TW316838B - - Google Patents

Description

A7

S1CB3S V. Description of the invention (1) ---- ~~ · The present invention relates to an emulsifiable composition for insect control and its use. The emulsifiable composition of the present invention is a substituted phenylpyridine that kills insects at the w • position, and it is not conducive to the formation of crystals. When the 1-position substituted phenylpyrazole insecticide is stored or used, it can easily crystallize in the composition. When using these compounds in various applications, some crystallization or recrystallization problems may occur ’, which hinders proper and simple use. Such a situation may occur in many practical applications, for example: in the use of spraying through the nozzle, the nozzle may be blocked; when dilution is performed in the storage tank, the active ingredients in it may crystallize and Settling to the bottom of the storage tank; when applied to animal hair, the quality of these hairs may be damaged due to the attachment of crystals. For animals such as playmates, the most important condition is to have high-quality hair, which makes people feel comfortable and pleasant when touching or touching. In addition, insect control, especially white-ant control professionals often prepare diluted insecticides as they are used, and use the remaining liquid the next day. Because these liquids contain crystalline active ingredients, they can only be slightly emulsified, and within a few hours after the preparation of the spray emulsion, they are also susceptible to crystallization, resulting in a large amount of useless liquids, or making the spray suction help for foam applications. Pu is blocked. In the special case of insect control, especially termite control methods, these methods are generally divided into two main groups. Among them-the category is for wood treatment. According to this method, the wooden parts of the house are treated with insecticides; the other is for the soil treatment. According to this method, the liquid insecticide is based on the Chinese national standard. (CNS) A4 jealous of you (210X297mm) (please read the notes on the back before filling in this page)-Binding 'Order the consumer cooperation of the Central Bureau of the Ministry of Economy II. Printed by workers and consumer cooperatives A7 B7 V. Description of the invention (2) The area sprayed under the floor of the house. Taking into account the health problems and activities of workers when using these pesticides in such a limited space under the floor The application of flowable formulations in which the ingredients are suspended becomes an advantage. However, such dilute aqueous solutions have a tendency to crystallize. Generally known flowable formulations are not satisfactory. Japanese Patent Publication No. 2-7282 has proposed prevention The method of crystallizing the active ingredient of the phenyl ethox insecticide that is not substituted at the 1_ position. Japanese Patent Application No. 50-69230 has described a liquid herbicide composition whose activity The portion is dinitroaniline herbicide and Ν-allyl-Ν'-alkoxy vein herbicide. The case has also been disclosed to provide physical stability of the composition under shipping, storage, and final use conditions It is the use of emulsifying agents and solvents composed of alicyclic ketones. The object of the present invention is to provide an improved emulsifiable composition which can reduce the odor of the solvent and / or prevent the substitution of phenyl leaves at the time of dilution Crystallization of dagger insecticides and / or generally is better than conventional flowable formulations. Another object of the present invention is to provide improved emulsifiable compositions suitable for use in combination with foaming agents, Treat the area under the floor of the house in the form of foam. The emulsifiable composition of the present invention comprises: an insecticidal compound of formula (I), a pyrethroid, and a weakly polar solvent, and a Emulsifier, and -5- This paper scale is applicable to the Central Park National Standard Rate (CNS) Α4 specification (2 ΙΟχ 297 g ^ 7 -------- ί -installation ------ order --- -"猓-* (Please read the notes on the back before filling out this page)» .ί Λ ^ Λ Patent Application No. 84113057 Amendment to the Chinese specification of L Gd3g; g (October 85 > & f · Μ Β7 Fifth, invention description (3

