CN105517325B - The metal-clad structure of printed circuit board - Google Patents

The metal-clad structure of printed circuit board Download PDF

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Publication number
CN105517325B
CN105517325B CN201510862535.4A CN201510862535A CN105517325B CN 105517325 B CN105517325 B CN 105517325B CN 201510862535 A CN201510862535 A CN 201510862535A CN 105517325 B CN105517325 B CN 105517325B
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CN
China
Prior art keywords
metal
coat
fabric
circuit board
printed circuit
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Expired - Fee Related
Application number
CN201510862535.4A
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Chinese (zh)
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CN105517325A (en
Inventor
卢美珍
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Foshan Shunde Gaoxin Electronic Industry Co ltd
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Individual
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Priority to CN201510862535.4A priority Critical patent/CN105517325B/en
Publication of CN105517325A publication Critical patent/CN105517325A/en
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Publication of CN105517325B publication Critical patent/CN105517325B/en
Expired - Fee Related legal-status Critical Current
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Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/0296Conductive pattern lay-out details not covered by sub groups H05K1/02 - H05K1/0295
    • H05K1/0298Multilayer circuits
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55Epoxy resins
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/03Conductive materials
    • H05K2201/0332Structure of the conductor
    • H05K2201/0335Layered conductors or foils
    • H05K2201/0338Layered conductor, e.g. layered metal substrate, layered finish layer or layered thin film adhesion layer

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Laminated Bodies (AREA)
  • Parts Printed On Printed Circuit Boards (AREA)
  • Structure Of Printed Boards (AREA)
  • Production Of Multi-Layered Print Wiring Board (AREA)

Abstract

The invention discloses a kind of metal-clad structures of printed circuit board, including:First coat of metal, to be 5~6 μm containing copper 35~40%, tin 20~25%, the alloy that remaining is lead, and the thickness of first coat of metal;Second coat of metal, to be 5~15 μm containing copper 40~50%, silver 5~25%, the alloy that remaining is tin, and the thickness of first coat of metal;Wherein, second coat of metal is located at most inner side, and first coat of metal is located at outermost;Wherein, further include fabric, most middle part, second coat of metal for being located at printed circuit board are covered in fabric;Fabric is to be constituted immersed with the fabric of resin combination, and fabric has double-layer cavity structure comprising upper fabric surface and lower fabric surface, with 2~3 μm of gap between two fabric surfaces.The present invention has better installation, the advantageous effect of the connection reliability of each sublayer structure and etching performance.

