TW436422B - Glass fiber-reinforced laminates, electronic circuit boards and methods for assembling a fabric - Google Patents

Abstract

The present invention provides reinforced laminates for printed circuit boards having a woven reinforcement fabric of a yarn including E-glass fibers having a coating which is compatible with the polymeric matrix material. The yarn has a loss on ignition ranging from about 0.01 to about 0.6 weight percent and an air jet transport drag force of greater than about one gram force per gram mass of yarn evaluated using a needle air jet nozzle unit having an internal air jet chamber having a diameter of 2 millimeters and a nozzle exit tube having a length of 20 centimeters at a yarn feed rate of about 274 meters (about 300 yards) per minute and an air pressure of about 310 kiloPascals (about 45 pounds per square inch) gauge. The laminate has a flexural strength in the fill direction of the fabric greater than about 3 x 10<SP>7</SP> kilograms per square meter (about 42.7 kpsi). The yarn coating can include polyester and a polymer selected from vinyl pyrrolidone polymers, vinyl alcohol polymers, starches and mixtures thereof. Alternatively, the laminate has a coefficient of thermal expansion in the z-direction of less than about 4.5 percent at a temperature of 288 DEG C.

Description

436422 A7 B7 V. Description of the invention (1)

-II. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economics. FIELD OF THE INVENTION The present invention relates to a reinforced laminate for electric circuit boards, and in particular, to the use of fresh air nozzles that are compatible with the matrix resin of the laminate. Looms can promote the lamination of woven coated glass fiber woven fabrics. BACKGROUND OF THE INVENTION Electronic circuit boards are generally formed of a fabric laminate layer composed of reinforcing fibers, such as glass fibers, which can provide dimensional stability of the circuit board to maintain the integrity of the circuit disposed thereon. Twisting or warping of the board due to temperature gradients during manufacturing due to different thermal expansion rates of the components of the circuit board will adversely affect the adhesion of the circuit to the circuit board, and thus affect its reliability and performance. The smoothness of the laminate surface can also affect the adhesion of electronic circuits to circuit boards. Weaving defects such as broken monofilaments or fine hairs of the woven fabric adversely affect the surface smoothness and suppress the adhesion between the circuit and the laminate. In an air jet loom, when the glass fiber monofilaments bundled when the warp is impacted by a column or the weft is blown by a high-speed air jet, fine hairs are generated. As the speed of modern air jet loom increases, the integrity of the fiber bundle and the resistance to fiber breakage provided by the fiber bundle coating become more important. »The coating on glass fibers also affects the quality of circuit boards. Starch, which is a component of many sizing compositions for glass fibers used in weaving operations, can adversely affect the adhesion between the glass fibers and the laminate matrix material, i.e. starch is generally not compatible with the laminate resin matrix material. In order to avoid the incompatibility between glass fiber and laminate resin matrix material, the sizing component (heat treatment or degreasing) is generally decomposed by heat before lamination, or the coating or sizing composition is removed from the fabric by washing with water ° The conventional thermal cleaning method includes heating the woven cloth at 380 t for 60 to 80 hours (please read the precautions on the back before filling out this page) IIII · Packing. Order -4-This paper size is suitable for financial and family standards 隼) Μ specifications (2 | ^ 97 male thin 43 64 2 2 A7 A7 B7 5. When the invention was explained (2). Then the cleaned woven fabric was coated with a silane coupling agent to improve the adhesion between the glass-breaking fiber and the matrix resin. The strength of glass fiber In particular, the flexural strength of the laminate can be greatly reduced due to these thermal fiber coating removal procedures. Heat-cleaned glass fibers such as D-glass, S-glass, and Q-glass with high oxidized stone content, due to strength Loss and distortion are therefore particularly poor. Many coating compositions as reinforcements in composites or laminates of glass fibers that require heat or water cleaning prior to use are disclosed in the art. Patent Application No. 9-208,268 Reveal a kind of standing after spinning Cloth made of yarn or synthetic resin and 0_001 to 20_0% by weight inorganic solid particles such as colloidal silica, calcium carbonate, kaolin and talc-coated glass fibers. Heat or water is required before forming the laminate USP 5,286,562 discloses a mesh screen product that can be woven on an air jet loom and has a coating of at least 45% by weight, a lubricant, a polyethylene p-cyclohexane, and an organosilicon coupling agent. Fabric fiber bundle. USP 5,038,555 discloses a double-twisted glass fiber bundle for screen products, which is composed of epoxy film-forming agent, emulsifier, lubricant, organic functional organic metal coupling agent, polyvinylpyrrolidone, polyethylene and Coating of water-based chemical treatment composition of water. Printed by the Central Government Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives i ^ ϋ. ^^ 1 1 ^ 1 1 ^ 1 —-. * 氏 I'- -5 (Please read the back first Note: Please fill in this page again) In order to avoid cleaning the glass fiber cloth with heat, Japanese Patent Application No. 8-1 19,682 discloses a main sizing agent for glass fiber containing water-soluble epoxy resin and pH 5.5 to 7.5. Quickly remove sizing agent with water Similarly, USP 5,236,777 discloses a method for manufacturing glass cloth for reinforced resin, which comprises at least one selected from the group consisting of amine-modified epoxy resin, ethylene oxide-added epoxy resin, and ethylene oxide-added Biphenol A water-soluble film-forming agent, silicon-5- This paper is in accordance with Chinese National Standard (CNS) A4 specification (2 丨 0X297 male f) 436 ^ 1 ο Α7 Β7 Printed by the Consumers' Cooperatives of the Central Government Bureau of the Ministry of Health Preparation 5. Description of the invention (3), the main sizing agent of alkane coupling agent and lubricant is used to coat the glass yarn, and the yarn is washed with water until the main sizing amount is reduced to less than 0 2 55% by weight L Ο1 and the Secondary sizing treatment. Japanese Patent Application No. 9-268,034 discloses an adhesive without double-tested glass fiber yarns, comprising a water-soluble urethane compound and / or a water-soluble epoxy product modified by an addition reaction with a polyol. USP 4,933,381 discloses a resin-compatible sizing composition for glass fibers containing an epoxy film former, a nonionic lubricant, a cationic lubricant 'a silane coupling agent, and an acid such as acetic acid or citric acid. Japanese Patent Application No. 8-325,950 discloses a glass fiber sizing agent containing, as the main components, polyvinylpyrrolidone, a water-soluble epoxy resin amine addition product, and a silane coupling agent that does not require thermal removal from a finished glass cloth. Japanese Patent Application No. 7-102,483 discloses a secondary warp sizing agent for glass fibers of woven glass cloth, which does not need to be removed with hot oil. This secondary warp sizing agent is mainly made of polyethylene. It is composed of pyrrolidone and contains additives such as high molecular weight polyvinyloxy. The water-soluble epoxy resin may be contained therein as an adhesive component. However, there is still a need for a glass fiber that is compatible with various polymeric matrix materials and avoids the formation of fine hairs and fiber breaks during weaving to improve the adhesion between the laminate and the circuit, and is compatible with modern air jet weaving equipment to increase production. SUMMARY OF THE INVENTION An object of the present invention is a reinforcing laminate for electrons and supports. The laminate includes: (a) a polymeric matrix material; and (b) a woven reinforced fabric. Base material compatible coatings at least part 6 This paper size is applicable to Chinese National Standard (CNS) M specification (2! 0 × 297). I I, In 1 ^ —JII—eJ (Please read the notes on the back before filling in (This page) Printed by the Central Laboratories of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, 4 3 64 22 a? B7 V. Description of the invention (4) Coated glass fiber yarn, the burning loss of the yarn is from about 0.0 1 to about 0_6% by weight and the drag force of air jet conveyance is greater than about 100,000 grams of force per gram of mass yarn 'using a needle-shaped air jet nozzle unit with an internal air jet chamber with a diameter of 2 mm and a nozzle outlet pipe with a length of 20 cm on the yarn The linear feed rate is about 274 meters (about 300 yards) per minute and about 3 10 仟 Baska (about 45 pounds per square inch) gauge air pressure. The laminate has a bending strength greater than the fabric filling direction. About 3 X 107 kg per square meter (Approximately 42.7 kpsi). Another object of the present invention is a reinforcing laminate for an electronic support, the laminate comprising: (a) a polymeric matrix material; and (b) a woven reinforced fabric comprising Yarn of at least partially coated glass fibers coated with a coating compatible with a polymeric matrix material, the coating comprising (1) polyester; and (2) at least one selected from the group consisting of ethylene pyrrolidone polymer and ethyl ethyl alcohol polymer Polymers in groups formed by starch and starch "Another object of the present invention relates to a reinforcing laminate for an electronic support, the laminate comprising: (a) a polymeric matrix material; and (b) a woven reinforced fabric, It includes yarns containing glass fibers coated at least partially with a coating compatible with a polymeric matrix material, the coating including (1) polyester; and (2) ethylene pyrrolidone polymer. Yet another object of the present invention is an electronic circuit board comprising: (a) a laminate for an electronic support, including: (i) a woven reinforced fabric including a glass fiber-containing yarn, the yarn being Burning weight loss is from about 0.01 to about 0.6% by weight and air jet conveying drag is greater than about 100,000 grams of force per gram of mass yarn, using needle-shaped air jet nozzles with an internal air jet chamber having a diameter of 2 mm. The scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) --------- install-(Please read the precautions on the back before filling this page) Order 436422 A7 87 Central Standard of the Ministry of Economic Affairs Printed by 隼 扃 贝 工 consuming cooperatives 5. Description of the invention (5 units and nozzle outlet pipe with a length of 20 cm at a yarn feed rate of about 274 meters (about 300 yards) per minute and about 3 1 0 Baska (about (4 5 pounds per square inch) gauge under air pressure, where the flexural strength of the laminate in the fabric filling direction is greater than about 3 X 107 kilograms per square meter (about 42.7 kpsi); and (ii) coated A layer of polymeric matrix material on at least a portion of the fabric; and The conductive layer of the selected part of the selected side. Another object of the present invention is an electronic circuit board, including (a) a laminate for an electronic support, including: (i) a woven fabric, including Parts of glass fiber-coated yarn coated with a coating comprising (1) polyester; and (2) at least one polymer selected from the group consisting of ethylene pyrrolidone polymer, vinyl alcohol polymer, and starch ; And (ii) a layer of polymeric matrix material coated on at least a portion of the fabric; and (b) a conductive layer of a selected portion adjacent to a selected side of the laminate. Yet another object of the present invention is an electronic circuit The plate 'includes: (a) a laminate of an electronic support, including: (i) a first composite layer, including: (1) a woven fabric' including yarns containing glass fibers, the yarns having a weightless combustion loss 〇001 to about 0.6% by weight and the drag force of the air jet conveyance is greater than about 100 gram force per gram of mass yarn, using a 釺 -shaped air jet nozzle unit having an internal air jet chamber with a diameter of 2 mm and a length of 20 Nozzle exit tube during yarn feed About 274 meters per minute (about 300 yards) and air pressure of about 3 10 Baska (about 45 pounds per square inch) gauge air pressure, the bending strength of the laminate in the fabric filling direction is greater than about 3 x 107 kg per square meter (approximately 42 7 kpsi); and (2) a layer of polymeric matrix material coated on at least a portion of the fabric; and (π) a second composite layer stomach different from the first composite layer: And e (b) next to each other -------- install ------- order (please read the notes on the back before filling this page) Printing 4 3 64 2 2 a? ______ B7 ____ V. Description of the Invention (6) * ·-The conductive layer on the selected part of the laminated side through the selected side. Still another object of the present invention is an electric circuit board 'including: (a) a laminate for an electronic support, including: (i) a first composite layer' including: (1) a woven fabric 'comprising Parts of a glass fiber yarn coated with a coating comprising (A) a polyester; and (B) at least one polymer selected from the group consisting of a vinylpyrrolidone polymer, a vinyl alcohol polymer, and starch; And (2) a layer of polymeric matrix material coated on at least a portion of the fabric; and (ii) a second composite layer different from the first composite layer; and (b) a selection adjacent to the selected side of the laminate Part of the conductive layer. Another object of the present invention is a copper-clad reinforced laminate for an electronic support, the laminate comprising: (a) a polymeric matrix material; and one or more woven reinforced fabrics, each layer comprising from about 30 to about 75% by weight A yarn containing a coating compatible with a polymeric matrix material, at least partially coated glass fiber, wherein the thermal expansion coefficient of the laminate in the z direction at a temperature of 288 ° C is less than about 45%. Yet another object of the present invention is a method for assembling fabrics. The first yarn and the second yarn are alternately woven to form a fabric. The improvement includes: the first yarn is made of a coating compatible with the polymer matrix material. The partially-coated glass-breaking fiber, the coating comprises (1) polyester; and at least one polymer selected from the group consisting of ethylene pyrrolidone polymer, ethylene alcohol polymer, and irrigation powder. Yet another object of the present invention is a method for forming a laminate of a woven fabric and a polymeric matrix material. The method is to coat the woven fabric with the polymeric matrix material to form a coated fabric, and apply heat to the coated fabric. The woven fabric includes glass fiber-containing yarns, and the improvements include: at least a portion of the paper size of the glass fiber applies the Chinese national standard (CNS} A4 specification (2 丨 Ox 2 meals) ----- * (please Read the precautions on the back before filling in this page. Binding · Ordering A7 436422 V. Description of the invention (7) Coated with a coating compatible with the polymer matrix material, the burning loss of the yarn is from about 0.01 to about 〇 , 6% by weight and air jet conveying drag force is greater than about 10,000 grams of force per gram of mass yarn, using a needle-shaped air jet nozzle unit with an internal air jet chamber with a diameter of 2 mm and a length of 20 The nozzle outlet tube of the centimeter is evaluated under an air pressure of about 274 meters (about 300 yards) per minute and about 3 10 仟 Baska (about 45 pounds per square inch) gauge pressure, in which the laminate is in The bending strength of the fabric filling direction is greater than 3 × 200 kg per square meter (approximately 42.7 kpsi). Another object of the present invention is a method for forming a woven fabric and a polymer matrix material sense laminate. The woven fabric is at least partially coated with the polymer matrix material. Forming a coated fabric and applying heat to the coated fabric, the woven fabric including glass fiber-containing yarns, where improvements include: the glass fibers are at least partially coated with a coating compatible with the polymeric matrix material, The coating comprises (1) a polyester; and (2) at least one polymer selected from the group consisting of a vinylpyrrolidone polymer, an ethyl alcohol polymer, and starch. The drawing briefly illustrates the foregoing summary and the following preferred specifics The details of the examples will be easier to understand with the drawings. "In the drawings: Figure 1 is a cross-sectional view of the reinforced laminate of the present invention; Figure 2 is a top view of the fabric of the present invention; Figure 3 is a view of the coated fiber bundle of the present invention Perspective view; Figure 4 is a cross-sectional view of the electronic support of the present invention; Figure 5 is a cross-sectional view of another specific example of the electronic support of the present invention; Figure 6 is a schematic view of a method for assembling fabrics and forming a laminate according to the present invention; -10 -This paper size Use Chinese National Standard (CNS) A4 specification (210X29 ^) -----______. ^ N ^^^ 1! I HI (-I tmf, Ding (Please read the precautions on the back before filling this page) Ministry of Economy Central Procurement Bureau Consumer Work Co-operation Consumer Du Duanzhuang Ministry of Economic Affairs Central Standards Bureau Employees Cooperative Cooperative Print 4364 2 2 at _______B7 ____ V. Description of the Invention (8) Figure 6a is an enlarged view of part of Figure 6. Details of the Invention The laminate is reinforced with a woven fabric including coated glass fiber bundles, which can provide the laminate with low thermal expansion coefficient, good flexural strength, thermal stability, hydrolytic stability, low corrosion resistance, and high humidity, response Acidic acid and reactivity in the presence of the test. The coated glass fiber bundle is compatible with a variety of polymeric matrix materials &apos; eliminating the need to clean the glass fiber fabric with heat or water before lamination. Another obvious advantage of the coated glass-breaking fiber bundle of the present invention is its good processability in knitting and knitting, especially air jet knitting. As used herein, "air nozzle weaving" means a type of fabric weaving in which the yarn (weft) is inserted into the warp chamber by blowing compressed air from one or more air jet nozzles (see Fig. 5). 2Air jet delivery drag force (as described below) is an indicator of the compatibility of the beam with the air jet propulsion procedure. A higher air jet drag force value means that the yarn is properly monofilamented without breaking and is therefore more conducive to air jet Propulsive aerodynamics. Low fine hair and low aperture, low broken monofilaments, low forming cups, low spool%, low fiber bundle tension, high fHabiiity and low insertion time are other things that can be provided by the coated glass-breaking fiber of the present invention Desired features to promote weaving and knitting and thus provide fabrics with good smoothness and few surface defects in printed circuit board applications. Now refer to FIG. 1, where the same numbers in the description represent the same elements, and FIG. 1 shows the layers of the present invention The laminate 10 includes a polymeric matrix material 12 (detailed below), which is reinforced with a woven fabric lining 4. The fabric lining 4 may be n-ϋ I n--inin I. HI T 1____ _ Λ &lt; Please read the precautions on the reverse side before filling out this page) This paper size is applicable to the ns family standards (CNS) (21QX297 Gongguang 436422 A7 B7 Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 5. Description of the invention (9) Any suitable knitting or weaving procedure is formed, but preferably formed by an air jet weaving method described in detail later. Referring now to FIGS. 2 and 3, the fabric 14 includes one or more fibers containing at least one glass fiber. Coated fiber bundles of U. 6. Preferred bundles 6 include a plurality of glass fibers 18. As described herein, &quot; bundle &quot; means one or more individual fibers. 'Fiber' means individual monofilaments Glass fiber 18 may be made of any kind of fiberizable glass composition known in the art, including fiberizable glass compositions such as &quot; E_glass &quot; '&quot; A.glass &quot;, "C-glass" , &Quot; D-broken &quot;, &quot; q_glass &quot;, "R-glass &quot;, glass &quot;, and E-glass derivatives. &Quot; E_glass &quot; means a small amount Fluorine and / or boron and preferably boron-free and / or boron-free glass compositions. As described herein, a small amount means less than about 1% by weight fluorine and less than about 5% by weight butterfly barium salt and mineral wool fibers are other examples of glass fibers that can be used in the present invention. Preferred glass fibers are made of E-glass Or E-glass derivatives. This composition and the method for making glass monofilaments from this composition are known in the art and JL believes that it is not necessary to discuss further in this article. If additional information is needed, such glass combinations Materials and fiberization methods are described in K, Loewenstein, Glass Fiber Manufacturing Technology, (3rd Edition, 1993), 3 0-44 '47-60, 115-122, and 126-135, USP 4,542, 106, and 5,789,329 &amp; IPC · EG -140 &quot; Specification of Finished Fabric Weaving Made from "E" Glass of Printed Plates &quot;, page 1, Publication of the Association for Interconnection and Packaging Electronic Circuits (June 1997), And for reference in this article. The glass fiber may have a nominal monofilament diameter from about 5.0 to about 35.0 microns (equivalent to the monofilament designation D to U and above) and preferably has a diameter of about 90 to about 300-12.-This paper size applies to Chinese national standards (CNS) A4 specification (2l0x29 * 7mm) (Please read the notes on the back before filling in this page) Binding d36 ^ 22 V. Description of invention (10) A7 B7 Shellfish consumer cooperation of the Central Standards Bureau of the Ministry of Economic Affairs 衽The size of printed paper is applicable to the nominal monofilament diameter of China National Standard (CNS) A4 micron. Each bundle of cellulose may be from about 1000 to about 5,000, preferably from about 200 to about 7000. For further information on nominal filament diameters and glass fiber nomenclature, see Loewensteiji on pages 25 and 27, which are incorporated herein by reference. In addition to glass fibers, coated fiber bundles 6 can further include fibers 20 formed from other fiberizable natural or man-made materials such as non-glass inorganic materials, 'natural materials, organic polymeric materials, and combinations thereof. Herein, “t can be fiberized” means a material that can form a general continuous monofilament, fiber, bundle or yarn. Suitable non-glass inorganic fibers include silicon carbide, carbon, graphite, Fuming andalusite, alumina And ceramic ceramic fibers formed from piezoelectric ceramic magnetic materials. Non-limiting examples of suitable animal and plant-derived natural fibers include cotton, cellulose, natural rubber, linen, kenaf, hemp, sisal, and wool. Suitable artificial fibers Including polyamines (such as nylon and aramide), thermoplastic polyesters (such as polyethylene terephthalate and polybutylene terephthalate), acrylic acid (such as polyacrylonitrile), Polyolefin, Polyurethane and Acetyl Polymers (such as Polyvinyl Alcohol) "Non-Glass Fibers" I believe that the present invention and the method of making and processing this fiber are detailed in Polymer Science and Technology Encyclopedia, Section 6 Volumes' (1967) 'pp. 505-712' and incorporated herein by reference. It is important to understand that blends of the above materials, or polymers thereof, and fiber compositions formed from any of these materials can be used in the present invention if desired. Invention will now discuss On glass fiber bundles, those skilled in the art will understand that the bundle 16 may also contain one or more of the above non-glass fibers. See Figures 2 and 3, in a preferred embodiment, the fiber of bundle [6] is coated to -13- (210X297mm) ^ ~~ ----. Ϊ́ 衣 （Order I (please read the note on the back before filling this page) 4364 22 A7

