TW448038B - Methods for improving the residual control of mites and prolonging the protection of plants from mite infestations - Google Patents
Methods for improving the residual control of mites and prolonging the protection of plants from mite infestations Download PDFInfo
- Publication number
- TW448038B TW448038B TW087108861A TW87108861A TW448038B TW 448038 B TW448038 B TW 448038B TW 087108861 A TW087108861 A TW 087108861A TW 87108861 A TW87108861 A TW 87108861A TW 448038 B TW448038 B TW 448038B
- Authority
- TW
- Taiwan
- Prior art keywords
- plant
- compound
- plants
- item
- application
- Prior art date
Links
- 241000238876 Acari Species 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 17
- 201000002266 mite infestation Diseases 0.000 title claims abstract description 4
- 125000004104 aryloxy group Chemical group 0.000 claims abstract description 17
- -1 pyrimidine compound Chemical class 0.000 claims abstract description 15
- 241000196324 Embryophyta Species 0.000 claims description 42
- 150000001875 compounds Chemical class 0.000 claims description 31
- 235000013399 edible fruits Nutrition 0.000 claims description 16
- 230000002079 cooperative effect Effects 0.000 claims description 8
- 241001454293 Tetranychus urticae Species 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 150000003230 pyrimidines Chemical class 0.000 claims description 4
- 241000488581 Panonychus citri Species 0.000 claims description 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 3
- 230000002147 killing effect Effects 0.000 claims description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
- 241001643371 Brevipalpus phoenicis Species 0.000 claims description 2
- 240000007154 Coffea arabica Species 0.000 claims description 2
- SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- 241001122767 Theaceae Species 0.000 claims 1
- 239000008186 active pharmaceutical agent Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- 125000003944 tolyl group Chemical group 0.000 claims 1
- 238000011156 evaluation Methods 0.000 description 10
- 241000237858 Gastropoda Species 0.000 description 8
- 241000207199 Citrus Species 0.000 description 6
- 229940126062 Compound A Drugs 0.000 description 6
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 6
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 6
- 241000220324 Pyrus Species 0.000 description 5
- 230000000895 acaricidal effect Effects 0.000 description 5
- 230000001154 acute effect Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 241000488583 Panonychus ulmi Species 0.000 description 4
