TWI242403B - Method for fabricating heat superconducting bumps/sheets using electroplating - Google Patents

Method for fabricating heat superconducting bumps/sheets using electroplating Download PDF

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TWI242403B
TWI242403B TW91121730A TW91121730A TWI242403B TW I242403 B TWI242403 B TW I242403B TW 91121730 A TW91121730 A TW 91121730A TW 91121730 A TW91121730 A TW 91121730A TW I242403 B TWI242403 B TW I242403B
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heat
superconducting
conducting
sheets
metal
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Jiun-Fu Liou
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Jiun-Fu Liou
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Abstract

A method for fabricating heat superconducting bumps/sheets using electroplating is disclosed, which includes the steps of: (a) selecting heat superconducting tubes, substances, and electrolyte containing metal ions; (b) connecting the heat superconducting tubes and substances with the cathode of DC, and then dipping the heat superconducting tubes and substances in the electrolyte; (c) electrifying DC for a period of time to form metal conductive bumps and sheets adhered on the surface of the heat superconducting bumps and sheets; (d) cutting off the power supply and taking out the finished products; (e) processing the finished products to the shapes of conductive bumps as required.

Description

12424031242403

【發明領域】[Field of Invention]

本發明係提供— 、 法’特別是-種利用J以電鍍方式製造熱超導塊、片之方 超導管、體的表面:鍍的原该將t屬!料結合於熱傳; 來製造熱傳導超導总其可以剎用較低熔點的金屬管γ辨 精密的熱超導塊、降低製造成本,而且可以製造出更 【發明背景】 目前產業界針對^ 品所採用之散熱裝置%腦中央處理器(CM )或高熱源產 質散熱片(例如台L =是利用具ΐ高傳熱效率的紹材 ^ ^ + 弓公告第45 946 9號專利案所萝1 柯 體)的基座接觸於埶% *曰 Τ I w的散埶 鰭片上,再利用風’以將熱量吸收並傳遞到散熱片的、 者。 八扇°人出冷空氣將散熱片上的熱量排除 由於現今高效率之CPU所產生的高熱已非一般傳 ,材質散熱片所能快速傳導、排除,a而利用導熱效、率、 ,金屬約高出一倍的銅金屬來傳導cpu的熱量乃是另一種乂 選擇;然而,鋁金屬的密度約2· 7g/cm3,而銅金屬的密度 為8· 9 3g/cm3 (相同體積的銅金屬重量約為鋁金屬的三倍X ),因此,若完全採用銅金屬製造成散熱片,則會因為銅 的重量過重無法通過落地實驗,或是裝在主機板上過久後 造成主機板變形。目前市面上所謂具有銅底的鋁材質散熱 片’乃是以鍛壓或焊接的技術將預先成型好的銅板嵌固於 叙材質散熱片的基座底面;台灣專利公告第4 5 9 4 6 9號亦屬The present invention provides-, method ', and especially-a method for manufacturing a thermal superconducting block, a sheet of superconducting tube, and a body by electroplating using J. The surface of the plating should be t! Materials are combined with heat transfer; to produce thermally conductive superconductors, they can use lower-melting-point metal tubes to discriminate precise thermal superconducting blocks, reduce manufacturing costs, and can produce more [Background of the Invention] The current industry is targeting ^ products The heat dissipation device used is a brain central processing unit (CM) or a high heat source heat sink (for example, Taiwan L = is a material with high heat transfer efficiency ^ ^ + Bow Publication No. 45 946 9) 1 Ke body) The base is in contact with the scattered fins of 埶% * Τ I w, and the wind is used to absorb and transfer heat to the heat sink. Eight fans of cold air remove the heat on the heat sink. Due to the high heat generated by today's high-efficiency CPUs, it is no longer common. The material heat sink can quickly conduct and eliminate, a. The use of thermal conductivity, rate, and metal is about high. Twice as much copper metal to conduct heat from the CPU is another alternative; however, the density of aluminum metal is about 2.7g / cm3, and the density of copper metal is 8.9g / cm3 (the weight of copper metal of the same volume) It is about three times as much as aluminum metal). Therefore, if the heat sink is made entirely of copper metal, the weight of copper cannot pass the ground test or the motherboard is deformed after being installed on the motherboard for too long. At present, the so-called aluminum heat sink with a copper bottom on the market is a method of forging or welding that embeds a pre-formed copper plate on the bottom surface of the base of the heat sink in Taiwan; Taiwan Patent Bulletin No. 4 5 9 4 6 9 Also

