TW522426B - Anti-reflection/anti-static coating capable of forming pure black display panel on information display device - Google Patents

Anti-reflection/anti-static coating capable of forming pure black display panel on information display device Download PDF

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TW522426B
TW522426B TW90109326A TW90109326A TW522426B TW 522426 B TW522426 B TW 522426B TW 90109326 A TW90109326 A TW 90109326A TW 90109326 A TW90109326 A TW 90109326A TW 522426 B TW522426 B TW 522426B
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Taiwan
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display panel
information display
patent application
reflection
item
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TW90109326A
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Chinese (zh)
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Jiun-Min Hu
Guo-Ju Wang
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Chunghwa Picture Tubes Ltd
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Abstract

The present invention provides an anti-reflection/anti-static coating capable of forming pure black display panel on information display device. Carbon black powder and blue additive with spectrum range of 400 to 500 nm are mixed by a predetermined ratio, and then a predetermined ratio of distributing agent is added therein for dilution, so that the carbon black powder and blue additive can be uniformly mixed in a formed anti-static coating solution. Alternatively, the concentrated medical solution is added into an anti-static coating solution containing ATO, ITO or other conductive polymer components. After uniformly mixing, the coating solution is uniformly coated on the display panel surface of an information display device thereby forming an anti-static coating. Then, a solution containing silicon dioxide is uniformly coated on the anti-static coating, thereby forming a silicon dioxide film with low refractive index. Accordingly, the blue additive in the anti-static coating can effectively compensate the over absorption of blue light in spectrum of 400 to 700 nm by the carbon black component, so as to form a pure black display panel on the information device.

Description

522426 經濟部智慧財產局員工消費合作社印製 A7 _____Β7 五、發明說明(1 ) 發明背景: 本發明係關於一種可在資訊顯示器上形成純黑色顯示面板之抗反射/抗靜電 塗佈,尤指一種將均勻混合有碳黑及藍色添加物成份之抗靜電塗佈溶液,均勻地 塗佈在一資訊顯示器之顯示面板表面上,形成一抗靜電塗佈層,俾藉該藍色添加 物有效補償該碳黑在光譜波長爲400〜700nm範圍內對藍色光之過度吸收,令該抗 靜電塗佈溶液可在該資訊顯不器上形成純黑色之顯示面板。 先前技藝: 按,目前在製作陰極射線管時,所使用之抗反射(Anti-Reflection)及抗靜 電(Anti-Static )等塗佈處理,一般均係採用噴塗(spray)、旋轉式塗佈(spin coating) 或離子濺鍍(sputtering coating)方式,將含鍊錫氧化物(Antimony-doped Tin Oxide,以下簡稱ΑΤΟ ’如:鍊-二氧化錫Sb-Sn02)或銦錫氧化物(Indium_doped Tin Oxide,以下簡稱ITO,如:錫-三氧化二銦In203-Sii02)成份之抗靜電塗佈 溶液,塗佈在陰極射線管上呈曲面之顯示面板之外側表面,以形成一抗靜電塗佈 層,嗣再於該抗靜電塗佈層上,塗佈一含二氧化砍(Si02)(如:砂質凝膠,silica gel)成份之抗反射塗佈溶液,形成一抗反射塗佈層,以實現抗靜電及抗反射之 效果。 然而,近年來,陰極射線管之設計及製造業者,爲改善陰極射線管之可視 角度及外觀造型,已逐漸將呈曲面狀之顯示面板,設計成平面直角狀,由於此一 設計上之改變,頗受消費者喜愛,且已在坊間造成流行,幾乎有取代曲面狀陰極 射線管之趨勢。在現今廣泛被使用之平面直角陰極射線管中,參閱第1圖所示, 其顯示面板上位於中央位置之玻璃,均較其周邊位置之玻璃爲薄,導致其中央位 置玻璃之穿透率爲80%,而周邊位置玻璃之穿透率則僅爲約72%,故爲使該等 - 2- X 297公釐i (請先閱讀背面之注意事項再填寫本頁) 一 522426 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明) 平面直角陰極射線管之整體顯示面板具有較均勻之穿透率,一般均係藉降低整個 顯示面板之穿透率(大約將中心位置降至約50%),以縮小顯示面板上中央與周 邊位置間玻璃穿透率之差距比,令顯示面板能呈現更均勻之整體畫面。 以目前業界在平面直角陰極射線管平面管上所使用之塗佈方式爲例,除了 利用離子濺鍍方式,將含ITO、鈦金屬(Ti)及氮化鈦(TiN)成份之材料,塗佈至該 顯示面板上外,大都係利用含銀鈀(Ag-Pd)或銀金(Ag-Au)成份等導電材料之抗 靜電塗佈溶液,透過旋轉式塗佈(Spin coating)法,將其噴塗在於該顯示面板上, 以降地整個顯示面板之穿透率,進而縮小中央與周邊位置間玻璃穿透率之差距 比,然而,無論係利用前者或後者之作法,其製作成本均相當昂貴。 有鑑於此,發明人曾硏發出一種在抗靜電塗佈溶液中,添加碳黑(carbon black),俾可透過簡單且低成本之塗佈製程,藉調整碳黑之添加量,以有效調整 其在一資訊顯示器之顯示面板表面上,所形成之一抗靜電塗佈層之導電特性,及 整個顯示面板穿透率之均勻性。然而,由於在該塗佈製程中所添加之碳黑,在光 譜波長爲400〜700mn範圍內之色光中,對藍色光之吸光性遠較其它色光爲大, 此一特性,將令添加有碳黑成份之抗靜電塗佈溶液,被塗佈至顯示面板表面後, 其所形成之抗靜電塗佈層,將會呈現一黃黑色之底色,破壞了顯示面板之外觀色 調及資訊顯示器之影像色純,而無法爲消費者所接受。 發明綱要: 有鑑於前述在抗靜電塗佈溶液中,加入具有超導電度之碳黑,將造成顯示 面板底色偏黃黑色之問題,發明人乃硏究發明出一種可在資訊顯示器上形成純黑 色面板之抗反射抗靜電塗佈,主要係將碳黑粉末與光譜波長在400〜500nm之藍色 添加物,依一定比例混合,再於其中添加一定比例之分散劑,令二者均勻混合調 一 4一 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -------Γ丨.