ES2154417T3 - Polimeros del etileno con una elevada resistencia a la fisuracion por tensiones y un sistema catalizador para su obtencion. - Google Patents

Polimeros del etileno con una elevada resistencia a la fisuracion por tensiones y un sistema catalizador para su obtencion.

Info

Publication number
ES2154417T3
ES2154417T3 ES96927701T ES96927701T ES2154417T3 ES 2154417 T3 ES2154417 T3 ES 2154417T3 ES 96927701 T ES96927701 T ES 96927701T ES 96927701 T ES96927701 T ES 96927701T ES 2154417 T3 ES2154417 T3 ES 2154417T3
Authority
ES
Spain
Prior art keywords
alkyl
aryl
hydrogen
groups
catalyst system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96927701T
Other languages
English (en)
Inventor
Wolfgang Rohde
Roland Saive
Dieter Lilge
Martin Lux
Peter Bauer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7770039&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2154417(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2154417T3 publication Critical patent/ES2154417T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61904—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with another component of C08F4/60
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61925—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

POLIMERO DE ETILENO QUE SE PUEDE OBTENER POR POLIMERIZACION DE ETILENO Y OPCIONALMENTE OTROS COMONOMEROS EN PRESENCIA DE UN SISTEMA CATALIZADOR QUE CONTIENE COMO COMPONENTES ACTIVOS I) UN CATALIZADOR PHILLIPS, II) UN SOLIDO DISTINTO DE I), QUE CONTIENE UN COMPONENTE, QUE DERIVA DE COMPLEJOS DE METALOCENO DE FORMULA GENERAL (A), EN LA CUAL LOS SUSTITUYENTES E INDICES TIENEN EL SIGUIENTE SIGNIFICADO: R SUP,1} A R SUP,10} SON HIDROGENO, ALQUILO C SUB,1} A C SUB,10}, CICLOALQUILO DE 5 A 7 ESLABONES, QUE A SU VEZ PUEDE LLEVAR GRUPOS ALQUILO C SUB,1} A C SUB,6} COMO SUSTITUYENTES, ARILO C SUB,6} A C SUB,15} O ARILALQUILO Y DONDE OPCIONALMENTE TAMBIEN 2 RESTOS ADYACENTES PUEDEN SER JUNTOS GRUPOS CICLICOS QUE PRESENTAN ENTRE 4 Y 15 ATOMOS DE C O SI(R SUP,11}) SUB,3} SIENDO R SUP,11} ALQUILO C SUB,1} A C SUB,10}, ARILO C SUB,6} A C SUB,15} O CICLOALQUILO C SUB,3} A C SUB,10}, O DONDE LOS RESTOS R SUB,4} Y R SUB,9} FORMAN JUNTOS UN GRUPO -[Y(R SUP,12}R SUP,13}] SUB,M}-, SIENDO Y SILICIO, GERMANIO, ZINC O CARBONO, R SUP,12} Y R SUP,13} SON HIDROGENO, ALQUILO C SUB,1} A C SUB,10}, CICLOALQUILO C SUB,3} A C SUB,10} O ARILO C SUB,6} A C SUB,15}, M ES UN METAL DEL GRUPO DE TRANSICION IV A VIII O UN METAL DE LA SERIE DE LOS LANTANIDOS, Z SUP,1} Y Z SUP,2} ES FLUOR, CLORO, BROMO, YODO, HIDROGENO, UN RESTO ALQUILO C SUB,1} A C SUB,20} O UN RESTO ARILO, -OR SUP,14}, -OOCR SUP,14}, (A), (B) O (C), SIENDO R SUP,14} HIDROGENO O ALQUILO C SUP,1} A C SUP,20}, R SUP,15} ES ALQUILO C SUB,1} A C SUB,20}, M ES 1, 2, 3 O 4, N ES 0, 1 O 2, R ES 0, 1 O 2, DONDE LA SUMA DE N + R ES ASIMISMO 0, 1 O 2 Y OPCIONALMENTE III) ES UN COMPONENTE ORGANOMETALICO SELECCIONADO ENTRE LOS GRUPOS IA, IIA, IIB Y IIIA DEL SISTEMA PERIODICO DE LOS ELEMENTOS.
ES96927701T 1995-08-22 1996-08-07 Polimeros del etileno con una elevada resistencia a la fisuracion por tensiones y un sistema catalizador para su obtencion. Expired - Lifetime ES2154417T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19530766 1995-08-22

Publications (1)

Publication Number Publication Date
ES2154417T3 true ES2154417T3 (es) 2001-04-01

Family

ID=7770039

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96927701T Expired - Lifetime ES2154417T3 (es) 1995-08-22 1996-08-07 Polimeros del etileno con una elevada resistencia a la fisuracion por tensiones y un sistema catalizador para su obtencion.