第4頁 1242403 > 五、發明說明(2) 於將銅板嵌固 雖然將小 輕的重量條件 高導熱性質的 將具有高導熱 使散熱性能獲 9 1 1 0 6 7 8 0號、 述傳統散熱結 、、>姨些前申 導超導管結合 導超導營與金 方式將熱傳導 方式岣必須以 才果具進行壓鑄 與熱傳導超導 利用高遮來結 料的您點必須 壓,在製造過 管:體造成的 傳導性能,因 到車父大的限制 超導塊、片。 本發明即 的缺失再加以 於鋁材質散 厚度的銅板 下提昇導熱 物體結合在 性質的材料 得進一步的 91110345、 構所存在的 請案都有一 金屬塊或片 屬塊片、蓋 超導管與金 而溫將金屬 成型,或是 管結合在一 合’因此所 高於金屬的 程中更必須 影響,其是 此其產品的 ’製造成本 熱片的設計。 嵌植於鋁材質 性能的效果, 铭材質之類的 製成機器或機 提昇。本案發 9 1 1 0 6 0 84號申 缺失。 個共同的特色 、蓋體,所不 體的結合方式 屬塊、片、蓋 的熔融與熱傳 採用粉末冶金 起並形成導熱 選擇用來製造 炫點,而且必 考慮溫度及壓 否會影響熱傳 良率較低,因 較南,而且無 的散熱片具有在較 但如果能將具有更 散熱片,或是直接 具的外殼,則更能 明人先前所申請之 請案均在於解決前 ,即在於利 同者僅在於 。但無論是 體結合,其 導超導管一 的技術將金 塊、片,由 熱傳導超導 須能Ί几南溫 力的變化對 導超導管、 而材料選性 法製造出精 用熱傳 將熱傳 以何種 結合的 起放入 屬材料 於必須 管的材 與高 金屬 體的熱 範圍受 密的熱 是再針對該些前申請案在製造過程中所存在 改良者。Page 4 1242403 > V. Description of the invention (2) Although the copper plate is embedded, although it is small and light weight, the high thermal conductivity property will have high thermal conductivity and the heat dissipation performance will be 9 1 1 0 6 7 8 0. 、, > A few of the previous application of superconducting catheters combined the superconducting superconducting battalion and the gold method. The heat conduction method must be used for die casting and heat conduction. The superconductor using high shielding must be pressed. Tube: The conduction performance caused by the body is limited to the superconducting block and sheet of the car. The lack of the present invention is further added to the copper plate under the aluminum material to enhance the thermal conductivity. The combination of the material and the nature of the material is further advanced. Warmly forming metal, or combining tubes together, so it must be affected in the process of being higher than metal, which is the design of this product's manufacturing cost hot sheet. Embedded in the performance of the aluminum material, the material is made of a machine or a machine. Application 9 1 1 0 6 0 84 in this case is missing. A common feature, the cover body, the combination of the other is the block, sheet, cover melting and heat transfer using powder metallurgy and forming a heat transfer option to create dazzling points, and must consider whether temperature and pressure will affect heat transfer The yield rate is lower, because it is more south, and there is no heat sink. But if you can have a more heat sink, or a shell directly, it will be more clear that the previous applications are before the settlement, that is, Li Tong lies in the same. However, whether it is a body combination, its technology of superconducting catheter one will convert gold nuggets and sheets to thermally conductive superconductors, which can change the temperature and force of a few nanometers. What kind of combination is put into the metal material must be the material of the tube and the high metal body in the thermal range of the dense heat is the aim of these previous applications in the manufacturing process improvements.

