TW546201B - Decorative backing and the separation method thereof - Google Patents

Decorative backing and the separation method thereof Download PDF

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Publication number
TW546201B
TW546201B TW90122551A TW90122551A TW546201B TW 546201 B TW546201 B TW 546201B TW 90122551 A TW90122551 A TW 90122551A TW 90122551 A TW90122551 A TW 90122551A TW 546201 B TW546201 B TW 546201B
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TW
Taiwan
Prior art keywords
decorative
core material
core
adhesive layer
substrate
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TW90122551A
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Chinese (zh)
Inventor
Hiroyuki Ishikawa
Naohiko Maeda
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Matsushita Electric Works Ltd
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Publication of TW546201B publication Critical patent/TW546201B/en

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/78Recycling of wood or furniture waste

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

This invention intends to provide a decorative backing constituted by a decorative layer and a core layer which are bonded together by adhesive and can be easily separated so as to easily achieve the object of recycling of resource. The decorative backing 1 is formed by a core layer 2 and a decorative layer 3 which are bonded together by an adhesive layer 4 interposed therebetween. The adhesive layer 4 is formed by a material which foams when being heated. The core layer 2 can be easily separated from the decorative layer 3 by applying a heating treatment to the decorative backing 1 so as to make the adhesive layer 4 foam. By thus, the core layer 2 and the decorative layer 3 constituting the decorative backing 1 may be easily separated for recycling purpose.

