TW202307301A - Air texturized yarns - Google Patents
Air texturized yarns Download PDFInfo
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- TW202307301A TW202307301A TW111110727A TW111110727A TW202307301A TW 202307301 A TW202307301 A TW 202307301A TW 111110727 A TW111110727 A TW 111110727A TW 111110727 A TW111110727 A TW 111110727A TW 202307301 A TW202307301 A TW 202307301A
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- Prior art keywords
- nylon
- polyamide
- homopolymer
- yarn
- bicomponent
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- 239000000835 fiber Substances 0.000 claims abstract description 103
- 239000004744 fabric Substances 0.000 claims abstract description 67
- 239000004952 Polyamide Substances 0.000 claims abstract description 55
- 229920002647 polyamide Polymers 0.000 claims abstract description 55
- 229920000728 polyester Polymers 0.000 claims abstract description 52
- 238000000034 method Methods 0.000 claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- -1 poly(ethylene terephthalate) Polymers 0.000 claims description 62
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 40
- 229920001519 homopolymer Polymers 0.000 claims description 39
- 229920001778 nylon Polymers 0.000 claims description 24
- 239000004677 Nylon Substances 0.000 claims description 23
- 229920000642 polymer Polymers 0.000 claims description 23
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 16
- 238000011084 recovery Methods 0.000 claims description 15
- 230000000694 effects Effects 0.000 claims description 14
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 13
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 13
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims description 12
- 229920002215 polytrimethylene terephthalate Polymers 0.000 claims description 11
- 229920002292 Nylon 6 Polymers 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 8
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 7
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 7
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 6
- 229920000299 Nylon 12 Polymers 0.000 claims description 6
- 229920003189 Nylon 4,6 Polymers 0.000 claims description 4
- 229920000572 Nylon 6/12 Polymers 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- JMLPVHXESHXUSV-UHFFFAOYSA-N dodecane-1,1-diamine Chemical compound CCCCCCCCCCCC(N)N JMLPVHXESHXUSV-UHFFFAOYSA-N 0.000 claims description 4
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 claims description 4
- 239000011112 polyethylene naphthalate Substances 0.000 claims description 4
- 229920000297 Rayon Polymers 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 10
- 239000000178 monomer Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 229920001634 Copolyester Polymers 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 5
- 235000011037 adipic acid Nutrition 0.000 description 5
- 239000001361 adipic acid Substances 0.000 description 5
- 239000012467 final product Substances 0.000 description 5
- 229920001897 terpolymer Polymers 0.000 description 5
- 229920002334 Spandex Polymers 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 230000001186 cumulative effect Effects 0.000 description 4
- 125000001475 halogen functional group Chemical group 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 230000008961 swelling Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 229920006017 homo-polyamide Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229920001059 synthetic polymer Polymers 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- PNKIKVBTAQOSRP-UHFFFAOYSA-N 2-ethylhexanediamide Chemical compound CCC(C(N)=O)CCCC(N)=O PNKIKVBTAQOSRP-UHFFFAOYSA-N 0.000 description 2
- KIPDSRUZPCSGIJ-UHFFFAOYSA-N 2-methylhexanediamide Chemical compound NC(=O)C(C)CCCC(N)=O KIPDSRUZPCSGIJ-UHFFFAOYSA-N 0.000 description 2
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- OXIKYYJDTWKERT-UHFFFAOYSA-N [4-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCC(CN)CC1 OXIKYYJDTWKERT-UHFFFAOYSA-N 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000002788 crimping Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 229920001748 polybutylene Polymers 0.000 description 2
- 229920006123 polyhexamethylene isophthalamide Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- RAOOWULTQBCYEM-UHFFFAOYSA-N 1,4-dioxane-2,2-dicarboxylic acid Chemical compound OC(=O)C1(C(O)=O)COCCO1 RAOOWULTQBCYEM-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- NMYFVWYGKGVPIW-UHFFFAOYSA-N 3,7-dioxabicyclo[7.2.2]trideca-1(11),9,12-triene-2,8-dione Chemical compound O=C1OCCCOC(=O)C2=CC=C1C=C2 NMYFVWYGKGVPIW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000013305 flexible fiber Substances 0.000 description 1
- AEDIXYWIVPYNBI-UHFFFAOYSA-N heptanamide Chemical compound CCCCCCC(N)=O AEDIXYWIVPYNBI-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 239000003658 microfiber Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- YXTFRJVQOWZDPP-UHFFFAOYSA-M sodium;3,5-dicarboxybenzenesulfonate Chemical compound [Na+].OC(=O)C1=CC(C(O)=O)=CC(S([O-])(=O)=O)=C1 YXTFRJVQOWZDPP-UHFFFAOYSA-M 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G1/00—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
- D02G1/16—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam
- D02G1/165—Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam characterised by the use of certain filaments or yarns
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/292—Conjugate, i.e. bi- or multicomponent, fibres or filaments
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Woven Fabrics (AREA)
- Multicomponent Fibers (AREA)
Abstract
Description
本發明係關於包含芯纖維及聚醯胺或聚酯纖維之空氣變形紗、包含空氣變形紗之織物,以及用於製造空氣變形紗及其織物及服裝之方法。The present invention relates to air textured yarns comprising core fibers and polyamide or polyester fibers, fabrics comprising air textured yarns, and methods for manufacturing air textured yarns and fabrics and garments thereof.
由於耐綸紗具有耐久性、變通性及其能夠穿戴多次而不損失效能特性,因此耐綸紗用於多種針織及編織物。然而,儘管耐綸以輕量且同時展現極佳強度、耐磨性、光澤及彈性而著稱,但此合成聚合物不具有柔軟手感,使其對於服裝用途為不合需要的。Nylon yarns are used in many knits and knits due to their durability, flexibility and their ability to be worn many times without loss of performance characteristics. However, although nylon is known for being lightweight while exhibiting excellent strength, abrasion resistance, luster, and elasticity, this synthetic polymer does not have a soft hand, making it undesirable for apparel use.
因此,已持續投入工作以獲得具有柔軟手感及拉伸與回復效應的視覺上美觀的織物。Therefore, work has continued to be done to obtain visually pleasing fabrics with a soft hand and stretch and recovery effects.
經揭示之SUPPLEX®耐綸為看起來及感覺更像棉花但仍具有耐綸纖維之耐久性的一類耐綸。為了製成SUPPLEX®,經由儘可能最小之孔擠出耐綸,產生超薄、輕量且可撓之纖維。可將數千根此等超細纖維纏繞在一起以形成所揭示之SUPPLEX®織物,其如棉花般柔軟但不收縮、起皺或褪色。The disclosed SUPPLEX® nylon is a class of nylon that looks and feels more like cotton but still has the durability of nylon fibers. To make SUPPLEX®, nylon is extruded through the smallest possible holes, resulting in ultra-thin, lightweight and flexible fibers. Thousands of these microfibers can be intertwined together to form the disclosed SUPPLEX® fabric, which is soft like cotton but does not shrink, wrinkle or fade.