Description

The metal-clad structure of printed circuit board
Technical field
The present invention relates to printed-board technology fields.It is more particularly related to which a kind of printed circuit board covers Metal stacking harden structure.
Background technology
Printed circuit board (PCB circuit board), also known as printed circuit board are the suppliers of electronic component electrical connection.It Development have more than 100 years history;Its design is mainly layout design;Major advantage using circuit board is to subtract significantly Few mistake connected up and assemble, improves the gentle productive labor rate of Automated water.
In recent years, as the printed circuit board used in a large amount of electronic equipments such as intelligent hand, tablet computer, printed circuit board It is formed by the way that conductive pattern is arranged on metal-clad, wherein the important component metal-clad of printed circuit board Infiltration is typically impregnated by resin combination and forms prepreg in fabric substrate, by the way that metal foil is laminated on the prepreg of formation It is fabricated, in order to which printed circuit board upper conductor pattern is preferably fitted closely with metal-clad, metal-clad knot The connection of the installation of sublayer structure, insulating properties and each sublayer structure is reliable in the etching performance of structure, metal-clad Property become it is particularly important.
Invention content
It is an object of the invention to solve at least the above and/or defect, and provide at least one will be described later The advantages of.
It is folded that it is a still further object of the present invention to provide a kind of metal-clads of the printed circuit board with more preferable etching performance The surface of harden structure, outermost metal coating is sprayed with tin layers, avoids copper face from being easy oxidation, improves the solderability of circuit board.
It is a still further object of the present invention to provide a kind of metal-clads of the printed circuit board with better insulation performance Laminate structure, since fabric has double-layer cavity structure comprising upper fabric surface and lower fabric surface, two fabric tables With 2~3 μm of gap between face, the insulation performance between the metallic plate of the fabric both sides is improved.
In order to realize these purposes and other advantages according to the present invention, the present invention provides a kind of covering for printed circuit board Metal stacking harden structure, including:
First coat of metal, for containing copper 35~40%, tin 20~25%, the alloy that remaining is lead, and described first The thickness of the coat of metal is 5~6 μm;
Second coat of metal, to contain copper 40~50%, silver 5~25%, the alloy that remaining is tin, and second gold medal The thickness for belonging to coating is 5~15 μm;
Wherein, second coat of metal is located at most inner side, and first coat of metal is located at outermost;
Wherein, further include fabric, be located at the most middle part of the printed circuit board, second coat of metal covering In the fabric;
The fabric is the fabric composition immersed with resin combination, and the fabric has double-layer cavity knot Structure comprising go up fabric surface and lower fabric surface, there is 2~3 μm of gap between two fabric surfaces.
Preferably, wherein further include the third coat of metal, for containing copper 45~55%, gold 5~10%, remaining be The alloy of lead, and the thickness of the third coat of metal is 6~8 μm, the third coat of metal is covered in second metal On coating surface.
Preferably, wherein first coat of metal, for containing copper 36~38%, tin 21~23%, remaining be lead Alloy, and the thickness of first coat of metal be 5~6 μm.
Preferably, wherein second coat of metal, for containing copper 42~48%, silver 10~20%, remaining be tin Alloy, and the thickness of second coat of metal be 8~12 μm.
Preferably, wherein first coat of metal, for containing copper 37%, tin 22%, the alloy that remaining is lead, And the thickness of first coat of metal is 6 μm.
Preferably, wherein second coat of metal, for containing copper 45%, silver 15%, the alloy that remaining is tin, And the thickness of second coat of metal is 10 μm.
Preferably, wherein the third coat of metal, for containing copper 48~52%, gold 6~8%, remaining be lead Alloy, and the thickness of the third coat of metal is 6~8 μm, the third coat of metal is covered in second coat of metal On surface.
Preferably, wherein the third coat of metal, for containing copper 50%, gold 7%, the alloy that remaining is lead, and The thickness of the third coat of metal is 6 μm, and the third coat of metal is covered on second metal coating surface.
Preferably, wherein the resin combination is epoxy resin and acrylic rubber with naphthalene type skeleton.
The present invention includes at least following advantageous effect:
1, its surface of the metal layer of the metal-clad structure setting of printed circuit board provided by the invention is sprayed Tin, avoiding copper face from being easy oxidation causes to be not easy upper tin, and the metal-clad that circuit board is improved by layer on surface of metal spray tin is folded The solderability of plate;
2, the metal-clad structure of printed circuit board provided by the invention, since fabric has double-layer cavity knot Structure improves the insulation performance between the metallic plate of the fabric both sides;
3, the metal-clad structure of printed circuit board provided by the invention, due in fabric both sides in both sides shape At different thickness of coating, to facilitate the semiconductor original paper of selection installation different performance;
4, the metal-clad structure of printed circuit board provided by the invention, since fabric includes upper fabric surface With lower fabric surface, with 2~3 μm of gap between two fabric surfaces, while ensureing insulating properties, it may have centainly Elasticity can facilitate plating operation;
5, the metal-clad structure of printed circuit board provided by the invention, since fabric is immersed with resin group The fabric for closing object is constituted, and containing the epoxy resin with naphthalene type skeleton in the resin combination, printed circuit board can be improved Heat resistance.