^--------訂---------線· (請先閱讀背面之注意事項再填寫本頁) 522426 A7 B7 五、發明說明(^ ) (請先閱讀背面之注意事項再填寫本頁) 製成濃縮藥液,再於該濃縮藥液中加入一定比例之溶劑,加以稀釋,以令該碳黑 及藍色添加物能均勻地混合於所形成之一塗佈溶液中,或將該濃縮藥液添加至一 含ΑΤΟ、ITO或其它導電局分子成份之抗靜電塗佈溶液中,並在混合均勻後,再 將該抗靜電塗佈溶液均勻地塗佈在一資訊顯示器之顯示面板表面上,形成一抗靜 電塗佈層,再於該抗靜電塗佈層上,均勻塗佈一含二氧化矽成份之溶液,以形成 一具低折射率之二氧化矽薄膜。 本發明主要目的,係在利用光譜波長在400〜500mn之該藍色添加物,以有 效補償該碳黑成份在光譜波長爲400〜700nm範圍內對藍色光之過度吸收,以在該 資訊顯示器上形成純黑色之顯示面板。 圖式說明: 第1圖乃一傳統平面直角彩色陰極射線管之顯示面板之剖面示意圖; 第2圖乃一傳統彩色陰極射線管之縱剖面示意圖; 第3圖乃將抗靜電塗佈層及抗反射塗佈層應用於一傳統彩色陰極射線管之 顯示面板上之局部剖面示意圖; 第4圖乃在光譜波長爲400〜700nm範圍內,碳黑藥液、藍色添加物及二者 之均勻混合藥液,對色光吸收率之光譜示意圖。 經濟部智慧財產局員工消費合作社印製 詳細說明: 按,一般傳統之彩色陰極射線管10,參閱第2圖所示,主要包括一密封 之玻璃管體(sealed glass envelope)12,該管體12設有一玻璃面板(faceplate) 14、 一管頸部(neck portion)18 及一中間漏斗部(intermediate funnel portion)16,該 玻璃面板14之內壁表面塗佈有螢光層(phosphor screen)24,該螢光層24包括 一5- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 522426 A7 B7 五、發明說明(j ) 複數個可分別散發螢光之螢光單元,該密封玻璃管體12之管頸部18內,貝ij設 有複數個呈直線排列之電子槍20,用以產生三色電子束22,該等電子束22經 一磁偏掃轭(magnetic deflection yoke)之控制,可沿水平及垂直方向偏折,並 焦聚於該螢光層24上,當該彩色陰極射線管1〇所產生之三色電子束,焦聚在 該玻璃面板14內壁表面上之各該螢光單元時,該等單元將散發出有色光,以在 該玻璃面板14上顯示視訊影像。 參閱第3圖所示,乃一傳統之彩色陰極射線管上玻璃面板之局部剖面示意 圖,該玻璃面板40之內壁表面塗佈有一螢光層42,其外壁表面則塗佈有一塗 佈層44。該螢光層42係由複數個彼此間隔且呈點狀(dots)或帶狀(stripes) 分佈之螢光單元所組成。該塗佈層44包含內層之抗靜電塗佈層46及外層之抗 反射塗佈層48 ’該抗靜電塗佈層46之表面接設有一導電元件50,俾藉該導電 元件50將該玻璃面板40連接至接地端,以有效去除該玻璃面板40外壁表面所 累積之靜電荷;該抗反射塗佈層48則係用以減少該玻璃面板40外壁表面對外 界環境光之反射,俾該玻璃面板40上能呈現更淸晰之視訊影像。 本發明主要係將碳黑粉末與光譜波長在400〜500nm之藍色添加物,依一定 比例混合,再於其中添加一定比例之分散劑,令二者均勻混合調製成濃縮藥液, 再於該濃縮藥液中加入一定比例之溶劑,加以稀釋,以令該碳黑及藍色添加物能 均勻地混合於所形成之一抗靜電塗佈溶液中,或將該濃縮藥液添加至一含ΑΤΟ、 ΙΤΟ或其它導電高分子成份之抗靜電塗佈溶液中,並在混合均勻後,再將該抗靜 電塗佈溶液均勻地塗佈在一資訊顯示器之顯示面板表面上,形成一抗靜電塗佈 層,再於該抗靜電塗佈層上,均勻塗佈一含二氧化矽成份之溶液,以形成一具低 折射率之二氧化矽薄膜。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁)522426 Printed by A7 _____ Β7, Employee Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the Invention (1) Background of the Invention: The present invention relates to an anti-reflection / anti-static coating that can form a pure black display panel on an information display, especially one An antistatic coating solution uniformly mixed with carbon black and blue additives is uniformly coated on the surface of an information display display panel to form an antistatic coating layer, and the blue additives are used to effectively compensate The carbon black's excessive absorption of blue light in the spectral wavelength range of 400 ~ 700nm enables the antistatic coating solution to form a pure black display panel on the information display. Previous skills: According to the current application of anti-reflection (Anti-Reflection) and anti-static (Anti-Static) coatings in the production of cathode ray tubes, generally spraying, spin coating ( spin coating) or ion coating (Sputtering coating), the chain containing tin oxide (Antimony-doped Tin Oxide, hereinafter referred to as ATTO 'for example: chain-tin dioxide Sb-Sn02) or indium tin oxide (Indium_doped Tin Oxide , Hereinafter referred to as ITO, such as: tin-indium trioxide In203-Sii02) antistatic coating solution, coated on the outside surface of the display panel with a curved surface on the cathode ray tube to form an antistatic coating layer,嗣 Apply an anti-reflection coating solution containing SiO2 (such as sand gel) to the anti-static coating layer to form an anti-reflection coating layer to realize Antistatic and anti-reflective effect. However, in recent years, in order to improve the viewing angle and appearance of the cathode ray tube, manufacturers and manufacturers of the cathode ray tube have gradually designed curved display panels to be flat rectangular. Due to this design change, It is loved by consumers and has become popular in the market. It has almost replaced the curved cathode ray tube. In the flat right-angle cathode ray tube widely used today, as shown in Fig. 1, the glass in the center position on the display panel is thinner than the glass in the peripheral position, resulting in the penetration rate of the glass in the center position. 