----- II V. Description of the invention (11) The coating composition layer 22 on the surface of a small part of the fibers 18 is coated to protect the surface of the fibers from friction during processing and to suppress the breakage of the fibers. The preferred coating composition is applied to the entire outer surface or periphery of each fiber 18 of the bundle 16. The coating composition can be used as a sizing agent for fibers (preferably), as a secondary coating on the sizing and / or tertiary or overcoat (if required). &quot; Sizing, &quot; means a coating composition that is applied to the fibers immediately after the fibers are formed. In another specific example, &quot; gluing &quot; also indicates that the coating composition applied to the fiber after removing the conventional main coating composition by heat, water, or chemical treatment &quot; the cloth is called an oiling sizing agent &quot; ), That is, the agent is coated on the exposed glass fiber in a fabric state. &quot; Secondary coating &quot; refers to a second coating to one or more coating compositions after the sizing composition has been applied and preferably at least partially dried. The coating composition includes one or more polymeric materials such as thermosetting materials or thermoplastic materials, which are compatible with the polymeric matrix material 12 of the laminate 10, that is, the ingredients of the coating composition can promote the wetting and penetration of the matrix material into the fiber bundles. And provide appropriate physical properties in the composite. Preferably, a polymeric material forms a continuous film when applied to the surface of the fiber i 8. The polymeric material may be water-soluble, emulsifiable, dispersible and / or curable. Printed by I-I-I ^^ 1-n -I. ^ 次 ^^ 1 ^^ 1 1- III f Please read the notes on the back before filling out this page) Better specific For example, the coating composition includes one or more polymeric film-forming materials that are compatible with thermosetting matrix materials such as those used to form printed circuit boards, such as FR-4 epoxy resins, which are multifunctional epoxy resins. Moreover, in a specific embodiment of the present invention, it is a difunctional brominated epoxy resin and polyfluorene. See 1 Electricity_Materials Manual, ASM International Corporation (1989) pages 534-537, which is incorporated herein by reference. In this article, "Compatible with thermosetting matrix materials ·" means that the composition of the coating composition promotes the wetting of the fiber bundle by the matrix material -14-This paper size is applicable to the Chinese National Standard (CNS) M specification (Xinxin 7g Love) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4364 22 A7 ___B7 V. Description of the invention (12) ^ and wet through, and provide suitable physical properties in the composite, which is chemically compatible with the thermoset matrix material and resistant to Hydrolysis. The index of the polymer matrix material penetrating into the hot sheet is called &quot; penetration &quot;. The polymer matrix material flows through the glass fiber block to obtain the entire surface of each glass fiber. "Drenched". Useful polymeric film-forming materials include thermoplastic polymeric materials such as thermoplastic polyesters, ethylene polymers, polyalkylenes, polyamides (such as aliphatic polyamides or aromatic polyamides such as arylamine), thermoplastic polyurea Alkanes, acrylic polymers, and mixtures thereof are compatible with thermosetting matrix materials. Preferred thermoplastic polymers include DESMOPHEN 2000 and DESMOPHEN 2001KS (both from Bayer, Pittsburgh, PA) and rD-847a polyester resin (from Borden Chemical Company, Columbus, Ohio) ^ Polyamide available Contains VERSAMID products (purchased from General Abrasive Chemical Industry). Available thermoplastic polyurethanes include WITCOBOND® W-290H (purchased from Witco Chemical Company, Chicago, Illinois) and RUCOTHANE® 2011L polyurethane latex (purchased from Hick, New York) Murano Ruco Polymers). Useful thermosetting polymeric materials include thermosetting polyesters, epoxy materials, ethyl acetate, phosphors, amine-based plastics, thermosetting polyurethanes, and mixtures thereof, which are compatible with thermosetting matrix materials. Suitable thermosetting polyesters may include STYPOL polyacetate (commercially available at the Cock Compounds and Polymers Corporation of Port of Washington, Wisconsin) and NEOXIL polyester (commercially available from DSM B.V., Como, Italy). _ Useful epoxy materials contain at least one epoxy group or ethylene oxide group such as a polyglycidyl ether of a polyhydric alcohol or a thiol in the molecule. Applicable epoxy polymer 15- This paper uses China National Standards (Εϊίί ^^-210χ297 & '· 5 (Please read the precautions on the back before filling this page) Binding of the Ministry of Economic Affairs Central Bureau of Standards and Staff Consumption Cooperation Yin poly 4 3 64 2 2 A7 B7 V. Description of the invention (13) The material contains EPON® 826 and EPON® 880 epoxy resin, which is the epoxy functional group of biphenol A purchased from the Shell Chemical Company of Heston, Texas Polyglycidyl ether. However, the preferred coating composition is substantially free of epoxy material, that is, it comprises less than about 5% by weight of epoxy material and more preferably less than about 2% by weight. / Preferably, this coating composition Includes one or more polyesters (preferably DESMOPHEN 2000 and RD-847A) and one or more additional groups selected from the group consisting of vinylpyrrolidone polymer (preferred), ethyl alcohol polymer and / or starch Film-forming polymer. A preferred acetamylpyrrolidone polymer useful in the present invention includes polyvinylpyrrolidone such as PVP K-1 5, PVP K-30, PVP K-60, and PVP K-90 (all commercially available from ISP Chemical Company, Wiener, New Jersey). Available starches include mashed potatoes, corn , Wheat, snail corn, sago, rice, coarse millet, and mixtures thereof, such as K〇u〇tex 1250 (mainly low viscosity, low amylose potato starch etherified starch, (A VEBE from the Netherlands). The amount of additional polymer is preferably less than about 0% by weight, and more preferably from about 0.1 to about 5% by weight. The preferred coating composition is substantially free of starch ', ie Contains less than about 5 wt.% Starch and is preferably free of starch, which is often incompatible with matrix materials. In another preferred embodiment of the printed circuit board laminate, the polymeric material of the coating composition includes RD-847A. Mixture of polyester resin, PVP κ-30 polyvinylpyrrolidone, DESMOPHEN 2000 polyacetate and VERSAMID polyamide. This coating composition may include a mixture of one or more thermosetting polymer materials and / or multiple thermoplastic polymer materials. In general, the 'polymerized material' may constitute from about i to about 99% by weight, preferably from about 1 to about 50% by weight, and more preferably from about 1 to about 25% by weight of the total solids weight of the coating composition. -16-Paper Zhang scale is applicable to China National Standard (CNS) A4 specification (210X297 mm) -------- ^ ------ 1T ------- \ tPlease read the notes on the back before filling this page) 4 3 6--A7 _________B7 V. Description of the invention (14) In addition to or in place of the above polymer materials The coating composition preferably includes one or more coupling agents such as an organic second firing coupling agent, a transition metal coupling agent 'titanate coupling agent', an aluminum coupling agent, an amine group-containing Werner coupling agent, and a mixture thereof. These coupling agents are generally Has two functionalities. Each metal or silicon atom is attached to one or more groups that can react or compatibilize with the fiber surface and / or coating composition ingredients. "Compatible" in this context means that the base is chemically attracted (but not bonded) to the fiber surface and / or components of the coating composition, for example by virtue of polarity, wetting or solvating power. Examples of hydrolyzable groups include: 〇Η 0 r3, «, II II | -OR, -OCR, -N--C-R2 · -〇-N = CR '-〇-N = C ~~ R5, and monohydroxyl And / or a cyclic c2-3 group of a 1,2- or 1,3-diol, wherein Ri is a C3 alkyl group: R2 is a 14 or 01.4 alkyl group; R3 and R / are independently selected from η, 匚 b A cold fe group or a C 6 -8 aryl group 'and R 5 are a C 4 · 7 xanxyl group. Examples of suitable compatibilization or functional groups include epoxy, glycidyloxy, fluorenyl, cyano, methyl, propyl, alkyl, urethane, halo, isocyanate, ureido, imidazole, vinyl , Acrylic, methacrylic, amine or polyamines &gt; Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs nn ^ i ene--m I---l II ant &quot; TSJ (please first w Read the notes on the reverse side and fill in this page again) Functional organosilane coupling agents are preferably used in the present invention. Examples of usable functional organosilane coupling agents include r-aminopropyltrialkoxy crushing, r-isocyanatopropyltriethoxysilane, acetamyltrialkoxysilane, glycidyloxypropyltriol Sulfuryl succinate and uryl propyl trisalyl oxalate. The preferred functional organosilane coupling agent contains A-1 8 7 7 · Glycidyloxypropyl-17- This paper size is applicable to China National Standard (CNS) A4 standard (210X 297 mm) Central Ministry of Economic Affairs Associate Bureau Consumers' Cooperative Printing Poly 4 3 6 ^ ^ A7 _B7 _ V. Description of the Invention (15) ^ Trimethoxysilane, A-174 r -Methylpropionyloxypropyltrimethylsilane, A- 1100 7-Aminopropyltriethoxy Coupling Couplings, A-1108 Aminosilane Couplings and A-1 160 r-ureidopropyltriethoxysilanes (each from Tally City, New York) 0 Si professional industry company). The organosilane coupling agent can be at least partially hydrolyzed with water before being applied to the fibers, preferably in a stoichiometric ratio of about 1: 1 or, if necessary, in an unhydrolyzed state. Suitable transition metal coupling agents include &apos;, zirconium, metallurgy, and complex coupling agents. Suitable titanate coupling agents and germanate coupling agents were purchased from Kenrich Petrochemical Company. A suitable chromium compound was purchased from E. I. DuPont of Dalla Wilmington. A Werner-type coupling agent containing an amine group is a compound compound in which a trivalent nuclear atom such as chromium is coordinated with an organic acid having an acid function. Other metal chelating agents and coordination-type coupling agents known in the art can also be used herein. The coupling dose may be from about 1 to about 99% by weight, and preferably from about 1 to about 10% by weight, based on the total solids of the coating composition. Referring to FIG. 3, in a preferred embodiment of the present invention, the coating composition includes one or more solid particles 24 placed between or adhered to the outer surface of the fibers 18 ^ If the adjacent glass fibers 2 are placed in the bundle 16 6, 2 8 'then these solid particles 2 4 can provide interstitial space 3 0' which is usually equivalent to the average particle size of solid particles 2 4 3 2 ^ "solid 11" means invisible flow under appropriate stress A substance with a finite volume that resists the forces that deform it and maintains a finite size and shape under ordinary conditions. See Webster's New International Dictionary of English, 3rd Edition (1971), p. 2169. Moreover, the "solid" used in this article includes two kinds of β solid particles, crystalline and non-crystalline materials. 2 4 can have an average particle diameter of 3 2 (equivalent to a spherical diameter) from about -18. CNS) Α4 specification (210X297), ~~ ---- HI. In. N--ml (Please read the precautions on the back before filling this page) Central Consumers Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, Yin Chang 4-3 64 A7 _ _____B7 V. Description of the invention (16T-0.001 to greater than 5 microns', preferably from about 〖to about 10,000 microns, more preferably from about 丨 to about 25 microns. Better, the smallest average of the solid particles 24 The particle size is usually equivalent to the average nominal diameter of the glass fiber. The configuration or shape of the solid particles 24 is usually spherical (such as beads, microbeads, or solid hollow spheres), cubes, duckbills, or needles (mid-length) (Fibrous or fibrous). For more information on suitable particle characteristics, see Lattice of Katz et al. (Editor) _Material & Plastic Hand_11 (1987), pages 9-10, incorporated herein by reference. Solid particles are preferred in general Glass fiber processing conditions such as temperatures up to about 25 and more preferably up to about 400 ° C It does not shatter 'deform or dissolve to a particle size of less than 5 microns' and preferably not less than 3 microns. Glass fibers are in contact with adjacent glass fibers and / or are in contact with glass fibers during formation and subsequent processing such as weaving or knotting Friction and wear of other solid objects or materials in contact with the rough surface. "Friction and wear" in this context means to scrape or cut off the glass by frictional contact with the edges or the whole of particles or materials that are hard enough to cause damage to the glass fibers. Debris or broken glass fibers on the fiber surface. See K. Ludema 'Friction, abrasion, lubrication nqqw 坌 i page 9Q, which is hereby incorporated by reference. Friction and wear of glass fiber bundles causes bundle breakage during processing and products Such as surface defects in woven fabrics and composites, which increase waste and manufacturing costs. In order to minimize friction grinding, solid particles have a hardness value that does not exceed, that is, less than or equal to the hardness value of glass fiber. The hardness of solid particles and glass fiber The value can be determined by any conventional hardness measurement method, such as Vickers or Brinell hardness', but it is better to follow the original Mohs1 hardness standard (which indicates the material Surface relative scratch resistance). Mohs of glass fiber, hardness value is usually from about 4.5 to about -19- This paper size applies to Chinese National Standard (CNS) A4 specification (210X29? Mm} II--mmn ^ i ^^^ 1--I 士-I— d. ^^ 1 (Please read the note # 'on the back before filling in this page) 4 3 6 4 2 2 A7 B7 V. Description of the invention (17) 6.5, and Good about 6. R. We as t (eds.) Yearbook of Chemistry and Physics, CRC Press (1 975) at F-22, which is incorporated herein by reference. The Mohs' hardness value of the solid particles is preferably from about 0.5 to about 6. Mohs1 hardness values of several non-limiting example solid particles suitable for use in the present invention are shown in Table A below.

