TW595257B - Organic electro-luminescent device and method of manufacturing the same - Google Patents

Organic electro-luminescent device and method of manufacturing the same Download PDF

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Publication number
TW595257B
TW595257B TW092117553A TW92117553A TW595257B TW 595257 B TW595257 B TW 595257B TW 092117553 A TW092117553 A TW 092117553A TW 92117553 A TW92117553 A TW 92117553A TW 595257 B TW595257 B TW 595257B
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Taiwan
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layer
organic
light
substrate
patent application
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TW092117553A
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Chinese (zh)
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Jun-Wen Chung
Hong-Ru Guo
Cheng-Chung Yang
Chun-Che Hsu
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Chi Mei Optoelectronics Corp
Kyocera Corp
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Priority to TW092117553A priority Critical patent/TW595257B/en
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Publication of TW595257B publication Critical patent/TW595257B/en
Priority to JP2004187614A priority patent/JP4674281B2/en

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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80Constructional details
    • H10K59/8791Arrangements for improving contrast, e.g. preventing reflection of ambient light

Abstract

An organic electro-luminescent device and method of manufacturing the same. The device at least consists of an electrode on a substrate, an organic functional layer, and a transparent electrode. The feature is that the organic electro-luminescent device has a light absorptive layer which is located on the transparent electrode. Because of the light absorptive layer which is formed on the transparent electrode, it can decay the incident light form outside and increase contrast.

Description

595257 五、發明說明(l) : 發明所屬之技術領域 . 本發明是有關於一種由有機電激發光(〇 r g a n i c electro-luminescent,簡稱OEL)元件及其製作方法,且 特別是有關於一種可增加對比度(c ο n t r a s t r a t i〇)的有機 電激發光元件及其製作方法。 先前技術 有機電激發光元件具有自發光、廣視角、高應答速 度、低驅動電壓、全色彩等特點,目前已可實用化,可應 用於彩色平面顯示元件,例如小型顯示面板、戶外顯示看 板、電腦及電視螢幕等。而有機電激發光元件是利用兩個 電極包夾具有發光特性的有機膜,當施加直流電壓時,電 洞會由陽極(anode)注入而電子會由陰極(cathode)注入,_ 因為外加電場所造成的電位差,使得載子(c a r r i e r )在薄 膜中移動並產生再結合,部分由電子電洞再結合所放出之 能量會將發光分子激發形成單一激態分子。當單一激態分 子釋放能量回到基態時,其中一定比例的能量會以光子的 方式放出而發光,此即為有機電激發光元件的元件原理。 以頂部發光型態(t 〇 p e m i s s i ο η )的有機電激發光元件 為例,在陽極層與玻璃基底之間還有一層反射金屬層可反 射有機發光層射出的光。此外,目前的有機電激發光元件 為了增加其對比度,大多會在作為封蓋之玻璃基底上鍍一 層鉻層(C r )作為黑色矩陣(b 1 a c k m a t r i X,簡稱Β Μ )。但此 種方式有以下問題:一是每當封裝時,玻璃基底均需對位鲁 後才能壓合封裝,但是玻璃基底如有些微移位,將會造成595257 5. Description of the invention (l): The technical field to which the invention belongs. The present invention relates to an organic electro-luminescent (Organic electro-luminescent, OEL) element and a method for manufacturing the same, and more particularly to a method that can increase Contrast (c ο ntrastrati〇) organic electro-excitation light element and manufacturing method thereof. The organic electroluminescent element of the prior art has the characteristics of self-emission, wide viewing angle, high response speed, low driving voltage, full color, etc., and has been practically used at present, and can be applied to color flat display elements, such as small display panels, outdoor display panels, Computer and TV screens. The organic electroluminescent device uses two electrodes to enclose an organic film with light-emitting properties. When a DC voltage is applied, holes will be injected from the anode and electrons will be injected from the cathode. The resulting potential difference causes carriers to move in the film and cause recombination. Part of the energy released by the recombination of the electron holes will excite the light-emitting molecules to form a single excitable molecule. When a single exciton molecule releases energy to return to the ground state, a certain proportion of the energy will be emitted in the form of photons to emit light, which is the element principle of organic electro-excitation light elements. Taking the top-emission type (t o p e m i s s i ο η) organic electroluminescent element as an example, there is also a reflective metal layer between the anode layer and the glass substrate to reflect the light emitted by the organic light emitting layer. In addition, in order to increase the contrast of current organic electroluminescent devices, most of them are plated with a chromium layer (C r) as a black matrix (b 1 a c k m a t r X, referred to as BM) on the glass substrate as a cover. However, this method has the following problems: First, whenever the packaging is performed, the glass substrate needs to be aligned to seal the package, but if the glass substrate is slightly displaced, it will cause

ill33t.wf.ptd 第7頁 595257 五、發明說明(2) 面板故障(f a i 1 u r e );另一個問題是因為需額外再對作為 封蓋的玻璃基底加工製作前述黑色矩陣,因此將造成成本 的提高。 另外,目前還有一種有機電激發光元件是在電極與有 機發光層之間或是在透明電極與有機發光層之間插入一層 暗導電金屬合金層(dark conductive metal alloy 1 a y e r ),以增加有機電激發光元件在明亮環境下的對比 發明内容 因此,本發明之目的是提供一種有機電激發光元件及 其製作方法,可在增加對比度的同時降低製造成本。 根據上述與其它目的,本發明提出一種有機電激發光籲 元件,配置於一基底上,此種有機電激發光元件至少包括 一第一電極層、一第二電極層、一有機官能層以及一光吸 收層。其中,第一電極層係配置於基底上,而有機官能層 則配置於第一電極層上,第二電極層則是配置於有機官能 層上。而本發明之光吸收層係配置於第二電極層上,用以 衰減外界入射的光,而使對比度增加。 本發明再提出一種有機電激發光元件配置於一基底 上,此種有機電激發光元件至少包括一反射金屬層、一第 一電極層、一第二電極層、一有機官能層以及一光吸收 層。其中,反射金屬層配置於基底上,第一電極層則配置 於反射金屬層上,有機官能層則係配置於第一電極層上。籲 而第二電極層則是配置於有機官能層上。光吸收層則係配ill33t.wf.ptd Page 7 595257 V. Description of the invention (2) Panel failure (fai 1 ure); Another problem is that the aforementioned black matrix needs to be processed on the glass substrate as a cover, which will cause cost improve. In addition, there is currently another type of organic electroluminescent device that inserts a dark conductive metal alloy 1 ayer between the electrode and the organic light-emitting layer or between the transparent electrode and the organic light-emitting layer to increase the COMPARISON OF ELECTROMECHANICAL EXCITATION LIGHT ELEMENTS UNDER BRIGHT ENVIRONMENTAL SUMMARY Therefore, an object of the present invention is to provide an organic electrical excitation light element and a manufacturing method thereof, which can increase the contrast and reduce the manufacturing cost. According to the above and other objectives, the present invention proposes an organic electro-optic light-emitting element disposed on a substrate. The organic electro-optical light-emitting element includes at least a first electrode layer, a second electrode layer, an organic functional layer, and a Light absorbing layer. The first electrode layer is disposed on the substrate, the organic functional layer is disposed on the first electrode layer, and the second electrode layer is disposed on the organic functional layer. The light absorbing layer of the present invention is disposed on the second electrode layer, and is used to attenuate light incident from the outside and increase the contrast. The present invention further proposes an organic electro-optic light-emitting element disposed on a substrate. The organic electro-optical light-emitting element includes at least a reflective metal layer, a first electrode layer, a second electrode layer, an organic functional layer, and a light absorption device. Floor. The reflective metal layer is disposed on the substrate, the first electrode layer is disposed on the reflective metal layer, and the organic functional layer is disposed on the first electrode layer. The second electrode layer is disposed on the organic functional layer. Light absorbing layer