Description of the drawings
Fig. 1 is that the structure of the cross section of the metal-clad structure of printed circuit board in one embodiment of the present of invention is shown It is intended to;
Fig. 2 is the upper fabric surface of the metal-clad board structure of printed circuit board in one embodiment of the present of invention under The structural schematic diagram of fabric surface.
Specific implementation mode
Present invention will be described in further detail below with reference to the accompanying drawings, to enable those skilled in the art with reference to specification text Word can be implemented according to this.
In order to realize these purposes and other advantages according to the present invention,
Such as Fig. 1 and Fig. 2 shows a kind of metal-clad structures of printed circuit board of the present invention, including:
First coat of metal 4, for containing copper 35~40%, tin 20~25%, the alloy that remaining is lead, and described first The thickness of the coat of metal 4 is 5~6 μm;
Second coat of metal 2, for containing copper 40~50%, silver 5~25%, the alloy that remaining is tin, and described second The thickness of the coat of metal 2 is 5~15 μm;
Wherein, second coat of metal 2 is located at most inner side, and first coat of metal 4 is located at outermost;
Wherein, further include fabric 1, most middle part, second coat of metal 2 for being located at the printed circuit board cover It covers in the fabric 1;
The fabric 1 is the fabric composition immersed with resin combination, and the fabric 1 has double-layer cavity knot Structure comprising go up fabric surface and lower fabric surface 100, there is 2~3 μm of gap between two fabric surfaces.
Wherein, since the fabric 1 has double-layer cavity structure, 1 both sides metallic plate of the fabric is improved Between insulation performance;The fabric 1 includes upper fabric surface and lower fabric surface 100, is had between two fabric surfaces The gap for having 2~3 μm, while ensureing insulating properties, it may have certain elasticity can facilitate plating operation;
In wherein a kind of embodiment, for fabric, be not particularly limited, as long as with warp thread as such as plain weave and The material that the substantially orthogonal mode of weft yarn is made into can use such as material made of inorfil, such as glass cloth or the like Material, or the material made of organic fiber, such as aromatic polyamides cloth or the like material, the thickness of fabric is preferred 210~300 μm.
Further include the third coat of metal 3 in wherein a kind of embodiment, for containing copper 45~55%, gold 5~10%, Remaining is the alloy of lead, and the thickness of the third coat of metal 3 is 6~8 μm, and the third coat of metal 3 is covered in described On the surface of second coat of metal 2.
Wherein, the third coat of metal 3 preferably comprises copper 48~52%, gold 6~8%, the alloy that remaining is lead, and The thickness of the third coat of metal 3 is 6~8 μm;Further preferably copper 50%, gold 7%, the alloy that remaining is lead, and it is described The thickness of the third coat of metal 3 is 6 μm.
In another embodiment, first coat of metal 4 preferably containing copper 36~38%, tin 21~23%, its The remaining alloy for lead, and the thickness of first coat of metal 4 is 5~6 μm;More preferably contain copper 37%, tin 22%, its The remaining alloy for lead, and the thickness of first coat of metal is 6 μm.
In another embodiment, second coat of metal 2 preferably containing copper 42~48%, silver 10~20%, its The remaining alloy for tin, and the thickness of second coat of metal 2 is 8~12 μm;More preferably contain copper 45%, silver 15%, Remaining is the alloy of tin, and the thickness of two coat of metal 2 is 10 μm.
In another embodiment, the resin combination is epoxy resin and acrylic rubber with naphthalene type skeleton. Also, this mode is a kind of explanation of preferred embodiments, and however, it is not limited to this.It in carrying out the present invention, can be according to making The performance of user's demand fabric is different and selects different state sample implementations.
Wherein, the epoxy resin with naphthalene type skeleton can be a kind of or a variety of, can be with naphthalene type skeleton Epoxy resin with without naphthalene type skeleton epoxy resin composition, or individually with naphthalene type skeleton epoxy The combination of resin, still, wherein must it is at least one be the epoxy resin with naphthalene type skeleton, to improve printed circuit board The heat resistance of metal-clad structure, such as printed circuit board are mounted on the heat resistance in electronic product, or in circuit board The upper heat resistance for carrying out scolding tin increases the service life of printed circuit board and uses sensitivity.
Wherein, do not have unsaturated bond as such as double bond, three keys, carbon in the ingredient of acrylic rubber between carbon atom It is bonded by singly-bound between atom, avoids that there is unsaturated bond to be easy oxidation and make the metal-clad of printed circuit board folded Harden structure follows the string and becomes fragile, and influences the respective performances of printed circuit board.
As described above, according to the present invention, since fabric has double-layer cavity structure, the fabric two is improved Insulation performance between the metallic plate of side;Fabric includes upper fabric surface and lower fabric surface, is had between two fabric surfaces The gap for having 2~3 μm, while ensureing insulating properties, it may have certain elasticity can facilitate plating operation;Due to fabric Base is the fabric composition immersed with resin combination, contains the epoxy resin with naphthalene type skeleton in the resin combination, The heat resistance of printed circuit board can be improved;Due to forming different thickness of coating on both sides in fabric both sides, to facilitate choosing Select the semiconductor original paper of installation different performance.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited In specific details and legend shown and described herein.

Claims (9)

1. a kind of metal-clad structure of printed circuit board, which is characterized in that including:
First coat of metal, to contain copper 35~40%, tin 20~25%, the alloy that remaining is lead, and first metal The thickness of coating is 5~6 μm;
Second coat of metal, to contain copper 40~50%, silver 5~25%, the alloy that remaining is tin, and second metal-plated The thickness of layer is 5~15 μm;
Wherein, second coat of metal is located at most inner side, and first coat of metal is located at outermost;
Wherein, further include fabric, most middle part, second coat of metal for being located at the printed circuit board are covered in institute It states in fabric;
The fabric is the fabric composition immersed with resin combination, and the fabric has double-layer cavity structure, Including upper fabric surface and lower fabric surface, there is 2~3 μm of gap between two fabric surfaces.
2. the metal-clad structure of printed circuit board as described in claim 1, which is characterized in that further include third metal Coating, to be 6 containing copper 45~55%, gold 5~10%, the alloy that remaining is lead, and the thickness of the third coat of metal ~8 μm, the third coat of metal is covered on second metal coating surface.
3. the metal-clad structure of printed circuit board as described in claim 1, which is characterized in that first metal-plated Layer, for be 5 containing copper 36~38%, tin 21~23%, the alloy that remaining is lead, and the thickness of first coat of metal~ 6μm。
4. the metal-clad structure of printed circuit board as described in claim 1, which is characterized in that second metal-plated Layer, for containing copper 42~48%, silver 10~20%, the alloy that remaining is tin, and the thickness of second coat of metal be 8~ 12μm。
5. the metal-clad structure of printed circuit board as described in claim 1, which is characterized in that first metal-plated Layer, to be 6 μm containing copper 37%, tin 22%, the alloy that remaining is lead, and the thickness of first coat of metal.
6. the metal-clad structure of printed circuit board as described in claim 1, which is characterized in that second metal-plated Layer, to be 10 μm containing copper 45%, silver 15%, the alloy that remaining is tin, and the thickness of second coat of metal.
7. the metal-clad structure of printed circuit board as claimed in claim 2, which is characterized in that the third metal-plated Layer, to be 6~8 μ containing copper 48~52%, gold 6~8%, the alloy that remaining is lead, and the thickness of the third coat of metal M, the third coat of metal are covered on second metal coating surface.
8. the metal-clad structure of printed circuit board as claimed in claim 7, which is characterized in that the third metal-plated Layer, to be 6 μm containing copper 50%, gold 7%, the alloy that remaining is lead, and the thickness of the third coat of metal, the third The coat of metal is covered on second metal coating surface.
9. the metal-clad structure of printed circuit board as described in claim 1, which is characterized in that the resin combination For epoxy resin, acrylic rubber with naphthalene type skeleton.
CN201510862535.4A 2015-11-30 2015-11-30 The metal-clad structure of printed circuit board Expired - Fee Related CN105517325B (en)

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Application Number Priority Date Filing Date Title
CN201510862535.4A CN105517325B (en) 2015-11-30 2015-11-30 The metal-clad structure of printed circuit board

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CN105517325B true CN105517325B (en) 2018-07-24

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5837624A (en) * 1995-10-16 1998-11-17 Matsushita Electric Works, Ltd. Woven glass cloth for printed wiring board and printed wiring products manufactured therefrom
WO1999044959A1 (en) * 1998-03-03 1999-09-10 Ppg Industries Ohio, Inc. Glass fiber-reinforced laminates, electronic circuit boards and methods for assembling a fabric
WO2010113892A1 (en) * 2009-03-30 2010-10-07 株式会社トクヤマ Process for producing metallized substrate and metallized substrate
CN103167731A (en) * 2011-12-08 2013-06-19 祝琼 Soft board base material without glue and preparation method thereof
CN104837622A (en) * 2012-12-06 2015-08-12 三菱瓦斯化学株式会社 Method for producing metal-foil-clad laminate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5837624A (en) * 1995-10-16 1998-11-17 Matsushita Electric Works, Ltd. Woven glass cloth for printed wiring board and printed wiring products manufactured therefrom
WO1999044959A1 (en) * 1998-03-03 1999-09-10 Ppg Industries Ohio, Inc. Glass fiber-reinforced laminates, electronic circuit boards and methods for assembling a fabric
WO2010113892A1 (en) * 2009-03-30 2010-10-07 株式会社トクヤマ Process for producing metallized substrate and metallized substrate
CN103167731A (en) * 2011-12-08 2013-06-19 祝琼 Soft board base material without glue and preparation method thereof
CN104837622A (en) * 2012-12-06 2015-08-12 三菱瓦斯化学株式会社 Method for producing metal-foil-clad laminate

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Inventor after: Lu Meizhen

Inventor after: Yi Tugui

Inventor before: Lu Meizhen

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20190524

Address after: 528305 Tianfulai International Industrial City, 33 Changbaoxi Road, Ronggui Rongli Residential Committee, Shunde District, Foshan City, Guangdong Province (Phase III), 13 Blocks, 1 Floor 101

Patentee after: Foshan Shunde Gaoxin Electronic Industry Co.,Ltd.

Address before: 536000, 8 floor, Ledu tower, West Bay Road, Beihai, the Guangxi Zhuang Autonomous Region.

Patentee before: Lu Meizhen

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180724

Termination date: 20211130