在一些應用中,耐綸紗已用於藉由絞撚或藉由噴氣變形來覆蓋彈性人造纖維。因此,由此等紗製成之一些織物具有良好拉伸性及回復性,但通常不具有所需之視覺美觀性。此外,彈性人造纖維為橡膠纖維,其不良好吸收染料。此外,因為彈性人造纖維為橡膠纖維,所以其不提供所需柔軟感或「手感」。In some applications, nylon yarns have been used to cover elastane by twisting or by air texturing. As a result, some fabrics made from these yarns have good stretch and recovery, but often do not have the desired visual aesthetics. Furthermore, elastane is a rubber fiber which does not absorb dyes well. Furthermore, because elastane is a rubber fiber, it does not provide the desired soft feel or "hand."
其他成果已導向製造雙組分紗。舉例而言,美國專利第4,601,949及第4,740,339號教示聚醯胺結合物長絲或雙組分紗,及使用直列式紡紗及拉伸方法製備其之方法。類似地,美國專利第3,671,379號揭示藉由熔紡、拉伸及退火製備之聚(對苯二甲酸乙二酯)及聚(對苯二甲酸丙二酯)之雙組分纖維。Other efforts have led to the manufacture of bicomponent yarns. For example, US Patent Nos. 4,601,949 and 4,740,339 teach polyamide conjugate filament or bicomponent yarns and methods of making them using in-line spinning and drawing methods. Similarly, US Patent No. 3,671,379 discloses bicomponent fibers of poly(ethylene terephthalate) and poly(trimethylene terephthalate) prepared by melt spinning, drawing and annealing.
如此等專利中所描述之雙組分紗之益處為其產生適用於伸展服裝之構造的膨脹或捲曲效果。舉例而言,此等專利教示藉由在雙組分紗中使用具有不同收縮之聚合物,可獲得所需膨脹或捲曲效果。此差別收縮可藉由使用不同聚合物或使用具有不同相對黏度之類似聚合物來獲得。然而,僅由雙組分紗構成之織物通常不具有所需視覺效果、柔軟手感及拉伸性及回復性。A benefit of bicomponent yarns as described in these patents is that they create a swelling or curling effect suitable for the construction of stretch garments. For example, these patents teach that by using polymers with different shrinkages in bicomponent yarns, the desired swelling or curling effects can be obtained. This differential shrinkage can be obtained by using different polymers or by using similar polymers with different relative viscosities. However, fabrics composed only of bicomponent yarns generally do not have the desired visual effects, soft hand, and stretch and recovery properties.
美國專利第6,548,429號揭示一種包含雙組分紗及第二紗之雙組分花式紗,其可針織或編織成具有所需視覺衝擊力、手感及拉伸性及回復性之織物。此外,因為此等編織物較佳由耐綸紗製成,所以其亦為可染的且耐用的。揭示由此等紗製成之織物的紋理與已知其他織物相比具有光滑且天鵝絨般的手感。US Patent No. 6,548,429 discloses a bicomponent fancy yarn comprising a bicomponent yarn and a second yarn, which can be knitted or woven into a fabric with desired visual impact, hand feeling, stretchability and recovery. Furthermore, since these braids are preferably made of nylon yarn, they are also dyeable and durable. The texture of fabrics made from these yarns was revealed to have a smooth and velvety hand compared to other known fabrics.
需要紗及此類紗製造之織物及服裝,其提供涼爽及乾燥效果,同時亦提供高拉伸性及回復性,且較長時間保持形狀。There is a need for yarns and fabrics and garments made from such yarns that provide cooling and drying benefits while also providing high stretch and recovery and retaining shape for longer periods of time.
本發明之一態樣係關於包含芯纖維及聚醯胺或聚酯纖維之紗,該紗藉由噴氣變形產生,其可用於織物及服裝中以提供涼爽及乾燥效果,同時亦提供高拉伸性及回復性,且較長時間保持形狀。One aspect of the present invention relates to a yarn comprising a core fiber and a polyamide or polyester fiber, produced by air jet texturing, which can be used in fabrics and garments to provide cooling and drying effects while also providing high stretch Resilience and recovery, and keep the shape for a long time.
本發明之另一態樣係關於一種用於製造供織物及服裝之用的紗的方法,該等織物及服裝具有涼爽及乾燥效果、高拉伸性及回復性且較長時間保持形狀,該方法包含將芯纖維及聚醯胺或聚酯纖維一起空氣變形。Another aspect of the present invention relates to a method for manufacturing yarns for fabrics and garments having cooling and drying effects, high stretch and recovery, and long-term shape retention, which The method involves air texturing a core fiber together with a polyamide or polyester fiber.
本發明之另一態樣係關於具有涼爽及乾燥效果、高拉伸性及回復性且較長時間保持形狀之織物及服裝,其包含紗,該紗藉由噴氣變形產生,包含芯纖維及聚醯胺或聚酯纖維。Another aspect of the invention relates to fabrics and garments with cooling and drying effects, high stretch and recovery, and long-term shape retention, comprising yarns produced by air-jet texturing, comprising core fibers and polyester Amide or polyester fibers.
本專利申請案主張2021年3月25日申請之美國臨時申請案第63/165,987號之優先權,該案之內容以全文引用之方式併入本文中。This patent application claims priority to U.S. Provisional Application Serial No. 63/165,987, filed March 25, 2021, the contents of which are hereby incorporated by reference in their entirety.
本發明提供空氣變形紗及含有該紗之織物及服裝,其展現涼爽及乾燥效果、高拉伸性及回復性且較長時間保持形狀。The present invention provides air textured yarns and fabrics and garments containing the yarns, which exhibit cooling and drying effects, high stretchability and recovery, and maintain shape for a longer period of time.
本發明之紗包含芯纖維。The yarns of the present invention comprise a core fiber.
在一個非限制性實施例中,芯纖維為聚酯纖維。In one non-limiting example, the core fiber is polyester fiber.
在一個非限制性實施例中,芯纖維為雙組分纖維。In one non-limiting embodiment, the core fiber is a bicomponent fiber.