80%, and the penetration rate of the surrounding glass is only about 72%, so in order to make these-2-X 297 mmi (Please read the precautions on the back before filling this page)-522426 A7 B7 Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperative Co., Ltd. 5. Description of the invention) The overall display panel of the flat right-angle cathode ray tube has a more uniform transmission rate, which is generally reduced by reducing the transmission rate of the entire display panel (about reducing the center position to about 50%), in order to reduce the gap ratio of the glass transmittance between the central and peripheral positions on the display panel, so that the display panel can present a more uniform overall picture. Taking the coating method currently used on the flat tube of the flat right-angle cathode ray tube in the industry as an example, in addition to using ion sputtering, a material containing ITO, titanium metal (Ti) and titanium nitride (TiN) components is coated. To the display panel, most of them are anti-static coating solutions containing conductive materials such as silver-palladium (Ag-Pd) or silver-gold (Ag-Au) components, which are spin-coated by a spin coating method. Spraying is applied to the display panel to reduce the transmittance of the entire display panel, thereby reducing the ratio of the transmittance of the glass between the central and peripheral positions. However, whether the former or the latter method is used, the production cost is quite expensive. In view of this, the inventors have proposed to add carbon black to the antistatic coating solution. The carbon black can be effectively adjusted by adjusting the amount of carbon black through a simple and low-cost coating process. On the surface of a display panel of an information display, the conductive properties of an antistatic coating layer formed and the uniformity of the transmittance of the entire display panel. However, due to the carbon black added in the coating process, among colored lights with a spectral wavelength in the range of 400 to 700 mn, the light absorption of blue light is much greater than other colored lights. This feature will make carbon black added. After the component's antistatic coating solution is applied to the surface of the display panel, the antistatic coating layer formed by it will show a yellow and black background color, which will destroy the appearance color of the display panel and the image color of the information display. Pure and not acceptable to consumers. Summary of the Invention: In view of the foregoing, the addition of carbon black with superconductivity to the antistatic coating solution will cause the problem of yellowish black background color of the display panel. The inventor has invented a method that can form a pure color on the information display. The anti-reflection and anti-static coating of the black panel is mainly composed of carbon black powder and blue additives with a spectral wavelength of 400 ~ 500nm, mixed in a certain ratio, and then a certain proportion of dispersant is added to make the two uniformly mixed and adjusted. 1-4 The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ------- Γ 丨. ^ -------- Order -------- -Line · (Please read the precautions on the back before filling this page) 522426 A7 B7 V. Description of the invention (^) (Please read the precautions on the back before filling this page) Make a concentrated liquid, and then add the concentrated liquid Add a certain proportion of solvent to the solution and dilute it so that the carbon black and blue additives can be evenly mixed in one of the coating solutions formed, or add the concentrated chemical solution to a solution containing ATTO, ITO, or other Antistatic coating solution of conductive molecular components, and after mixing well , And then uniformly coating the antistatic coating solution on the surface of a display panel of an information display to form an antistatic