TW346493B - Supported metallocene complexes having heterofunctional groups in the cyclopentadienyl system as catalyst systems - Google Patents

Supported metallocene complexes having heterofunctional groups in the cyclopentadienyl system as catalyst systems

Info

Publication number
TW346493B
TW346493B TW084101849A TW84101849A TW346493B TW 346493 B TW346493 B TW 346493B TW 084101849 A TW084101849 A TW 084101849A TW 84101849 A TW84101849 A TW 84101849A TW 346493 B TW346493 B TW 346493B
Authority
TW
Taiwan
Prior art keywords
alkyl
group
formula
catalyst systems
supported metallocene
Prior art date
Application number
TW084101849A
Other languages
English (en)
Inventor
Langhauser Franz
Fischer David
Kerth Juergen
Schweier Gunther
Barsties Elke
Brintzinger Hans-Herbert
Schaible Stefan
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Application granted granted Critical
Publication of TW346493B publication Critical patent/TW346493B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
TW084101849A 1994-03-03 1995-02-28 Supported metallocene complexes having heterofunctional groups in the cyclopentadienyl system as catalyst systems TW346493B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4406964A DE4406964A1 (de) 1994-03-03 1994-03-03 Geträgerte Metalloxenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem als Katalysatorsysteme

Publications (1)

Publication Number Publication Date
TW346493B true TW346493B (en) 1998-12-01

Family

ID=6511704

Family Applications (1)

Application Number Title Priority Date Filing Date
TW084101849A TW346493B (en) 1994-03-03 1995-02-28 Supported metallocene complexes having heterofunctional groups in the cyclopentadienyl system as catalyst systems

Country Status (7)

Country Link
US (1) US5627246A (zh)
EP (1) EP0670336B1 (zh)
JP (1) JPH0834812A (zh)
DE (2) DE4406964A1 (zh)
ES (1) ES2100752T3 (zh)
TW (1) TW346493B (zh)
ZA (1) ZA951725B (zh)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4406963A1 (de) * 1994-03-03 1995-09-07 Basf Ag Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
RU2178421C2 (ru) * 1995-11-27 2002-01-20 Дзе Дау Кемикал Компани Катализатор на носителе, содержащий связанный активатор, образующий катион
FI961511A (fi) * 1996-04-03 1997-10-04 Mikrokemia Oy Menetelmä olefiinien polymerointikatalyyttien valmistamiseksi
ES2129323B1 (es) * 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
IT1283010B1 (it) * 1996-05-15 1998-04-03 Enichem Spa Complesso metallocenico supportato e procedimento per la sua prepa- razione
DE19622481A1 (de) * 1996-06-05 1997-12-11 Hoechst Ag Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
SK15299A3 (en) * 1996-08-08 2000-03-13 Dow Chemical Co 2-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
DE69705186T2 (de) 1996-10-30 2002-03-14 Repsol Quimica S.A., Madrid Katalysatorsysteme für die (Co)Polymerisation von Alpha-Olefinen
JP3955140B2 (ja) * 1996-10-31 2007-08-08 レプソル・ケミカ・ソシエダ・アノニマ アルフアオレフインの重合及び共重合用触媒系
US6100214A (en) * 1997-06-05 2000-08-08 Exxon Chemical Patents Inc. Polymeric supported catalysts for olefin polymerization
DE19813656A1 (de) 1998-03-27 1999-09-30 Aventis Res & Tech Gmbh & Co Übergangsmetallverbindung
ATE257490T1 (de) 1998-04-27 2004-01-15 Repsol Quimica Sa Katalysatorsysteme für die polymerisation und copolymerisation von alpha-olefinen
ES2216473T3 (es) * 1998-04-29 2004-10-16 Repsol Quimica S.A. Preparacion y uso de componentes de catalizador heterogeneos para polimerizacion de olefinas.
US6194343B1 (en) * 1999-03-11 2001-02-27 University Of Waterloo Bridged “tethered” metallocenes
US6908876B2 (en) * 2003-04-16 2005-06-21 Saudi Basic Industries Corporation Supported metallocene catalyst system for olefin polymerization, method for making and using the same

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1268754A (en) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
DE3782243T2 (de) * 1986-08-26 1993-03-04 Mitsui Petrochemical Ind Katalysator zur polymerisierung von alpha-olefin und verfahren.
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
TW300901B (zh) * 1991-08-26 1997-03-21 Hoechst Ag
DE59305691D1 (de) * 1992-05-26 1997-04-17 Hoechst Ag Verfahren zur Herstellung von Polyolefinwachsen
EP0582195B1 (de) * 1992-08-03 2000-12-20 TARGOR GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung spezieller Metallocene

Also Published As

Publication number Publication date
DE59500200D1 (de) 1997-06-05
ES2100752T3 (es) 1997-06-16
EP0670336A1 (de) 1995-09-06
DE4406964A1 (de) 1995-09-07
ZA951725B (en) 1996-09-02
US5627246A (en) 1997-05-06
EP0670336B1 (de) 1997-05-02
JPH0834812A (ja) 1996-02-06

Similar Documents

Publication Publication Date Title
TW346493B (en) Supported metallocene complexes having heterofunctional groups in the cyclopentadienyl system as catalyst systems
TW362101B (en) Catalyst systems for the polymerization of C2-C10-ALK-1-ENES
TW429265B (en) Metallocene complexes having heterofunctional groups in the cyclopentadienyl system
CA2055219A1 (en) 2-substituted bisindenylmetallocenes, process for their preparation, and their use as catalysts in the polymerization of olefins
KR920002640A (ko) 산화 활성을 갖는 부가 중합 촉매
NZ332842A (en) Catalyst compositions comprising transition metal salicylaldimine chelates
ATE200786T1 (de) Geträgerte katalysatorsysteme
ID24621A (id) Katalis polietilena aktivitas tinggi
ES2154417T3 (es) Polimeros del etileno con una elevada resistencia a la fisuracion por tensiones y un sistema catalizador para su obtencion.
DE69726821T2 (de) Katalysatorsysteme für die Polymerisation und die Copolymerisation von Alpha-Olefinen
TW363985B (en) Metallocene compound
EP0852230A4 (en) TRANSITION METAL COMPLEXES, OLEFIN POLYMERIZATION CATALYST AND PROCESS FOR PRODUCING OLEFIN POLYMERS
ATE236181T1 (de) Bimetallisches-metallocene katalysatorsystem für isotactische polypropylen-polymerisation
TH37944EX (th) ระบบตัวเร่งปฏิกิริยาสำหรับการเกิดพอลิเมอร์ของ c2-c10-แอลค์-1-อีน
TH37944A (th) ระบบตัวเร่งปฏิกิริยาสำหรับการเกิดพอลิเมอร์ของ c2-c10-แอลค์-1-อีน
PL334255A1 (en) Organoziliceous compounds containing urea groups, their production and application
NZ291855A (en) Bridged azabicyclo-piperazin-1-yl-2-phenyl-butan-1-one derivatives as 5-ht1a antagonists
TH8817EX (th) แคทาลิสท์สำหรับโพลีเมอไรเซชั่นของโอลิฟิน
TH18780A (th) สารเชิงซ้อนเมทัลลอซีนที่มีหมู่เฮเทอโรฟังก์ชันนัลในระบบไซระบบไซโคลเพนทาไดอีนิล
TW363982B (en) Catalyst composition of polystyrene or vinylaryl compounds, and the polymerization method therewith
TW335402B (en) Catalyst for olefin polymerization
TH23720A (th) เมทัลโลซีนคอมเพล็กซ์บนสารรองรับ ซึ่งมีหมู่เฮเทอโรฟังค์ชันในระบบไซโคลเพนทาไดเอนิล เพื่อเป็นระบบตัวเร่งปฎิกิริยา
TH18780B (th) สารเชิงซ้อนเมทัลลอซีนที่มีหมู่เฮเทอโรฟังก์ชันนัลในระบบไซระบบไซโคลเพนทาไดอีนิล
TH9285EX (th) สารผสมสำหรับซักฟอก