TW332210B - Solid precursor of a catalytic system for the polymerization of olefins, process for its preparation, catalytic system comprising this solid precursor and process for the polymerization of olefins in the presence of this catalytic system - Google Patents
Solid precursor of a catalytic system for the polymerization of olefins, process for its preparation, catalytic system comprising this solid precursor and process for the polymerization of olefins in the presence of this catalytic systemInfo
- Publication number
- TW332210B TW332210B TW083101682A TW83101682A TW332210B TW 332210 B TW332210 B TW 332210B TW 083101682 A TW083101682 A TW 083101682A TW 83101682 A TW83101682 A TW 83101682A TW 332210 B TW332210 B TW 332210B
- Authority
- TW
- Taiwan
- Prior art keywords
- catalytic system
- olefins
- polymerization
- solid precursor
- precursor
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/906—Comminution of transition metal containing catalyst
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/907—Specified means of reacting components of transition metal catalyst
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE9300191A BE1006880A3 (fr) | 1993-03-01 | 1993-03-01 | Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique. |
Publications (1)
Publication Number | Publication Date |
---|---|
TW332210B true TW332210B (en) | 1998-05-21 |
Family
ID=3886874
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW083101682A TW332210B (en) | 1993-03-01 | 1994-02-28 | Solid precursor of a catalytic system for the polymerization of olefins, process for its preparation, catalytic system comprising this solid precursor and process for the polymerization of olefins in the presence of this catalytic system |
Country Status (14)
Country | Link |
---|---|
US (2) | US5763349A (zh) |
EP (2) | EP0613908B1 (zh) |
JP (1) | JP3492749B2 (zh) |
KR (1) | KR100300486B1 (zh) |
CN (1) | CN1044372C (zh) |
AT (2) | ATE206141T1 (zh) |
BE (1) | BE1006880A3 (zh) |
BR (1) | BR9400684A (zh) |
CA (1) | CA2116404A1 (zh) |
DE (2) | DE69411968T2 (zh) |
ES (2) | ES2122142T3 (zh) |
PT (1) | PT838476E (zh) |
RU (1) | RU2141972C1 (zh) |
TW (1) | TW332210B (zh) |
Families Citing this family (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5498582A (en) * | 1993-12-06 | 1996-03-12 | Mobil Oil Corporation | Supported metallocene catalysts for the production of polyolefins |
DE4431838A1 (de) * | 1994-09-07 | 1996-03-14 | Basf Ag | Geträgerte Metallocen-Katalysatorsysteme |
BE1009186A3 (fr) * | 1995-03-13 | 1996-12-03 | Solvay | Solide catalytique pour la (co)polymerisation d'ethylene, procede pour sa preparation, systeme catalytique pour la (co)polymerisation d'ethylene et procede de (co)polymerisation d'ethylene. |
US6451725B1 (en) * | 1995-04-12 | 2002-09-17 | Borealis Technology Oy | Method for preparing catalyst components |
DE19606166A1 (de) | 1996-02-20 | 1997-08-21 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von Alkenen durch Suspensionspolymerisation |
DE19606165A1 (de) | 1996-02-20 | 1997-08-21 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von Alkenen durch Gasphasenpolymerisation |
DE19606167A1 (de) | 1996-02-20 | 1997-08-21 | Basf Ag | Geträgerte Katalysatorsysteme |
US5965477A (en) * | 1997-02-21 | 1999-10-12 | Council Of Scientific & Industrial Research | Process for the preparation of supported metallocene catalyst |
US5955554A (en) * | 1997-03-27 | 1999-09-21 | Council Of Scientific Industrial Research | Process for polymerization and copolymerization of olefins |
AU702218B2 (en) * | 1997-03-31 | 1999-02-18 | Kyushu-Taiyoukasei., Ltd. | Liner film for bulk container and container liner |