coating layer, and then uniformly coating a silicon dioxide-containing component on the antistatic coating layer. Solution to form a silicon dioxide film with a low refractive index. The main purpose of the present invention is to use the blue additive with a spectral wavelength of 400 to 500 mn to effectively compensate the carbon black component's excessive absorption of blue light in the spectral wavelength of 400 to 700 nm in order to display the information on the information display. Form a pure black display panel. Description of the drawings: Fig. 1 is a schematic cross-sectional view of a display panel of a traditional flat right-angle color cathode ray tube; Fig. 2 is a longitudinal cross-sectional view of a conventional color cathode ray tube; Fig. 3 is an antistatic coating layer and anti- The partial cross-section schematic diagram of the reflective coating applied to the display panel of a traditional color cathode ray tube; Figure 4 is a uniform mixture of the carbon black chemical solution, the blue additive and the two in the spectral wavelength range of 400 ~ 700nm Schematic diagram of the absorption spectrum of the medicinal solution. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs in detail: According to the general traditional color cathode-ray tube 10, see FIG. 2, which mainly includes a sealed glass envelope 12, the tube body 12 A glass faceplate 14, a neck portion 18 and an intermediate funnel portion 16 are provided, and the inner wall surface of the glass panel 14 is coated with a phosphor screen 24, The fluorescent layer 24 includes a 5-size paper which is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 522426 A7 B7 V. Description of the invention (j) A plurality of fluorescent units capable of emitting fluorescence, In the neck portion 18 of the sealed glass tube body 12, Beij is provided with a plurality of linearly arranged electron guns 20 for generating three-color electron beams 22, which are passed through a magnetic deflection yoke ) Control, it can be deflected in the horizontal and vertical directions and focused on the fluorescent layer 24. When the three-color electron beams generated by the color cathode ray tube 10 are focused on the inner wall surface of the glass panel 14 Each of the fluorescent units Such unit emit colored light to display the video image on the glass panel 14. Refer to FIG. 3, which is a schematic partial cross-sectional view of a glass panel on a conventional color cathode ray tube. The inner surface of the glass panel 40 is coated with a fluorescent layer 42 and the outer wall surface is coated with a coating layer 44. . The fluorescent layer 42 is composed of a plurality of fluorescent units spaced apart from each other and distributed in dots or stripes. The coating layer 44 includes an inner anti-static coating layer 46 and an outer anti-reflection coating layer 48. The surface of the anti-static coating layer 46 is provided with a conductive element 50, and the glass is borrowed from the conductive element 50. The panel 40 is connected to a ground terminal to effectively remove the electrostatic charge accumulated on the outer wall surface of the glass panel 40; the anti-reflection coating layer 48 is used to reduce the reflection of the outer wall surface of the glass panel 40 to the external ambient light, and the glass The panel 40 can present a clearer video image. The present invention mainly mixes carbon black powder and blue additives with a spectral wavelength of 400 ~ 500nm in a certain ratio, and then adds a certain proportion of a dispersant therein, so that the two are evenly mixed to prepare a concentrated chemical solution. Add a certain proportion of solvent to the concentrated chemical solution and dilute it so that the carbon black and blue additives can be uniformly mixed in one of the formed antistatic coating solutions, or add the concentrated chemical solution to an ΑΤΟ , ITO or other conductive polymer components in an antistatic coating solution, and after mixing well, the antistatic coating solution is evenly coated on the surface of an information display display panel to form an antistatic coating. Layer, and then uniformly coating a solution containing a silicon dioxide component on the antistatic coating layer to form a silicon dioxide film with a low refractive index. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