Description

546201546201

五、發明說明(l) 【發明所屬技術領域】 本發明係有關於一種裝飾基材及其分離方法。 【習知技術】 粒子i:ί二l已!人提供將中密度纖維基板(m d f )或如 知士月曰片或裝飾鋼板等裝飾材料而構置 材或家具材料等。 衣飾基材,用作建 在製作這種裝飾基材時,以往係用 裝飾材料。 r侵削黏接心材和 而,近年來由於環境問題升高,或、 等,要求藉由工業產品再生而有效利用資、·,,、=源之要求 所示之裝飾基材也要求裝飾材料或芯材之再、生利:如上述 【發明要解決之課題】 可疋在過去用黏接劑接合之芯材和穿餘好4 乃為困難之事。 衣飾材科的分離 本發明鐘於上述之問題點,其 分離用黏接劑接合之芯材和裝錦材料並容易的 材料分離之裝飾基材之分離方法。 材之心材和裝飾 【解決課題之方式】 在經由 依本發明之申請專利範圍第1項之裝飾基材】 546201 90122551 五、發明說明(2) _ ::=層:接接芯材2和裝飾材料3而成之裝飾基材1中,其 ,…^接劑4層係利用加熱發泡而形成。 第2項之發明’除了如申請專利範圍 .、構化以外,裝飾材料3係使用樹脂片,@ ;fe 使用木質基板而成。 ?τ月曰月而心材2係 2係使用石ΐ::1:4飾材料3係使用裝飾鋼板,而芯材 又如申凊專利範圍第4項之發 圍第1至3項t卜項之構造“除了二令請專利範 而成。 卜使用水洛性之黏接劑4 又如申請專利範圍第5項之發 圍第1至3項中任一項之错i 毛月除了如申請專利範 酯系之黏接劑4而成、。構w以外,使用乙烤系或氨基甲酸 方法,其特徵為對:申!=!弟6項之裝,基材1之分離 飾基材1進行加熱處理而\專^範®第1至3項中任一項之裝 裝飾材料3。 7 妾劑4發泡後,自芯材2剝離 圍第6項之構、專:外视圍發明,除了如申請專利範 自芯材2剝離裝飾材料3"。拘,<加熱處理後之裝飾基材1而 發明之實施例】 以下說明本發明之實施例 $ 7頁 546201 修正 ^S9〇122551 五、發明說明(3) 裝飾基材1如圖1(a)所示,經由黏接 和裝飾材料3而構成。 i Μ 5 ^ ^虞飾材料3之組合係按照用途適當的設定的, 1 ρ /Λ,例如可在裳倚#料3上使用樹脂片而且在怎 Ϊ可在Wll纖維基板⑽F)或粒子板等木質基板,^ 使用裳飾鋼板而且在芯材2上使用石膏 基板,在樹脂片上使用進行了木紋印刷之厚 ^纖/ ,二,4者對於900_χ 18〇〇_χ 12_ 之:,': ;度5匪之鋼板將厚度2—之稀煙片疊層而成之= 又’關於黏接劑4,係採用形成黏接劑4層 =2和裝飾材料3,且此黏接劑4層於受熱時會^泡^妾芯 枓。邊黏接劑4係使用水溶性物(emuisi〇n)較好,1 況,如以往之施工法藉著使用疊層器等將弋 ,此情 料3接合後,用壓床加壓,、八〜材和衣飾材 芯材2和裝飾材料3之間开4了斑自拉黏接劑4令水分散發後,在 黏接刻4未滿發泡之严;/开成劑4層而黏接,此時係在 _ 匕炙,皿度形成黏接劑4層的。 钍 适種黏接劑4,並未特別 域-般使用之乙婦系或脲院系黏接劑4 : 材領 可使用混入有發泡劑者。 σ種^接劑4, 岔:b |關於乙烯系黏接劑4,可使 劑…吏用聚醋系聚 久虱丞Τ馼酯乳液或聚醚系聚氨丧 ^ τ 546201 __f號90122551 车 月 日 修炎_—— 五、發明說明(4) 酯乳液等。 又,關於混入於黏接劑4之發泡劍,有機系和無機系 中之任一者都可使用。在無機系發泡劑上例如有碳酸銨、 碳酸氫銨、亞硝酸銨、氫化銨等分離型之無機系發泡 劑。又關於無機系發泡劑,有例如三氯氟甲烷等氟化鏈 烷、偶氮二異丁腈等偶氮系化合物、對甲苯磺醯基醯肼等 肼系4匕合物、p-甲代亞苯基磺醯基氨基脲等脲氨基系化 合物、N,N-二亞硝基對苯二醯胺等亞硝基化合物、及 其他之低彿點溶媒等。 使用這種黏接劑4將芯材2和裝飾材料3接合時,例如 對於过材2以1 0 0 g / m2之塗抹量塗抹黏接劑4後,使用疊層 器等可將芯材2和裝飾材料3接合。 在將照這樣構成之裝飾基材1之芯材2和裝飾材料3分 離時,首先使用具有遠紅外線加熱器之加熱設備等在芯材 2或裝飾材料3之碳化溫度以下將裝飾基材1加熱。例如在 芯材2上使用碳化溫度約26 0 °C之中密度纖維基板之情況, 可在17 0〜180 °C之範圍加熱2〜3分鐘。該加熱溫度係按昭兮 η裝飾材料3之碳化溫度或黏接劑4層之: 的設著這些材質之選擇也可在約12〇t“^ 耩者延種加熱處理,如圖1(b)所示,、 而變成多孔質狀。變成多孔質狀 :妾1 或裝飾材料3之接合面之接觸面積變小,之在和芯材2 之強度也降低,因而芯材2和裝飾材料3易/接劑4層本身 因此,藉著自芯材2剝離該加熱處理後之裝飾基捫之 546201V. Description of the Invention (l) [Technical Field of the Invention] The present invention relates to a decorative substrate and a method for separating the same. [Knowledge technology] Particle i: ί two l already! People provide materials such as medium-density fiber substrates (m d f) or decorative materials such as chinoisuki or decorative steel plates to construct materials or furniture materials. Clothing substrates have been used as decorative materials in the manufacture of such decorative substrates. rInsults the adhesion of heartwood and, in recent years, due to the increase in environmental problems, or, etc., it is required to effectively use resources through the regeneration of industrial products. The decorative substrates shown in the requirements of decorative materials also require decorative materials. Or the core material, and profit: As mentioned above [the problem to be solved by the invention] It can be difficult to use the core material and wear allowance 4 bonded by adhesive in the past. Separation of clothing and materials department The present invention is directed to the above-mentioned problem, and a method for separating a decorative base material for separating a core material joined with an adhesive and an easy-to-separate material. Heart material and decoration of materials [Method for solving the problem] In the decorative substrate through item 1 of the scope of patent application according to the present invention] 546201 90122551 V. Description of the invention (2) _ :: = Layer: Connect the core material 2 and decoration In the decorative base material 1 made of the material 3, the ... 4 layers of the adhesive are formed by heating and foaming. In addition to the invention of the second item, in addition to the scope of patent application and structure, the decorative material 3 is made of resin sheet, @; fe is made of wooden substrate. ? τ month is month and heartwood 2 is 2; stone is used for 2: 2; 4 is used for decorative materials; 3 is used for decorative steel, and the core material is the same as the hairline of items 4 to 3 of the patent application. Structure "except for the second order, please apply for a patent. Use of a water-soluble adhesive 4 is the same as the application of the scope of the patent No. 5 of the hairpin any one of the 1 to 3 mistakes i It is made of adhesives of the standard ester type 4. In addition to the structure w, the method of bake or carbamic acid is used, which is characterized by: the installation of 6 items of the Shen! =! Brother, and the separation of the base material 1 Heat treatment and the special decoration material 3 of any one of the items 1 to 3. 7 After the liniment 4 is foamed, the structure of the sixth item is peeled from the core material 2, and the invention is: Except for the example of applying for a patent, the decorative material 3 is stripped from the core material 2 " The embodiment of the invention < the decorative substrate 1 after heat treatment >] The following describes the embodiment of the present invention $ 7Page 546201 Modification ^ S9〇122551 5 3. Description of the invention (3) As shown in FIG. 1 (a), the decorative base material 1 is constituted by bonding and a decorative material 3. The combination of Μ 5 ^ ^ 玉 饰 材料 3 is appropriately set according to the application. 1 ρ / Λ, for example, resin sheets can be used on Sang Yi # 3 and how can wood substrates such as Wll fiber substrates or particle boards be used, ^ Sang decorative steel plates and gypsum substrates on core material 2, The thickness of wood fiber printed on the resin sheet is ^ fiber /, 2, 4 for 900_χ 1800__ 12_ :, ':; steel sheet with a thickness of 5 is laminated with a thin tobacco sheet with a thickness of 2— Zhi = again 'About adhesive 4, use adhesive layer 4 = 2 and decorative material 3, and this adhesive layer 4 will ^ foam ^ core core when heated. Side adhesive 4 is used The water-soluble substance (emuisi) is better. In the case of the conventional construction method, the 弋 is used by using a laminator, etc. In this case, the material 3 is joined, and then pressurized with a press. Between the core material 2 and the decorative material 3, there are 4 spots of self-pulling adhesive 4 to disperse the hair, and the foam is not fully foamed at the adhesion engraving 4; _ Dizzy, the adhesive layer is formed into 4 layers. 钍 Suitable adhesive 4, which is not used in the same field-ordinary women's or urea hospital adhesives 4: The material can be mixed with foam Agents σ species ^ 4, Fork: b | Regarding ethylene-based adhesive 4, it can make the agent ... Use polyacetate-based polygalacid emulsion or polyether-based ammonia ^ τ 546201 __f number 90122551 car moon day repair inflammation_ —— V. Description of the invention (4) Ester emulsion, etc. Regarding the foaming sword mixed in the adhesive 4, either organic or inorganic can be used. Examples of the inorganic foaming agent include: Separate inorganic foaming agents such as ammonium carbonate, ammonium bicarbonate, ammonium nitrite, and ammonium hydride. As for inorganic foaming agents, there are fluorinated alkanes such as trichlorofluoromethane, azobisisobutyronitrile, etc. Azo compounds, hydrazine-based compounds such as p-toluenesulfonylhydrazine, urea-amino compounds such as p-methylphenylsulfonamidocarbazone, and N, N-dinitroso-p-phenylenedihydrazone Nitroso compounds such as amines, and other low-buddle solvents. When the core material 2 and the decorative material 3 are bonded using this adhesive 4, for example, the core material 2 can be applied with a spreading amount of 100 g / m2 to the material 2 and then the core material 2 can be laminated using a laminator or the like. It is joined to the decorative material 3. When separating the core material 2 and the decoration material 3 of the decoration base material 1 thus constituted, firstly, the heating of the decoration base material 1 below the carbonization temperature of the core material 2 or the decoration material 3 using a heating device having a far-infrared heater or the like . For example, when a medium-density fiber substrate having a carbonization temperature of about 260 ° C is used for the core material 2, it can be heated at a range of 170 to 180 ° C for 2 to 3 minutes. The heating temperature is based on the carbonization temperature of the decoration material 3 or the 4 layers of the adhesive: the choice of these materials can also be extended to heat treatment at about 120 t ", as shown in Figure 1 (b ) And become porous. Become porous: 妾 1 or the contact area of the decorative material 3 becomes smaller, and its strength with the core material 2 is also reduced, so the core material 2 and the decoration material 3 The easy / adhesive layer 4 itself, therefore, by peeling the heat-treated decorative base 546201 from the core material 2

裝飾材料3,可容易的分離芯材2和裝飾材料3。又# 對於裝飾基材1送風,自芯材2吹掉裴飾材料3,可 芯材2和裝飾材料3。 Γ刀離 又,藉著使用粉碎機等將加熱處理後之裝飾基 卜2分鐘,將裝飾材料3或芯材2粉碎,而且 將 飾材料3和芯材2分離。在此情況,例如如圖ι( Τ一將 藉著使裝飾基材1通過一對粉碎輥5之間,可對裝飾美=’ ,加應力而粉碎。此時對裝飾基材j施加用以粉碎之土 時’利用該應力自芯材2剝離裝飾材料3。 心The decorative material 3 can be easily separated from the core material 2 and the decorative material 3. Also # For the decorative substrate 1, the core material 2 and the decorative material 3 can be blown off from the core material 2 by blowing off the Pei decorative material 3. The knife is separated, and the decorative base 3 after heating is pulverized by using a pulverizer or the like for 2 minutes, the decorative material 3 or the core material 2 is pulverized, and the decorative material 3 and the core material 2 are separated. In this case, for example, as shown in Figure ι, by passing the decorative substrate 1 between a pair of crushing rollers 5, the decorative beauty can be crushed by applying stress. At this time, the decorative substrate j is applied with When crushing the soil, 'the decorative material 3 is peeled from the core material 2 using this stress.

,,這種粉碎處理時,得到混合了裝飾材料3之粉碎 飾分』材2之粉碎物21之狀態,但是如圖1(d)所示將裝 粉碎物31和芯材2之粉碎物21之混合物放入離心 ^ 栈6吟,利用比重之差異將裝飾材料3之粉碎物3 1和 之粉碎物21分離。於是,照這樣做自裝飾基材】分離 心才2和裝飾材料3可供再資源化。 辟而ί —如上述所不’藉著將加熱處理後之裝飾基材1粉 # 心材2剝離裝飾材料3時,不必利用人力剝離該裝飾In this crushing process, the crushed material 21 mixed with the decorative material 3 is obtained, but the crushed material 21 containing the crushed material 31 and the core material 2 is obtained as shown in FIG. 1 (d). The mixture was placed in a centrifugal stack 6 and the crushed product 31 of the decorative material 3 and the crushed product 21 were separated by using the difference in specific gravity. Then, as such, the self-decorative substrate] separates the heart 2 and the decorative material 3 for recycling.而 而 ί—As mentioned above ’By heating the decorative base material 1 powder # Heartwood 2 When peeling the decorative material 3, there is no need to use human labor to peel off the decoration

八μ爸’將自裝飾基材1之加熱處理至怒材2和裝飾材料3之 刀“、、止之處理製程自動化,可提高處理效率。 【發明之效果】 美絲如上述所示,本發明之如申請專利範圍第1項之裝飾 因在經由黏接劑層黏接芯材和裝飾材料而成之裝飾 在黏接劑層上利用加熱發泡的,藉著對裝飾基材進Ba μ Da 'automates the process of heating from the decorative substrate 1 to the blades 2 and 3 of the decorative material 3, which can improve the processing efficiency. [Effect of the invention] As shown in the above, this silk The decoration of the invention, such as the scope of application for the first item of the patent, is made by adhering the core material and the decoration material through the adhesive layer. The decoration is made by heating and foaming on the adhesive layer.

第10頁 546201 五、發明說明⑹ — 劑發泡,可容易的自芯材剝離裝飾材 Ϊ源r 材之芯材或裳飾材料分離後可容易的再 又如申請專利範圍第2項之發至# 圍第1項之構造以外,因在穿飭好把L除了如申M專利靶 芯材上❹木質基板,可將構成裝使用^旨片而且在 基板容易的再資源化。 哪基材之樹月曰片或木質Page 10 546201 V. Description of the invention ⑹ — agent foaming, which can easily peel the decorative material from the core material, the core material or the dress material of the material can be easily separated as described in the second patent application. In addition to the structure of item # 1, it is possible to use a wooden substrate on the core material such as the patented M patent target in addition to wearing it, so that the component can be used and the substrate can be easily recycled. Which substrate is a tree moon or wood

® f ^ J ^ ^ Τ ^ ,i II 在芯材上使用石衣飾材料上使用裝飾鋼板而且 膏板容易Κΐ;::可將構成裝飾基材之裝飾鋼板或石 圍第1至3項中任」之發明,除了如申請專利範 劑,在將芯材和裝飾材^::二之黏接 層器等將芯材和裝#材 衣=”材時,使用疊 容易的將芯材和裴掷材料接合4目&床加壓可黏接,可 又如申凊專利範圍第 圍第1至3項中任一項之貝之^月,除了如申請專利範® f ^ J ^ ^ Τ ^, i II Use of decorative steel plate on the core material and stone material on the core material and easy to paste the plate; ::: The decorative steel plate or stone wall constituting the decorative substrate can be used in items 1 to 3 In addition to the patent application, when the core material and the decorative material are used, when the core material and the decoration material such as the second bonding layer device are used, the core material and the decoration material are easily stacked. Pei Throw material can be bonded with 4 mesh & bed pressure, and it can be used as the month of any one of items 1 to 3 of the patent scope, except for the patent application.

酸酯系之黏接劑,藉著對^分因使用乙烯系或氨基F 劑發泡’可容易的自芯材;加熱處理而令黏接 之芯材或裝錦材料分可料,將構成裝.飾基材 又本發明之,T备易的再貧源化。 方法,因對如申請專圍^項之裝飾基材之分離 、黏接劑發泡後…材剝離裝:::材 546201 五、發明說明(7) ^ 將構成裝錦基材之芯材或裝 化。 飾材料分離德π ^ <可容易的再資满 又如申請專利範圍第 、原 圍第6項之構迕以认 項之發明,扒 而ώ 外,因藉著杂、π 除了如申請專利範 芯材軔離裝飾材料,藉1 Λ加熱處理後之裝飾基衧 碎可自芯材剝離裝曰吏用粉碎機等將裝飾基 材料,將自加熱處理η不;:用人力自芯材剥離:: 製程自動化,τ接上;1和裝饰材料之分離為c j軚咼處理效率。 疋之處理 第12頁 546201 案號 90122551 年月曰 曰 修正 圖式簡單說明 實施例中,用以分離裝 圖1(a)〜(d)係表示本發明之一 飾基材之各製程之概況的剖面圖。 【符號說明】 裝飾基材 芯材 裝飾材料 黏接劑Ester-based adhesives can be easily separated from the core material by foaming with ethylene-based or amino F-agents; heat-treated adhesive core materials or packaging materials can be separated to form The decoration base material is also the present invention, which makes T Beiyi lean again. Method, because of the separation of decorative substrates such as the application of ^, after the adhesive foam ... Material peeling: :: 546201 V. Description of the invention (7) ^ Will form the core material of the decorative substrate or Equipment. Decoration material separation π ^ < can be easily re-funded, as in the scope of patent application, the original circle of the 6th structure and recognized inventions, but not free, because by miscellaneous, π except for patent applications The core material can be separated from the decorative material, and the decorative base material can be peeled from the core material by 1 Λ heating treatment. The decorative base material can be pulverized with a grinder, etc., and will not be self-heated. :: Process automation, τ is connected; 1 and the separation of decorative materials is cj 軚 咼 processing efficiency.处理 的 处理 第 12 页 546201 Case No.90122551 Modified drawing Brief description In the embodiment, the process of separating and assembling Figure 1 (a) ~ (d) shows the outline of each process of a decorative substrate of the present invention Section view. [Symbol description] Decorative base material Core material Decorative material Adhesive

第13頁Page 13

Claims (1)

年(0月 > 曰 修正Year (0 month > day 5462〇fJ 件 18^90122551 車療專米範- 材料而 酸酯系 2. 飾材津斗 3. 飾材料 4. 利範圍 接劑發 5 . 其中, 芯材剝 一種 成,其 之黏接 如申 係使用 如申 係使用 一種 第1至3 泡後, 如申 藉著將 離裝飾 裝飾基材, 待徵為:該 劑,且係藉 請專利範圍 樹脂片,而 諳專利範圍 裝飾鋼板, 裝飾基材之 項中任一項 自芯材剝離 請專利範圍 加熱處理後 椅料。 藉由該黏接劑層黏接芯材和裝 黏接劑層係使用乙烯系或氨基甲 由加熱會發泡之材料形成。 第1項之裝飾基材,其中,該壯 該芯材係使用木質基板而成'衣 第1項之裝飾基材,其中,兮壯 而該芯材係使用石膏板而/衣 分離方法,其特徵為對如i 之裝飾基材施以加熱處理=專 裝飾材料。 而令黏 第4項之裝飾基材之分離 之裝飾基材予以粉碎之方去, 式而65462〇fJ pieces 18 ^ 90122551 car treatment meter range-material and acid ester series 2. decorative materials Jindou 3. decorative materials 4. Li-range contact hair 5. Among them, the core material is peeled into one, and its adhesion is as follows After applying the application, such as the application of the first to the third bubble, if the application is to decorate the decorative base material, the application is: the agent, and the patent scope resin sheet, and the patent scope decorative steel plate, decoration Any one of the items of the base material is peeled from the core material, and the patent scope is that of the heat-treated chair material. The core material and the adhesive layer are adhered by the adhesive layer, and the adhesive layer is formed of a material that foams when heated by using ethylene or carbamic acid. The decorative substrate of item 1, wherein the core material is made of a wooden substrate. The decorative substrate of item 1, wherein the core material is strong and the core material is a gypsum board / cloth separation method. It is characterized by applying heat treatment to a decorative substrate such as i = special decorative material. Then, the decorative base material which is separated from the decorative base material of item 4 is crushed.
TW90122551A 2000-09-26 2001-09-11 Decorative backing and the separation method thereof TW546201B (en)

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Publication number Priority date Publication date Assignee Title
JP2003088844A (en) * 2001-09-17 2003-03-25 Matsushita Electric Works Ltd Method of separating decorative wooden material
JP4956996B2 (en) * 2003-12-24 2012-06-20 株式会社ブリヂストン Fuel cell air purification method and apparatus, and fuel cell
JP4738383B2 (en) * 2007-06-01 2011-08-03 株式会社トクヤマ Separation of paper and paper from a gypsum-paper joint
KR101690610B1 (en) 2015-01-23 2016-12-28 오용택 Method manufacturing vibration/noise insulating panel board and Panel board thereby
CN111604347B (en) * 2019-06-05 2022-01-07 北新集团建材股份有限公司 Assembled wall body recovery method

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Publication number Priority date Publication date Assignee Title
JPS60252681A (en) * 1984-05-30 1985-12-13 F S K Kk Heat peelable adhesive sheet
JP2898480B2 (en) * 1992-09-14 1999-06-02 日東電工株式会社 Heat-peelable adhesive and adhesive member
JP3405576B2 (en) * 1993-11-12 2003-05-12 ダイセル化学工業株式会社 Thermal release film and release method
JP2000239620A (en) * 1999-02-19 2000-09-05 Fujimori Kogyo Co Ltd Thermal release self-adhesive and self-adhesive member using same
JP2000248240A (en) * 1999-03-01 2000-09-12 Nitto Denko Corp Heat-releasable adhesive sheet

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JP2002103506A (en) 2002-04-09
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