A water-soluble solvent, and optionally a foam stabilizer and / or a foaming agent, and / or a polar solvent and / or an aromatic solvent and / or other additives. The compound of formula ⑴ as the active ingredient in the present invention is lH-R1 2,6- (R2) p phenyl] -3-cyano-4- [R4-S (〇) n] 5-R5P ratio ⑴ R -(§ (〇) n CN

Printed by the Employee Consumer Cooperatives and Cooperatives of the Central Bureau of Economics of the Ministry of Economic Affairs where: R1 is halogen, low-carbon haloalkyl, low-carbon haloalkoxy or Sf5 (low-carbon number refers to an integer from 1 to 4, which is Preferably, R2 is an element, each R2 may be the same or different, R4 is a halogen, a low-carbon alkyl or haloalkyl, R5 is a halogen, a low-carbon alkyl or amine, η is 0 or 1 or 2 ; p is 0 or 1 or 2, preferably 2. The halogen located before the name of the group means that this group can be substituted by one or more halogen atoms. The preferred compound of formula ⑴ is 5-aminocyano Yl- (2,6-digas-4-trifluoromethylphenyl) -4-trifluoromethanesulfinylpyrazole, hereafter referred to as compound (Α). Used for insect control in this case, In particular, the emulsifiable compounds used for the control of Baishen, the compound of formula (1) has been described in the European Patent Application No. Ms 1 η and the International Patent Applications W〇93 / 6089 and 94/21606. The control of animals, plant nematodes, protozoan pests and insects, especially termites, farm pests and the like, or arthropods such as steles Effective. 'Examples of arachnids I can be used in the present invention include pyrethroid compounds: Ya Wu Shu, Ning [' 肖 旋 _3_allyl-2-methyl-4-cyano_2 _Cyclopenta-6 Mu.'S Zhang scale phase 'National County (CNS) A4 specification (21GX 297 meal) (please first «read the back. Note and then fill out this page) 丨 installed. Order No. 84113057 Patent Application ..: Each Ά Patent Application No. 84113057 ..: Each Ά is printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. V. Description of Invention (4) Xyl-race-cis, trans-chrysanthenate] 2_ 艾Ethofenprox [2- (4-ethoxyphenyl) -2-methylpropyl-3-phenoxybenzyl ether] 3. Cycloprothrin [(RS) -a-cyanide Yl-3-phenoxyfluorenyl (RS) -2,2-difluoro-1- (4-ethoxyphenyl) -cyclopropane carboxylate] 4. Cyhalothrin [(RS) -a -Cyano-3-phenoxybenzyl (z) · (lRS, 3RS) -3- (2-lact-3,3,3 · trifluoropropyl) -2,2-di · methyl-3 gang Propylene carboxylate] 5. Cyfluthrin [(RS)-< aT · cyanofluoro · 3-phenoxybenzyl (11 ^, 31 ^)-(11 ^, 3115) _3- ( 2,2-Difluorovinyl) -2,2-dimethylcyclopropan-hyun • Glic acid self-purpose] 6. Saime (Cypermethrin) [(RS) -a-cyano-3-phenoxybenzyl (lRS, 3RS) -3- (2,2-difluorovinyl) -2,2-dimethylcyclopropane carboxylate 7. Pyrethrin 8. Tralomethrin [(S) -a-cyano-3-phenoxyfluorenyl (lR, 3S) -2,2-dimethyl-3- (l, 2,2,2-Tetrabromoethyl) -cyclopropane carboxylate] 9. Fenvalerate [(RS) -α-cyano-3-phenoxybenzyl (RS) -2- (4 -Gas phenyl) -3-methylbutyrate] 10. Fenpropathrin [(RS) -α-Gas-3-phenoxy-2,2,3,3-tetramethyl ring Propane carboxylate] 11. Flucythrinate [(RS) -Amino-3-phenoxy group- (S) -2- (4-difluoromethoxyphenyl) -3-methylbutane Ester] -1 12. Fluorethrin [3-phenoxyfluorenyl (11 ^, 31 ^)-(1115,31 ^)-(2,2-difluorovinyl) -2,2-dimethyl Cyclopropane carboxylate] This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) ml ml i ϋ · — mt 1J nn I i ^ i ^ — -le i (Please read the precautions on the back first (Fill in this page) .'Disease, 'Patent Application No. 84113057 Amendment page for the Chinese specification (October 85) ί Α7 Β7 Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs System V. Description of the invention (5) 13. Bifenthrin (2-methylbiphenyl-3-yl-methyl-like) · (1 ft 3, 3 ft 5) -3- (2-gas-3 , 3,3-trifluoroprop-1-enyl) _2,2-dimethylcyclopropane carboxylate] 14_Silafluofen (Silafluofen) [4-ethoxyphenyl- [3- (3 -Phenoxy-4-fluorophenyl) propyl] (dimethyl) silane] Resmethrin [5-benzyl-3-p furanmethyl-rac-cis, trans-chrysanthemum Ester] 16. Tefluthrin [2,3; 5,6 · tetrafluoro-4-methylbenzyl- (1RS) -cis-3- (Z-2-gas_3,3 , 