本文中可互換使用之術語「雙組分纖維」與「雙組分紗」係指至少兩種可熔紡纖維組分之結合產物,其中該結合產物具有至少兩種不同縱向共延之聚合鏈段。纖維組分由此項技術中已知之任何適合的可熔紡纖維形成聚合物構成。用於雙組分之第一及/或第二組分的適合纖維形成聚合物包括聚醯胺、聚烯烴(諸如聚乙烯及聚丙烯)、聚酯、黏液聚合物(諸如嫘縈)及乙酸酯之任何均聚物、共聚物及三元共聚物。術語「雙組分」並不意欲受限於僅兩種組分,而是意欲包括三種或更多種組分,其將產生具有至少三種或更多種不同的縱向共延之聚合鏈段的結合產物。此類雙組分可稱為多組分纖維。The terms "bicomponent fiber" and "bicomponent yarn" are used interchangeably herein to refer to the combined product of at least two melt-spinnable fiber components, wherein the combined product has at least two different longitudinally coextensive polymeric chains part. The fiber component is composed of any suitable melt-spinnable fiber-forming polymer known in the art. Suitable fiber-forming polymers for the first and/or second components of the bicomponent include polyamides, polyolefins (such as polyethylene and polypropylene), polyesters, viscopolymers (such as rayon), and vinyl Any homopolymers, copolymers and terpolymers of acid esters. The term "bicomponent" is not intended to be limited to only two components, but is intended to include three or more components that will result in a composition having at least three or more different longitudinally coextensive polymeric segments. combined product. Such bicomponents may be referred to as multicomponent fibers.
較佳雙組分纖維係包含沿纖維長度彼此緊密黏著之一對聚合物的纖維,使得纖維橫截面為例如並列、偏心鞘芯型或可產生適用捲曲之其他適合橫截面。此外,較佳地,纖維具有相當大之體積。Preferred bicomponent fibers are fibers comprising a pair of polymers intimately adhered to each other along the length of the fiber such that the fiber cross-section is, for example, side-by-side, eccentric sheath-core, or other suitable cross-section that produces a suitable crimp. Furthermore, preferably, the fibers have a relatively large volume.
如本文所用,術語「收縮」係指在暴露於濕熱時,雙組分纖維之各組分的縱向尺寸之減小。雙組分纖維的組分之間的此差別收縮可藉由選擇在聚合物類型、聚合物特性(諸如相對黏度、可結晶特性、橫截面、存在於各聚合鏈段中之添加劑之量或此等特性之組合)中之一或多者方面不同的纖維形成聚合物而獲得。雙組分纖維之組分的此等差異提供差別收縮以實現膨脹效應或不同縱向共延之聚合鏈段。雙組分纖維之組分可視需要佈置,例如以並列或鞘芯型佈置。為了得到最佳美觀效果,鞘芯應較佳地具有偏心或不對稱鞘芯型佈置。As used herein, the term "shrinkage" refers to the reduction in the longitudinal dimension of each component of a bicomponent fiber upon exposure to moist heat. This differential shrinkage between the components of a bicomponent fiber can be determined by selection of the polymer type, polymer properties such as relative viscosity, crystallizable properties, cross-section, amount of additives present in each polymeric segment, or the like. Combination of properties such as) in one or more aspects of different fiber-forming polymers obtained. These differences in the components of the bicomponent fibers provide differential shrinkage to achieve swelling effects or different longitudinally coextensive polymeric segments. The components of the bicomponent fiber can be arranged as desired, for example in a side-by-side or sheath-core arrangement. For best aesthetics, the sheath core should preferably have an eccentric or asymmetric sheath core type arrangement.
雙組分纖維芯之適合聚醯胺包括但不限於:聚六亞甲基己二醯胺均聚物(耐綸66);聚己醯胺均聚物(耐綸6);聚庚醯胺均聚物(耐綸7);耐綸10;聚十二烷內醯胺均聚物(耐綸12);聚己二醯丁二胺均聚物(耐綸46);聚六亞甲基癸二醯胺均聚物(耐綸610);正十二烷二酸及己二胺之聚醯胺均聚物(耐綸612);及十二亞甲基二胺及正十二烷二酸之聚醯胺均聚物(耐綸1212)。用於形成上述均聚物之單體的共聚物及三元共聚物亦適用於本發明。Suitable polyamides for the bicomponent fiber core include, but are not limited to: polyhexamethylene adipamide homopolymer (nylon 66); polycapamide homopolymer (nylon 6); polyheptanamide Homopolymer (Nylon 7); Nylon 10; Polydodecanylamide Homopolymer (Nylon 12); Polybutylene Adipamide Homopolymer (Nylon 46); Polyhexamethylene Sebacamide homopolymer (nylon 610); polyamide homopolymer of n-dodecanedioic acid and hexamethylenediamine (nylon 612); and dodecanediamine and n-dodecanediamine Polyamide homopolymer of acid (Nylon 1212). Copolymers and terpolymers of the monomers used to form the homopolymers described above are also suitable for use in the present invention.
用於雙組分纖維芯之適合共聚醯胺包括但不限於用於形成上述均聚醯胺之單體的共聚物。另外,其他適合的共聚醯胺包括例如與耐綸6、耐綸7、耐綸10及/或耐綸12接觸且緊密混合的耐綸66。例示性聚醯胺亦包括由以下製得之共聚物:二羧酸組分,諸如對苯二甲酸、間苯二甲酸、己二酸或癸二酸;醯胺組分,諸如聚六亞甲基對苯二甲醯胺、聚-2-甲基己二醯戊二胺、聚-2-乙基己二醯丁二胺或聚六亞甲基間苯二甲醯胺;二胺組分,諸如己二胺及2-甲基戊二胺;及1,4-雙(胺基甲基)環己烷。較佳地,雙組分紗之一種組分為與聚-2-甲基己二醯戊二胺(MPMD)共聚合之耐綸66的共聚醯胺。此共聚醯胺可藉由使己二酸、己二胺及MPMD聚合在一起製得。最佳地,雙組分紗之一種組分為與聚-2-甲基己二醯戊二胺共聚合之耐綸66的共聚醯胺,且第二組分為耐綸66。Suitable copolyamides for bicomponent fiber cores include, but are not limited to, copolymers of the monomers used to form the homopolyamides described above. Additionally, other suitable copolyamides include, for example, Nylon 66 in contact with Nylon 6, Nylon 7, Nylon 10, and/or Nylon 12 and intimately mixed. Exemplary polyamides also include copolymers made from dicarboxylic acid components such as terephthalic acid, isophthalic acid, adipic acid, or sebacic acid; amide components such as polyhexamethylene phenylterephthalamide, poly-2-methylpentamethyleneadipamide, poly-2-ethyladipamide butylenediamine or polyhexamethyleneisophthalamide; diamine component , such as hexamethylenediamine and 2-methylpentamethylenediamine; and 1,4-bis(aminomethyl)cyclohexane. Preferably, one component of the bicomponent yarn is a copolyamide of nylon 66 copolymerized with poly-2-methyladipamide (MPMD). This copolyamide can be prepared by polymerizing adipic acid, hexamethylenediamine and MPMD together. Most preferably, one component of the bicomponent yarn is a copolyamide of nylon 66 copolymerized with poly-2-methylpentamethylene adipamide, and the second component is nylon 66.
