0011]

[Chemical 2]

Specific examples of these organic solvents include ethanol, isopropanol, n-propanol,
n-butanol, isobutanol, ethylene glycol, propylene glycol, 1,3-butanediol,
Benzyl alcohol, cinnamyl alcohol, phenethyl alcohol, p-anisyl alcohol, p-methylbenzyl alcohol, phenoxyethanol, 2-benzyloxyethanol, methyl carbitol, ethyl carbitol, propyl carbitol, butyl carbitol, triethylene glycol mono. Ethyl ether, triethylene glycol monobutyl ether, glycerin,
N-methylpyrrolidone, N-octylpyrrolidone, N-
Examples thereof include laurylpyrrolidone.

The amount of the organic solvent blended is 0.5 to 50.
%, Especially 1 to 35% is preferable. If it is less than 0.5%, a sufficient hair dyeing effect cannot be obtained even after a short standing time, and if it exceeds 50%, no improvement in the effect is observed.

The pH of the hair dye composition of the present invention (measured as a 10% aqueous solution) is 2.0 to 4.5, more preferably 2.5 to 4.5, and particularly preferably 2.5 to 4. It is 0. If the pH exceeds 4.5, it is not preferable because the standing time after applying the hair dye to the hair is not shortened, and if the pH is less than 2.0, irritation of the hand skin due to the acid component becomes a problem.

Further, the hair dye composition of the present invention has a buffering capacity of 0.01 to 0.2 gram equivalent of a 10% aqueous solution of the composition.
It is necessary to indicate l. Here, the buffering capacity in the present invention is a value obtained by the following formula using the concentration of the base required to raise the pH of the 10% aqueous solution of the hair dye composition at 25 ° C. by 1 from the initial value as a scale. .

[0016]

[Equation 1]

If the buffering capacity is less than 0.01 gram equivalent / l, a sufficient effect cannot be obtained even after a short standing time, and the value of 0.
When it exceeds 2 gram equivalent / l, the hair dyeing effect is not noticeably improved, and it is not preferable because the pH buffering agent which imparts the buffering ability and other components are not easily dissolved. The preferable buffer capacity is 0.01 to 0.05 gram equivalent /
It is l.

Such a buffering capacity is used in the pH of the hair dye composition.
It can be provided by adding a buffering agent, a surfactant, a chelating agent, a dye, a preservative and the like. this house,
As the pH buffering agent, an organic acid or an inorganic acid having a buffering action in the range of pH 2.0 to 4.5 and a salt thereof can be used. Examples of the organic acid include citric acid, glycolic acid, succinic acid, tartaric acid, lactic acid, fumaric acid, malic acid,
Examples include levulinic acid, butyric acid, valeric acid, oxalic acid, maleic acid, fumaric acid, mandelic acid, and the like, and examples of the inorganic acid include phosphoric acid, sulfuric acid, nitric acid, and the like. Examples of salts of these acids include sodium salts, potassium salts, ammonium salts, alkanolamine salts such as triethanolamine salts, and the like. The compounding amount of the compound that provides the buffering capacity is not particularly limited, and varies depending on the type of the compound that provides the buffering capacity. For example, when a citric acid sodium salt is mainly used as a compound that provides a buffering capacity, it is mixed at a concentration of about 2 to 2.5% by weight or more.

Further, the hair dye composition of the present invention contains various surfactants, cationic polymers, oily components, thickeners such as hydroxyethyl cellulose and xanthan gum, and silicone derivatives within the range that does not impair the effects of the present invention. , A fragrance, an antiseptic, an ultraviolet absorber, an antioxidant, a bactericide and the like may be added. Here, as the surfactant, anionic surfactants such as olefin sulfonic acid, alkane sulfonic acid, fatty acid alkyl ether carboxylic acid and N-acyl amino acid;
Any of amphoteric surfactants such as amidobetaine, carbobetaine and hydroxysulfobetaine; cationic surfactants such as mono- or dialkyl quaternary ammonium salts; nonionic surfactants such as polyoxyalkylene alkyl ethers can be used. . Examples of the cationic polymer include cationized cellulose, cationized starch, cationized guar gum, diallyl quaternary ammonium salt polymer, diallyl quaternary ammonium salt / acrylamide copolymer, hydroxyethyl cellulose dimethyl diallyl 4
Examples thereof include quaternary ammonium copolymers. Examples of the oily component include fatty acid esters, linear or branched alkyl glyceryl ether, branched higher alcohols and the like.