3_trifluoroprop-1-enyl) -2,2-dimethylcyclopropane carboxylate] '' 17. Acdnathdn [(S)-α -cyano-3 -Phenoxybenzyl (Z)-(lR, 3S) -2,2-dimethyl-3- [2- (2,2,2-trifluoro-1-trifluoromethylethoxycarbonyl) vinyl ] Cyclopropane carboxylate] 18 · Parethrin (prarethrin) [(RS) -2-methyl-4-oxy-3-prop-2-enylcyclopent-2-yl (1RS)- Cis-trans-2,2-dimethyl-2- (2-methylprop-1-enyl) cyclopropane carboxylate], 1 9. Cismethrin! ^-^ Yl- 3-Creanomethyl (1R) -trans-2,2-dimethyl-3- (2-methylpropan-1-yl) cyclopropane carboxylate] 20. (1-fenso @ 执 （(1-?] ^ 11〇 化] ^ 11) [3-phenoxy phenoxy (1115) -cis-trans-2,2-dimethyl-3- (2-methylpropan-1- Xyl) cyclopropane carboxylate] 21. Deltamethrin [(S) · yl-3-phenoxybenzyl (1R) -cis-3- (2,2-dibromovinyl) -2 , 2-Dimethylcyclo_propane carboxylate] 22. Tetramethrin [Cyclohex-1-yl-1,2-diokisylamino · methyl- (1 ft. 5, 31 ^ ， 1115,3511) -2,2-dimethyl-3- (2-methylpropan-1-enyl) (Please read the precautions on the back before filling in this page) -Install.,-° line -8

B7 Patent Application No. 84113057 JC 〇3 § Chinese specification amendment page (October 85) V. Description of invention (6) Cyclopropane carboxylate] 23.Fluvalinate (Fluvalinate) [(RS) -α- Cyano-3-phenoxyfluorenyl N- (2-chloro-α a, or -trifluoro-p-methylene) -racemic-phenaminoamine] only each component is included in the composition of the invention The ratio of the compound varies widely, and the better advantageous composition of the present invention includes (the ratio is expressed as a weight percentage, that is, the weight component in each 100 weight component): 0.2 to 10% of the compound of formula (I), preferably 0.5 to 5% (more preferably 1 to 5%), and / or a 0.1 to 10% pyrethroid, and / or 1 to 15 % Weakly polar solvents (more specifically 1 to 0% and preferably 2 to 10%), and / or 5 to 20% emulsifier, and / or selective 1 to 5% foam stabilization Agent, and / or at least one water-soluble solvent to make up the composition to 100%; the proportion of such solvent (s) in the composition of the present invention is generally more than 40〇 / 〇 ' For more than 60%, selectivity of 0 to 15% polar solvents and selection 0 to 20% of aromatic solvents and optional other additives. The weakly polar solvents that can be used in the present invention are generally those with positive dipole moments, preferably greater than 1 (in Debye units), and their winter solubility in water (under 2〇.c) is less than 10 %By. These weakly polar solvents are preferably selected from cyclic amide and hydroxyethyl ether solvents. -9- The size of this paper standard) A4 specification---I ^^^ 1--I-.-1 ----- In. (Please read the precautions on the back and fill in two pages), \ s ° The Ministry of Economic Affairs, Central Bureau of Standards, and Employee Consumer Cooperatives printed the Ministry of Economic Affairs, Central Bureau of Standards, and Employee Consumer Cooperatives. A7 Β7 5. Invention Description (7) An example of a cyclic amide that can be used here is N-octyl_2 _Pyrrolidone, N_dodecyl-2-pyrrolidone and N_dodecyl-caprolactam. Examples of light polar acetic acid weak polar solvents that can be used for this are: ethylene glycol monophenyl ether ethylene glycol monohexyl silver carp, ethylene glycol mono-2-ethylhexyl ether, ethylene glycol dibutyl ether, diethylene glycol dibutyl ether Acid, propylene glycol monophenyl ether, dipropylene glycol monopropyl silver carp, ethylene glycol single chain and the like. The preferred ethylene glycol solvent is monoethylene glycol-2-ethylhexyl. The emulsifier that can be used here is one or more selected from nonionic or anionic emulsifiers. Examples of nonionic emulsifiers that may be mentioned include polyoxyethylene phenylphenyl ether, polyoxyethylene alkyl ether, polyethylene glycol fatty ester, sorbitan fatty ester, polyoxyethylene sorbitan fatty ester, poly Oxygen. Ethylene sorbitan fatty vinegar, polyoxyethylene polyoxy-propylene burned chain, polyoxyethylene castor oil. Examples of anionic emulsifiers that may be mentioned include alkyl sulfates, polyoxyethylene alkyl ether sulfates, sulfosuccinates, taurine derivatives, carnitine derivatives, phosphate esters, alkylbenzenes Sulfonates are similar. A three-component mixture consisting of polyoxyethylene stylpropylene vinyl phenyl