ES2100752T3 - Complejos de metaloceno soportados con grupos heterofuncionales en el sistema de ciclopentadienilo como sistemas de catalizador. - Google Patents
Complejos de metaloceno soportados con grupos heterofuncionales en el sistema de ciclopentadienilo como sistemas de catalizador.Info
- Publication number
- ES2100752T3 ES2100752T3 ES95102479T ES95102479T ES2100752T3 ES 2100752 T3 ES2100752 T3 ES 2100752T3 ES 95102479 T ES95102479 T ES 95102479T ES 95102479 T ES95102479 T ES 95102479T ES 2100752 T3 ES2100752 T3 ES 2100752T3
- Authority
- ES
- Spain
- Prior art keywords
- metalochene
- hetero
- functional groups
- catalyst systems
- cyclopentadienyl system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
Abstract
LA INVENCION SE REFIERE A UN SISTEMA DE CATALIZADOR SOPORTADO, OBTENIBLE POR MEDIO DE A) TRANSFORMACION DE UN PORTADOR FINAMENTE DIVIDIDO CON UN COMPUESTO ALFA - TRISALCOXISILIL - OMEGA - HALOGENALQUIL, B) ADICION DE UN COMPLEJO METALOCENO CON GRUPO HETEROFUNCIONALES EN EL SISTEMA CICLOPENTADIENO, C) TRANSFORMACION CON UN AGENTE DE CUATERNIZACION Y D) EVENTUALMENTE ADICION DE UN COMPUESTO ALUMOXANO EN LA SUCESION EN SERIE DADA PREVIAMENTE.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4406964A DE4406964A1 (de) | 1994-03-03 | 1994-03-03 | Geträgerte Metalloxenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem als Katalysatorsysteme |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2100752T3 true ES2100752T3 (es) | 1997-06-16 |
Family
ID=6511704
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95102479T Expired - Lifetime ES2100752T3 (es) | 1994-03-03 | 1995-02-22 | Complejos de metaloceno soportados con grupos heterofuncionales en el sistema de ciclopentadienilo como sistemas de catalizador. |
Country Status (7)
Country | Link |
---|---|
US (1) | US5627246A (es) |
EP (1) | EP0670336B1 (es) |
JP (1) | JPH0834812A (es) |
DE (2) | DE4406964A1 (es) |
ES (1) | ES2100752T3 (es) |
TW (1) | TW346493B (es) |
ZA (1) | ZA951725B (es) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4406963A1 (de) * | 1994-03-03 | 1995-09-07 | Basf Ag | Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem |
ES2120868B1 (es) * | 1995-08-03 | 2000-09-16 | Repsol Quimica Sa | Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas. |
HUP9902066A3 (en) * | 1995-11-27 | 1999-11-29 | Grace W R & Co | Supported catalyst containing tethered cation forming activator |
FI961511A (fi) * | 1996-04-03 | 1997-10-04 | Mikrokemia Oy | Menetelmä olefiinien polymerointikatalyyttien valmistamiseksi |
ES2129323B1 (es) * | 1996-04-18 | 2000-09-16 | Repsol Quimica Sa | Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas |
IT1283010B1 (it) * | 1996-05-15 | 1998-04-03 | Enichem Spa | Complesso metallocenico supportato e procedimento per la sua prepa- razione |
DE19622481A1 (de) * | 1996-06-05 | 1997-12-11 | Hoechst Ag | Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
EP1021454A1 (en) * | 1996-08-08 | 2000-07-26 | The Dow Chemical Company | 2-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
DE69705186T2 (de) | 1996-10-30 | 2002-03-14 | Repsol Quimica Sa | Katalysatorsysteme für die (Co)Polymerisation von Alpha-Olefinen |
ES2154017T3 (es) * | 1996-10-31 | 2001-03-16 | Repsol Quimica Sa | Sistemas cataliticos para la polimerizacion y copolimerizacion de alfa-olefinas. |
ATE398635T1 (de) * | 1997-06-05 | 2008-07-15 | Exxonmobil Chem Patents Inc | Katalysator auf polymerträger zur polymerisation von olefinen |
DE19813656A1 (de) | 1998-03-27 | 1999-09-30 | Aventis Res & Tech Gmbh & Co | Übergangsmetallverbindung |
ES2211013T3 (es) | 1998-04-27 | 2004-07-01 | Repsol Quimica S.A. | Sistemas cataliticos para la polimerizacion y copolimerizacion de alfa-olefinas. |
ATE264344T1 (de) * | 1998-04-29 | 2004-04-15 | Repsol Quimica Sa | Verfahren und verwendung von heterogenen katalysatorbestandteilen für die olefinpolymerisation |
US6194343B1 (en) * | 1999-03-11 | 2001-02-27 | University Of Waterloo | Bridged “tethered” metallocenes |
US6908876B2 (en) * | 2003-04-16 | 2005-06-21 | Saudi Basic Industries Corporation | Supported metallocene catalyst system for olefin polymerization, method for making and using the same |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1268754A (en) * | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
WO1988001626A1 (en) * | 1986-08-26 | 1988-03-10 | Mitsui Petrochemical Industries, Ltd. | CATALYST FOR POLYMERIZING alpha-OLEFIN AND POLYMERIZATION PROCESS |
DE3840772A1 (de) * | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
TW300901B (es) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
ES2100388T3 (es) * | 1992-05-26 | 1997-06-16 | Hoechst Ag | Procedimiento para preparar ceras de poliolefina. |
ES2153368T3 (es) * | 1992-08-03 | 2001-03-01 | Targor Gmbh | Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos especiales. |
-
1994
- 1994-03-03 DE DE4406964A patent/DE4406964A1/de not_active Withdrawn
-
1995
- 1995-02-22 DE DE59500200T patent/DE59500200D1/de not_active Expired - Fee Related
- 1995-02-22 EP EP95102479A patent/EP0670336B1/de not_active Expired - Lifetime
- 1995-02-22 ES ES95102479T patent/ES2100752T3/es not_active Expired - Lifetime
- 1995-02-28 JP JP7040783A patent/JPH0834812A/ja active Pending
- 1995-02-28 TW TW084101849A patent/TW346493B/zh active
- 1995-03-01 US US08/396,716 patent/US5627246A/en not_active Expired - Fee Related
- 1995-03-02 ZA ZA951725A patent/ZA951725B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
ZA951725B (en) | 1996-09-02 |
EP0670336B1 (de) | 1997-05-02 |
US5627246A (en) | 1997-05-06 |
EP0670336A1 (de) | 1995-09-06 |
DE4406964A1 (de) | 1995-09-07 |
JPH0834812A (ja) | 1996-02-06 |
TW346493B (en) | 1998-12-01 |
DE59500200D1 (de) | 1997-06-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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