T · ϋ n ^ Ί a —Bi 1_1 ·ϋ emmmf n ϋ ·_1 I 經濟部智慧財產局員工消費合作社印製 522426 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明($) 在本發明之一實施例中,該濃縮藥液中該藍色添加物與碳黑之重量百分比, 約在5%〜60%範圍內,而該藍色添加物及碳黑與該分散劑均勻混合後,所形成之 濃縮藥液’可視實際需要,直接於其中加入一定比例之溶劑,加以稀釋,形成該 抗靜電塗佈溶液,該溶劑可爲甲、乙、丙或丁醇等含有〇Η·結構之有機溶劑,或 水、醚類及酮類等溶劑,俾藉由該等溶劑令該等材料成份能被均勻混合,調製 成所需之抗靜電塗佈溶液;或將該濃縮藥液以10%〜50%之重量百分比,添加至 含ΑΤΟ、ITO或其它導電高分子成份之該抗靜電塗佈溶液中,俟各該成份被均勻 混合後’可採用噴_spray)或旋轉式塗佈(Spin c〇ating)方式,將該抗靜電塗佈 溶液均勻地塗佈在資訊顯示器之顯示面板表面上,以形成一抗靜電塗佈層。 本發明在該濃縮藥液未被添加至含該ΑΤΟ、ITO或其它導電高分子成份之 抗靜電塗佈溶液時’可利用超優導電度特性之碳黑成份,以增加該抗靜電塗佈材 料之導電效果,並可藉調整碳黑成份之添加量,以有效調整該顯示面板之穿透率, 若該濃縮藥液係被添加至含該ΑΤΌ、ΙΤΟ或其它導電高分子成份之抗靜電塗佈溶 液中時,則該碳黑成份可爲一不具導電特性之碳黑。在本發明中,該藍色添加物 可爲光譜波長在400〜500nm之藍色顏料或染料,俾有效補償該碳黑成份在光譜波 長爲4〇0〜7〇Omn範圍內對藍色光之過度吸收,參閱第4圖所示,令該抗靜電塗佈 層對各色光具有較均勻之吸收特性,而在該資訊顯示器上形成一純黑色之抗靜電 塗佈層。 該抗靜電塗佈層上可塗佈一含二氧化矽(Si〇2)成份之溶液,該溶液可由矽氧 院基化合物(silicon alkoxide)在酸中水解而成,以形成一層具低折射率之二氧化 矽膜’並可藉由調整該抗反射塗佈層之厚度,以得到最佳之抗反射效果。如此, 本發明即可透過簡單之製程,及較低之成本,在該彩色陰極射線管之玻璃面板上 __- 7- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁)T · ϋ n ^ Ί a —Bi 1_1 · ϋ emmmf n ϋ · _1 I Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 522426 Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economics A7 B7 V. Description of the invention ($) In one embodiment of the invention, the weight percentage of the blue additive and carbon black in the concentrated chemical solution is in the range of about 5% to 60%, and the blue additive and carbon black are uniformly mixed with the dispersant. According to actual needs, a certain concentration of the formed liquid solution is directly added to the solvent solution and diluted to form the antistatic coating solution. The solvent may be methyl, ethyl, propyl, or butanol, etc. Organic solvents, or solvents such as water, ethers, and ketones, so that these materials can be uniformly mixed to prepare the required antistatic coating solution; or % ~ 50% by weight, added to the antistatic coating solution containing ATTO, ITO or other conductive polymer components, after each component is uniformly mixed, 'spray spraying' or spin coating ( Spin c〇ating) The coating solution was uniformly coated on the surface of the display panel of the display information to form an antistatic coating layer. In the present invention, when the concentrated chemical solution is not added to the antistatic coating solution containing the ATTO, ITO, or other conductive polymer components, the carbon black component with super excellent conductivity characteristics can be used to increase the antistatic coating material. The conductive effect can be adjusted by adding the amount of carbon black ingredients to effectively adjust the transmittance of the display panel. If the concentrated chemical solution is added to the antistatic coating containing the AT, ITO or other conductive polymer ingredients When in a cloth solution, the carbon black component may be a carbon black with no conductive properties. In the present invention, the blue additive may be a blue pigment or dye with a spectral wavelength of 400 to 500 nm, which effectively compensates the carbon black component ’s excessive blue light in the range of the spectral wavelength of 400 to 700 nm. Absorption, as shown in FIG. 4, so that the antistatic coating layer has relatively uniform absorption characteristics for each color of light, and a pure black antistatic coating layer is formed on the information display. The antistatic coating layer can be coated with a solution containing silicon dioxide (SiO2). The solution can be hydrolyzed from silicon alkoxide in acid to form a layer with a low refractive index. The silicon dioxide film can be adjusted by adjusting the thickness of the anti-reflection coating layer to obtain the best anti-reflection effect. In this way, the present invention can adopt a simple manufacturing process and a lower cost on the glass panel of the color cathode ray tube. 7- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ) (Please read the notes on the back before filling this page)