ether, polyoxyethylene castor oil and calcium alkylbenzene sulfonate, and ammonium salt of polyoxyethylene nonyl phenyl ether hexanoic acid are particularly preferred. Foam stabilizers can be used as additives to maintain the mixture in a stable foam form during foam application. Examples of foam stabilizers that can be used here are one or more high carbon number alcohols, preferably fatty alcohols, more preferably composed of decanol, dodecanol, tetradecyl alcohol, cetyl alcohol 'and the like Selected by the group. The water-soluble solvent that can be used here is one or more selected from glycol ethers having the general formula (π): __________- 10- This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (2〇〇297 public ) (Please read the precautions on the back before filling out this page). Installed--Ordered by the Ministry of Economic Affairs Central Standards Bureau Employee Consumer Cooperative Printed V. Invention Instructions (R0 (CH2CH20) qH (Π) where R stands for C-1 to C -6 burned base and q is an integer from 1 to 8. Examples of such glycol acids include diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, triethylene glycol Alcohol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monopropyl ether, diethylene glycol monobutyl ether, polyethylene glycol (q = 4 to 6) monocarboxylic acid. Polar solvents and / or aromatic solvents can also be used Need to be used in the composition of the present invention. Polar solvents that are not weakly polar solvents generally have positive dipole moments, preferably greater than 1 (in Debye units), and their solubility in water is greater than 10 ° / 〇. The polar solvents include cycloamide or lactone, such as N_methyl-2-pyrrolidone, N-cyclohexyl-2-pyrrolidone, caprolactone, butyrolactone ; And ethyl alcohol chains, such as tripropylene glycol monomethyl ether, diethylene glycol dimethyl ether. Suitable aromatic solvents are those that are liquid at room temperature and have a boiling point of at least 200 ° C. May be selected from petroleum fractions, catalytically cracked oil fractions, or synthetic oils and the like. Examples that may be mentioned include: mono- or poly-alkylbenzenes, such as alkylbenzene or trimethyl Benzene; asparagus, such as methyl tea, dimethyl asparagus, dimethyl monopropyl asparagus, dimethyl dipropyl asparagus, or phenyl stilbenes; alkyl diphenyl alkane, like phenyl Ethyl ethane or alkyl diphenyl ethane; indene derivatives; tris-propyl di-alkanes, such as triallyl ethane; dioxin ether; diester sour sour and similar. When applied, Foaming agents that can be incorporated into the emulsifiable composition diluted with water may contain a surfactant, a foam stabilizer, and optionally a solvent * or water. The amount of these foaming agents depends on the specific The amount of foam required varies greatly depending on the application method. A suitable surfactant may be, for example, polyoxyethylene Sodium salt of alkyl phenyl ether sulfate, poly 11-Μ sheet size it financial gj g home transfer (CNS) (i210 X297mm (please read the precautions on the back before filling in this page) Packing · Order A7 B7 Economy Printed by the Central Standards Bureau of the Ministry X Consumer Cooperative V. Description of the invention (9) Ammonium salt of oxyethylene alkyl phenyl ether sulfate, amine salt of polyoxyethylene alkyl phenyl ether sulfate, sodium salt of alkyl sulfate , Amine salts of alkyl sulfates, ammonium salts of alkyl sulfates and the like. Foam stabilizers and solvents may be the same compounds used in the composition of the present invention. When used together with a foaming agent, The composition of the present invention can be diluted with water to obtain a foam emulsion having a desired concentration, and the emulsion can be applied to a confined space under the floor by a spray nozzle driven by a pump. The emulsifiable composition of the present invention can be prepared by any conventional procedure suitable for preparing emulsifiable concentrates. The emulsifiable composition for termite control according to the present invention is against insects, especially insects, especially termites, including termites from Taiwan. Reticulitermes speratus (Kolbe), black-winged soil termites and