lU.33twf.ptd 第8頁 595257 五、發明說明(3) 置於反射金屬層與第一電極層之間。 本發明又提出一種主動式有機電激發光元件,架構於 一基底上。此種主動式有機電激發光元件至少包括數個薄 膜電晶體、陰極隔離層、上電極、有機官能層、數種光吸 收層以及一似黑色矩陣(p s e u d 〇 - B Μ )。而薄膜電晶體是位 於基底上,其中薄膜電晶體均具有一畫素電極。陰極隔離 層則是位於基底上之每一薄膜電晶體的畫素電極之間,而 上電極則係位於陰極隔離層之間的基底上。再者,有機官 能層是位於薄膜電晶體與上電極之間。不同種類之光吸收 層則是分別覆蓋有機官能層上方之上電極且互相交疊於陰 極隔離層頂面,其中各光吸收層之互相交疊部份可作為一 似黑矩陣。 _ 本發明另外提出一種被動式有機電激發光元件,架構 於一基底上。此種有機電激發光元件陣列至少包括數條陽 極、數條陰極隔離層、數條陰極、數個有機官能層、光吸 收層以及一似黑色矩陣。其配置係陽極位於基底上、陰極 隔離層則位於基底與陽極上,且陰極隔離層之延伸方向垂 直於陽極之延伸方向。而陰極是位於陰極隔離層之間的基 底與陽極上。有機官能層則是位於陽極與陰極之間。再 者,光吸收層是位於基底上且覆蓋有機官能層上方之陰 極,而似黑色矩陣則係覆蓋陰極隔離層之頂面。 本發明又提出一種有機電激發光元件的製作方法,包 括於一基底上形成一電極,再於電極上形成一有機官能 馨 層。然後,於有機官能層上形成一透明電極,再於透明電lU.33twf.ptd Page 8 595257 5. Description of the invention (3) It is placed between the reflective metal layer and the first electrode layer. The invention also proposes an active organic electro-optical light emitting element, which is structured on a substrate. Such an active organic electro-optic light-emitting element includes at least several thin-film transistors, a cathode isolation layer, an upper electrode, an organic functional layer, several light-absorbing layers, and a black matrix (p s e u d 0-B M). The thin film transistor is located on a substrate, and each of the thin film transistors has a pixel electrode. The cathode isolation layer is between the pixel electrodes of each thin film transistor on the substrate, and the upper electrode is on the substrate between the cathode isolation layers. Furthermore, the organic functional layer is located between the thin film transistor and the upper electrode. Different types of light absorption layers cover the upper electrodes above the organic functional layer and overlap each other on the top surface of the cathode isolation layer. The overlapping portions of the light absorption layers can be used as a black matrix. _ The present invention further proposes a passive organic electro-optic light emitting element, which is structured on a substrate. Such an organic electro-optical light-emitting element array includes at least a plurality of anodes, a plurality of cathode isolation layers, a plurality of cathodes, a plurality of organic functional layers, a light-absorbing layer, and a black-like matrix. The configuration is that the anode is located on the substrate, the cathode insulation layer is located on the substrate and the anode, and the extension direction of the cathode insulation layer is perpendicular to the extension direction of the anode. The cathode is located between the substrate and the anode between the cathode separator. The organic functional layer is located between the anode and the cathode. Furthermore, the light absorbing layer is the cathode on the substrate and covers the organic functional layer, while the black-like matrix covers the top surface of the cathode isolation layer. The invention also proposes a method for manufacturing an organic electro-optic light emitting element, which includes forming an electrode on a substrate, and forming an organic functional layer on the electrode. Then, a transparent electrode is formed on the organic functional layer, and then a transparent electrode is formed.

11133twf.pt.d 第9頁 595257 五、發明說明(4) 極上形成一光吸收層,以使外界入射至有機電激發光元件 的光衰減。 本發明還提出一種有機電激發光元件的製作方法,包 括於一基底上形成一反射金屬層,再於反射金屬層上形成 一光吸收層。之後,於光吸收層上形成一電極,再於電極 上依序形成一有機官能層以及一透明電極。 再者,本發明另外提出一種主動式有機電激發光元件 的製作方法,包括提供一基底,其中具有數個薄膜電晶 體,且每一薄膜電晶體具有一畫素電極。隨後,於基底的 母一薄膜電晶體之畫素電極之間形成數條陰極隔離層。接 著,於陰極隔離層之間的晝素電極上形成數個有機官能 層,再於基底上形成一上電極層,這個上電極層係藉由陰_ 極隔離層自動分成數個電性隔離的上電極。之後,於基底 上形成數個第一光吸收層,其係互相重疊於陰極隔離層的 邊緣以作為似黑色矩陣。11133twf.pt.d Page 9 595257 V. Description of the invention (4) A light absorbing layer is formed on the electrode to attenuate the light incident on the organic electro-optical excitation element from the outside. The present invention also provides a method for manufacturing an organic electro-optic light emitting element, which includes forming a reflective metal layer on a substrate, and forming a light absorbing layer on the reflective metal layer. After that, an electrode is formed on the light absorbing layer, and an organic functional layer and a transparent electrode are sequentially formed on the electrode. Furthermore, the present invention further provides a method for manufacturing an active organic electro-optic light emitting element, which includes providing a substrate having a plurality of thin film transistors, and each thin film transistor has a pixel electrode. Subsequently, a plurality of cathode isolation layers are formed between the pixel electrodes of the mother-thin film transistor of the substrate. Next, several organic functional layers are formed on the day electrode between the cathode isolation layers, and then an upper electrode layer is formed on the substrate. This upper electrode layer is automatically divided into several electrically isolated by the cathode isolation layer. On the electrode. After that, a plurality of first light absorbing layers are formed on the substrate, and the first light absorbing layers overlap each other on the edges of the cathode isolation layer as a black-like matrix.

另外,本發明又提出一種有機電激發光元件的製作方 法,包括於一基底上形成數條陽極,再於基底與陽極上形 成數條陰極隔離層,其中陰極隔離層之延伸方向垂直於陽 極之延伸方向。接著,於陰極隔離層之間的陽極上形成數 個有機官能層,再於基底上形成一陰極層,其係藉由陰極 隔離層自動分成數條陰極,這些陰極係互相電性隔離的。 隨後,於基底上形成數個光吸收層,這些光吸收層係互相 重疊於有機官能層的邊緣,以作為似黑色矩陣。 H 本發明因為在有機電激發光元件透光部的透明電極上In addition, the present invention also provides a method for manufacturing an organic electro-optic light emitting element, which includes forming a plurality of anodes on a substrate, and forming a plurality of cathode isolation layers on the substrate and the anode, wherein an extension direction of the cathode isolation layer is perpendicular to the anode. Direction of extension. Next, several organic functional layers are formed on the anode between the cathode isolation layers, and then a cathode layer is formed on the substrate, which is automatically divided into a plurality of cathodes by the cathode isolation layer, and these cathodes are electrically isolated from each other. Subsequently, a plurality of light absorbing layers are formed on the substrate, and these light absorbing layers overlap each other on the edges of the organic functional layer as a black-like matrix. H. The present invention is because the transparent electrode

11133twf.ptd 第10頁 595257 五、發明說明(5) 或在反射金屬層與透明電極之間增加一層光吸收層,抑或 是在兩處皆形成光吸收層,所以從外界入射的光會被衰 減’而使對比度增加。另外,在有機電激發光元件陣列中 配置於陰極隔離層上的兩光吸收層之重疊部分可作為似黑 色矩陣,故於外界亮態時能夠增加對比度。 為讓本發明之上述和其他目的、特徵、和優點能更明 顯易懂,下文特舉較佳實施例,並配合所附圖式,作詳細 說明如下: 實方黾方式 本發明可應用於有機電激發光(〇 r g a n i c electro-luminescent,簡稱0 E L )元件,以下之實施例係 以頂部發光型態(t 〇 p e m i s s i ο η )的有機電激發光元件之製4 作為例,然其並非用以限定本發明,而是作為範例之用。 第一實施例 第1圖係依照本發明之第一實施例之有機電激發光元 件的製造流程步驟圖。 請參照第1圖,首先於步驟1 0 0中,於基底上形成一反 射金屬層,而反射金屬層之材質例如是铭,而基底之材質 可以是玻璃或其他適用的基底材質。接著,於步驟1 1 0 中,於一反射金屬層上形成一電極,其材質譬如是銦錫氧 化物(indium tin oxide,簡稱ΙΤ0)或者其它透明電極。 之後,於步驟1 2 0中,於電極上形成一有機官能層,其步 驊例如是於電極上先形成一電洞傳輸層(h ο 1 e t r a n s ρ 〇 r t · layer,簡稱HTL),以幫助電洞傳輸。隨後,於電洞傳輸11133twf.ptd Page 10 595257 5. Description of the invention (5) Either add a light absorption layer between the reflective metal layer and the transparent electrode, or form a light absorption layer at both places, so the light incident from the outside will be attenuated 'And increase the contrast. In addition, the overlapping portion of the two light absorbing layers arranged on the cathode isolation layer in the organic electroluminescent device array can be used as a black-like matrix, so that it can increase the contrast when the outside is bright. In order to make the above and other objects, features, and advantages of the present invention more comprehensible, the following describes the preferred embodiments in detail with the accompanying drawings, as follows: The present invention can be applied to Organic electro-luminescent (0 EL) elements. The following embodiments are based on the organic light-emitting element 4 of the top emission type (t 〇pemissi ο η) as an example, but it is not used for The invention is limited and is used as an example. First Embodiment FIG. 1 is a flow chart of a manufacturing process of an organic electro-excitation light-emitting device according to a first embodiment of the present invention. Please refer to FIG. 1. First, in step 100, a reflective metal layer is formed on the substrate. The material of the reflective metal layer is, for example, Ming, and the material of the substrate may be glass or other suitable substrate material. Next, in step 110, an electrode is formed on a reflective metal layer, and the material is, for example, indium tin oxide (ITO) or other transparent electrodes. After that, in step 120, an organic functional layer is formed on the electrode. For example, a hole transport layer (h ο 1 etrans ρ 〇rt · layer, referred to as HTL) is first formed on the electrode to help Hole transmission. Then, in the hole