DE69735755T2 (de) * | 1997-05-14 | 2007-04-12 | Council Of Scientific And Industrial Research | Verfahren zur Polymerisation von Olefinen |
GB9712663D0 (en) * | 1997-06-16 | 1997-08-20 | Borealis As | Process |
DE19811934A1 (de) | 1998-03-19 | 1999-09-23 | Basf Ag | Ethylencopolymere mit enger Comonomerverteilung |
BE1012364A3 (fr) * | 1998-12-22 | 2000-10-03 | Solvay | Procede pour la preparation d'une composition catalytique pour la polymerisation des alpha-olefines, composition catalytique obtenue et procede de polymerisation utilisant une telle composition catalytique |
US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
EP1620479B1 (en) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
US7618913B2 (en) * | 2006-08-31 | 2009-11-17 | Formosa Plastics Corporation, U.S.A. | Highly active alpha-olefin copolymerization catalyst system |
AU2007319883B2 (en) * | 2006-11-14 | 2012-12-13 | Univation Technologies, Llc. | Catalyst systems and polymerization processes |
MY159709A (en) | 2011-01-28 | 2017-01-13 | Crane & Co Inc | A laser marked device |
AU2012299113B2 (en) | 2011-08-19 | 2015-05-07 | Visual Physics, Llc | Optionally transferable optical system with a reduced thickness |
CA2760264C (en) | 2011-12-05 | 2018-08-21 | Nova Chemicals Corporation | Passivated supports for use with olefin polymerization catalysts |
RU2621558C9 (ru) | 2012-08-17 | 2017-12-05 | Визуал Физикс, Ллс | Процесс переноса микроструктур на конечную подложку |
CN105339180B (zh) | 2013-03-15 | 2018-05-11 | 光学物理有限责任公司 | 光学安全性设备 |
US9873281B2 (en) | 2013-06-13 | 2018-01-23 | Visual Physics, Llc | Single layer image projection film |
ES2973122T3 (es) | 2013-07-09 | 2024-06-18 | Dow Global Technologies Llc | Interpolímeros de etileno/alfa-olefina con fluidez de gránulos mejorada |
US10766292B2 (en) | 2014-03-27 | 2020-09-08 | Crane & Co., Inc. | Optical device that provides flicker-like optical effects |
AU2015235889B2 (en) | 2014-03-27 | 2018-10-11 | Visual Physics, Llc | An optical device that produces flicker-like optical effects |
CA2955372C (en) | 2014-07-17 | 2022-10-11 | Visual Physics, Llc | An improved polymeric sheet material for use in making polymeric security documents such as banknotes |
RU2707595C9 (ru) | 2014-09-16 | 2020-02-14 | Кране Секьюрити Технолоджис, Инк. | Защищенный слой линз |
US9303106B1 (en) * | 2014-10-17 | 2016-04-05 | Chevron Phillips Chemical Company Lp | Processes for preparing solid metallocene-based catalyst systems |
CN107250459B (zh) | 2015-02-11 | 2021-06-11 | 克瑞尼股份有限公司 | 用于安全器件到基底的表面施加的方法 |
WO2018063899A1 (en) * | 2016-09-29 | 2018-04-05 | Dow Global Technologies Llc | Magnesium halide-supported titanium (pro) catalysts |
EP4026702A1 (en) | 2017-02-10 | 2022-07-13 | Crane & Co., Inc. | Machine-readable optical security device |
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US4242480A (en) * | 1977-12-13 | 1980-12-30 | Phillips Petroleum Company | Catalyst and process of polymerization of alpha monoolefins |
US5077255A (en) * | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
PL276385A1 (en) * | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
ES2087145T3 (es) * | 1989-10-10 | 1996-07-16 | Fina Technology | Catalizadores metalocenos con acidos de lewis y alkilo-aluminios. |
DE69026679T3 (de) * | 1989-10-30 | 2005-10-06 | Fina Technology, Inc., Houston | Addition von Alkylaluminium zum Verbessern eines Metallocenkatalysators |
US5387568A (en) * | 1989-10-30 | 1995-02-07 | Fina Technology, Inc. | Preparation of metallocene catalysts for polymerization of olefins |