Country Status (10)

Country Link
US (1) US6180731B1 (es)
EP (1) EP0846131B1 (es)
JP (2) JP4224134B2 (es)
KR (2) KR100437987B1 (es)
CN (1) CN1135240C (es)
AT (1) ATE198898T1 (es)
CA (1) CA2227248A1 (es)
DE (1) DE59606391D1 (es)
ES (1) ES2154417T3 (es)
WO (1) WO1997008213A1 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO960350A (no) † 1996-01-26 1997-04-28 Borealis As Fremgangsmåte og katalysatorsystem for polymerisering av etylen, eventuelt sammen med <alfa>-olefiner, og fremstilt polymermateriale
NO980552D0 (no) 1998-02-09 1998-02-09 Borealis As Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik
NO981631L (no) * 1998-04-08 1999-10-11 Borealis As Katalysator for polymerisasjon av etylen, og fremgangsmaate for fremstilling av denne
US6274684B1 (en) * 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US7041617B2 (en) * 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
DE10034191A1 (de) * 2000-07-13 2002-01-24 Basell Polyolefine Gmbh Kunststoffhohlkörper aus hochdichten Polyolefinen hergestellt mit einem fluormodifizierten Chrom-Katalysator
US7244795B2 (en) * 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US7163906B2 (en) 2004-11-04 2007-01-16 Chevron Phillips Chemical Company, Llp Organochromium/metallocene combination catalysts for producing bimodal resins
CN101080424B (zh) * 2004-11-04 2011-11-09 切弗朗菲利浦化学公司 用于生产双峰树脂的有机铬/茂金属组合催化剂
DE102005019393A1 (de) 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Polyethylenformmassen für Spritzgussanwendungen
DE102005019395A1 (de) * 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators
CA2605044C (en) * 2007-10-01 2014-12-02 Nova Chemicals Corporation Polymerization process using a mixed catalyst system
CN110878130B (zh) * 2018-09-06 2023-04-07 中国石油化工股份有限公司 负载型铬和茂双金属催化剂、其制备方法及其应用

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2540279C2 (de) 1975-09-10 1987-02-05 Basf Ag, 6700 Ludwigshafen Verfahren zum Herstellen eines Katalysators für die Polymerisation von Olefinen
US4284527A (en) 1978-06-19 1981-08-18 Chemplex Company Polymerization catalyst
US4424139A (en) * 1982-03-30 1984-01-03 Phillips Petroleum Company Catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
US4806513A (en) 1984-05-29 1989-02-21 Phillips Petroleum Company Silicon and fluorine-treated alumina containing a chromium catalyst and method of producing same
ATE133690T1 (de) 1987-04-03 1996-02-15 Fina Technology Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke.
US5198400A (en) 1987-05-20 1993-03-30 Quantum Chemical Corporation Mixed chromium catalysts and polymerizations utilizing same
EP0339571B1 (en) 1988-04-26 1994-02-23 Showa Denko Kabushiki Kaisha Process for preparation of ethylene polymers
CA2078366A1 (en) 1991-09-18 1993-03-19 Joel L. Martin Polyethylene blends
US5399622A (en) * 1993-11-17 1995-03-21 Phillips Petroleum Company System of chromium catalyst and yttrium catalyst, olefin polymerization process, and polymer
US5624877A (en) * 1994-02-25 1997-04-29 Phillips Petroleum Company Process for producing polyolefins
US5543376A (en) * 1994-02-25 1996-08-06 Phillips Petroleum Company Process for producing polyolefins
US5714424A (en) 1995-01-09 1998-02-03 W. R. Grace & Co.-Conn. Multi-component polyolefin catalysts

Also Published As

Publication number Publication date
JPH11511488A (ja) 1999-10-05
KR20040014672A (ko) 2004-02-14
EP0846131A1 (de) 1998-06-10
CN1135240C (zh) 2004-01-21
KR19990044053A (ko) 1999-06-25
KR100437987B1 (ko) 2004-08-16
CN1193984A (zh) 1998-09-23
DE59606391D1 (de) 2001-03-01
KR100440847B1 (ko) 2004-07-19
JP2008231434A (ja) 2008-10-02
JP4224134B2 (ja) 2009-02-12
EP0846131B1 (de) 2001-01-24
US6180731B1 (en) 2001-01-30
CA2227248A1 (en) 1997-03-06
WO1997008213A1 (de) 1997-03-06
ATE198898T1 (de) 2001-02-15

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