- 235000020971 citrus fruits Nutrition 0.000 description 4
- 208000015181 infectious disease Diseases 0.000 description 4
- 241000239290 Araneae Species 0.000 description 3
- 206010061217 Infestation Diseases 0.000 description 3
- 235000021017 pears Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 235000000832 Ayote Nutrition 0.000 description 2
- 244000241235 Citrullus lanatus Species 0.000 description 2
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 235000009854 Cucurbita moschata Nutrition 0.000 description 2
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 241000219146 Gossypium Species 0.000 description 2
- 241000758791 Juglandaceae Species 0.000 description 2
- 241000218922 Magnoliophyta Species 0.000 description 2
- 244000070406 Malus silvestris Species 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 235000014443 Pyrus communis Nutrition 0.000 description 2
- 241000124033 Salix Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 244000098338 Triticum aestivum Species 0.000 description 2
- 241000269370 Xenopus <genus> Species 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000000642 acaricide Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 235000021016 apples Nutrition 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 235000008504 concentrate Nutrition 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004495 emulsifiable concentrate Substances 0.000 description 2
- 244000037666 field crops Species 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 235000014571 nuts Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 235000015136 pumpkin Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000012085 test solution Substances 0.000 description 2
- 235000020234 walnut Nutrition 0.000 description 2
- 241000254032 Acrididae Species 0.000 description 1
- 235000009434 Actinidia chinensis Nutrition 0.000 description 1
- 235000009436 Actinidia deliciosa Nutrition 0.000 description 1
- 241001506414 Aculus Species 0.000 description 1
- 244000144725 Amygdalus communis Species 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- 241000208223 Anacardiaceae Species 0.000 description 1
- 235000002147 Australian walnut Nutrition 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- 235000004936 Bromus mango Nutrition 0.000 description 1
- 244000045232 Canavalia ensiformis Species 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- 241001070941 Castanea Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- 241000723382 Corylus Species 0.000 description 1