US5266544A (en) * | 1989-12-29 | 1993-11-30 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for the polymerization of olefins |
JP3115595B2 (ja) * | 1990-07-24 | 2000-12-11 | 三井化学株式会社 | α―オレフィンの重合触媒及びそれを用いたポリ―α―オレフィンの製造方法 |
JP2895199B2 (ja) * | 1990-10-02 | 1999-05-24 | 三井化学株式会社 | オレフィンの重合触媒 |
US5369196A (en) * | 1990-11-30 | 1994-11-29 | Idemitsu Kosan Co., Ltd. | Production process of olefin based polymers |
DE69222700T2 (de) * | 1991-07-11 | 1998-03-26 | Idemitsu Kosan Co | Verfahren zur Herstellung von Polymeren auf Olefinbasis und Olefin-Polymerisationskatalysatoren |
FR2686675B1 (fr) * | 1992-01-24 | 1995-06-16 | Sicmo | Clapet de detendeur pour pistolet a peinture. |
BE1005957A5 (fr) * | 1992-06-05 | 1994-04-05 | Solvay | Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine. |
JP3153000B2 (ja) * | 1992-06-11 | 2001-04-03 | 三菱化学株式会社 | α‐オレフィン重合体の製造法 |
US5710222A (en) * | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
BE1006438A3 (fr) * | 1992-12-17 | 1994-08-30 | Solvay | Systeme catalytique, utilisation de ce systeme catalytique pour la (co)polymerisation d'olefines, procede de preparation de ce systeme catalytique et procede de (co)polymerisation d'olefines. |
EP0739365B2 (en) * | 1994-01-11 | 2009-02-25 | ExxonMobil Chemical Patents Inc. | Alumoxanes and catalysts comprising alumoxanes |
-
1993
- 1993-03-01 BE BE9300191A patent/BE1006880A3/fr not_active IP Right Cessation
-
1994
- 1994-02-17 EP EP94200399A patent/EP0613908B1/fr not_active Expired - Lifetime
- 1994-02-17 ES ES94200399T patent/ES2122142T3/es not_active Expired - Lifetime
- 1994-02-17 AT AT97120938T patent/ATE206141T1/de not_active IP Right Cessation
- 1994-02-17 DE DE69411968T patent/DE69411968T2/de not_active Expired - Fee Related
- 1994-02-17 PT PT97120938T patent/PT838476E/pt unknown
- 1994-02-17 ES ES97120938T patent/ES2164979T3/es not_active Expired - Lifetime
- 1994-02-17 EP EP97120938A patent/EP0838476B1/fr not_active Expired - Lifetime
- 1994-02-17 DE DE69428464T patent/DE69428464T2/de not_active Expired - Fee Related
- 1994-02-17 AT AT94200399T patent/ATE169033T1/de not_active IP Right Cessation
- 1994-02-24 CA CA002116404A patent/CA2116404A1/fr not_active Abandoned
- 1994-02-25 BR BR9400684A patent/BR9400684A/pt not_active IP Right Cessation
- 1994-02-28 RU RU94006783A patent/RU2141972C1/ru active
- 1994-02-28 TW TW083101682A patent/TW332210B/zh active
- 1994-03-01 CN CN94104084A patent/CN1044372C/zh not_active Expired - Fee Related
- 1994-03-01 JP JP03124794A patent/JP3492749B2/ja not_active Expired - Fee Related
- 1994-03-02 KR KR1019940003953A patent/KR100300486B1/ko not_active IP Right Cessation
-
1996
- 1996-02-15 US US08/606,686 patent/US5763349A/en not_active Expired - Fee Related
-
1998
- 1998-04-13 US US09/058,962 patent/US6214948B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69428464D1 (de) | 2001-10-31 |
CN1044372C (zh) | 1999-07-28 |
RU2141972C1 (ru) | 1999-11-27 |
ATE169033T1 (de) | 1998-08-15 |
EP0838476A1 (fr) | 1998-04-29 |
BE1006880A3 (fr) | 1995-01-17 |
CN1098110A (zh) | 1995-02-01 |
JP3492749B2 (ja) | 2004-02-03 |
DE69411968D1 (de) | 1998-09-03 |
US5763349A (en) | 1998-06-09 |
ES2122142T3 (es) | 1998-12-16 |
ES2164979T3 (es) | 2002-03-01 |
KR940021589A (ko) | 1994-10-19 |
US6214948B1 (en) | 2001-04-10 |
EP0613908B1 (fr) | 1998-07-29 |
PT838476E (pt) | 2002-03-28 |
KR100300486B1 (ko) | 2001-10-22 |
DE69411968T2 (de) | 1999-03-18 |
BR9400684A (pt) | 1994-10-18 |
EP0613908A1 (fr) | 1994-09-07 |
JPH06287212A (ja) | 1994-10-11 |
EP0838476B1 (fr) | 2001-09-26 |
ATE206141T1 (de) | 2001-10-15 |
DE69428464T2 (de) | 2002-05-23 |
CA2116404A1 (fr) | 1994-09-02 |
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