Coptotermes domesticus (Haviland) have significant effects on house damage. When the house is treated with foam medicine, insects, especially termites, can be completely exterminated, and the treated wood parts can be protected from insect decay. The invention also relates to an insecticidal composition as described above, which has a considerable effect on the treatment of houses, especially the area under the floor of the house, especially when fighting against white worms, and it further contains a foaming agent . The corresponding treatment method using the composition is also part of the present invention. The present invention is more about a method for controlling insects, especially termites, in which an effective amount of the aforementioned composition is applied to a site that has been infested by the aforementioned pests, or may be its infestation site (the site may be A cultivation area), the application dosage of the active ingredient is preferably 0.01 to 15.0 mg / sq.-12- This paper scale is applicable to the Chinese National Standard (CNS) (210 X 297mm ')' (Please read the notes on the back first (Fill in this page again)-Pack. Order 3 C838

V. Description of the invention (in the range of 10 meters, and more preferably in the range of 0.1 to 5.0 milligrams per square meter. A range of people. The Ministry of Economic Affairs Central Standards Bureau employee consumer cooperative printed the composition of the present invention for the treatment of many insects. They are very useful for treating termites, fleas, and even more mosquitoes, and sinking in a wide range of people. (Attacks or insects that attack cats or dogs or other playmates or arachnid arthropods such as ticks, As well as other insects mentioned in European Patent Application No. 295117, this application is included in this case as a reference. The present invention is further advanced-about excluding equipment or steles or insects from dogs and dogs: control Wanfa, in which an effective dose of the aforementioned composition is applied to animals that have been or may be attacked by the aforementioned pests. The present invention is illustrated by the following examples, comparative examples and experimental examples, but it is not limited to The details of each example. Unless otherwise specified, the indicated components are based on weight. Example 1 1 component compound (Α) 1 component Bifenju, 3 component octyl_2_ Eloprofen Mixture of 7-component dimethyldipropylene, 5-component dodecyl alcohol, 10-component polyoxyethylene alkylphenyl acid, polyoxyethylene castor oil, and calcium alkylbenzenesulfonate (" Hymal 1071 ", Obtained from MatSumoto Yushi Sdyaky's heart" '2 components of polyoxyethylene ethylene base basic ugly sulfate vinegar (" Hyten〇i n-08 ,,, obtained from Daiichi Kogyo Seiyaku Inc.) and 7i component After homogeneously dissolving polyoxyethylene monomethyl ether, the emulsifiable composition of the present invention is obtained. Examples 2 to 2 8 In each of the examples, the emulsifiable composition of the present invention is similar to that of Example 1. The 'method' is prepared according to the corresponding formula shown in Tables 1 to 6. The 13- & Min scale is applicable to the Chinese National Standard (CNS) A4 specification (2i0x297mm) (please read the precautions on the back before filling this page) -Installed

'• II Ball A7 B7 V. Description of the invention (H) Printed by the Consumer Standardization Bureau of the Central Bureau of Standards of the Ministry of Economic Affairs 1 Example No. 1 2 3 4 5 6 Compound CA) 1.0 1.0 5.0 5.0 1.0 1.0 Bifenjuth Vinegar 1.0 1.0 1.0 5.0 1.0 1.0 N-octyl-2-pyrrolidone 3.0 5.0 10.0 10.0 3.0 3.0 dimethyldipropylnaphthalene 7.0 10.0 20.0 20.0 20.0 7.0 Hymal 1071 10.0 10.0 10.0 10.0 10.0 10.0 Hytenol N-08 2.0 2.0 2.0 2.0 2.0 2.0 twelve Alcohol 5.0 5.0 5.0 5.0 5.0 1.0 Polyoxyethylene monomethyl ether 71.0 66.0 47.0 43.0 58.0 75.0 Total 100.0 100.0 100.0 100.0 100.0 100.0 Table 2 Example number 7 8 9 10 11 Compound (A) 1.0 1.0 1.0 1.0 1.0 Bifenthrin 5.0 1.0 5.0 Fenfarol 1.0 Sepomethrin 1.0 N-octyl-2-p bilodinone 3.0 3.0 3.0 N-dodecyl-2-p ratio 11 each bite 3.0 N-dodecyl-caprolactone Acetylamine 3.0 Dimethyldipropylxanthene 10.0 7.0 7.0 7.0 7.0 Hymal 1071 10.0 10.0 10.0 10.0 10.0 Hytenol N-08 2.0 2.0 2.0 2.0 2.0 Dodecanol 5.0 5.0 5.0 5.0 5.0 Polyoxyethylene monomethyl ether 64.0 71.0 67.0 71.0 71.0 Total 100.0 100.0 100. 