- 235000007466 Corylus avellana Nutrition 0.000 description 1
- 241000219122 Cucurbita Species 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 241001558857 Eriophyes Species 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 244000081841 Malus domestica Species 0.000 description 1
- 240000007228 Mangifera indica Species 0.000 description 1
- 235000014826 Mangifera indica Nutrition 0.000 description 1
- 241000207836 Olea <angiosperm> Species 0.000 description 1
- 244000025272 Persea americana Species 0.000 description 1
- 235000008673 Persea americana Nutrition 0.000 description 1
- 235000010617 Phaseolus lunatus Nutrition 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 241001396980 Phytonemus pallidus Species 0.000 description 1
- 241000952063 Polyphagotarsonemus latus Species 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 240000007651 Rubus glaucus Species 0.000 description 1
- 241000646858 Salix arbusculoides Species 0.000 description 1
- 235000009184 Spondias indica Nutrition 0.000 description 1
- 241000271567 Struthioniformes Species 0.000 description 1
- 241001454295 Tetranychidae Species 0.000 description 1
- 241000488589 Tetranychus kanzawai Species 0.000 description 1
- 241000488530 Tetranychus pacificus Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 240000006909 Tilia x europaea Species 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- 235000020224 almond Nutrition 0.000 description 1
- 230000000908 anti-sweet Effects 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 235000020226 cashew nut Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 235000021038 drupes Nutrition 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 235000021013 raspberries Nutrition 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000021012 strawberries Nutrition 0.000 description 1
- 229940028300 tigan Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N29/00—Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
- A01N29/10—Halogen attached to an aliphatic side chain of an aromatic ring system
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Description
448 〇3b A7 ——--__- 五、發明説明(1 ) 蜗類在園藝植物和農業作物上造成巨大的經濟損失。特 …,蟎類在葉部及成熟果實上取食,危害柑拮類、梨 果類。 爲控制㈣之侵染,植物在生長季中被多次施以市售的 殺蜗劑。僅管將現今市面上可得的殺端劑複合施用,職 侵染對植物造成的傷害依舊發生。因此,一直持續研究, 以期發現不需複合施用而能保護植物不受蜗類侵染之更有 效的新殺蟎劑。 在W0 94/02470中述及-些適用爲有效殺蜗劑的㈣化 合物。然而,該文獻並未揭示任何殘餘殺蟎活性。 尸斤以本發明目的之一即提供—種改善蜗類殘餘控制的方 法。 本發明另一項目的是提供一種延長植物保護對抗蟎類侵 染的方法。 由以下的詳細敘述中,本發明此二項及其他因的將更爲 明確。 發明摘述 經濟部中央標準局負工消费合作社印製 --------)A------π ·'··,· (請先聞讀背面之注意事項#-填寫本頁) 本發明提供改良蟎之殘餘控制及延長植物保護對抗蟎之 染的方法’此方法爲在易受蟎類侵染的植物葉部施用有 效殺蟎量的非對稱性4,6-雙(芳氧基)嘧啶化合物。 發明説明 本發明提供—種改良蟎之殘餘控制的方法,其包括在易 受蟎類侵染的植物葉部施用有效殺蟎量的非對稱性4,6_雙 -4- 本紙張尺度適用中國國家標準(CNS〉Α4規格(2Η)Χ297公犮)