Table A

Solid particle material Mohs1 hardness (original standard) boron nitride approximately 21 graphite approximately 0.5-12 molybdenum disulfide approximately I3 talc approximately 1-I.54 mica approximately 2.8-3.25 kaolin approximately 2.0-2.56 gypsum approximately 1.6-27 calcite (calcium carbonate ) About 38 calcium fluoride about 49 zinc oxide about 4.510 aluminum about 2.511 copper about 2.5-312 iron about 4-513 gold about 2_5-3 丨 4 nickel about 515 production bar-about 4.816 about 4.317 silver about 2.5-41S central Standard Bureau of Shellfish Consumer Cooperation Du printed I »KH ^ (Please read the notes on the back before filling this page) -20- This paper size applies to China National Standard (CNS) A4 size (210X297 mm) A7 4 3 6 ^ 1 2 2 B7 V. Description of the invention (18) v-1 Hi.-1 f / lt (Please read the notes on the back before filling this page) 1 K. Ludema friction, wear, lubrication U 996) Page 27, which is incorporated herein by reference. 2 Edited by R. WeasU) Handbook of Chemistry and Physics, CRC Press Π975) Page F-22. 3 R. Lewis, Sr., Hawley's Condensed Chemistry Dictionary (12th edition, 1993), p. 793, which is incorporated herein by reference. 4 R. Lewis, Sr., Hawley's Condensed Chemistry Dictionary (12th edition, 1993), page 1113, which is incorporated herein by reference. 5 R. Lewis, Sr., Hawley ’s Condensed Chemistry Dictionary (12th edition, 1993), p. 784, which is incorporated herein by reference. 6 Handbook of Chemistry and Physics, page F-22_. 7 Handbook of Chemistry and Physics, page F-22. 8 麾 檫, abrasion, lubrication, page 27. 9 麾 檫, wear, lubrication, p. 27. 10 Friction 'Wear, lubrication, p. 27. 11 Friction, Wear, Lubrication, p. 27. 12 Handbook of Chemistry and Physics, page F-22. 13 Handbook of Chemistry and Physics, page F-22 »14 Handbook of Chemistry and Physics, page F-22. Secoro Central Bureau of Standards Employee Cooperative Copies 15 Handbook of Chemistry and Physics, page F-22. 16 Handbook of Chemistry and Physics, page F-22. 17 Handbook of Chemistry and Physics, page F-22. 18 Handbook of Chemistry and Physics, page F-22. -21-This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 43 642 2 A7 ____________ B7 V. Description of the invention (19) As mentioned above, Mohs, The hardness criterion is related to the scratch resistance of the material. The invention therefore relates to particles whose surface hardness is different from the internal hardness below the surface of the particles. In detail, the surface of the particles can be modified in any way known in the art, including (but not limited to) coating, winding or covering the particles or using the technology known in the art to chemically modify the surface characteristics, so the surface hardness of the particles is not cut into glass. The hardness of the fiber is not greater than the hardness of the glass fiber. For example (but not limiting the present invention), inorganic particles such as silicon carbide and nitride can be provided with sand oxide, carbon «or micro-order". In addition, the material-based side-bond cleavage coupling agent can react with the surface of many oxide particles to Provides a &quot; softer &quot; surface. Generally, the solid particles 24 used in the present invention may be formed of an inorganic material, an organic material, or a mixture thereof. Preferably, the solid particles 24 are made of an inorganic material selected from the family of ceramic materials and metal materials. Formation. Suitable ceramic magnetic materials include metal nitrides, metal oxides, metal carbides, metal sulfides, metal borides, metal silicates, metal carbonates, and mixtures thereof. Non-limiting suitable metal nitrides are boron nitride, A non-limiting example of a metal oxide that can be used as the preferred inorganic material β for forming solid particles of the present invention is zinc oxide. Suitable metal sulfides include fine disulfide, disulfide, disulfide μ and m available gold core ❹Cut acid chain and magnesium silicate such as vermiculite. Suitable metal materials include graphite, molybdenum, platinum, palladium, nickel, aluminum, copper, gold, iron, silver and mixtures thereof. The solid particles 24 are also solid lubricants. In this context, "solid lubricants" means that the inorganic solid particles 24 have the ability to cut them to slide easily on each other and therefore between the glass fibers and adjacent surfaces (at least move them-) Anti-Friction-22- National Sample Rate (CNS) A4 * t # · (210X297) for paper size 14 1 ^ 1 ^^^ 1 ^^^^ 1 m ^^^ 1 I Multi Λ〆 TJ * 1 (Please read the precautions on the back before filling this page) Λ7 436422 V. The characteristic crystalline nature of the thin flat sheet with smooth effect of the description of the invention (20). (See R, Lewis, Sr., Hawlcy_si Zinc Code f 12th edition '1993), page 712, which is incorporated herein by reference) ^ Friction is the resistance to solid sliding against each other. F Clauss UijajfJi] and self-lubricating solid Π972) 篦 1 alfalfa, which is incorporated herein by reference. In a preferred embodiment, the 'solid lubricant particles have a layered structure. Particles with a layered or hexagonal crystal structure are composed of sheets or plates with atoms arranged in a hexagonal pattern. 'Have strong bonding in the sheet and weak Van der Waals bonding between the sheets' are provided between the sheets. Low shear strength. Friction, Wear, Lubrication, page 125, mM lubricants and self-slip agents 19-22, 42-54, 75-77, 80-81 '82, 90- 102, 113-120, and 128 pages and W .

Campbell &quot; Solid Lubricants', Interfacial Lubrication: The World's Leaders, ASME Lubrication Research Committee (1969), pp. 202-203, which is incorporated herein by reference. Inorganic solid particles with a layered fu] lerene (buckyball) structure can also be used in the present invention. Non-limiting examples of suitable inorganic solid lubricant particles with a layered structure include boron nitride, graphite, metal dichalcogenide, mica , Talc, gypsum, kaolin, calcite, cadmium iodide, silver sulfide and mixtures thereof. Preferred inorganic solid lubricant particles include boron nitride 'graphite, metal dichalcogenides, and mixtures thereof. Suitable metal dichalcogenides include molybdenum disulfide, molybdenum diselenide 'disulfide buttons, diselenide buttons, tungsten disulfide, tungsten diselenide, and their mixed use in hexagonal crystalline structures in aqueous sizing compositions The boron nitride particles are the best. Nitrided m zinc and montmorillonite particles are also used in polymeric matrix materials such as ^^ 1 I-1 ^ 1 I m. f Please read the precautions on the back before you read isf.

Printed by the Central Bureau of Standards, Ministry of Economic Affairs, 4 Consumer Cooperatives A7 B7 V. Description of Invention (21) Nylon 6.6 compound provides good whiteness. Non-limiting examples of boron nitride particles suitable for the present invention are pOarTherm® 100 series (PT120, PT140, PT160 and PT180), 300 series (PT350) and 600 series (PT620, PT630, PT640 and PT670) nitriding Boron powder particles purchased from Advanced Ceramics Corporation of Lakewood, Ohio. &quot; Polar Therm® thermally conductive filler "" Technical Bulletin of Advanced Ceramics Corporation of Lake Wood, Ohio "and incorporated herein by reference. The thermal conductivity of these particles at 25 X: approximately per foot. K 250 to 300 watts The dielectric constant is about 3.9 and the volume resistance is about 10 15 ohm-mm. The average particle size of 100 series powder is from about 5 to about 14 microns, the average particle size of 300 series is from about 100 to about 150 microns and the average particle size of 600 series The diameter is from about 16 to greater than about 200 microns. The solid lubricant particles 24 may be present as a dispersion'suspension or emulsion in water. Other solvents such as mineral oil or alcohol (preferably less than about 5% by weight) may be included In the sizing composition, a non-limiting example of a preferred dispersion of about 25% by weight of boron nitride particles in water is ORPAC BORON NITRIDE RELEASECOAT-CONC from ZYP Coatings Industries, Oakbridge, Tennessee. &Quot; ORPAC BORON NITRIDE RELEASECOAT-CONC is a technical bulletin for the ZYP coating industry, which is incorporated herein by reference. According to the supplier, the average particle size of the boron nitride particles in this product is less than about 3 microns. This dispersion has about 1% by weight of magnesium - Silicate, as shown by the supplier, binds boron nitride particles to a dispersion-coated substrate. Other available products from the ZYP coating industry include BORON NITRIDE LUBRICOAT® paint, BRAZE STOP, and WELD RELEASE Product. Although not preferred, this coating composition may contain hydratable or hydrated inorganic solids-24-

Standards for Quick Use of Ten National Standards (CNS) A4 (210 X297 mm I 1 ^ ^ rn n ^ i I In I.ιί: κν 1 ^ 1 • yi (Please read the precautions on the back before filling the chicken page ) Printed by the Consumer Cooperative of the Central Bureau of Samples of the Ministry of Economic Affairs 43 64 2 2 at B7 —.. 丨 丨 -V. Invention Description (22) •-Lubricant material. This hydratable inorganic solid lubricant material is non-limiting An example is a clay mineral phyllosilicate containing mica (such as muscovite), talc, montmorillonite 'kaolin and gypsum (CaS〇4 · 2H2〇). In this paper "quotable" means solid inorganic lubricant particles and water Molecules react to form hydrates or hydrated water or crystal water. &Quot; Hydrate is produced by the reaction of water with substances in which the Η-〇Η bond is not split. (See R. Lewis, Sr., Hawley's Condensation Service , Fengshen Dian (2nd edition, 1993) 'pages 609-610 and T. Perros. J Dology (1967) pages 186-187, which are incorporated herein by reference. In the chemical formula of hydrates, water molecules The addition is represented by the center point, such as 3MgO · 4Si02 · H2〇 ('moon stone), 81203 * 25 丨 2 * 2 ^ 12〇 (鬲Soil). Hydrate contains coordination water 'which coordinates with cations in the hydrated material and cannot be removed without damaging the structure, and / or contains structured water which occupies the crystal lattice in the structure to add electrostatic energy without hit Chaotic charge balance. R. Evans, Introduction to Crystallization, page 276, which is incorporated herein by reference. Preferably, the coating composition is substantially free of hydratable inorganic solid lubricant particles or abrasive silica particles or calcium carbonate, That is, it includes less than about 20% by weight of total solids, hydratable inorganic lubricant particles, abrasive silica particles, or calcium carbonate, more preferably less than about 5% by weight, and most preferably less than 0.0001% by weight. -In the specific example, the 'solid particles 24 can be formed of organic polymer materials selected from the group consisting of thermosetting materials, thermoplastic materials, starch, and mixtures thereof. Suitable thermosetting materials include polymer brewing, ethylene vinegar, epoxy materials, and brewing. Types, amine-based plastics, thermosetting polyurethanes, and mixtures thereof, such as the following. Appropriately ,: Plastic materials include vinyl polymers, thermoplastic polymers, polyhexyl cigarettes, hydrazine &amp; plastic ice. Urine, C Acid polymer and its mixture. Preferable 25. The paper size is in accordance with the Chinese standard (yA4 specification (21〇 father 297 public ID II-.---- il! I ^^^ 1 ^^^ 1 ^ ^^ 1 ^^^ 1-^ (Please read the notes on the back before filling in this page) A7 B7 436422 V. Description of the invention (23) The organic solid particles are microbeads or hollow spheres. n I nn I 1 n 1 I — ^ I — Ding U3, T f, please read the precautions on the back before filling out this page} In addition-in a specific example, the solid particles 24 are thermally conductive, that is, have thermal conductivity The rate is greater than about 30 watts per meter K, such as the above-mentioned boron nitride, graphite, and metal inorganic solid lubricants. The thermal conductivity of solid materials can be measured by any method known in the art, such as ASTM (M77-85's Protective Hot Plate Method (which is also incorporated herein by reference) and measured at a temperature of about 300K. In another preferred embodiment, 'inorganic The solid particles 24 are electrically insulating or have a high resistance, that is, a resistance greater than about 1,000 microohm · cm, such as a nitriding shed. If solid lubricant particles are present, the amount may be about 0.0 of the total solids amount of the coating composition. 01 to about 99% by weight 'preferably about 1 to about 80% by weight, and more preferably about 1 to about 40% by weight. The Ministry of Economic Affairs and the Central Bureau of Standards, Bureau of Work and Consumer Cooperatives, India dare this coating composition to be Including one or more organic lubricants that are chemically different from the polymeric materials described above. Although the coating composition may include up to about 60% by weight of an organic lubricant, the preferred coating composition is substantially free of organic lubricants, that is, it contains Less than about 10% by weight of an organic lubricant, and more preferably from about 1 to about 5% by weight of an organic lubricant. Examples of such organic lubricants include cationic, nonionic or anionic lubricants and mixtures thereof, such as fatty acids Amine salt Benzyl olfactory derivatives such as CATION X from Rhone Poulenc, Principe, New Jersey, acid-dissolved fatty acid amidine, fatty acids and polyethylenimine and polyethylenimine substituted by amine Condensates of imines, such as EMERY® 6717 (partially aminated polyethylenimine from Henkel, Inc., Kenkage, Ill.) _ The coating composition may contain one or more for emulsification or Emulsifiers for dispersing coating composition ingredients, such as inorganic particles. Non--26 suitable emulsifiers or surfactants. This paper size applies to China Standard (CNS) A4 (210X297 mm) A7 B7 436422 V. Description of the invention (24) I-1 ^^ 1---m »nn I n HI ^^ 1 {Please read the notes on the back before filling out this page) Ophthalmic examples include polyoxyethylene block copolymers (if purchased from PTLURONICT M F-108 Polyoxypropylene. Polyoxyethylene Copolymer, BASF Corporation, Paspani, New Jersey, Emulsified Pit Base (Speaking from IEPAL CA- 630 ethoxylated octylphenoxyethanol), polyoxyethylene octylphenyl glycol mystery, sorbitol ester of ethylene oxide Derivatives, polyoxyethylated vegetable oils (such as ALKAMULS EL-719 from Rhone-Poulenc) and nonyl-based 'surfactants (MACOL NP-6 from BASF Corporation, Parsippany, NJ) . Emulsifiers typically comprise from about 1 to about 30 weight 0/0 of the total solids of the coating composition. The coating composition may include one or more water-soluble, emulsifiable, or dispersible snail materials such as vegetable, animal soil, dish, synthetic, or petroleum ants. Preferred waxes are petroleum waxes such as MICHEM® LUBE 296 microcrystalline wax, POLYMEBCON® SPP-W microcrystalline wax, and PETROLITE 75 microcrystalline wax, which were purchased from Michelman Industries, Cincinnati, Ohio, and Petr, Tossa, Ore. 〇iite company. Usually the amount of wax is from about 1 to about 0% by weight of the total solids of the coating. Cross-linking materials such as melamine formaldehyde, and plasticizers such as phthalic acid esters, trimellitic acid esters, and adipic acid esters may also be included in the coating composition. The amount of crosslinking agent or plasticizer is from about 1 to about 5% by weight of the total solids of the coating composition. Consumers ’cooperation with the Central Bureau of Standards of the Ministry of Economic Affairs. Other additives can be included in the coating composition, such as silica, fungicides, fungicides and antifoam materials. The amount is usually less than about 5% by weight. The coating composition has an organic and / or inorganic acid or base in an amount of about 2 to about 10 pH. A non-limiting example of a suitable silicone emulsion is the LE-9300 epoxy silicone emulsion from OSi Professional Industries, Dambury, Connecticut. A suitable example of a suitable fungicide is the Biomet 27 purchased from M &amp; T Chemical Company of Rohawe, Jersey.- This paper is sized for the Chinese National Standard (CNS) A4 (2IOx297 mm) 436422 A7 B7 V. Invention Instructions (25) ♦ ^^ 1 »m ml ^^^ 1-I--. I.--I 1 (Please read the notes on the back before filling this page) 66. Suitable defoaming materials are SG materials from Danbury, Connecticut, professional materials and MAZU DF-136, purchased from b S F Company of Parsippany, New Jersey. If desired, ammonium hydroxide can be added to the coating composition for stabilization. The coating composition preferably contains water (preferably deionized water) in an amount sufficient to facilitate the application of a uniform coating on the bundle, usually in an amount of about 25 to about 99% by weight. The weight percentage of solids in the aqueous coating composition is generally from about 1 to about 75 weight percent. The coating composition is preferably substantially free of glass materials. As used herein, 'substantially free of glass material' means that the coating composition includes less than 20% by volume of a glass matrix material for forming a glass composite, preferably less than about 5% by volume and more preferably is free of glass material. Examples of glass matrix materials include black broken glass ceramic magnetic matrix materials or aluminosilicate matrix materials such as those skilled in the art. The coated fiber bundle of the invented glass fiber is coated with a main dry layer of an aqueous sizing composition including PolarTherm® 160 boron nitride powder and / or BORON NITRIDE RELEASECOAT dispersion, EPON 826 epoxy film-forming material , PVP K-30 polyvinylpyrrolidone 'A-187 epoxy-functional organosilane coupling agent, ALKAMULS EL-719 polyoxyethylated vegetable oil, IGEPAL CA-630 ethoxylated octylphenoxyethanol, KESSCO PEG 600 poly Glycol monolaurate (purchased from Stepan Company, Chicago, Ill.) And EMERY® 6717 partially aminated polyethylenimine.

In a preferred embodiment of the woven cloth, the glass fiber of the coated fiber bundle of the present invention is coated with a main dry layer of an aqueous superior composition, which composition comprises Polar Therm® 160 boron nitride powder and / or BORON NITRIDE -28- Paper size is applicable to China National Standard (CNS) A4 (210X297) & printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 4 3 6 4-22 A7 __ B7 V. Description of Invention (26)-RELEASECOAT Dispersion , RD.847A Poly§, PVP K 3〇 Polyethylenepyrrolidone, DESMOPHEN 2000 polyester, A 74 acrylic functional organosilane coupling agent and A_187 epoxy functional organosilane coupling agent ^ The coating composition of the present invention may be any Prepared by a suitable method, such as a conventional mixing method known in the art. Preferably, the ingredients are diluted with water to a desired weight percent solids and mixed together. Powdered thermally conductive inorganic solid particles can be pre-mixed with water or added to the polymeric material before mixing with other components of the coating. The coating layer can be applied to the fibers in a number of ways, such as by contacting the monofilament with a roller or ribbon coater, spraying or other methods. The coated fibers are preferably dried at room temperature or elevated temperature. The dryer removes excess moisture from the fibers and cures any curable coating composition ingredients, if any. The temperature and time of the dried glass fiber depend on variables such as the percentage of solids in the coating composition, the composition of the coating composition, and the type of glass fiber. The coating composition is present on the fibers as a dry sizing layer in an amount between about 0.01 to about 25 weight percent after drying. Fibers typically have a weight loss on combustion of less than about 0.6% by weight, and preferably less than about 0.5% by weight. /. And more preferably from about 0.01 to about 0.45 weight. /. . The burning loss of the coated fiber sample can be measured by heating the fiber for 20 minutes in a muffle furnace at 1200 ° C. The secondary coating composition can be used to coat or soak a portion of the bundle in an amount effective to coat the secondary layer on the coating composition described above, such as immersing the bundle in a spray containing the grade Alternatively, the bundle is brought into contact with the above-mentioned coater. The coated strand can be passed through the die to remove excess coating composition from the strand and / or dried as described above for a time sufficient to at least partially dry or cure the secondary coating composition. Method and device for coating a secondary coating composition on a bundle of materials -29- This paper size is applicable to the Chinese National Standard {CNS) A4 specification (210X297 mm) --------- ^ — (Please (Read the notes on the back before filling out this page)

• 1T 43 64 22 a7 B7 V. Description of the invention (27) Determined by the configuration part = It is better to dry the coating after coating the secondary coating composition in a manner known in the art. The secondary coating is different from the sizing composition, that is, it contains (1) at least one component having chemical properties different from those of the sizing composition; or (2) a content different from that of the same composition Amount of at least one ingredient. Non-limiting examples of suitable secondary coating compositions comprising polyurethane are disclosed in USP 4,762,750 and 4,762,751, which are incorporated herein by reference. In another preferred embodiment of the present invention, the glass fiber of the fiber bundle may be coated with a conventional sizing agent for a main drying layer or may include a sizing composition of any of the above-mentioned sizing components. Examples of suitable sizing compositions are described in Loewenstein, pages 237-291 (3rd edition, 1993) and USP 4,390,647 and 4,795,678, each of which is incorporated herein by reference. The secondary or primary layer of the present invention is a secondary coating which is applied to at least part and preferably the entire outer surface of the entire primary layer. The secondary coating composition may include one or more of the solid particles described above and / or as described in Tables C, D and E below. (Please read the precautions on the back before filling out this page) Printed AC Inorganic Solid Materials Thermal Conductivity (W / mK at 300K) Resistance (microohm-cm) Mohs' hardness (original) Standard) Boron Nitride about 20019 1.7 X 10 丨 920 about 221 Phosphonium Boron about 35022 _ about 9.523 Aluminium Phosphate about 13024 _ Aluminium Nitride about 20025 greater than 101926 about 927 Gallium Nitride about 17028 _-Gallium Phosphate about 10029- 30-This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297mm). The work of the Central Samples Bureau of the Ministry of Economic Affairs and Consumer Cooperation · Du printed 436422 at B7 V. Description of the invention (28) Silicon carbide approximately 27030 4x 105 to 1 X 1〇631 greater than 932 nitrides about 3033 1019 to 1020 34 about 935 beryllium oxide about 24036 about 937 9 G. Slack &quot; non-metallic crystal with high thermal conductivity, |, j phys Chem. Solids. (1973), Volume 34, page 322, which is incorporated herein by reference. 20 A. Weimer (eds), carbides; synthesis and processing of nitride and boride materials, (1997) p. 654. 21 Friction, abrasion, lubrication, p. 27. G. Slack Non-Metallic Crystals with High Thermal Conductivity &quot;, j. Phys. Chem. Solids. (1973) 'Vol. 34, p. 325, which is incorporated herein by reference. 23 R. Lewis, Sr., Hgwlev, Condensed Chemicals, Yi Lian, 12th edition, 1993), p. 164, which is incorporated herein by reference. 24 G. Slack &quot; Nonmetallic Crystals with High Thermal Conductivity &quot;, j. Phys. Chem. Solids. (1973), Vol. 34, p. 333, which is incorporated herein by reference. 25 G. Slack &quot; with High Thermal Conductivity Nonmetallic Crystals I ,, j phys chem. Solids. (1973) 'Vol. 34, p. 329, which is incorporated herein by reference * 26 A. Weimer (eds.), Carbide; Synthesis of nitride and boride materials Machining, (1997), p. 654. 27 Friction, abrasion, lubrication, p. 27. 2 8 G_ Slack Non-metallic crystal with high thermal conductivity &quot;, j. Phys. Chem,

Solids. (1973), Vol. 34, p. 333, which is incorporated herein by reference. 29 G. Slack &quot; Nonmetallic Crystals with High Thermal Conductivity &quot;, j. Phys. Chem. Solids. (19), vol. 34, p. 321, which is incorporated herein by reference. 3 ° Microelectronic Packaging Manual, page 36, which is incorporated herein by reference. -31-This paper size is applicable to Chinese National Standard (CNS) A4 specification (2 丨 OX297 public love) .--------- Installation-{Please read the back: Note &quot; item before filling this page ) Order 2 2 4 6 3 4

A V. Description of the Invention (29), 31 A. Weimer (eds.), Carbide; Synthesis and Processing of Argonide and Sideline Material, (1997) p.653. 32 Friction, Wear, Lubrication, p. 27. 33 Microelectronic Packaging Manual, page 36, which is incorporated herein by reference. 34 A. Weimer (eds.), Carbides; synthesis and processing of halide and boride materials, (1997) p. 653. 35 Friction, Wear, Lubrication, p. 27. 36 Microelectronic Packaging Manual, page 905, which is incorporated herein by reference. 31 R. Lewis, Sr., Hawley ’s Condensed Chemical Dictionary (12th edition, 1993), p. 141, which is incorporated herein by reference. (Please read the precautions on the back before filling out this page.) Equipment · Centre of Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs, Form D Thermal conductivity of inorganic solid materials (W / m K at 300K) Resistance (microohm-cm) Mohs' hardness (Original standard) Zinc oxide about 26 about 4_538 sulfuration about 2539 2 · 7χ 105 to 1.2x 101240 about 3.5-441 diamond about 230042 2.7χ10843 1〇44 silicon about 8445 about 10,046 about 747 graphite up to 200048 10049 about 0.5-150 molybdenum About 13851 about 5.252 platinum. About 6953 about 10.654 about 4.355 about 7056 about 10.857 about 4.858 tungsten about 20059-about 5.560 nickel about 9261 about 6_862 about 563 about 20564 about 4.365 about 2.566 chromium about 6667 about 206S about 9.069 -32- The paper size of the edition is applicable to the Chinese National Standard (CNS) A4 (210X297 mm). The Central Government Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumption Cooperation · Du printed 4 3 64 2 2 at _________B7 V. Description of the invention (30) 38 Friction and wear , Lubrication, p. 27. "Jian-Xue Physics # _, CRC Press (1975) pp. 12-54. 40 Supervision-Science. Physics JL, crc Press (71st Edition, 1990) pp. 12_63 'It is incorporated herein by reference. 41 CRC Publication Du (71st Edition, 1990), pages 4_158 'and incorporated herein by reference. 42-disc electronic packaging manual, page 36. 43 Jian-Feng Physical Handbook-, CRC Press (71st Edition, (1990), pages 12-63, which are incorporated herein by reference. 44 Handbook of Chemical Physics, F-22, 45 Sheep Book for Microelectronics Packaging, p. 174, 46 Also learn physics, _, F-166 , Which is incorporated herein by reference. 47 Scrub, Wear, Lubrication, p. 27. G. Slack &quot; Non-metallic Crystals with High Thermal Conductivity ", j Phys chem. Solids (1973) 'Vol. 34 No. 322 Page, which is incorporated herein by reference. W-Callister Materials_Introduction to Materials Science and Engineering f 2nd edition, 1991), p. 637, which is incorporated herein by reference. 50 Chemical Physics Rich Sleeve · Page F-22. 5 E 1 Annual of Electronic Packaging, p. 174. 52 U) Subpackaging Manual, page 37. 53 I · 1_ Yu Packing Manual, No. 174th. 54 Select Jt_Packaging Manual, page 37. 55 iL Handbook of Physics, page F-22. 56 Pneutron Packing Manual, p. 37. -33 * The paper size is suitable for financial and family care (CNS) A4 (2tGX297) ^-m ^^^ 1 IK ^^^ 1 an t '*, fyc ^^^^ 1 ma ^^ i— « 3. Words (please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs, Form E Thermal Conductivity of Inorganic Solid Materials (W / m KK at 300K) Resistance (microohm-cm) Mohs1 Hardness (original standard) Copper about 398 ™ about 1.771 about 2.5-372 gold about 29973 about 2.274 about 2.5-375 iron about 74.576 about 977 about 4-578 silver about 41879 about I.680 about 2.5-481 43 64 2 2 A7 B7 V. Description of the Invention (31) ^ 57 Microelectronic Packaging Manual, page 37. 58 Chemical Physics Manual, page F-22. 59 Microelectronic Packaging Manual, page 37. 60 Microelectronic Packaging Manual, page 37. 65 Microelectronic Packaging Handbook, page 174. 62 Microelectronic Packaging Handbook, page 37. 63 Chemical Physics Handbook, page F-22. 64 Microelectronic Packaging Handbook, page 174. 65 Microelectronic Packaging Handbook 'page 37. 66 Friction, Wear and Lubrication, page 27. 67 Microelectronics Packaging Manual, page 37. 6S Microelectronics Packaging Manual, page 37. 69 Chemicals Manual, page F-22. 70 Microelectronic Packaging Manual, page 174. 71 Microelectronic Packaging Manual, page 37. 72 Chemical Physics Manual, page F-22. Microelectronic Packaging Manual, page 174. -34 -This paper size applies Chinese national standard (CNS 丨 A4 specification (210 × 297 mm) binding \ (Please read the precautions on the back before filling in this page) 4 3 64 2 2 a? B7 V. Description of the invention (32) to- 74 Microelectronic Packaging Handbook, page 37. "Handbook of Chemical Physics" on page F-22. 76 Microelectronic Packaging Handbook, page 174. 77 ~ Huaqian Lihu volume, CRC Press (075), page D_171, which And for reference in this article, 78 Handbook of Chemical Physics, page F-22. 79 Handbook of Microelectronic Packaging, page 174. 80 Years of Microelectronic Packaging, page 37. 81 Handbook of Chemical Physics, page F-22. Two Rhenium sulfide and magnesium oxide can be used for other inorganic solid particles of the secondary or third coating of the present invention. Those skilled in the art will understand that the present invention can use a mixture of any of the foregoing inorganic solid particles. The inorganic particles in the secondary coating composition account for About 1 to about 99% by weight of total solids and preferably about 20 to 90% by weight. The solids percentage of the aqueous secondary coating composition is usually from about 5 to about 75% by weight. In another embodiment, a third layer may be coated on the surface of the secondary coating and preferably on the entire surface. The third coating composition, that is, such a fiber bundle, has a primary sizing layer, a secondary coating composition secondary layer, and a third coating outer layer. The third coating is different from the sizing composition and the secondary coating composition, that is, the third coating composition (1) contains at least one component that is chemically different from the components of the sizing and the secondary coating composition; or ( 2) Contains at least one ingredient in an amount different from the same ingredient amount contained in the sizing or the secondary coating composition. In this specific example, the secondary coating composition includes one or more of the above-mentioned polymeric materials -35- This paper size is applicable to China National Standards (CNS) A4 specifications (2 丨 0X 297 mm) (Please read the precautions on the back before (Fill in this page)

11T M Printed by the Central Standards Bureau of the Ministry of Economic Affairs, the Consumer Cooperatives of the Ministry of Economic Affairs, and printed by the Ministry of Economic Affairs of the Central Bureau of Standards, and printed by the Shellfish Consumer Cooperatives. 436422 at _______B7 V. Description of the Invention (33) Includes powdered thermally conductive inorganic particles, such as PolarTherm® boron nitride as described above. Preferably, the powdered coating is applied by passing the bundle coated with the liquid secondary coating composition through a fluidized bed or a spray device to adhere the powder particles to the adhesive secondary coating composition. Alternatively, the bundles may be assembled into a fabric 114 before the third coating layer 140 is applied, as shown in FIG. The weight percentage of the powdered thermally conductive inorganic solid particles adhered to the coated bundle may be about 0 to about 75% by weight based on the total weight of the dry bundle. The third coating material may also contain one or more of the above-mentioned polymeric materials, such as propionic acid polymers, epoxides, conventional stabilizers and other modifiers known in the coatings field, preferably in the form of a dry powder. The fiber bundles can be processed into woven fabrics, preferably knitted or woven. The weaving fabric ί 4 is used as a reinforced polymer matrix material 12 to form a composite or laminate 10 ′. As shown in FIG. 1, it is preferably used for printed circuit boards. The warp harness of the fabric can be used before weaving. Twisting for non-twisting or any conventional twisting technique known in the art, such as the use of a twisting frame to impart twist to the bundle of about 0.5 to about 3 twists per pair. "The reinforcing fabric 14 may contain About 100 warp harnesses, and preferably about 3 to about 25 weft yarns per millimeter of weft harness (about 1 to about 15 weft yarns per inch). The weave structure may be regular plain weave, but any other weave type known in the art may be used, such as twill weave or satin weave. The fabric 14 is preferably woven into a type suitable for printed circuit board laminates, as described in "Global Fabrics", which is a technical bulletin from Clark-Schwebel Industries, Anderson, North Carolina (1995) and is incorporated herein. For reference. The preferred fabric type using E225 E-broken glass fiber is Style 2116, which is -36- per 5 square centimeters. This paper rule applies to Chinese national standard {CNS} A4 (210X297 mm 1 n 1 ^ 1 I ί an I-— ^ J (Please read and read the notes on the back before filling out this page) Printed by the Shell Cooperative Consumer Cooperative of the Central Bureau of Procurement, Ministry of Economic Affairs 4 3 6 4 2 P A7 B7 V. Description of the Invention (34) Plot has 118 warp yarns and 114 weft yarns (60 warp yarns and 58 weft yarns per square pair); use 7 22 ιχ〇 (Ε225 1/0) warp and weft yarns Thread; has a nominal fabric thickness of 0094 mm (0.037 忖); and a fabric weight of 103.8 g / m2 (3.06 ounces per square yard) ^ The preferred fabric type using G75 E-glass weave is Style 7628, which is 5 square meters Cm area with 8 7 warp yarns and 61 weft yarns (4 4 warp yarns and 31 weft yarns per square inch ); Use 968 lxO (G75 1 /】 0) warp and weft yarns; have a nominal fabric thickness of 0.173 mm (0.0068 pairs); and a fabric weight of 203.4 g / m2 (6.00 oz per square yard). Use 0450 E -The preferred fabric type of glass fiber is Style 1080 'with 5 warp yarns and 9 3 weft yarns per 60 cm2 area (60 warp yarns and 4 7 weft yarns per square pair Thread); use 5 11 lx0 (D450 1/0) warp and weft yarns; have a nominal fabric thickness of 0.053 mm (0.0021 inches); and a fabric weight of 46.8 g / m (1.38 pans per square yard). These and Other available fabric types and specifications can be found in IPC-EG-140 &quot; "Specification of printed fabrics from E 'glass for printing plates", "Gazette of Interconnection and Packaging Electronic Circuit Association (June 1997)" It is incorporated herein by reference. Suitable woven reinforcement fabrics 1 4 can be formed using any conventional looms known in the art, such as shuttle looms or rapier looms, but air jet wovens are preferred Machine. The preferred air jet loom was purchased from EJ

Tsudakoma Model 103 and Sulzer Ruti Models L-5000 or L-5100 (speaking from Sulzer Brothers, Lurich, Switzerland). Product Bulletin for Sulzer Ruti L5000 and L5100 of Sulzer Ruti, Switzerland, which is incorporated herein by reference. -37- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling in this page} 袈

11T Printed by the Consumer Cooperatives of the Central Procurement Bureau of the Ministry of Economic Affairs 43 64 2 2 A7 _______B7 V. Description of the Invention (35) "Air-jet weaving" in this article means weaving with air-jet loom 526 (shown in Figure 6) Fabric type, in which weft yarn 5 10 is inserted into the warp web by compressed air 514 output from one or more air spray nozzles 518 (shown in Figures 6 and 6a), as described above. Weft yarn 5 10 borrows compression Air pushes through fabric 528 with a width 524 (about 0 to about 60 inches), and more preferably about 0.91 meters (about 36 inches). The air jet filling system may have a single main nozzle 516, but it is also better There are a plurality of supplementary spare nozzles 520 along the warp width 5 12 for blowing in the supplementary air 522 to the weft yarn 510 to maintain the pressure required for the yarn 5 1 〇 across the warp fabric 528 width 5 24. Supply to the main The air pressure (gauge pressure) of the air nozzle 516 is preferably from about 103 to about 4 13 仟 Baska (k P a) (about 15 to 60 pounds per square leaf (psi)) and more preferably about 3 10 kPa (Approximately 45 psi). The preferred type of primary air nozzle 516 is the Sulzer Ruti needle air jet nozzle unit model. 44 455 001 'It has an internal air spray chamber with a diameter of 517 2 mm and a nozzle outlet pipe 519 with a length of 521 20 cm (purchased from Sulzer Ruti, Spartanburg, North Carolina). Air jet filling The system has 15 to about 20 supplemental air nozzles 520 that supply auxiliary air flow in the direction across the weft yarns 510 to help push the yarns 510 through the loom 526. Supply to each of the supplementary air nozzles 520 The air pressure (gauge pressure) is preferably from about 3 to about 6 bar. The weft yarn 5 10 is fed by the feed system 532 at a feed rate of about 80 to about 5500 meters per minute 'and preferably about 274 meters per minute ( (About 300 yards) The feed rate is stretched by the supply package 530. The weft yarn 5 10 is fed into the main nozzle 518 via a clamp. The air stream pushes a yarn of a predetermined length (approximately the width of the fabric required) Sea bass confusor yarn guide. When the insertion is completed, the main nozzle 518 ends of the yarn ends are cut by the cutter 534. -38- This paper size applies to Chinese national standards (CNS &gt; A4 size (210X297)) --- ----- II I -1-. ........- ^^ 1! I--'-^^ 1 I _ I ^^ 1 (Please read the back first (Please note this page before filling in this page) A7 43 6422 ________ B7 V. Description of the Invention (36) The compatibility and aerodynamic properties of different yarns produced by air jet weaving can be determined by the following methods, which are usually expressed as &quot; Air nozzle firing drag force &quot; test method. The air-jet conveying drag force test is used to measure the attraction or pushing force (·· dragging force_ ') applied to the yarn and thread when the yarn is pushed into the air-jet nozzle by the jet-jet force. In this method, 'each yarn sample is fed into the Sulzer Ruti needle jet air nozzle unit model 〇44 455 001 at a feed rate of about 274 meters per minute (about 300 yards), which has an internal air jet of 517 mm in diameter of 2 mm Chamber and 20 cm nozzle outlet pipe 519 (constructed from Sulzer Ruti in Spartanburg, North Carolina) with an air pressure of about 310 仟 Baska (about 45 pounds per square inch) gauge pressure . Before the yarn enters the air jet nozzle, make the tensiometer contact the yarn. The tensiometer measures the number of grams of force (dragging force) applied to the yarn as it is pushed into the air jet nozzle. The drag force per unit mass can be used as a benchmark for relative comparison of yarn samples. Relatively speaking, the drag force measurement is nominalized on a 1 cm long yarn. The gram mass of J cm length yarn is determined according to formula (I): gram mass = (; r (¢ 1/2) 2) (1 ^) (0 M) (l cm long yarn) (1) where d is The single fiber diameter of the yarn bundle, N is the number of fibers in the yarn bundle and / 〇it »* is the glass at about 250 degrees (about 2,6 grams per cubic centimeter). Table F lists the fiber diameters and quantities in the yarns of several typical glass fiber yarn products. -39- This paper size is in accordance with China National Standard (CNS) 8-4 specification (2 丨 0X297 mm) f Jingxian read the back of the two &gt; i Matters 4 and fill in 1 book. Consumption cooperation of employees A7 Β7 436 ^ 22 V. Description of invention (37)

^ F yarn type fiber diameter (cm) cellulose in bundle G75 9 xlO · 4 400 G150 9 xlO * 4 200 E225 7 xlO * 4 200 D450 5.72 x 1 (Π (9xl0-4 / 2) 2) (4〇〇) (2.6 g per cubic centimeter) (1 cm long yarn) = 6.62 x 10 "gram mass. For D450 yarn, the gram mass is 1.34 X 1 (Γ4 gram mass. Relative drag force per unit mass Air jet transport drag force __) is calculated by dividing the drag force measurement (gram force) measured by the tensiometer by the gram mass of the type of yarn tested For example, for a G 7 5 yarn sample, if the drag force measured by the tensiometer is 68.5, the drag force of air jet conveyance is equal to 68.5 divided by 6.62 X 10 · 4 equals 103,474 grams of force per gram of yarn. The air jet conveying drag force of the woven fabric forming the laminate of the present invention (measured in accordance with the above air jet conveying drag force test method) is greater than about 100,000 grams of force per gram of mass yarn, preferably about 100,000 grams of gram of mass yarn To about 400,000 grams of force, and better about 120,000 to about 300,000 grams of force per gram of mass yarn. Referring to Figure 1, fabric 14 may be used to coat and / or impregnate one or more layers of fabric 14 by polymerizing a thermoplastic or thermoset matrix material 12 to form laminate 10. Laminate 10 is suitable as an electronic support 30. Herein, "Electronic support" means the structure of the mechanical support and / or the electronic X-phase connecting element, including -40- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ^^^ 1 I n ^ l «k ^^^^ 1 I (Please read the notes on the back before filling in this page) Staff Consumer Cooperative of the Central Procurement Bureau of the Ministry of Economic Affairs, India, and Consumer Policy Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperation. Du Yinzhuang 43642P A7 _____87 5 2. Description of the invention (38) (but not limited to) activated electronic components' passivated electronic components' printed circuits' integrated circuits, semiconductor devices and other hardware related to these components, including (but not limited to connectors, sockets, sockets, Retains cursors and heat sinks.) The matrix materials that can be used in the present invention include thermosetting materials such as thermosetting polyesters, vinyl esters, epoxides (containing at least one epoxy or ethylene oxide group in the molecule such as polyols or sulfur Polycondensation Glyceryl ether), phenols, amine-based plastics, thermosetting polyurethanes, derivatives and mixtures thereof. The preferred matrix materials for forming printed circuit board laminates are FR-4 epoxy resin, polyimide, and liquid crystal polymers. 'Its composition is known to those skilled in the art. For further information on this composition, see 1ϋTechnical Manual 1 ^, ASM International Corporation (1989) pages 534-537. Non-limiting examples of suitable thermoplastic polymeric matrix materials include polyalkylenes, polyamides, thermoplastic polyurethanes and thermoplastic polyesters, ethylenic polymers and mixtures thereof. Further examples of useful thermoplastic materials include polyimide, Polyether fluorene, polyphenyl fluorene, polyetherketone 'polyphenylene oxide, polyphenylene sulfide, polyacetal, polyvinyl chloride and polycarbonate. Available matrix material formulations are composed of EPON 1120-A80 epoxy resin, dicyandiamide, 2-methylimidazole, and DOWANOL PM. Other ingredients that can be included in the composite with polymeric matrix materials and reinforcements include colorants or pigments, lubricants or processing aids' ultraviolet (UV) stabilizers, antioxidants, other fillers and diluents. The fabric 14 can be coated and impregnated by immersing the fabric 14 in a polymer matrix material 2 bath, for example, described in R. Tummala (edited electronic package, page 895-896, which is incorporated herein by reference) 。Polymeric matrix material I] and weaving -41-This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 Gongchu) --------- Approve clothing ------ ίτ (Please Read the notes on the back before filling in this page) 4 3 64. Α7 Β7 V. Description of the invention (39) *-物 14 By various methods to form composites or laminates 10, depending on, for example, the type of polymer matrix material used For example, for thermosetting matrix materials, laminates can be formed by compression or injection molding, pultrusión 'manual cladding, or by tablet molding and then compression or injection molding. Thermoset polymer matrix materials can be applied to the matrix The material contains a cross-linking agent and / or curing by application of heat. Suitable cross-linking agents for cross-linking the polymeric material matrix are as described above. The curing temperature and time of the thermosetting polymeric matrix material depend on, for example, the type of polymeric matrix material used, the matrix system Other additives and the thickness of the compound and other factors (only described And a few). For thermoplastic matrix materials, suitable methods for forming composites include direct molding or extrusion mixing followed by injection molding. The methods and devices for forming composites by the methods described above are described in I. Rubin Plastics and Technology Yearbook QH · Page 1062 'Pages 1Π9-1215 and 1225-1271, which are incorporated herein by reference. Also in the specific embodiment of the present invention shown in FIG. 4, the composite or laminate 1 includes a compatible matrix material 1 2 Impregnated fabric 1 4. The impregnated fabric can then be squeezed between a set of metering rollers to leave a measured amount of matrix material and dried to form a semi-cured substrate or an electronic support in a prepreg state. The conductive layer 4 〇 It can be placed along the 42 part of the prepreg side. The placement method is described later, and the prepreg is cured to form a laminate 10, which has the function of an electronic support 50 with a conductive layer. In another specific example, and more usually in the electronic support industry, two or more prepregs are combined with a conductive layer and laminated together and cured in a manner known in the art to form a multilayer electronic support β such as (but Not limited to the present invention), can be borrowed Compressed prepreg stack between polished steel plates under elevated temperature and pressure -42-Thai paper size applies to China National Standard (CNS) A4 specification (210 × 297 mm) (Read the precautions on the back before filling this page)

L Γ Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 436422 A7 ________ _B7 V. Description of the invention (40) Objects are laminated in a predetermined period of time to cure polymer materials and Φ to the required thickness < Laminate. Before lamination, one or more prepreg parts may be provided with: a conductive layer, and a solid dagger, so that the obtained electronic support is a laminate having at least one conductive layer along the exposed surface (hereinafter referred to as Is &quot; Covering Laminate 丨 '). 'Connection: the circuit can be formed from the conductive layer of a single or multi-layer electric support using the technology known in the art', and the structure of the printed circuit board is collectively referred to as the electronic branch m, spring electronic circuit board, spring state It is possible to form perforations or holes in the U-sub-supports (also known as, through-holes) to create electrical connections between components on the opposite surface of circuits and / or electronic supports, and to form through-holes. Known any convenient method 'includes (but is not limited to) mechanical drilling and laser drilling. More specifically, after the perforation is formed, a layer of conductive material is deposited on the perforated wall or a conductive material is filled in the perforation to promote the required Electrical connection and / or teaching heat. Printed by the Central Ministry of Standards and Consumers Cooperatives in — ^ n--^^ 1----I — ^ 1 ^^^ 1 ί n (Please read the first 89 Note that please fill in this page again) The conductive layer 40 can be learned by any technique by using this technique. For example (but not limited to the present invention) by laminating at least part of the semi-cured or cured prepreg or laminate side Sheets or foils of metallic material to form a conductive layer. Alternatively, known techniques can be used to include (but not (Limited to) Electroplating, electroless plating, or sputtering methods are used to form a conductive layer by depositing a metal material layer on at least part of a semi-solid or cured prepreg or a laminated side. Metal materials suitable as the conductive layer include (but are not limited to ) Steel (preferably) 'silver, aluminum, gold, tin, tin-lead alloy' palladium and combinations thereof. In another embodiment of the present invention, the electronic support may be one or more electronic circuit boards (such as The above) is a multilayer electronic circuit board structure constructed by laminating one or more coating laminates (as described above) and / or one or more prepregs. If -43- the paper's dimensions apply to Chinese national standards (CNS) A4 specification (210X297 rounding &gt; 436422 A7 ---------------- B7 V. Description of the invention (41) It should be possible to electrically support the support such as along a multilayer electronic circuit The exposed side of the board incorporates an additional conductive layer. Furthermore, if necessary, additional circuits can be formed from the conductive layer in the manner described above. 1 Understand that depending on the relative positions of the layers of the multilayer electrical circuit board, the circuit board can be used for both external circuits. As mentioned earlier, additional perforations can be made partially or completely through the circuit board to allow Electrical interconnections are made between selected locations between layers. 1 Know that the resulting structure may have certain perforations that extend completely through the structure, some perforations only extend partially through the structure, and some perforations that are completely within the structure. Better, form an electronic support The thickness of the laminate of object 50 is greater than about 0.05 mm (0.002 leaf) 'and more preferably from about 0.3 mm (0.0 (5) pairs) to about 25 mm (about 0.1 inch) For 8-layer laminates of type 7628 fabric, the thickness is about ¥ 1.32 without meters (0.052 inches). The number of 14 layers of fabric in laminate 10 can be changed according to the required thickness of the laminate. In order to make the figure The formula is clearer and only a single layer of fabric is shown in the laminates in Figures i, 4 and 5. The number of layers can range from 1 to about 40 layers. It has 8 layers of fabric or prepreg compared to the concrete laminate. The resin content of the laminate may be from about 35 to about 80% by weight, and more preferably from about 40 to about 75% by weight. The amount of fabric in the laminate can be from about 20 to about 65 weight. / 〇 and more preferably from about 25 to about 60% by weight. Printed by the Consumer Cooperatives of the Bureau of Misunderstanding of the Ministry of Economic Affairs

In nn 1 I. ^ Ϋ In -riJ (谙 Read the precautions on the back before filling in this f) For woven E-glass fiber and use FR-4 epoxy resin with a minimum glass transition temperature of about 1 10 core For the laminate formed by the matrix material, the required minimum bending strength across the machine or width direction (usually perpendicular to the longitudinal axis of the fabric) is greater than 3 X 107 kg / m 2 'preferably greater than about 3.52 X 107 kg / M2 (approximately 50 kpsi) 'and better than approximately 4.9 X 107 kg / m2 (approximately 70 kpsi), based on the IP C-4101H rigid multi-layer printing board substrate material specifications • 44- This paper is a standard in China National Standard (CMS) A4 specification (210X 297 mm) 436422 A7 B7 Printed by the Central Bureau of Standards, Ministry of Economic Affairs and Consumers ’Co-operative Society And Packaging Electronic Circuit Association Bulletin (December 1997). IPC-4101 is hereby incorporated by reference. In the length direction, the minimum bending strength required for the length direction (usually parallel to the longitudinal axis of the fabric) is greater than about 4 X 107 kg / M 2 ′ and preferably greater than 4.23 X 107 kg / m 2. According to ASTM D-790 and IPC-TM-650 Test Method Manual (Interconnect and Packaging Electronics Association, December 1994, which is hereby incorporated by reference) 'According to PC-4101 Paragraph 3.8.2.4 Completely removing the package by etching Measured with metal. The advantages of the electronic support of the present invention include high bending strength (tensile and compressive strength) and high modulus, which can reduce the deformation of circuit boards (including laminates). It is copper-clad FR-4 epoxy In the laminate state, the electric pre-support of the present invention preferably has a thermal expansion coefficient of less than about 4'5% in the Z-direction of the laminate, that is, across the thickness of the laminate, And more preferably from about 0.001 to about 45% by weight (determined according to the IP C test method 2.4 · 41, which is incorporated herein by reference). Such laminates preferably each contain 8 layers of 7628 type fabric, However, 080 or 2116 type fabrics can be used alternately. Laminates with a low thermal expansion coefficient are generally less likely to expand and contract and can reduce circuit board distortion. The present invention also relates to a method for manufacturing a multilayer laminate and an electronic circuit board. The circuit board includes at least one composite layer made in accordance with the techniques herein and A composite layer D made in a different way from the cultural and educational composite layers (that is, using conventional glass fiber composite technology), and more specifically and as known to the skilled artisan, 'continuous glass traditionally used for woven fabrics The monofilaments in the fiber bundles include partially or fully dextrinized starch or amylose, hydrogenated vegetable oils, cationic humectants, emulsifiers, and water-based starch / oil sizing agents, sizing -45- ( 210x 297 mm) i ^^^ 1 mmt ^^ i *-1 ^ 1 1--1-tn, lei {谙 Please read the note on the back side # 'item before filling out this page) 436422 A7 B7 V. Description of the invention (43) Please read the memorandum before you fill in%. The agent on this page contains (but is not limited to) those disclosed by Lowenstein on pages 237-244 (3rd edition '1993), which is incorporated herein by reference. The warp yarns made from these bundles are gathered before weaving at, for example, usp 4,53,876, line 3, line 67 to line 4, line 11 (which is also incorporated herein by reference) ( Vinyl alcohol) solution to protect the bundles from friction during the weaving process. This operation is commonly referred to as sizing ^ Printed poly (vinyl alcohol) and starch / oil sizing agents are usually not compatible with the polymer matrix materials used by composite manufacturers and the fabric is wetted It must be cleaned to remove substantially all organic materials from the surface of the fiberglass. This can be done in various ways, such as by scraping the fabric, or more often by heat treating the fabric in a manner known in the art. As a result of the cleaning operation, an unsuitable interface was created between the polymer matrix material used to wet the fabric and the cleaned glass fiber surface, so a coupling agent must be applied to the glass fiber surface. This operation is sometimes referred to as oiling by those skilled in the art. The coupling agents most commonly used for oiling operations are silanes, including, but not limited to, those disclosed by Ep Plueddemann-Inverse 1 End_Yueshe Agent (1982) pages 146 · 147 (which is incorporated herein by reference). See also Lowenstein, pages 249 to 25th (3rd ed., 1993). After the silane treatment, the fabric is wetted with a compatible polymeric matrix material, squeezed between a set of metering rollers and dried to form the semi-cured prepreg described above. It should be understood that depending on the nature of the matrix resin used in the sizing agent cleaning operation and / or the compound, the sizing and / or oiling steps may be omitted. Next, one or more prepregs incorporated into the conventional glass fiber composite technology and one or more prepregs incorporated into the present invention can be combined to form the above-mentioned electric pre-support, and especially a multilayer laminate. Or electronic circuit board. For more information on the electronic circuit board weaving method ', see 1 Electronic Materials IL Manual τΜ, asm International Corporation (1989) pages 113-115, R. Tummala (grading), installation manual, (1989), -46-this book The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 4 3 6 4 ^ :: 'A7 ____B7 V. Description of the invention (44) Pages 858-861 and 895-909, MW Jawitz, printing The circuit board is J. (1997), pages 9.1, 9.42, and CF Coombs, Jr. (eds.), 3rd edition, 1988 ^^^, all of which are incorporated herein by reference. The composites and laminates forming the electro-supports of the present invention can be used to form packaging for the electronics industry, and especially the first, second and / or third repackaging, as disclosed by Tummala on pages 25-43 Or, it is incorporated herein by reference. In addition, the invention can also be applied to other degrees of packaging. The present invention also includes a method for assembling a fabric 1-4, in which a first yarn (weft) and a second yarn (warp) are woven with each other to form a woven fabric 14, such as the above-mentioned air jet weaving. The improvements include [yarns with coatings compatible with polymeric matrix materials, the yarns including rhenium—or multiple polymers and (2) at least one selected from vinylpyrrolidone polymers, vinyl alcohol polymers, starch, and Its mixture (detailed as before). Another object of the present invention is to form a laminate of a woven fabric and a polymeric matrix material. The woven fabric is coated with a polymeric matrix material to form a coated fabric and to apply heat to the coated fabric. The woven fabric includes yarns containing E · glass fiber. The improvement includes sloping glass fibers compatible with polymeric matrix materials. The yarn has air jet conveying drag force greater than about the center of the economy per gram of yarn. Standard Bureau employee consumer cooperative printed 100,000 grams of force, using a needle-shaped air jet nozzle unit with an internal air spray chamber with a diameter of 2 mm and a nozzle outlet pipe with a length of 20 cm at a yarn feed rate of about 274 meters per minute ( Approx. 300 yards) and approx. 3 丨 0 仟 Baska (approximately 45 hours per square inch) gauge pressure under the pressure of krypton gas pressure 'and the bending strength of the laminate in the fabric filling direction is greater than about 3 per square meter χ〗 〇7 kg (about 42.7 kpsi). -47 · This paper is a standard Ficai household materials (CNS) A Che (210X297) A7 4364 2 2 B7 V. Description of the invention (milk) ^-I Packing --- Order (Jing first read the back Note: Please fill in this tile again.) Another object of the present invention is a method for forming a laminate of a woven fabric and a polymeric matrix material. The method is to coat the woven fabric with a polymeric matrix material to form a coated fabric and apply the coated fabric. heating. The woven fabric includes a yarn containing E_glass fiber. The improvements include E-glass fibers with a coating compatible with the polymeric matrix material. The coating includes: (丨) polyester; and (2) at least one polymer selected from the group consisting of ethylpyrrolidone polymers, vinyl alcohol polymers, Vinyl alcohol polymer and starch polymer. The invention will be illustrated by the following specific non-limiting examples. Example 1 Using the detailed description above, the air jet delivery drag force &quot; test method was used to determine the compatibility of several different yarn samples in the air jet knitting process. The yarn samples of the present invention are shown in the following Table 丨 A matrix resin compatible water-forming sizing composition A-F coated and used, air jet delivery drag force &quot; test method s. Each composition contained less than 1% by weight acetic acid. Each sizing composition has about 2.5% by weight. Each coated glass fiber bundle is twisted to form a yarn and wound onto a bobbin in a similar manner using conventional twisting equipment. The sample Bvae was coated with an aqueous forming sizing composition β, but was evacuated at a temperature of 19 ° C. It was dried for about 46 hours. The weight loss values of the samples Chi and Dhi were 1.59 and 1.66% by weight, respectively. &Lt; »-48- The paper size is toward the towel _ home turn (CNS) M specifications (21 () &gt; &lt; 297 Gongchu) 436422 A7 B7 5 Description of the invention (46) Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives, Form 1 A,% by weight of total solids, Ingredients, ABCDEF, Thermoplastic polyester film-forming polymer 82 28.6 29.1 31.58 50.71 0 0 83 43.7 39.1 0 0 0 0 epoxy film-forming polymer 84 0 0 21.05 0 0 0 epoxy film-forming polymer 85 0 0 0 0 16.12 63.54 polyvinylpyrrolidone 86 0 9.7 15.79 15.21 1.31 5.18 epoxy functional group Organosilane coupling agent 87 2.3 2.3 8.42 8.11 3.17 12.51 Acrylic functional organosilane coupling agent 88 4.7 4.8 0 0 0 0 Amine functional organosilane coupling agent 89 0 0 8.42 8.11 0 0 Polyoxy secondary alkyl block copolymer 9Q 10: 7 5.6 0 0 0 0 Ethyl octylphenoxyethanol 91 0 0 4.74 6.39 1.63 6.44 Polyamine 92 4.8 4.8 0 0 0 0 Polyoxyethylated vegetable oil 93 0 0 0 0 1.63 6.44 Polyethylene glycol Monolaurate 94 0 0 0 0 0.79 3.11 Surfactant 95 3 .6 3.6 4.74 6.39 0 0 Organic lubricant% 0 0 0 0 0.40 1.56 Organic lubricant 97 0 0 4.21 4.06 0 0 Polyoxyethylene polymer 98 0.6 0 0 0 0 0 Boron nitride powder particles 99 1.0 1.0 0 0 74.78 1.00 Aqueous suspension of boron nitride particles IGG 0 0 1.05 1.01 0 0 82 was purchased from Borden Chemical Company, RD-847A, Columbus, Ohio. 83 DESMOPHEN 2000 polyethylene glycol adipic acid, commercially available from Bayer, Pittsburgh, PA. 84 EPI-REZ® 3522-W- -49- purchased from Houston Hull Chemical Company, Texas. This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) {Please read the precautions on the back before filling in this Page) Binding A.3642 2 a? __B7_ V. Description of the Invention (47) — 66 ° 8 5 EPON 826 from Houston Shell Chemical Company, Texas. 86 PVP K-30 Polyethylenylpyrrolidone &lt; Sunshine, purchased from IS Chemical Company, Warner, NJ. 87 A-187 r-glycidyloxypropyltrimethoxyzine from OSi Professional Industries, Tarrytown, New York. 88 A-174 r-methylpropionyloxypropyltrimethoxysilane was purchased from OSi Professional Industries, Tarrytown, New York. 89 A-1100 amine-functional silicone coupling coupler purchased from OSi Professional Industries, Tarrytown, New York. 90 PLURONICTM F-108 polyoxypropylene-polyoxyethylene cock copolymer, purchased from BASF Company, Parsippany, New Jersey. 91 IGEPAL CA-630 ethoxylated octylphenoxyethanol purchased from G AF Company, Wiener, New Jersey. 92 was purchased from VERSAMID 140 Polyamine, which is suitable for the grinding chemistry industry. 93 ALKAMULS EL-719 polyoxyethylated vegetable oil from Rhone-Poulenc. 94 KESSCO PEG 600 polyethylene glycol monolaurate purchased from Stepan Company of Chicago, Illinois. Fanfan, Consumers Cooperative of Central Bureau of Standards, Ministry of Economic Affairs, ^^^ 1 — ^ n Λ—:-1 ri ^ — 1 ^ 1- _---1 ^ 1 ^^^ 1, a ei (Please read the back first Note: Please fill in this page again.) 9 5 MACOL NP-6 nonylphenol active agent purchased from BASF, Pasipani, New Jersey. 96 Part EMERY® 6717 purchased from Henkel Corporation, Kenkage, Ill. Amidated polyethylenimine. 9 7 EMERY® 6760 Lubricant-50 purchased from Henkel Company, Kenkachi, Illinois-This paper size applies to Chinese national standard {CNS) A4 specification (2tOX297 mm) 436422 A7 B7 V. Description of the invention (48) Facial agent β 9 8 POL YOX WSR-3 01 polyoxyethylene polymer from Danbury, Connecticut, United Carbon. 99 PolarTherm® PT 160 boron nitride powder particles purchased from Advanced Ceramics Corporation of Lakewood, Ohio. 100 ORPAC BORON NITRIDE RELEASCOAT-CONC Boron Nitride Particles in Aqueous Dispersion, purchased from ZYP Coatings, Oakbridge, Tennessee. The "Air Jet Conveying Drag Force" test method was also used to evaluate commercially available samples 63 1 and 633 D-450 starch-oil coated yarn chains; 690 and 695 starch-oil coated yarns and 1383 G-75 yarns. (Purchased from PPG Industries). Three comparative samples X 1, X2, and X3 coated with the same aqueous forming composition X listed in Table 1 B below were also tested. Comparative sample X 1 had 2.5% solids by weight. Comparative sample X2 With 4.9% by weight solids and air-dried at about 25 ° C for about 8 hours. Comparative sample X3 has 4.6% by weight solids. --------. ^ ------ 1T ----- -# (Please read the precautions on the back before filling out this page) Printed Form 1B of the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs,% by weight of the total solids Composition Sample No. X Thermoplastic polyester film-forming polymer 1ω 28.9 Thermoplastic Polyester film-forming polymer ltK 44.1 Epoxy-functional organic silane coupling agent 11) 3 2.3 Acrylic-functional organic silane coupling agent 1 (M 4.8 -51-This paper size applies to China National Standard (CNS) A4 specification (210X297) (%) 436422 A7 B7 Printed by the Consumer Cooperatives of the Central Procurement Bureau of the Ministry of Economic Affairs 49) Polyoxyalkylene block copolymer 105 10.9 Polyamine 1Q6 4.8 Surfactant 1Q7 3.6 Polyoxyethylene polymer 1GS 0.6 Purchased from RD-847A polyester resin from Borden Chemical Company, Columbus, Ohio. 11) 2 Purchased DESMOPHEN 2000 Polyethylene Adipate from Bayer Corporation of Pittsburgh, PA. 103 A- [87-Glycidoxypropyltrimethoxysilane was purchased from TSi City, New York Professional Industries. 10 4 Buy A-174 r -methacryloxypropyltrimethoxypropane smelt a 105 si professional soil industry from Tali City, New York purchased from PLURONICtm F-108 Polymer of BASF Company, Parsippany, New Jersey Oxypropylene-polyoxyethylene copolymer. 106 purchased from General Mill Chemical Corporation VERSAMID 140 polyamine. 107 purchased from BASF iMACOL NP-6 nonylphenol active agent in Parsippany, NJ. 108 POLYOX WSR-301 polyoxyethylene polymer purchased from Danbury United Carbonation, Connecticut. Each yarn sample was ejected through a Sulzer Ruti needle air nozzle at a rate of 274 meters (300 yards) per minute. Unit model 〇44 455 001 feed, the nozzle unit has an air spray chamber with a diameter of 2 mm And nozzle outlet pipe with a length of 20 cm (purchased from Su 丨 zer Ruti, Spartanburg, NC), empty -52- (Please read the precautions on the back before filling this page)

Jne Γ One standard one country I country I country one medium size paper on paper one grid one gauge I centimeters A7 43 64 2 2

7 B 5 'Explanation of invention (50) Air pressure 3 10 仟 Baska (45 pounds per square inch) gauge. The tensiometer comes into contact with the yarn before it enters the air jet. The tensiometer measures the gram force (dragging force) applied to each yarn sample when the individual yarn sample is pushed into the air jet nozzle ^ These values are listed in Table 1C below.

Table 1 C Sample number Yarn type Burning weight loss (%) Drag force (gram force) Air jet conveying drag force (gram force per gram mass) A G-75 0.35 68.5 103,474 B G-75 0.30 84.9 128,248 Bvac G-75 0.35 95.0 143,587 c D-450 0.52 37.33 278,582 D D-450 0.40 '47.1 351,493 E G-75 0.35 79.3 119,789 F G-75 0.35 83.2 125,680 Comparative sample 63Γ D-450 1.6 21.45 160,075 633 · D-450 1.3 38.1 284,328 690 * G-75 1.0 108.23 163,489 695 * G-75 1.0 100.46 151,752 1383 G-75 0.75 14.47 21,858 XI G-75 0.33 36.4 54,85 X2 G-75 0.75 19.0 28,701 X3 D-450 1.37 12.04 89,851 Chi D-450 1.59 _ 9.00 67,164 Dhi D-450 1.66 10.43 77,836 * Coated with starch-oil sizing formula by the Central Bureau of Standards of the Ministry of Economic Affairs, Pui Gong Consumer Cooperatives (铕 Please read the precautions on the back before filling this page) -53- This paper size is applicable to China Standard (CNS &gt; A4 specification (210X297 mm) 436422 A7 B7_ V. Description of the invention (51) ^-As shown in Table 1 c above, each yarn coated with the polymer matrix material of the present invention is compatible with the sizing composition Air jet conveyance The drag value is greater than 100, 000. Only starch-oil commercially available bundles of starch-oil bundles that are not generally compatible with the above polymeric matrix materials have a drag value greater than 100,000. Sample yarns with a polymeric matrix compatible coating Chi And Dhi's air jet delivery drag is less than 100, 000. Due to the high amount of coating on the yarn, that is, the loss of combustion is greater than about 1.50 /., And the single fiberization of the yarn by air jet is suppressed. In order to evaluate the layer The strength of the composite was formed from samples of 695, sample B, and sample Bvac G-75 yarn (as described above) into 7628 type fabric (such as the above-mentioned type parameters). Each stack of fabric samples was EPON 1120-A80 epoxy resin, two Ammonia diamine, 2-methylimidazole and DOWANOL's FR-4 resin system are laminated to form a laminate. According to the ASTM D-790 and IPC-TM-650 test methods of the Interconnect and Packaging Electronics Association Manual (and For reference herein, the flexural strength (maximum failure stress) of each laminate is evaluated, but the coated metal is completely removed by etching in accordance with IPC-4101 paragraph 3.8 2 4 and used in accordance with ASTM-2344 (and incorporated herein by reference) 15.9 Mm (5/8 inch) means And 1.27 mm / minute (0.05 inch / minute) cross head speed evaluation interlayer shear strength β These evaluation results are shown in the following table 1 D »-54- Specification (2 丨 〇χ297 公 董 y (please read the notes on the back before filling out this page) Ordered by the Central Consumers Bureau of the Ministry of Economic Affairs and printed by the Consumer Cooperative 436422 A7 ______B7 V. Description of the invention (52)

Table 1 D Sample Bending Strength Bending Modulus Short Beam Shear Strength xlO8 62959 2.3 xlO10 3360800 2.3 X 107 3264 As shown in Table 1D 'Laminate samples B and Bva prepared according to the present invention. Compared with 695 starch-oil coated glass fiber yarn, it has higher bending strength and modulus value and similar short-bundle shear strength. Practice 2 Each laminate sample containing 8 layers of type 7628 fabric prepared from a sample of Bvae-coated yarn (Sample A) and 695 starch-oil-coated yarn (as described above) (control group) was evaluated. Coefficient of thermal expansion in the Z-direction (11Z-CTE) (that is, across the thickness of the laminate). The laminate was prepared using the FR-4 epoxy resin described in Example 1 and tested using IP C Test Method 2.4 · 4 1 ( It is incorporated herein by reference.) It is coated with copper. The thermal expansion coefficient in the Z-direction was evaluated for each laminate sample at 288 C according to the IPC test method 2.4.41. The evaluation results are shown in Table 2 below. ------ ---..---- Please read the notes on the back before filling in this page.) Ordered by the Central Consumers Bureau of the Ministry of Economic Affairs and printed by the Consumer Cooperatives -55- This paper is a common Chinese national standard (CNS) A4 specification 〇X 29? Mm) 4 3 6422 A7 B7 V. Description of the invention (53 sample sample A1 sample A1 (retest) sample A2 sample A2 (retest) sample A3 sample A3 (retest) sample 1 sample 2

As shown in Table 2, for the layered grain samples A1-A3 of the present invention, the thermal expansion coefficient in the layer Z-direction of the layered grains was lower than that of samples 1 and 2 prepared by the 695 starch-oil coated yarn. Example 3 Aqueous sizing compositions A-D (described in Table 1 A, Example 1) and Comparative Sample No. 1 were coated on E-glass fiber bundles. The formula for Comparative Sample No. 1 is shown in Table 3 below. Each sizing composition has about 2.5% solids by weight. Each coated glass fiber was twisted in a similar manner using conventional twisting equipment to form a yarn and wound onto a bobbin. -------- Installation ------ 11 ------ ^ {Please read the precautions on the back before filling out this page} Printed by the Bayer Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs-56 copies The paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297), 4364 22 V. Description of the invention (54) A7 B7 Table 3 Ingredients accounted for the total solids weight No. 0 / n composition thermoplastic polyester film-forming polymer 1 Thermoplastic polyester film-forming polymer 1 epoxy-functional organosilane coupling agent 111 propionic acid-functional organosilane coupling agent 112 polyoxyalkylene block copolymer m Sample number comparison sample number. 1 28.9 44.1 2.3 4.8 10.9 (Please read the notes on the back before filling this page) Polyamide 1 4.8 Surfactant Π5 3.6 Polyoxyethylene polymer 116 0.6 Γ 09 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economy 114 Constructed by Borden Chemical Columbus, Ohio The company's RD-847A polymerization resin. 10 DESMOPHEN 2000 poly (hexamethylene) hexanoic acid diol purchased from Bayer Corporation of Pittsburgh, PA. 11A-1 87 r-glycidyloxypropyltrimethoxysilane purchased from TSI City, New York, Professional Industry. 12A-174r-Methylpropoxypropyltrimethoxysacrylic acid, purchased from TSi City, New York. 13 Lectures from PLURONICTM F- 108 polyoxypropylene-polyoxyethylene copolymer. VERS AMID 140 polyamine from General Milling Chemicals. MACOL NP-6 nonylphenol bound from BASF, Pasipani, Jersey -57- This paper size is suitable for financial transfer (CNS) A4 size (2 | Gx297 public change) Employees of the Central Bureau of Prospecting, Ministry of Economic Affairs Printed by Consumer Cooperatives 4 3 6 4 2 ί: Α7 --4__ Β7 _____ V. Description of the Invention (55) I 、 Active Sword β 116 POL γοχ WSR-301 polyoxygen, purchased from Danbury United Carbonation, Connecticut Ethylene polymer. 117 * Commercially available PPG Industries, Inc's 1383 Fiberglass Yarn Products 0 Evaluation Samples A-D, Comparative Sample Number 1 and Comparative Sample Number 2 ί 17 (Fiberglass Yarn Products Sold by P PG Industries 1 986) Several types of yarn are physically exempt, such as weight loss on combustion (LO), air jet compatibility (air drag), friction, and broken monofilaments. The average weight loss on ignition (thickness of solids forming the sizing composition divided by the total weight of glass and dry forming-sizing composition) of the three tests of each sample is shown in Table 4. The dagger is controlled by a check thread tensiometer (which applies tension to the yarn) at a controlled feed rate of 274 meters (300 yards) per minute, and Ruti two at a gas pressure of 301 kpa (45 pounds per square inch). The millimeter-diameter air nozzle feeds the yarn and evaluates the air drag of each yarn. At a rate of 274 meters (300 yards) per minute, the sample was stretched through a conventional tension measuring device through one of the fixed chromium with a diameter of about 5 cm (2 inches), and replaced by a straight path between the tension measuring devices. For a 5 cm yarn, a tension of about 30 grams was also applied to each yarn sample to evaluate the friction between the sample and the comparative sample. The frictional differences in grams are listed in Table 4 below. This friction test is intended to simulate the frictional forces experienced by a yarn during a weaving operation. Fractured monofilaments were also evaluated for each sample and comparative samples using an abrasion tester. When each test sample was stretched through the abrasion testing device at a speed of 0.46 meters (8 inches) per minute, a tension of 200 g was applied to each test sample. Samples and Comparative Samples-58- This paper standard is in accordance with Chinese national standard. Α4 ^ Grid (2 offering 297mm ^ ------ II — &quot;-H, I-I ί I 丁 (Please read first Note on the back page, please fill in this page j 4364 2 2 A7 ____B7 V. Description of the invention (56) to-The product was evaluated twice, and the average number of broken filaments is listed in Table 4. The wear tester consists of two parallel steel springs. Each test yarn sample is curled between two adjacent rows of steel springs in the first row, and then curled between two adjacent rows of steel springs in the second row. The distance is 丨 / 2 inches. The steel spring is shifted back and forth over a length of 4 inches at a rate of 240 cycles per minute in a direction parallel to the yarn passing. Sample AD and comparative samples have air drag forces, friction, and breakage of wear. The monofilament results are listed in Table 4. Sample — AB .CD Compare Sample No. 1 Compare m Item No. 2 LOI (wt% 1) 0.35 0.30 0.52 0.40 0.33 0.75 Air drag (g) 68.5 84.9 37.3 47.1 36.4 19.0 Friction (g ) 24.7 18.3 • 23.9 38.1 Number of broken filaments per yard of yarn 2.0 1.0 —-3.8 1,0 Table 4 ^^^ 1 u ^ ^^ 1---31 1 ^ 1 j-1. ^ 1. L ------- ----- ^ — ^ 1 I ------- 1 /, τ (Please read the back first Please pay attention to this page, please fill in this page) As shown in Table 4, printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Fewer broken monofilaments, lower friction, and higher air drag values. Samples C and D also have higher air drag values than the comparative samples. 2 Air drag test is to simulate the yarn propelled through the weaving by air Relative test of weft insertion process of air jet loom on cloth weaving machine. It is easier to use air jet monofilament yarn to provide a larger surface area of air jet advancement, which can speed up the yarn passing through the loom and increase production. Sample A -D (invention system-59- in the heart-fit financial standard) (cnsTa Na (2 297 mm 1 — i R 4 2 2 A7 ___ _____B7 Invention Note (57) a prepared sample) The comparative sample is high, which indicates excellent air-jet compatibility. Example 4 The ingredients in the amounts listed in Table 5 are mixed in a similar manner as described above to form the aqueous solution of the present invention. Sungsang composition E, F'G, and Η and comparative samples. Each composition contained less than about 1% by weight of acetic acid. Each of the aqueous sizing compositions of Table 5 was coated at 0-7 5E -On broken glass fiber bundles. Each sizing-forming composition has a solids amount of from about 6 to about 25 weight 0/0. f Please read the precautions on the back before filling in this page. Packing. Consumption cooperation with employees of the China Standards Bureau of the Ministry of Economic Affairs. Du Yinfan Table 5-Composition% by weight of total solids Sample No. Component EFG Η Comparative Sample _ Epoxy Film-forming polymer 118 16.12 63.54 16.12 63.54 60.58 Polyvinylpyrrolidone 119 1.31 5.18 1.31 5.18 4.97 Polyoxyethylated vegetable oil 12ΰ 1.63 6.44 1.63 6.44 6.18 Ethoxylated octylphenoxyethanol 121 1.63 6.44 1.63 6.44 6.18 Polyethylene glycol Monolaurate 122 0.79 3.11 0.79 3.11 2.98 Epoxy-functional organic silane coupling agent 123 3.17 12.51 3.17 12.51 12.00 Organic lubricant m 0.40 1.56 0.40 1.56 1.50 Polyethylene emulsion 125 0 0 0 0 4.6 i Boron nitride powder particles 126 74.78 1.00 0 0 0 Boron nitride particles in aqueous suspension 127 0 0 74.78 1.00 0 Purchased from Epon 826, Houston Shell Chemical Company, Texas. PVP KK-3 0 Polyethylene -60 from IS P Chemical Company, Warner, New Jersey-60- This paper is sized for the Chinese National Standard (CMS) A4 (210X297 mm). Central Bureau of Standards, Ministry of Economic Affairs Consumption cooperation by employees. Printed 4 3 6 ^ 22 Α7 Β7 Five 'invention description (58) _-11 Biha Tiger Snail 120 120 ALKAMULS EL-719 polyoxyethylated vegetable oil purchased from Rhone-Poulenc. 121 IGEPAL CA-630 ethoxylated octylphenoxyethanol purchased from G AF Company, Wiener, New Jersey. 122 KESSCO PEG 600 polyethylene glycol monolaurate e purchased from Stepan Corporation of Chicago, Illinois. 123 A-187 r-glycidoxypropyltrimethoxy crushed roasted from Taly City, New York. . 124 Part EMERY® 6717 purchased from Henkel Corporation, Kenkatch, Ill. Amidated polyethylenimine. -12 5 Protolube HD high-density polyethylene emulsion purchased from Sybron Chemical Company, Birmingham, New Jersey "126 PolarTherm® PT 160 boron nitride powder particles purchased from Advanced Ceramics Corporation of Lakewood, Ohio" £ 27 purchased from ORPAC BORON NITRIDE RELEASECOAT-CONC Nitrided Rotary Granules in Aqueous Dispersions, Oakbridge, Tennessee ZYP Coating Industry. Each coated glass fiber bundle is bridged in a similar manner using a conventional twisting device to form a yarn and wound on a bobbin. Samples F and F yarns exhibit minimal glue overflow during twisting and yarns of samples E and G. The thread showed serious glue overflow during twisting. "Similar to the above Example 3 Evaluation Sample Ε-Η and the air drag of Comparative Example Yarn -61-This paper size applies the Chinese National Standard (CNS) A4 specification (210 × 297 mm)

HI ^^^ 1-n ^ — ^^^ 1 · I ~,-ft Ίϊ ^. (Please read the notes on the back before filling out this page. J A7 The staff consumption cooperation of the Central Provincial Bureau of the Ministry of Economic Affairs 436422 Description of the invention (59) The drag value of King of Kings is measured on two packages samples at the pressure shown in Table 6. Shirley model 84 〇 4 丨 [broken monofilament detector (purchased from British sdl International Industries) 5 is estimated The average number of broken monofilaments per 200 meters of each yarn at 200 meters per minute. These values represent the average of measurements made on 4 packages of each yarn. The values of broken monofilaments are reported from the full bGbbin), 136 grams (3/10 pounds) and 272 grams (6/10 pounds) of yarn rolled out of the package. The closed-door force test of each yarn is also evaluated and is listed in Table 6 below. The number of broken monofilaments measured by the closed ... tensile test method was taken out from the package at a speed of 2000 m / min, passed through a series of 8 parallel ceramic magnetic needle guide wires, and passed through the Shirley broken monofilament detector described above. Count the number of broken filaments and measure. Table ΰ Broken yarn per meter of yarn. Sample E Sample F Sample G Sample Η Comparative sample 0.887 0.241 greater than 10 0.065 0.192 136 grams (3/10 pounds) 0.856 0.017 greater than 10 0.013 0.320 272 grams (6/10 pounds) 0.676 0.030 greater than 10 0.101 0.192 door tension (fines per gram) gate 2 _ 0.039 0.0235 0.721 gate 3 _ 0.025 0.028 0.571 Gate 4 0.0125 0.068 0.4795 Gate 5 0.015 0.093 0.85 Gate 6 0.0265 0.118 0.993 Gate 7-0.0695. 0.31 1.0835 Gate 8-0.117 0.557 1.81 Air Bago (gram) 25 psi package 1 10.420 10.860 11.610 -62- This paper size applies the National Standard (CNS) Α4 specification (2! 〇χ297 公 楚) ^ 11 ------ ^ (Please read the notes on the back before filling this page) 436422 A7 B7 5 Description of the invention (6Q) package 2 10.600 7.850 11.610 30 psi package 1 • 11.690-12.500 13.680 package 2-12.200 8.540 13.850 35 psi package 1 _ 13.490 _ 14.030 15.880 package 2 13.530 9.570 15.630 40 psi package 1 _ 14.740 _ 14.110 17.560 package 2 _ 14.860 11.010 17.610 45 psi package 1 16.180 16.390 19.830 package 2 16.680 _ 12.700 18.950 50 psi package 1 layer 17.510 1 9.280 22.410 Barrel 2 _ 17.730 14.000 20.310 55 psi Barrel 1 19.570 _ 23.350 29.35 &amp; Barrel 2-19.660-20.250 26.580 Although the test results shown in Table 6 show that the sample E-Η of the present invention generally has higher abrasion resistance than the comparative sample It is believed that these results are not conclusive, as it is believed that the polyethylene emulsion composition of the comparative sample (not included in sample E-Η) imparted yarn abrasion properties. From the foregoing, it can be seen that the present invention provides a laminate having good bending strength and modulus, and a coefficient of thermal expansion in the Z-direction, as well as other desirable advantages, which can be used in a wide range of applications such as strengthening printed circuit boards. Those skilled in the art will understand that various changes can be made to the above specific examples without departing from the theory of the present invention. Therefore, it should be understood that the present invention is not limited to the specific specific examples disclosed, but is intended to include various modifications within the spirit of the present invention and the scope defined by the scope of patent application. -63- This paper size is applicable to China National Standard (CNS) A4 (210X297mm) -------- ^ ------ IT ------% (Please read the Please fill in this page again for attention.)

Claims (1)

436 Cargoes ± A8 B8 C8 D8 Six Application Standards ... 1. A reinforced laminate for electronic support, the laminate includes: (a) a polymeric matrix material; and (b) a woven fabric including Contains coated parts that are compatible with the polymer matrix material; coated; coated glass fiber yarns that have a weight loss of combustion of &lt; 0.6% by weight and a drag force greater than one gram by air jet. ]! 〇〇〇, 〇〇〇 Graf force, using the needle needle air jet nozzle with a straight back 2 mm needle needle; and a nozzle with a length of 20 spirits, such as the dream line feed rate of 74 cents per minute Meters continued for 0 yards> L3 10 Shibaska! ^ &lt; 45 pounds per square inch) under cold air pressure •. · * · 'wherein the bending of the laminate in the fabric filling direction ^ flexural strength is greater than 4; per square meter &quot; i · m 3 X 107 kg () ^ 42.7 kpsi). 2_ The reinforced laminate according to item 1 of the patent application scope, wherein the polymeric matrix material includes at least one material selected from the group consisting of a thermosetting matrix material and a thermoplastic matrix material. 3. The reinforced laminate according to item 2 of the scope of patent application, wherein the polymer matrix material includes a group selected from the group consisting of thermosetting polyester, vinyl ester, epoxide, phenols, amine-based plastics, thermosetting polyurethane and mixtures thereof At least one of a group of thermosetting matrix materials. 4. The reinforced laminate according to claim 3, wherein the thermosetting matrix material includes an epoxide. 5. The reinforced laminate according to item 2 of the scope of the patent application, wherein the polymeric matrix material comprises a material selected from the group consisting of polyolefin, polyimide, polyurethane plastic 'thermoplastic polyester, vinyl polymer, polyimide, polyimide Ether, Polyphenylsulfone, Polytestosterone 'Polyethenyl Oxide, Polyphenylene Sulfide, Polyacetal, Polycarbonate-64 Taiji Paper Standards 闳 珀 + Pupakura Power Station i fMS, A4 report it f 210 ^ 007 镎, ^^ 1--n in-— In 1 ^ 1 n 1 ^ 1 ^^^ 1 J, va (please read the precautions on the back before filling this page) Ministry of Economic Affairs Central Standard Printed by the Bureau I Industrial Consumer Cooperative 436422 A & BS C8 D8 VI. Patent application scope At least one thermoplastic matrix material for the group of esters and their mixtures. 6. The reinforced laminate according to item 1 of the scope of the patent application, wherein at least one glass fiber is selected from E · glass fiber, D · glass fiber, s-glass fiber, Q-glass fiber, E-glass fiber derivative and The group of its combination. 7. The reinforced laminate according to item 6 of the application, wherein at least one glass fiber is E-glass fiber. 8 'The reinforced laminate according to item 6 of the scope of the patent application, wherein at least one of the glass fibers is an E-glass fiber derivative. 9. The reinforced laminate according to the scope of the patent application, wherein the coating on the glass-breaking fibers of the fabric includes inorganic solid lubricant particles. 10. The reinforced laminate according to item 9 of the scope of patent application, wherein the solid lubricant particles of the coating have a layered structure. M 11. The reinforced laminate according to item 9 of the scope of the patent application, wherein the inorganic solid lubricant particles include at least one selected from the group of non-hydratable inorganic solid lubricant particles, hydratable inorganic solid lubricant particles, and mixtures thereof. One particle. / A 12. According to the reinforced laminate of the scope of application for patent, the solid particles of the non-water soluble human machine include the selected from graphite, boron nitride, and gold P., sentence one-* ^ 丨 1 &gt; It belongs to the group of grains printed by employees' cooperatives, cadmium iodide, silver sulfide, and mixtures of them. Ruler to seed 13. Strengthening laminate according to item 12 of the scope of the patent application, where the solid lubricant particles of the classic machine include six-sided green crystalline structure nitrogen: water 0 14. Strengthening according to item 12 of the patent scope Laminates, solid lubricant particles of the machine include selected from molybdenum disulfide, diselenide Z hydration --- ~ ___-65-this record from Le) ------- 436422 ABCD At least one metal dichalcogenide printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, 15. 15. According to the scope of patent application No. 1 The reinforced laminate of 1 item, wherein the non-water-soluble inorganic solid lubricant particles include a group selected from the group consisting of indium, osmium, tin, copper, gold, silver, calcium carbonate, calcium fluoride, zinc oxide, and mixtures thereof At least one particle. 16. The reinforced laminate according to patent application No. I1, wherein the hydratable inorganic solid lubricant particles include phyllosilicate. 17. The reinforced laminate according to item 16 of the scope of patent application, wherein the fossilate includes at least one kind of phyllosilicate selected from the group consisting of mica, talc, gypsum, kaolin, montmorillonite and mixtures thereof. 18. The reinforced laminate according to item 11 of the scope of the patent application, wherein the hardness value of the inorganic solid lubricant particles is less than or equal to the hardness value of E-glass fiber. 19. The reinforced laminate according to item 1 of the patent application park, wherein the coating on the fabric glass fiber includes a film-forming polymer. 20. The reinforced laminate according to Item 1 of the applied patent, wherein at least one glass fiber is a fiberizable material selected from the group consisting of non-glass inorganic materials, 'natural materials, organic polymer materials, and combinations thereof. _ 21. Reinforced laminate I: according to item 1 of the scope of the patent application, where the flexural strength of the laminate in the fabric filling direction is greater than ## 9 x 107 kg per square (# 70kpsi). Ming: 22. — A reinforcing layer preparation for an electronic support, the laminate comprising: (a) a polymeric matrix material; and (b) a woven fabric reinforced fabric including a material containing a polymer matrix material ( Please read the precautions on the reverse side before filling out this page) 订 _Order '66-This paper size applies to Chinese national standards (CNS &gt; 8 4 grids (21 ^ 297 public _______ 436422 A8 B8 C8 DA Ministry of Economy · Printed by the Consumer Standards Cooperative of the Central Bureau of Standards 6. The patent-applied Fan Guorong's coating is at least partially coated with glass fiber yarn, the coating includes (1) polyester; and (2) at least one polymer selected from vinylpyrrolidone polymerization Polymer, vinyl alcohol polymer, and starch group polymer β 23. The reinforced laminate according to item 22 of the application, wherein the polymer matrix material includes at least one group selected from the group consisting of thermosetting matrix material and thermoplastic matrix material. 24. A reinforced laminate according to item 23 of the scope of the patent application, wherein the polymeric matrix material comprises a material selected from the group consisting of thermosetting polymers, ethylene esters, epoxides, polymers, amine-based plastics, thermosetting polyurethanes, and its At least one type of thermosetting matrix material of the group of compounds "25. The reinforcing laminate according to item 24 of the patent application park, wherein the thermosetting matrix material includes an epoxide. 26. The reinforcing layer according to item 23 of the scope of the patent application Polymer, wherein the polymeric matrix material comprises a material selected from the group consisting of polyolefins, polyamides, thermoplastic polyurethanes, thermoplastic polyesters, ethylene polymers, polyimines, polyethers, polybenzenes, polystyrene At least one thermoplastic matrix material of the group consisting of polyethylene oxide, polystyrene sulfide, polyethylene acryl, polyhexyl ester and mixtures thereof. 27_ Reinforced laminate according to item 22 of the scope of patent application, At least one of the glass-breaking fibers is selected from the group consisting of E-glass fiber, D-glass fiber, S-glass fiber, Q-glass fiber 'E-glass fiber derivative, and combinations thereof. 28. According to the scope of the patent application The strong 1 d laminate of item 27, at least one kind of glass fiber of which is E-glass fiber. 29. According to the reinforced laminate of item 27 of the scope of patent application, at least one of the -67- winter paper scales is applicable to China Kneading (CNS) A4 (210X297 mm) (Please read the notes on the back before filling out this page) -s T 436422 VI. Application for Patent Scope The Ministry of Economic Affairs Order Central Standard Bureau Employees' Consumer Cooperatives Coil glass fiber is E-glass fiber derivative. 30 The coating on glass fiber reinforced laminate according to the patent application No. 22 includes inorganic solid lubricant particles 31. According to the reinforced laminate of the patent application No. 30, the organic solid lubricant particles are layered Structure 32. According to the reinforced laminate of item 30 of the scope of patent application, the lubricant particles include one selected from the group consisting of non-hydratable inorganic solid lubricants: hydratable inorganic solid lubricant particles and mixtures thereof. Kinds of particles. Ruler V — 33. The reinforced laminate according to item 32 of the scope of the patent application, wherein the non-hydratable inorganic solid particles include a material selected from the group consisting of graphite ... boron nitride, metal dichalcogenide, sulphurized compounds, silver sulfide At least one particle of a group of a mixture. Article 34. The reinforced laminate according to item 33 of the patent application park, wherein the non-hydratable inorganic solid lubricant particles include hexahedral crystal structure nitrided side particles. 35. The reinforced laminate according to item 33 of the patent application park, wherein the non-hydratable inorganic solid lubricant particles include a member selected from the group consisting of molybdenum disulfide, molybdenum diselenide, light disulfide, dinitrium, and dissolve tungsten , At least one metal dichalcogenide of the group consisting of Erhan Huayan and mixtures thereof. 36. The reinforced laminate according to item 32 of the scope of the patent application, wherein the non-hydratable inorganic solid lubricant particles include selected from the group consisting of indium, snake, tin, copper, zinc, gold and silver carbonate, fluoride fluoride, oxygen zinc and At least one particle of a group of mixtures thereof. 37. Reinforced laminate according to item 32 of the patent application, which can hydrate non-woven fabrics, non-woven fabrics, non-inorganic solid binding papers Λ36422 A8 B8 C8 D8 Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 6. The scope of the patent application. The solid lubricant particles of the machine include phyllosilicate β 38. The reinforced laminate according to item 37 of the scope of the patent application, wherein the phytosilicate includes a compound selected from mica, talc, gypsum, kaolin, montmorillonite At least one type of phyllosilicate in the group of soil and mixtures thereof. 39. The reinforced laminate according to item 30 of the scope of the patent application, wherein the hardness value of the inorganic solid lubricant particles is less than or equal to the hardness value of E_glass fiber. 40. The reinforced laminate according to item 22 of the patent application, wherein the coating on the glass fiber comprises a film-forming polymer. 41. The reinforced laminate according to item 22 of the scope of patent application, wherein at least one glass fiber is a fiber-resilient material selected from the group consisting of non-glass inorganic materials, natural materials, organic polymer materials, and combinations thereof. 42. The reinforced laminate according to item 22 of the application_ 申请 range, wherein the burning loss of the yarn is from &lt; 0.01 to · 0.6% by weight and the drag force of the air jet conveying is greater than f 1 per gram of yarn 〇〇〇〇〇 克 force, is using a 2mm diameter inner air injection chamber and 20 nozzles. Needle-shaped air jets of weeping nozzles obstruct the sound element, which is difficult to reach 74 meters (000 yards) per minute. The yarn feed rate and air pressure at 10 仟 Baska (me square inch% 45 pounds) gauge pressure were evaluated. Qin / 43. The reinforced laminate according to item 22 of the scope of patent application, in which the bending strength of the laminated inspection fabric is greater than the filling strength per square meter (<3 X 107 mm / 42.7 kpsi) «iMif! 44. A Reinforced laminates for use in electronic supports, the laminates comprising: (a) a polymeric matrix material; and (b) a woven reinforced fabric 'which includes Applicable to China National Sample Rate (CNS) (2 丨 〇 &gt; &297; first read the note on the back and then fill out this page) Order ABCD 436 ^^ 2 6. The patent application scope covers at least partially coated glass Yarn of fibers, the coating comprising (1) polyester; and (2) vinylpyrrolidone polymer. H -1 I II III II----- -II I. {Please read the precautions on the back before filling out this page) 45. According to the reinforced laminate of item 4 of the scope of patent application, at least one kind of glass The fiber is selected from the group consisting of E-glass fiber, d-glass fiber, S-glass fiber, Q-glass fiber, E-glass fiber derivative, and a group thereof. 46. An electronic circuit board, including: (a) a laminate for an electronic support, including: (i weaving: cloth strong # release%, glass fiber-containing yarn, the yarn's burning weight loss from _ &lt; Q [〇l 盖 ^) _ 6% by weight and the drag force of the air jet conveyance is greater than 100, -00 gram force per gram of quality neat paper, using an internal air jet with a diameter of 2 mm. Needle-less air jet nozzles are single and have a length of 20 cm _ mouth outlet pipe at _ feed rate # 274 m yards per minute extinguished -10 仟 Baska ('^ square inch 45 pounds) gauge air The professional sweat evaluator 'in which the bending strength of the laminate in the direction of fabric filling is% &lt; 3 X 107 kg per square meter (&lt; 42.7 kpsi); (ii) coated on at least part of the fabric-layer polymerization Matrix materials; and consumption of employees of the Central Bureau of Standards of the Ministry of Economic Affairs. &Quot;?-(B) Conductive layer adjacent to the selected part of the laminated side. 47 'The electronic circuit board according to item 46 of the scope of patent application, wherein at least one glass fiber is selected from the group consisting of E-glass fiber, D-glass fiber, and S_glass fiber' Q-glass fiber 'E-glass fiber derivative And its group of groups 6 48. According to the 46th electronic circuit board of the scope of application for patents, it also covers the extension -70-This paper size applies the Chinese National Standard (CNS) A4 standard (21〇 × 297) (B) ABCD d36A22 6. The scope of patent application passes through at least one perforation of at least part of the circuit board. »^ P ^^^^ 1--^^ — ^ 1 1 ^ 1 ^ 1 —flu Inf I. {Please read the precautions on the back before filling this page) 49. Electronic circuit according to item 46 of the scope of patent application Board, where the circuit board is the first 'second or third heavy packaging. 50. An electronic circuit board comprising: (a) a laminate for an electronic support, including: (i) a woven fabric, including a yarn containing at least a portion of glass fiber coated with a coating, the coating including (1) polyester; and (2) at least one polymer selected from the group consisting of ethynylpyrrolidone polymer, vinyl alcohol polymer, and starch; and (ii) coated on at least part of the fabric A layer of polymeric matrix material; and (b) a conductive layer adjacent to a selected portion of the selected side of the laminate. 51. The electronic circuit board according to item 50 of the scope of patent application, wherein at least one glass fiber is selected from E_glass fiber, D-glass fiber, s-glass fiber, Q-glass fiber, E-glass fiber derivative and The group's group. 52. The electronic circuit board according to item 50 of the patent application scope further includes at least one perforation extending through at least part of the circuit board. Printed by the Central Laboratories of the Ministry of Economic Affairs and Consumer Cooperatives 53. According to the electronic circuit board of the 50th patent application scope, the circuit board is the first, second or third heavy packaging. 54. — An electronic circuit board comprising: (a) a laminate of electronic alternatives, including: ⑴ first — _ 'including ^ _ (1) weaving association 1 package' includes yarns containing glass fibers, the yarns The burning weight loss of the wire is from [纟 0.01 to # 〇6% by weight and the drag force of air jet conveyance :: 士 Γ &lt; ___- 71-This paper size applies to China National Standard (CNS) A4 specification (210X297) by 4364 ^ 2 588 .C8 -----—________ D8 6. Application for patent application ^ '' ~~. _ Greater than # 1〇〇, 〇〇〇 克 force per gram of quality yarn, using an axe, diameter 2 milliseconds · needle Shaped air nozzle with nozzle, ¥ 2 〇A knife nozzle out of the π tube at a feed rate of 5 lines per minute Fengshan each meter 3 () 〇iR ^ ―0 Shibaska_ ^ square leaf 45 empty Air pressure critics, in which the laminate has a bending degree greater than 3 x 107 kilograms per square meter per square meter at the filling point; and (2) one layer coated on at least part of the food Polymeric matrix material: and (ii) a second composite layer different from the first composite layer; and (b) a conductive layer β adjacent to a selected portion of the laminated side of the laminate. The electric circuit board of item 4, wherein at least one glass fiber is selected from the group consisting of E-glass fiber, D-glass fiber, S-glass fiber, Q-glass fiber, E-glass fiber derivative and its group. By. 56_ The electronic circuit board according to item 54 of the scope of patent application, further comprising at least one perforation extending through at least part of the circuit board. 57. An electronic circuit board according to item 54 of the scope of patent application, wherein the circuit board is a first, second, or third heavy packaging. 58 · —An electronic circuit board, including: (a) a laminate for electronic gifts, including: (i) a first composite layer, including: (1) a woven fabric, including—at least partially coated with a coating Yarn covered with glass fiber, the coating comprises (A) polyester; and (B) at least one selected from the group consisting of ethylpyrrolidone polymer, vinyl alcohol polymer, and starch -72- This paper is applicable to China Standards (CNS) 8 (4) (210〆297 directors) (please read the precautions on the back before filling out this page) ^ I. I. The Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, Yin Ben 436422 —- '' Scope of Patent Application 8 888 ABCD Polymers of the Neem Group of the Consumer Cooperative of the Central Luzhun Bureau of the Ministry of Economic Affairs; and (2) a layer of a polymeric matrix material coated on at least part of the fabric; and (H) a different layer from the first composite layer Two composite layers; and (b) a conductive layer adjacent to a selected portion of the selected side of the laminate. The electronic circuit board according to Item 58 of the scope of patent application, wherein at least one kind of diglass fiber is selected from E-glass fiber, D · glass fiber, s_glass fiber, Q · glass fiber, E-glass fiber derivative and Group of people. 60. Electricity to the circuit board according to item 58 of the scope of the patent application. At least one __ perforation through at least part of the circuit board. 61. Electric circuit board according to item 58 of the scope of patent application. First, second or third repacking. 62 · ~ copper-clad reinforced laminates for electronic supports, the U) polymer matrix material; and (b) —or multi-layer woven reinforced fabrics, each layer comprising Coated with at least partially coated glass fiber, compatible with g matrix materials, where the thermal expansion coefficient of the laminate at the temperature of 288; ζ · direction is small _ 〖. 5%. 63. According to the lamination of the Weng Shao item in the scope of the patent application: the thermal% expansion coefficient of the laminate in n in the Z-direction at the Ms t temperature is &lt; i to Shuang 4.5%. • The layer [compound according to item 62 of the scope of the patent application, wherein at least one glass fiber is selected from E-glass fiber, D-glass fiber, S-glass fiber broken glass fiber, E-glass fiber derivative and its Group of people. It also includes the extension pass, where the circuit board is I n n n n-I-τ-$ Heavy Q- -73- This paper size adopts Chinese National Standard (CNS) M Regulation K 210 X 297 mm 43 64 22 A8 B8 CS D8 Patent Application Fanyuan Ministry of Economic Affairs Central Government Standards Bureau Employees Consumer Cooperatives Stamp 65. According to The laminate of the scope of application for item 62 also includes at least one perforation extending through at least part of the circuit board. 66. The laminate according to item 62 of the patent application, wherein the circuit board is the first, second or third repack. 67. The laminate according to item 62 of the application, wherein the laminate includes 8 stacks of 7628-type woven fabrics. 68. A method for assembling fabrics, wherein the first yarn and the second yarn are alternately woven to form a fabric, wherein the improvement includes that the first yarn is at least partially coated with a coating compatible with the polymer matrix material Glass fiber, the coating comprises (1) polyester; and (2) at least one polymer selected from the group consisting of vinylpyrrolidone polymer, vinyl alcohol polymer, and starch. 69. The method according to item 68 of the scope of patent application, wherein at least one glass fiber is selected from the group consisting of E-glass fiber, D-glass fiber, s-glass fiber 'Q-glass fiber', E-glass fiber derivative and group thereof Group of people. 70. A method of forming a laminate of a woven fabric and a polymeric matrix material, comprising coating the woven fabric with at least a portion of the polymeric matrix material to form a coated fabric, and applying heat to the coated fabric. Including yarns containing glass fiber, the improvements include: at least part of the glass fiber is coated with a polymer-based compatible coating, the yarn has a weight loss from ^ {| .01 to · ^^% by weight and air The spraying drag force is greater than the mass per gram. The amount | yarn gram force is the use of two needle-shaped air spray nozzles with an internal race gas spray of ϋ diameter meters—: ¾ Fortunately, 20 male nozzle outlet pipe »feed rate per minute , 274 meters (and. Yards) k _ 1 〇 仟 Baska (Ao Bei square pay 4 5 pieces) Exempt: ·: -74 This paper uses the national standard (CNS) A4 specification (2 丨 〇χ: 297 public epidemic) (Please read the precautions on the back before filling out this page) Pack-• 1T A8 08 C8 DS 43 6A22 ---- The air pressure evaluator of the gauge pressure of the patent application range, in which the laminated fabric has a large bending strength of 3 x 107 kg in the direction of filling (see M · 7 kpsi). 71. According to The method for applying for a patent item, in which at least one glass fiber is selected from the group consisting of E-broken 3¾-dimensional, D-glass fiber, six glass fiber, Q · glass fiber, E-glass fiber derivative and groups 72. — A method of forming a laminate of a woven fabric and a polymeric matrix material, comprising at least partially coating the woven fabric with the polymeric matrix material to form a coated fabric, and applying heat to the coated fabric. Cloth fabrics include yarns containing glass fibers, where improvements include: the glass fibers are at least partially coated with a coating compatible with the polymeric matrix material; the coating includes (1) polyester; k and (2) at least one Selected from the group consisting of vinylpyrrolidone polymer, acetohydrin polymer and starch 73. The method according to item 72 of the scope of the patent application, wherein at least one glass fiber is selected from the group consisting of E · glass fiber, D-glass fiber, glass fiber, glass fiber, and E-glass fiber. Derivatives and their groups. Please read the note on the back! Order printed by the Central Standards Bureau of the Ministry of Economic Affairs-Industrial and Consumer Cooperatives. Mm)