The hair dye composition of the present invention can be manufactured by a conventional method by mixing the above components, and the method of use thereof is very similar to the usual hair rinse. That is, after taking the hair dye composition of the present invention with a bare hand without using a tool and applying it to the hair, 12
After leaving it for a time of 0 seconds or less, it is sufficient to squeeze. About 5-10
With repeated use, a hair dyeing effect such as white hair becoming less noticeable can be obtained. From the viewpoint of hair dyeing effect, leaving time is 30 seconds to 120
Seconds are preferred. Even when the standing time is 120 seconds or longer, no significant improvement in the hair dyeing effect that makes gray hair inconspicuous is not seen.

[0021]

By using the hair dye composition of the present invention, it is possible to gradually make the white hair inconspicuous by applying it to the hair with bare hands without using a tool, leaving it for a short time of 120 seconds or less, and then washing it off. it can.

[0022]

The present invention will be described in more detail with reference to examples, but the present invention is not limited thereto. In the examples, the "buffering capacity" of the composition is measured as follows. That is, 10 g of the composition was taken, water was added to 100 ml, the pH at this time was measured, and then a 1N sodium hydroxide aqueous solution was added to this, and a 1N sodium hydroxide aqueous solution required for the pH to rise once was added. The buffer capacity = xx10 /
Calculated by 1000 gram equivalents / l.

Examples 1 to 3 After shampooing about 10 g of a dried white hair bundle, water was drained (the weight of the hair bundle after draining water was 17 g).
3 g of each of the above compositions was rapidly and uniformly applied, and then left standing at 35 ° C. for a certain period of time and rinsed. After drying, shampooing and similar operations were repeated to evaluate hair dyeing and hand skin stains. The stain (ΔE) and the stain on the hand skin were evaluated as follows. (1) Dyeing (ΔE) The dyed hair bundle was set to L with a color difference meter (CR200 manufactured by Minolta),
The a and b values are measured to obtain the color difference (ΔE) from undyed hair,
The stain was evaluated. In addition, ΔE represents that the larger the value, the better the dyeing. (2) Stain on hand skin The composition was picked up by 10 panelists and then washed with soap to examine the stain on the hand. The evaluation was based on the following criteria. ◯: Dirt on hands was removed by washing with soap twice. X: Dirt on hands was not removed even by washing with soap twice.

[0024]

[Table 1]

It can be seen from Table 1 that the product of the present invention exhibits a good hair-dyeing effect after a short standing time and stains on the skin of hands are easily removed by washing with soap.

Comparative Example 4 After shampooing 10 female monitors in the 40's having a white hair ratio of about 10% on the forehead, a hairdresser gave Comparative Example 1
About 15 g of (Table 1) was applied, left at 35 ° C. for 30 seconds, rinsed, and then dried with a dryer. After repeating the same operation four more times, the conspicuousness of white hair was visually evaluated by 10 panelists. The results are shown in Table 2.

Example 4 After shampooing 10 female monitors in the 40's having a white hair ratio of about 10% on the forehead, a hairdresser applied about 15 g of Inventive Example 1 (Table 1), After leaving it at 35 ° C. for 30 seconds, it was rinsed and dried with a dryer. After repeating the same operation four more times, the conspicuousness of white hair was visually evaluated by 10 panelists. The results are shown in Table 2.