11133rwf.ptd 第11頁 595257 五、發明說明(6) 層上形成一有機發光層(emitting layer,簡稱E ML),再 於有機發光層上形成一電子傳輸層(electron transport 1 a y e r ,簡稱E T L ),以幫助電子傳輸。另外,還可以在電 洞傳輸層形成之前先於電極上形成一電洞注入層(h ο 1 e i n j e c t i n g 1 a y e r,簡稱Η I L ),其功用在於在電壓低時仍 可將電洞注入發光層。另外,在電子傳輸層形成之後,可 先於電子傳輸層上形成一電子注入層(electron i n j e c t i n g 1 a y e r ,簡稱E I L ),以幫助電子的注入。 接著,於步驟1 3 0中,於有機官能層上形成一透明電 極。之後,於步驟1 4 0中,於透明電極上形成一光吸收 層,其步驟譬如是在透明電極上方鍍上一層染料或顏料, 而光吸收層所顯示的顏色較佳是與有機官能層所發出的顏馨 色相同,以限制從有機官能層所發出的光的顏色,而對有 機電機發光元件的色飽和度有助益,且發出不同顏色光的 有機官能層間不會有混色的現象發生。 另外,以頂部發光型態的有機電激發光元件之製作為 例,還可以於步驟1 0 0與步驟1 1 0之間進行步驟1 0 2,於一 反射金屬層上形成另一層光吸收層,以使外界入射至有機 電激發光元件的光衰減,進而增加外界為亮態時有機電激 發光元件的對比度。 而根據第一實施例所製作的有機電激發光元件如第2 圖所示。 第2圖係依照本發明之第一實施例製得之有機電激發_ 光元件的剖面示意圖。請參照第2圖,本實施例之有機電11133rwf.ptd Page 11 595257 V. Description of the invention (6) An organic light emitting layer (e-ML) is formed on the layer, and an electron transport layer (electron transport 1 ayer, ETL) is formed on the organic light-emitting layer. To help with electronic transmission. In addition, a hole injection layer (h ο 1 e i n j c t i n g 1 a y e r (referred to as Η I L)) may be formed on the electrode before the hole transport layer is formed. Its function is to inject holes into the light emitting layer when the voltage is low. In addition, after the electron transport layer is formed, an electron injection layer (electron i n j e c t i n g 1 a y e r, abbreviated as E I L) may be formed on the electron transport layer to help electron injection. Next, in step 130, a transparent electrode is formed on the organic functional layer. Then, in step 140, a light absorbing layer is formed on the transparent electrode. The step is, for example, plating a layer of dye or pigment on the transparent electrode, and the color displayed by the light absorbing layer is preferably the same as that of the organic functional layer. The color of the emitted Yan Xin is the same to limit the color of the light emitted from the organic functional layer, which is helpful to the color saturation of the organic motor light-emitting element, and there is no color mixing between the organic functional layers that emit light of different colors. . In addition, taking the production of a top-emission type organic electro-excitation light-emitting device as an example, step 102 can also be performed between step 100 and step 110, to form another layer of light absorption on a reflective metal layer. To attenuate the light incident on the organic electroluminescent device from the outside, thereby increasing the contrast of the organic electroluminescent device when the external environment is bright. The organic electro-optical light-emitting device manufactured according to the first embodiment is shown in FIG. 2. FIG. 2 is a schematic cross-sectional view of an organic electro-excitation optical device made according to the first embodiment of the present invention. Please refer to FIG. 2, the organic electricity of this embodiment

11133twf.ptd 第12頁 595257 五·•發明說明(7) 激發光元件係架構於一基底2 0 0上,此一有機電激發光元 件中包括一有機官能層206 、一第一電極層202、一第二電 極層204以及至少一光吸收層220a或220b,其中基底200之 材質可以是玻璃或其他適用的基底材質,而第一與第二電 極層2 0 2、2 0 4之材質譬如是銦錫氧化物(I T 0 )或者其它透 明電極。而第一電極層2 0 2以及第二電極層2 0 4係分別配置 於有機官能層206兩面作為陰極與陽極之用,其中當本發 明之有機電激發光元件的透光部譬如是在第一電極層2 0 2 那一面;也就是說,第一電極層2 0 2為透明材質時,本發 明之光吸收層220b可配置於第一電極層202與基底200之 間,以增加有機電激發光元件的對比度與色飽和度。 此外,當透光部是在第二電極層2 0 4那一面時,即本φ 發明應用於頂部發光型態的有機電激發光元件時,還可以 在第一基底200與第一電極層202之間配置一反射金屬層 2 0 8,例如鋁,用以反射有機發光層2 0 6射出的光。不過這 種結構在外界為亮態時會有對比不明顯的問題,所以可於 反射金屬層208與第一電極層202之間配置另一光吸收層 2 0 2 b,以使外界入射至有機電激發光元件的光衰減,進而 增加外界為亮態時的對比度。另外,在第一電極層2 0 2與 反射金屬層2 ◦ 8之間的光吸收層2 0 2 b還可作為隔離結構 (insulator) 〇 另外,本發明之有機電激發光元件中的有機官能層 206至少需包括一有機發光層,而更可包括一電子傳輸 參 層,位於有機發光層與第二電極層2 0 4之間以及一電洞傳11133twf.ptd Page 12 595257 V. Description of the invention (7) The excitation light element is structured on a substrate 200. This organic electrical excitation light element includes an organic functional layer 206, a first electrode layer 202, A second electrode layer 204 and at least one light absorbing layer 220a or 220b. The material of the substrate 200 may be glass or other suitable substrate materials, and the materials of the first and second electrode layers 2 0 2 and 2 0 4 are, for example, Indium tin oxide (IT 0) or other transparent electrodes. The first electrode layer 202 and the second electrode layer 204 are respectively disposed on both sides of the organic functional layer 206 as a cathode and an anode. The light-transmitting portion of the organic electro-optical light-emitting element of the present invention is An electrode layer 2 02 side; that is, when the first electrode layer 202 is a transparent material, the light absorbing layer 220b of the present invention may be disposed between the first electrode layer 202 and the substrate 200 to increase organic electricity. Contrast and color saturation of the excitation light element. In addition, when the light-transmitting portion is on the side of the second electrode layer 204, that is, when the φ invention is applied to an organic electroluminescent device with a top emission type, the first substrate 200 and the first electrode layer 202 may also be used. A reflective metal layer 208, such as aluminum, is disposed therebetween to reflect light emitted from the organic light emitting layer 206. However, this structure has a problem that the contrast is not obvious when the outside is bright, so another light absorbing layer 2 0 2 b can be arranged between the reflective metal layer 208 and the first electrode layer 202 to make the outside incident The light of the electromechanical excitation light element is attenuated, thereby increasing the contrast when the outside world is bright. In addition, the light absorbing layer 2 0 2 b between the first electrode layer 202 and the reflective metal layer 2 ◦ 8 can also be used as an insulator. In addition, the organic function in the organic electro-optic light-emitting device of the present invention The layer 206 needs to include at least an organic light-emitting layer, and may further include an electron-transport parameter layer, which is located between the organic light-emitting layer and the second electrode layer 204 and an electric hole transmission.