0 100.0 100.0 Table 3 Example number 12 13 14 15 16 Compound (A) 1.0 1.0 1.0 1.0 1.0 1.0 benzyl vinegar 1.0 taromethrin 1.0 ........ I m · "· 1-^^ 1 l (Please read the precautions on the back before filling this page) -14-The size of the paper is in accordance with the Chinese National Standard (CNS) A4 specification (210X 297mm) 〇; fGS38 V. Description of invention (12) A7 B7 Flofa Linne 1.0 Sevefluthrin 1.0 Esofenbo 1.0 N-octyl-2-p bilodiphene 3.0 3.0 3.0 3.0 3.0 dimethyldipropylnaphthalene 7.0 7.0 7.0 7.0 7.0 Hymal 1071 10.0 10.0 10.0 10.0 10.0 Hytenol N-08 2.0 2.0 2.0 2.0 2.0 Dodecanol 5.0 5.0 5.0 5.0 5.0 Polyoxyethylene monomethyl ether 71.0 71.0 71.0 71.0 71.0 Total 100.0 100.0 100.0 100.0 100.0 Table 4 Example number 17 18 19 20 21 Compound (A) 1.0 1.0 1.0 1.0 1.0 Bifenthrin 1.0 1.0 1.0 1.0 Ciraprofen 1.0 N-octyl-2-p biloxon copper 3.0 2.0 2.0 2.0 3.0 N-methyl-2-pyrrolidone 0.5 Cyclohexanone 0.5 N, N -Diethylformamide 0.5 Dimethyldipropylnaphthalene 7.0 .7.5 7.5 7.5 Dimethyl Monopropylnaphthalene 7.0 Hymal 1071 10.0 10.0 10.0 10.0 10.0 Hytenol N-08 2.0 2.0 2.0 2.0 2.0 Dodecanol 5.0 5.0 5.0 5.0 5.0 Polyoxyethylene monomethyl ether 71.0 71.0 71.0 71.0 71.0 Total 100.0 100.0 100.0 100.0 100.0 Table 5 ( Please read the precautions on the back first and then fill out this page)-Packing and Ordering Example Number 22 23 24 printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Compound (A) 1.0 1.0 1.0 Bifenchine Vinegar 1.0 1.0 1.0 N-octyl -2-say pyrrolidone 3.0 3.0 2.0 N-methyl-2-p than pyrrolidone 0.5 0.5 dimethyl dipropylnaphthalene 5.0 5.0 ______- 1Γ- This paper is again applicable to the Chinese il family standard (CNS) A4 Specifications; 210X 297 mm) A7 B7 V. Description of the invention (13) Dimethyl monopropyl xanthene 7.5 5.0 5.0 Hymal 1071 10.0 10.0 10.0 Hytenol N-08 2.0 2.0 2.0 Dodecanol 5.0 5.0 5.0 Polyoxyethylene monomethyl Ether 70.0 68.0 68.5 Total 100.0 100.0 100.0 Table 6 Example number 25 26 27 28 Compound (A) 1.0 1.0 1.0 1.0 Bifenthrin 1.0 1.0 1.0 1.0 1.0 Ethylene glycol mono-2-ethylhexyl ether 20.0 18.0 Ethylene glycol monohexyl ether 20.0 Monoethylene glycol Benzyl ether 2.0 N-methyl-2-pyrrolidone 2.0 Hymal 1071 10.0 10.0 10.0 10.0 Hytenol N-08 2.0 2.0 2.0 2.0 Dodecanol 5.0 5.0 5.0 5.0 Polyoxyethylene monomethyl ether 61.0 61.0 61.0 61.0 Total 100.0 100.0 100.0 100.0 Comparative Examples 1 and 2 ll ·! I. ^ 1 ^ 1 ^^ 1 -—1, 丨 【'Shi I (please read the precautions on the back and then fill out this page) Order the Ministry of Economic Affairs Central Standards Bureau Staff Consumer Cooperative Printing In each example, the emulsifiable composition was prepared according to the corresponding formula shown in Table 7 using a formula similar to Example 1. Table 7 Comparative Example No. 1 2 Compound CA) 1.0 1.0 Bifenthrin 1.0 1.0 N-methyl-2-p biluodian_ 3.0 dimethyldipropylpyridine 7.0 Hymal 1071 10.0 Hytenol N-08 2.0 Solpol 355X 10.0- 16- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 ϋ297mm) CG338 A7 B7 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Invention Instructions (14 ----- 5.0 Polyoxyethylene Monomethyl broken --- 71.0 urgent-88.0 total 5 10 100.0 100.0

Solpol 3 55X (a mixture of polyoxyalkylene allyl phenyl ether, polyoxyalkylene allyl phenyl acid gel and calcium benzene sulfonate, obtained from Matsumot〇Yushi Seiyaku Inc.) Example I. 1 : Crystallization test in emulsion Put 100 ml of 3 in a 100 ml beaker. To hard water, 1.0 g of emulsifiable composition prepared according to the above Examples and Comparative Examples was added thereto, and then stirred and mixed uniformly. At 5. (: After standing for 24 hours, 'pass the resulting emulsion through a sieve with a 45 mm opening. Then' the total amount of crystals left on the sieve is visually observed according to the following criteria. The results obtained are shown in Table 7. Among Examples 1 to 28, none of the examples found the existence of crystals or the phenomenon of crystallization. On the contrary, a large number of crystals and crystallization phenomena appeared in Comparative Example