以上共聚醯胺可藉由此項技術中已知之方法製得。舉例而言,適合之共聚醯胺可藉由混合固定比例之呈薄片或聚合物顆粒形式之各聚醯胺組分且以均質長絲形式擠出而製得。或者,共聚醯胺可藉由在高壓釜中混合適當單體且進行如此項技術中已知之聚醯胺化方法而製得。任一方法均適合於製備本發明中所用之共聚醯胺。The above copolyamides can be prepared by methods known in the art. For example, suitable copolyamides can be prepared by mixing fixed proportions of the individual polyamide components in the form of flakes or polymer pellets and extruding in the form of homogeneous filaments. Alternatively, copolyamides can be prepared by mixing the appropriate monomers in an autoclave and performing a polyamidation process as known in the art. Either method is suitable for preparing the copolyamides used in the present invention.
用於形成上述均聚物之單體的三元聚醯胺亦可適用於本發明且可藉由此項技術中已知之方法製得。Terpolymers of the monomers used to form the homopolymers described above are also suitable for use in the present invention and can be prepared by methods known in the art.
雙組分紗之纖維形成聚合物亦可為任何已知聚酯,包括聚對苯二甲酸乙二酯(PET)、聚萘二甲酸乙二酯、聚對苯二甲酸丙二酯及聚對苯二甲酸丁二酯。聚(對苯二甲酸丙二酯)亦稱為聚(對苯二甲酸丙二酯),且聚(對苯二甲酸丁二酯)亦稱為聚(對苯二甲酸丁二酯)。聚酯可為此等聚酯之均聚物或共聚物。聚酯可藉由此項技術中已知之方法製得。The fiber-forming polymer of the bicomponent yarn can also be any known polyester, including polyethylene terephthalate (PET), polyethylene naphthalate, polytrimethylene terephthalate, and polyethylene terephthalate Butylene phthalate. Poly(trimethylene terephthalate) is also known as poly(trimethylene terephthalate), and poly(butylene terephthalate) is also known as poly(butylene terephthalate). The polyesters may be homopolymers or copolymers of such polyesters. Polyesters can be prepared by methods known in the art.
接下來描述較佳聚酯。符號「//」用於分隔用於製造雙組分纖維的兩種聚合物。「2G」意謂乙二醇,「3G」意謂1,3-丙二醇,「4G」意謂1,4-丁二醇,及「T」意謂對苯二甲酸。因此,例如,「2G-T//3G-T」指示包含聚(對苯二甲酸乙二酯)及聚(對苯二甲酸丙二酯)之雙組分纖維。Preferred polyesters are described next. The symbol "//" is used to separate the two polymers used to make bicomponent fibers. "2G" means ethylene glycol, "3G" means 1,3-propanediol, "4G" means 1,4-butanediol, and "T" means terephthalic acid. Thus, for example, "2G-T//3G-T" indicates a bicomponent fiber comprising poly(ethylene terephthalate) and poly(trimethylene terephthalate).
用於本發明之雙組分花式紗之聚酯雙組分的兩種聚酯可具有不同組成,例如2G-T及3-G-T (較佳)或2G-T及4G-T,且較佳具有不同固有黏度。或者,其組成可為相同的,例如2G-T,但固有黏度可不同。其他有用聚酯包括聚(2,6-二萘二甲酸乙二酯、聚(2,6-二萘二甲酸丙二酯)、聚(聯苯甲酸丙二酯)、聚(對苯二甲酸1,4-環己二亞甲酯)、聚(對苯二甲酸1,3-環丁烷二亞甲酯)及聚(聯苯甲酸1,3-環丁烷二亞甲酯)。聚合物在固有黏度(「IV」)及組成方面均不同為有利的,例如具有約0.45-0.80 dl/g之IV的2G-T及具有約0.85-1.50 dl/g之IV的3G-T,以達成高熱定型後捲曲收縮值。The two polyesters used in the polyester bicomponent of the bicomponent fancy yarn of the present invention can have different compositions, such as 2G-T and 3-G-T (preferred) or 2G-T and 4G-T, and are more Best have different intrinsic viscosities. Alternatively, the composition can be the same, eg 2G-T, but the intrinsic viscosity can be different. Other useful polyesters include poly(ethylene 2,6-dinaphthalate), poly(trimethylene 2,6-dinaphthalate), poly(trimethylene bibenzoate), poly(trimethylene terephthalate 1,4-cyclohexanedimethylene), poly(1,3-cyclobutanedimethylene terephthalate) and poly(1,3-cyclobutanedimethylene dibenzoate). Polymerization Advantageously, the compounds differ in both intrinsic viscosity ("IV") and composition, for example 2G-T having an IV of about 0.45-0.80 dl/g and 3G-T having an IV of about 0.85-1.50 dl/g, and Achieve curl shrinkage after high heat styling.
聚酯雙組分纖維中之一或兩種聚酯可為共聚酯。舉例而言,可使用共聚(對苯二甲酸乙二酯),其中用於製造共聚酯的共聚單體為間苯二甲酸、戊二酸、己二酸、1,3-丙二醇或1,4-丁二醇。共聚單體可以約0.5至15莫耳%之量存在於共聚酯中。當兩種聚酯在其他方面相同時,共聚酯之使用可尤其適用,例如2G-T//2G-T/I。共聚酯亦可含有少量其他共聚單體,諸如約0.2至5莫耳%之量的5-磺酸基間苯二甲酸鈉,其限制條件為此類共聚單體對本發明之有利效果不具有不良影響。One or both of the polyesters in the polyester bicomponent fibers may be copolyesters. For example, copoly(ethylene terephthalate) can be used, where the comonomer used to make the copolyester is isophthalic acid, glutaric acid, adipic acid, 1,3-propanediol or 1, 4-butanediol. Comonomers may be present in the copolyester in amounts of about 0.5 to 15 mole percent. The use of copolyesters may be especially useful when the two polyesters are otherwise identical, eg 2G-T//2G-T/I. The copolyesters may also contain small amounts of other comonomers, such as sodium 5-sulfoisophthalate in amounts of about 0.2 to 5 mole percent, provided that such comonomers do not adversely contribute to the beneficial effects of the present invention Influence.
用於構成雙組分纖維之聚合物可具有任何橫截面形狀。舉例而言,橫截面形狀可包括圓形、橢圓形、三葉形、對稱葉數較多的形狀,以及狗骨形。The polymers used to form the bicomponent fibers can have any cross-sectional shape. For example, cross-sectional shapes may include circles, ovals, trilobes, shapes with more symmetrical lobes, and dog-bone shapes.