第5頁 1242403 五、發明說明(3) 【發明之綜合說明】 本發明之主要目的在提供一種以電鍍方式製造熱超導 塊、片之方法,主要係利用電鍍的原理將具有良好導熱性 質的金屬材料沉積附著於熱傳導超導管的表面,最後再將 所附著的金屬加工成型出所需要的導熱塊、片的形狀,使 得在製造過程中不需要考慮溫度與壓力變化對熱傳導超導 管之傳熱性能的影響,可據以提昇產品的良率,更可以製 造出精密的成品者。 基於此,本發明所提供之以電鍍方式製造熱超導塊、 片之方法,首先必須選用熱傳導超導管、體以及含金屬離 子之電解液,然後將該熱傳導超導管、體連接於直流電之 陰極,並且使該熱傳導超導管、體沉浸於該電解液中,再 通入直流電一段時間,以在熱傳導超導管、體的表面附著 金屬形成導熱塊、片,待斷電取出成品後,將成品加工成 所需導熱塊之形狀。 茲配合下列圖式將本發明之其它目的及功能做進一步 的說明。 【實施例說明】 參閱弟^一圖之流程圖以及配合弟《—圖之成品所不’本 發明所提供之以電鍍方式製造熱超導塊、片之方法,係包 括有以下的步驟: a.選用熱傳導超導管、體1以及含金屬離子之電解液。Page 5 1242403 V. Description of the invention (3) [Comprehensive description of the invention] The main purpose of the present invention is to provide a method for manufacturing thermal superconducting blocks and sheets by electroplating, which is mainly based on the principle of electroplating. Metal materials are deposited and attached to the surface of the heat-conducting superconducting tube, and finally the attached metal is processed into the shape of the required heat-conducting block and sheet, so that the heat transfer performance of the heat-conducting superconducting tube need not be considered during the manufacturing process. The effect can be used to improve the yield of the product, and can also produce precision finished products. Based on this, the method provided by the present invention for manufacturing thermal superconducting blocks and sheets by electroplating must first select a thermally conductive superconducting tube, a body and an electrolyte containing metal ions, and then connect the thermally conductive superconducting tube and a body to a cathode of a direct current. And immerse the heat-conducting superconducting tube and the body in the electrolyte, and then apply direct current for a period of time to attach metal to the surface of the heat-conducting superconducting tube and the body to form a thermally conductive block and sheet. After the power is removed, the finished product is processed. Into the shape of the required thermal block. Other objects and functions of the present invention will be further explained with the following drawings. [Embodiment description] Refer to the flow chart of the figure and the method of manufacturing the superconducting block and sheet by electroplating provided by the present invention. The method includes the following steps: a .Select heat conducting superconduit, body 1 and electrolyte containing metal ions.

1242403 五、發明說明(4) b. 將該熱傳導超導管、體1連接於直流電之陰極,並且使 該熱傳導超導管、體1沉浸於該電解液中。 c. 通入直流電一段時間’以在該熱傳導超導管、體1的表 面附著金屬形成導熱塊、片2。 d. 斷電取出成品。 e. 將成品加工成所需導熱塊之形狀。 所述熱傳導超導管、體1可以是圓形管或矩形管,因 而可以依其表面的形狀沉積附著成如第二圖所示的圓柱形 金屬塊、片2,或是如第三圖所示的矩形金屬塊、片2。成 型後的金屬塊、片2則可以再加工成如第四圖所示具有複 數鰭片的散熱片3。 所述的熱傳導超導管、體係可以採用抗壓度與抗溫度 均較低但可自由彎折或變形之金屬管、體(例如銅、鋁或 其它金屬管體)以降低成本;所述充填於金屬管、體内的 熱傳導超導材料係一種具有高速熱傳導性能之材料,例 如: 1、 無機高溫超導化合物材料,例如:紀鋇銅氧化合物( YBC0 )超導材料、鉈鋇鈣銅氧化合物(TBCC0 )超導材1242403 V. Description of the invention (4) b. Connect the heat-conducting superconductor and body 1 to the cathode of the direct current, and immerse the heat-conducting superconductor and body 1 in the electrolyte. c. Direct current is applied for a period of time 'to attach a metal to the surface of the heat-conducting superconduit and the body 1 to form a heat conducting block and a sheet 2. d. Power off and remove the finished product. e. Process the finished product into the shape of the required thermal block. The heat-conducting superconduit and the body 1 may be a circular tube or a rectangular tube, and thus may be deposited and attached as a cylindrical metal block, a sheet 2 as shown in the second figure, or as shown in the third figure Of rectangular metal blocks, pieces 2. The formed metal block and fin 2 can be further processed into a heat sink 3 having a plurality of fins as shown in the fourth figure. The heat-conducting superconducting pipe and system can use metal pipes and bodies (such as copper, aluminum or other metal pipe bodies) that have low pressure resistance and temperature resistance but can be freely bent or deformed; the filling in The metal tube and the body's heat-conducting superconducting material are materials with high-speed heat-conducting properties, such as: 1. Inorganic high-temperature superconducting compound materials, such as: barium copper oxide compounds (YBC0) superconducting materials, barium calcium copper oxide compounds (TBCC0) Superconducting material