11133twf.ptd 第13頁 595257 五、發明說明(8) 輸層,位於有機發光層與第一電極層2 0 2之間。再者,位 於電子傳輸層與第二電極層204之間可配置一電子注入 層。而在電洞傳輸層與第一電極層2 0 2之間可再配置一電 洞注入層。 第二實施例 本發明尚可應用於具有陰極隔離層的主動式有機電激 發光元件以及被動式有機電激發光元件及前述兩者之製作 方法,以下為詳細的實施例說明。 第3 A圖係依照本發明之第二實施例之主動式有機電激 發光元件的上視示意圖。 請參照第3 A圖,本實施例之主動式有機電激發光元件 3 0 0包括掃描配線3 1 2、資料配線3 1 4、薄膜電晶體3 0 1 、陰·[ 極隔離層(separator)310、上電極、有機官能層306、數 種光吸收層以及似黑色矩陣(pseudo-BM),其中部分構件 將於之後的製程部分詳述。薄膜電晶體3 0 1係位於一基底 (未繪示)上交錯的掃描配線3 1 2與資料配線3 1 4所劃分的區 域中,其中薄膜電晶體30 1均具有一畫素電極3 0 2 ,係作為 主動式有機電激發光元件3 0 0之下電極。而陰極隔離層3 1 0 則位於基底上之每一薄膜電晶體3 0 1的畫素電極3 0 2之間。 上電極(未繪示)則係配置於陰極隔離層3 1 0之間的基底 上。而有機官能層3 0 6則是位於畫素電極3 0 2與上電極之 間。 再者,請繼續參照第3 A圖,本實施例之各種光吸收層β 分別覆蓋有機官能層3 0 6上方之上電極且互相交疊於陰極11133twf.ptd Page 13 595257 V. Description of the invention (8) The transport layer is located between the organic light emitting layer and the first electrode layer 202. Furthermore, an electron injection layer may be disposed between the electron transport layer and the second electrode layer 204. A hole injection layer may be further disposed between the hole transport layer and the first electrode layer 202. Second Embodiment The present invention can also be applied to active organic electroluminescence light emitting elements and passive organic electroluminescence light elements having a cathode isolation layer, and a method for manufacturing the foregoing two. The detailed embodiments are described below. FIG. 3A is a schematic top view of an active organic electroluminescent device according to a second embodiment of the present invention. Please refer to FIG. 3A. The active organic electroluminescent element 3 0 0 of this embodiment includes scanning wiring 3 1 2, data wiring 3 1 4, thin film transistor 3 0 1, female and [electrode separator (separator) 310. The upper electrode, the organic functional layer 306, several kinds of light absorbing layers, and a pseudo-BM. Some components will be described in detail in the subsequent manufacturing process. The thin film transistor 3 0 1 is located in a region divided by the scanning wiring 3 1 2 and the data wiring 3 1 4 interlaced on a substrate (not shown), in which the thin film transistor 30 1 has a pixel electrode 3 0 2 , As the lower electrode of the active organic electro-optical light element 300. The cathode isolation layer 3 1 0 is located between the pixel electrodes 3 2 of each thin film transistor 3 0 1 on the substrate. The upper electrode (not shown) is disposed on the substrate between the cathode isolation layers 3 10. The organic functional layer 3 06 is located between the pixel electrode 30 2 and the upper electrode. Furthermore, please continue to refer to FIG. 3A. The various light absorbing layers β of this embodiment respectively cover the upper electrodes above the organic functional layer 3 06 and overlap each other on the cathode.

11133r.wf.ptd 第14頁 595257 五、發明說明(9) 隔離層3 1 0頂面,其中光吸收層之互相交疊部份可作為似 黑色矩陣(未繪示)。另外,還可以在畫素電極3 0 2下方配 置一反射金屬層(未繪示),再於反射金屬層與畫素電極 3 0 2之間選擇性地配置另一光吸收層,以使外界入射至主 動式有機電激發光元件3 0 0的光衰減,進而增加外界為亮 態時元件的對比度。另外,本實施例之有機官能層3 0 6的 組成配置可參照第一實施例的有機官能層。 而前述之主動式有機電激發光元件的製作譬如第4 A圖 至第4 F圖所示,其係依照第3 A圖所繪示之有機電激發光元 件的A - A ’剖面製造流程示意圖。請參照第4 A圖,提供一基 底4 0 0 ,其中具有數個薄膜電晶體,其中每一薄膜電晶體 具有一畫素電極4 0 3。此外,當本發明應用於頂部發光型肇 態的有機電激發光元件之製作時,還可以多形成一反射金 屬層,或是如第4 A圖直接選用合適材質(例如··鋁)的畫素 電極403作為反射金屬層。之後,再於反射金屬層上選擇 性地形成一光吸收層4 0 1。 之後,請參照第4 B圖,於基底4 0 0的每一薄膜電晶體 之畫素電極4 0 3之間形成數條陰極隔離層4 1 0 ,其中陰極隔 離層4 1 0最好是一具有逆斜度的倒梯形結構體(t a p e r s t r u c t u r e ),且其材質譬如是絕緣材料或是透明的材質。 陰極隔離層4 1 0在此處可防止畫素電極4 0 3與之後形成的上 電極之間的交互干擾(c r 〇 s s t a 1 k )。 接著,請參照第4 C圖,於陰極隔離層4 1 0之間的畫素_ 電極4 0 3上形成數個有機官能層4 0 6,其中有機官能層4 0 611133r.wf.ptd Page 14 595257 V. Description of the invention (9) The top surface of the isolation layer 3 1 0, where the overlapping portions of the light absorption layer can be used as a black-like matrix (not shown). In addition, a reflective metal layer (not shown) may be disposed below the pixel electrode 3 02, and then another light absorption layer may be selectively disposed between the reflective metal layer and the pixel electrode 3 02 to make the outside world The light incident on the active organic electroluminescent element 300 is attenuated, thereby increasing the contrast of the element when the outside is bright. In addition, for the composition configuration of the organic functional layer 306 in this embodiment, reference may be made to the organic functional layer in the first embodiment. The fabrication of the aforementioned active organic electroluminescent device is shown in FIGS. 4A to 4F, which are schematic diagrams of the manufacturing process of the AA ′ cross section of the organic electroluminescent device shown in FIG. 3A. . Referring to FIG. 4A, a substrate 400 is provided, which has a plurality of thin film transistors, each of which has a pixel electrode 403. In addition, when the present invention is applied to the production of a top-emission organic electroluminescent element, an additional reflective metal layer may be formed, or a picture made of a suitable material (such as aluminum) may be directly selected as shown in FIG. 4A. The element electrode 403 functions as a reflective metal layer. After that, a light absorbing layer 401 is selectively formed on the reflective metal layer. Then, referring to FIG. 4B, a plurality of cathode isolation layers 4 1 0 are formed between the pixel electrodes 4 0 3 of each thin film transistor of the substrate 400, and the cathode isolation layer 4 1 0 is preferably one An inverted trapezoid structure with a reverse slope, and the material is, for example, an insulating material or a transparent material. The cathode isolation layer 4 1 0 can prevent cross interference between the pixel electrode 4 0 3 and an upper electrode formed later (c r s s t a 1 k). Next, referring to FIG. 4C, a plurality of organic functional layers 4 0 6 are formed on the pixel_electrode 4 0 3 between the cathode isolation layers 4 1 0, wherein the organic functional layers 4 0 6

I1133twf.ptd 第15頁 595257 五、發明說明(ίο) 至少是顯示相同顏色或顯示不同顏色的有機發光層,主要 是取決於由於有機電激發光元件依據顯示色彩可分為是單 一色彩或多彩的。而且,形成有機官能層4 0 6的方式譬如 是利用具有開口的光罩作為罩幕,並將其罩幕開口對準欲 形成有機官能層4 0 6的區域(請見第3圖之標號3 0 6 ),再進 行有機官能層4 0 6的成長。因此,如果有機電激發光元件 是多彩(如紅、綠、藍三原色排列)顯示的,則可利用移動 式罩幕,於不同區域中形成顯示不同顏色的有機發光層。 隨後,請參照第4 D圖,於基底4 0 0上形成一上電極層 404,且上電極層404係藉由陰極隔離層410而自動分成數 條上電極4 0 4 a 、4 0 4 b,這些上電極4 0 4 a與4 0 4 b係互相電性 隔離。 _ 之後,請參照第4 E圖與第4 F圖,於基底4 0 0上形成數 層光吸收層420a與420b,且其覆蓋有機官能層406上方之 上電極404a與部分陰極隔離層410,這些光吸收層420a與 4 2 0 b係於有機官能層4 0 6的邊緣互相重疊作為似黑色矩 陣。舉例來說,當本實施例之有機發光層4 0 6所發出的光 是兩兩相異時,則如第4 E圖所示,先於基底4 0 0上形成第 一層光吸收層420a,且其僅供與其下方之有機官能層406 所發出的光相同顏色的光通過。然後,如第4 F圖所示,於 基底400上再形成第二層光吸收層420b ,其t第一層與第 二層光吸收層420a、420b於有機官能層406的邊緣之陰極 隔離層4 1 0頂面互相重疊,所以其重疊部位4 4 0不會有漏光® 而可作為似黑色矩陣。I1133twf.ptd Page 15 595257 V. Description of the Invention (ίο) At least organic light-emitting layers that display the same color or different colors are mainly determined by the fact that organic electro-luminescent elements can be classified as single or colorful according to the display color . In addition, the method of forming the organic functional layer 406 is, for example, using a photomask with an opening as a mask, and aligning the opening of the mask with the area where the organic functional layer 4 06 is to be formed (see reference numeral 3 in FIG. 3). 0 6), and then the organic functional layer 406 is grown. Therefore, if the organic electroluminescent elements are displayed in multiple colors (such as the three primary colors of red, green, and blue), a mobile mask can be used to form organic light-emitting layers that display different colors in different areas. Subsequently, referring to FIG. 4D, an upper electrode layer 404 is formed on the substrate 400, and the upper electrode layer 404 is automatically divided into a plurality of upper electrodes 4 0 4 a and 4 0 4 b by a cathode isolation layer 410. These upper electrodes 4 0 4 a and 4 4 b are electrically isolated from each other. _ After that, referring to FIGS. 4E and 4F, several layers of light absorbing layers 420a and 420b are formed on the substrate 400, and they cover the upper electrode 404a and part of the cathode isolation layer 410 above the organic functional layer 406. These light absorbing layers 420a and 4 2 0 b are superimposed on each other at the edges of the organic functional layer 406 as a black-like matrix. For example, when the light emitted by the organic light emitting layer 406 in this embodiment is different from each other, as shown in FIG. 4E, a first light absorbing layer 420a is formed on the substrate 400 , And it can only pass light of the same color as the light emitted by the organic functional layer 406 below it. Then, as shown in FIG. 4F, a second light absorbing layer 420b is formed on the substrate 400, which is a cathode isolation layer of the first and second light absorbing layers 420a and 420b on the edge of the organic functional layer 406. The top surface of 4 1 0 overlaps with each other, so its overlapping part 4 4 0 can be used as a black-like matrix without light leakage.