在一個非限制性實施例中,雙組分芯纖維為雙組分長絲。In one non-limiting example, the bicomponent core fiber is a bicomponent filament.
「雙組分長絲」意謂一種長絲,其包含聚(對苯二甲酸乙二酯)及聚(對苯二甲酸丙二酯)沿著長絲之長度彼此緊密黏著,使得長絲橫截面為例如並列、偏心鞘芯型或可產生適用捲曲之其他適合橫截面。此類長絲為非彈性的,因為不依賴於任何捲曲,其不具有超過100%之斷裂伸長率。相反地,其依賴於螺旋捲曲以獲得其彈性,藉由熱處理長絲自發形成。進行本發明方法之並列長絲可具有「雪人」、橢圓形或實質上圓形之橫截面形狀。偏心鞘芯型纖維可具有橢圓形或實質上圓形的橫截面形狀。「實質上圓形」意謂在纖維橫截面之中心處以90°彼此交叉之兩個軸之長度的比不大於約1.2:1。「橢圓形」意謂在纖維橫截面之中心處以90°彼此交叉之兩個軸之長度的比大於約1.2:1。「雪人」橫截面形狀可描述為並列橫截面,其具有長軸、實質上垂直於長軸之短軸、及在對照長軸繪製時短軸長度上之至少兩個最大值。"Bicomponent filament" means a filament comprising poly(ethylene terephthalate) and poly(trimethylene terephthalate) tightly adhered to each other along the length of the filament such that the filament crosswise The cross-section is, for example, side-by-side, eccentric sheath-core, or other suitable cross-section that produces a suitable crimp. Such filaments are inelastic in that, independent of any crimp, they do not have an elongation at break of more than 100%. Instead, it relies on helical coiling for its elasticity, with the filaments forming spontaneously by heat treatment. The side-by-side filaments subjected to the method of the invention may have a "snowman", oval, or substantially circular cross-sectional shape. Eccentric sheath core fibers can have an oval or substantially circular cross-sectional shape. "Substantially circular" means that the ratio of the lengths of two axes that intersect each other at 90° at the center of the fiber cross-section is not greater than about 1.2:1. "Oval" means that the ratio of the lengths of two axes intersecting each other at 90° at the center of the fiber cross-section is greater than about 1.2:1. A "snowman" cross-sectional shape can be described as a juxtaposed cross-section having a major axis, a minor axis substantially perpendicular to the major axis, and at least two maxima in the length of the minor axis when plotted against the major axis.
雙組分纖維之組分中之每一者以足以獲得得到膨脹作用所需之差別收縮的量存在且可藉由已知方法獲得。舉例而言,差別收縮可藉由利用不同類型之聚合物、具有不同特性(諸如相對黏度及可結晶特性)之組分或使用不同比率之組分來獲得。舉例而言,雙組分紗之一種組分可由快速結晶纖維形成聚醯胺形成,而雙組分紗之另一組分由非快速結晶纖維形成聚醯胺形成。如以引用之方式併入本文中的美國專利第4,740,339號所教示,可藉由選擇具有不同末端速度距離之聚醯胺來實現可結晶性之差異,此又引起如藉由高負載捲曲測試值指示之較大膨脹。Each of the components of the bicomponent fiber is present in an amount sufficient to obtain the differential shrinkage required to obtain expansion and can be obtained by known methods. For example, differential shrinkage can be obtained by utilizing different types of polymers, components with different properties such as relative viscosity and crystallizable properties, or using different ratios of components. For example, one component of the bicomponent yarn can be formed from a rapidly crystallizing fiber-forming polyamide while the other component of the bicomponent yarn is formed from a non-rapidly crystallizing fiber-forming polyamide. As taught in U.S. Patent No. 4,740,339, which is incorporated herein by reference, differences in crystallizability can be achieved by selecting polyamides with different terminal velocity distances, which in turn lead to differences in crystallinity as measured by high-load curl test values. Indicates greater expansion.
另一方面,雙組分纖維之組分可基於相對黏度之差異而選擇。當雙組分纖維之一種組分由與雙組分紗之另一組分相同之化學式的結構重複單元構成時,選擇具有不同相對黏度之聚合物產生所需膨脹作用。雙組分紗之組分的相對黏度的差異應足以獲得足夠實現膨脹作用之差別收縮。舉例而言,當使用不同相對黏度(RV)之耐綸66聚醯胺形成聚合鏈段時,該兩種耐綸66之間的RV差值應為至少5,較佳至少15,且最佳至少30,其中低RV耐綸66之RV為至少20,例如至少50,或至少65。較佳地,雙組分紗之組分由相同重複結構單元構成,但其具有不同RV。On the other hand, the components of bicomponent fibers can be selected based on differences in relative viscosities. When one component of the bicomponent fiber is composed of structural repeating units of the same chemical formula as the other component of the bicomponent yarn, polymers having different relative viscosities are selected to produce the desired swelling. The difference in the relative viscosities of the components of the bicomponent yarn should be sufficient to obtain differential shrinkage sufficient to effect expansion. For example, when nylon 66 polyamides of different relative viscosities (RV) are used to form the polymeric segments, the RV difference between the two nylon 66 should be at least 5, preferably at least 15, and optimally At least 30, wherein the RV of the low RV nylon 66 is at least 20, such as at least 50, or at least 65. Preferably, the components of the bicomponent yarn are composed of the same repeating structural units, but have different RVs.
或者,差別收縮可藉由改變雙組分紗中各組分之比率或使用不同類型之聚合物作為各組分以實現。同樣,紗中之每一組分的量應為足以獲得足夠實現膨脹作用之差別收縮的量。Alternatively, differential shrinkage can be achieved by varying the ratio of the components in the bicomponent yarn or using different types of polymers for the components. Likewise, the amount of each component in the yarn should be an amount sufficient to obtain differential shrinkage sufficient to effect expansion.
如本文所用,「膨脹作用」係指雙組分紗之固有的捲曲能力且可藉由在雙組分紗之組分之間具有差別收縮而實現。雙組分紗之固有的捲曲能力有利地允許雙組分紗「自膨脹」,因為其不需要在膨脹此等類型之纖維中使用機械牽伸絞撚或變形方法。完全由此類型之纖維製成的一些織物可具有拉伸性及回復性特性,且手感類似於來自機械變形處理纖維。當使用2G-T//3G-T雙組分時,常常提供比變形處理纖維高得多的拉伸性及回復性。As used herein, "swelling" refers to the inherent crimping capability of a bicomponent yarn and can be achieved by having differential shrinkage between the components of the bicomponent yarn. The inherent crimping ability of bicomponent yarns advantageously allows bicomponent yarns to "self-expand" because it does not require the use of mechanical draft twisting or texturing methods in expanding these types of fibers. Some fabrics made entirely of this type of fiber can have stretch and recovery properties and feel similar to fibers from mechanically deformed treatments. When using 2G-T//3G-T bicomponent, it often provides much higher stretchability and recovery than textured fiber.