522426 A7 _____B7 五、發明說明) 依序形成所需之抗靜電及抗反射塗佈層,以有效消除靜電壓及環境光對該資訊 顯示器所造成之不良影響。 在本發明中,該分散劑(surface activation agent)可爲陰離子型之高分子分 散劑,如:多兀竣化物(polycarboxylate)及聚苯乙儲磺化物(polystyrene sulfonate) 等,其添加量與該濃縮藥液中該藍色添加物及碳黑之重量百分比,約在5%〜200% 之範圍間。 在本發明之前述實施例中,該資訊顯示器之玻璃面板外壁表面上,所形成 之該抗靜電塗佈層,其厚度約在50〜500nm(其中n=10 9,m=公尺)範圍,而該抗 靜電塗佈層上所塗佈之二氧化矽膜,其厚度約在50〜5〇Onm(其中n=l〇-9,m=公 尺)範圍,在該等可行之厚度範圍內,又以該抗靜電塗佈層厚度在80〜120nm,且 二氧化矽膜厚度在SOcrmnm之範圍內,所製作出之資訊顯示器爲最佳。 以上所述,僅係本發明之較佳實施例,惟,本發明所主張之權利範圍,並 不局限於在彩色陰極射線管上之應用,按凡熟悉該項技藝人士,依據本發明所 揭露之技術內容,在其它資訊顯示器(如:電獎顯示器或液晶顯示器)上之應用, 均應屬不脫離本發明之保護範疇。 (請先閱讀背面之注意事項再填寫本頁) -I n ϋ ϋ ^OJI n ϋ ·ϋ n βϋ - 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 522426 A7 _B7 五、發明說明(f ) 附圖之圖號說明: 玻璃管體 …… ......12 顯示面板 …… .......14 胃頸部 …… ......18 漏斗部 ...... .......16 電子槍 …… ......20 螢光層 ...... .......24 抗靜電塗佈層·…… ......46 抗反射塗佈層…… .......48 導電元件 ·…… ......50 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 -9-本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)522426 A7 _____B7 V. Description of the invention) The required antistatic and antireflection coating layers are formed in order to effectively eliminate the adverse effects of static voltage and ambient light on the information display. In the present invention, the dispersant (surface activation agent) may be an anionic polymer dispersant, such as polycarboxylate and polystyrene sulfonate, etc., and the addition amount thereof is the same as that of the dispersant. The weight percentage of the blue additive and carbon black in the concentrated medicinal solution is in the range of about 5% to 200%. In the foregoing embodiment of the present invention, the thickness of the antistatic coating layer formed on the outer wall surface of the glass panel of the information display device is about 50 ~ 500nm (where n = 109, m = meter), The thickness of the silicon dioxide film coated on the antistatic coating layer is about 50 ~ 50nm (where n = 10-9, m = meter), which is within these feasible thickness ranges. With the thickness of the antistatic coating layer in the range of 80 ~ 120nm and the thickness of the silicon dioxide film in the range of SOcrmnm, the information display produced is the best. The above are only the preferred embodiments of the present invention. However, the scope of the claimed rights of the present invention is not limited to the application on color cathode ray tubes. According to those skilled in the art, the disclosure according to the present invention The application of the technical content to other information displays (such as electronic award displays or liquid crystal displays) should not depart from the protection scope of the present invention. (Please read the precautions on the reverse side before filling out this page) -I n ϋ ϋ ^ OJI n ϋ · ϋ n βϋ-Printed on paper standards of the Ministry of Economic Affairs and Intellectual Property Bureau's Consumer Cooperatives, this paper is compliant with China National Standard (CNS) A4 specifications ( (210 X 297 mm) 522426 A7 _B7 V. Description of the invention (f) Drawing number description of drawings: Glass tube body ...... 12 Display panel ...... 14 Gastric neck ............ 18 Funnel section ............ 16 Electron gun ............ 20 Fluorescence layer ............ .24 Antistatic coating ......... 46 Antireflection coating ......... 48 Conductive element ... 50 (Please read the Note: Please fill in this page again.) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. -9- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm).