i, while a small amount of crystals and crystallization phenomena It was observed in Comparative Example 2. Experimental Example 2: Foaming test—Emulsifiable compositions prepared according to the above Examples and Comparative Examples were diluted in water to a predetermined diluted solution, and then, 3% A general commercially available foaming agent (" Dolfoam ", obtained from Nihon Noyaku Inc.) was added to the solution. The obtained mixture was foamed using a foam sprayer. The degree of foaming was evaluated by visual observation. No foam was observed in Comparative Example 2. In Examples 1 and 8 and Comparative Example 1, the same as -17-

The standard of this paper is applicable to the Chinese National Standard (CNS) A4 (2lOX2_9Ti ^ T (please read the precautions on the back before filling out this page)-installed. Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

CtGS38 V. Description of the invention (15) " Dolfoam " Equal foaming degree. The emulsifiable composition of the present invention for insect control, especially insects, especially termites, when diluted in water to prepare a spray emulsion suitable for application, did not observe any crystallization phenomenon, so it was found It can be used for insect control, especially for foam control for white sacrificial control. A7 B7 (Please read the precautions on the back before filling in this page) »n n — ^ n 1 1 taxi-ball book -18- This paper wave scale is applicable to the Chinese National Standard (CNS) 8.4 Lilo (210X297mm)

Claims (1)

Patent No. 84113057 Chinese Patent Application Λ8 Β8 C8 D8 a 2.11 Printed by the Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economy 6. Patent Application 1_ An emulsifiable composition for insect control, which contains 0.2 to 0.2% as an active ingredient 10% of the compound of formula (1) and 0.1 to 10% of pyrethroids, and further contains 1 to 15% of weakly polar solvents and 5 to 20% of emulsifier, and 1 to 5% foam stabilizer, and / or 0 to 15% of polar solvents and / or 0 to 20% of aromatic solvents and at least one water-soluble agent as supplements up to 100% Supplement, the proportion of such (this _. Etc.) solvent in the composition of the present invention exceeds 40%, and the weak polar solvent has a dipole moment higher than 1 and a water solubility lower than 10%; wherein (I) is H4-R1 2,6- (R2) p phenyl] -3-cyano-4- [R4-S (0) n] 5-R5 ^ also (1) Where: R1 is halogen, low-carbon haloalkyl, low-carbon haloalkoxy or sf5 (low-carbon number refers to an integer from 1 to 4), R2 is halogen, and each R2 may be the same or different R4 is halogen, low-carbon alkyl or haloalkyl, R5 is halogen, low-carbon alkyl or amine, η is 0 or 1 or 2; and p is 0 or 1 or 2. 2. The composition according to item i of the scope of the patent application, where Ri is halomethyl or the size of this paper is applicable to the Chinese National Standard (CNS) A4 washing grid (210X: 297 mm) II binding --- 11- ' Quan (please read the precautions on the back before filling this page) d · έΓ C8j 4- Λ Ί 出 -9 Compiled by the Ministry of Economic Affairs, Central Standardization Bureau, Employee Consumer Cooperative Printing Policy 4. The scope of patent application Halomethoxy; and p is 2. 3. The composition according to item 1 of patent application Fan Gu, wherein the compound of formula ⑴ is 5-amino-3-cyano-l- (2,6-digas-4-trifluoromethylphenyl) · 4-Trifluoromethylene is indeed brewed than Biling. 4. The composition according to item 1 of the patent application scope, wherein the pyrethroids are selected from the group consisting of Allethrin, Ethofenprox, Cycloprothrin and Cylo Cyhalothrin, Cyfluthrin 'Cypermethrin, Pyrethrin, Tralomethrin, Fenvalerate, Fenpropathrin, Husaining (Flucythrinate), Permethrin, Bifenthrin, Silafluofen, Resmethrin, Tefluthrin, Akulina vinegar ( Acrinathrin), Prarethrin, Cismethrin, Phenothrin, Deltamethrin, Tetramethrin, Fluvalinate In the group consisting of 3 5. The composition according to item 丨 of the patent application scope, which contains a weakly polar solvent selected from the group consisting of N-octyl-2-pyrrolidone and N-dodecyl- 2-pyrrolidone and N-dodecyl-caprolactam, and hydroxyethyl ether. 