製造雙組分纖維之方法為此項技術中已知的且本文所用之彼等雙組分纖維可根據任何已知方法形成。舉例而言,美國專利第4,740,339號以引用之方式併入本文中,描述了一種藉由紡絲拉伸方法製造具有不同相對黏度之雙組分紗,以沿長絲長度形成並列組態的方法。另一已知方法描述於美國專利第4,244,907號及第4,202,854號,其均以引用之方式併入本文中,其中一種製造雙組分紗之方法藉由擠壓單一聚合物以形成單組分熔融流,可在其完全固化之前利用單側冷卻處理或在其完全固化之後利用單側加熱處理,且接著拉伸長絲。可根據已知手段,諸如藉由加熱或汽蒸來進行雙組分紗之拉伸,及使雙組分紗隨後膨脹。此外,雙組分紗可與本發明之合成聚合物紗的生產以連續方式製造。或者,雙組分紗可離線生產且隨後與第二紗合併。Methods of making bicomponent fibers are known in the art and those bicomponent fibers used herein can be formed according to any known method. For example, U.S. Patent No. 4,740,339, incorporated herein by reference, describes a method of making bicomponent yarns of different relative viscosities by a spin-draw process to form side-by-side configurations along the length of the filaments . Another known method is described in U.S. Pat. Nos. 4,244,907 and 4,202,854, both of which are incorporated herein by reference, in which a method of making bicomponent yarns consists of extruding a single polymer to form a monocomponent melt The stream can be treated with one-sided cooling before it is fully solidified or with one-sided heat after it is fully solidified, and the filaments are then drawn. Stretching of the bicomponent yarn and subsequent expansion of the bicomponent yarn can be carried out according to known means, such as by heating or steaming. Furthermore, bicomponent yarns can be produced in a continuous manner with the production of the synthetic polymer yarns of the present invention. Alternatively, bicomponent yarns can be produced off-line and subsequently combined with a second yarn.
本發明之紗進一步包含第二聚醯胺或聚酯纖維。The yarn of the present invention further comprises a second polyamide or polyester fiber.
較佳地,第二聚醯胺或聚酯纖維鬆散地纏繞在芯纖維周圍。Preferably, the second polyamide or polyester fiber is loosely wound around the core fiber.
用於此第二纖維之適合的均聚醯胺包括但不限於:聚六亞甲基己二醯胺均聚物(耐綸66);聚己醯胺均聚物(耐綸6);聚庚醯胺均聚物(耐綸7);耐綸10;聚十二烷內醯胺均聚物(耐綸12);聚己二醯丁二胺均聚物(耐綸46);聚六亞甲基癸二醯胺均聚物(耐綸610);正十二烷二酸及己二胺之聚醯胺均聚物(耐綸612);及十二亞甲基二胺及正十二烷二酸之聚醯胺均聚物(耐綸1212)。用於形成上述均聚物之單體的共聚物及三元共聚物亦適用於本發明。Suitable homopolyamides for this second fiber include, but are not limited to: polyhexamethylene adipamide homopolymer (nylon 66); polycapamide homopolymer (nylon 6); Heptanamide Homopolymer (Nylon 7); Nylon 10; Polydodecanamide Homopolymer (Nylon 12); Polybutylene Adipamide Homopolymer (Nylon 46); Methylene sebacamide homopolymer (nylon 610); polyamide homopolymer of n-dodecanedioic acid and hexamethylenediamine (nylon 612); Polyamide homopolymer of dioxanedioic acid (Nylon 1212). Copolymers and terpolymers of the monomers used to form the homopolymers described above are also suitable for use in the present invention.
適用於此第二纖維之共聚醯胺包括但不限於用於形成上述均聚醯胺之單體的共聚物。另外,其他適合的共聚醯胺包括例如與耐綸6、耐綸7、耐綸10及/或耐綸12接觸且緊密混合的耐綸66。例示性聚醯胺亦包括由以下製得之共聚物:二羧酸組分,諸如對苯二甲酸、間苯二甲酸、己二酸或癸二酸;醯胺組分,諸如聚六亞甲基對苯二甲醯胺、聚-2-甲基己二醯戊二胺、聚-2-乙基己二醯丁二胺或聚六亞甲基間苯二甲醯胺;二胺組分,諸如己二胺及2-甲基戊二胺;及1,4-雙(胺基甲基)環己烷。較佳地,雙組分紗之一種組分為與聚-2-甲基己二醯戊二胺(MPMD)共聚合之耐綸66的共聚醯胺。此共聚醯胺可藉由使己二酸、己二胺及MPMD聚合在一起製得。最佳地,雙組分紗之一種組分為與聚-2-甲基己二醯戊二胺共聚合之耐綸66的共聚醯胺,且第二組分為耐綸66。Copolyamides suitable for use in this second fiber include, but are not limited to, copolymers of the monomers used to form the homopolyamides described above. Additionally, other suitable copolyamides include, for example, Nylon 66 in contact with Nylon 6, Nylon 7, Nylon 10, and/or Nylon 12 and intimately mixed. Exemplary polyamides also include copolymers made from dicarboxylic acid components such as terephthalic acid, isophthalic acid, adipic acid, or sebacic acid; amide components such as polyhexamethylene phenylterephthalamide, poly-2-methylpentamethyleneadipamide, poly-2-ethyladipamide butylenediamine or polyhexamethyleneisophthalamide; diamine component , such as hexamethylenediamine and 2-methylpentamethylenediamine; and 1,4-bis(aminomethyl)cyclohexane. Preferably, one component of the bicomponent yarn is a copolyamide of nylon 66 copolymerized with poly-2-methyladipamide (MPMD). This copolyamide can be prepared by polymerizing adipic acid, hexamethylenediamine and MPMD together. Most preferably, one component of the bicomponent yarn is a copolyamide of nylon 66 copolymerized with poly-2-methylpentamethylene adipamide, and the second component is nylon 66.
以上共聚醯胺可藉由此項技術中已知之方法製得。舉例而言,適合之共聚醯胺可藉由混合固定比例之呈薄片或聚合物顆粒形式之各聚醯胺組分且以均質長絲形式擠出而製得。或者,共聚醯胺可藉由在高壓釜中混合適當單體且進行如此項技術中已知之聚醯胺化方法而製得。任一方法均適合於製備本發明中所用之共聚醯胺。The above copolyamides can be prepared by methods known in the art. For example, suitable copolyamides can be prepared by mixing fixed proportions of the individual polyamide components in the form of flakes or polymer pellets and extruding in the form of homogeneous filaments. Alternatively, copolyamides can be prepared by mixing the appropriate monomers in an autoclave and performing a polyamidation process as known in the art. Either method is suitable for preparing the copolyamides used in the present invention.