11133twf.ptd 第16頁 發明說明(11) 另外’第3 B圖則係依照本發明# 有機電激發光元件的上視示意圖。之弟二實施例之被動式 。月參A?、弟J3 β圖,本實施例之 3 0 0至少包括數條陽極3 〇 2、數 式有機電激發光元件 極3 0 4、數個有機官能層3 〇 6、數^氺1^離層3 1 0、數條陰 似黑色矩陣(未繪示),其中部分吸收層(未繪示)以及 述。陽極3 0 2係位於一基底(未怜示將於之後的剖面圖詳 陰極隔離層3 10之延伸方向垂直於陪\於基底30 〇上,且 者,降怀乂 直於^極302之延伸方向。再 君哈極3 0 4疋位於陰極隔離層3 1 〇之門从曾广卞也上 再 上。而有機官能層306則是位於陽極3n9 j圣302 之阶η/ V/之光吸收層是覆蓋於有機官能層3 0 6上方醤 :陰極3 0 4 ’而似黑色矩陣則係覆蓋陰極隔離層31〇之頂· 發光L: ϊ ί Ϊ動ΐ有機電激發光元件與主動式有機電激 ^ ^兀件的1作之差別僅在於被動式的陰極隔離層31〇是 形成於基底與陽極3Q2上。 ,第5圖係依照第3 Β圖所繪示之有機電激發光元件的 B 一 \,面不意圖。請參照第5圖,被動式有機電激發光元 件係,構於一基底4〇〇上,其中至少包括數條位於基底4 〇〇 上的陽極4 0 2、數條位於基底4 〇 〇與陽極4 〇 2上的陰極隔離 層410。另外’於陰極隔離層41〇之間的基底4〇〇與陽極4〇2 上有數條陰極4 0 4 a與4 0 4b,而有機官能層4 0 6則位於陽極| 4 0 2與陰極4 〇4a之間。再者,光吸收層4 2 0 a、4 2 0 b配置於11133twf.ptd Page 16 Description of the invention (11) In addition, the third diagram B is a schematic top view of an organic electro-excitation light element according to the present invention. The second embodiment of the passive type. Monthly reference A ?, younger J3 β chart, 300 in this embodiment includes at least a number of anodes 3 0 2, the number of organic electro-optic excitation element poles 3 0 4, a plurality of organic functional layers 3 0 6, a number ^ 氺1 ^ 离层 3 1 0, several negative black matrix (not shown), some of which are absorption layers (not shown) and described. The anode 3 0 2 is located on a substrate (not shown in detail in a later section). The extension direction of the cathode isolation layer 3 10 is perpendicular to the substrate 30 0, and the lower part is straight to the extension of the electrode 302. Orientation. The gate of the anode 3 0 4 is located at the cathode isolation layer 3 1 〇 from Zeng Guangye, and the organic functional layer 306 is a light absorption layer at the anode 3n9 j Saint 302 level η / V /. It is covered on top of the organic functional layer 306: the cathode 3 0 4 ', and the black-like matrix covers the top of the cathode isolation layer 31 °. Luminescence L: ί ί Ϊ Ϊ ΐ organic electro-excitation light element and active organic electricity The only difference between the first and second excitations is that the passive cathode isolation layer 31 is formed on the substrate and the anode 3Q2. Fig. 5 is the B of the organic electro-excitation light element shown in Fig. 3B. \ , The surface is not intended. Please refer to FIG. 5. The passive organic electro-optic light-emitting element system is constructed on a substrate 400, which includes at least a plurality of anodes 4 2 on the substrate 4 2 and a plurality of substrates on the substrate. The cathode isolation layer 410 on the anode 400 and the anode 400. In addition, There are several cathodes 4 0 4 a and 4 4 b on the substrate 4 0 and the anode 4 2, and the organic functional layer 4 6 is located between the anode | 4 2 and the cathode 4 0a. Furthermore, the light absorbing layer 4 2 0 a, 4 2 0 b

595257 五、發明說明(12) 基底400上,且覆蓋有機官能層406上方之陰極404a。而本 發明之似黑色矩陣4 4 0則覆蓋陰極隔離層4 1 0之頂面。 另外,請繼續參照第5圖,當本實施例應用於頂部發 光型態的被動式有機電激發光元件陣列時,還可以在陽極 402下方配置一反射金屬層403 ,再於反射金屬層403與陽 極4 0 2之間選擇性地配置另一層光吸收層4 0 1 ,以使外界入 射至有機電激發光元件的光衰減,進而增加外界為亮態時 元件的對比度。另外,本實施例之有機官能層4 0 6的組成 配置可參照第一實施例的有機官能層。 而且,前述在基底400上形成互相重疊於陰極隔離層 410頂面的光吸收層4 2 0a與4 2 0b (請見第4E圖、第4F圖與第 5圖)時所使用的罩幕開口必須比在畫素單元中形成有機發φ 光層4 0 6 (請見第4 C圖)時所使用的罩幕開口大。以第6圖為 例,其係一畫素單元及製作本發明之有機發光層與光吸收 層的罩幕開口 ,請參照第6圖,假設一具有顯示紅、綠、 藍色的晝素單元6 0 0之長寬均為X,則形成其中之一種色彩 的有機發光層所使用的罩幕開口 5 1 0的長寬X π 、X’則需符 合下式: X’丨 <χ ;χ’<χ/3 而形成單一光吸收層所使用的罩幕開口 5 2 0之長寬y "、y ’ 的範圍則如下式: (x/2)_(x,/2)<y,《2x/3)-x,;(3x/2) -(x,,/2)<y”<2x-x" 因此,本發明之特點係在有機電激發光元件透光部 透明電極上或在反射金屬層與透明電極之間增加一層光吸595257 5. Description of the invention (12) The cathode 404a on the substrate 400 and covering the organic functional layer 406. The black matrix 4 4 0 of the present invention covers the top surface of the cathode isolation layer 4 1 0. In addition, please continue to refer to FIG. 5. When this embodiment is applied to a passive organic electroluminescent device array of a top emission type, a reflective metal layer 403 can be further disposed under the anode 402, and then the reflective metal layer 403 and the anode can be disposed. Another layer of light absorbing layer 4 0 1 is selectively arranged between 4 0 2 to attenuate the light incident on the organic electro-excitation light element from the outside, thereby increasing the contrast of the element when the outside is bright. In addition, the composition and configuration of the organic functional layer 406 in this embodiment can refer to the organic functional layer in the first embodiment. Furthermore, the mask openings used when the light absorbing layers 4 2 0a and 4 2 0b (see FIGS. 4E, 4F, and 5) formed on the substrate 400 overlap each other on the top surface of the cathode isolation layer 410 are described above. It must be larger than the mask opening used to form the organic light emitting layer 406 (see Figure 4C) in the pixel unit. Taking Figure 6 as an example, it is a pixel unit and a mask opening for manufacturing the organic light-emitting layer and the light absorbing layer of the present invention. Please refer to Figure 6, assuming a daylight unit with red, green, and blue colors. The length and width of 6 0 0 are both X, then the length and width X π and X ′ of the mask opening 5 1 0 used to form one of the color organic light-emitting layers must conform to the following formula: X '丨 <χ; χ '< χ / 3 and the range of the length and width y ", y' of the mask opening 5 2 0 used to form a single light absorbing layer is as follows: (x / 2) _ (x, / 2) < y, "2x / 3) -x ,; (3x / 2)-(x ,, / 2) < y" < 2x-x " Therefore, the present invention is characterized in that the organic electro-active light emitting element transmits light Add a layer of light absorption on the transparent electrode or between the reflective metal layer and the transparent electrode

11133twf.ptd 第18頁 595257 五、發明說明(13) 收層,抑或是在兩處皆形成光吸收層,所以從外界入射的 光會被衰減,而使對比度增加。另外,在有機電激發光元 件陣列中配置於陰極隔離層上的兩光吸收層之重疊部分可 作為似黑色矩陣,故於外界亮態時能夠增加有機電激發光 元件的對比度。 雖然本發明已以較佳實施例揭露如上,然其並非用以 限定本發明,任何熟習此技藝者,在不脫離本發明之精神 和範圍内,當可作各種之更動與潤飾,因此本發明之保護 範圍當視後附之申請專利範圍所界定者為準。11133twf.ptd Page 18 595257 V. Description of the invention (13) The layer is retracted, or a light absorption layer is formed at both places, so the light incident from the outside will be attenuated and the contrast will be increased. In addition, the overlapping portion of the two light absorbing layers disposed on the cathode isolation layer in the organic electroluminescent device array can be used as a black-like matrix, so it can increase the contrast of the organic electroluminescent device when the outside is bright. Although the present invention has been disclosed as above with preferred embodiments, it is not intended to limit the present invention. Any person skilled in the art can make various modifications and retouches without departing from the spirit and scope of the present invention. Therefore, the present invention The scope of protection shall be determined by the scope of the attached patent application.

11133t',vf. ptd 第19頁 595257 圖式簡單說明 第1圖係依照本發明之第一實施例之有機電激發光元 件的製造流程步驟圖; 第2圖係依照本發明之第一實施例製得之有機電激發 光元件的剖面示意圖; 第3 A圖係依照本發明之第二實施例之主動式有機電激 發光元件的上視示意圖; 第3 B圖係依照本發明之第二實施例之被動式有機電激 發光元件的上視示意圖; 第4 A圖至第4 F圖係依照第3 A圖所繪示之有機電激發光 元件的A - A ’剖面製造流程示意圖; 第5圖係依照第3 B圖所繪示之有機電激發光元件的 B -B’剖面示意圖;以及 < 第6圖係一畫素單元及製作本發明之有機發光層與光 吸收層的罩幕開口。 10 0 於 基 底 上 形 成 一 反 射 金 屬 層 102 於 一 反 射 金 屬 層 上 形 成 另 一 層 光吸收層 110 於 一 反 射 金 屬 層 上 形 成 一 電 極 120 於 電 極 上 形 成 一 有 機 官 能 層 130 於 有 機 官 能 層 上 形 成 .— 透 明 電 極 140 於 透 明 電 極 上 形 成 — 光 吸 收 層 圖式標示說明 200 , 4〇0 :基底 2 0 2,2 0 4,3 0 2,3 0 4,4 0 2,40 4,4 0 4a,4 0 4 b :電麟 層11133t ', vf. Ptd Page 19 595257 Brief description of the drawings Figure 1 is a flow chart of the manufacturing process of an organic electro-optical light emitting device according to the first embodiment of the present invention; Figure 2 is a first embodiment according to the present invention A schematic cross-sectional view of the organic electroluminescent device obtained; FIG. 3A is a schematic top view of an active organic electroluminescent device according to a second embodiment of the present invention; FIG. 3B is a second implementation according to the present invention Example schematic top view of a passive organic electroluminescent device; Figures 4A to 4F are schematic diagrams of the A-A 'cross-section manufacturing process of the organic electroluminescent device according to Figure 3A; Figure 5 FIG. 3B is a schematic cross-sectional view taken along the line BB ′ of the organic electro-optical light-emitting element; and FIG. 6 is a pixel unit and a mask opening for fabricating the organic light-emitting layer and the light-absorbing layer of the present invention. . 100 forming a reflective metal layer 102 on a substrate forming another light absorbing layer 110 on a reflective metal layer 110 forming an electrode 120 on a reflective metal layer forming an organic functional layer 130 on the electrode and forming the organic functional layer. — The transparent electrode 140 is formed on the transparent electrode — The pattern of the light absorption layer is 200, 400: the substrate 2 0 2, 2 0 4, 3 0 2, 3 0 4, 4 0 2, 40 4, 4 0 4a , 4 0 4 b: electric layer

11133t.wf.ptd 第20頁 595257 圖式簡單說明 2 0 6,3 0 6 ,4 0 6 :有機官能層 208 ,403 :反射金屬層 220a,220b,401 ,420a,420b :光吸收層 3 0 0 :有機電激發光元件 3 1 0,4 1 0 :陰極隔離層 4 4 0 :似黑色矩陣 6 0 0 :畫素單元 6 1 0 ,6 2 0 :罩幕開口11133t.wf.ptd Page 20 595257 Brief description of the drawings 2 0 6, 3 0 6, 4 0 6: Organic functional layer 208, 403: Reflective metal layer 220a, 220b, 401, 420a, 420b: Light absorbing layer 3 0 0: organic electroluminescent element 3 1 0, 4 1 0: cathode isolation layer 4 4 0: black matrix-like 6 0 0: pixel unit 6 1 0, 6 2 0: mask opening

11133twf.ptd 第21頁11133twf.ptd Page 21

Claims (1)