Claims (1)

522426 A8 B8 C8 D8 六、申請專利範圍 1、 一種可在資訊顯示器上形成純黑色顯示面板之抗反射/抗靜電塗佈,主要 係將碳黑粉末與藍色添加物,依一定比例混合,再於其中添加一定比例之分散劑, (請先閱讀背面之注意事項再填寫本頁) • 令二者均勻混合調製成濃縮藥液,並於該濃縮藥液中加入一定比例之溶劑,加以 稀釋後,再均句地塗佈在一資訊顯示器之顯示面板表面上’以形成一塗佈層’俾 藉其中之該藍色添加物,有效補償該碳黑成份在光譜波長爲4〇〇〜700nm範圍內 對藍色光之過度吸收,令該資訊顯示器上形成一純黑色之塗佈層。 2、 如申請專利範圍第1項所述之可在資訊顯示器上形成純黑色顯示面板之 抗反射/抗靜電塗佈,其中該濃縮藥液可添加至一含導電材料成份之抗靜電塗佈 溶液中,再將該抗靜電塗佈溶液均勻地塗佈在資訊顯示器之顯示面板表面上,以 形成一抗靜電塗佈層。 3、 如申請專利範圍第1或2項租述之可在資訊顯示器上形成純黑色顯示面 板之抗反射/抗靜電塗佈,其中各該塗佈層上可均勻塗怖一含二氧化矽成份之溶 液,以形成一具低折射率之二氧化矽薄膜。 4、 如申請專利範圍第1或2項租述之可在資訊顯示器上形成純黑色顯示面 板之抗反射/抗靜電塗佈,其中該藍色添加物係光譜波長在400〜500nm之藍色顏 料。 經濟部智慧財產局員工消費合作社印製 5、 如申請專利範圍第1或2項租述之可在資訊顯示器上形成純黑色顯示面 板之抗反射/抗靜電塗佈,其中該藍色添加物係光譜波長在400〜500nm之藍色染 料。 6、 如申請專利範圍第1或2項»之可在資訊顯示器上形成純黑色顯示面 板之抗反射/抗靜電塗佈,其中該濃縮藥液中該藍色添加物與碳黑粉末之重量百 分比約在5%〜60%間。 國國家標準(CNS)A4規格(210 X 297公釐) 522426 A8 B8 C8 D8 六、申請專利範圍 7、如申請專利範圍第1或2項所述之可在資訊顯示器上形成純黑色顯示面 板之抗反射/抗靜電塗佈,其中該分散劑之添加量與該濃縮藥液中該藍色添加物 及碳黑粉末之重量百分比,約在5%〜200%之範圍間。 8 '如申請專利範圍第7項g述之可在資訊顯示器上形成純黑色顯示面板之 抗反射/抗靜電塗佈,其中該分散劑可爲一陰離子型之高分子分散劑。 9、如申請專利範圍第8項β之可在資訊顯示器上形成純黑色顯示面板之 抗反射/抗靜電塗佈,其中該分散劑可爲含多元羧化物(polycarboxylate)成份之分 散劑。 10 '如申請專利範圍第8項g述之可在資訊顯示器上形成純黑色顯示面板 之抗反射/抗靜電塗佈,其中該分散劑可爲含聚苯乙儲擴化物(polystyrene sulfonate戚份之分散劑。 11、 如申請專利範圍第2項所述之可在資訊顯示器上形成純黑色顯示面板 之抗反射/抗靜電塗佈,其中該藍色添加物與碳黑藥液之均勻混合所調製成之藥 液,與該抗靜電塗佈溶液之重量百分比約在10%〜50°/。間。 12、 如申請專利範圍第2項所述之可在資訊顯示器上形成純黑色顯示面板 之抗反射/抗靜電塗佈,其中該抗靜電塗佈溶液可爲一含導電高分子成份之抗靜 電塗佈溶液。 13、 如申請專利範圍第2項所述之可在資訊顯示器上形成純黑色顯示面板 之抗反射/抗靜電塗佈,其中該抗靜電塗佈溶液可爲一含ΑΤΟ成份之抗靜電塗佈 溶液。 14、 如申請專利範圍第2項所述之可在資訊顯示器上形成純黑色顯示面板 之抗反射/抗靜電塗佈,其中該抗靜電塗佈溶液可爲一含ΙΤΟ成份之抗靜電塗佈 溶液。 ___ -11 -_ 紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) --------訂---------線». 經濟部智慧財產局員工消費合作社印製 522426 A8 B8 C8 D8 申請專利範圍 15、 如申請專利範圍第3項所述之可在資訊顯示器上形成純黑色顯示面板 之抗反射/抗靜電塗佈,其中該抗靜電塗佈層之厚度約在50〜500nm範圍。 16、 如申請專利範圍第3項所述之可在資訊顯示器上形成純黑色顯示面板 之抗反射/抗靜電塗佈,其中該二氧化矽膜之厚度約在50〜500nm範圍。 (請先閱讀背面之注意事項再填寫本頁) my ---------訂---------線», 經濟部智慧財產局員工消費合作社印製 12 ‘紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)522426 A8 B8 C8 D8 6. Scope of patent application 1. An anti-reflection / anti-static coating that can form a pure black display panel on an information display, which is mainly a mixture of carbon black powder and blue additives in a certain proportion, and then Add a certain proportion of dispersant to it (please read the precautions on the back before filling this page) • Make the two uniformly mixed to prepare a concentrated chemical solution, and add a certain proportion of the solvent to the concentrated chemical solution and dilute it. , And then evenly coated on the surface of an information display's display panel to form a coating layer. The blue additive is used to effectively compensate the carbon black component at a spectral wavelength of 400 to 700 nm. The excessive absorption of blue light in the inside causes a pure black coating layer to be formed on the information display. 2. The anti-reflection / antistatic coating that can form a pure black display panel on an information display as described in item 1 of the scope of the patent application, wherein the concentrated chemical solution can be added to an antistatic coating solution containing a conductive material component Then, the antistatic coating solution is evenly coated on the surface of the display panel of the information display to form an antistatic coating layer. 3. Anti-reflection / anti-static coating that can form a pure black display panel on the information display as leased in item 1 or 2 of the scope of patent application, wherein each of the coating layers can be evenly coated with a silicon dioxide-containing component Solution to form a silicon dioxide film with a low refractive index. 4. Anti-reflection / anti-static coating that can form a pure black display panel on the information display as leased in item 1 or 2 of the scope of patent application, where the blue additive is a blue pigment with a spectral wavelength of 400 ~ 500nm . Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. If the leased item 1 or 2 of the patent application applies to the anti-reflection / anti-static coating on the information display, a pure black display panel can be formed. The blue additive is Blue dye with a spectral wavelength of 400 ~ 500nm. 6. Anti-reflection / antistatic coating that can form a pure black display panel on the information display if the scope of patent application is item 1 or 2 », wherein the weight percentage of the blue additive and carbon black powder in the concentrated chemical solution About 5% ~ 60%. National Standard (CNS) A4 Specification (210 X 297 mm) 522426 A8 B8 C8 D8 VI. Patent Application Range 7, as described in item 1 or 2 of the patent application range, which can form a pure black display panel Anti-reflection / anti-static coating, wherein the added amount of the dispersant and the weight percentage of the blue additive and carbon black powder in the concentrated chemical solution are in the range of about 5% to 200%. 8 'As described in item 7g of the scope of patent application, anti-reflection / antistatic coating that can form a pure black display panel on an information display, wherein the dispersant may be an anionic polymer dispersant. 9. The anti-reflection / anti-static coating which can form a pure black display panel on an information display, such as item 8 of the scope of patent application, wherein the dispersant may be a dispersant containing a polycarboxylate component. 10 'As described in item 8g of the scope of patent application, an anti-reflective / antistatic coating that can form a pure black display panel on an information display, wherein the dispersant may be a polystyrene sulfonate-containing compound Dispersant 11. The anti-reflection / anti-static coating that can form a pure black display panel on the information display as described in item 2 of the scope of the patent application, wherein the blue additive is prepared by uniformly mixing the carbon black chemical liquid The weight percentage of the finished medicinal solution and the antistatic coating solution is between about 10% and 50 ° /. 12. As described in item 2 of the scope of patent application, the resistance of the pure black display panel can be formed on the information display. Reflection / antistatic coating, wherein the antistatic coating solution may be an antistatic coating solution containing a conductive polymer component. 13. As described in item 2 of the scope of patent application, a pure black display can be formed on the information display. The anti-reflective / anti-static coating of the panel, wherein the anti-static coating solution may be an anti-static coating solution containing ATTO component. 14. As described in item 2 of the patent application scope, it can form a pure anti-static coating solution. Anti-reflection / anti-static coating of color display panels, where the anti-static coating solution can be an anti-static coating solution containing ITO. ___ -11 -_ Paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) (Please read the precautions on the back before filling out this page) -------- Order --------- line ». Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 522426 A8 B8 C8 D8 Patent application range 15, as described in item 3 of the patent application range, anti-reflective / antistatic coating that can form a pure black display panel on the information display, wherein the thickness of the antistatic coating layer is about 50 Range of ~ 500nm. 16. The anti-reflection / antistatic coating that can form a pure black display panel on the information display as described in item 3 of the patent application range, wherein the thickness of the silicon dioxide film is in the range of 50 ~ 500nm. (Please read the precautions on the back before filling out this page) my --------- Order --------- line », Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, 12 'paper scale Applicable to China National Standard (CNS) A4 (210 X 297 mm)
TW90109326A 2001-04-18 2001-04-18 Anti-reflection/anti-static coating capable of forming pure black display panel on information display device TW522426B (en)

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