用於形成上述均聚物之單體的三元聚醯胺亦可適用於本發明且可藉由此項技術中已知之方法製得。Terpolymers of the monomers used to form the homopolymers described above are also suitable for use in the present invention and can be prepared by methods known in the art.
適用於第二纖維之聚酯包括但不限於聚對苯二甲酸乙二酯(PET)、聚萘二甲酸乙二酯、聚對苯二甲酸丙二酯及聚對苯二甲酸丁二酯。聚(對苯二甲酸丙二酯)亦稱為聚(對苯二甲酸丙二酯),且聚(對苯二甲酸丁二酯)亦稱為聚(對苯二甲酸丁二酯)。聚酯可為此等聚酯之均聚物或共聚物。聚酯可藉由此項技術中已知之方法製得。Polyesters suitable for the second fiber include, but are not limited to, polyethylene terephthalate (PET), polyethylene naphthalate, polytrimethylene terephthalate, and polybutylene terephthalate. Poly(trimethylene terephthalate) is also known as poly(trimethylene terephthalate), and poly(butylene terephthalate) is also known as poly(butylene terephthalate). The polyesters may be homopolymers or copolymers of such polyesters. Polyesters can be prepared by methods known in the art.
在一個非限制性實施例中,第二纖維包含耐綸6或耐綸6,6。In one non-limiting example, the second fiber comprises nylon 6 or nylon 6,6.
在一個非限制性實施例中,本發明之紗由在芯處使用LYCRA® T400®纖維且在花式紗處使用聚醯胺POY 6.6的空氣變形方法產生。In one non-limiting example, yarns of the present invention are produced by air texturing using LYCRA® T400® fiber at the core and polyamide POY 6.6 at the fancy yarn.
如熟習此項技術者將理解且如本文所展現,芯纖維之不同紗組成及聚醯胺或聚酯纖維產生若干最終支數(分德士)。As will be understood by those skilled in the art and as demonstrated herein, different yarn compositions of the core fiber and polyamide or polyester fibers yield several final counts (centex).
根據本發明之芯纖維或第二纖維中所用的聚合物可包含可有助於改良聚合物特性之習知添加劑作為其他成分。此等添加劑之實例包括抗靜電劑、抗氧化劑、抗菌劑、防焰劑、潤滑劑、染料、光穩定劑、聚合反應催化劑及佐劑、黏著促進劑、消光劑(delustrant) (諸如氧化鈦)、消光劑(matting agent),及/或有機亞磷酸鹽。The polymer used in the core fiber or the second fiber according to the invention may contain, as further constituents, conventional additives which may contribute to improving the properties of the polymer. Examples of such additives include antistatic agents, antioxidants, antibacterial agents, flame retardants, lubricants, dyes, light stabilizers, polymerization catalysts and adjuvants, adhesion promoters, delustrants (such as titanium oxide) , a matting agent, and/or an organic phosphite.
視預期用途而定,合併之芯纖維及第二聚醯胺或聚酯纖維可以不同比率存在於最終產物中。最終產物之組分中之每一者的分率可例如根據其總丹尼值及丹尼值/長絲量測。總丹尼值或丹尼值/長絲愈大,最終產物中組分之量愈大。基於此等因素調節組分可實現最終產物之不同功能。舉例而言,較高拉伸性可藉由在最終產物中具有較大分率之聚酯或雙組分纖維獲得。反之,具有較低拉伸性之織物可藉由具有較大分率之第二聚醯胺或聚酯纖維獲得,尤其在第二纖維為單組分紗時。Depending on the intended use, the combined core fiber and the second polyamide or polyester fiber may be present in different ratios in the final product. The fraction of each of the components of the final product can be measured, for example, in terms of its total Deny and Deny per filament. The greater the total denier or denier/filament, the greater the amount of component in the final product. Adjusting the components based on these factors can achieve different functions of the final product. For example, higher stretchability can be achieved by having a greater fraction of polyester or bicomponent fibers in the final product. Conversely, fabrics with lower stretchability can be obtained by having a larger fraction of second polyamide or polyester fibers, especially when the second fibers are monocomponent yarns.
在本發明中,芯纖維與第二聚醯胺或聚酯紗經由噴氣變形合併以形成單一紗。聚酯或雙組分芯纖維及第二聚醯胺或聚酯纖維中之每一者可分別離線製得,且隨後經由噴氣變形合併,經由雙重紗之加料,在芯中饋入聚酯或雙組分纖維及同時在外部饋入第二聚醯胺或聚酯纖維,以形成最終合成聚合物。In the present invention, the core fiber is combined with a second polyamide or polyester yarn via air-jet texturing to form a single yarn. Each of the polyester or bicomponent core fiber and the second polyamide or polyester fiber can be produced separately off-line and then combined via air-jet texturing, feeding polyester or polyester in the core via double yarn feed. Bicomponent fibers with simultaneous external feeding of a second polyamide or polyester fiber to form the final synthetic polymer.
已經發現,經由噴氣變形生產此芯纖維及第二聚醯胺或聚酯纖維(較佳地鬆散纏繞於芯纖維外部周圍)產生合成紗,其視覺上類似於棉紗,具有高捲曲收縮、高彈性及紗上約20%至約33%的高潛在伸長率。此外,包含此空氣變形紗之織物出乎意料地展現涼爽及乾燥效果以及優良手感。已發現使用本發明之空氣變形紗,有可能製備比藉由100%聚醯胺變形紗製得之原始SUPPLEX®織物具有更高的拉伸性及回復性的織物。另外,由包含空氣變形紗之織物製造的服裝較長時間保持其形狀。It has been found that producing this core fiber and a second polyamide or polyester fiber (preferably loosely wound around the outside of the core fiber) via air-jet texturing produces a synthetic yarn that is visually similar to cotton yarn, has high crimp shrinkage, high elasticity and a high potential elongation of about 20% to about 33% on the yarn. Furthermore, fabrics comprising this air textured yarn unexpectedly exhibit a cooling and drying effect as well as a good hand. It has been found that using the air textured yarns of the present invention, it is possible to prepare fabrics with higher stretch and recovery properties than the original SUPPLEX® fabric made with 100% polyamide textured yarns. In addition, garments made from fabrics comprising air textured yarns retain their shape for longer periods of time.
織物之「涼爽效果」意謂織物之觸感為清涼的,其增強由此類織物製備之服裝的舒適性。The "cooling effect" of a fabric means that the feel of the fabric is cool to the touch, which enhances the comfort of garments made from such fabrics.