6. The composition according to item 1 of the patent application scope, which contains a nonionic or anionic emulsifier. 7. The composition according to item -k of the patent application scope, which contains a water-soluble solvent having the general formula R〇 (CH2CH20) qH 'where R represents C-1 to C-6 alkyl and q is 1 to An integer of 8. -2- (Please read the note $ item on the back before filling this page) Order J 'Patent application scope A8 B8 C8 D8 8 · Push' The composition according to item 7 of the patent application scope, wherein the water solubility is a &-alcohol bond 'which is selected from the group consisting of diethylene glycol monomethyl ether, diethylene glycol Monoethyl alcohol, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monopropyl ether, triethylene glycol monopropyl ether, triethylene glycol monobutyl ether and polyethylene glycol A group of squints. 9. The composition according to claim 1 of patent application Fan Gu, which comprises a foam stabilizer 'which is a high carbon number alcohol. -10. According to the combination description of item 9 of patent application Fan Gu, wherein the foam stabilizer is a fatty alcohol. 11. The composition according to item 10 of the patent application scope, wherein the fatty alcohol is selected from the group consisting of decanol, dodecanol, tetradecyl alcohol, cetyl alcohol, and the like. 12. The composition according to item 1 of the patent application scope further includes a polar solvent having a dipole moment higher than 1 and a water solubility higher than 10%. 13. The composition according to item 12 of the scope of the patent application, wherein the solvent is selected from N-methyl-2-ρbiloxanone and N-cyclohexyl-2-pbihalbitan_ or caprolactone Or butyrolactone or tripropylene glycol monomethyl ether or diglyme. 14_ The composition according to item 1 of the scope of the patent application, which contains an aromatic agent ' the solvent is liquid at temperatures below 30 ° C. It is liquid at a temperature and / or has a boiling point of at least 200 ° C. 15. The composition according to item f of the patent application scope, wherein the weight ratio of the compound of formula (I) to pyrethroid is in the range of 1 to 10. 16. The composition according to item 1 of the patent application scope, which still contains a bubble sword 3-I National Standard for Paper ([Milk] Person 4 Specification (210 father 297 mm) -------- J ^ Installation -------- order ----- one salt (please read the precautions on the back and then fill out this page) '· Please apply for the patent scope A8 charge in the printing and printing six of the employee consumer cooperative of the China Standards Bureau of the Ministry of Economic Affairs. 5. -2. Marriage and / or a foam stabilizer of the employee consumer cooperative of the Central Standards Bureau of the Ministry of Economy. 17. The composition according to item 1 of the patent application garden, which contains 0.5 to 5% of the compound of formula (I), and / or 0.1 to 10% of pyrethroid, and / or 1 to 10% of the weak Polar solvents, and / or 5 to 20% of emulsifiers, and / or 1 to 5% of foam stabilizers, and / or 0 to 112% of polar solvents and products, or 0 Up to 20% of aromatic solvents and at least one water-soluble solvent are used as supplements up to 100%. The proportion of such solvents (s) in the composition of the present invention exceeds 400 / 〇. 18. The composition according to item 17 of the patent application scope, which contains 1 to 5% of the compound of formula (I), and / or 0.1 to 10% of pyrethroid, and / or 2 to 10% of the weak Polar solvents, and / or 5 to 20% emulsifier, and / or 1 to 2 ° / as appropriate. Foam stabilizer, and / or 0-15% of polar solvent and / or 0-20% of aromatic solvent and at least one water-soluble solvent as the supplement to 100%. The proportion of these solvents (s) in the composition of the present invention exceeds 40%. 19_ The composition according to item -k of the scope of the patent application, in which the proportion of such (these) solvents in the composition of the invention exceeds 60% ^ ------------ ,-/ ------ iT ------ ^ (Please read the precautions on the back before filling in this page) · Guang 1 2 The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm )