五、發明說明（1 ) 【發明領域】 材料本:：Γ關於-種成型複合材料製品的方法及該複合 有光、^1 種在準備好複合材料基材後一次成型具 表面之複合材料的方法，並具有高結 皁縫之複合材料。 【習知技藝說明】 袋、^=上常見由複合材料所製成之物品有高爾夫球 、大哥大外殼等，該複合材料大都先以破 人、” &纖維等材質製成一基布層，並將該基布層 維含浸熱固性樹脂（例如環氧 β 纖 树月曰）後’疊置數層含浸樹 :佟“：以所需厚⑨，續加以熱壓即成型複合材料， 經修邊後噴覆多層聚氨基甲酸 :’最後再於該複合材料上施以冷壓以成型所預 ^品。上述複合材料雖然具有厚度可隨意增減與強度佳之 優點’但因於每次喷漆後均需有报長的等待乾燥時間 成型時間長；再者’該基布層之纖維中含浸有熱固性樹脂， =::力材料：|後的硬度將會太硬’而導致製品無法採 因此，為提供複合材料適當強度且能解決車縫加 問題，又可將基布層與硬度適中之聚氯乙烯（p 的 聚苯乙烯（P S )等接合層結合成複合材料，其作法θ 接合層上膠、貼合基布層’再於基布層另—面貼人聚：將 甲酸醋（ρυ)之接合層或塗佈數層聚氨基甲酸酯σ(ρ:基 漆，使其成型後具有光滑表面，但由於基布層與接合層貝)占 五 、發明說明 2 合後均需有很長之碩 於纖維材料所_ & ^ 故其成型時間長；再者，由 2= 成之基布層與接合層係屬不同材質，故： 彼此間容易產生剝離脫落之現象，：：的：二強度不佳’ 的殘留溶劑會產生混:蜀m 纟加…過程時’膠水 美觀，因… 泡產生’將造成結合後之不 待改善之課題。 Μ* 口材#運用上極 【發明概要】 同時 種結 /因此，本發明之目&即在提供一種可快速成型 形成光滑表面之複合材料製品的成型方法，並提供 合強度高，且可車縫加工之複合材料。 於是，本發明成型複合材料製品的方法，其製造過程 包含有：準備基材、熱壓成型複合材料、裁切成預定尺寸 及冷壓成型製品等步驟，其中： 該準備基材步驟··準備用以成型複合材料的基材，包 括一纖維製成且添加有二胺類之表面處理劑的基布層、二 由熱塑性聚氨醋彈性體（丁 P U )所構成之薄膜層7以及 接合層，其中，该等薄膜層是分別設在基布層上、下方 之一第一基面與一第二基面上，在兩薄膜層其中之一上即 覆蓋有該接合層； 遠熱壓成型複合材料步驟··施以溫度12 〇〜1 8 〇 與廢 力2〜10 kg/cm 2給予整體熱壓，經60〜250秒之時間後， 使接合層藉由薄膜層滲熔融入基布層纖維中，而與表面處 理劑產生化學鍵結以穩固的結合在基布層之其中一基面 本紙張尺度適用中國國家標準（CNS) A4規格（210x 297公釐） 第4頁 572825 A7 __B7 五、發明說明（3 ) 上，同時，基布層另一基面亦由薄膜層形成光滑表面以一 次形成一複合材料； 該裁切成預定尺寸步驟：利用裁切技術將熱壓成型後 之複合材料裁切成預定之尺寸形狀·，及 該冷壓成型製品步驟：以預定之成型模具在裁切成預 定尺寸形狀之複合材料上，施以溫度1〇〇〜13(rc與壓力2 〜10 kg/cm 2之加壓成型，經6〇〜18〇秒之時間後以完成該 複合材料製品。 由上述可知，該複合材料製品是由一複合材料藉由加 熱加壓所成型，且該等薄膜層是由熱塑性聚氨酯彈性體（ 丁 P U )所構成，而分別鋪設在基布層之兩基面上，並可藉 由加熱加壓而穩固地黏接該接合層與基布層，以達到較佳 之結合強度。 而本發明之複合材料包含：一由纖維材料所構成之基 布層、兩薄膜層，以及至少一接合層，其中，該基布層2 有一第一基面及一第二基面，其特徵在於·· 该等薄膜層皆是由熱塑性聚氨酯彈性體（丁 P U )所 構成，且分別鋪設在基布層之兩基面上，並可藉由加熱加 壓而穩固地黏接該接合層與基布層，並同時形成一光滑表 面。 【圖式之簡單說明】 本發明之其他特徵及優點，在以下配合參考圖式之較 佳貫施例的詳細說明中，將可清楚的明白，在圖式中： 第一圖是本發明複合材料製品之一較佳實施例的製造 本紙張尺度適财關家標準（CNS) A4規格⑵Gx 297公爱） 572825 五、發明說明（4 ) 流程圖； 一第一圖疋第一圖中該複合材料之立體分解圖，圖中顯 示j複合材料是在一尚未受壓成型為製品前之狀態，並說 土布層一薄膜層與一接合層的相對關係； 說明該基布 圖中顯示該 及 第三圖是第二圖之局部縱向組合剖視圖 層、二薄膜層與二接合層的聯結關係； 第四圖是該較佳實施例之一立體組合圖 複合材料受冷壓成型製品後所形成之物品型態一 第五圖是一類似第三圖之組合剖視圖，說明該複合材 料是由基布層、二薄膜層與一接合層組裝而成。 【較佳實施例之詳細說明】 參閱第-、二圖，本發明成型複合材料製品i之方法 依序包含有準備基# 11、熱壓成型複合材料12、裁切成預 定尺寸13及冷壓成型製品14,其中，該準備基材η之步 驟中’該基材是包括-由碳纖維物（―他⑷所製 成且添加有二胺類之表面處理劑的基布層2ι、二由軌塑性 聚氨醋彈性體（TPU)所構成之薄膜層22，以及二接合 層23,其中’該基布層21具有一位於上方之第_基面211: 以及-位於下方之第二基面212，該等接合層Μ即分別覆 蓋在二基面211、212 而該接合層23可為聚氣乙烯（p vc)、丙烯腈-丁二稀-苯乙烯（ABS)、聚苯乙烯（p S )、聚碳酸酯（P C )或聚對苯二曱酸乙酯（p E 丁） 。配合第三圖，該熱壓成型複合材料丨2步驟則θ在芙材上 施以12〇〜職之熱壓溫度’同時施加2〜1〇、二之： 本紙張尺度適用中國國家標準（CNS) Α4規格（21〇χ 297公董） 572825 A7 ___B7 五、發明說明（5 ) 力給予整體熱壓，經過6〇〜250秒，該薄膜層22會先熱融 而滲入基布層21纖維中而與基布層21表面處理劑產生化 學鍵結’使該接合層2 3藉由薄膜層2 2之黏結而穩固的結 合在基布層21之二基面211、212上以形成一複合材料2。 而该裁切成預定尺寸1 3步驟，係利用裁切技術將熱壓成型 複合材料後之複合材料2裁切成預定之尺寸形狀。該冷壓 成型製品14步驟，是以預定之成型模具在裁切成預定尺寸 形狀後之複合材料2上施以1 〇 〇〜1 3 〇 °c之冷壓溫度與2〜 10 kg/cm之加壓壓力，經60〜1 80秒之時間即完成，此過 私中乃先使複合材料2先軟化，再予以加壓成型即可完成 該複合材料製品1，如第四圖所示者。 由前述可知本發明藉由基布層21有添加二胺類之表 面處理劑，而丁 PXJ薄膜層22的末端基—NC ◦與二胺類 易於反應形成-C Ο N Η基，故結構中，基布層21與該等 接合層2 3間形成化學鍵結，受外力破壞時，較不易有脫層 的現象產生’再者，本發明之製造過程不僅簡單且快速， 更可達到製造便捷之另一功效。 參閱第五圖，當然本發明在準備基材11步驟中，亦可 將4原本分別覆蓋在二薄膜層2 2上之二結合層2 3改為單 接合層23覆蓋在二薄膜層22其中之一上，即該複合材 料2僅接合一接合層23，因其製造過程完全相同故在此不 再贅述，當複合材料2成型後，該複合材料2在未覆蓋有 接合層23之另一基面212上的薄膜層22同樣會受熱而融 化滲入基布層21之纖維中以形成光滑表面而一次形成該 本紙張尺度適砰5^標準（CNS) λ4規格（21Gx 297公釐） 572825 五、發明說明（6 ) 因此，本發明；rt； i、土 達到形成一光滑表面之創 複合材料2 作目的。 參閱第二、三圖，本發明* 月車乂佳實施例之複合材料2句 含·一基布層21、兩薄膜匕 寻膜I 22，以及二接合層23，其中， 該基布層21是由碳纖維（carb 古-脸+主^ fabric )所製成且添加 有一胺類之表面處理劑，該基布 土叩噌21具有一位於上方之第 一基面211，以及一位於下方之楚 Γ万之苐二基面212。該等薄膜層 22是由熱塑性聚氨酯彈性體 ® ( thermplastic urethane elastomer，以下簡稱τ P U )所椹# 口八口，-丄L丄 y W稱成，且分別融貼在基布 層21之兩基面211、212上。