經濟部中央標準局員工消費合作社印繁 448 〇38 Α7 B7 五、發明説明(2 ) (芳氧基)嘧啶化合物,其結構式如式工
其中X爲氯、硝基或氰基。 :發明也提供一種延長植物保護對抗蜗之侵染的方法, 其包括在植物葉部施用有效殺蜗量的—式 (芳氧基)嘧啶化合物。 ’又 本發明非對稱性4,6_雙(芳氧基)喃咬化合物及其相應之 對稱性類似物在W0 9稱247〇有相關叙述。該文獻僅示急 性(非^餘性)殺虫茜效力的評估。現已驚喜地發現,當施用 生物T急性劑量(如LC„値)的嘧啶化合物於植物上時,本 發明的非對稱性4,6_雙(芳氧基)“化合物比其對稱性响 呢類似物明顯地更具蟎類殘餘控制效力。 更有利地,單獨施用一種本發明的非對稱性4,6-雙(芳氧 基)嘧啶化合物,可保護植物全季不受蟎類侵染。在使用 舊式殺蟎劑時,需複合施用以保護植物不受蟎類侵染,因 而造成3承境負擔,而一次施用本發明非對稱性4,6_雙(芳氧 基)嘧啶化合物即能達到全季保護植物的效果,顯著減少 壤境負擔。 本發明較佳具體實施例中非對稱性4,6-雙(芳氧基)嘧啶 化合物是4-[(4·氣 α,α,α-三氟-間-甲苯基)氧]-6-[〇,α, α,4-四氟·間-甲苯基)氧]嘧啶。 -5 本紙狀度賴中關家縣(CNS ) Α规格⑺⑽加公楚 (請先閱讀背面之注意事項每填寫本頁) • ------—訂----- 448 ο 38 A7 B7 經 濟 部 中 標 準 工 消 合 作 社 印 製 五、發明説明(3 本發明式I化合物對草食性蟎類的殘餘控制特別有用。 草食性蟎類包括(但不限於)葉蟎科如二斑葉蟎(Tetranychus urticae) ' 太平洋葉蟎(丁etranychus pacificus)、神澤葉蟎 (Tetranychus kanzawai)、蘋果全爪蟎(Pan〇nychus ulmi)、柑 橘全爪蟎(Pan〇nychus citri)和草地小爪蟎(〇Hg〇nychus pratensis);細蟎科如 Phytonemus pallidus 和茶黃蟎 (Polyphagotarsonemus latus);銹蟎科如女貞刺癭蟎(Aculus schlechtendali) ' 刺瘦蟎(PhylI〇c〇ptrata 〇leiv〇ra)和甜芽癭 蟎(Eriophyes sheldoni);和細鬚蟎科如紫紅短鬚蟎 (Brevipalpus phoenicis)。特定言之,本發明非對稱性4,6_ 雙(芳氧基)嘧啶化合物對二斑葉蟎、蘋果全爪蟎、柑橘全 爪蟎和紫外短鬚蟎之殘餘控制特別有效。 能被本發明式I化合物長期保護,不受蟎類侵染的植物 包括(但不限於):柑桔類植物如柳橙、葡萄柚、檸檬、萊 姆;梨果類如蘋果、梨、奇異果;核果類如酪梨、桃子、 櫻桃、無花果、橄欖、芒果;藤蔓類果樹如葡萄、草莓' 覆盆子;果仁類如杏仁、大胡桃、核桃、開心果、腰果、 榛子、栗子、澳洲核桃、巴西豆;田園作物如棉花、玉 米、大豆、小麥、南瓜、西瓜;裝飾植物如開花植二、灌 木’·咖啡;及茶。本發明非對稱性4,6、—雙(芳氧基)嘧啶化 合物特別適用於長期保護柑桔類植物、梨果類不受蟎嗦俨 染。 ^ 爲延長蟎類殘餘控制,對果樹及裝飾植物施以含有約】 克/公石到]00公克/公石(以5公克/公石到2 5 * A兄/公石爲 -6- 448 Ο 3 d A7 B7 五、發明説明(4 經濟部中央標準局負工消费合作社印製 佳)的式I非對稱性4,6-雙(芳氧基)嘧啶化合物的分散液, 以水性較佳。實際上,通常是將分散液施用在果樹或裝飾 植物上至流下爲止。 當對作物施用足量有效成份使施用率達約〇 〇 1公斤/公頃 到1.0公斤/公頃(0.08公斤/公頃到〇 3公斤/公頃爲佳)時, 本發明非對稱性4,6 -雙(芳氧基)嘧啶化合物也適用於延長 田間作物之蟎類殘餘控制。 此處所指之”植物葉部"包括(但不限於)植物的葉、芽、 果、莖 '細枝、粗枝和/或花。此處所指之"果樹包括(但 不限於)柑桔類植物、梨果類植物、核果類植物、藤蔓類 果樹和果仁類作物。此處所指之”裝飾植物"包括(但不限 於)開花植物和灌木。還有,此處所指之”田園作物,,包括 (但不限於)南瓜、西瓜等蔬果,及棉花、玉米、大豆、小 麥等成排的作物 ‘ 二 本發明非對稱性4,6_雙(芳氧基)嘧啶化合物的劑型可調 配成乳化濃縮物、流質濃縮物或可濕化散劑,可加水戋其 他適當極性溶劑,在通常原處稀釋,然後呈稀釋噴液^ =壓此非對稱性4,6.雙(芳氧基)·化合物亦可調配成乾 性壓縮顆粒、粒劑、粉劑、粉狀濃縮物、懸浮渡縮物、微 扎剑,寺。本發明此等調配物或组合物包括本發明 性4,6-雙(芳氧基)嘧啶化合物與—種或多種農 I 的惰性固態或液態載體混合。 "要 爲了促進對本發明更進一步的了解,提 甘φ #各, 「@例況 ”更砰盡的細節。本發明範圍不應被實例限制, 申請專利範圍中定義的所有主題。 .’w 受 明 包括 0拍衣------.玎 (請先聞讀背面之注意事項#填寫衣買) -7 5張尺度適用 448 〇3d Λ7 ~—------- B7 五、發明説明(5 ) 實例1 支見盖對抗二斑葉餘殺蟎活性之誶估 將菜昱(sieva lima bean)的葉子浸泡在5〇%丙酮試液中。 每種試液中含有已測試過化合物之二斑葉蟎1^99値的二倍 跟度。所採用之LC"値是此化合物在急性劑量測試中能殺 死二斑葉蟎的濃度,單位爲百萬分一(ppm)。採用LC99 値’在測試之初提供待測化合物作爲生物當量急性劑量。 之後植物放在平台上風乾、底部澆水,放在溫室中,每曰 日照1 4小時。分別在施藥後〇天' 3天、7天爲植物取樣。 每個取樣期,自溫室中取出適當植物,每片葉子感染約 50-60隻二斑葉蟎。三天後計算成蟎數,並估算蟎之死亡 率,結果如表I。受評估之化合物分別名稱如下,表〗中以 數字代表的化合物爲本發明的化合.勒,以字母代表的化合 物爲對照化合物。 .’ 由表I中的數據可見,本發明非對稱性4,6_雙(芳氡基)嘧 啶化合物比其相應對應性類似物明顯地更具有二斑葉蜗殘 餘控制效力。這是預料之外的結果,因早先曾在植物上施 用生物當量急性劑量。 經濟部中央標準局員工消費合作社印製 尺 I張 紙 一本 毕 一標 I家 國 國 I中 用 I適 8 4 4 038 A7 B7 五、發明説明(6