料、汞鋇I弓銅氧化合物(HBCC0 )超導材料、麵錄彡弓銅氧 化合物(BSCC0 )超導材料、或其他無機超導材料。 2、 有機超導材料,例如:純水或其它有機超導材料。 3、 其它可達到高速熱傳導性材料。 當該熱傳導超導材料充填於金屬管、體内後,係將 管、體加工封閉,以防止所述的導熱材料漏出管體;藉由Materials, mercury barium I bow copper oxide compound (HBCC0) superconducting material, surface recording bow copper oxide compound (BSCC0) superconducting material, or other inorganic superconducting materials. 2. Organic superconducting materials, such as pure water or other organic superconducting materials. 3. Other materials that can achieve high-speed thermal conductivity. After the heat-conducting superconducting material is filled in the metal tube and the body, the tube and the body are closed to prevent the heat-conducting material from leaking out of the tube body;

第7頁 1242403 五、發明說明(5)Page 7 1242403 V. Description of the invention (5)

所述的金屬管、體與包含在其内部的導熱材料構成熱傳導 超導管、體;以上所述無機高超導材料其所應用的原理, 係利用管、體内的分子受熱時產生之高速震盪與摩擦,讓 熱能以波動方式快速熱傳,有機南溫超導材料,其所應用 的原理,係利用金屬管、體内液體的分子受熱時產生之相 變化而快速傳熱,因傳輸速度非常快,故稱為「熱傳導超 導管、體」,且因熱傳導超導管、體由熱端傳輸至冷端之 傳輸時間很短,因此熱端與冷端之溫差很小,可達到最佳 導熱效果。經實驗證實,其傳熱的速率約為銅的五倍以, 更較一般鋁金屬之傳熱速度快十倍以上。 藉由前述本發明的方法,其可以先將金屬管、體彎曲 成迴彎形狀或其它立體形狀後,再將單支或複數支熱傳導 超導管、體連接於直流電的陰極並且放入含有金屬離子的 電解液中,然後通入直流電,使得電解液中的金屬離子沉 積附著於熱傳導超導管1的表面而形成金屬塊、片2,該金 屬塊、片則可以依所需要的形狀再施以切割或其它方式的 加工。The metal tube, the body and the heat-conducting material contained in the metal tube and the body constitute a heat-conducting superconducting tube and a body; the above-mentioned principle of the application of the inorganic high-superconducting material uses the high-speed vibration generated when the molecules in the tube and the body are heated. And friction to allow rapid heat transfer in a fluctuating manner. Organic south temperature superconducting materials, the principle of which is applied, is based on the use of phase changes generated when the molecules of the liquid in the metal tube and the body are heated to transfer heat quickly. It ’s fast, so it is called “heat-conducting super-conduit and body”, and because the heat-conducting super-conduit and body transfer time from the hot end to the cold end is very short, the temperature difference between the hot end and the cold end is very small, which can achieve the best heat conduction effect. . It has been confirmed by experiments that the heat transfer rate is about five times that of copper, and more than ten times faster than that of ordinary aluminum metals. With the aforementioned method of the present invention, it is possible to bend a metal tube or a body into a bent shape or other three-dimensional shape, and then connect a single or multiple heat-conducting superconducting tubes and bodies to a cathode of a direct current and put metal ions into them. And then direct current is applied to make the metal ions in the electrolyte deposit and adhere to the surface of the heat-conducting superconducting tube 1 to form metal blocks and sheets 2. The metal blocks and sheets can be cut according to the required shape Or other processing.