該等接合層23是可選自聚氯 乙稀（pvc)、丙稀腈-丁二稀_笨乙稀（ABS)、聚 苯乙烯（P S )、聚碳酸酯（p c) 5戈聚對苯二曱酸乙酯 (PET)等材質’且分別藉該等Tpu薄膜j 與基 布層21作結合。成型後之複合材料2即可藉由上述之冷壓 成型製品方法壓製出製造業者所需的製品外觀型態。 為了使基布層21與兩接合層23達到較佳之結合強 度，本實施例是在二接合層23與基布層21間夾以τ p U 4膜層22，而；f；以習知之膠水黏合。在熱壓成型複合材料 的過程中，即以熱壓溫度使TPU薄膜層22融化滲入基布 層21纖維中，使TPU薄膜層22的末端基_Nc〇與基布 層21之二胺類表面處理劑反應形成_c〇nh基，而形成 穩固的化學鍵結，而具有較佳的結合強度，當受外力破壞 時’較不易有脫層的現象產生；再者，本發明之基布層21 並未塗佈有環氧樹脂，因此，可適用於一般之車缝加工， 本紙張尺度適用中國國家標準（CNS) A4規格（210x 297公釐） 第8頁 572825 五、發明說明（7 ) 而提供更多樣化的加工方式。 合，f月，基布…可僅與一接合層㈡作結 ,疋以本實鉍例所揭示之兩接合層23為限，此 夺，：結合接合層23的TPU薄膜層22則形成光滑表面。 八Α布二說明可知’本實施例利用Τ”薄膜層22來結 層2丨與接合層23,可使複合材料2製品i的結合 強度車父佳，曰τ ρ τ τ错脱b? 合… TPU薄膜層22因未含有溶劑，於加熱後不 :產生氣泡影響整體美m，故本發明該製造方法可製造出 美親且結合強度較佳的製品1。 "上述本發明複合材料所成型之製品可適用於一 般傳統之車縫加工，且 用於 後具有-光滑表面，再者，層：其加熱加· 塑性聚氨醋彈性體…ΐ 之複合材料藉由熱 乳《弹14體所構成之薄膜層作為結合基布層盥 合層之技術確實可使製品之結合強度較佳且更具美觀； 又’本發明之複合材料亦可利用冷壓成型製品而製作 種幾何形狀外觀以因應消費者的需求，故確實能 之目的。 准以上所述者，僅為本發明之較佳實施例而已，告 :以此限定本發明實施之範圍，#大凡依本發明申請：利 粑圍及發明說明書内容所作之簡單的等效變化與修飾 應仍屬本發明專利涵蓋之範圍内。 572825 A7 B7 五、發明說明 (8 ) 【元件標號對照】 1 製品 21 基布層 11 準備基材 211 第一基 面 12 熱壓成型複合材料 212 第二基 面 13 裁切成預定尺寸 22 T P U 薄膜層 14 冷壓成型製品 23 接合層 2 複合材料 本紙張尺度適用中國國家標準（CNS) A4規格（210x 297公釐） 第10頁V. Description of the invention (1) [Field of the invention] Material :: Γ About a method for molding composite material products and the composite light, ^ 1 kind of composite material on the surface of a molding tool after the composite material substrate is prepared Method, and a composite material with high knots. [Description of Knowing Skills] Bags, ^ = Common materials made of composite materials include golf balls, big brother's shells, etc. Most of the composite materials are first made of a base fabric layer with materials such as "smashing", & fiber. And impregnating the base fabric layer with a thermosetting resin (for example, epoxy beta fiber tree month) and stacking several layers of impregnated tree: 佟 ": to form a composite material with a desired thickness, followed by hot pressing, and repair Then spray multiple layers of polyurethane: 'Finally, cold pressing is applied to the composite material to form the desired product. Although the above-mentioned composite material has the advantages of being able to increase and decrease the thickness at will and good strength, but because of the long waiting time required for drying after each painting, the molding time is long; furthermore, the fibers of the base fabric layer are impregnated with thermosetting resin, = :: Force material: | The hardness after | will be too hard, and the product will not be used. Therefore, in order to provide the appropriate strength of the composite material and solve the problem of sewing seam, the base fabric layer and polyvinyl chloride with moderate hardness ( The bonding layer of p, such as polystyrene (PS), is combined into a composite material. The method θ The bonding layer is glued and adhered to the base fabric layer, and then the base fabric layer is adhered to the other side: the formic acid (ρυ) is bonded Layer or coating several layers of polyurethane σ (ρ: base paint to make it have a smooth surface after molding, but because the base fabric layer and the bonding layer shell) account for five, the description of the invention 2 need to have a long time after the combination Master of fiber materials _ & ^ Therefore, it takes a long