595257 六、申請專利範圍 1 · 一種有機電激發光元件,配置於一基底上,該有機 電激發光元件至少包括: 一第一電極層,配置於該基底上; 一有機官能層,配置於該第一電極層上; 一第二電極層,配置於該有機官能層上;以及 一第一光吸收層,配置於該第二電極層上。 2.如申請專利範圍第1項所述之有機電激發光元件, 更包括一反射金屬層,配置於該第一電極層與該基底之 間。 3 ·如申請專利範圍第2項所述之有機電激發光元件, 更包括一第二光吸收層,配置於該反射金屬層與該第一電 極層之間。 讀 4.如申請專利範圍第1項所述之有機電激發光元件, 其中該有機官能層至少包括一有機發光層。 5,如申請專利範圍第4項所述之有機電激發光元件, 其中該有機官能層更包括: 一電子傳輸層,位於該有機發光層與該第二電極層之 間;以及 一電洞傳輸層,位於該有機發光層與該第一電極層之 間。 6 .如申請專利範圍第5項所述之有機電激發光元件, 其中該有機官能層更包括一電子注入層,位於該第二電極 層與該電子傳輸層之間。 讀 7.如申請專利範圍第5項所述之有機電激發光元件,595257 6. Scope of patent application1. An organic electro-optical light-emitting element is disposed on a substrate. The organic electro-optical light-emitting element includes at least: a first electrode layer disposed on the substrate; an organic functional layer disposed on the substrate; On the first electrode layer; a second electrode layer disposed on the organic functional layer; and a first light absorption layer disposed on the second electrode layer. 2. The organic electro-optic light-emitting device according to item 1 of the scope of patent application, further comprising a reflective metal layer disposed between the first electrode layer and the substrate. 3. The organic electro-optical light-emitting device according to item 2 of the scope of the patent application, further comprising a second light absorbing layer disposed between the reflective metal layer and the first electrode layer. Read 4. The organic electroluminescent device according to item 1 of the scope of patent application, wherein the organic functional layer includes at least one organic light emitting layer. 5. The organic electro-optic light-emitting device according to item 4 of the scope of patent application, wherein the organic functional layer further includes: an electron transport layer between the organic light emitting layer and the second electrode layer; and a hole transmission A layer between the organic light emitting layer and the first electrode layer. 6. The organic electro-optic light-emitting device according to item 5 of the scope of patent application, wherein the organic functional layer further includes an electron injection layer located between the second electrode layer and the electron transport layer. Read 7. The organic electroluminescent device as described in item 5 of the scope of patent application, 11133twf.ptd 第22頁 595257 六、申請專利範圍 其中該有機官能層更包括一電洞注入層,位於該電洞傳輸 層與該第一電極層之間。 8 · —種有機電激發光元件,配置於一基底上,該有機 電激發光元件至少包括: 一反射金屬層,配置於該基底上 一第一電極層,配置於該反射金屬層上; 一有機官能層,配置於該第一電極層上; 一第二電極層,配置於該有機官能層上;以及 一光吸收層,配置於該反射金屬層與該第一電極層之 間。 9,如申請專利範圍第8項所述之有機電激發光元件, 其中該有機官能層至少包括一有機發光層。 _ 1 0 .如申請專利範圍第9項所述之有機電激發光元件, 其中該有機官能層更包括: 一電子傳輸層,位於該有機發光層與該第二電極層之 間;以及 一電洞傳輸層,位於該有機發光層與該第一電極層之 間。 1 1 .如申請專利範圍第1 〇項所述之有機電激發光元 件,其中該有機官能層更包括一電子注入層,位於該電子 傳輸層與該第二電極層之間。 1 2 .如申請專利範圍第1 0項所述之有機電激發光元 件,其中該有機官能層更包括一電洞注入層,位於該電洞馨 傳輸層與該第一電極層之間。11133twf.ptd Page 22 595257 6. Scope of patent application The organic functional layer further includes a hole injection layer, which is located between the hole transport layer and the first electrode layer. 8. An organic electro-optical light-emitting element disposed on a substrate, the organic electro-optical light-emitting element includes at least: a reflective metal layer, a first electrode layer disposed on the substrate, and the reflective metal layer; An organic functional layer is disposed on the first electrode layer; a second electrode layer is disposed on the organic functional layer; and a light absorbing layer is disposed between the reflective metal layer and the first electrode layer. 9. The organic electro-optical light-emitting device according to item 8 of the scope of the patent application, wherein the organic functional layer includes at least one organic light-emitting layer. _ 10. The organic electro-optic light-emitting device according to item 9 of the scope of the patent application, wherein the organic functional layer further includes: an electron transport layer between the organic light-emitting layer and the second electrode layer; and The hole transport layer is located between the organic light emitting layer and the first electrode layer. 1 1. The organic electro-optic light-emitting element according to item 10 of the scope of patent application, wherein the organic functional layer further includes an electron injection layer between the electron transport layer and the second electrode layer. 12. The organic electro-optic light-emitting device according to item 10 of the patent application scope, wherein the organic functional layer further includes a hole injection layer located between the hole transmission layer and the first electrode layer. 11133twf.ptd 第23頁 595257 六、申請專利範圍 1 3 . —種主動式有機電激發光元件,架構於一基底 上,至少包括: 複數個薄膜電晶體,位於該基底上,其中該些薄膜電 晶體均具有一畫素電極; 複數條陰極隔離層,位於該基底上之每一薄膜電晶體 的該畫素電極之間, 複數個上電極,位於該些陰極隔離層之間的該基底 上; 複數個有機官能層,位於該些薄膜電晶體與該些上電 極之間;以及 複數種第一光吸收層,分別覆蓋該些有機官能層上方 之該些上電極且互相交疊於該些陰極隔離層頂面,其中該 些第一光吸收層之互相交疊部份作為一似黑矩陣。 1 4.如申請專利範圍第1 3項所述之主動式有機電激發 光元件,其中該些陰極隔離層包括逆斜度的倒梯形結構 體。 1 5 ·如申請專利範圍第1 3項所述之主動式有機電激發 光元件,更包括一反射金屬層,配置於該些陽極層與該基 底之間。 1 6 .如申請專利範圍第1 5項所述之主動式有機電激發 光元件,更包括一第二光吸收層,配置於該些陽極層與該 反射金屬層之間。 1 7 .如申請專利範圍第1 3項所述之主動式有機電激發| 光元件,其中該些有機官能層至少包括一有機發光層。11133twf.ptd Page 23 595257 6. Scope of patent application 1 3. An active organic electro-optic light element, which is structured on a substrate and includes at least: a plurality of thin-film transistors on the substrate, wherein the thin-film transistors are The crystals each have a pixel electrode; a plurality of cathode isolation layers between the pixel electrodes of each thin film transistor on the substrate, and a plurality of upper electrodes on the substrate between the cathode isolation layers; A plurality of organic functional layers located between the thin film transistors and the upper electrodes; and a plurality of first light absorbing layers respectively covering the upper electrodes above the organic functional layers and overlapping each other on the cathodes The top surface of the isolation layer, wherein the overlapping portions of the first light absorbing layers serve as a black matrix. 1 4. The active organic electro-optical light-emitting device according to item 13 of the scope of the patent application, wherein the cathode isolation layers include an inverted trapezoidal structure with a reverse slope. 1 5 · The active organic electro-optical light-emitting device according to item 13 of the scope of patent application, further comprising a reflective metal layer disposed between the anode layers and the substrate. 16. The active organic electro-optical light-emitting device according to item 15 of the scope of patent application, further comprising a second light absorbing layer disposed between the anode layers and the reflective metal layer. 17. The active organic electro-excitation | optical element according to item 13 of the scope of patent application, wherein the organic functional layers include at least one organic light-emitting layer. limtwf.ptd 第24頁 595257 六、申請專利範圍 1 8 ·如申請專利範圍第1 7項所述之主動式有機電激發 光元件,其中該些有機官能層更包括: 一電子傳輸層,位於該有機發光層與該些陰極之間; 以及 一電洞傳輸層,位於該有機發光層與該些陽極之間。 1 9 ·如申請專利範圍第1 8項所述之主動式有機電激發 光元件,其中該有機官能層更包括一電子注入層,位於該 電子傳輸層與該些陰極之間。 2 〇 ·如申請專利範圍第1 8項所述之主動式有機電激發 光元件,其中該有機官能層更包括一電洞注入層,位於該 電洞傳輸層與該些陽極之間。limtwf.ptd Page 24 595257 VI. Patent Application Range 1 8 · The active organic electro-optical light-emitting device described in item 17 of the patent application range, wherein the organic functional layers further include: an electron transport layer, which is located in the An organic light emitting layer and the cathodes; and a hole transporting layer between the organic light emitting layer and the anodes. 19 · The active organic electro-optic light-emitting device according to item 18 of the scope of patent application, wherein the organic functional layer further includes an electron injection layer located between the electron transport layer and the cathodes. 2 0. The active organic electro-optic light-emitting device according to item 18 of the scope of patent application, wherein the organic functional layer further includes a hole injection layer between the hole transport layer and the anodes. 2 1 . —種被動式有機電激發光元件,架構於一基底 上,至少包括: 複數條陽極,位於該基底上; 複數條陰極隔離層,位於該基底與該陽極上,且該些 陰極隔離層之延伸方向垂直於該些陽極之延伸方向; 複數條陰極,位於該些陰極隔離層之間的該基底與該 些陽極上; 複數個有機官能層,位於該些陽極與該些陰極之間; 一第一光吸收層,位於該基底上且覆蓋該些有機官能 層上方之該些陰極;以及 一似黑色矩陣,覆蓋該些陰極隔離層之頂面。 2 2 .如申請專利範圍第2 1項所述之被動式有機電激發_ 光元件,其中該些陰極隔離層包括逆斜度的倒梯形結構2 1. A passive organic electro-optic light-emitting element, which is structured on a substrate and includes at least: a plurality of anodes on the substrate; a plurality of cathode isolation layers on the substrate and the anode, and the cathode isolation layers The extending direction is perpendicular to the extending direction of the anodes; a plurality of cathodes are located on the substrate and the anodes between the cathode isolation layers; a plurality of organic functional layers are located between the anodes and the cathodes; A first light absorbing layer is located on the substrate and covers the cathodes above the organic functional layers; and a black matrix covers the top surfaces of the cathode isolation layers. 