藉由前述本發明之方法所製成的熱超導導熱塊、片, 主要是用於將熱源的熱量傳導到另外的散熱元件,以提昇 導熱效率者;例如,其可以將熱超導導熱塊、片的一端接 觸於熱源,而熱超導導熱塊、片的另一端則接觸於散熱片 或機殼等部位,以將熱量傳導到較容易散熱的元件再配合 風扇進行散熱,其適合於熱源所在之位置較狹小而不易裝 設散熱元件的設備,或是需要將熱量再分散傳導以提昇散The thermal superconducting thermal block and sheet made by the method of the present invention are mainly used to conduct heat from a heat source to another heat dissipation element to improve thermal conduction efficiency; for example, it can transfer the thermal superconducting thermal block One end of the sheet is in contact with the heat source, while the other end of the sheet is in contact with the heat sink or the case to conduct heat to the more easily radiated components and cooperate with the fan to dissipate the heat. It is suitable for heat sources Equipment that is located in a small place and is not easy to install heat-dissipating components, or needs to redistribute heat to improve heat dissipation

第8頁 1242403 >Page 8 1242403 >

五、發明說明(6) 熱效果者,因此,本發明對於熱傳導超導管、體也可以彎 曲成3 D立體的形狀,以因應不同環境的需要而加工成各 種形狀的熱超導導熱塊、片或零件。 以上所述者僅為用以解釋本發明之較佳實施例,並非 企圖據以對本發明作任何形式上之限制,是以,凡有在相 同之發明精神下所作有關本發明之任何修飾或變更,皆仍 應包括在本發明意圖保護之範疇。V. Description of the invention (6) For those who have thermal effects, the present invention can also bend the heat conducting superconducting tube and body into a 3D three-dimensional shape to process into various shapes of superconducting heat conducting blocks and sheets according to the needs of different environments. Or parts. The above is only used to explain the preferred embodiments of the present invention, and is not intended to limit the present invention in any form. Therefore, any modification or change related to the present invention made under the same spirit of the invention Should still be included in the scope of the present invention.

第9頁 1242403 圖式簡單說明 【圖式簡要說明】 第一圖為顯示本發明製造方法之流程圖。 第二圖為顯示本發明在熱傳導超導管、體的表面沉積附著 出圓柱形金屬之實施例立體圖。 第三圖為顯示本發明將所沉積附著出的金屬加工成型為矩 形塊體之實施例立體圖。 第四圖為顯示本發明進一步將矩形的金屬塊再加工為具有 複數鰭片之散熱片形態之實施例立體圖。 【元件符號說明】 (1 )熱傳導超導管、體 (2 )金屬塊、片 (3 )散熱片Page 9 1242403 Brief description of the drawings [Brief description of the drawings] The first figure is a flowchart showing the manufacturing method of the present invention. The second figure is a perspective view showing an embodiment in which a cylindrical metal is deposited and adhered to the surface of a heat-conducting superconduit and a body according to the present invention. The third figure is a perspective view showing an embodiment in which the deposited metal is processed into a rectangular block according to the present invention. The fourth figure is a perspective view showing an embodiment of the present invention in which a rectangular metal block is further processed into a heat sink having a plurality of fins. [Explanation of component symbols] (1) Thermally conductive superconduit, body (2) Metal block, sheet (3) Heat sink

第10頁Page 10

Claims (1)

1242403 案號 91121730 A_η 曰 修正 修正 六、申請專利範圍 1. 一種以電鍍方式製造熱超導塊、片之方法,其包括有以 下之步驟: a. 選用熱傳導超導管、體以及含金屬離子之電解液; b. 將該熱傳導超導管、體連接於直流電之陰極,並且使該 熱傳導超導管、體沉浸於該電解液中; c. 通入直流電一段時間,以在該熱傳導超導管、體的表面 附著金屬形成導熱塊、片; d. 斷電取出成品; e. 將成品加工成所需導熱塊之形狀。 #1242403 Case No. 91121730 A_η Revision 6. Application for patent scope 1. A method for manufacturing thermal superconducting blocks and sheets by electroplating, which includes the following steps: a. Selection of thermally conductive superconducting tubes, bodies and electrolysis containing metal ions B. Connect the heat-conducting superconductor and the body to the cathode of the direct current, and immerse the heat-conducting superconductor and the body in the electrolyte; c. Apply direct current for a period of time to the surface of the heat-conducting superconductor and the body Adhering metal to form heat-conducting blocks and sheets; d. Remove the finished product after power off; e. Process the finished product into the shape of the required heat-conducting block. # 第11頁Page 11
TW91121730A 2002-09-23 2002-09-23 Method for fabricating heat superconducting bumps/sheets using electroplating TWI242403B (en)

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