Example 5 After shampooing 10 female monitors in their 40s with a white hair ratio of the frontal region of about 10%, a hairdresser applied about 15 g of the hair dye composition shown below, After leaving it at 35 ° C. for 90 seconds, it was rinsed and dried with a dryer. After repeating the same operation four more times, the conspicuousness of white hair was visually evaluated by 10 panelists. The results are shown in Table 2. Moreover, the dirt on the hand of the hairdresser after applying the hair dye was removed by washing with soap. The preparation method was the same as in Examples 1 to 3, and the pH was 4.0 and the buffer capacity was 0.024 gram equivalent / l. Blending component Blending amount (%) (1) 1,3-butanediol 20 (2) N-methylpyrrolidone 10 (3) Citric acid 6 (4) Black 401 No. 0.006 (5) Purple 401 No. 0.003 ( 6) Red No. 106 0.004 (7) Orange No. 205 0.035 (8) Xanthan gum 1.0 (9) NaOH proper amount (10) Purified water balance

[0029]

[Table 2]

Examples 6 to 8 The following compositions were excellently dyed such that white hair became inconspicuous after being used about 5 times under the condition that the time from application to hair to rinsing was 60 seconds (35 ° C). Showed in hair effect. Also, stains on hands when applying the hair dye were removed by washing with soap. The composition of all the compositions was the same as in Examples 1 to 3, and the pH was 3.5. The buffer capacity of the compositions of Examples 6 and 8 was 0.025 gram equivalent / l, and the buffer capacity of the composition of Example 7 was 0.037 gram equivalent / l.

(Example 6) Blending component blending amount (%) (1) Ethanol 20 (2) Benzyl alcohol 5 (3) Lactic acid 5 (4) Black 401 0.004 (5) Purple 401 0.005 ( 6) Yellow No. 403 0.009 (7) Orange No. 205 0.030 (8) Hydroxyethyl cellulose 1.5 (9) NaOH proper amount (10) Purified water balance

(Example 7) Blending component blending amount (%) (1) Ethanol 20 (2) 2-Benzyloxyethanol 5 (3) Lactic acid 7 (4) Black No. 401 0.005 (5) Purple No. 401 0 0.005 (6) Orange No. 205 0.045 (7) Polymer JR-400 ^{* 1} 0.3 (8) Amisoft LS-11 ^{* 2} 0.3 (9) Hydroxyethyl cellulose 1.7 (10) NaOH proper amount (11) ) Purified water balance * 1: UCC, cationized cellulose * 2: Ajinomoto Co., lauroyl glutamate monosodium salt

(Example 8) Blending component blending amount (%) (1) 1,3-butanediol 25 (2) benzyl alcohol 5 (3) lactic acid 7 (4) black 401 0.015 (5) purple 401 No. 0.030 (6) Orange No. 205 0.020 (7) Polyether-modified silicone ^{* 3} 0.5 (8) Dimethylpolysiloxane ^{* 4} 0.3 (9) Xanthan gum 1.0 (10) NaOH proper amount (11 ) Purified water balance * 3: Shin-Etsu Chemical Co., Ltd., KF352A * 4: 4 million centistokes

Claims (3)

[Claims] 1. The following components (A) and (B) (A) Acid dye: 0.01 to 0.2% by weight (B) Organic solvent: 0.5 to 50% by weight, and a pH of 2.0. ~ 4.5, buffer capacity 0.0
A hair dye composition, which is 1 to 0.2 gram equivalent / l. 2. The following components (A) and (B) (A) one or more acid dyes selected from black No. 401, purple No. 401, orange No. 205, yellow No. 403 and red No. 106. 0.01 to 0.2 wt% (B) Organic solvent 0.5 to 50 wt% is contained, pH is 2.0 to 4.5 and buffer capacity is 0.0.
A hair dye composition, which is 1 to 0.2 gram equivalent / l. 3. A hair dyeing method comprising applying the hair dye composition according to claim 1 to hair and rinsing the hair within 2 minutes.