表I 嘧啶之殘餘殺蟎故力 二斑葉虫S(Tetranychus urticae) 死亡率% 處理後天數 施用率 二倍1^99値 0 3 1 化合物 fppm') 本發明化合物1 7 100 99 99 本發明化合物2 10 100 96 97 對稱性化合物A 8 100 80 25 對稱性化合物B 6 100 49 未評估 請 先 閔 讀 背 之 注 意 筆 項 再' ύ 寫 本 頁 經濟部中央標準局員工消費合作社印製 實例2 殘餘殺蟎活性之由間試驗 評估數種草食性蟎類在果樹及柑桔類之殘餘控制的田間 試驗中,將含有5或1 5公克/公石待測化合物的水性混合物 以手持喷器施用在植物葉部,喷撒量約1 〇〇〇到2000公升/公 頃(即喷在葉上至流下止)。此水性混合物是由適量待測化 合物的可乳化濃縮物加水製備而成。在此評估法中,此可 乳化濃縮物含有重量比9.7%的待測化合物,3.5%陶喜姆 (TOXIMUL®) 3403F(伊利諾州,諾司非得,史地潘公司 (Stepan Company, Northfield, Illinois)出品之陰離子 / 非離 子性混合清潔劑),3.5%陶喜姆3404F(史地潘公司出品之 陰離子/非離子性混合清潔劑),和83.3%阿若馬地 (AROMATIC®) 200(德州,休士頓EXXON化學藥品阿美利 本紙張尺度適用中國國家標準(CMS ) Α4規格(210X297公釐) 0 3 8 A7 __B7 五、發明説明(7 ) 加(EXXON Chemicals Americas)出品之芳香煙溶劑)° 在施用藥劑後,約每週檢查植物上之活蟎數,比較已處 理和未處理的植株上蟎類數目而評估殘餘控制效力。結果 如表11 -表V I。在表II-VI中化合物係如實例1,以數字或 字母代表。 由表II-VI的數據可見,本發明非對稱性4,6-雙(芳氧基) 嘧啶化合物(4-[(4-氯-α,β,沈-三氟間甲苯基)氧] or,α,4-四氟-間-甲幕基)氧]ρ密咬)比對稱性ρ密咬類似物 (4,6-雙[〇, α,λ,4-四氟-間-曱苯基)氧]嘧啶)對紫紅起鬚 蟎、紅蜘蛛、歐洲紅蜘蛛有明顯更大程度的殘餘控制今 力。
表II 田間柳燈上施用抗Brevipalpus phoenicis(紫紅短鬚蜗)喝 啶之評估-評估1 蟎類控制百分率 處理後天數 --------裝— (請先閲讀背面之注f事項I填馬本頁) 訂 處理 經濟部中夬榡準局員工消費合作社印製 本發明化合物1
對稱性化合物A 施用率 7 21 50 (公克/公石) 15 94 100 90 1〇0 5 100 100 93 88 15 97 100 93 δδ 5 94 100 69 68 -10 本紙張尺度適用中國國家標準(CMS ) A4規格(210X297公釐) 448 〇38 A7 B7 五 、發明説明(8 )
表III 田間柳燈上施用抗Brevipalpus phoenicis(紫紅短鬚蟎)嘧 啶之評估-評估2 虫禹類控制百分率 處理後天數 MM 施用率 (公克/公石) 7_ 30. 1A 90 120 本發明化合物I 15 100 98 98 94 99 5 100 94 96 91 79 對稱性化合物A 15 100 94 98 58 63 5 100 95 89 58 64
表IV 田間柳燈上施用抗Brevipalpus phoenicis(紫紅短鬚蜗)嘧 症之評估-評枯3 (讀先閱讀背面之注-意事項再填寫本頁〕 裝 經濟部中央標準局員工消費合作社印製 端類控制百分率 處理後天數 處理 施用率 (公克/公石) 7 35. Μ 90. 124 本發明化合物1 15 89 100 100 100 98 5 95 100 98 98 80 對稱性化合物A 15 97 100 100 98 71 5 96 94 95 72 0 -11 - 本纸張又度適用中國國家標準(CNS ) A4規格(2〗0X29?公釐) 448〇38 A7 B7 五 、發明説明(9 ) 表V 面間柳梭'上施用抗甜稿全爪蜗(Panonychus citri)(紅缺i蛛)喊 啶之評估 蟎類控制百分率 處理後天數 施用率 (公克/公石) 7 21 30 本發明化合物I 15 99 97 94 對稱性化合物A 15 88 85 69 表VI 田間蘋果上施用抗蘋果全爪蟎(Panonychus ulmi)(歐洲 蜘蛛)嘧啶之評估 蜗類控制百分率 處理後天數 〇丫裝— (諳先閱讀背面之;!意事項•再填寫本頁} 訂 經濟部中央標準局貝工消費合作社印製
Mm 施用率 2 ϋ 21 36 (公克/公石) 本發明化合物I 15 97 99 97 94 5 77 92 94 64 對稱性化合物A 15 90 93 96 78 5 ΊΊ 70 86 28 -12 - 本紙張尺度適用中國國家標準(CNS ) Μ规格(21〇X297/>t ) 448038
A
7 B 明説 明 發五
淖载诨??命穿A ^蹲洛-ib 命#2 ^緣^-岭蓉一 -命芽 y。 ^c 〇 a-VA^VSxc. 3 c· hi
.^/3s^sΛνΛβ
-韋1^ (讀先閱讀背面之注意事項再填寫本頁) -. . 訂 經濟部中央標準扃負工消费合作社印製 4>i(4-a4 n - H |l-甚-f 沭鲥)-^5a 4,6-5?k,54i |l-?-3舛辦)^-泰硌 4-【(Q, Q, Q ,4-風!,-a^^)lt;l -、·( α ,θ, IL-4i“,-sK¥ -?l J ,^-A· 4-【(4-羚,an 笋-s--s^B^ -H( Q, θ, Q ,4-3 齊-涵-3休^)5命硌 3 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X297公釐)