2 2. The passive organic electro-excitation optical element according to item 21 of the scope of patent application, wherein the cathode isolation layers include an inverted trapezoidal structure with a reverse slope 1l133twf.ptd 第25頁 595257 六、申請專利範圍 體。 2 3 ·如申請專利範圍第2 1項所述之被動式有機電激發 光元件1更包括一反射金屬層,配置於該些陽極層與該基 底之間。 2 4 ·如申請專利範圍第2 3項所述之被動式有機電激發 光元件,更包括一第二光吸收層,配置於該些陽極層與該 反射金屬層之間。 2 5 ·如申請專利範圍第2 1項所述之被動式有機電激發 光元件,其中該些有機官能層至少包括一有機發光層。 2 6 „如申請專利範圍第2 5項所述之被動式有機電激發 光元件,其中該些有機官能層更包括: 一電子傳輸層,位於該有機發光層與該些陰極之間;· 以及 一電洞傳輸層,位於該有機發光層與該些陽極之間。 2 7。如申請專利範圍第2 6項所述之被動式有機電激發 光元件,其中該有機官能層更包括一電子注入層,位於該 電子傳輸層與該些陰極之間。 2 8 .如申請專利範圍第2 6項所述之被動式有機電激發 光元件,其中該有機官能層更包括一電洞注入層,位於該 電洞傳輸層與該些陽極之間。 2 9 . —種有機電激發光元件的製作方法,包括: 於一基底上形成一電極; 於該電極上形成一有機官能層; _ 於該有機官能層上形成一透明電極;以及1l133twf.ptd Page 25 595257 6. The scope of patent application. 2 3 · The passive organic electro-optic light-emitting element 1 described in item 21 of the scope of patent application further includes a reflective metal layer disposed between the anode layers and the substrate. 24. The passive organic electro-optic light-emitting device according to item 23 of the scope of patent application, further comprising a second light absorbing layer disposed between the anode layers and the reflective metal layer. 25. The passive organic electroluminescent device according to item 21 of the scope of patent application, wherein the organic functional layers include at least one organic light emitting layer. 2 6 „The passive organic electroluminescent device described in item 25 of the patent application scope, wherein the organic functional layers further include: an electron transport layer between the organic light emitting layer and the cathodes; and A hole transporting layer is located between the organic light emitting layer and the anodes. 2 7. The passive organic electro-optical excitation light element as described in item 26 of the patent application scope, wherein the organic functional layer further includes an electron injection layer, Located between the electron-transporting layer and the cathodes. 28. The passive organic electro-optic light-emitting device according to item 26 of the patent application scope, wherein the organic functional layer further includes a hole injection layer located in the hole. Between the transmission layer and the anodes. 2 9. A method for manufacturing an organic electro-optical light-emitting device includes: forming an electrode on a substrate; forming an organic functional layer on the electrode; and on the organic functional layer Forming a transparent electrode; and 11133twf.ptd 第26頁 595257 六、申請專利範圍 於該透明電極上形成一第一光吸收層。 3 0 „如申請專利範圍第2 9項所述之有機電激發光元件 的製作方法,其中於該基底上形成該陽極層之步驟前,更 包括於該基底上形成一反射金屬層。 3 1 ·如申請專利範圍第3 0項所述之有機電激發光元件 的製作方法,其中於該基底上形成該反射金屬層之步驟後 以及於該基底上形成該陽極層之步驟前,更包括於該反射 金屬層上形成一第二光吸收層。 3 2 . —種有機電激發光元件的製作方法,包括: 於一基底上形成一反射金屬層; 於該反射金屬層上形成一光吸收層; 於該光吸收層上形成一電極; _ 於該電極上形成一有機官能層;以及 於該有機官能層上形成一透明電極。 3 3 . —種主動式有機電激發光元件的製作方法,包 括: 提供一基底,該基底具有複數個薄膜電晶體,其中每 一薄膜電晶體具有一畫素電極; 於該基底之每一薄膜電晶體的該畫素電極之間形成複 數條陰極隔離層; 於該些陰極隔離層之間的該畫素電極上形成複數個有 機官能層; 於該基底上形成一上電極層,該上電極層係藉由該4 陰極隔離層自動分成複數個上電極,該些上電極係互相電11133twf.ptd Page 26 595257 6. Scope of patent application A first light absorbing layer is formed on the transparent electrode. 3 0 „The method for manufacturing an organic electro-optic light-emitting device according to item 29 of the patent application scope, wherein before the step of forming the anode layer on the substrate, it further comprises forming a reflective metal layer on the substrate. 3 1 The method for manufacturing an organic electro-optical light-emitting device according to item 30 of the scope of the patent application, wherein after the step of forming the reflective metal layer on the substrate and before the step of forming the anode layer on the substrate, it is further included in A second light absorbing layer is formed on the reflective metal layer. 3 2. A method for manufacturing an organic electro-active light element includes: forming a reflective metal layer on a substrate; and forming a light absorbing layer on the reflective metal layer. Forming an electrode on the light absorbing layer; forming an organic functional layer on the electrode; and forming a transparent electrode on the organic functional layer. 3 3. —A method for manufacturing an active organic electro-active light element, The method includes: providing a substrate, the substrate having a plurality of thin film transistors, wherein each thin film transistor has a pixel electrode; the picture of each thin film transistor on the substrate; A plurality of cathode isolation layers are formed between the electrodes; a plurality of organic functional layers are formed on the pixel electrode between the cathode isolation layers; an upper electrode layer is formed on the substrate, and the upper electrode layer is formed by the 4 The cathode isolation layer is automatically divided into a plurality of upper electrodes, and the upper electrodes are electrically connected to each other. I1133r.wf.ptd 第27頁 595257 六、申請專利範圍 性隔離;以及 於該基底上形成複數個第一光吸收層,該些第一光吸 收層係互相重疊於該些陰極隔離層的邊緣以作為似黑色矩 陣。 3 4 ·如申請專利範圍第3 3項所述之主動式有機電激發 光元件的製作方法,其中該些陰極隔離層包括逆斜度的結 構體。 3 5 ·如申請專利範圍第3 3項所述之主動式有機電激發 光元件的製作方法,其中於該基底上形成該些陽極之步驟 前,更包括於該基底上形成一反射金屬層。 3 6 .如申請專利範圍第3 5項所述之主動式有機電激發 光元件的製作方法,其中於該基底上形成該反射金屬層之φ 步驟後以及於該基底上形成該些陽極之步驟前,更包括於 該反射金屬層上形成一第二光吸收層。 3 7 . —種被動式有機電激發光元件的製作方法,包 括: 於一基底上形成複數條陽極; 於該基底與該些陽極上形成複數條陰極隔離層,其中 該些陰極隔離層之延伸方向垂直於該些陽極之延伸方向; 於該些陰極隔離層之間的該些陽極上形成複數個有機 官能層; 於該基底上形成一陰極層,該陰極層係藉由該些陰極 隔離層自動分成複數條陰極,該些陰極係互相電性隔離;φ 以及I1133r.wf.ptd Page 27 595257 6. Application for patent scope isolation; and forming a plurality of first light absorption layers on the substrate, the first light absorption layers overlapping each other on the edges of the cathode isolation layers to As a black-like matrix. 3 4 · The method for manufacturing an active organic electro-optic device described in item 33 of the scope of the patent application, wherein the cathode isolation layers include a structure with a reverse slope. 3 5 · The method for manufacturing an active organic electro-optic device according to item 33 of the scope of the patent application, wherein the step of forming the anodes on the substrate further comprises forming a reflective metal layer on the substrate. 36. The method for manufacturing an active organic electro-optical light-emitting device according to item 35 of the scope of patent application, wherein after the φ step of forming the reflective metal layer on the substrate and the steps of forming the anodes on the substrate The method further includes forming a second light absorbing layer on the reflective metal layer. 37. A method for manufacturing a passive organic electro-optic light-emitting device, comprising: forming a plurality of anodes on a substrate; forming a plurality of cathode isolation layers on the substrate and the anodes, wherein an extension direction of the cathode isolation layers Perpendicular to the extending direction of the anodes; forming a plurality of organic functional layers on the anodes between the cathode isolation layers; forming a cathode layer on the substrate, the cathode layer is automatically formed by the cathode isolation layers Divided into a plurality of cathodes which are electrically isolated from each other; φ and lll33rwf.ptd 第28頁 595257 六、申請專利範圍 於該基底上形成複數個第一光吸收層,該些第一光吸 收層係互相重疊於該些有機官能層的邊緣以作為似黑色矩 陣。 3 8 ·如申請專利範圍第3 7項所述之被動式有機電激發 光元件的製作方法,其中該些陰極隔離層包括逆斜度的結 構體。 3 9 .如申請專利範圍第3 7項所述之被動式有機電激發 光元件的製作方法,其中於該基底上形成該些陽極之步驟 前,更包括於該基底上形成一反射金屬層。 4 0 .如申請專利範圍第3 9項所述之被動式有機電激發 光元件的製作方法,其中於該基底上形成該反射金屬層之 步驟後以及於該基底上形成該些陽極之步驟前,更包括於φ 該反射金屬層上形成一光吸收層。lll33rwf.ptd Page 28 595257 6. Scope of patent application A plurality of first light absorbing layers are formed on the substrate, and the first light absorbing layers overlap each other on the edges of the organic functional layers as a black matrix. 38. The method for manufacturing a passive organic electro-optic device according to item 37 of the scope of the patent application, wherein the cathode isolation layers include a structure having a reverse slope. 39. The method for manufacturing a passive organic electro-optic device according to item 37 of the scope of patent application, wherein before the steps of forming the anodes on the substrate, it further comprises forming a reflective metal layer on the substrate. 40. The method for manufacturing a passive organic electro-optic light-emitting device according to item 39 of the scope of patent application, wherein after the step of forming the reflective metal layer on the substrate and before the step of forming the anodes on the substrate, It further includes forming a light absorbing layer on the φ reflective metal layer. lU33twf.ptd 第29頁lU33twf.ptd Page 29
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