織物之「乾燥效果」意謂吸濕能力或濕氣管理能力,其增強由此類織物製備之服裝的舒適性。"Drying effect" of a fabric means the ability to absorb moisture or manage moisture which enhances the comfort of garments made from such fabrics.
織物之「手感(hand/hand touch)」係指織物之觸感或觸覺美感。由本發明之空氣變形紗製成之織物為類似軟棉之手感。特定言之,當利用本發明之紗製得時,針織織物之手感出乎意料地柔軟。舉例而言,用本發明之紗製得之圓形針織物具有極佳柔軟手感以及極佳拉伸性及回復性,其與當針織物完全由雙組分纖維製成時所觀測到之通常『硬性』手感有明顯對比。The "hand/hand touch" of a fabric refers to the tactile or tactile aesthetics of the fabric. The fabric made from the air textured yarn of the present invention has a soft cotton-like feel. In particular, knitted fabrics have an unexpectedly soft hand when made using the yarns of the invention. For example, circular knitted fabrics made with the yarns of the present invention have an excellent soft hand as well as excellent stretch and recovery properties, which are in contrast to those normally observed when knitted fabrics are made entirely of bicomponent fibers. There is a clear contrast to the "hard" feel.
此外,本文描述之芯纖維及聚醯胺或聚酯纖維之空氣變形方法允許經由生態無害及可持續方法生產原胚布(灰色與米色混合)與黑色組分之混合物,及100%黑色形式。Furthermore, the air texturing method of the core fiber and polyamide or polyester fibers described herein allows the production of mixtures of greige (gray and beige mixed) with black components, and 100% black forms, via an ecologically sound and sustainable method.
本發明之空氣變形紗可單獨編織成織物,或用作熟習此項技術者熟知之一或多種伴隨紗的緯紗或經紗,供用於多種織物。此類織物可製成各種製品,包括但決不限於服裝諸如上裝、下裝包括粗斜紋布牛仔褲、針織襪、無縫服裝、頭飾、內衣、手套及制服。The air textured yarns of the present invention can be woven into fabrics alone, or used as weft or warp yarns with one or more companion yarns well known to those skilled in the art, for use in a variety of fabrics. Such fabrics can be made into a variety of articles including, but in no way limited to, apparel such as tops, bottoms including denim jeans, hosiery, seamless garments, headwear, underwear, gloves, and uniforms.
以下實施例展現本發明及其用於製造織物及服裝之能力。本發明能夠實現其他及不同實施例,且能夠在不背離本發明之範疇及精神的情況下在各種顯而易見的態樣中對其若干細節加以修改。因此,認為實例為說明性的且非限制性的。 實例 實例 1 :測試紗之例示性範圍 The following examples demonstrate the invention and its ability to be used to make fabrics and garments. The invention is capable of other and different embodiments, and its several details are capable of modifications in various obvious respects, all without departing from the scope and spirit of the invention. Accordingly, the examples are considered to be illustrative and not restrictive. Examples Example 1 : Exemplary Range of Tested Yarns
如表1中所示,製備且評估包含雙組分2G-T//3G-T纖維於芯處及聚醯胺POY 6.6之空氣變形紗的測試樣品1至6。
表 1
相比之下,參見表2,展示對伸長率顯著降低之100%聚醯胺紗的比較性分析。
表 2
測試1:用於牛仔褲(下裝)之粗斜紋布織物Test 1: Denim fabric for jeans (bottoms)
織物結構: 粗斜紋布-斜紋 3×1經紗:棉16/1 Ne-6300經紗 Fabric Construction: Denim - twill 3×1 Warp: Cotton 16/1 Ne-6300 Warp
緯紗:空氣變形紗465/204分德士(23% PA66 + 77% 2G-T//3G-T - 17緯紗/cm)Weft: Air textured yarn 465/204 cents (23% PA66 + 77% 2G-T//3G-T - 17 picks/cm)
織機處之織物寬度:208 cm BO後之織物寬度:151 cm市售織物寬度:150 cmFabric width at loom: 208 cm Fabric width after BO: 151 cm Commercially available fabric width: 150 cm
洗滌後之織物伸長率:24%Fabric elongation after washing: 24%
對此織物之分析結果展示於表3中。
表 3
測試2:用於上裝(輕)之粗斜紋布織物Test 2: Denim fabric for tops (light)
織物結構:粗斜紋布-斜紋2×1經紗:棉20/1 Ne-5664經紗Fabric Construction: Denim - Twill 2×1 Warp: Cotton 20/1 Ne-5664 Warp
緯紗:空氣變形紗285/136分德士(37% PA66 + 63 2G-T//3G-T) - 18緯紗/cm織機處之織物寬度:170 cmWeft: Air Textured Yarn 285/136 centaxi (37% PA66 + 63 2G-T//3G-T) - 18 Weft/cm Fabric Width at Loom: 170 cm
BO後之織物寬度:140 cmFabric width after BO: 140 cm
市售織物寬度:136 cm洗滌後之織物伸長率:24%Commercially available fabric width: 136 cm Fabric elongation after washing: 24%
對此織物之分析結果展示於表4中。
表 4
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US6548429B2 (en) | 2000-03-01 | 2003-04-15 | E. I. Du Pont De Nemours And Company | Bicomponent effect yarns and fabrics thereof |
MXPA04002719A (en) * | 2001-09-28 | 2004-07-05 | Du Pont | Hetero-composite yarn, fabrics thereof and methods of making. |
KR20110029373A (en) * | 2009-09-15 | 2011-03-23 | (주) 배명 | Airtextured yarn for bag sheet having deep color and process of producing thereof |
-
2022
- 2022-03-23 BR BR112023019595A patent/BR112023019595A2/en unknown
- 2022-03-23 KR KR1020237036098A patent/KR20230160346A/en unknown
- 2022-03-23 TW TW111110727A patent/TW202307301A/en unknown
- 2022-03-23 WO PCT/US2022/021454 patent/WO2022204222A1/en active Application Filing
- 2022-03-23 CN CN202280029806.6A patent/CN117178085A/en active Pending
- 2022-03-23 EP EP22715906.8A patent/EP4314399A1/en active Pending
- 2022-03-23 JP JP2023558561A patent/JP2024513768A/en active Pending
- 2022-03-23 MX MX2023011295A patent/MX2023011295A/en unknown
Also Published As
Publication number | Publication date |
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JP2024513768A (en) | 2024-03-27 |
BR112023019595A2 (en) | 2023-11-14 |
CN117178085A (en) | 2023-12-05 |
KR20230160346A (en) | 2023-11-23 |
EP4314399A1 (en) | 2024-02-07 |
MX2023011295A (en) | 2023-10-05 |
WO2022204222A1 (en) | 2022-09-29 |
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