Claims (1)
- 448〇38 厂’·· · 1申請專—藏W AS B8 C8 D8 1. 一種改良蟎之殘餘控制的方法, 之植物葉部上施用有效殺竭量的非易受 嘧啶化合物,其結構式如下: %〖生4,心雙(芳虱基)經濟部中夬標準局員工消費合作社印製 其中 X爲氣,硝基或氰基。 2. 根據申請專利範圍第1項之方法, 卜 々古,其中孩化合物爲4_[(仁 虱-Ha-三氟-間-曱苯基)氣1 曱笨基)氧心。 )氧…(m心四氣-間- 3. 根據申請專利範圍第】項之方法,其中該植物係選自: 甜括類植物、樂果類水果、核果類水果、藤蔓類水果、 果仁類作物 '田園作物、裝飾植物、咖啡和茶。 4·根據中請專利範圍第i項之方法,纟中該植物爲果樹或 裝飾植物,且施用在植物葉部之化合物施用率爲約i公 克/公石到1 〇 〇公克/公石。 5. 根據申請專利範圍第丨項之方法,其中該植物爲田園作 物,且施用在植物葉部之化合物施用率爲約〇〇丨公斤/公 頃到1.0公斤/公頃。 6. —種延長植物保護對抗蟎類侵染的方法,其包括在植物-葉郅施用有效殺蟎量的非對稱性4,6-雙(芳氧基)嘧啶化 合物,其結構式如下: -14 本紙張尺度適用中國國家標準(CNS ) Μ規格(2丨0 X 297公釐) (諳先閱讀背面之注意事項再填寫本頁) Ό—裂_ -訂 …線 °38 A8 B3 C8 DS 、申請專利範圍其中 X是氣,硝基或氰基。 7_根據申請專利範園第6項之方法,其中該化合物爲4-[(4-氣-α,α,心三氟··間_甲苯基)氧]四氟_間_ 甲卑•基)氧]D密淀。 8.根據申請專利範圍第7項之方法,其中該蟎類係選自: 二斑葉蜗(Tetranychus urticae),蘋果全爪蜗(pan〇nyclius ulmi)柑橘全爪蜗(Panonychus citri),和紫紅短鬚虫禹. (Brevipalpus phoenicis) ° . 9,根據申請專利範圍第6項之方法,其中該植物爲果樹或 裝飾植物,且施用在;ik物葉部的化合物施用率爲約1公 克/公石到1〇〇公克/公石。 瓜根據申請專利範園第6項之方法,其中該植物是田園作. 物’且施用在植物葉部的化合物施用率爲約Q · Q 1公斤/公 頃到1.0公斤/公頃。 (請先鬩讀背面之注意事項再填寫本頁) .裝. 訂 ;線 鲤濟部中央標率局員工消費合作社印製 -15- 本纸張尺度適用中國國家標準(CNS ) A4規格(210 X 297公釐)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/874,116 US5883104A (en) | 1997-06-12 | 1997-06-12 | Methods for improving the residual control of mites and prolonging the protection of plants from mites infestations |
Publications (1)
Publication Number | Publication Date |
---|---|
TW448038B true TW448038B (en) | 2001-08-01 |
Family
ID=25363008
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW087108861A TW448038B (en) | 1997-06-12 | 1998-06-04 | Methods for improving the residual control of mites and prolonging the protection of plants from mite infestations |
Country Status (27)
Country | Link |
---|---|
US (1) | US5883104A (zh) |
EP (1) | EP0883991B1 (zh) |
JP (1) | JP4205207B2 (zh) |
KR (1) | KR100519419B1 (zh) |
CN (1) | CN1115959C (zh) |
AR (1) | AR015883A1 (zh) |
AT (1) | ATE230213T1 (zh) |
AU (1) | AU726913B2 (zh) |
BR (1) | BR9801809A (zh) |
CA (1) | CA2240205C (zh) |
CZ (1) | CZ293984B6 (zh) |
DE (1) | DE69810386T2 (zh) |
DK (1) | DK0883991T3 (zh) |
ES (1) | ES2190044T3 (zh) |
GE (1) | GEP20012424B (zh) |
HU (1) | HU218986B (zh) |
ID (1) | ID21027A (zh) |
IL (1) | IL124746A (zh) |
OA (1) | OA10796A (zh) |
PL (1) | PL191616B1 (zh) |
RU (1) | RU2259043C2 (zh) |
SG (1) | SG74056A1 (zh) |
SK (1) | SK284052B6 (zh) |
TR (1) | TR199801071A2 (zh) |
TW (1) | TW448038B (zh) |
UA (1) | UA59351C2 (zh) |
ZA (1) | ZA985098B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10013914A1 (de) | 2000-03-21 | 2001-09-27 | Bayer Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
US6903053B2 (en) | 2000-06-09 | 2005-06-07 | The Procter & Gamble Company | Agricultural items and agricultural methods comprising biodegradable copolymers |
DE10055941A1 (de) | 2000-11-10 | 2002-05-23 | Bayer Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
DE10353281A1 (de) | 2003-11-14 | 2005-06-16 | Bayer Cropscience Ag | Wirkstoffkombination mit insektiziden und akariziden Eigenschaften |
DE102007045922A1 (de) | 2007-09-26 | 2009-04-02 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW234077B (zh) * | 1992-07-17 | 1994-11-11 | Shell Internat Res Schappej B V | |
SG63694A1 (en) * | 1996-03-07 | 1999-03-30 | American Cyanamid Co | Process for the preparation of unsymmetrical 4,6-bis (aryloxy) pyrimidine compounds |
-
1997
- 1997-06-12 US US08/874,116 patent/US5883104A/en not_active Expired - Fee Related
-
1998
- 1998-06-03 IL IL12474698A patent/IL124746A/xx not_active IP Right Cessation
- 1998-06-04 ID IDP980825A patent/ID21027A/id unknown
- 1998-06-04 TW TW087108861A patent/TW448038B/zh not_active IP Right Cessation
- 1998-06-05 JP JP17389198A patent/JP4205207B2/ja not_active Expired - Fee Related
- 1998-06-09 BR BR9801809-4A patent/BR9801809A/pt not_active Application Discontinuation
- 1998-06-09 CZ CZ19981781A patent/CZ293984B6/cs not_active IP Right Cessation
- 1998-06-10 AT AT98304593T patent/ATE230213T1/de not_active IP Right Cessation
- 1998-06-10 EP EP98304593A patent/EP0883991B1/en not_active Expired - Lifetime
- 1998-06-10 ES ES98304593T patent/ES2190044T3/es not_active Expired - Lifetime
- 1998-06-10 CA CA002240205A patent/CA2240205C/en not_active Expired - Fee Related
- 1998-06-10 SG SG1998001385A patent/SG74056A1/en unknown
- 1998-06-10 PL PL326778A patent/PL191616B1/pl not_active IP Right Cessation
- 1998-06-10 DE DE69810386T patent/DE69810386T2/de not_active Expired - Fee Related
- 1998-06-10 GE GEAP19984340A patent/GEP20012424B/en unknown
- 1998-06-10 DK DK98304593T patent/DK0883991T3/da active
- 1998-06-11 UA UA98063034A patent/UA59351C2/uk unknown
- 1998-06-11 ZA ZA9805098A patent/ZA985098B/xx unknown
- 1998-06-11 KR KR1019980021688A patent/KR100519419B1/ko not_active IP Right Cessation
- 1998-06-11 TR TR1998/01071A patent/TR199801071A2/xx unknown
- 1998-06-11 HU HU9801322A patent/HU218986B/hu not_active IP Right Cessation
- 1998-06-11 RU RU98111069/15A patent/RU2259043C2/ru not_active IP Right Cessation
- 1998-06-11 SK SK784-98A patent/SK284052B6/sk not_active IP Right Cessation
- 1998-06-11 AU AU70116/98A patent/AU726913B2/en not_active Ceased
- 1998-06-11 AR ARP980102785A patent/AR015883A1/es active IP Right Grant
- 1998-06-12 OA OA9800078A patent/OA10796A/en unknown
- 1998-06-12 CN CN98109888A patent/CN1115959C/zh not_active Expired - Fee Related
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2720351T3 (es) | Uso de derivados de trifluoroetilsulfóxido sustituidos con N-arilamidina para combatir ácaros tetraníquidos mediante riego, aplicación por goteo, aplicación por inmersión o inyección en el suelo | |
KR20090060360A (ko) | 기생의 치료 또는 예방 방법 | |
EP0404872A4 (en) | Environmentally safe insecticide | |
TW448038B (en) | Methods for improving the residual control of mites and prolonging the protection of plants from mite infestations | |
TWI265784B (en) | Compositions for improving growth of plants comprising pyroquilon and neonicotinoids compounds | |
RU2727654C1 (ru) | Средство для комплексного воздействия на растения | |
Mitchell | Plant-growth regulators | |
Nderitu et al. | Utilization of synthetic and botanical insecticides to manage thrips (Thysan.: Thrip.) on snap beans (Fabaceae) in Kenya | |
RU2609404C2 (ru) | Способ регулирования роста растений и применение кломазона для улучшения роста растений | |
Panday et al. | Comparative efficacy of seed treatment and their combinations with foliar spray of insecticides for the management of Antigastra catalaunalis in sesame | |
TW201119578A (en) | Active compound combinations | |
JP4602491B2 (ja) | 害虫駆除剤 | |
MXPA98004415A (en) | Methods to improve the residual control of machines and to prolong the protection of plants contrainfestaciones de aca | |
KR20050087965A (ko) | 수란 추출물을 함유하는 천연 농약 조성물 | |
BR112021015081A2 (pt) | Misturas fungicidas, composição pesticida, métodos para controlar pragas fitopatogênicas, para melhorar a saúde das plantas e para proteção de material de propagação de plantas contra pragas e material de propagação de plantas | |
CN113016452A (zh) | 一种利用捕食螨防治桃树害螨的方法及应用 | |
CN114097802A (zh) | 一种含氟环唑和稻瘟灵的乳油剂型 | |
EP1139747A1 (en) | Fungicidal composition | |
US20150245612A1 (en) | Active ingredient for controlling spider mites | |
PA | of one, three, seven and fifteen days after spraying and with reference to the same sample of leaves as selected for pre-treatment observation. The per cent control due to treatment was obtained with the help of HENDEB | |
JPS58198406A (ja) | 植物栽培上の新規な用途にホスホン酸化合物を利用する方法 | |
JPS5829282B2 (ja) | 植物の摘花及び落葉促進剤及びその製法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
GD4A | Issue of patent certificate for granted invention patent | ||
MM4A | Annulment or lapse of patent due to non-payment of fees |