time to form; In addition, the base fabric layer and the bonding layer made of 2 = are of different materials, so: The phenomenon of peeling and peeling easily occurs between each other ::: Residual solvents with poor strength can cause mixing: During the process, the “glue is beautiful, due to ... bubble generation” will cause unresolved problems after the combination. Ｍ * 口 材 # 用上 极 [Summary of Invention] Simultaneous seeding / therefore, the purpose of the present invention & A molding method for rapidly forming a composite material product that forms a smooth surface, and provides a composite material that has a high strength and can be machined. Therefore, the method for molding a composite material product of the present invention includes the following steps: preparing a substrate, heat Compression molding of composite materials, cutting to a predetermined size, and cold-pressed molding, etc., among which: the preparation of the substrate step ... preparing the substrate for molding the composite material, including a fiber-made surface with added diamines The base fabric layer of the treatment agent, two film layers 7 and a bonding layer composed of a thermoplastic polyurethane elastomer (butyl PU), wherein the film layers are one of the first Surface and a second base surface, the bonding layer is covered on one of the two film layers; the step of remote hot-pressing the composite material is applied at a temperature of 12 0 to 1 8 0 and a waste force of 2 to 10 k g / cm 2 is given overall hot pressing. After a period of 60 ~ 250 seconds, the bonding layer is infiltrated and melted into the fibers of the base fabric layer through the film layer, and a chemical bond with the surface treatment agent is generated to firmly bind the base fabric layer. One of the base surfaces of this paper applies the Chinese National Standard (CNS) A4 specification (210x 297 mm) Page 4 572825 A7 __B7 5. In the description of the invention (3), at the same time, the other base surface of the base fabric layer is also made of film The layer forms a smooth surface to form a composite material at a time; the step of cutting into a predetermined size: using a cutting technique to cut the hot-pressed composite material into a predetermined size and shape; and the step of cold-pressing a product: The molding die is pressed on the composite material cut into a predetermined size and shape, and is pressure-molded at a temperature of 100 to 13 (rc and a pressure of 2 to 10 kg / cm 2), and after a time of 60 to 180 seconds, Finish the composite product. From the above, it can be known that the composite material product is formed by heating and pressing a composite material, and the film layers are composed of a thermoplastic polyurethane elastomer (butyl PU), and are respectively laid on the two base surfaces of the base fabric layer. The bonding layer and the base cloth layer can be firmly adhered by heating and pressing to achieve better bonding strength. The composite material of the present invention includes: a base fabric layer composed of a fibrous material, two film layers, and at least one bonding layer, wherein the base fabric layer 2 has a first base surface and a second base surface. The reason is that the film layers are made of thermoplastic polyurethane elastomer (PU), and are respectively laid on the two base surfaces of the base fabric layer, and the bonding layer and the bonding layer can be firmly adhered by heating and pressing. The base fabric layer forms a smooth surface at the same time. [Brief description of the drawings] Other features and advantages of the present invention will be clearly understood in the following detailed description of preferred embodiments with reference to the drawings. In the drawings: The first figure is a composite of the present invention Manufacture of one of the preferred embodiments of the material product The paper size is suitable for financial standards (CNS) A4 size ⑵Gx 297 public love) 572825 5. Description of the invention (4) Flow chart; a first picture 疋 the first picture A three-dimensional exploded view of the material. The figure shows that the j composite material is in a state before being pressed into a product, and the relative relationship between the soil cloth layer, a thin film layer, and a bonding layer is described. The third figure is the partial longitudinal sectional view of the second figure, the connection relationship between the two film layers, the two film layers and the two bonding layers; the fourth figure is one of the preferred embodiments of the three-dimensional combination diagram of the composite material formed by cold-pressed products The fifth form is a combined cross-sectional view similar to the third figure, illustrating that the composite material is assembled from a base fabric layer, two film layers, and a bonding layer. [Detailed description of the preferred embodiment] Referring to the first and second figures, the method for forming a composite material product according to the present invention includes, in order, a preparation base # 11, a hot-pressed composite material 12, a cut to a predetermined size 13 and cold pressing. A molded product 14, wherein in the step of preparing the substrate η, the substrate is composed of a base fabric layer made of carbon fiber material (-" A thin film layer 22 made of a plastic polyurethane elastomer (TPU) and two bonding layers 23, wherein the base fabric layer 21 has a first base surface 211 located above and a second base surface 212 located below The bonding layers M are respectively covered on the two base surfaces 211 and 212, and the bonding layer 23 may be poly (vinyl chloride), acrylonitrile-butadiene-styrene (ABS), polystyrene (p S ), Polycarbonate (PC) or polyethylene terephthalate (p E butyl). According to the third figure, the hot-pressed composite material 丨 2 steps then apply 12 to the position The hot-pressing temperature is applied at the same time 2 ~ 10, the second one: This paper size is applicable to China National Standard (CNS) Α4 specification (21〇χ 297) ) 572825 A7 ___B7 V. Description of the invention (5) Forced to give the overall hot pressing, after 60 ~ 250 seconds, the film layer 22 will first melt and penetrate into the fibers of the base cloth layer 21 to generate with the surface treatment agent of the base cloth layer 21 The 'chemical bonding' causes the bonding layer 23 to be firmly bonded to the two base surfaces 211 and 212 of the base fabric layer 21 through the bonding of the thin film layer 22 to form a composite material 2. The cut into a predetermined size 1 3 The step is to use a cutting technique to cut the composite material 2 after the hot-press molding of the composite material into a predetermined size. The 14 steps of the cold-pressed molded product are a composite of a predetermined molding die after being cut into a predetermined size and shape. Material 2 is subjected to a cold pressing temperature of 100 to 130 ° C and a pressing pressure of 2 to 10 kg / cm, which is completed in 60 to 180 seconds. This compound is first made of composite materials. 2 First, the composite material product 1 can be completed by softening and then pressure forming, as shown in the fourth figure. From the foregoing, it can be seen that the present invention has a surface treatment agent added with diamines through the base fabric layer 21, and PXJ NC, the end group of the thin film layer 22, easily reacts with diamines to form -C Ο N fluorenyl groups Therefore, in the structure, a chemical bond is formed between the base fabric layer 21 and the bonding layers 23, and when it is damaged by external forces, it is less likely to cause delamination. Furthermore, the manufacturing process of the present invention is not only simple and fast, but also can be achieved. Another effect that is convenient to manufacture. Referring to the fifth figure, of course, in the step of preparing the substrate 11 of the present invention, 4 can also be covered on the two thin film layers 22 and the two bonding layers 2 3 to be covered with a single bonding layer 23 On one of the two film layers 22, that is, the composite material 2 is bonded to only one bonding layer 23, and its manufacturing process is completely the same, so it will not be repeated here. After the composite material 2 is formed, the composite material 2 is not covered with The thin film layer 22 on the other base surface 212 of the bonding layer 23 will also be heated to melt and penetrate into the fibers of the base fabric layer 21 to form a smooth surface. This paper is formed in a size of 5 ^ standard (CNS) λ4 size (21Gx) 297 mm) 572825 V. Description of the invention (6) Therefore, the present invention; rt; i. The soil achieves the purpose of forming a smooth composite material 2 on the surface. Referring to the second and third figures, the composite material of the preferred embodiment of the present invention includes a base fabric layer 21, two thin film finder films I 22, and two bonding layers 23, where the base fabric layer 21 It is made of carbon fiber (carb-face + main fabric) and added with an amine-based surface treatment agent. The base cloth soil 21 has a first base surface 211 located above and a Chu located below. Γ 万 之 苐 二 基 面 212. The film layers 22 are made of thermoplastic polyurethane elastomer® (thermplastic urethane elastomer (hereinafter referred to as τ PU)), which is called “丄 L 丄 y W”, and is adhered to the two bases of the base fabric layer 21 respectively. Faces 211, 212. The bonding layers 23 may be selected from the group consisting of polyvinyl chloride (PVC), acrylonitrile-butadiene_styrene (ABS), polystyrene (PS), and polycarbonate (pc). Materials such as ethyl diacetate (PET) are combined with the base fabric layer 21 by these Tpu films j, respectively. The composite material 2 after molding can be used to press the cold-pressed molded product method described above to obtain the product appearance shape required by the manufacturer. In order to achieve a better bonding strength between the base fabric layer 21 and the two bonding layers 23, in this embodiment, a τ p U 4 film layer 22 is sandwiched between the two bonding layers 23 and the base fabric layer 21, and f is a conventional glue. Sticky. In the process of hot-pressing the composite material, that is, the TPU film layer 22 is melted and penetrated into the fibers of the base fabric layer 21 at the hot-pressing temperature, so that the terminal group_Nc0 of the TPU film layer 22 and the diamine surface of the base fabric layer 21 The treatment agent reacts to form a _onh group, which forms a stable chemical bond, and has better bonding strength. When it is damaged by an external force, it is' less likely to have delamination; and the base fabric layer 21 of the present invention It is not coated with epoxy resin, so it can be used for general sewing processing. This paper size applies the Chinese National Standard (CNS) A4 specification (210x 297 mm) Page 8 572825 V. Description of the invention (7) Provide more diverse processing methods. In a month, the base fabric can be combined with only one bonding layer, which is limited to the two bonding layers 23 disclosed in the present example of bismuth. The following: the TPU film layer 22 bonding the bonding layer 23 is smooth surface. The description of 8A and 2b shows that 'this embodiment uses T' film layer 22 to bond layer 2 丨 and bonding layer 23, which can make the composite material 2 product i have a good bonding strength, said τ ρ τ τ staggered b? … Because the TPU film layer 22 does not contain a solvent, it does not generate bubbles after heating to affect the overall beauty, so the manufacturing method of the present invention can produce a product with beautiful affinity and good bonding strength1. &Quot; The above-mentioned composite material The molded product can be used for general conventional sewing processing, and it has a smooth surface after being used. Furthermore, the layer: its heating plus plastic polyurethane elastomer ... The technology of the formed film layer as a combination of the base fabric and the toilet layer can indeed make the product have better bonding strength and more beautiful appearance; and 'The composite material of the present invention can also use cold-pressed products to make various geometric shapes and appearances. According to the needs of consumers, it can really achieve the purpose. The above mentioned ones are only the preferred embodiments of the present invention, which will limit the scope of implementation of the present invention. # 大凡 应用 应用 ： 利 粑 围And the description of the invention The simple equivalent changes and modifications should still fall within the scope of the patent of the present invention. 572825 A7 B7 V. Description of the invention (8) [Comparison of component numbers] 1 Product 21 Base fabric layer 11 Preparing substrate 211 First base surface 12 Hot-pressed composite material 212 Second base surface 13 Cut to predetermined size 22 TPU film layer 14 Cold-pressed molded product 23 Joint layer 2 Composite material This paper size is applicable to China National Standard (CNS) A4 (210x 297 mm) Page 10